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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 05 Issue: 04 | Apr-2018 www.irjet.net p-ISSN: 2395-0072
© 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 406
Eco-Friendly concrete by partial replacement of cement with Sodium
Bentonite and FlyAsh
Roobankumar R1, Niyas Ali A2, Shahul Hameed.D.K.S3, Shankar Raj B4, Syed Ayub Z5.
1 Assistant Professor,Department of Civil Engineering, Dhaanish Ahmed College of Engineering, Chennai, India
2,3,4,5 Department of Civil Engineering, Dhaanish Ahmed College of Engineering, Chennai, India
---------------------------------------------------------------------***---------------------------------------------------------------------
Abstract - The main objective of the project is to find out
the effectiveness of fly ash and Sodium bentonite collectively
on the concrete strength. In this work it was proposed thatthe
cement is partially replaced in the ratio of 40%ofcementwith
partial replacement of (35% Fly ash and 5% Sodium
bentonite, 30% of Fly ash and 10% of Sodium Bentonite, 25%
Fly ash and 15% Sodium Bentonite) and recycled materials
respectively. For investigating the potential use of Sodium
bentonite and fly ash in cement concrete by replacing
Ordinary Portland cement (OPC) and evaluate the strength
and impact of these materials of concrete. Many of the
developing countries are replacing the materials with the
materials which are recycled so as to minimize the
environmental hazards and safe guarding the natural
resources. Cubes and cylinders were casted with M30 design
mix and compressive, split tensile strength were studied for 7,
14, 28 days and compared with conventional concrete based
on the test results, the various strengths were identified.
Key Words: Fly Ash, Sodium Bentonite, Tensile Strength,
Compressive Strength
1. INTRODUCTION
The protection of environment became a challenge to many
of the developing countries, nearly 7% of CO2 production by
cement industry, causes huge damage to the environment.
Bentonite is second largest available raw material; the
production cost of the bentonite is very less compared with
Ordinary Portland Cement (OPC) in India. Calciumbentonite
is expensive and it has the capacitytoincreasethevolumeby
addition of water. For investigating the potential use of
Calcium bentonite and fly ash in cement concrete by
replacing. Many of thedevelopingcountriesare replacingthe
materials with the materials which are recycled so as to
minimize the environmental hazards and safe guarding the
natural resources. Fly ash is the notorious waste product of
coal based on electricity generating thermal power plants
known for its effect on agricultural land, surface and
subsurface water pollution, soil and earth pollution. Theuse
of Fly ash in concrete contributes in the reduction of
greenhouse emission with negative impact on the economy.
It has been observed that 0.9 tons of co2 is produced per ton
of cement production. To improve the environment
friendliness of concrete to make it suitable as a “Green
building” material. Inorganic residual productareused more
efficiency as green aggregates in concrete and the
environment is protected from waste deposit. The cement is
replaced with material and mineral admixture will improve
the strength and durability of concrete. However, people act
less alqutruistically and are more likely to cheat and steal
after purchasing green product then after purchasing
conventional product, Environmentally friendly also eco
friendly, natural friendly[8]. Most of the concrete
considering from every aspect of raw material manufacture
to structural design, construction. Instead, consumption of
products which is causing harmful impacts on the
environment is gaining further momentum. Such a
phenomenon is detrimental to environmental sustainability
and therefore requires immediate attention and corrective
action.
MATERIALS
Cement used in this experimental work is of 53
grade of Ordinary Portland Cement (OPC), Specific Gravity –
3.12, Standard Consistency – 32, Initial Setting Time – 30
minutes, Final Setting time – 320 minutes are within the
limit as per IS 10262-2001. The golden colored, finest form
of Sodium Bentonite was purchased from the metro rail
project work in Ennore, Chennai. Fly Ash, Class C was
purchased from Ennore power house anditsSpecificGravity
is 2.6. The Coarse Aggregate of 20mm size, angular shape is
used and its specific gravity is 2.75. The Fine Aggregate
which is used has the specific gravity of 2.52. Normal tap
water is used for the concrete mix.
