1. An industrial test was conducted at a Prista blending plant in Bulgaria to evaluate the effectiveness of a cavitation cold blending (CCBL) unit for blending various types of lubricants as an alternative to mechanical blending.
2. Several tests were run blending engine oils, marine cylinder oils, hydraulic oils, and industrial gear oils using the CCBL unit. Samples were taken and analyzed to compare results to specifications.
3. The test results found the lubricants blended using the CCBL unit met specifications and laboratory analysis found the samples were homogeneous. The CCBL unit was able to blend the lubricants in less time than traditional mechanical blending.
Food waste and food processing waste for renewable energy productionLPE Learning Center
Full proceedings at: http://www.extension.org/72790 This high efficient and low-cost eggshell catalyst could make the process of biodiesel production economic and fully ecologically friendly. The ecologically friendly and economic process could effectively reduce the processing cost of biodiesel, making it competitive with petroleum diesel.
BENFIELD LIQUOR:Determination of Diethanolamine Using an Auto TitratorGerard B. Hawkins
BENFIELD LIQUOR:Determination of Diethanolamine Using an Auto Titrator
1 SCOPE AND FIELD OF APPLICATION
This method is suitable for the determination of diethanolamine in Benfield Liquor.
2 PRINCIPLE
Diethanolamine is converted quantitatively into ammonia by boiling in the presence of sulfuric acid and copper sulfate. The ammonia is distilled from an alkaline medium and absorbed into boric acid. The solution is titrated with standard acid.
Experimental investigation of four stroke single cylinder rope brake dynamome...Premier Publishers
The present work is focused on the effects of waste cooking oil based methyl ester and its blends with petrodiesel on a single cylinder, 4 stroke, naturally aspirated, direct injection, water cooled, rope brake dynamometer assisted CI engine at varying loads. The physical and chemical properties of WCO based methyl ester were determined using standard ASTM methods. The suitability of WCO based methyl ester and its blends were evaluated through determining the performance and emission characteristics of CI engine. These results were compared to petrodiesel for validation. By analyzing these results, it was observed that the performance and emission characteristics were shown both satisfactory and unsatisfactory results. This was due to lower calorific value and high viscosity of waste cooking oil methyl ester resulted delay in combustion. From the critical analysis, it was observed that B20 of WCO based methyl ester reserved 32.2% brake thermal efficiency slightly greater than petrodiesel i.e. 32% without any engine modifications. It is concluded that B20 of WCO based methyl ester is suitable with no modification in engine.
Naphtha Steam Reforming Catalyst Reduction with MethanolGerard B. Hawkins
Procedure for Naphtha Steam Reforming Catalyst Reduction with Methanol
Scope
This procedure applies to the in situ reduction of VULCAN Series steam reforming catalysts using methanol cracking to form hydrogen over the catalyst in the steam reformer.
The procedure is likely to be applied to plants using only heavier feeds (e.g.: LPG and/or naphtha) and some combination of VULCAN Series catalysts.
Introduction
A small number of steam reforming plants do not have an available source of the commonly used reducing media (e.g.: hydrogen, hydrogen-rich off-gas, natural gas). These plants will usually operate on LPG and/or naphtha feed only where cracking of this hydrocarbon is not usually advised for reduction of the steam reforming catalyst ...
Performance characteristics-of-single-cylinder-c-i-engine-by-using-tamarind-o...Abu Sufyan Malik
Biodiesel has become one of the most versatile alternative fuel options for diesel engine applications. The recent biodiesel research in India receives its attention towards tamarind oil based biodiesel. In the present work, biodiesel derived from the tamarind oils extracted from tamarind seeds was used as fuel in diesel engine to investigate its performance. This project presents the results of investigation carried out in studying the properties and behavior of methyl ester of tamarind oil and its blends with diesel fuel in C.I engine. Engine test have been carried out to determine the performance characteristics of tamarind oil. The tests have been carried out in a 4- stroke single cylinder, direct injection diesel engine at different loads. The loads were varied 0% to 90% of the maximum load in steps of 20%. The various blends of tamarind oil biodiesel with diesel, B20, B40, B50, B60 were used in the experiments and the results indicate that brake specific fuel consumption and break thermal efficiency were higher with B60 fuel than that of diesel. The performance parameter like brake specific fuel consumption, brake thermal efficiency, volumetric ratio, mechanical efficiency and air fuel ratio were found for above blends. The results showed that the properties of the above mentioned oils are comparable with conventional diesel. The 60% blends performed well in running a diesel engine at a constant speed of 1500 rpm. Keywords: TOME:-Tamarind Oil Methyl Ester, BSFC:- Break Specific Fuel Consumption, BSEC:- Break Specific Energy Consumption, BTE:- Break Thermal Efficiency,B20:- 20% BDF+80%DF,B40:-40%BDF+60%DF,B50:- 50% BDF+50%DF, B60:- 60% BDF+40%DFThe increasing industrialization and motorization there is a scarcity of petroleum products. So, there is need for suitable alternative fuels for diesel engines. In the present study, Tamarind seed oil methyl esters (TSOME) were prepared through Transesterification and the properties of oil were found within acceptable limits. A compression ignition engine was fuelled with three blends of TSOME (10,20 &30) with diesel on basis of volume and the performance and emission results are evaluated and compared with base line data of diesel. The performance results are shows that there is an increase in BTE and decrease in BSFC, The emission parameters are HC and smoke opacity are lower compared to the diesel. This may be accredited to improve the combustion for TSOME blends. The oxides of nitrogen emissions are almost all nearer for blends compared to the diesel fuel. Addition of DMC (Di-methyl carbonate) fuel additive as 5%, 10% and 15% volume ratios to the optimum blend as TSOME20 for evaluating the engine performance and emission parameters the main intention is to use fuel additives as improve the combustion process and reduce the emissions. Finally the results are concluded that the potentiality of the Tamarind seed methyl ester as alternative fuel for compression ignition engines.
Food waste and food processing waste for renewable energy productionLPE Learning Center
Full proceedings at: http://www.extension.org/72790 This high efficient and low-cost eggshell catalyst could make the process of biodiesel production economic and fully ecologically friendly. The ecologically friendly and economic process could effectively reduce the processing cost of biodiesel, making it competitive with petroleum diesel.
BENFIELD LIQUOR:Determination of Diethanolamine Using an Auto TitratorGerard B. Hawkins
BENFIELD LIQUOR:Determination of Diethanolamine Using an Auto Titrator
1 SCOPE AND FIELD OF APPLICATION
This method is suitable for the determination of diethanolamine in Benfield Liquor.
2 PRINCIPLE
Diethanolamine is converted quantitatively into ammonia by boiling in the presence of sulfuric acid and copper sulfate. The ammonia is distilled from an alkaline medium and absorbed into boric acid. The solution is titrated with standard acid.
Experimental investigation of four stroke single cylinder rope brake dynamome...Premier Publishers
The present work is focused on the effects of waste cooking oil based methyl ester and its blends with petrodiesel on a single cylinder, 4 stroke, naturally aspirated, direct injection, water cooled, rope brake dynamometer assisted CI engine at varying loads. The physical and chemical properties of WCO based methyl ester were determined using standard ASTM methods. The suitability of WCO based methyl ester and its blends were evaluated through determining the performance and emission characteristics of CI engine. These results were compared to petrodiesel for validation. By analyzing these results, it was observed that the performance and emission characteristics were shown both satisfactory and unsatisfactory results. This was due to lower calorific value and high viscosity of waste cooking oil methyl ester resulted delay in combustion. From the critical analysis, it was observed that B20 of WCO based methyl ester reserved 32.2% brake thermal efficiency slightly greater than petrodiesel i.e. 32% without any engine modifications. It is concluded that B20 of WCO based methyl ester is suitable with no modification in engine.
Naphtha Steam Reforming Catalyst Reduction with MethanolGerard B. Hawkins
Procedure for Naphtha Steam Reforming Catalyst Reduction with Methanol
Scope
This procedure applies to the in situ reduction of VULCAN Series steam reforming catalysts using methanol cracking to form hydrogen over the catalyst in the steam reformer.
The procedure is likely to be applied to plants using only heavier feeds (e.g.: LPG and/or naphtha) and some combination of VULCAN Series catalysts.
