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Rimsha FarooqSyeda Rehab Gillani
BBS153009BBS153012
Presented to : Dr. Arshia AminButt
CONTENTS
5/7/2020 10:49:39 AM Capital University of Science and Technology Islamabad 2
Introduction
Composition of Syringes
Radiation effect on Syringes
Natural Bio gradation of commonly used Syringes
TPSPP Blends
Alternatives of Syringes
Degradation of Syringes
Gloves Chemical composition and DEgradation
INTRODUCTION
5/7/2020 10:49:39 AMCapital University of Science and Technology Islamabad
3
(1)Domestic wastes
(2)Hazardous wastes
(3)Infectious wastes
5/7/2020 10:49:39 AM Capital University of Science and Technology Islamabad 4
• Syringe plunger, barrel and
cap are made of
polypropylene (PP) or
polyethylene (PE) plastic
materials. These materials
must be at medical grade
because of their medical use.
RADIATION EFFECTS ON SYRINGES
25-40 k gy radiation doses, some changes can occur on the plastic syringe materials
5/7/2020 10:49:39 AMCapital University of Science and Technology Islamabad
5
While cross-linking occurs in PE plastic material, PP is sensitive to discoloration
Melting and crystallization behavior of PP syringes, they applied DSC and obtained the
melting temperature and fusion enthalpy
NATURAL BIODEGRADATION OF
COMMONLY USED SYRINGES
If the syringe is made of polyethylene (PE)
If syringe is made of polypropylene (PP)
5/7/2020 10:49:39 AM Capital University of Science and Technology Islamabad 6
POLYETHYLENE(PE)
5/7/2020 10:49:39 AMCapital University of Science and Technology Islamabad
7
POLYPROPYLENE(PP)
5/7/2020 10:49:39 AM Capital University of Science and Technology Islamabad 8
TPSPP BLENDS
• Pseudo plastic and exhibited shear-thinning behavior, where the viscosity
decreased with increasing shear rate
5/7/2020 10:49:39 AMCapital University of Science and Technology Islamabad
9
• The flow behavior of the blends is more sensitive to temperature
compared with PP
TPSPE BLENDS
5/7/2020 10:49:39 AMCapital University of Science and Technology Islamabad
10
ALTERNATIVE OF PEPP
SYRINGES
5/7/2020 10:49:39 AM Capital University of Science and Technology Islamabad 11
BIODEGRADATION OF POLYCARBONATE
• − (−OC6H4)2C (CH3)2CO−) −n + H2O → (CH3)2C (C6H4OH)2 + CO2
5/7/2020 10:49:39 AMCapital University of Science and Technology Islamabad
12
Surface crystals were formed. Measurements indicated that about 70% by
mass of the surface crystals were bisphenol A (BPA).
PHOTO-OXIDATION OF
POLYCARBONATE
• UV light, oxidation of this polymer yields compounds such as ketones, phenols,
o-phenoxybenzoic acid, benzyl alcohol and other unsaturated compounds
5/7/2020 10:49:39 AM Capital University of Science and Technology Islamabad 13
Pathway A
(OC6H4)2C(CH3CH2)CO + O2, H* → HO(OC6H4)OCO + CH3COCH2(OC6H4)OCO
Pathway B
(OC6H4)2C(CH3CH2)CO)n + O2, H* → OCO(OC6H4)CH2OH + OCO(OC6H4)COCH3
THERMAL DEGRADATION
• About 40–50% liquid, 14–16% gases, while 34–43% remained as solid
residue
• Geotrichum candidum, was found to consume the polycarbonate found in
compact discs (CD)
5/7/2020 10:49:39 AMCapital University of Science and Technology Islamabad
14
COMPOSITION OF PLASTIC
GLOVES
• Each of these categories has multiple subcategories with distinct requirements.
