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Acid and bases
by
Dr. Rania S. Seoudi
1
Acid and bases
Brønsted acid: A substance capable of donating a proton.
Brønsted base: A substance capable of accepting a proton.
Conjugate acid-base pair: an acid and its conjugate base or a base and its
conjugate acid.
2
Acid –base properties of water
- Water is a poor conductor
- Ionize in a small extent:
3
The ion product of water
4
5
pH- A measure of acidity
- H+ and OH- ions in aqueous solution are frequently very small numbers to work
with. Instead we work with pH:
- pH is simple way to express hydrogen ion concentration, and acidic and basic
solution can be distinguish by their pHs values:
- If pH value is given and hydrogen ion concentration is needed to be calculated:
-
6
- Again for ion – product constant of water at 25oC:
7
8
Strength of acids and bases
- Strong acids are strong electrolytes that, for practical purposes, are assumed to ionize completely in
water.
- Most of strong acids are inorganic acids such as: hydrochloric acid (HCl), nitric acid (HNO3),
perchloric acid (HClO4), and sulfuric acid (H2SO4):
- Most acids are weak acids (ionize to limit extent).
- Weak acids contain nonionized acid moleucles such as: hydrofluoric acid (HF),
acetic acid (CH3COOH), and the ammonium ion (NH+
4).
9
- Conjugate acid-base pairs have the following properties:
1. If an acid is strong, its conjugate base has no measurable strength. Thus, the Cl2 ion, which
is the conjugate base of the strong acid HCl, is an extremely weak base.
2. H3O+ is the strongest acid that can exist in aqueous solution. Acids stronger than H3O+
react with water to produce H3O+ and their conjugate bases.
For weak acids than H3O+
1. The OH- ion is the strongest base that can exist in aqueous solution. Bases stronger than
OH- react with water to produce OH- and their conjugate acids.
10
Weak acids and acid ionization constants
- The vast majority of acids are weak acids.
- Consider the weak monprotic acid HA
- The equilibrium expression for this ionization is
11
- If we know pH of weak acid and initial concentration we can know Ka
- Example: calculate pH od 0.50M HF solution at 25oC (Ka=7.1x10-4):
So,
12
In summary, the main steps for solving weak acid ionization problems are:
1. Identify the major species that can affect the pH of the solution. In most cases we can
ignore the ionization of water. We omit the hydroxide ion because its concentration is
determined by that of the H+ ion.
2. Express the equilibrium concentrations of these species in terms of the initial concentration
of the acid and a single unknown x, which represents the change in concentration.
3. Write the weak acid ionization and express the ionization constant Ka in terms of the
equilibrium concentrations of H+, the conjugate base, and the unionized acid and solve x.
4. Having solved for x, calculate the equilibrium concentrations of all species and/or the pH of
the solution.
13

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Acid and bases

  • 1. Acid and bases by Dr. Rania S. Seoudi 1
  • 2. Acid and bases Brønsted acid: A substance capable of donating a proton. Brønsted base: A substance capable of accepting a proton. Conjugate acid-base pair: an acid and its conjugate base or a base and its conjugate acid. 2
  • 3. Acid –base properties of water - Water is a poor conductor - Ionize in a small extent: 3
  • 4. The ion product of water 4
  • 5. 5
  • 6. pH- A measure of acidity - H+ and OH- ions in aqueous solution are frequently very small numbers to work with. Instead we work with pH: - pH is simple way to express hydrogen ion concentration, and acidic and basic solution can be distinguish by their pHs values: - If pH value is given and hydrogen ion concentration is needed to be calculated: - 6
  • 7. - Again for ion – product constant of water at 25oC: 7
  • 8. 8
  • 9. Strength of acids and bases - Strong acids are strong electrolytes that, for practical purposes, are assumed to ionize completely in water. - Most of strong acids are inorganic acids such as: hydrochloric acid (HCl), nitric acid (HNO3), perchloric acid (HClO4), and sulfuric acid (H2SO4): - Most acids are weak acids (ionize to limit extent). - Weak acids contain nonionized acid moleucles such as: hydrofluoric acid (HF), acetic acid (CH3COOH), and the ammonium ion (NH+ 4). 9
  • 10. - Conjugate acid-base pairs have the following properties: 1. If an acid is strong, its conjugate base has no measurable strength. Thus, the Cl2 ion, which is the conjugate base of the strong acid HCl, is an extremely weak base. 2. H3O+ is the strongest acid that can exist in aqueous solution. Acids stronger than H3O+ react with water to produce H3O+ and their conjugate bases. For weak acids than H3O+ 1. The OH- ion is the strongest base that can exist in aqueous solution. Bases stronger than OH- react with water to produce OH- and their conjugate acids. 10
  • 11. Weak acids and acid ionization constants - The vast majority of acids are weak acids. - Consider the weak monprotic acid HA - The equilibrium expression for this ionization is 11
  • 12. - If we know pH of weak acid and initial concentration we can know Ka - Example: calculate pH od 0.50M HF solution at 25oC (Ka=7.1x10-4): So, 12
  • 13. In summary, the main steps for solving weak acid ionization problems are: 1. Identify the major species that can affect the pH of the solution. In most cases we can ignore the ionization of water. We omit the hydroxide ion because its concentration is determined by that of the H+ ion. 2. Express the equilibrium concentrations of these species in terms of the initial concentration of the acid and a single unknown x, which represents the change in concentration. 3. Write the weak acid ionization and express the ionization constant Ka in terms of the equilibrium concentrations of H+, the conjugate base, and the unionized acid and solve x. 4. Having solved for x, calculate the equilibrium concentrations of all species and/or the pH of the solution. 13