Introduction
A small number of steam reforming plants do not have an available source of the commonly used reducing media (e.g.: hydrogen, hydrogen-rich off-gas, natural gas). These plants will usually operate on LPG and/or naphtha feed only where cracking of this hydrocarbon is not usually advised for reduction of the steam reforming catalyst ...
Performance characteristics-of-single-cylinder-c-i-engine-by-using-tamarind-o...Abu Sufyan Malik
Biodiesel has become one of the most versatile alternative fuel options for diesel engine applications. The recent biodiesel research in India receives its attention towards tamarind oil based biodiesel. In the present work, biodiesel derived from the tamarind oils extracted from tamarind seeds was used as fuel in diesel engine to investigate its performance. This project presents the results of investigation carried out in studying the properties and behavior of methyl ester of tamarind oil and its blends with diesel fuel in C.I engine. Engine test have been carried out to determine the performance characteristics of tamarind oil. The tests have been carried out in a 4- stroke single cylinder, direct injection diesel engine at different loads. The loads were varied 0% to 90% of the maximum load in steps of 20%. The various blends of tamarind oil biodiesel with diesel, B20, B40, B50, B60 were used in the experiments and the results indicate that brake specific fuel consumption and break thermal efficiency were higher with B60 fuel than that of diesel. The performance parameter like brake specific fuel consumption, brake thermal efficiency, volumetric ratio, mechanical efficiency and air fuel ratio were found for above blends. The results showed that the properties of the above mentioned oils are comparable with conventional diesel. The 60% blends performed well in running a diesel engine at a constant speed of 1500 rpm. Keywords: TOME:-Tamarind Oil Methyl Ester, BSFC:- Break Specific Fuel Consumption, BSEC:- Break Specific Energy Consumption, BTE:- Break Thermal Efficiency,B20:- 20% BDF+80%DF,B40:-40%BDF+60%DF,B50:- 50% BDF+50%DF, B60:- 60% BDF+40%DFThe increasing industrialization and motorization there is a scarcity of petroleum products. So, there is need for suitable alternative fuels for diesel engines. In the present study, Tamarind seed oil methyl esters (TSOME) were prepared through Transesterification and the properties of oil were found within acceptable limits. A compression ignition engine was fuelled with three blends of TSOME (10,20 &30) with diesel on basis of volume and the performance and emission results are evaluated and compared with base line data of diesel. The performance results are shows that there is an increase in BTE and decrease in BSFC, The emission parameters are HC and smoke opacity are lower compared to the diesel. This may be accredited to improve the combustion for TSOME blends. The oxides of nitrogen emissions are almost all nearer for blends compared to the diesel fuel. Addition of DMC (Di-methyl carbonate) fuel additive as 5%, 10% and 15% volume ratios to the optimum blend as TSOME20 for evaluating the engine performance and emission parameters the main intention is to use fuel additives as improve the combustion process and reduce the emissions. Finally the results are concluded that the potentiality of the Tamarind seed methyl ester as alternative fuel for compression ignition engines.
Determination of Hydrogen Sulfide by Cadmium Sulfide PrecipitationGerard B. Hawkins
Plant Analytical Techniques
Gas Analysis: Determination of Hydrogen Sulfide by Cadmium Sulfide Precipitation
SCOPE AND FIELD OF APPLICATION
This method is suitable for the in situ determination of hydrogen sulfide in ammonia plant gas streams when testing is required during catalyst reduction.
PRINCIPLE
Hydrogen sulfide present in the gas precipitates cadmium sulfide from a cadmium solution. The precipitate is filtered then reacted with iodine; the excess iodine is then titrated with sodium thiosulfate.
Comparison of Supercritical Fluid Extraction with Steam Distillation for the ...inventionjournals
Bay oil, an extract of Pimenta Racemosa, is produced in Dominica by the traditional process of Steam Distillation Extraction (SDE), and commercially utilised in the perfume and food industries. The objective of the work described in this paper seeks to investigate if it could be better produced by Supercritical Fluid Extraction (SFE) using carbon dioxide as extracting fluid. Experiments were therefore carried out on a bench scale SFE unit to evaluate the extraction characteristics of bay leaves and to compare the results with those from a bench scale SDE unit. The results showed that the SFE extracts contained mainly eugenol and chavicol up to about 1 hour of extraction time, after which higher components, including waxes, were incorporated into the extracts. The optimum operating conditions were deemed to be 150 bar pressure and 50oC temperature. The SDE extracts were also mainly eugenol and chavicol, but in addition contained a significant quantity of myrcene. The extract yield from SFE after I hour was similar to that of the ultimate yield from SDE (~4.0%), but the extraction time for SDE was in excess of twice that figure. It is concluded that the higher phenol content of the SFE product together with lower extraction times makes the use of SFE potentially preferable to the traditional SDE process.
Experimental investigation and optimization study of combustion chamber geome...IJERD Editor
An experimental investigation and optimization study of various piston geometries was conducted
on Greaves single cylinder direct injection compression ignition engine using straight diesel and blends of rice
bran biodiesel. The three combustion chamber geometries used in this study were Standard toroidal piston
(STP), hemispherical bowl piston (HBP) and Shallow toroidal re-entrant piston (STRP) at compression ratios of
18:1, 19.04:1 and 16.4:1 respectively. Rice bran biodiesel was derived by two step trans-esterification process
with an optimum yield of 86% with molar ratio 1:6, 06% of catalyst (KOH), 90 min reaction time and 65oC
reaction temperature. The performance parameters like brake specific energy consumption, brake thermal
efficiency and the emission parameters like carbon monoxide, unburned hydrocarbons and oxides of nitrogen
were analysed in detail. It was noticed that the BSEC of STRP was 12.1% with diesel and 14.02% with B100
biodiesel blend. The brake thermal efficiency was also found to be improved with biodiesel blend with STRP on
comparison with STP and HBP. The carbon monoxide and hydrocarbon emission was found to decrease with
STRP geometry were as HBP exhibited negative improvement. NOx emission was also found to increase with
STRP.
Physical properties and thermochemistry for reactor technologyGerard B. Hawkins
Physical Properties and Thermochemistry for Reactor Technology
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 PHYSICAL PROPERTIES
4.1 Form of Equations
4.2 The Physical Property System: “The VAULT”
4.3 Physical Property Programs
4.4 Physical Property Estimation
4.5 Sources of Expertise
5 INTERFACING COMPUTER PROGRAMS TO THE
GBHE VAULT PHYSICAL PROPERTIES PACKAGE
5.1 Preparation of the Physical Property Data
6 THERMOCHEMISTRY
6.1 Hess's Law
6.2 Standard States
6.3 Heats of Formation
6.4 Determination of Heats of Reaction
7 CALCULATION OF HEATS OF REACTION
7.1 Analogous Reactions
7.2 Heat of Formation Data Compilations
7.3 Estimation of Standard Heats of Formation
7.4 Heats of Neutralization
7.5 Temperature Effect on Heat of Reaction
8 HEATS OF SOLUTION, DILUTION AND MIXING
8.1 Calculation of Heats of Solution / Dilution from
Literature Data
8.2 Estimation of Heats of Solution and Mixing
8.3 Integral and Differential Heats
9 EXPERIMENTAL DETERMINATION OF
THERMOCHEMICAL PARAMETERS
9.1 Isoperibol Calorimetry for Heats of Reaction and Solution
9.2 Heat Flow Calorimetry
9.3 Adiabatic Calorimeter
9.4 Differential Scanning Calorimetry
10 COMPUTER CALCULATION OF ENTHALPY OR
TEMPERATURE
11 BIBLIOGRAPHY
Determination of the Optimal Process Conditions for the Acid Activation of Ng...ijceronline
In this work, the optimal adsorption parameters for the adsorption of Carotenoid in the bleaching of palm oil was investigated. Ngwo clay, a local adsorbent obtained from Ngwo town in the South-Eastern province of Nigeria, was used in the study. The palm oil used was also obtained from a local market in Enugu in the same region. The purpose of the work was to develop a model to optimize the efficiency of a local adsorbent that will be cheap and environmentally friendly, for the removal of pigments during refining of vegetable oils. The clay was first, acid activated and characterized, and used in the investigation. Central Composite Design (CCD) package was used to optimize the effects of process parameters of Temperature, Time and Clay Dosage on the bleaching efficiency of Palm Oil. A linear model was predicted and optimized based on BBD. This gave bleaching time of 40min., Temperature of 99.83oC, and Clay dosage of 4%, at a predicted bleaching efficiency of 83%. The optimum conditions were validated to obtain an experimental value of 82.5% with 1.7% error condition.
