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OXIDE DISPERSION STRENGTHENED 
AUSTENITIC STAINLESS STEEL 
Presented by 
Suresh Beera 
12ETMM11 
M.Tech/Ph.D 
Materials Engineering 
SEST, UoH 
10/24/2014 
1
CONTENTS 
 Introduction to Stainless steels 
 Austenitic stainless steels 
 Oxide dispersion strengthening 
 ODS procedure 
 Comparisons with non ODS steels 
 Microstructure of ODS steel 
 applications 
 Advantages & disadvantages 
 Summary 
 References 
10/24/2014 
2
Stainless Steel 
• Add Chromium to steel 
• Above 13%, it precipitates 
at the surface, 
• Forms a Cr2O3 layer 
Which doesn’t corrode. 
•Martensitic (Heat Treated) 
•Duplex (Mo and Ni) 
•Ferrite (with Mo) 
•Austenitic (with Ni, Mn) 
10/24/2014 
3
AUSTENITIC STAINLESS STEELS when 
compare to a typical carbon steel. 
•high ductility, 
•low yield stress 
•relatively high ultimate tensile strength 
•good corrosion resistance, 
A carbon steel on cooling transforms from 
Austenite to a mixture of ferrite and 
cementite. 
type 304 typically contain 18Cr and 8Ni 
wt% (18/8 stainless) type 316 which 
contains up to 3 wt% Mo, offers an 
improved general and pitting corrosion 
resistance, 
They contain a maximum of 0.15% carbon, 
a minimum of 16% chromium and sufficient 
nickel and/or manganese to retain an 
austenitic structure at all temperatures 
from the cryogenic region to the melting 
point of the alloy 
10/24/2014 
4
What Is An Oxide Dispersion Strengthened (ODS) 
Alloy? 
Oxide dispersion strengthened alloys (ODS alloys) typically 
consist of a high temperature metal matrix - such as iron 
aluminide, iron chromium, iron-chromium-aluminium, nickel 
chromium or nickel aluminide - with small (5-50nm) oxide 
particles of alumina (Al2O3) or yttria (Y2O3) dispersed within 
it. 
Iron-based and nickel-based oxide dispersion strengthened 
alloys exhibit good corrosion resistance and mechanical 
properties at elevated temperatures. 
These alloys also show excellent creep resistance, and 
partly from the very large elongated grain structure 
10/24/2014 
5
The composition of two commercially-available oxide 
dispersion strengthened (ODS) alloys (one iron-based, 
the other nickel-based) 
Composition (wt%) 
Name Ni Fe Cr Al Ti C Yttrium 
Oxide 
INCONEL 
MA754 
78 1.0 20 0.3 0.5 0.05 0.6 
INCOLOY 
MA956 
- 74 20 4.5 0.5 0.05 0.5 
10/24/2014 
6
HOW ARE OXIDE DISPERSION STRENGTHENED 
(ODS) ALLOYS PRODUCED? 
yttria 
10/24/2014 
7
A Comparison Of Commercial ODS 
Steels & ferritic/martensitic steels 
A comparison of the yield stress 
as a function of test temperature 
for the three commercial ODS 
steels and the non-ODS 
10/24/2014 
8
A comparison of the ultimate tensile 
strength as a function of test temperature 
for the three commercial ODS steels and 
the non-ODS 
10/24/2014 
9
MICRO STRUCTURE OF STAINLESS STEEL 316L & 
MECHANICAL ALLOYED 316L 
a b 
SEM Images of (a) AISI 316L Stainless Steel, (b) Ti, 
10/24/2014 
10
C 
(d) MA Powders Composed of 99.4 
wt% AISI 316L Stainless Steel, 
0.3 wt% Ti , 
0.3 wt% Y2O3 
10/24/2014 
11 
(c) Y2O3
Applications 
0xide dispersion strengthened alloys (ODS) 
are used for high temperature turbine blades 
and heat exchanger tubing.Alloys of nickel 
are the most common but work is being done 
on iron aluminum alloys. 
ODS steels are used in nuclear 
applications. 
ODS materials are used on space crafts as 
a layer designed to protect the vehicle 
10/24/2014 
12
ADVANTAGES: 
Can be machined, brazed, formed, cut with available 
processes. 
Develops a protective oxide layer that is self-healing. 
Allows the design of thin-walled structures (sandwich). 
Resistant to harsh weather conditions in the troposphere 
Low maintenance cost. 
DISADVANTAGES: 
It has a higher expansion coefficient than other materials, 
causing higher thermal stresses. 
Lower maximum allowable temperature. 
10/24/2014 
13
Summary 
ODS steels can by produced by mechanical alloying process, 
hot isostatic pressing, and rolling. 
ODS austenitic stainless steel , exhibit good corrosion 
resistance, creep resistance and mechanical properties at 
elevated temperatures 
Yield strength and tensile strength of ODS Steels is higher 
than ferritic/martensitic steels 
Changes in Micro structure of Mechanical Alloying Stainless 
Steel 316L was observed 
10/24/2014 
14
REFERENCES 
Elements of metallurgy and engineering alloys f.C. 
Campbell, editor, p 573.148,441-445 
F.C. Campbell, manuf acturin g technology for aerospace 
structu ral mat erials, elsevier scientific, 2006 
Oxide dispersion-strengthened steels: a comparison of 
experimental and commercial steels―r. L. Klueh, j. P. 
