ACIDS, BASES & SALTS
Pranabjyoti Das
Acids
Introduction :
An acid is any hydrogen containing
substance that is capable of donating
a proton or hydrogen Ion to another
substance.
Arrhenius definition:
Any substance that, when dissolved in water,
increases the concentration of hydronium ion
(H3O+) is called as Acid
Thus acids are proton donors or electron
acceptors.
Example : H2SO4, HCl, CH3COOH
Properties ofacids
They taste sour. The word 'acid' comes from the Latin
“acere”, which means 'sour'
Acids can change litmus from blue to red
Aqueous solutions of acids canconduct electric
current
Acids react with bases to form salts and water
Acids can release H2 upon reaction with an active metal
such as zinc, aluminum etc
Classification of acids:
Strong Acid:
They break down completely to give off many H+ ions in
their aquous state
Weak Acids:
They partially breaks down, gives less number
of H+ in their aquous solutions
Some Common Acids
Strong Acids The Formula
Sulphuric acid H2SO4
Hydrochloric acid HCl
Hybrobromic acid HBr
Hydroiodic acid HI
Nitric acid
Perchloric acid
HNO3
HClO4
Some weak Acids are …
Weak Acid The Formula
Acetic acid(vinegar)
Carbonic acid
CH₃COOH
H₂CO₃
Uses of Acids
Acids have numerous uses, some of which
include:
HCl in stomach
H2SO4 in car batteries, asdryingagent’
HNO3 in manufacturing of fertilizers
Ethanoic acid in food industry
Fatty acids in soap making
Ascorbic acid in medicine
Bases
Bases produce OH- ions in aqueoussolutions.
Bases are proton acceptors
Bases are electron pairdonors
Least restrictive of acid-basedefinitions
Examples of Bases:
NaOH, Mg(OH)2, Ca(OH)2.
Properties of Bases
Bases taste bitter
Bases are slippery or soapy to touch
Bases can turn acidified red litmus to blue
Their aqueous solutions conduct electric current
Bases react with acids to form salts andwater
Classification of Bases
Strong bases:
A strong base is a basic chemical compound that can release hydroyl
ions in maximum amount. Common examples of strong bases include
hydroxides of alkali metals and alkaline earth metals like NaOH and
Ca(OH)2
Strong Bases Formulae
Potassium hydroxide (KOH)
Barium hydroxide (Ba(OH)2)
Cesium hydroxide (CsOH)
Sodium hydroxide (NaOH)
Strontium hydroxide (Sr(OH)2)
Calcium hydroxide
Lithium hydroxide
(Ca(OH)2)
(LiOH)
Rubidium hydroxide (RbOH)
Weak Bases
A weak base is a basic chemical compound that can
release hydroyl ions in less amount. Common example of
weak base is NH4OH
Strong Bases Formulae
Ammonia NH3
Methylamine CH3NH2
Pyridine C5H5N
Ammonium hydroxide NH4OH
Preparation of Bases
There are various methods for the preparation ofbases.
Reaction of oxygen with metals to form metal oxide:
Many metals react with oxygen gas to form the metal oxide.
Forexample, calcium reacts in the following manner.
2Ca(s) + O2(g) 2 CaO(s)
Thermal decomposition of carbonates:
Metal carbonates such as calcium carbonate break down when
heated strongly. This is called thermal decomposition. Here
are the equations for the thermal decomposition of calcium
carbonate:
CaCO3 ―> CaO +CO2
By double decomposition reaction:
A chemical reaction between two compounds in which
parts of each are interchanged to form two new
compounds
(AB + CD = AD + CB)
By dissolving basic oxides in water:
The oxides of feebly acidic cations react exothermically
with water
producing the hydroxide.
CaO + H2O ‹―› Ca(OH)2
Uses of Bases:
 Sodium hydroxide (caustic soda) is used in the manufacture of
soap. It is used in petroleum-refining; in making medicines,
paper, pulp, etc. It is used in making rayon.
 Calcium hydroxide is also known as slaked lime. It is used to
neutralize acid in water supplies; in the manufacture of
bleaching powder; as a dressing material for acid burns; as an
antidote for food poisoning; in the preparation of fungicides
and in the mixture of whitewash. It is mixed with sand and
water to make mortar which is used in the construction of
buildings. It is also used by farmers on the fields to neutralize
the harmful effects of acid rain.
 Ammonium hydroxide is used toremove ink spots from clothes
and to remove grease from window-panes. It is used in the
cosmetic industry.