gloves can be made from materials including nylon, ethylene vinyl acetate
(EVA), polyethylene (PE), polypropylene (PP), and polyolefin
5/7/2020 10:49:39 AM Capital University of Science and Technology Islamabad 15
DEGRADATION FOR PVC GLOVES
• Thermal and photo degradation of PVC
• Biodegradation by white rot fungi
5/7/2020 10:49:39 AMCapital University of Science and Technology Islamabad
16
ALTERNATIVE TO GLOVES
• Latex Gloves
• Vinyl Golves
• Nitrile Gloves
5/7/2020 10:49:39 AM Capital University of Science and Technology Islamabad 17
DEGRADATION FOR LATEX GLOVES
• Degradation of polymer in the presence of UV light
5/7/2020 10:49:39 AMCapital University of Science and Technology Islamabad
18
• Ozonolysis method showed better reaction
• Sonochemical method using ultrasonic
waves
REFERENCES
• Alshehrei, F. (2017). Biodegradation of Synthetic and Natural Plastic by Microorganisms, 5(1),
8–19. https://doi.org/10.12691/jaem-5-1-2
• Bharadwaj, A., Yadav, D., & Varshney, S. (2015). Non-Biodegradable Waste – Its Impact &
Safe Disposal. International Journal of Advanced Technology in Engineering and Science, 3,
184–191. https://doi.org/10.1016/j.ijrobp.2013.06.1524
• Ibrahim, S., Board, M. R., Othman, N., & Ismail, H. (2016). Degradation of natural rubber
latex, (January).
• Kaseem, M., Hamad, K., & Deri, F. (2012). Thermoplastic Starch Blends : A Review of Recent
Works 1, 54(2), 165–176. https://doi.org/10.1134/S0965545X1202006X
• Technologies, L. (n.d.). Leader in syringe technologies.
5/7/2020 10:49:39 AM Capital University of Science and Technology Islamabad 19
THANK YOU 
5/7/2020 10:49:39 AMCapital University of Science and Technology Islamabad
20

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Project ppt bioremediation

  • 1. Rimsha FarooqSyeda Rehab Gillani BBS153009BBS153012 Presented to : Dr. Arshia AminButt
  • 2. CONTENTS 5/7/2020 10:49:39 AM Capital University of Science and Technology Islamabad 2 Introduction Composition of Syringes Radiation effect on Syringes Natural Bio gradation of commonly used Syringes TPSPP Blends Alternatives of Syringes Degradation of Syringes Gloves Chemical composition and DEgradation
  • 3. INTRODUCTION 5/7/2020 10:49:39 AMCapital University of Science and Technology Islamabad 3 (1)Domestic wastes (2)Hazardous wastes (3)Infectious wastes
  • 4. 5/7/2020 10:49:39 AM Capital University of Science and Technology Islamabad 4 • Syringe plunger, barrel and cap are made of polypropylene (PP) or polyethylene (PE) plastic materials. These materials must be at medical grade because of their medical use.
  • 5. RADIATION EFFECTS ON SYRINGES 25-40 k gy radiation doses, some changes can occur on the plastic syringe materials 5/7/2020 10:49:39 AMCapital University of Science and Technology Islamabad 5 While cross-linking occurs in PE plastic material, PP is sensitive to discoloration Melting and crystallization behavior of PP syringes, they applied DSC and obtained the melting temperature and fusion enthalpy
  • 6. NATURAL BIODEGRADATION OF COMMONLY USED SYRINGES If the syringe is made of polyethylene (PE) If syringe is made of polypropylene (PP) 5/7/2020 10:49:39 AM Capital University of Science and Technology Islamabad 6
  • 7. POLYETHYLENE(PE) 5/7/2020 10:49:39 AMCapital University of Science and Technology Islamabad 7
  • 8. POLYPROPYLENE(PP) 5/7/2020 10:49:39 AM Capital University of Science and Technology Islamabad 8
  • 9. TPSPP BLENDS • Pseudo plastic and exhibited shear-thinning behavior, where the viscosity decreased with increasing shear rate 5/7/2020 10:49:39 AMCapital University of Science and Technology Islamabad 9 • The flow behavior of the blends is more sensitive to temperature compared with PP
  • 10. TPSPE BLENDS 5/7/2020 10:49:39 AMCapital University of Science and Technology Islamabad 10
  • 11. ALTERNATIVE OF PEPP SYRINGES 5/7/2020 10:49:39 AM Capital University of Science and Technology Islamabad 11
  • 12. BIODEGRADATION OF POLYCARBONATE • − (−OC6H4)2C (CH3)2CO−) −n + H2O → (CH3)2C (C6H4OH)2 + CO2 5/7/2020 10:49:39 AMCapital University of Science and Technology Islamabad 12 Surface crystals were formed. Measurements indicated that about 70% by mass of the surface crystals were bisphenol A (BPA).