Acetylation of Corn Cobs Using Iodine Catalyst, For Oil Spills Remediationtheijes
This study investigated the process of cleaning oil spills using both raw corn cobs (RCC) and acetylated corn cobs (ACC). The corn cobs were acetylated in a solvent free system using acetic anhydride, in the presence of Iodine, under mild reaction conditions. The acetylation was carried out at 100oC for 2 hours using 1% iodine. The system conditions played significant roles on the extent of acetylation expressed as Weight Percent Gain (WPG). The weight percent gain (WPG) due to acetylation was found to be 17.6%. Sorption studies were also carried out on both RCC and ACC. The result of the analysis showed higher values of oil sorption capacities (g/g) for ACC than RCC. This goes to prove that acetylation increased the oil sorption capacity of the corn cobs. It was found that particle size, sorption time, sorbent dosage and temperature has very significant effects on the oil sorption capacities of the modified corn cobs. To investigate the acetylation reaction, functional analysis of the RCC and ACC were carried out using Fourier transform infrared spectroscopy (FT-IR). The FTIR data showed a clear evidence of successful acetylation. ACC are therefore recommended for oil spillage clean up, as well as for further development.
Other Separations Techniques for Suspensions
PRESSURE-DRIVEN MEMBRANE SEPARATION
PROCESSES
1.1 INTRODUCTION
1.2 MEMBRANES
1.3 OPERATION
1.4 FACTORS AFFECTING PERFORMANCE
1.4.1 Polarization / Fouling
1.4.2 Pressure
1.4.3 Crossflow
1.4.4 Temperature
1.4.5 Concentration
1.4.6 Membrane Pore Size
1.4.7 Particle Size
1.4.8 Particle Charge
1.4.9 Other Factors
1.5 ADVANTAGES / LIMITATIONS
1.6 SUMMARY OF SYMBOLS USED
2 ELECTRO-DIALYSIS
2.1 INTRODUCTION
2.2 EQUIPMENT
2.3 IMPORTANT PARAMETERS IN ED
2.4 EXAMPLES
3 ELECTRODEWATERING AND ELECTRODECANTATION
3.1 INTRODUCTION
3.2 PRINCIPLES AND OPERATION
3.3 EQUIPMENT AND OPERATING PARAMETERS
3.4 EXAMPLES
4 MAGNETIC SEPARATION METHODS
5 REFERENCES
FIGURES
1 APPLICATION RANGES FOR MEMBRANE SEPARATION TECHNIQUES
2 SIMPLE UF / CMF RIG
4 FLUX VERSUS PRESSURE
5 ELECTRODIALYSIS PROCESS
6 ELECTRODIALYSIS PLANT FOR BATCH PROCESS
7 DEPENDENCE OF MEMBRANE AREA AND ENERGY ON
CURRENT DENSITY
8 DIFFUSION ACROSS THE BOUNDARY LAYER
Suspensions Processing Guide - Basic Principles & Test MethodsGerard B. Hawkins
Basic Principles & Test Methods
0 GENERAL CONSIDERATIONS
In all of the operations and methods dealt with in this SPG, Suspensions Processing Guide, a degree of solid-liquid separation is affected by expelling liquid from a suspension of particles by mechanical means. The driving force is a pressure gradient developed in the fluid, often called the capillary pressure gradient. In general this may either be developed directly by the application of positive or negative pressure to a cake, as in pressure or vacuum filtration, or may result from the application of a body force to the particles (that is, a gravitational, centrifugal or electrical force) which cause them to migrate relative to the fluid. The forces opposing or retarding the concentration or consolidation of the solid phase comprise the viscous drag associated with the outflow of liquid from the particulate mass, and the direct resistance of the matrix of particles forming ...
Crimson Publishers-Temperature Assessment and Process Optimization of Alkali ...CrimsonPublishersRDMS
Temperature Assessment and Process Optimization of Alkali Catalyzed Transesterification of Waste Cooking Oil Using Microwave Flow System by Hamed Nayebzadeh in Research & Development in Material Science
This report analyzes the worldwide markets for Petroleum Additives in Millions of US$ for Fuel Oil Additives, and Lubricating Oil Additives. The market for Lubricating Oil Additives is further analyzed in Thousand Metric Tons and US$ Million by the following Functional Segments: Antioxidants, Antiwear Agents, Corrosion Inhibitors, Detergents, Dispersants, Extreme Pressure Additives, Foam Control Agents, Pour Point Depressants, Viscosity Index Improvers, and Other Lube Additives. The report provides separate comprehensive analytics for the US, Canada, Japan, Europe, Asia-Pacific, Middle East, and Latin America. Annual estimates and forecasts are provided for the period 2007 through 2015. A seven-year historic analysis is also provided for these markets. The report profiles 183 companies including many key and niche players such as Afton Chemical Corp., Baker Hughes, Inc., Chemtura Corporation, Chevron Oronite Company LLC, ENI SpA, Ethyl Corporation, ExxonMobil Chemical, Infineum International Limited, Evonik Rohmax Additives GmbH, Innospec Inc., North American Petroleum, Inc., OM Group, Inc., Petroleos De Venezuela, CITGO Petroleum Corporation, Qatar Petroleum, Repsol YPF, Royal Dutch Shell Plc, and The Lubrizol Corporation. Market data and analytics are derived from primary and secondary research. Company profiles are mostly extracted from URL research and reported select online sources.
Determination of Hydrogen Sulfide by Cadmium Sulfide PrecipitationGerard B. Hawkins
Plant Analytical Techniques
Gas Analysis: Determination of Hydrogen Sulfide by Cadmium Sulfide Precipitation
SCOPE AND FIELD OF APPLICATION
This method is suitable for the in situ determination of hydrogen sulfide in ammonia plant gas streams when testing is required during catalyst reduction.
PRINCIPLE
Hydrogen sulfide present in the gas precipitates cadmium sulfide from a cadmium solution. The precipitate is filtered then reacted with iodine; the excess iodine is then titrated with sodium thiosulfate.
Comparison of Supercritical Fluid Extraction with Steam Distillation for the ...inventionjournals
Bay oil, an extract of Pimenta Racemosa, is produced in Dominica by the traditional process of Steam Distillation Extraction (SDE), and commercially utilised in the perfume and food industries. The objective of the work described in this paper seeks to investigate if it could be better produced by Supercritical Fluid Extraction (SFE) using carbon dioxide as extracting fluid. Experiments were therefore carried out on a bench scale SFE unit to evaluate the extraction characteristics of bay leaves and to compare the results with those from a bench scale SDE unit. The results showed that the SFE extracts contained mainly eugenol and chavicol up to about 1 hour of extraction time, after which higher components, including waxes, were incorporated into the extracts. The optimum operating conditions were deemed to be 150 bar pressure and 50oC temperature. The SDE extracts were also mainly eugenol and chavicol, but in addition contained a significant quantity of myrcene. The extract yield from SFE after I hour was similar to that of the ultimate yield from SDE (~4.0%), but the extraction time for SDE was in excess of twice that figure. It is concluded that the higher phenol content of the SFE product together with lower extraction times makes the use of SFE potentially preferable to the traditional SDE process.
Experimental investigation and optimization study of combustion chamber geome...IJERD Editor
An experimental investigation and optimization study of various piston geometries was conducted
on Greaves single cylinder direct injection compression ignition engine using straight diesel and blends of rice
bran biodiesel. The three combustion chamber geometries used in this study were Standard toroidal piston
(STP), hemispherical bowl piston (HBP) and Shallow toroidal re-entrant piston (STRP) at compression ratios of
18:1, 19.04:1 and 16.4:1 respectively. Rice bran biodiesel was derived by two step trans-esterification process
with an optimum yield of 86% with molar ratio 1:6, 06% of catalyst (KOH), 90 min reaction time and 65oC
reaction temperature. The performance parameters like brake specific energy consumption, brake thermal
efficiency and the emission parameters like carbon monoxide, unburned hydrocarbons and oxides of nitrogen
were analysed in detail. It was noticed that the BSEC of STRP was 12.1% with diesel and 14.02% with B100
biodiesel blend. The brake thermal efficiency was also found to be improved with biodiesel blend with STRP on
comparison with STP and HBP. The carbon monoxide and hydrocarbon emission was found to decrease with
STRP geometry were as HBP exhibited negative improvement. NOx emission was also found to increase with
STRP.
