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WASTEWATER GENERATION
 The dairy industry is one of the most
polluting of industries, not only in terms of
the volume of effluent generated, but also in
terms of its characteristics as well.
 A chain of operations involving receiving
and storing of raw materials, processing of
raw materials into finished products,
packaging and storing of finished products,
and a group of other ancillary operations
(e.g., heat transfer and cleaning) will
produce wastewater.
 In the dairy industry, some amount of
wastewater gets produced during starting,
equilibrating, stopping, and rinsing of the
processing units. However, a majority of
wastewater gets produced during cleaning
operations, especially between product
changes when different types of products are
produced in a specific production unit and
clean-up operations. Dairy processing effluents
are generated in an intermittent way and the
flow rates of these effluents change
significantly. The quality and quantity of the
product content in the dairy wastewater at a
given time changes with the application of
another technological cycle in the processing
line.
SOURCES OF WASTEWATER
DAIRY PROCESS SOURCES OF WASTE
Preparation stages
1) Milk receiving/storage.
2) Pasteurization/Ultra heat
treatment
 Poor drainage of tankers
 Spills and leaks from
pipes
 Foaming
 Spils from storage tanks
 Cleaning operations
 Liquid losses
 Foaming
 Recovery of downgraded
product
 Cleaning operations
 Deposits on surface of
heating equipment.
3) Homogenisation
4) Separation/Clarification
Product Processing
Stage
5) Market milk
 Liquid losses/leaks
 Cleaning operations
 Foaming
 Pipe leaks
 Product washing
 Sludge removal from
clarifier
 Damaged milk packages
 Overfilling
 Poor drainage
 Cleaning of filling
machinery
 Leaks
 Cleaning operations
6) Cheese Making
7) Butter Making
8) Milk powder manufacture
 Overfilling vats
 Incomplete separation of
whey from curd
 Using salt in cheese
making
 Product washing
 Vacreation( reduced
pressure pasteurization
using stream) and salt use.
Spills of powder handling
 Start up and shut down
losses
 Plant malfunction
 Stack losses
 Cleaning of evaporators
and driers
 Bagging losses
EFFLUENT GENERATION FROM VARIOUS UNITS
OF MILK OPERATION
CLARIFICATION/STANDARDIZATION
STORAGE TANK
RECEIVING
PASTEURIZATION
HOMOGENISATION
DEODORISATION
STORAGE TANK
PACKING
STORAGE
TRANSPORTATION
DS
WW
DS WW
DSWW
DS WW,CW,ST
DS WW
ST, DS WW
DS WW
DS WW
DS WW
EF
EF
EF
EF
EF
EF
EF
EF
EF
EF
DS-Detergents and Sanitizing Agents, WW-Wash Water, ST-Steam, CW-Cooling Water.
CHARACTERISTICS OF WASTE WATER
 Dairy wastewater contains milk solids, detergents,
sanitizers, milk wastes, and cleaning water.
 It is characterized by high concentrations of nutrients,
and organic and inorganic contents.
 Salting activities during cheese production may result in
high salinity levels.
 Wastewater may also contain acids, alkali with a number
of active ingredients, and disinfectants, as well as a
significant microbiological load, pathogenic viruses, and
bacteria.
 Other wastewater streams include cooling water from
Parameters UNITS GUIDELINE VALUE
pH - 4-12
Suspended solids mg/l 24-5700
BOD5 mg/l 450-4,790
COD mg/l 80 - 95000
Total nitrogen mg/l 15-180
Total phosphorus mg/l 11-160
Oil and grease mg/l 10
Total coliform bacteria Mpn/100ml 400
Magnesium mg/l 25-49
Potassium mg/l 11-160
Chloride mg/l 48-469
Calcium mg/l 57-112
BIS GUIDELINES OF PARAMETERS
BOD : COD RATIO
BOD:COD Ratio of Milk Constituents
0
0.2
0.4
0.6
0.8
1
1.2
1.4
Whole
Milk
Skim
Milk
Butter
Milk
Whey
Lactose
Casein
Whey
Protein
Fat
Constituents
BOD:COD
TREATMENT METHODS
 Primary:
i. Physical
Treatment
ii. Chemical
Treatment
 Secondary:
i. Biological
Treatment
ii. Chemical
Treatment
iii. Membrane
Method
iv. Electrolytic
Method
Primary Treatment
Secondary Treatment
Aerobic Process of Treatment
ANAEROBIC PROCESS OF
TREATMENT
• Conventional Anaerobic Digester
• Anaerobic Contact Digester
• Anaerobic Fixed Film Reactor
• Up flow Anaerobic Sludge Blanket
• Two Phase / Hybrid Reactor
• Combined - Anaerobic & Aerobic
Process
Chemical Treatment
• It can reduce COD by 78% and BOD by 84%.
Membrane Method:
• It can reclaim Valuable milk solids or
chemicals for resale, reuse or less expensive
method.
Electrolytic Method
Miscellaneous and Modified Method
TERTIARY
TREATMENT(Optional)
BIOLOGICAL TREATMENT
Aerobic Anaerobic
Applicability low strength: low, medium and high strength:
(BOD, mg/l) (100 - 2000 mg/l) (250 - > 100.000 mg/l)
BOD-removal: 93-99% 90%
NH3-conversion: 95% low
NO3-removal: 90%* high
Advantage Disadvantage
Anaer
obic
* possible production of energy
* low need for land
* power failure or shutdown will not
affect the system
* no energy consumption
* low production of excess sludge
* optimal process temperature is about 30°C
* post-treatment for BOD-removal is often
required
Aerob
ic
* low process temperature
* end treatment of waste-water
* energy need for aeration
* high need for land
* power failure or shutdown will affect the
entire system
* post-treatment for further nutrient removal is
often required
* high production of excess sludge

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Dairy Industry Waste & its treatment

  • 1.
