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E-Waste, Health &
Environment
Dr. Mahmoud M. Amr
Professor of Occupational & Environmental Medicine
Prime Founder, Ex-Director & Consultant of the
National Toxicology Center NECTR
Faculty of Medicine – Cairo University.
President of the National Toxicology Committee (NTC)
Academy of Scientific Research & Technology (ASRT)
Cairo, Egypt
Introduction
Environmental Protection
 Env. Medicine.
 Health Protection Agency.
 Outdoor air pollution.
 Indoor air Pollution.
 Water Pollution.
 Soil Pollution.
 Food contamination.
AMR 2019 2
Ecosystem
disturbances
 Env. Medicine:
Exposures Routes Inhalative
Ingestion
Dermal etc.
Quantification
Outcome
Control
Assessment & health impact
AMR 2019 3
 Health Protection Agency:
i.e. EEAA in Egypt and EPA in
USA.
AMR 2019 4
 Outdoor Pollution : (Air Pollution)
Particles autoexhoust
Industry
Power generation
Natural (i.e volcanoes)
Gases So2
NO2
Ozone (O3)
CO
AMR 2019 5
- Others: Carcinogen (i.e benzene)
Heavy metals lead
Mercury etc.
Health Effects
Mortality Asthma Lung
cancer mothers
"Long-term exposure"
Hospital admission Morbidity
AMR 2019 6
 Indoor air Pollution
- Tobacco smoke - NO2
- Allergens - CO
- Fumes - Ozone
- Dust - Kerosene
- Microorganisms - fuel combustion
- Endotoxins - volatile
substances
- Radon
Health Effects
AMR 2019 7
Health Effects
Respiratory Asthma
Symptoms
Lung cancer COPD
AMR 2019 8
 Water Pollution:
˗ Arsenic
˗ Fluoride
˗ Lead
˗ Organic chemicals
˗ Others Nitrates
Chlorine
Endocrine disruptors
* Drugs & hormones
AMR 2019 9
Pesticides
Solvents
POPs
Soil Pollution
- Soil Contaminants
Heavy Metals
Asbestos
Cyanide POP's
From e-waste incineration
Disposal of e-waste
liquids.
AMR 2019 10
Food Contamination:
from waste dumps
Agents: Cadmium, mercury,
lead and solvents.
AMR 2019 11
Health hazards caused by e-waste
disposal
Causes of E-waste generation
◦ Upgrade
◦ Lifestyle changes
◦ End of usage
Health hazards – improper e-waste disposal
effects
◦ Reproductive issues
◦ Developmental problems
◦ Damage to the immune system
◦ Interference with regulatory hormones
◦ Damage to the nervous system
◦ Kidney damage
◦ lung cancer
AMR 2019 12
◦ Chronic beryllium disease
◦ Skin diseases
◦ Cadmium accumulations on liver and
kidney
◦ Asthmatic bronchitis
◦ DNA damage
◦ Muscle weakness
◦ Endocrine system disruption
E-waste management – who’s
responsible?
1. The Government
2. Equipment Manufacturers
3. The Society
AMR 2019 13
Electronic waste
 Electronic waste or ̏ e-waste ̋ of electrical or electronic devices:
◦ Reuse
◦ Resale
◦ Recycling
◦ or disposal
 Informal processing of e-waste in developing countries can lead
to adverse human health effects and environmental pollution.
 E-waste contains potentially harmful materials such
as lead, cadmium, beryllium, etc...
 E-waste involve significant risk to health of workers and
communities
 Great care must be taken to avoid unsafe exposure in recycling
operations and leaking of materials such as heavy metals
from landfills and incinerator ashes.
AMR 2019 14
• E-waste Environmental impact
&
 Its Human health and safety effects
among:-
◦ Residents living near the recycling sites
◦ Prenatal exposure and neonates' health
◦ Children
◦ E-waste recycling workers
AMR 2019 15
AMR 2019 16
"Ghana E-Waste Country
Assessment", found that of
215,000 tons of electronics
imported to Ghana, 80% of the
imports into Ghana were being
burned in primitive conditions.
AMR 2019 17
Amount of electronic waste
worldwide
 In 2006, the United Nations estimated
the amount of worldwide electronic
waste discarded each year to be 50
million metric tons.