Physical properties and thermochemistry for reactor technologyGerard B. Hawkins
Physical Properties and Thermochemistry for Reactor Technology
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 PHYSICAL PROPERTIES
4.1 Form of Equations
4.2 The Physical Property System: “The VAULT”
4.3 Physical Property Programs
4.4 Physical Property Estimation
4.5 Sources of Expertise
5 INTERFACING COMPUTER PROGRAMS TO THE
GBHE VAULT PHYSICAL PROPERTIES PACKAGE
5.1 Preparation of the Physical Property Data
6 THERMOCHEMISTRY
6.1 Hess's Law
6.2 Standard States
6.3 Heats of Formation
6.4 Determination of Heats of Reaction
7 CALCULATION OF HEATS OF REACTION
7.1 Analogous Reactions
7.2 Heat of Formation Data Compilations
7.3 Estimation of Standard Heats of Formation
7.4 Heats of Neutralization
7.5 Temperature Effect on Heat of Reaction
8 HEATS OF SOLUTION, DILUTION AND MIXING
8.1 Calculation of Heats of Solution / Dilution from
Literature Data
8.2 Estimation of Heats of Solution and Mixing
8.3 Integral and Differential Heats
9 EXPERIMENTAL DETERMINATION OF
THERMOCHEMICAL PARAMETERS
9.1 Isoperibol Calorimetry for Heats of Reaction and Solution
9.2 Heat Flow Calorimetry
9.3 Adiabatic Calorimeter
9.4 Differential Scanning Calorimetry
10 COMPUTER CALCULATION OF ENTHALPY OR
TEMPERATURE
11 BIBLIOGRAPHY
Determination of the Optimal Process Conditions for the Acid Activation of Ng...ijceronline
In this work, the optimal adsorption parameters for the adsorption of Carotenoid in the bleaching of palm oil was investigated. Ngwo clay, a local adsorbent obtained from Ngwo town in the South-Eastern province of Nigeria, was used in the study. The palm oil used was also obtained from a local market in Enugu in the same region. The purpose of the work was to develop a model to optimize the efficiency of a local adsorbent that will be cheap and environmentally friendly, for the removal of pigments during refining of vegetable oils. The clay was first, acid activated and characterized, and used in the investigation. Central Composite Design (CCD) package was used to optimize the effects of process parameters of Temperature, Time and Clay Dosage on the bleaching efficiency of Palm Oil. A linear model was predicted and optimized based on BBD. This gave bleaching time of 40min., Temperature of 99.83oC, and Clay dosage of 4%, at a predicted bleaching efficiency of 83%. The optimum conditions were validated to obtain an experimental value of 82.5% with 1.7% error condition.
Acetylation of Corn Cobs Using Iodine Catalyst, For Oil Spills Remediationtheijes
This study investigated the process of cleaning oil spills using both raw corn cobs (RCC) and acetylated corn cobs (ACC). The corn cobs were acetylated in a solvent free system using acetic anhydride, in the presence of Iodine, under mild reaction conditions. The acetylation was carried out at 100oC for 2 hours using 1% iodine. The system conditions played significant roles on the extent of acetylation expressed as Weight Percent Gain (WPG). The weight percent gain (WPG) due to acetylation was found to be 17.6%. Sorption studies were also carried out on both RCC and ACC. The result of the analysis showed higher values of oil sorption capacities (g/g) for ACC than RCC. This goes to prove that acetylation increased the oil sorption capacity of the corn cobs. It was found that particle size, sorption time, sorbent dosage and temperature has very significant effects on the oil sorption capacities of the modified corn cobs. To investigate the acetylation reaction, functional analysis of the RCC and ACC were carried out using Fourier transform infrared spectroscopy (FT-IR). The FTIR data showed a clear evidence of successful acetylation. ACC are therefore recommended for oil spillage clean up, as well as for further development.
Other Separations Techniques for Suspensions
PRESSURE-DRIVEN MEMBRANE SEPARATION
PROCESSES
1.1 INTRODUCTION
1.2 MEMBRANES
1.3 OPERATION
1.4 FACTORS AFFECTING PERFORMANCE
1.4.1 Polarization / Fouling
1.4.2 Pressure
1.4.3 Crossflow
1.4.4 Temperature
1.4.5 Concentration
1.4.6 Membrane Pore Size
1.4.7 Particle Size
1.4.8 Particle Charge
1.4.9 Other Factors
1.5 ADVANTAGES / LIMITATIONS
1.6 SUMMARY OF SYMBOLS USED
2 ELECTRO-DIALYSIS
2.1 INTRODUCTION
2.2 EQUIPMENT
2.3 IMPORTANT PARAMETERS IN ED
2.4 EXAMPLES
3 ELECTRODEWATERING AND ELECTRODECANTATION
3.1 INTRODUCTION
3.2 PRINCIPLES AND OPERATION
3.3 EQUIPMENT AND OPERATING PARAMETERS
3.4 EXAMPLES
4 MAGNETIC SEPARATION METHODS
5 REFERENCES
FIGURES
1 APPLICATION RANGES FOR MEMBRANE SEPARATION TECHNIQUES
2 SIMPLE UF / CMF RIG
4 FLUX VERSUS PRESSURE
5 ELECTRODIALYSIS PROCESS
6 ELECTRODIALYSIS PLANT FOR BATCH PROCESS
7 DEPENDENCE OF MEMBRANE AREA AND ENERGY ON
CURRENT DENSITY
8 DIFFUSION ACROSS THE BOUNDARY LAYER
Suspensions Processing Guide - Basic Principles & Test MethodsGerard B. Hawkins
Basic Principles & Test Methods
0 GENERAL CONSIDERATIONS
In all of the operations and methods dealt with in this SPG, Suspensions Processing Guide, a degree of solid-liquid separation is affected by expelling liquid from a suspension of particles by mechanical means. The driving force is a pressure gradient developed in the fluid, often called the capillary pressure gradient. In general this may either be developed directly by the application of positive or negative pressure to a cake, as in pressure or vacuum filtration, or may result from the application of a body force to the particles (that is, a gravitational, centrifugal or electrical force) which cause them to migrate relative to the fluid. The forces opposing or retarding the concentration or consolidation of the solid phase comprise the viscous drag associated with the outflow of liquid from the particulate mass, and the direct resistance of the matrix of particles forming ...
Crimson Publishers-Temperature Assessment and Process Optimization of Alkali ...CrimsonPublishersRDMS
Temperature Assessment and Process Optimization of Alkali Catalyzed Transesterification of Waste Cooking Oil Using Microwave Flow System by Hamed Nayebzadeh in Research & Development in Material Science
This report analyzes the worldwide markets for Petroleum Additives in Millions of US$ for Fuel Oil Additives, and Lubricating Oil Additives. The market for Lubricating Oil Additives is further analyzed in Thousand Metric Tons and US$ Million by the following Functional Segments: Antioxidants, Antiwear Agents, Corrosion Inhibitors, Detergents, Dispersants, Extreme Pressure Additives, Foam Control Agents, Pour Point Depressants, Viscosity Index Improvers, and Other Lube Additives. The report provides separate comprehensive analytics for the US, Canada, Japan, Europe, Asia-Pacific, Middle East, and Latin America. Annual estimates and forecasts are provided for the period 2007 through 2015. A seven-year historic analysis is also provided for these markets. The report profiles 183 companies including many key and niche players such as Afton Chemical Corp., Baker Hughes, Inc., Chemtura Corporation, Chevron Oronite Company LLC, ENI SpA, Ethyl Corporation, ExxonMobil Chemical, Infineum International Limited, Evonik Rohmax Additives GmbH, Innospec Inc., North American Petroleum, Inc., OM Group, Inc., Petroleos De Venezuela, CITGO Petroleum Corporation, Qatar Petroleum, Repsol YPF, Royal Dutch Shell Plc, and The Lubrizol Corporation. Market data and analytics are derived from primary and secondary research. Company profiles are mostly extracted from URL research and reported select online sources.
