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Seminar 2 (SE)
Bio refineries
Guided by, Co-guided by,
Dr. Reshama Patel Prof. Jignesh Brhmbhatt
BIRLA
VISHVAKARMA
MAHAVIDYALAYA
(2019-2020)
Presented By,
SHIVANGI PATEL
[18EN803]
M. Tech 3rd sem., Environment Engg.,
BVM, VV nagar
INDEX
 Introduction
 Literature Review
 Classification of Biorefinery systems
 Economic viability of Biorefinery systems
 Environmental impact of Biorefinery systems
 Biorefinery Prospects in India
 Benefits
 Applicability
 References
INTRODUCTION
 A biorefinery is a facility that integrates biomass conversion
processes and equipment to produce fuels, power, and value-added
chemicals from biomass.
 Biorefinery is analogous to today’s petroleum refinery, which
produces multiple fuels and products from petroleum.
 By producing several products, a biorefinery takes advantage of the
various components in biomass and their intermediates, therefore
maximizing the value derived from the biomass feedstock.
Process of Biorefinery Source: Bioenergyconsultant.com
LITERATURE REVIEW
Author, Publication
year
Title Observation
Mahmoud A.
Sharara, Edgar C.
Clausen and
Danielle Julie
Carrier
(2012)
An Overview of
Biorefinery
Technology
• The thermochemical conversion platform is conducted at
temperatures of at least 3000C and results in the production
of bio-oils or syngas that can be upgraded into further
products.
• Biomass processing following the biochemical conversion
platform is, in a sense, more mild because of the
requirements of cell wall loosening coupled to enzymatic
release of the structural sugars. Because the sugars are
further fermented into various products, this technology
platform offers the possibility of producing various bio-
based products.
• The goal of this paper is to illustrate that specialty
chemicals and other bio-based products could be extracted
prior to or after the conversion process, increasing the
overall profitability and sustainability of the biorefinery.
Author, Publication
year
Title Observation
Meenakshi Suhag and
Hardeep Rai Sharma
(2015)
Biorefinery Concept:
An Overview of
Producing
Energy, Fuels and
Materials from
Biomass
Feedstocks
• Different types of biomass can be used in biorefineries.
• They are the industrial facilities, aiming sustainable
transformation of biomass into their building blocks with the
affiliated production of biofuels, energy, chemicals and
materials, and can play an important role in the creation of
sustainable and more environmentally friendly future.
• For sustainable economic growth many countries of the world
including India, can be encouraging places for biorefinery
approach due to abundance of different residual biomass
substrates.
• From the economic point of view less energy-requiring and
waste generating biorefinery technologies should be designed
and promoted for the assessment of lignocellulose and
breakdown processes.
• In addition, efficient microbial strains able to operate under
industrial process conditions and more efficient and economic
technology will be needed to make biorefinery approach a
successful one.
Author,
Publication year
Title Observation
S. Venkata
Mohan , G.N.
Nikhil, P.
Chiranjeevi, C.
Nagendranatha
Reddy, M.V.
Rohit, A. Naresh
Kumar,
Omprakash
Sarkar
(2016)
Waste biorefinery
models towards
sustainable
circular bio
economy:
Critical review and
future perspectives
• Increased urbanization worldwide has resulted in a substantial
increase in energy and material consumption as well as
anthropogenic waste generation.
• The main source for our current needs is petroleum refinery, which
have grave impact over energy-environment nexus.
• Therefore, production of bioenergy and biomaterials have
significant potential to contribute and need to meet the ever
increasing demand.
• This review illustrates different bioprocess based technological
models that will pave sustainable avenues for the development of
bio based society.
• The proposed models hypothesize closed loop approach wherein
waste is valorized through a cascade of various biotechnological
processes addressing circular economy.
• Biorefinery offers a sustainable green option to utilize waste and to
produce a gamut of marketable bio products and bioenergy on par
to petro-chemical refinery.