 The amount of e-waste could rise by
as much as 500 percent over the next
decade.
 Electrical waste contains hazardous
but also valuable and scarce
materials.
 In the United States, an estimated 70%
of heavy metals in landfills comes from
AMR 2019 18
Global trade issues
 Transfer of pollution-generating
activities, such as smelting of copper
wire & electronic waste is being sent
to developing countries for
processing, sometimes illegally. Many
laptops are routed to developing
nations as “dumping grounds for e-
waste”.
 BASEL Action Network estimates
that about 80% of the electronic waste
directed to recycling in the U.S. does
not get recycled there at all but in
developing countries.
AMR 2019 19
 Thousands of men, women, and
children are employed in reuse,
repair, and re-manufacturing.
 China:
Uncontrolled burning, disassembly, and
disposal has led to a number of
environmental problems such as
groundwater contamination,
atmospheric pollution, and water
pollution either by immediate discharge
or from surface runoff (especially near
coastal areas), as well as health
problems including occupational safety
and health effects among those directly
and indirectly involved, due to the
methods of processing the waste.
AMR 2019 20
Other informal e-waste recycling
sites:
India
Nigeria
Philippines
AMR 2019 21
Environmental impact
 The processes of disposing of electronic waste in
developing countries led to a number of
environmental impacts as liquid and atmospheric
releases end up in bodies of water, groundwater,
soil, and air and therefore in land and sea
animals, in crops eaten by both animals and
human, and in drinking water.
< ECOSYSTEM Changes >
AMR 2019 22
 Environmental effects:-
◦ Airborne dioxins.
◦ Levels of carcinogens in cadmium, copper,
nickel, and lead.
◦ Heavy metals ̋ lead ̏ over 300 times
Ghana found a presence of lead levels as high
as 18,125 ppm in the soil.
US EPA standard for lead in soil is
400 ppm -1200 ppm.
AMR 2019 23
The environmental impact of the processing of
different electronic waste components
AMR 2019 24
E-waste Component Potential Environmental Hazard
• Cathode ray tubes (used
in TVs)
Lead, barium and other heavy metals
leaching into the ground water and
release of toxic phosphor
• Board
Air emissions and discharge into rivers
of glass dust, tin, lead, brominated
dioxin, beryllium cadmium, and mercury
• Chips
PAHs, heavy metals, brominated flame
retardants discharged directly into rivers
acidifying fish and flora. Tin and lead
contamination of surface and groundwater. Air
emissions of brominated dioxins, heavy
metals, and PAHs
• Plastics Emissions of brominated dioxins, heavy
metals, and hydrocarbons
• Computer PAHs released into air, water, and soil.
E-waste Management
Recycling
 Recycling is an essential element of e-waste
management.
 The circuit boards contain such precious metals as gold,
silver, platinum and metals as copper, iron, aluminum, etc.
 Properly disposing of or reusing electronics can help
prevent health problems, reduce greenhouse-gas
emissions, and create jobs, offer a more environmentally
friendly and socially conscious alternative
to downcycling processes.AMR 2019 25
Consumer awareness efforts
The U.S. Environmental Protection Agency
encourages
electronic recyclers to become certified.
The Certified Electronics Recycler program for
electronic
recyclers is a comprehensive, integrated management
system standard that incorporates key operational and
continual improvement elements for quality,
environmental
and health and safety performance.
There have also been efforts to raise awareness of
AMR 2019 26
Benefits of recycling
1. Reuse of various materials “ferrous (iron-
based) and non-ferrous metals, glass, and
various types of plastic.”
2. Avoid Air and Water Pollution.
3. Reduce of Greenhouse gas emissions.
AMR 2019 27
Electronic waste substances
 Fiberglass, PCBs, PVC (polyvinyl
chlorides), thermosetting plastics, lead, tin,
copper, silicon, beryllium, carbon, iron, and
aluminum.
 Cadmium, mercury, and thallium.
 Americium, antimony, arsenic, barium, bismuth,
boron, cobalt, europium, gallium, germanium,
gold, indium, lithium, manganese, nickel, niobium,
palladium, platinum, rhodium, ruthenium,
selenium, silver, tantalum, terbium, thorium,
titanium, vanadium, and yttrium.