NTM Corp: Mobil Presentation on After-Market Oil Additivesjapjaca
A presentation prepared for Automotive and Industrial customer on the awareness of application of after-market oil additives to finished lubricants.
NOTE: This contains parts of the standard Mobil presentation decks.
Analysis of the Aug 25 events at the Amuay Refinery.
Disclaimer: RMG has developed the following material based on detailed analysis of information freely available on the net, our data bases, and from peers and our industry contacts. We believe that an accurate event simulation and fact sheet has been developed, describing to the best of our knowledge the facts and consequences without warranties or judgments of any kind
Lube Oil Blending Plants (LOBPs) have a key role to play in the manufacture, sales and distribution of bulk and packed lubricants. This study gives an overview of the Global lubricants market and proposes a methodology for Performance evaluation of Lube Oil Blending Plants.
Calculation of an Ammonia Plant Energy Consumption: Gerard B. Hawkins
Calculation of an Ammonia Plant Energy Consumption:
Case Study: #06023300
Plant Note Book Series: PNBS-0602
CONTENTS
0 SCOPE
1 CALCULATION OF NATURAL GAS PROCESS FEED CONSUMPTION
2 CALCULATION OF NATURAL GAS PROCESS FUEL CONSUMPTION
3 CALCULATION OF NATURAL GAS CONSUMPTION FOR PILOT BURNERS OF FLARES
4 CALCULATION OF DEMIN. WATER FROM DEMIN. UNIT
5 CALCULATION OF DEMIN. WATER TO PACKAGE BOILERS
6 CALCULATION OF MP STEAM EXPORT
7 CALCULATION OF LP STEAM IMPORT
8 DETERMINATION OF ELECTRIC POWER CONSUMPTION
9 DETERMINATION OF THE TOTAL ENERGY CONSUMPTION OF THE AMMONIA PLANT ISBL
10 ADJUSTMENT OF ELECTRIC POWER CONSUMPTION FOR TEST RUN CONDITIONS
11 CALCULATION OF AMMONIA SHARE IN MP STEAM CONSUMPTION IN UTILITIES
12 CALCULATION OF AMMONIA SHARE IN ELECTRIC POWER CONSUMPTION IN UTILITIES
13 DETERMINATION OF THE TOTAL ENERGY CONSUMPTION OF THE AMMONIA PLANT OSBL
14 DETERMINATION OF THE TOTAL ENERGY CONSUMPTION OF THE AMMONIA PLANT
Due to increase demand of energy, increasing price
of petroleum fuels, depletion of petroleum fuels, and
environmental pollution by these fuel emissions, it is very
necessary to find the alternative fuels. This work focused on use
of hybrid blends of Karanja and Cottonseed oil Biodiesels. In this
work 20% and 25% blends are used and the performance and
emission tests were conducted on single cylinder, 4-stroke, water
cooled CI engine by running the engine at a speed of 1500rpm, at
a compression ratio of 16.5:1 and at an injection pressure of
205bar and performance parameters like BP, BSFC, BTE and
the emissions like CO, HC and NOx are compared. It was found
that the blends gave comparatively good results in respect of
performance and emissions.
International Journal of Engineering Research and DevelopmentIJERD Editor
Electrical, Electronics and Computer Engineering,
Information Engineering and Technology,
Mechanical, Industrial and Manufacturing Engineering,
Automation and Mechatronics Engineering,
Material and Chemical Engineering,
Civil and Architecture Engineering,
Biotechnology and Bio Engineering,
Environmental Engineering,
Petroleum and Mining Engineering,
Marine and Agriculture engineering,
Aerospace Engineering.
Effect of injection pressure on performance and emission analysis of ci engin...eSAT Journals
Abstract Gradual depletion of world petroleum reserves and increase in the exhaust emissions day by day have led to an urgent need for alternative fuels to replace diesel. Vegetable oils biodiesel is considered as an alternative for diesel because of their properties which have been close to pure diesel. In the present study non edible vegetable oils like Honge and Jatropha oils biodiesel and their blends were used as fuel in a constant speed direct injection diesel engine. Further effect of injection pressure on the performance parameters such as brake thermal efficiency, brake specific fuel consumption, brake power and emission parameters such as HC, CO and NOX were investigated in a constant speed direct injection diesel engine with varied injection pressures of 180, 200 and 220 bar.The test results showed that Honge and Jatropa oil biofuel blends are having good performance and emission results at 200 bar injection pressure when compared to 180 and 200 bar injection pressure. The test results also showed that performance and emission results of Honge and Jatropa biofuel blends are near to that of the results obtained for pure diesel and they can be used to replace pure diesel. Keywords: - Performance parameters, Emission parameters, Biodiesel, Jatropa oil, Honge oil
Canola biodiesel an experimental investigation for production of biodiesel a...eSAT Journals
Abstract The experimental investigation was made to estimate the performance of methyl esters of Canola waste cooking oil and their blends in a direct injection diesel engine. The Canola waste cooking oil methyl ester (CWCOME) was prepared through transesterification process by using methanol and KOH as a catalyst. The Canola biodiesel blends were ready in proportion of 10%, 20%, 30% and 100% of biodiesel with diesel. The effects of pure biodiesel and their blends on engine performance, and exhaust emission were studied under various loading conditions. The experimental results concluded that up to 20% of methyl esters did not affect the performance parameter like fuel consumption rate and brake thermal efficiency. On the other hand above CB20 (20% Canola biodiesel with 80% diesel) a decrease in performance and combustion parameter were clearly observed form the study. Keywords: Canola waste cooking oil, Canola methyl ester, Transesterification, Internal combustion engine, Engine performance.
Biodiesel Production from waste Oil with Micro-Scale Biodiesel System Under L...IJERDJOURNAL
ABSTRACT:- The aim of this project is to produce biodiesel from waste oil. The use of vegetable oils as diesel fuel started with the invention of diesel engines in the 1900s and is also common in many countries today. The fact that the oils used in biodiesel production are also an important input of the food industry is a limiting factor in production. For this reason, it is aimed to produce biodiesel from waste oil which can not be assessed in food production in this study. The most important contribution of the study to biodiesel researches is the establishment of a small-capacity biodiesel unit in laboratory conditions. The waste oils from the food production facilities of Namık Kemal University (NKU) have been collected and biodiesel has been produced using two different experimental methods. The analyses that determine the quality of the biodiesel samples have been carried out by Energy Agriculture Research Center of Black Sea Agricultural Research Institute in Republic of Turkey Ministry of Food, Agriculture and Livestock. As a result of the research, it has been determined that the biodiesel fuel obtained by the B-1 method using KOH as a catalyst conforms to the standards and can be used with confidence in diesel engines.
Encryption in Microsoft 365 - ExpertsLive Netherlands 2024Albert Hoitingh
In this session I delve into the encryption technology used in Microsoft 365 and Microsoft Purview. Including the concepts of Customer Key and Double Key Encryption.
Threats to mobile devices are more prevalent and increasing in scope and complexity. Users of mobile devices desire to take full advantage of the features
available on those devices, but many of the features provide convenience and capability but sacrifice security. This best practices guide outlines steps the users can take to better protect personal devices and information.
20 Comprehensive Checklist of Designing and Developing a WebsitePixlogix Infotech
Dive into the world of Website Designing and Developing with Pixlogix! Looking to create a stunning online presence? Look no further! Our comprehensive checklist covers everything you need to know to craft a website that stands out. From user-friendly design to seamless functionality, we've got you covered. Don't miss out on this invaluable resource! Check out our checklist now at Pixlogix and start your journey towards a captivating online presence today.
GridMate - End to end testing is a critical piece to ensure quality and avoid...ThomasParaiso2
End to end testing is a critical piece to ensure quality and avoid regressions. In this session, we share our journey building an E2E testing pipeline for GridMate components (LWC and Aura) using Cypress, JSForce, FakerJS…
Alt. GDG Cloud Southlake #33: Boule & Rebala: Effective AppSec in SDLC using ...James Anderson
Effective Application Security in Software Delivery lifecycle using Deployment Firewall and DBOM
The modern software delivery process (or the CI/CD process) includes many tools, distributed teams, open-source code, and cloud platforms. Constant focus on speed to release software to market, along with the traditional slow and manual security checks has caused gaps in continuous security as an important piece in the software supply chain. Today organizations feel more susceptible to external and internal cyber threats due to the vast attack surface in their applications supply chain and the lack of end-to-end governance and risk management.