Biorefinery Concept Source: Bioenergyconsult.com
CLASSIFCATION OF BIOREFINERY
SYSTEMS
 Biorefinery can be classified based in four main features:
1. Platforms: Refers to key intermediates between raw material and final products. The
most important intermediates are:
• Biogas from anaerobic digestion
• Syngas from gasification
• Hydrogen from water-gas shift reaction, steam reforming, water electrolysis and
fermentation
• C6 sugars from hydrolysis of sucrose, starch, cellulose and hemicellulose
• C5 sugars (e.g., xylose, arabinose: C5H10O5), from hydrolysis of hemicellulose and
food and feed side streams
• Lignin from the processing of lignocellulose biomass.
• Liquid from Pyrolysis (pyrolysis oil)
2. Products: Bio refineries can be grouped in two main categories according to the
conversion of biomass in a energetic or non-energetic product. In this classification the
main market must be identified:
• Energy-driven biorefinery systems: The main product is a second energy carrier as
biofuels, power and heat.
• Material-driven biorefinery systems: The main product is a bio based product.
3. Feedstock: Dedicated feed stocks (Sugar crops, starch crops, lignocelluloses crops, oil-
based crops, grasses, marine biomass); and residues (oil-based residues, lignocellulose
residues, organic residues and others)
4. Processes: Conversion process to transform biomass into a final product:
• Mechanical/physical: The chemical structure of the biomass components is preserved.
This operation includes pressing, milling, separation, distillation, among others.
• Biochemical: Processes under low temperature and pressure, using microorganism or
enzymes.
• Chemical processes: The substrate suffer change by the action of an external chemical
(e.g., hydrolysis, transesterification, hydrogenation, oxidation, pulping)
• Thermochemical: Severe conditions are apply to the feedstock (high pressure and high
temperature, with or without catalyst).
Biorefining classification process Source: IEA Task42
ECONOMIC VIABILITY OF
BIOREFINERY SYSTEMS
 Techno-economic assessment (TEA) is a methodology to evaluate whether a technology
or process is economically attractive.
 TEA research has been developed to provide information about the performance of the
biorefinery concept in diverse production systems as sugarcane mills, biodiesel
production, pulp and paper mills, and the treatment of industrial and municipal solids
waste.
 The high generation of waste biomass is an attractive source for conversion to valuable
products, several biorefinery routes has been proposed to upgrade waste streams in
valuable products.
 The valorization of municipal solid waste through integrated mechanical biological
chemical treatment (MBCT) systems for the production of levulinic acid has been
studied, the revenue from resource recovery and product generation (without the
inclusion of gate fees) is more than enough to out- weigh the waste collection fees,
annual capital and operating costs.
Conceptual Biorefinery
ENVIRONMENTAL IMPACT OF
BIOREFINERY SYSTEMS
 One of the main goals of biorefinery is to contribute to a more sustainable industry by
the conservation of resources and by reducing greenhouse gas emissions and other
pollutants.
 Life cycle assessment (LCA) is a methodology to evaluate the environmental load of a
process, from the extraction of raw materials to the end use. LCA can be used to
investigate the potential benefits of biorefinery systems; multiple LCA studies has been
developed to analyze whether bio refineries are more environmentally friendly
compared to conventional alternatives.
 The majority of the LCA studies for the valorization of food waste have been focused
on the environmental impacts on biogas or energy production, with only few on the
synthesis of high value-added chemicals; hydroxymethylfurfural (HMF) has been listed
as one of the top 10 bio-based chemicals by the US Department of Energy.
BIOREFINERY PROSPECTS IN INDIA
 India has a tremendous biomass potential which could easily be relied upon to fulfil most
of our energy needs. An estimated 50 MMT (million metric tones) of liquid fuels are
consumed annually in India, but with the actual biomass potential and its full utilization,
India is capable of generating almost double that amount per annum.
 These biomass estimates only constitute the crop residues available in the country and
essentially the second-generation fuels since the use of first-generation crop bases fuels in
such food-starved nations is a criminal thought.
 Currently, there are various technologies available to process such crop residues and
generate value products from them. However, essentially, they all revolve around two
main kinds of processes, either biochemical or thermal.