 Alkalis are used in alkaline batteries. Generally potassium
hydroxide is used in such batteries.
Salts
+ 2NaOH(aq) ==== Na2SO4(aq) +
H2SO4(aq) 2H2O(l)
Here sodium sulphate (Na2SO4) is the salt formed.
The chemical symbol for table salt isNaCl
When H+ ion of an acid is replaced by a metal ion, a
salt is produced
Properties of salts
Most of the salts are crystallinesolid.
Salts may be transparent oropaque.
Most of the salts are soluble inwater.
Solution of salts conducts electricity.
Salts conduct electricity intheir molten statealso.
The salt may be salty, sour, sweet and bitter
Neutral salts areodourless.
Salts can be colourless or ofcoloured.
Classification of Salts
1.Normal salt The hydrogen ions of the acid are completely
replaced by metallic ions . Examples are NaCl, CuSO4, KNO3,
and CaCO3. Normal salts are electrically neutral.
2.Acid salt The salt still has hydrogen atom(s) from an acid
which can further be replaced by metallic ions. Examples
include: NaHSO4, NaHCO3 etc
3.Basic salt The salt contains hydroxides together with
metallic ions and negative ions from an acid. Examples are
basic zinc chloride, ZnOHCl, basic magnesium chloride etc
There are different kinds of salts. Theseinclude:
Uses of Salts
S.No Salt Use
1 Ammonium Chloride In torch batteries
2 Ammonium Nitrate In fertilizers
3 Calcium Chloride As drying agent
4 Iron Sulphate In Iron tablets
5 Magnesium Sulphate In medicine
6 Potassium Nitrate In gunpowder etc.
7 Silver Bromide In photography
8 Sodium Chloride Making NaOH
9 Sodium Stearate In making soap.
pH Scale
The negative logarithm of the hydronium ion concentration of an
aqueous solution; used to express acidity.
pH is the measure of the acidity
or basicity of a solution. The pH scale
ranges from 1 to 14
1 through 6 being acidic
7 is considered neutral
8 through 14 being basic
pH is a way to measure how acidic
or basic a solution is.
Low pH values = Acids
High pH values = Bases
pH measures the concentration
of hydrogen ions = H+
Acids, Bases and Salts

Acids, Bases and Salts

  • 1.
    ACIDS, BASES &SALTS Pranabjyoti Das
  • 2.
    Acids Introduction : An acidis any hydrogen containing substance that is capable of donating a proton or hydrogen Ion to another substance. Arrhenius definition: Any substance that, when dissolved in water, increases the concentration of hydronium ion (H3O+) is called as Acid Thus acids are proton donors or electron acceptors. Example : H2SO4, HCl, CH3COOH
  • 3.
    Properties ofacids They tastesour. The word 'acid' comes from the Latin “acere”, which means 'sour' Acids can change litmus from blue to red Aqueous solutions of acids canconduct electric current Acids react with bases to form salts and water Acids can release H2 upon reaction with an active metal such as zinc, aluminum etc
  • 4.
    Classification of acids: StrongAcid: They break down completely to give off many H+ ions in their aquous state
  • 5.
    Weak Acids: They partiallybreaks down, gives less number of H+ in their aquous solutions
  • 6.
    Some Common Acids StrongAcids The Formula Sulphuric acid H2SO4 Hydrochloric acid HCl Hybrobromic acid HBr Hydroiodic acid HI Nitric acid Perchloric acid HNO3 HClO4 Some weak Acids are … Weak Acid The Formula Acetic acid(vinegar) Carbonic acid CH₃COOH H₂CO₃
  • 7.
    Uses of Acids Acidshave numerous uses, some of which include: HCl in stomach H2SO4 in car batteries, asdryingagent’ HNO3 in manufacturing of fertilizers Ethanoic acid in food industry Fatty acids in soap making Ascorbic acid in medicine
  • 8.
    Bases Bases produce OH-ions in aqueoussolutions. Bases are proton acceptors Bases are electron pairdonors Least restrictive of acid-basedefinitions Examples of Bases: NaOH, Mg(OH)2, Ca(OH)2.
  • 9.
    Properties of Bases Basestaste bitter Bases are slippery or soapy to touch Bases can turn acidified red litmus to blue Their aqueous solutions conduct electric current Bases react with acids to form salts andwater
  • 10.