The software team must secure its software delivery process to avoid vulnerability and security breaches. This needs to be achieved with existing tool chains and without extensive rework of the delivery processes. This talk will present strategies and techniques for providing visibility into the true risk of the existing vulnerabilities, preventing the introduction of security issues in the software, resolving vulnerabilities in production environments quickly, and capturing the deployment bill of materials (DBOM).
Speakers:
Bob Boule
Robert Boule is a technology enthusiast with PASSION for technology and making things work along with a knack for helping others understand how things work. He comes with around 20 years of solution engineering experience in application security, software continuous delivery, and SaaS platforms. He is known for his dynamic presentations in CI/CD and application security integrated in software delivery lifecycle.
Gopinath Rebala
Gopinath Rebala is the CTO of OpsMx, where he has overall responsibility for the machine learning and data processing architectures for Secure Software Delivery. Gopi also has a strong connection with our customers, leading design and architecture for strategic implementations. Gopi is a frequent speaker and well-known leader in continuous delivery and integrating security into software delivery.
LF Energy Webinar: Electrical Grid Modelling and Simulation Through PowSyBl -...DanBrown980551
Do you want to learn how to model and simulate an electrical network from scratch in under an hour?
Then welcome to this PowSyBl workshop, hosted by Rte, the French Transmission System Operator (TSO)!
During the webinar, you will discover the PowSyBl ecosystem as well as handle and study an electrical network through an interactive Python notebook.
PowSyBl is an open source project hosted by LF Energy, which offers a comprehensive set of features for electrical grid modelling and simulation. Among other advanced features, PowSyBl provides:
- A fully editable and extendable library for grid component modelling;
- Visualization tools to display your network;
- Grid simulation tools, such as power flows, security analyses (with or without remedial actions) and sensitivity analyses;
The framework is mostly written in Java, with a Python binding so that Python developers can access PowSyBl functionalities as well.
What you will learn during the webinar:
- For beginners: discover PowSyBl's functionalities through a quick general presentation and the notebook, without needing any expert coding skills;
- For advanced developers: master the skills to efficiently apply PowSyBl functionalities to your real-world scenarios.
UiPath Test Automation using UiPath Test Suite series, part 5DianaGray10
Welcome to UiPath Test Automation using UiPath Test Suite series part 5. In this session, we will cover CI/CD with devops.
Topics covered:
CI/CD with in UiPath
End-to-end overview of CI/CD pipeline with Azure devops
Speaker:
Lyndsey Byblow, Test Suite Sales Engineer @ UiPath, Inc.
Generative AI Deep Dive: Advancing from Proof of Concept to ProductionAggregage
Join Maher Hanafi, VP of Engineering at Betterworks, in this new session where he'll share a practical framework to transform Gen AI prototypes into impactful products! He'll delve into the complexities of data collection and management, model selection and optimization, and ensuring security, scalability, and responsible use.
How to Get CNIC Information System with Paksim Ga.pptxdanishmna97
Pakdata Cf is a groundbreaking system designed to streamline and facilitate access to CNIC information. This innovative platform leverages advanced technology to provide users with efficient and secure access to their CNIC details.
Climate Impact of Software Testing at Nordic Testing DaysKari Kakkonen
My slides at Nordic Testing Days 6.6.2024
Climate impact / sustainability of software testing discussed on the talk. ICT and testing must carry their part of global responsibility to help with the climat warming. We can minimize the carbon footprint but we can also have a carbon handprint, a positive impact on the climate. Quality characteristics can be added with sustainability, and then measured continuously. Test environments can be used less, and in smaller scale and on demand. Test techniques can be used in optimizing or minimizing number of tests. Test automation can be used to speed up testing.
GDG Cloud Southlake #33: Boule & Rebala: Effective AppSec in SDLC using Deplo...James Anderson
Effective Application Security in Software Delivery lifecycle using Deployment Firewall and DBOM
The modern software delivery process (or the CI/CD process) includes many tools, distributed teams, open-source code, and cloud platforms. Constant focus on speed to release software to market, along with the traditional slow and manual security checks has caused gaps in continuous security as an important piece in the software supply chain. Today organizations feel more susceptible to external and internal cyber threats due to the vast attack surface in their applications supply chain and the lack of end-to-end governance and risk management.
The software team must secure its software delivery process to avoid vulnerability and security breaches. This needs to be achieved with existing tool chains and without extensive rework of the delivery processes. This talk will present strategies and techniques for providing visibility into the true risk of the existing vulnerabilities, preventing the introduction of security issues in the software, resolving vulnerabilities in production environments quickly, and capturing the deployment bill of materials (DBOM).
Speakers:
Bob Boule
Robert Boule is a technology enthusiast with PASSION for technology and making things work along with a knack for helping others understand how things work. He comes with around 20 years of solution engineering experience in application security, software continuous delivery, and SaaS platforms. He is known for his dynamic presentations in CI/CD and application security integrated in software delivery lifecycle.
Gopinath Rebala
Gopinath Rebala is the CTO of OpsMx, where he has overall responsibility for the machine learning and data processing architectures for Secure Software Delivery. Gopi also has a strong connection with our customers, leading design and architecture for strategic implementations. Gopi is a frequent speaker and well-known leader in continuous delivery and integrating security into software delivery.
GraphSummit Singapore | The Future of Agility: Supercharging Digital Transfor...Neo4j
Leonard Jayamohan, Partner & Generative AI Lead, Deloitte
This keynote will reveal how Deloitte leverages Neo4j’s graph power for groundbreaking digital twin solutions, achieving a staggering 100x performance boost. Discover the essential role knowledge graphs play in successful generative AI implementations. Plus, get an exclusive look at an innovative Neo4j + Generative AI solution Deloitte is developing in-house.
zkStudyClub - Reef: Fast Succinct Non-Interactive Zero-Knowledge Regex ProofsAlex Pruden
This paper presents Reef, a system for generating publicly verifiable succinct non-interactive zero-knowledge proofs that a committed document matches or does not match a regular expression. We describe applications such as proving the strength of passwords, the provenance of email despite redactions, the validity of oblivious DNS queries, and the existence of mutations in DNA. Reef supports the Perl Compatible Regular Expression syntax, including wildcards, alternation, ranges, capture groups, Kleene star, negations, and lookarounds. Reef introduces a new type of automata, Skipping Alternating Finite Automata (SAFA), that skips irrelevant parts of a document when producing proofs without undermining soundness, and instantiates SAFA with a lookup argument. Our experimental evaluation confirms that Reef can generate proofs for documents with 32M characters; the proofs are small and cheap to verify (under a second).
Paper: https://eprint.iacr.org/2023/1886
Communications Mining Series - Zero to Hero - Session 1DianaGray10
This session provides introduction to UiPath Communication Mining, importance and platform overview. You will acquire a good understand of the phases in Communication Mining as we go over the platform with you. Topics covered:
• Communication Mining Overview
• Why is it important?
• How can it help today’s business and the benefits
• Phases in Communication Mining
• Demo on Platform overview
• Q/A
Why You Should Replace Windows 11 with Nitrux Linux 3.5.0 for enhanced perfor...SOFTTECHHUB
The choice of an operating system plays a pivotal role in shaping our computing experience. For decades, Microsoft's Windows has dominated the market, offering a familiar and widely adopted platform for personal and professional use. However, as technological advancements continue to push the boundaries of innovation, alternative operating systems have emerged, challenging the status quo and offering users a fresh perspective on computing.
One such alternative that has garnered significant attention and acclaim is Nitrux Linux 3.5.0, a sleek, powerful, and user-friendly Linux distribution that promises to redefine the way we interact with our devices. With its focus on performance, security, and customization, Nitrux Linux presents a compelling case for those seeking to break free from the constraints of proprietary software and embrace the freedom and flexibility of open-source computing.
Maruthi Prithivirajan, Head of ASEAN & IN Solution Architecture, Neo4j
Get an inside look at the latest Neo4j innovations that enable relationship-driven intelligence at scale. Learn more about the newest cloud integrations and product enhancements that make Neo4j an essential choice for developers building apps with interconnected data and generative AI.