  • 13. PHOTO-OXIDATION OF POLYCARBONATE • UV light, oxidation of this polymer yields compounds such as ketones, phenols, o-phenoxybenzoic acid, benzyl alcohol and other unsaturated compounds 5/7/2020 10:49:39 AM Capital University of Science and Technology Islamabad 13 Pathway A (OC6H4)2C(CH3CH2)CO + O2, H* → HO(OC6H4)OCO + CH3COCH2(OC6H4)OCO Pathway B (OC6H4)2C(CH3CH2)CO)n + O2, H* → OCO(OC6H4)CH2OH + OCO(OC6H4)COCH3
  • 14. THERMAL DEGRADATION • About 40–50% liquid, 14–16% gases, while 34–43% remained as solid residue • Geotrichum candidum, was found to consume the polycarbonate found in compact discs (CD) 5/7/2020 10:49:39 AMCapital University of Science and Technology Islamabad 14
  • 15. COMPOSITION OF PLASTIC GLOVES • Each of these categories has multiple subcategories with distinct requirements. gloves can be made from materials including nylon, ethylene vinyl acetate (EVA), polyethylene (PE), polypropylene (PP), and polyolefin 5/7/2020 10:49:39 AM Capital University of Science and Technology Islamabad 15
  • 16. DEGRADATION FOR PVC GLOVES • Thermal and photo degradation of PVC • Biodegradation by white rot fungi 5/7/2020 10:49:39 AMCapital University of Science and Technology Islamabad 16
  • 17. ALTERNATIVE TO GLOVES • Latex Gloves • Vinyl Golves • Nitrile Gloves 5/7/2020 10:49:39 AM Capital University of Science and Technology Islamabad 17
  • 18. DEGRADATION FOR LATEX GLOVES • Degradation of polymer in the presence of UV light 5/7/2020 10:49:39 AMCapital University of Science and Technology Islamabad 18 • Ozonolysis method showed better reaction • Sonochemical method using ultrasonic waves
  • 19. REFERENCES • Alshehrei, F. (2017). Biodegradation of Synthetic and Natural Plastic by Microorganisms, 5(1), 8–19. https://doi.org/10.12691/jaem-5-1-2 • Bharadwaj, A., Yadav, D., & Varshney, S. (2015). Non-Biodegradable Waste – Its Impact & Safe Disposal. International Journal of Advanced Technology in Engineering and Science, 3, 184–191. https://doi.org/10.1016/j.ijrobp.2013.06.1524 • Ibrahim, S., Board, M. R., Othman, N., & Ismail, H. (2016). Degradation of natural rubber latex, (January). • Kaseem, M., Hamad, K., & Deri, F. (2012). Thermoplastic Starch Blends : A Review of Recent Works 1, 54(2), 165–176. https://doi.org/10.1134/S0965545X1202006X • Technologies, L. (n.d.). Leader in syringe technologies. 5/7/2020 10:49:39 AM Capital University of Science and Technology Islamabad 19
  • 20. THANK YOU  5/7/2020 10:49:39 AMCapital University of Science and Technology Islamabad 20