    Classification of Bases Strongbases: A strong base is a basic chemical compound that can release hydroyl ions in maximum amount. Common examples of strong bases include hydroxides of alkali metals and alkaline earth metals like NaOH and Ca(OH)2 Strong Bases Formulae Potassium hydroxide (KOH) Barium hydroxide (Ba(OH)2) Cesium hydroxide (CsOH) Sodium hydroxide (NaOH) Strontium hydroxide (Sr(OH)2) Calcium hydroxide Lithium hydroxide (Ca(OH)2) (LiOH) Rubidium hydroxide (RbOH)
  • 11.
    Weak Bases A weakbase is a basic chemical compound that can release hydroyl ions in less amount. Common example of weak base is NH4OH Strong Bases Formulae Ammonia NH3 Methylamine CH3NH2 Pyridine C5H5N Ammonium hydroxide NH4OH
  • 12.
    Preparation of Bases Thereare various methods for the preparation ofbases. Reaction of oxygen with metals to form metal oxide: Many metals react with oxygen gas to form the metal oxide. Forexample, calcium reacts in the following manner. 2Ca(s) + O2(g) 2 CaO(s) Thermal decomposition of carbonates: Metal carbonates such as calcium carbonate break down when heated strongly. This is called thermal decomposition. Here are the equations for the thermal decomposition of calcium carbonate: CaCO3 ―> CaO +CO2
  • 13.
    By double decompositionreaction: A chemical reaction between two compounds in which parts of each are interchanged to form two new compounds (AB + CD = AD + CB) By dissolving basic oxides in water: The oxides of feebly acidic cations react exothermically with water producing the hydroxide. CaO + H2O ‹―› Ca(OH)2
  • 14.
    Uses of Bases: Sodium hydroxide (caustic soda) is used in the manufacture of soap. It is used in petroleum-refining; in making medicines, paper, pulp, etc. It is used in making rayon.  Calcium hydroxide is also known as slaked lime. It is used to neutralize acid in water supplies; in the manufacture of bleaching powder; as a dressing material for acid burns; as an antidote for food poisoning; in the preparation of fungicides and in the mixture of whitewash. It is mixed with sand and water to make mortar which is used in the construction of buildings. It is also used by farmers on the fields to neutralize the harmful effects of acid rain.  Ammonium hydroxide is used toremove ink spots from clothes and to remove grease from window-panes. It is used in the cosmetic industry.  Alkalis are used in alkaline batteries. Generally potassium hydroxide is used in such batteries.
  • 15.
    Salts + 2NaOH(aq) ====Na2SO4(aq) + H2SO4(aq) 2H2O(l) Here sodium sulphate (Na2SO4) is the salt formed. The chemical symbol for table salt isNaCl When H+ ion of an acid is replaced by a metal ion, a salt is produced
  • 16.
    Properties of salts Mostof the salts are crystallinesolid. Salts may be transparent oropaque. Most of the salts are soluble inwater. Solution of salts conducts electricity. Salts conduct electricity intheir molten statealso. The salt may be salty, sour, sweet and bitter Neutral salts areodourless. Salts can be colourless or ofcoloured.
  • 17.
    Classification of Salts 1.Normalsalt The hydrogen ions of the acid are completely replaced by metallic ions . Examples are NaCl, CuSO4, KNO3, and CaCO3. Normal salts are electrically neutral. 2.Acid salt The salt still has hydrogen atom(s) from an acid which can further be replaced by metallic ions. Examples include: NaHSO4, NaHCO3 etc 3.Basic salt The salt contains hydroxides together with metallic ions and negative ions from an acid. Examples are basic zinc chloride, ZnOHCl, basic magnesium chloride etc There are different kinds of salts. Theseinclude:
  • 18.
    Uses of Salts S.NoSalt Use 1 Ammonium Chloride In torch batteries 2 Ammonium Nitrate In fertilizers 3 Calcium Chloride As drying agent 4 Iron Sulphate In Iron tablets 5 Magnesium Sulphate In medicine 6 Potassium Nitrate In gunpowder etc. 7 Silver Bromide In photography 8 Sodium Chloride Making NaOH 9 Sodium Stearate In making soap.
  • 19.
    pH Scale The negativelogarithm of the hydronium ion concentration of an aqueous solution; used to express acidity. pH is the measure of the acidity or basicity of a solution. The pH scale ranges from 1 to 14 1 through 6 being acidic 7 is considered neutral 8 through 14 being basic
  • 20.
    pH is away to measure how acidic or basic a solution is. Low pH values = Acids High pH values = Bases pH measures the concentration of hydrogen ions = H+