  • 2. WASTEWATER GENERATION  The dairy industry is one of the most polluting of industries, not only in terms of the volume of effluent generated, but also in terms of its characteristics as well.  A chain of operations involving receiving and storing of raw materials, processing of raw materials into finished products, packaging and storing of finished products, and a group of other ancillary operations (e.g., heat transfer and cleaning) will produce wastewater.
  • 3.  In the dairy industry, some amount of wastewater gets produced during starting, equilibrating, stopping, and rinsing of the processing units. However, a majority of wastewater gets produced during cleaning operations, especially between product changes when different types of products are produced in a specific production unit and clean-up operations. Dairy processing effluents are generated in an intermittent way and the flow rates of these effluents change significantly. The quality and quantity of the product content in the dairy wastewater at a given time changes with the application of another technological cycle in the processing line.
  • 4. SOURCES OF WASTEWATER DAIRY PROCESS SOURCES OF WASTE Preparation stages 1) Milk receiving/storage. 2) Pasteurization/Ultra heat treatment  Poor drainage of tankers  Spills and leaks from pipes  Foaming  Spils from storage tanks  Cleaning operations  Liquid losses  Foaming  Recovery of downgraded product  Cleaning operations  Deposits on surface of heating equipment.
  • 5. 3) Homogenisation 4) Separation/Clarification Product Processing Stage 5) Market milk  Liquid losses/leaks  Cleaning operations  Foaming  Pipe leaks  Product washing  Sludge removal from clarifier  Damaged milk packages  Overfilling  Poor drainage  Cleaning of filling machinery  Leaks  Cleaning operations
  • 6. 6) Cheese Making 7) Butter Making 8) Milk powder manufacture  Overfilling vats  Incomplete separation of whey from curd  Using salt in cheese making  Product washing  Vacreation( reduced pressure pasteurization using stream) and salt use. Spills of powder handling  Start up and shut down losses  Plant malfunction  Stack losses  Cleaning of evaporators and driers  Bagging losses
  • 7. EFFLUENT GENERATION FROM VARIOUS UNITS OF MILK OPERATION CLARIFICATION/STANDARDIZATION STORAGE TANK RECEIVING PASTEURIZATION HOMOGENISATION DEODORISATION STORAGE TANK PACKING STORAGE TRANSPORTATION DS WW DS WW DSWW DS WW,CW,ST DS WW ST, DS WW DS WW DS WW DS WW EF EF EF EF EF EF EF EF EF EF DS-Detergents and Sanitizing Agents, WW-Wash Water, ST-Steam, CW-Cooling Water.
  • 8. CHARACTERISTICS OF WASTE WATER  Dairy wastewater contains milk solids, detergents, sanitizers, milk wastes, and cleaning water.  It is characterized by high concentrations of nutrients, and organic and inorganic contents.  Salting activities during cheese production may result in high salinity levels.  Wastewater may also contain acids, alkali with a number of active ingredients, and disinfectants, as well as a significant microbiological load, pathogenic viruses, and bacteria.  Other wastewater streams include cooling water from
  • 9. Parameters UNITS GUIDELINE VALUE pH - 4-12 Suspended solids mg/l 24-5700 BOD5 mg/l 450-4,790 COD mg/l 80 - 95000 Total nitrogen mg/l 15-180 Total phosphorus mg/l 11-160 Oil and grease mg/l 10 Total coliform bacteria Mpn/100ml 400 Magnesium mg/l 25-49 Potassium mg/l 11-160 Chloride mg/l 48-469 Calcium mg/l 57-112 BIS GUIDELINES OF PARAMETERS
  • 10. BOD : COD RATIO BOD:COD Ratio of Milk Constituents 0 0.2 0.4 0.6 0.8 1 1.2 1.4 Whole Milk Skim Milk Butter Milk Whey Lactose Casein Whey Protein Fat Constituents BOD:COD
  • 11. TREATMENT METHODS  Primary: i. Physical Treatment ii. Chemical Treatment  Secondary: i. Biological Treatment ii. Chemical Treatment iii. Membrane Method iv. Electrolytic Method
  • 14. Aerobic Process of Treatment
  • 15. ANAEROBIC PROCESS OF TREATMENT • Conventional Anaerobic Digester • Anaerobic Contact Digester • Anaerobic Fixed Film Reactor • Up flow Anaerobic Sludge Blanket • Two Phase / Hybrid Reactor • Combined - Anaerobic & Aerobic Process
  • 16.
  • 17. Chemical Treatment • It can reduce COD by 78% and BOD by 84%. Membrane Method: • It can reclaim Valuable milk solids or chemicals for resale, reuse or less expensive method. Electrolytic Method Miscellaneous and Modified Method
  • 19. BIOLOGICAL TREATMENT Aerobic Anaerobic Applicability low strength: low, medium and high strength: (BOD, mg/l) (100 - 2000 mg/l) (250 - > 100.000 mg/l) BOD-removal: 93-99% 90% NH3-conversion: 95% low NO3-removal: 90%* high
  • 20. Advantage Disadvantage Anaer obic * possible production of energy * low need for land * power failure or shutdown will not affect the system * no energy consumption * low production of excess sludge * optimal process temperature is about 30°C * post-treatment for BOD-removal is often required Aerob ic * low process temperature * end treatment of waste-water * energy need for aeration * high need for land * power failure or shutdown will affect the entire system * post-treatment for further nutrient removal is often required * high production of excess sludge