Shingledecker, r. W. Swindeman, and d. T. Hoelzer (oak ridge 
national laboratory) 
Oxide dispersion strengthened steels: a comparison of 
microstructure features of some commercial steels with 
Applying of doppler broadening spectroscopy 
J. Veterníková, s. Kilpeläine, v. Slugen, f. Tuomisto 
10/24/2014 
15
THANK YOU 
10/24/2014 
16

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ODS Austenitic Stainless Steel Properties

  • 1. OXIDE DISPERSION STRENGTHENED AUSTENITIC STAINLESS STEEL Presented by Suresh Beera 12ETMM11 M.Tech/Ph.D Materials Engineering SEST, UoH 10/24/2014 1
  • 2. CONTENTS  Introduction to Stainless steels  Austenitic stainless steels  Oxide dispersion strengthening  ODS procedure  Comparisons with non ODS steels  Microstructure of ODS steel  applications  Advantages & disadvantages  Summary  References 10/24/2014 2
  • 3. Stainless Steel • Add Chromium to steel • Above 13%, it precipitates at the surface, • Forms a Cr2O3 layer Which doesn’t corrode. •Martensitic (Heat Treated) •Duplex (Mo and Ni) •Ferrite (with Mo) •Austenitic (with Ni, Mn) 10/24/2014 3
  • 4. AUSTENITIC STAINLESS STEELS when compare to a typical carbon steel. •high ductility, •low yield stress •relatively high ultimate tensile strength •good corrosion resistance, A carbon steel on cooling transforms from Austenite to a mixture of ferrite and cementite. type 304 typically contain 18Cr and 8Ni wt% (18/8 stainless) type 316 which contains up to 3 wt% Mo, offers an improved general and pitting corrosion resistance, They contain a maximum of 0.15% carbon, a minimum of 16% chromium and sufficient nickel and/or manganese to retain an austenitic structure at all temperatures from the cryogenic region to the melting point of the alloy 10/24/2014 4
  • 5. What Is An Oxide Dispersion Strengthened (ODS) Alloy? Oxide dispersion strengthened alloys (ODS alloys) typically consist of a high temperature metal matrix - such as iron aluminide, iron chromium, iron-chromium-aluminium, nickel chromium or nickel aluminide - with small (5-50nm) oxide particles of alumina (Al2O3) or yttria (Y2O3) dispersed within it. Iron-based and nickel-based oxide dispersion strengthened alloys exhibit good corrosion resistance and mechanical properties at elevated temperatures. These alloys also show excellent creep resistance, and partly from the very large elongated grain structure 10/24/2014 5
  • 6. The composition of two commercially-available oxide dispersion strengthened (ODS) alloys (one iron-based, the other nickel-based) Composition (wt%) Name Ni Fe Cr Al Ti C Yttrium Oxide INCONEL MA754 78 1.0 20 0.3 0.5 0.05 0.6 INCOLOY MA956 - 74 20 4.5 0.5 0.05 0.5 10/24/2014 6
  • 7. HOW ARE OXIDE DISPERSION STRENGTHENED (ODS) ALLOYS PRODUCED? yttria 10/24/2014 7
  • 8. A Comparison Of Commercial ODS Steels & ferritic/martensitic steels A comparison of the yield stress as a function of test temperature for the three commercial ODS steels and the non-ODS 10/24/2014 8
  • 9. A comparison of the ultimate tensile strength as a function of test temperature for the three commercial ODS steels and the non-ODS 10/24/2014 9
  • 10. MICRO STRUCTURE OF STAINLESS STEEL 316L & MECHANICAL ALLOYED 316L a b SEM Images of (a) AISI 316L Stainless Steel, (b) Ti, 10/24/2014 10
  • 11. C (d) MA Powders Composed of 99.4 wt% AISI 316L Stainless Steel, 0.3 wt% Ti , 0.3 wt% Y2O3 10/24/2014 11 (c) Y2O3
  • 12. Applications 0xide dispersion strengthened alloys (ODS) are used for high temperature turbine blades and heat exchanger tubing.Alloys of nickel are the most common but work is being done on iron aluminum alloys. ODS steels are used in nuclear applications. ODS materials are used on space crafts as a layer designed to protect the vehicle 10/24/2014 12
  • 13. ADVANTAGES: Can be machined, brazed, formed, cut with available processes. Develops a protective oxide layer that is self-healing. Allows the design of thin-walled structures (sandwich). Resistant to harsh weather conditions in the troposphere Low maintenance cost. DISADVANTAGES: It has a higher expansion coefficient than other materials, causing higher thermal stresses. Lower maximum allowable temperature. 10/24/2014 13
  • 14. Summary ODS steels can by produced by mechanical alloying process, hot isostatic pressing, and rolling. ODS austenitic stainless steel , exhibit good corrosion resistance, creep resistance and mechanical properties at elevated temperatures Yield strength and tensile strength of ODS Steels is higher than ferritic/martensitic steels Changes in Micro structure of Mechanical Alloying Stainless Steel 316L was observed 10/24/2014 14
  • 15. REFERENCES Elements of metallurgy and engineering alloys f.C. Campbell, editor, p 573.148,441-445 F.C. Campbell, manuf acturin g technology for aerospace structu ral mat erials, elsevier scientific, 2006 Oxide dispersion-strengthened steels: a comparison of experimental and commercial steels―r. L. Klueh, j. P. Shingledecker, r. W. Swindeman, and d. T. Hoelzer (oak ridge national laboratory) Oxide dispersion strengthened steels: a comparison of microstructure features of some commercial steels with Applying of doppler broadening spectroscopy J. Veterníková, s. Kilpeläine, v. Slugen, f. Tuomisto 10/24/2014 15