MIX DESIGN OF CONCRETE
The mix design was done from recommended IS: 10262-
1982. The concrete mix proportion was 1:1.62:2.95 by
weight. The percentage of materials used based mix
proportion is tabulated in the below table2.
Table -1: Chemical properties of Ordinary Portland
Cement.
S.NO CHEMICAL PROPERTIES PERCENTAGE
1 Tricalcium silicate CaO.SiO2 (C3S) 3%
2
Dicalcium silicate 2CaO.SiO2 (C2S) 40%
3 Tricalcium aluminate 3CaO.Al2O3 (C3A) 11%
4 Tetracalcium aluminate
4CaO.Al2O3.Fe2O3
11%
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 05 Issue: 04 | Apr-2018 www.irjet.net p-ISSN: 2395-0072
© 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 407
Table -2: Mix Proportions in Kg
MIX
PERCENTAGE
W/C
RATIO
CEMENT FLY
ASH
SODIUM
BENTONITE
FINE
AGGREGATE
35% Fly ash 5%
bentonite
0.45 6 3.5 0.5 10.5
30% Fly Ash 10%
bentonite
0.45 6 3 1 10.5
25% Fly Ash 15%
bentonite
0.45 6 2.5 1.5 10.5
Table -3 Compressive strength of concrete
PERCENTAGE 7 DAYS 14 DAYS 28 DAYS
35% Fly ash
5% bentonite
12 15.55 18.88
30% Fly ash
10% bentonite
12.44 16 17.77
25% Fly ash
15% bentonite
12 17.77 21.12
The above table shows, if using 25% fly ash and 15%
bentonite the compressive strength of concrete is 21.12
N/mm2.
Chart -1: Compressive Strength of concrete
Table -4 Split Tensile Strength of Concrete
PERCENTAGE 7 DAYS 14 DAYS 28 DAYS
35% Fly ash
5% bentonite
2.22 1.75 2.16
30% Fly ash
10% bentonite
2 2.38 1.59
25% Fly ash
15% bentonite
1.59 2.32 2.61
The more tensile strength of concrete is 2.61 N/mm2 if using
25% of fly ash and 15% of bentonite than 25% of fly ash &
10% of bentonite.
Chart -2: Split Tensile Strength of concrete
Fig 1 Compressive Strength Test
3. CONCLUSIONS
Based on higher than study the subsequent observationsare
created on partial cement replacementbyflyashandsodium
bentonite. In which many test performed to ascertain the
performance of flyash and sodium bentonite. Fullfilling the
condition of partial cementreplacement materialswegot the
result for different percentage of material.
For Compressive Strength, For different percentage of 35%
Fly ash 5% Sodium bentonite, 30% Fly ash 10% Sodium
bentonite, 25% Fly ash 15% Sodium bentonite we got 28
days result of 18.88 N/mm2, 17.77 N/mm2, 21.12 N/mm2.
For Tensile strength, For different percentrage of 35% Fly
ash 5% Sdium bentonite, 30% Fly ash 10% Sodium
bentonite, 25% Fly ash 15% Sodium bentonite we got 28
days result of 2.16N/mm2, 1.59 N/mm2, 2.61N/mm2.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 05 Issue: 04 | Apr-2018 www.irjet.net p-ISSN: 2395-0072
© 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 408
Overall that, it is preferred to use the percentage of 25% Fly
Ash and 15%Sodium Bentonite for the concrete of partial
replacement of cememt.
ACKNOWLEDGEMENT
Authors thank Dhaanish Ahmed College of Engineering,
Chennai, India for the support to conduct the research work
REFERENCES
[1] Indian mineral handbook.Part-III:mineral reviews,52ed
edition, Bentonite, Government of India, Ministry of mines,
Indian bureau of mines, 2013.
[2] International Journal ofCivil EngineeringandTechnology
(IJCIET) Volume 8, Issue 1, January 2017.