In the rapidly evolving landscape of technologies, XML continues to play a vital role in structuring, storing, and transporting data across diverse systems. The recent advancements in artificial intelligence (AI) present new methodologies for enhancing XML development workflows, introducing efficiency, automation, and intelligent capabilities. This presentation will outline the scope and perspective of utilizing AI in XML development. The potential benefits and the possible pitfalls will be highlighted, providing a balanced view of the subject.
We will explore the capabilities of AI in understanding XML markup languages and autonomously creating structured XML content. Additionally, we will examine the capacity of AI to enrich plain text with appropriate XML markup. Practical examples and methodological guidelines will be provided to elucidate how AI can be effectively prompted to interpret and generate accurate XML markup.
Further emphasis will be placed on the role of AI in developing XSLT, or schemas such as XSD and Schematron. We will address the techniques and strategies adopted to create prompts for generating code, explaining code, or refactoring the code, and the results achieved.
The discussion will extend to how AI can be used to transform XML content. In particular, the focus will be on the use of AI XPath extension functions in XSLT, Schematron, Schematron Quick Fixes, or for XML content refactoring.
The presentation aims to deliver a comprehensive overview of AI usage in XML development, providing attendees with the necessary knowledge to make informed decisions. Whether you’re at the early stages of adopting AI or considering integrating it in advanced XML development, this presentation will cover all levels of expertise.
By highlighting the potential advantages and challenges of integrating AI with XML development tools and languages, the presentation seeks to inspire thoughtful conversation around the future of XML development. We’ll not only delve into the technical aspects of AI-powered XML development but also discuss practical implications and possible future directions.
1. INDUSTRIAL TEST REPORT
Cavitation Cold Blending of Lubricants unit
CCBL unit supplier: GQOIL Innovation Europe sp z o.o
CCBL test holder: PRISTA OIL HOLDING EAD
RUSE June, 2015
2. 1. INTRODUCTION
a. OBJECTIVE:
The objec ve of the industrial test was to verify the ability of the CCBL to blend lubes as an
alterna ve way to other types of blending processes like mechanical blending and in-line blending.
In add on the test shall should verify the c veness of the CCBL during normal and regular
produ on of lubricants (engine oils and industrial oils).
b. PLACE OF THE TEST:
The test has been run at PRISTA blending plant, located in Bulgaria, Ruse.
2. TEST EQUIPMENT:
a. CCBL BLENDING UNIT – GQOIL provided a mobile CCBL blending unit with capacity of 6 MT/h. The
unit was installed and delivered in 20 FT sea container.
b. The unit consisted of:
CCBL produ on line
Control room
Computerized process control
Electrical panel board
c. PRISTA PRE MIX EQUIPMENT – PRISTA provided 4 mechanical blending vessels, each 6 MT capacity
for the purpose of dosing, pre-mix oper ons and storage r comple on of CCBL blending.
3. PRISTA LABORATORY – PRISTA provided laboratory test control at site. PRISTA laboratory is accredited
as per EN ISO/IEC 17025:2006. The same is organiz onal member of ASTM INTERNATIONAL
4. GENERAL DESCRIPTION OF THE TEST
Test was run to blend several types of lube oils.
The procedure included:
- Dosing of components (base oil and add ves) in PRISTA mechanical blenders.
- Pre-mix of the components between 10 – 20 min, at ambient temperature.
- CCBL blending
- Storage and lab test of each batch of produ on
onal test parameters monitored during the test:
- Temperature of the pre-mix;
- Temperature r CCBL;
- Electrical con on of CCBL KWh;
- Time of CCBL blending and total me including pre-mix;
- Produc on capacity per hour.
Physical and chemical parameters of the produced lubricants:
For each type of lubricant, parameters were tested as per the technical ca on.
Dev on from the general procedure, if any, was discussed and agreed for each single test and
separately described.
3
3.
Lube oil: mu -grade engine oil “PRISTA® SUPER BENZIN 15 W 40 “
15W40 API SL/CF, ACEA A3/B3
SN 150 59,70%
SN 500 22,00%
Add 1 10,00%
Add 2 VII 8,00%
Add 3 PPD 0,30%
100,00%
DESCRIPTION OF THE TEST
Var on from the general procedure:
Purpose: to compare the lab results of lube oil mixed under CCBL technology with classical mechanical
mixing technology using one and the same me.
Pre-mix volume: 6 MT
Connec on diagram:
Connec on made exi hoses:
10 minutes were taken for the pre-mix opera on in the mechanical blender.
A er comp on of the pre-mix, 3000 liters were transferred to CCBL blending.
The remaining volume stayed in the mechanical blender.
A er comp on of the CCBL blending the remaining quan y in the mechanical blender was processed
by a classical mechanical blending op on for a tota me of 30 minutes.
4
4. Samples were taken from CCBL blended volume, and stored separately r comp on.
The first sample was taken immediately a er comp on and the second er 30 minutes.
Another sample has been taken from the volume in the mechanical blender er comp on of the
process – the rst one immediately, and the second one r 60 minutes.
Pre-mix temperature: +27.7 C
Temperature er CCBL: +28.9 C
El. Consump on at CCBL: 6.97 KWh
Time CCBL blending: 27.53 min
Volume: 3000 liters
Total me (pre-mix + CCBL blending): 37.53 min.
Total me (pre-mix + mechanical blending): 40 min.
ATTACHMENTS
1. Sp on of the produced lube oil
2. te of analysis
CONCLUSION
The blended lube oil as per CCBL mixing process is in conformity with the PRISTA manufacturing
on. Lab results comparison between CCBL mixing process and mechanical mixing process are
more or less the same. D erences are too small and they are within the repeatability limits as per the
te g methods.
Note: Total me for mechanical blending as per PRISTA opera onal ins ons is min. 2 hours (dosing
and mixing at +40 C). Dosing usually takes 20 minutes maximum for batches up to 6 MT.
5
12.
Lube oil: mu -grade engine oil “PRISTA® SUPER BENZIN 15 W 40 “
15W40 API SL/CF, ACEA A3/B3
SN 150 59,70%
SN 500 22,00%
Add 1 10,00%
Add 2 VII 8,00%
Add 3 PPD 0,30%
100,00%
DESCRIPTION OF THE TEST
Purpose: to evaluate the e ec veness of CCBL blending process.
Pre-mix volume was 6600 liters
Connec on diagram:
10 minutes were taken for pre-mix oper on in the mechanical blender.
A er comp on of the pre-mix, 6600 liters were transferred to CCBL blending.
Samples were taken from CCBL blended volume, stored separately a er comp on.
First sample was taken immediately r comple on.
er op on of mechanical blending was run for a total me of 60 minutes.
A er comp on of the add onal mechanical blending, the second sample was taken for analysis.
Pre-mix temperature: +27.5 C
Temperature er CCBL: +28.2 C
El. Consump on at CCBL: 15.27 KWh
Time CCBL blending: 64 minutes
Volume: 6600 liters
Total me (pre-mix + CCBL blending): 74 min.
Add onal mechanical blending: 60 min.
ATTACHMENTS
1. Sp on of the produced lube oil
2. te of analysis
13
13. CONCLUSION
The lab results of sample 1 and sample 2 are prac ly iden . This v es that the CCBL blending
process secures full homogeniz nish lube oil. The add onal run of mechanical blending didn’t
improve the result.
Note: Total me for mechanical blending as per PRISTA oper onal instru ons is min. 2 hours (dosing
and mixing at +40 C). Dosing usually takes 20 minutes maximum for batches up to 6 MT.
14
21.
Lube oil: Marine cylinder oil “PRISTA® MARINE CM 50/70 “
Brst 28,75%
SN 500 49,15%
Add 1 22,00%
Add 2 PPD 0,10%
100,00%
DESCRIPTION OF THE TEST
Purpose: to evaluate the e ec veness of CCBL blending process for produc on of marine cylinder oils,
where the treat rate of add ves reach 22 %.
Pre-mix volume was 6700 liters.
Connec on diagram:
20 minutes were taken for a pre-mix op on in the mechanical blender.
A er comp on of the pre-mix, 6700 liters were transferred to CCBL blending.
Samples were taken from CCBL blended volume, stored separately a er comp on.
First sample was taken immediately r comple on.
Second sample was taken a er 60 min.