 Lead and tin (as solder) and copper (as wire
and printed circuit board tracks).AMR 2019 28
Hazardous
Non-Hazardous
Hazardous
AMR 2019 29
E-Waste Component Adverse Health Effects
Americium (The radioactive
source in smoke alarms)
Carcinogenic
Lead impaired cognitive function
behavioral disturbances
attention deficits
hyperactivity
conduct problems
and lower IQ
most damaging to children
Mercury sensory impairment
Dermatitis
memory loss
muscle weakness
fetal deficits in motor function
Attention
reduced fertility
slower growth and development.
Cadmium Severe damage to the lungs and is also
known to cause kidney damage.
Deficits in cognition, learning, behavior,
and neuromotor skills in children.
Hexavalent
chromium
Carcinogen
Cytotoxic and genotoxic effects
Inhibit cell proliferation
Sulphur liver damage
kidney damage
heart damage
eye and throat irritation
Brominated Flame
Retardants (BFRs)
impaired development of the nervous
system
thyroid problems
liver problem.
Environmental effects: similar effects as
in animals
AMR 2019 30
Perfluorooctanoic
acid (PFOA)
Hepatotoxicity
developmental toxicity
Immunotoxicity
hormonal and carcinogenic effects
abortion (miscarriage)
stillbirth.
low birth weight
Beryllium oxide lung cancer
beryllium sensitization
chronic beryllium disease
acute beryllium disease
Polyvinyl
chloride(PVC)
dioxins
pollutants in the air, water, and soil
reproductive and developmental health
effects.
AMR 2019 31
Generally non-hazardous
◦ Aluminiumn
◦ Copper
◦ Germanium
◦ Gold
◦ Lithium
◦ Nickel
◦ Silicon
◦ Tin
◦ Zinc
AMR 2019
32
Human health and safety
① Residents living near the recycling sites
o The environmental exposure due to the food, water,
and environmental contamination caused by e-waste,
because main exposure pathways: inhalation, ingestion,
and dermal contact.
o They have a higher daily intake of heavy metals and a
more serious body burden. Potential health risks include
mental health, impaired cognitive function, and general
physical health damage.
o DNA damage.
AMR 2019 33
② Prenatal exposure and neonates'
health
o Increased umbilical cord blood lead
concentration of neonates
o Adverse birth outcomes (still birth, low
birth weight, etc.) and longterm effects
such as behavioral and learning
problems of the neonates in their future
life.
AMR 2019 34
③ Children
 Children are especially sensitive to e-waste
exposure because of several reasons, size, higher
metabolism rate, larger surface area, and multiple
exposure pathways.
 Children's exposure to developmental neurotoxins
containing in e-waste such as lead, mercury,
cadmium, chromium and PBDEs can lead to a
higher risk of lower
 IQ, impaired cognitive function
 a decreased lung function of children
 impaired coagulation
 hearing loss
 decreased vaccine antibody tiltersAMR 2019 35
④ E-waste recycling workers
Hazards of recycling workers:
 crushing hazards
 hazardous energy released
 toxic metals.
AMR 2019 36
Hazards applicable to recycling in general
 Slips, trips, and falls
 Crushing hazards
 Hazardous energy released
 Cuts and lacerations
 Noise
 Toxic chemicals
OSHA has also specified some chemical components of
electronics
that can potentially do harm to e-recycling workers' health,
such as
lead, mercury, PCBs, asbestos, refractory ceramic fibers
(RCFs), and
radioactive substances.AMR 2019 37
Occupational exposure limits (OELs) of some
hazardous chemicals
AMR 2019 38
Hazardous
chemicals
OELs (mg/m^3) Type of OELs
lead (Pb)
0.05 NIOSH recommended
exposure limits (REL), time
weighted average (TWA)
mercury (Hg)
0.05
NIOSH REL, TWA
cadmium (Cd)
0.005 OSHA permissible exposure
limit (PEL), TWA
hexavalent
chromium
0.005 OSHA PEL, TWA
sulfer dioxide
5
NIOSH REL, TWA
Hazard controls
For occupational health and safety of e-
waste
recycling workers, both employers and
workers should take actions.
AMR 2019 39
Safety Measures:
Hazards What should workers do
General
wear PPE (personal protective equipment)
report anything unsafe
Dust
clean the workplace
Shower before going home
test the blood lead
use respirator
Cuts and
lacerations
using special gloves and oversleeves.
