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Cast Aluminum Alloys
Aluminum alloys favorable
characteristics
· Good fluidity
· Low melting point
· Rapid heat transfer from the molten aluminum to the
mold
· Hydrogen is the only gas with appreciable solubility in
aluminum and its alloys and it can be removed with
several methods.
· Free from hot-short cracking and tearing tendencies
· Chemical stability
Cast Alloy Designations
No single universally accepted designation
system
Designations systems include:
 US 3 digit number, plus 1 decimal
 EN 5 digit number (RSA standard since1990’s)
 Chemical designations (eg old DIN)
 UK discontinued LM series still commonly
cited in RSA
 Others – eg old eastern Europe
 Others Far East – including Japan
Aluminum Casting Designations
Cast Alloy Designation (US)
US 3 digit number, plus 1 decimal
Al+
Pure Al Cu Si/Cu/Mg Si Mg Zn Sn
Other
1xx.x 2xx.x 3xx.x 4xx.x 5xx.x 7xx.x 8xx.x 9xx.x
Non-heat-treatable
Heat-treatable
AXXX.XIndicates a modification of the
original alloy or an impurity
limit ( Starting with A)
Aluminium Casting Designations
Cast Alloy Designation (US)
Principle Alloying Element
Specific alloy of the family
(Except for 1xx.x series)
Product Form - Final Casting (.0) or Ingot (.1 or .2)*
*Depending on Purity Limits
Example
Alloy A356.0 represents :
A finished casting (xxx.0)
Silicon plus copper and/or magnesium serie
(3xx.x)
Tighter controls on iron and other
impurities(Axxx.x)
Non-heat-treatable and Heat-treatable Alloys
Heat treatable Alloys Non heat treatable
Alloys
2xx.x 1xx.x
3xx.x 4xx.x
7xx.x 5xx.x
8xx.x
9xx.x
or without
O: annealed. The O applies to cast products that are
annealed to improve ductility and dimensional stability
Cast alloy designation system
2xx.x series (Aluminum-Copper)
× Poor castability
× Poor corrosion resistance
× High specific gravities
So Al-Cu cast alloys have been replaced by
Al–Si–Mg alloys
Heat treatable
Capable of developing the highest strengths among all cas
alloys through heat treating
Highest strengths and hardnesses of all casting alloys at
elevated temperatures (to 300 °C)
Example
242 ( 4% Cu , 2% Ni & 1.5% Mg )
Has high strength at elevated temperatures due to addition o
nickel and magnesium
Application
Internal combustion engine pistons
3xx.x series
(Aluminum-Silicon, with added copper and/or
magnesium)
In addition to silicon, contain magnesium, copper, or both
(Al-Si-Mg, Al-Si-Cu, or Al-Si-Cu-Mg)
Highest-volume-usage alloys
Silicon contents range from 5% to 22%
Copper contents range from 0% to a maximum of 4.5%
Magnesium contents ranging from as low as 0.3% to 0.6%
Increase in strength and hardness in the as cast (F) tempe
through solid-solution hardening both copper and magnesiu
Much greater Increases afforded by T5 tempers or by T6 o
tempers
Precipitation hardening results from precipitate structures
based on Mg2Si, Al2Cu, Al2CuMg, or combinations of these
phases.
Thermal expansion coefficient decreases with increasing
silicon
beneficial for engine applications such as pistons
Enhancing wear resistance when Silicon content exceeds
12%,
as in alloys 390.0 through 393.0 by primary silicon
3xx.x series
Example
356 Alloy
Application : Aircraft wheels
7% Si for enabling castablilty
0.35% Mg for enabling heat treatability
Mg2Si responsible for precipitation hardening
 Addition of Na in order to :
1. Refine eutectic structure
2. Improvement in mechanical properties
3. Less micro-shrinkages between dendrites
Without modification With modification
S
i
S
i
4xx.x series (Aluminum-Silicon
High fluidity
Excellent feeding during solidification
Free from hot shortness
More corrosion resistance in acidic environments
Not considered heat treatable due to small solubility of Si in
Aluminum
A simple eutectic system
Examples
413
Contains 12% Si
Used in die casting
443
Contains 5.3% Si
Used in sand and permanent mold
castings
Solidification of 443(5% Si)
First solidification of almost pure Aluminum dendrites
Space between dendrites fills with Al-Si eutectic
As eutectic freezes, it decompose into pure Al and Si
Faster solidification rates result in smaller dendrites
cells
Sand cast Permanent mold cast
Die cast
Dendrites
 Addition of Na or Sr results in
1. Refining eutectic structure (less angular)
2. Improvement in mechanical properties
Aluminum-Silicon modification
Without Na With Na
Eutectic structure can also be refined with faster cooling
rates
Sand cast( slow cooling
rate) with and without Na
Chill cast
Typical mechanical properties of sand- , permanent-mold- and die-cast
Al alloys
Yield Strength, ksiTensile Strength,
ksi
Mn addition
Al-Si-Fe intermetallics
Selection of Casting Alloys
· Casting process considerations: fluidity, resistance to hot
tearing, solidification range
· Casting design considerations: solidification range, resist
to hot tearing, fluidity, die soldering (die casting)
· Mechanical-property requirements: strength and ductility,
Heat treatability, hardness
· Service requirements: corrosion resistance, surface treat
, dimensional stability, thermal stability
· Economics: machinability, weldability, ingot and melting c
heat treatment
Selection of Casting Alloys
1=best ,
5=lowest
Cast Aluminum Alloys

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Cast Aluminum Alloys