[3] International Journal ofCivil EngineeringandTechnology
(IJCIET) Volume 8, Issue 4, April 2017,
[4]Suman et al, International Journal of Advanced
Engineering Research and Studies, FLY ASH CONCRETE: A
TECHNICAL ANALYSIS FOR COMPRESSIVE STRNGTH,
IJAERS/Vol. II/ Issue I/ Oct – Dec, 2012/ 128-129.
[5]IMPACT: International Journals of Research in
Engineering and Technology(IMPACT:IJRET)ISSN(E):2321-
8843: ISSN(P):2347-4599 Vol. 2, Issue2,Feb2014,259-264.
[6]International Journal of Research in Advent Technology
(E-ISSN: 2321:9637) Special Issue, National Conference,
“Vishwacon’16”,19 March 2016.
[7]ARPN Journals of engineering and Applied Science, SSN
1819-6608, Vol 11, No 5, March 2015.
[8]CBS E- journals, bez n bytes, vol. 6, Dec.,2010 ISSN 0976-
0458
[9]IIMT College of Engineering, Greater Noida,
India(ICETETSM-17) ISBN: 978-93-86171-38-2, 12th April
2017.
[10]Contemporary Management Research Pages 35-46,
Vol.9, No. 1, March 2013 doi:10.7903cmr, 10209.
[11]Karthikeyan M, Raja R P, Nandhini A, Vinodha R.
Application on partial substitute of cement by bentonite in
cement concrete. International Journal Of ChemTech and
Research.
[12]Junaid Akbar, Bashir A, Mahummas S, Salman A, Khan S.
Evaluating the effect of bentonite on strength and durability
of High-performance concrete. International Journal of
Advanced Structures And Geotechnical Engineering. 2013
January; 2(1), 1-5.
[13]Kaci A, Chaouchi M, Andreani P A. Influence ofbentonite
clay on the rheological behavior of fresh mortars. Cement
And Concrete Research. 2011; 41, 373-379.
[14]Lima G D, Mello I, Resnde R, Silva R. Use ofbentonite and
organobentonite as alteratives of partial substitution of
cement in concrete manufacturing. International Journal of
Concrete Structures and materials 2014 March; 8(1), 15-26.
[15]Rafat Siddique. Utilization of industrial by-products in
concrete. 2nd International conference on sustainable civil
engineering structures and constructionmaterials.Procedia
Engineering. 2014; 95, 335 - 347.

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  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 04 | Apr-2018 www.irjet.net p-ISSN: 2395-0072 © 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 406 Eco-Friendly concrete by partial replacement of cement with Sodium Bentonite and FlyAsh Roobankumar R1, Niyas Ali A2, Shahul Hameed.D.K.S3, Shankar Raj B4, Syed Ayub Z5. 1 Assistant Professor,Department of Civil Engineering, Dhaanish Ahmed College of Engineering, Chennai, India 2,3,4,5 Department of Civil Engineering, Dhaanish Ahmed College of Engineering, Chennai, India ---------------------------------------------------------------------***--------------------------------------------------------------------- Abstract - The main objective of the project is to find out the effectiveness of fly ash and Sodium bentonite collectively on the concrete strength. In this work it was proposed thatthe cement is partially replaced in the ratio of 40%ofcementwith partial replacement of (35% Fly ash and 5% Sodium bentonite, 30% of Fly ash and 10% of Sodium Bentonite, 25% Fly ash and 15% Sodium Bentonite) and recycled materials respectively. For investigating the potential use of Sodium bentonite and fly ash in cement concrete by replacing Ordinary Portland cement (OPC) and evaluate the strength and impact of these materials of concrete. Many of the developing countries are replacing the materials with the materials which are recycled so as to minimize the environmental hazards and safe guarding the natural resources. Cubes and cylinders were casted with M30 design mix and compressive, split tensile strength were studied for 7, 14, 28 days and compared with conventional concrete based on the test results, the various strengths were identified. Key Words: Fly Ash, Sodium Bentonite, Tensile Strength, Compressive Strength 1. INTRODUCTION The protection of environment became a challenge to many of the developing countries, nearly 7% of CO2 production by cement industry, causes huge damage to the environment. Bentonite is second largest available raw material; the production cost of the bentonite is very less compared with Ordinary Portland Cement (OPC) in India. Calciumbentonite is expensive and it has the capacitytoincreasethevolumeby addition of water. For investigating the potential use of Calcium bentonite and fly ash in cement concrete by replacing. Many of thedevelopingcountriesare replacingthe materials with the materials which are recycled so as to minimize