 The biochemical process involves application of aerobic/anaerobic digestion for the
production of biogas; or fermentation, which results in the generation of ethanol. Both
these products could be subsequently treated chemically and through trans-esterification
process, leading to production of biodiesel.
 Alternatively, the thermochemical processes involve either the combustion, gasification
or pyrolysis techniques, which produces heat, energy-rich gas and liquid fuels
respectively. These products can be used as such, or could be further processed to
generate high quality biofuels or chemicals.
Biorefinery Model Source: intechopen.com
 The estimated organized energy breakup for India is 40 percent each for domestic
and transport sectors and 20 percent for the industrial sectors. The current share of
crude oil and gases is nearly 90 percent for the primary and transport sectors and the
remaining 10 percent for the generation of industrial chemicals.
 The fluctuating prices of crude oil in the international market and the resulting
concern over energy security, has lead developing nations to explore alternative and
cheap sources of energy to meet the growing energy demand. One of the promising
solution for agrarian economies is Biorefinery.
BENEFITS
 Bio refineries can help in utilizing the optimum energy potential of organic
wastes and may also resolve the problems of waste management and GHGs
emissions.
 Wastes can be converted, through appropriate enzymatic/chemical
treatment, into either gaseous or liquid fuels.
 The pre-treatment processes involved in bio refining generate products like
paper-pulp, HFCS, solvents, acetate, resins, laminates, adhesives, flavor
chemicals, activated carbon, fuel enhancers, undigested sugars etc. which
generally remain untapped in the traditional processes.
 The suitability of this process is further enhanced from the fact that it can
utilize a variety of biomass resources, whether plant-derived or animal-
derived.
APPLICABILITY
 The concept of biorefinery is still in early stages at most places in the world.
Problems like raw material availability, feasibility in product supply chain,
scalability of the model are hampering its development at commercial-scales.
 The National Renewable Energy Laboratory (NREL) of USA is leading the front
in biorefinery research with path-breaking discoveries and inventions.
 Although the technology is still in nascent stages, but it holds the key to the
optimum utilization of wastes and natural resources that humans have always
tried to achieve.
 The onus now lies on governments and corporate to incentivize or finance the
research and development in this field.
REFERENCES
• International Energy Agency - Bioenergy Task 42.” Bio-based Chemicals: Value Added Products from Biorefineries” (PDF). Retrieved 2019-
02-11.
• Cherubini, Francesco (July 2017). "The biorefinery concept: Using biomass instead of oil for producing energy and chemicals". Energy
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• Qureshi, Nasib; Hodge, David; Vertès, Alain (2014). Biorefineries. Integrated Biochemical Processes for Liquid Biofuels. Elsevier.
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a common classification approach for biorefinery systems". Modeling and Analysis. 3 (5): 534–546. DOI:10.1002/bbb.172.
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Bio-refineries

  • 1. Seminar 2 (SE) Bio refineries Guided by, Co-guided by, Dr. Reshama Patel Prof. Jignesh Brhmbhatt BIRLA VISHVAKARMA MAHAVIDYALAYA (2019-2020) Presented By, SHIVANGI PATEL [18EN803] M. Tech 3rd sem., Environment Engg., BVM, VV nagar
  • 2. INDEX  Introduction  Literature Review  Classification of Biorefinery systems  Economic viability of Biorefinery systems  Environmental impact of Biorefinery systems  Biorefinery Prospects in India  Benefits  Applicability  References
  • 3. INTRODUCTION  A biorefinery is a facility that integrates biomass conversion processes and equipment to produce fuels, power, and value-added chemicals from biomass.  Biorefinery is analogous to today’s petroleum refinery, which produces multiple fuels and products from petroleum.  By producing several products, a biorefinery takes advantage of the various components in biomass and their intermediates, therefore maximizing the value derived from the biomass feedstock.