  • 2. Aluminum alloys favorable characteristics · Good fluidity · Low melting point · Rapid heat transfer from the molten aluminum to the mold · Hydrogen is the only gas with appreciable solubility in aluminum and its alloys and it can be removed with several methods. · Free from hot-short cracking and tearing tendencies · Chemical stability
  • 3. Cast Alloy Designations No single universally accepted designation system Designations systems include:  US 3 digit number, plus 1 decimal  EN 5 digit number (RSA standard since1990’s)  Chemical designations (eg old DIN)  UK discontinued LM series still commonly cited in RSA  Others – eg old eastern Europe  Others Far East – including Japan
  • 4. Aluminum Casting Designations Cast Alloy Designation (US) US 3 digit number, plus 1 decimal Al+ Pure Al Cu Si/Cu/Mg Si Mg Zn Sn Other 1xx.x 2xx.x 3xx.x 4xx.x 5xx.x 7xx.x 8xx.x 9xx.x Non-heat-treatable Heat-treatable
  • 5. AXXX.XIndicates a modification of the original alloy or an impurity limit ( Starting with A) Aluminium Casting Designations Cast Alloy Designation (US) Principle Alloying Element Specific alloy of the family (Except for 1xx.x series) Product Form - Final Casting (.0) or Ingot (.1 or .2)* *Depending on Purity Limits
  • 6. Example Alloy A356.0 represents : A finished casting (xxx.0) Silicon plus copper and/or magnesium serie (3xx.x) Tighter controls on iron and other impurities(Axxx.x)
  • 7. Non-heat-treatable and Heat-treatable Alloys Heat treatable Alloys Non heat treatable Alloys 2xx.x 1xx.x 3xx.x 4xx.x 7xx.x 5xx.x 8xx.x 9xx.x
  • 8.
  • 9. or without O: annealed. The O applies to cast products that are annealed to improve ductility and dimensional stability
  • 10.
  • 12. 2xx.x series (Aluminum-Copper) × Poor castability × Poor corrosion resistance × High specific gravities So Al-Cu cast alloys have been replaced by Al–Si–Mg alloys Heat treatable Capable of developing the highest strengths among all cas alloys through heat treating Highest strengths and hardnesses of all casting alloys at elevated temperatures (to 300 °C)
  • 13. Example 242 ( 4% Cu , 2% Ni & 1.5% Mg ) Has high strength at elevated temperatures due to addition o nickel and magnesium Application Internal combustion engine pistons
  • 14. 3xx.x series (Aluminum-Silicon, with added copper and/or magnesium) In addition to silicon, contain magnesium, copper, or both (Al-Si-Mg, Al-Si-Cu, or Al-Si-Cu-Mg) Highest-volume-usage alloys Silicon contents range from 5% to 22% Copper contents range from 0% to a maximum of 4.5% Magnesium contents ranging from as low as 0.3% to 0.6%
  • 15. Increase in strength and hardness in the as cast (F) tempe through solid-solution hardening both copper and magnesiu Much greater Increases afforded by T5 tempers or by T6 o tempers Precipitation hardening results from precipitate structures based on Mg2Si, Al2Cu, Al2CuMg, or combinations of these phases. Thermal expansion coefficient decreases with increasing silicon beneficial for engine applications such as pistons Enhancing wear resistance when Silicon content exceeds 12%, as in alloys 390.0 through 393.0 by primary silicon 3xx.x series
  • 16. Example 356 Alloy Application : Aircraft wheels 7% Si for enabling castablilty 0.35% Mg for enabling heat treatability Mg2Si responsible for precipitation hardening  Addition of Na in order to : 1. Refine eutectic structure 2. Improvement in mechanical properties 3. Less micro-shrinkages between dendrites
  • 17. Without modification With modification S i S i
  • 18. 4xx.x series (Aluminum-Silicon High fluidity Excellent feeding during solidification Free from hot shortness More corrosion resistance in acidic environments Not considered heat treatable due to small solubility of Si in Aluminum A simple eutectic system
  • 19.
  • 20. Examples 413 Contains 12% Si Used in die casting 443 Contains 5.3% Si Used in sand and permanent mold castings
  • 21. Solidification of 443(5% Si) First solidification of almost pure Aluminum dendrites Space between dendrites fills with Al-Si eutectic As eutectic freezes, it decompose into pure Al and Si Faster solidification rates result in smaller dendrites cells
  • 22. Sand cast Permanent mold cast Die cast Dendrites
  • 23.  Addition of Na or Sr results in 1. Refining eutectic structure (less angular) 2. Improvement in mechanical properties Aluminum-Silicon modification Without Na With Na
  • 24. Eutectic structure can also be refined with faster cooling rates Sand cast( slow cooling rate) with and without Na Chill cast
  • 25.
  • 26. Typical mechanical properties of sand- , permanent-mold- and die-cast Al alloys Yield Strength, ksiTensile Strength, ksi
  • 28.
  • 29. Selection of Casting Alloys · Casting process considerations: fluidity, resistance to hot tearing, solidification range · Casting design considerations: solidification range, resist to hot tearing, fluidity, die soldering (die casting) · Mechanical-property requirements: strength and ductility, Heat treatability, hardness · Service requirements: corrosion resistance, surface treat , dimensional stability, thermal stability · Economics: machinability, weldability, ingot and melting c heat treatment
  • 30. Selection of Casting Alloys 1=best , 5=lowest