the environmental hazards and safe guarding the natural resources. Fly ash is the notorious waste product of coal based on electricity generating thermal power plants known for its effect on agricultural land, surface and subsurface water pollution, soil and earth pollution. Theuse of Fly ash in concrete contributes in the reduction of greenhouse emission with negative impact on the economy. It has been observed that 0.9 tons of co2 is produced per ton of cement production. To improve the environment friendliness of concrete to make it suitable as a “Green building” material. Inorganic residual productareused more efficiency as green aggregates in concrete and the environment is protected from waste deposit. The cement is replaced with material and mineral admixture will improve the strength and durability of concrete. However, people act less alqutruistically and are more likely to cheat and steal after purchasing green product then after purchasing conventional product, Environmentally friendly also eco friendly, natural friendly[8]. Most of the concrete considering from every aspect of raw material manufacture to structural design, construction. Instead, consumption of products which is causing harmful impacts on the environment is gaining further momentum. Such a phenomenon is detrimental to environmental sustainability and therefore requires immediate attention and corrective action. MATERIALS Cement used in this experimental work is of 53 grade of Ordinary Portland Cement (OPC), Specific Gravity – 3.12, Standard Consistency – 32, Initial Setting Time – 30 minutes, Final Setting time – 320 minutes are within the limit as per IS 10262-2001. The golden colored, finest form of Sodium Bentonite was purchased from the metro rail project work in Ennore, Chennai. Fly Ash, Class C was purchased from Ennore power house anditsSpecificGravity is 2.6. The Coarse Aggregate of 20mm size, angular shape is used and its specific gravity is 2.75. The Fine Aggregate which is used has the specific gravity of 2.52. Normal tap water is used for the concrete mix. MIX DESIGN OF CONCRETE The mix design was done from recommended IS: 10262- 1982. The concrete mix proportion was 1:1.62:2.95 by weight. The percentage of materials used based mix proportion is tabulated in the below table2. Table -1: Chemical properties of Ordinary Portland Cement. S.NO CHEMICAL PROPERTIES PERCENTAGE 1 Tricalcium silicate CaO.SiO2 (C3S) 3% 2 Dicalcium silicate 2CaO.SiO2 (C2S) 40% 3 Tricalcium aluminate 3CaO.Al2O3 (C3A) 11% 4 Tetracalcium aluminate 4CaO.Al2O3.Fe2O3 11%
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 04 | Apr-2018 www.irjet.net p-ISSN: 2395-0072 © 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 407 Table -2: Mix Proportions in Kg MIX PERCENTAGE W/C RATIO CEMENT FLY ASH SODIUM BENTONITE FINE AGGREGATE 35% Fly ash 5% bentonite 0.45 6 3.5 0.5 10.5 30% Fly Ash 10% bentonite 0.45 6 3 1 10.5 25% Fly Ash 15% bentonite 0.45 6 2.5 1.5 10.5 Table -3 Compressive strength of concrete PERCENTAGE 7 DAYS 14 DAYS 28 DAYS 35% Fly ash 5% bentonite 12 15.55 18.88 30% Fly ash 10% bentonite 12.44 16 17.77 25% Fly ash 15% bentonite 12 17.77 21.12 The above table shows, if using 25% fly ash and 15% bentonite the compressive strength of concrete is 21.12 N/mm2. Chart -1: Compressive Strength of concrete Table -4 Split Tensile Strength of Concrete PERCENTAGE 7 DAYS 14 DAYS 28 DAYS 35% Fly ash 5% bentonite 2.22 1.75 2.16 30% Fly ash 10% bentonite 2 2.38 1.59 25% Fly ash 15% bentonite 1.59 2.32 2.61 The more tensile strength of concrete is 2.61 N/mm2 if using 25% of fly ash and 15% of bentonite than 25% of fly ash & 10% of bentonite. Chart -2: Split Tensile Strength of concrete Fig 1 Compressive Strength Test 3. CONCLUSIONS Based on higher than study the subsequent observationsare created on partial cement replacementbyflyashandsodium bentonite. In which many test performed to ascertain the performance of flyash and sodium bentonite. Fullfilling the condition of partial cementreplacement materialswegot the result for different percentage of material. For Compressive Strength, For different percentage of 35% Fly ash 5% Sodium bentonite, 30% Fly ash 10% Sodium bentonite, 25% Fly ash 15% Sodium bentonite we got 28 days result of 18.88 N/mm2, 17.77 N/mm2, 21.12 N/mm2. For Tensile strength, For different percentrage of 35% Fly ash 5% Sdium bentonite, 30% Fly ash 10% Sodium bentonite, 25% Fly ash 15% Sodium bentonite we got 28 days result of 2.16N/mm2, 1.59 N/mm2, 2.61N/mm2.
