The paper discusses the performance of RGB and L-based supervised classification techniques using multispectral satellite imagery to assess land use and land cover in the Kiliyar sub-basin of the Palar River in Tamil Nadu. It emphasizes remote sensing data and GIS methods to create accurate classifications of different land cover types, employing various classification algorithms including maximum likelihood, minimum distance, and parallel piped classifications. The study aims to enhance the application of multispectral data for environmental monitoring and management through effective image classification techniques.