Noise
Wear the hearing protection
Lifting injuries When handling e-waste, try to decrease the
load per time.
AMR 2019 40
AMR 2019
41

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E waste, health &amp; enviroment-may2019

  • 1. E-Waste, Health & Environment Dr. Mahmoud M. Amr Professor of Occupational & Environmental Medicine Prime Founder, Ex-Director & Consultant of the National Toxicology Center NECTR Faculty of Medicine – Cairo University. President of the National Toxicology Committee (NTC) Academy of Scientific Research & Technology (ASRT) Cairo, Egypt
  • 2. Introduction Environmental Protection  Env. Medicine.  Health Protection Agency.  Outdoor air pollution.  Indoor air Pollution.  Water Pollution.  Soil Pollution.  Food contamination. AMR 2019 2 Ecosystem disturbances
  • 3.  Env. Medicine: Exposures Routes Inhalative Ingestion Dermal etc. Quantification Outcome Control Assessment & health impact AMR 2019 3
  • 4.  Health Protection Agency: i.e. EEAA in Egypt and EPA in USA. AMR 2019 4
  • 5.  Outdoor Pollution : (Air Pollution) Particles autoexhoust Industry Power generation Natural (i.e volcanoes) Gases So2 NO2 Ozone (O3) CO AMR 2019 5
  • 6. - Others: Carcinogen (i.e benzene) Heavy metals lead Mercury etc. Health Effects Mortality Asthma Lung cancer mothers "Long-term exposure" Hospital admission Morbidity AMR 2019 6
  • 7.  Indoor air Pollution - Tobacco smoke - NO2 - Allergens - CO - Fumes - Ozone - Dust - Kerosene - Microorganisms - fuel combustion - Endotoxins - volatile substances - Radon Health Effects AMR 2019 7
  • 9.  Water Pollution: ˗ Arsenic ˗ Fluoride ˗ Lead ˗ Organic chemicals ˗ Others Nitrates Chlorine Endocrine disruptors * Drugs & hormones AMR 2019 9 Pesticides Solvents POPs
  • 10. Soil Pollution - Soil Contaminants Heavy Metals Asbestos Cyanide POP's From e-waste incineration Disposal of e-waste liquids. AMR 2019 10
  • 11. Food Contamination: from waste dumps Agents: Cadmium, mercury, lead and solvents. AMR 2019 11
  • 12. Health hazards caused by e-waste disposal Causes of E-waste generation ◦ Upgrade ◦ Lifestyle changes ◦ End of usage Health hazards – improper e-waste disposal effects ◦ Reproductive issues ◦ Developmental problems ◦ Damage to the immune system ◦ Interference with regulatory hormones ◦ Damage to the nervous system ◦ Kidney damage ◦ lung cancer AMR 2019 12 ◦ Chronic beryllium disease ◦ Skin diseases ◦ Cadmium accumulations on liver and kidney ◦ Asthmatic bronchitis ◦ DNA damage ◦ Muscle weakness ◦ Endocrine system disruption
  • 13. E-waste management – who’s responsible? 1. The Government 2. Equipment Manufacturers 3. The Society AMR 2019 13
  • 14. Electronic waste  Electronic waste or ̏ e-waste ̋ of electrical or electronic devices: ◦ Reuse ◦ Resale ◦ Recycling ◦ or disposal  Informal processing of e-waste in developing countries can lead to adverse human health effects and environmental pollution.  E-waste contains potentially harmful materials such as lead, cadmium, beryllium, etc...  E-waste involve significant risk to health of workers and communities  Great care must be taken to avoid unsafe exposure in recycling operations and leaking of materials such as heavy metals from landfills and incinerator ashes. AMR 2019 14
  • 15. • E-waste Environmental impact &  Its Human health and safety effects among:- ◦ Residents living near the recycling sites ◦ Prenatal exposure and neonates' health ◦ Children ◦ E-waste recycling workers AMR 2019 15
  • 17. "Ghana E-Waste Country Assessment", found that of 215,000 tons of electronics imported to Ghana, 80% of the imports into Ghana were being burned in primitive conditions. AMR 2019 17
  • 18. Amount of electronic waste worldwide  In 2006, the United Nations estimated the amount of worldwide electronic waste discarded each year to be 50 million metric tons.  The amount of e-waste could rise by as much as 500 percent over the next decade.  Electrical waste contains hazardous but also valuable and scarce materials.  In the United States, an estimated 70% of heavy metals in landfills comes from AMR 2019 18
  • 19. Global trade issues  Transfer of pollution-generating activities, such as smelting of copper wire & electronic waste is being sent to developing countries for processing, sometimes illegally. Many laptops are routed to developing nations as “dumping grounds for e- waste”.  BASEL Action Network estimates that about 80% of the electronic waste directed to recycling in the U.S. does not get recycled there at all but in developing countries. AMR 2019 19