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 04 | Apr-2018 www.irjet.net p-ISSN: 2395-0072 © 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 408 Overall that, it is preferred to use the percentage of 25% Fly Ash and 15%Sodium Bentonite for the concrete of partial replacement of cememt. ACKNOWLEDGEMENT Authors thank Dhaanish Ahmed College of Engineering, Chennai, India for the support to conduct the research work REFERENCES [1] Indian mineral handbook.Part-III:mineral reviews,52ed edition, Bentonite, Government of India, Ministry of mines, Indian bureau of mines, 2013. [2] International Journal ofCivil EngineeringandTechnology (IJCIET) Volume 8, Issue 1, January 2017. [3] International Journal ofCivil EngineeringandTechnology (IJCIET) Volume 8, Issue 4, April 2017, [4]Suman et al, International Journal of Advanced Engineering Research and Studies, FLY ASH CONCRETE: A TECHNICAL ANALYSIS FOR COMPRESSIVE STRNGTH, IJAERS/Vol. II/ Issue I/ Oct – Dec, 2012/ 128-129. [5]IMPACT: International Journals of Research in Engineering and Technology(IMPACT:IJRET)ISSN(E):2321- 8843: ISSN(P):2347-4599 Vol. 2, Issue2,Feb2014,259-264. [6]International Journal of Research in Advent Technology (E-ISSN: 2321:9637) Special Issue, National Conference, “Vishwacon’16”,19 March 2016. [7]ARPN Journals of engineering and Applied Science, SSN 1819-6608, Vol 11, No 5, March 2015. [8]CBS E- journals, bez n bytes, vol. 6, Dec.,2010 ISSN 0976- 0458 [9]IIMT College of Engineering, Greater Noida, India(ICETETSM-17) ISBN: 978-93-86171-38-2, 12th April 2017. [10]Contemporary Management Research Pages 35-46, Vol.9, No. 1, March 2013 doi:10.7903cmr, 10209. [11]Karthikeyan M, Raja R P, Nandhini A, Vinodha R. Application on partial substitute of cement by bentonite in cement concrete. International Journal Of ChemTech and Research. [12]Junaid Akbar, Bashir A, Mahummas S, Salman A, Khan S. Evaluating the effect of bentonite on strength and durability of High-performance concrete. International Journal of Advanced Structures And Geotechnical Engineering. 2013 January; 2(1), 1-5. [13]Kaci A, Chaouchi M, Andreani P A. Influence ofbentonite clay on the rheological behavior of fresh mortars. Cement And Concrete Research. 2011; 41, 373-379. [14]Lima G D, Mello I, Resnde R, Silva R. Use ofbentonite and organobentonite as alteratives of partial substitution of cement in concrete manufacturing. International Journal of Concrete Structures and materials 2014 March; 8(1), 15-26. [15]Rafat Siddique. Utilization of industrial by-products in concrete. 2nd International conference on sustainable civil engineering structures and constructionmaterials.Procedia Engineering. 2014; 95, 335 - 347.