Pre-mix temperature: +30.6 C
Temperature er CCBL: +32.8 C
El. Consump on at CCBL: 16.05 KWh
Time CCBL blending: 64 minutes
Volume: 6700 liters
Total me (pre-mix + CCBL blending): 84 min.
ATTACHMENTS
1. Sp on of the produced lube oil
2. te of analysis
22
22. CONCLUSION
The lab results of sample 1 and sample 2 are prac ly iden . The produced marine cylinder oil was
produced within the target on, without the need for any correc on measures like add onal
add ve treatment and mechanical blending.
Note: Total me for mechanical blending as per PRISTA opera onal ins ons is min. 2 hours (dosing
and mixing at +40 C). Dosing usually takes 20 minutes maximum for batches up to 6 MT.
23
31.
Lube oil: Marine cylinder oil “GULFSEA CYLCARE® DCA 50/70 H“
Brst 28,75%
SN 500 49,15%
Add 1 22,00%
Add 2 PPD 0,10%
100,00%
DESCRIPTION OF THE TEST
Purpose: to evaluate the e ec veness of CCBL blending process of marine cylinder oils, where the treat
rate of add ves reach 22 %.
Pre-mix volume was 6700 liters
Connec on diagram:
20 minutes were taken for a pre-mix op on in the mechanical blender.
A er comp on of the pre-mix, 6700 liters were transferred to CCBL blending.
Samples were taken from CCBL blended volume, stored separately a er comp on.
First sample was taken immediately r comple on.
Second sample was taken a er 60 min.
Pre-mix temperature: +31.4 C
Temperature er CCBL: +32.7 C
El. Consump on at CCBL: 15.94 KWh
Time CCBL blending: 64 minutes
Volume: 6700 liters
Total me (pre-mix + CCBL blending): 84 min.
ATTACHMENTS
1. Sp on of the produced lube oil
2. te of analysis
32
32. CONCLUSION
The lab results of sample 1 and sample 2 are prac ly iden . This v es that the CCBL blending
process produces of full homogeniz nish marine cylinder oil.
33
40.
Lube oil: Hydraulic oil “PRISTA® MHM 32b “
DIN 51524 part 2, ISO 11158
SN 150 99,275%
Add 1 0,500%
Add 2 PPD 0,200%
Add 3 AF 0,025%
100,000%
DESCRIPTION OF THE TEST
Purpose: to evaluate the e ec veness of CCBL blending process in produc on of hydraulic oil viscosity
grade ISO VG 32.
Pre-mix volume was 4700 liters
Connec ons diagram:
30 minutes were taken for a pre-mix op on. Pre-mix was made by recircula on through CCBL,
without using mechanical blending.
A er comp on of the pre-mix, 4700 liters from the vessel were transferred to CCBL blending.
41
41. Samples were taken from CCBL blended volume, stored separately a er comp on.
First sample was taken immediately r comple on.
Second sample was taken a er 60 min.
Pre-mix temperature: +36.1 C
Temperature er CCBL: +38.6 C
El. Consump on at CCBL: 11.06 KWh
Time CCBL blending: 44 minutes
Volume: 4700 liters
Total me (pre-mix + CCBL blending): 74 min.
ATTACHMENTS
1. Sp on of the produced lube oil
2. te of analysis
CONCLUSION
The lab results of sample 1 and sample 2 are prac ly iden . All results shows conformity with the
on limits.
Note: PRISTA op onal in on for mechanical blending involves 2 hours, including dosing and
mixing at +40 C.
42
49.
Lube oil: Industrial Gear Oil “PRISTA® ROLON 150 “
DIN 51517, US STEEL 224
Brst 26,50%
SN 500 71,75%
Add 1 1,50%
Add 2 PPD 0,25%
100,00%
DESCRIPTION OF THE TEST
Purpose: to evaluate the the e veness of the CCBL blending process in produ on of industrial gear
oil, viscosity grade ISO VG 150, by making the pre-mix through CCBL recircu on mode of op on.
Pre-mix volume was 4700 liters
Connec ons diagram:
30 minutes were taken for a pre-mix op on. Pre-mix was made by recircula on through CCBL,
without using mechanical blending.
A er comp on of the pre-mix, 4700 liters from the vessel were transferred to CCBL blending.
Samples were taken from CCBL blended volume, stored separately a er comp on.
First sample was taken immediately r comple on.
Second sample was taken a er 60 min.
Pre-mix temperature: +28.9 C
Temperature er CCBL: +30.9 C
El. Consump on at CCBL: 11.12 KWh
Time CCBL blending: 44 minutes
Volume: 4700 liters
Total me (pre-mix + CCBL blending): 74 min.
ATTACHMENTS
1. Sp on of the produced lube oil
50
50. 2. te o lysis
CONCLUSION
The b results of s mple 1 d mple 2 re p ly ide . All results shows o formity with the
o limits.
Note: PRISTA op o i o for m l ble i g ol es 2 hours, i udi g dosi g d
mixi g t +40 C.
CCBL r l o mode of oper o e ely repl pre-mix, m de by m l ble di g.
51
58.
Lube oil: Transmission oil “PRISTA® EP 80W90 “
API GL 5
Brst 54,85%
SN 150 38,74%
Add 1 4,40%
Add 2 PPD 2,00%
Add 3 AF 0,01%
100%
DESCRIPTION OF THE TEST
Purpose: to evaluate the e ec veness of CCBL blending process in produc on of mu -grade
transmission oil, viscosity grade SAE 80W90, by making the pre-mix through CCBL recircu on mode of
op on.
Pre-mix volume was 4700 liters
Connec ons diagram:
30 minutes were taken for a pre-mix op on. Pre-mix was made by recircula on through CCBL,
without using mechanical blending.
A er comp on of the pre-mix, 4700 liters from the vessel were transferred to CCBL blending.
Samples were taken from CCBL blended volume, stored separately a er comp on.
First sample was taken immediately r comple on.
Second sample was taken a er 90 min.
Pre-mix temperature: +31.0 C
Temperature er CCBL: +32.9 C
El. Consump on at CCBL: 11.05 KWh
Time CCBL blending: 44 minutes
Volume: 4700 liters
Total me (pre-mix + CCBL blending): 74 min.
59
59. ATTACHMENTS
1. Sp on of the produced lube oil
2. te o lysis
CONCLUSION
The b results of s mple 1 nd mple 2 re p c ly iden . All results shows conformity with the
on limits.
Note: PRISTA op on in on for m n l blending involves 2 hours, including dosing d
mixing t +40 C.
CCBL recircul on mode of oper on n e ec vely repl pre-mix, m de by m n l blending.
60
68.
Mu -grade engine oil “PRISTA® SUPER BENZIN 15 W 40“
15W40 API SL/CF, ACEA A3/B3
SN 150 59,70%
SN 500 22,00%
Add 1 10,00%
Add 2 VII 8,00%
Add 3 PPD 0,30%
100,00%
DESCRIPTION OF THE TEST
Purpose: to evaluate the e ec veness of the CCBL blending process, making a whole blending process
in one vessel, using recircul on mode.
Pre-mix volume: 3000 liters, batch volume: 6700 liters
Connec on diagram:
3000 liters were used as input data for a pre-mix oper on with CCBL, working in recircu on mode
and without the use of mechanical blender. During the pre-mix process, base oil was added
con nuously to the tank.
A er comp on of the pre-mix, 3000 liters the CCBL was running to do the main, cavita on blending
with whole batch 6700 liters.
Samples were taken from CCBL blended volume, stored separately a er comp on.
First sample was taken immediately r comple on.
The second sample was tak er 60 minutes.
onal parameters:
Pre-mix temperature: +23.6 C
Temperature er CCBL: +26.4 C (recircul on mode)
69
69. El. Consump on at CCBL: 15.49 KWh
Time CCBL premix: 30 minutes
Volume: 6600 liters
Total me (pre-mix + CCBL blending): 62 min.
Add onal mechanical blending: not used.
ATTACHMENTS
1. Sp on of the produced lube oil
2. te of analysis
CONCLUSION
The lab results of sample 1 and sample 2 are prac ly iden . This v es that CCBL fully
recirculated blending process produces a fully homogeniz nished lube oil.
Note: Total me for mechanical blending as per PRISTA opera onal ins ons is min. 2 hours (dosing
and mixing at +40 C). Dosing usually takes 20 minutes maximum for batches up to 6 MT.
70