  • 20.  Thousands of men, women, and children are employed in reuse, repair, and re-manufacturing.  China: Uncontrolled burning, disassembly, and disposal has led to a number of environmental problems such as groundwater contamination, atmospheric pollution, and water pollution either by immediate discharge or from surface runoff (especially near coastal areas), as well as health problems including occupational safety and health effects among those directly and indirectly involved, due to the methods of processing the waste. AMR 2019 20
  • 21. Other informal e-waste recycling sites: India Nigeria Philippines AMR 2019 21
  • 22. Environmental impact  The processes of disposing of electronic waste in developing countries led to a number of environmental impacts as liquid and atmospheric releases end up in bodies of water, groundwater, soil, and air and therefore in land and sea animals, in crops eaten by both animals and human, and in drinking water. < ECOSYSTEM Changes > AMR 2019 22
  • 23.  Environmental effects:- ◦ Airborne dioxins. ◦ Levels of carcinogens in cadmium, copper, nickel, and lead. ◦ Heavy metals ̋ lead ̏ over 300 times Ghana found a presence of lead levels as high as 18,125 ppm in the soil. US EPA standard for lead in soil is 400 ppm -1200 ppm. AMR 2019 23
  • 24. The environmental impact of the processing of different electronic waste components AMR 2019 24 E-waste Component Potential Environmental Hazard • Cathode ray tubes (used in TVs) Lead, barium and other heavy metals leaching into the ground water and release of toxic phosphor • Board Air emissions and discharge into rivers of glass dust, tin, lead, brominated dioxin, beryllium cadmium, and mercury • Chips PAHs, heavy metals, brominated flame retardants discharged directly into rivers acidifying fish and flora. Tin and lead contamination of surface and groundwater. Air emissions of brominated dioxins, heavy metals, and PAHs • Plastics Emissions of brominated dioxins, heavy metals, and hydrocarbons • Computer PAHs released into air, water, and soil.
  • 25. E-waste Management Recycling  Recycling is an essential element of e-waste management.  The circuit boards contain such precious metals as gold, silver, platinum and metals as copper, iron, aluminum, etc.  Properly disposing of or reusing electronics can help prevent health problems, reduce greenhouse-gas emissions, and create jobs, offer a more environmentally friendly and socially conscious alternative to downcycling processes.AMR 2019 25
  • 26. Consumer awareness efforts The U.S. Environmental Protection Agency encourages electronic recyclers to become certified. The Certified Electronics Recycler program for electronic recyclers is a comprehensive, integrated management system standard that incorporates key operational and continual improvement elements for quality, environmental and health and safety performance. There have also been efforts to raise awareness of AMR 2019 26
  • 27. Benefits of recycling 1. Reuse of various materials “ferrous (iron- based) and non-ferrous metals, glass, and various types of plastic.” 2. Avoid Air and Water Pollution. 3. Reduce of Greenhouse gas emissions. AMR 2019 27
  • 28. Electronic waste substances  Fiberglass, PCBs, PVC (polyvinyl chlorides), thermosetting plastics, lead, tin, copper, silicon, beryllium, carbon, iron, and aluminum.  Cadmium, mercury, and thallium.  Americium, antimony, arsenic, barium, bismuth, boron, cobalt, europium, gallium, germanium, gold, indium, lithium, manganese, nickel, niobium, palladium, platinum, rhodium, ruthenium, selenium, silver, tantalum, terbium, thorium, titanium, vanadium, and yttrium.  Lead and tin (as solder) and copper (as wire and printed circuit board tracks).AMR 2019 28 Hazardous Non-Hazardous
  • 29. Hazardous AMR 2019 29 E-Waste Component Adverse Health Effects Americium (The radioactive source in smoke alarms) Carcinogenic Lead impaired cognitive function behavioral disturbances attention deficits hyperactivity conduct problems and lower IQ most damaging to children Mercury sensory impairment Dermatitis memory loss muscle weakness fetal deficits in motor function Attention reduced fertility slower growth and development.