  • 4. Process of Biorefinery Source: Bioenergyconsultant.com
  • 5. LITERATURE REVIEW Author, Publication year Title Observation Mahmoud A. Sharara, Edgar C. Clausen and Danielle Julie Carrier (2012) An Overview of Biorefinery Technology • The thermochemical conversion platform is conducted at temperatures of at least 3000C and results in the production of bio-oils or syngas that can be upgraded into further products. • Biomass processing following the biochemical conversion platform is, in a sense, more mild because of the requirements of cell wall loosening coupled to enzymatic release of the structural sugars. Because the sugars are further fermented into various products, this technology platform offers the possibility of producing various bio- based products. • The goal of this paper is to illustrate that specialty chemicals and other bio-based products could be extracted prior to or after the conversion process, increasing the overall profitability and sustainability of the biorefinery.
  • 6. Author, Publication year Title Observation Meenakshi Suhag and Hardeep Rai Sharma (2015) Biorefinery Concept: An Overview of Producing Energy, Fuels and Materials from Biomass Feedstocks • Different types of biomass can be used in biorefineries. • They are the industrial facilities, aiming sustainable transformation of biomass into their building blocks with the affiliated production of biofuels, energy, chemicals and materials, and can play an important role in the creation of sustainable and more environmentally friendly future. • For sustainable economic growth many countries of the world including India, can be encouraging places for biorefinery approach due to abundance of different residual biomass substrates. • From the economic point of view less energy-requiring and waste generating biorefinery technologies should be designed and promoted for the assessment of lignocellulose and breakdown processes. • In addition, efficient microbial strains able to operate under industrial process conditions and more efficient and economic technology will be needed to make biorefinery approach a successful one.
  • 7. Author, Publication year Title Observation S. Venkata Mohan , G.N. Nikhil, P. Chiranjeevi, C. Nagendranatha Reddy, M.V. Rohit, A. Naresh Kumar, Omprakash Sarkar (2016) Waste biorefinery models towards sustainable circular bio economy: Critical review and future perspectives • Increased urbanization worldwide has resulted in a substantial increase in energy and material consumption as well as anthropogenic waste generation. • The main source for our current needs is petroleum refinery, which have grave impact over energy-environment nexus. • Therefore, production of bioenergy and biomaterials have significant potential to contribute and need to meet the ever increasing demand. • This review illustrates different bioprocess based technological models that will pave sustainable avenues for the development of bio based society. • The proposed models hypothesize closed loop approach wherein waste is valorized through a cascade of various biotechnological processes addressing circular economy. • Biorefinery offers a sustainable green option to utilize waste and to produce a gamut of marketable bio products and bioenergy on par to petro-chemical refinery.
  • 8. Biorefinery Concept Source: Bioenergyconsult.com
  • 9. CLASSIFCATION OF BIOREFINERY SYSTEMS  Biorefinery can be classified based in four main features: 1. Platforms: Refers to key intermediates between raw material and final products. The most important intermediates are: • Biogas from anaerobic digestion • Syngas from gasification • Hydrogen from water-gas shift reaction, steam reforming, water electrolysis and fermentation • C6 sugars from hydrolysis of sucrose, starch, cellulose and hemicellulose • C5 sugars (e.g., xylose, arabinose: C5H10O5), from hydrolysis of hemicellulose and food and feed side streams • Lignin from the processing of lignocellulose biomass. • Liquid from Pyrolysis (pyrolysis oil)
  • 10. 2. Products: Bio refineries can be grouped in two main categories according to the conversion of biomass in a energetic or non-energetic product. In this classification the main market must be identified: • Energy-driven biorefinery systems: The main product is a second energy carrier as biofuels, power and heat. • Material-driven biorefinery systems: The main product is a bio based product. 3. Feedstock: Dedicated feed stocks (Sugar crops, starch crops, lignocelluloses crops, oil- based crops, grasses, marine biomass); and residues (oil-based residues, lignocellulose residues, organic residues and others) 4. Processes: Conversion process to transform biomass into a final product: • Mechanical/physical: The chemical structure of the biomass components is preserved. This operation includes pressing, milling, separation, distillation, among others. • Biochemical: Processes under low temperature and pressure, using microorganism or enzymes. • Chemical processes: The substrate suffer change by the action of an external chemical (e.g., hydrolysis, transesterification, hydrogenation, oxidation, pulping) • Thermochemical: Severe conditions are apply to the feedstock (high pressure and high temperature, with or without catalyst).
  • 12. ECONOMIC VIABILITY OF BIOREFINERY SYSTEMS  Techno-economic assessment (TEA) is a methodology to evaluate whether a technology or process is economically attractive.  TEA research has been developed to provide information about the performance of the biorefinery concept in diverse production systems as sugarcane mills, biodiesel production, pulp and paper mills, and the treatment of industrial and municipal solids waste.  The high generation of waste biomass is an attractive source for conversion to valuable products, several biorefinery routes has been proposed to upgrade waste streams in valuable products.  The valorization of municipal solid waste through integrated mechanical biological chemical treatment (MBCT) systems for the production of levulinic acid has been studied, the revenue from resource recovery and product generation (without the inclusion of gate fees) is more than enough to out- weigh the waste collection fees, annual capital and operating costs.
  • 14. ENVIRONMENTAL IMPACT OF BIOREFINERY SYSTEMS  One of the main goals of biorefinery is to contribute to a more sustainable industry by the conservation of resources and by reducing greenhouse gas emissions and other pollutants.  Life cycle assessment (LCA) is a methodology to evaluate the environmental load of a process, from the extraction of raw materials to the end use. LCA can be used to investigate the potential benefits of biorefinery systems; multiple LCA studies has been developed to analyze whether bio refineries are more environmentally friendly compared to conventional alternatives.  The majority of the LCA studies for the valorization of food waste have been focused on the environmental impacts on biogas or energy production, with only few on the synthesis of high value-added chemicals; hydroxymethylfurfural (HMF) has been listed as one of the top 10 bio-based chemicals by the US Department of Energy.
  • 15. BIOREFINERY PROSPECTS IN INDIA  India has a tremendous biomass potential which could easily be relied upon to fulfil most of our energy needs. An estimated 50 MMT (million metric tones) of liquid fuels are consumed annually in India, but with the actual biomass potential and its full utilization, India is capable of generating almost double that amount per annum.  These biomass estimates only constitute the crop residues available in the country and essentially the second-generation fuels since the use of first-generation crop bases fuels in such food-starved nations is a criminal thought.  Currently, there are various technologies available to process such crop residues and generate value products from them. However, essentially, they all revolve around two main kinds of processes, either biochemical or thermal.  The biochemical process involves application of aerobic/anaerobic digestion for the production of biogas; or fermentation, which results in the generation of ethanol. Both these products could be subsequently treated chemically and through trans-esterification process, leading to production of biodiesel.  Alternatively, the thermochemical processes involve either the combustion, gasification or pyrolysis techniques, which produces heat, energy-rich gas and liquid fuels respectively. These products can be used as such, or could be further processed to generate high quality biofuels or chemicals.
  • 16. Biorefinery Model Source: intechopen.com
  • 17.  The estimated organized energy breakup for India is 40 percent each for domestic and transport sectors and 20 percent for the industrial sectors. The current share of crude oil and gases is nearly 90 percent for the primary and transport sectors and the remaining 10 percent for the generation of industrial chemicals.  The fluctuating prices of crude oil in the international market and the resulting concern over energy security, has lead developing nations to explore alternative and cheap sources of energy to meet the growing energy demand. One of the promising solution for agrarian economies is Biorefinery.
  • 18. BENEFITS  Bio refineries can help in utilizing the optimum energy potential of organic wastes and may also resolve the problems of waste management and GHGs emissions.  Wastes can be converted, through appropriate enzymatic/chemical treatment, into either gaseous or liquid fuels.  The pre-treatment processes involved in bio refining generate products like paper-pulp, HFCS, solvents, acetate, resins, laminates, adhesives, flavor chemicals, activated carbon, fuel enhancers, undigested sugars etc. which generally remain untapped in the traditional processes.  The suitability of this process is further enhanced from the fact that it can utilize a variety of biomass resources, whether plant-derived or animal- derived.