  • 30. Cadmium Severe damage to the lungs and is also known to cause kidney damage. Deficits in cognition, learning, behavior, and neuromotor skills in children. Hexavalent chromium Carcinogen Cytotoxic and genotoxic effects Inhibit cell proliferation Sulphur liver damage kidney damage heart damage eye and throat irritation Brominated Flame Retardants (BFRs) impaired development of the nervous system thyroid problems liver problem. Environmental effects: similar effects as in animals AMR 2019 30
  • 31. Perfluorooctanoic acid (PFOA) Hepatotoxicity developmental toxicity Immunotoxicity hormonal and carcinogenic effects abortion (miscarriage) stillbirth. low birth weight Beryllium oxide lung cancer beryllium sensitization chronic beryllium disease acute beryllium disease Polyvinyl chloride(PVC) dioxins pollutants in the air, water, and soil reproductive and developmental health effects. AMR 2019 31
  • 32. Generally non-hazardous ◦ Aluminiumn ◦ Copper ◦ Germanium ◦ Gold ◦ Lithium ◦ Nickel ◦ Silicon ◦ Tin ◦ Zinc AMR 2019 32
  • 33. Human health and safety ① Residents living near the recycling sites o The environmental exposure due to the food, water, and environmental contamination caused by e-waste, because main exposure pathways: inhalation, ingestion, and dermal contact. o They have a higher daily intake of heavy metals and a more serious body burden. Potential health risks include mental health, impaired cognitive function, and general physical health damage. o DNA damage. AMR 2019 33
  • 34. ② Prenatal exposure and neonates' health o Increased umbilical cord blood lead concentration of neonates o Adverse birth outcomes (still birth, low birth weight, etc.) and longterm effects such as behavioral and learning problems of the neonates in their future life. AMR 2019 34
  • 35. ③ Children  Children are especially sensitive to e-waste exposure because of several reasons, size, higher metabolism rate, larger surface area, and multiple exposure pathways.  Children's exposure to developmental neurotoxins containing in e-waste such as lead, mercury, cadmium, chromium and PBDEs can lead to a higher risk of lower  IQ, impaired cognitive function  a decreased lung function of children  impaired coagulation  hearing loss  decreased vaccine antibody tiltersAMR 2019 35
  • 36. ④ E-waste recycling workers Hazards of recycling workers:  crushing hazards  hazardous energy released  toxic metals. AMR 2019 36
  • 37. Hazards applicable to recycling in general  Slips, trips, and falls  Crushing hazards  Hazardous energy released  Cuts and lacerations  Noise  Toxic chemicals OSHA has also specified some chemical components of electronics that can potentially do harm to e-recycling workers' health, such as lead, mercury, PCBs, asbestos, refractory ceramic fibers (RCFs), and radioactive substances.AMR 2019 37
  • 38. Occupational exposure limits (OELs) of some hazardous chemicals AMR 2019 38 Hazardous chemicals OELs (mg/m^3) Type of OELs lead (Pb) 0.05 NIOSH recommended exposure limits (REL), time weighted average (TWA) mercury (Hg) 0.05 NIOSH REL, TWA cadmium (Cd) 0.005 OSHA permissible exposure limit (PEL), TWA hexavalent chromium 0.005 OSHA PEL, TWA sulfer dioxide 5 NIOSH REL, TWA
  • 39. Hazard controls For occupational health and safety of e- waste recycling workers, both employers and workers should take actions. AMR 2019 39
  • 40. Safety Measures: Hazards What should workers do General wear PPE (personal protective equipment) report anything unsafe Dust clean the workplace Shower before going home test the blood lead use respirator Cuts and lacerations using special gloves and oversleeves. Noise Wear the hearing protection Lifting injuries When handling e-waste, try to decrease the load per time. AMR 2019 40