  • 19.
  • 20. APPLICABILITY  The concept of biorefinery is still in early stages at most places in the world. Problems like raw material availability, feasibility in product supply chain, scalability of the model are hampering its development at commercial-scales.  The National Renewable Energy Laboratory (NREL) of USA is leading the front in biorefinery research with path-breaking discoveries and inventions.  Although the technology is still in nascent stages, but it holds the key to the optimum utilization of wastes and natural resources that humans have always tried to achieve.  The onus now lies on governments and corporate to incentivize or finance the research and development in this field.
  • 21. REFERENCES • International Energy Agency - Bioenergy Task 42.” Bio-based Chemicals: Value Added Products from Biorefineries” (PDF). Retrieved 2019- 02-11. • Cherubini, Francesco (July 2017). "The biorefinery concept: Using biomass instead of oil for producing energy and chemicals". Energy Conversion and Management. Elsevier. 15 (7): 1412–1421. DOI:10.1016/j.enconman.2010.01.015. ISSN 0196-8904. • Bajpai, Pratima (2013). Biorefinery in the Pulp and Paper Industry. Elsevier. p. 99. ISBN 9780124095083. • Qureshi, Nasib; Hodge, David; Vertès, Alain (2014). Biorefineries. Integrated Biochemical Processes for Liquid Biofuels. Elsevier. p. 59. ISBN 9780444594983. • Cherubini, Francesco; Jungmeier, Gerfried; Wellisch, Maria; Willke, Thomas; Skiadas, Ioannis; Van Ree, René; de Jong, Ed (2009). "Toward a common classification approach for biorefinery systems". Modeling and Analysis. 3 (5): 534–546. DOI:10.1002/bbb.172. • Rabelo, S.C.; Carrere, H.; Maciel Filho, R.; Costa, A.C. (September 2011). "Production of bioethanol, methane, and heat from sugarcane bagasse in a biorefinery concept". Bioresource Technology. 102 (17): 7887–7895. DOI:10.1016/j.biortech.2011.05.081. ISSN 0960- 8524. PMID 21689929. • Lopes, Mario Lucio; de Lima Paulillo, Silene Cristina; Godoy, Alexander; Cherubin, Rudimar Antonio; Lorenzi, Marcel Salmeron; Carvalho Giometti, Fernando Henrique; Domingos Bernardino, Claudemir; de Amorim Neto, Henrique Berbert; de Amorim, Henrique Vianna (December 2016).” Ethanol production in Brazil: a bridge between science and industry”. Brazilian Journal of Microbiology. 47: 64– 76. DOI:10.1016/j.bjm.2016.10.003. PMC 5156502. PMID 27818090. • Gubicza, Krisztina; Nieves, Ismael U.; William J., Sagues; Barta, Zsolt; Shanmugam, K.T.; Ingram, Lonnie O. (May 2016). "Techno- economic analysis of ethanol production from sugarcane bagasse using a Liquefaction plus Simultaneous Saccharification and co- Fermentation process". Bioresource Technology. 208: 42–48. DOI:10.1016/j.biortech.2016.01.093. PMID 26918837. • Özüdoğru, H.M. Raoul; Nieder-Heitmann, M.; Haigh, K.F.; Görgens, J.F. (March 2019). "Techno-economic analysis of product biorefineries utilizing sugarcane lignocelluloses: Xylitol, citric acid and glutamic acid scenarios annexed to sugar mills with electricity co- production". Industrial Crops and Products. 133: 259–268. DOI:10.1016/j.indcrop.2019.03.015. ISSN 0926-6690. • Mandegari, Mohsen; Farzad, Somayeh; Görgens, Johann F. (June 2018). "A new insight into sugarcane biorefineries with fossil fuel co- combustion: Techno-economic analysis and life cycle assessment". Energy Conversion and Management. 165: 76– 91. DOI:10.1016/j.enconman.2018.03.057. ISSN 0196-8904.
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