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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056
Volume: 04 Issue: 06 | June -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 2067
Effect of Partial Replacement of Cement by Fly Ash and Metakaolin on
Concrete Strength with M. Sand as Fine Aggregate
Rajendra T N1 ,Surendra . B.V2,
1 Assistant Professor, Department of Civil Engineering
New Horizon college of Engineering, Bengaluru, Karnataka, India 560103
2Associate Professor, Department of Civil Engineering
New Horizon college of Engineering, Bengaluru, Karnataka, India 560103
---------------------------------------------------------------------***---------------------------------------------------------------------
Abstract – Due to rapid, worldwide growth in
construction, there is a tremendous increase in usage of
concrete that has resulted in heavy production of cement
and scarcity of river sand. Production of cement leads to
environmental pollution due to emission of carbon dioxide
(Co2). Extraction of river sand results into lowering of the
water head affecting ground water level. It also leads to
erosion of nearby land. The aim of the present investigation
is to study the variation in compressive strength and split
tensile strength properties by replacing cement partially
with fly ash and metakaolin and by using M.Sand in place of
river sand. The Experimental study consisting of the
concrete specimen containing cement 15% with metakalin
and fly ash at 5%, 10%, 15% and 20% and using M.Sand as
fine aggregates has been carried out. The results indicated
that there was an improvement in the strength properties.
Key Words: Cement concrete, Metakaolin, Fly ash, M.Sand
Compressive Strength, Split tensile strength.
1. INTRODUCTION
The demand for concrete is next only towater. With
the advancement of technology and increased field of
application of concrete and mortars, various properties of
the ordinary concrete needed modification to make it more
suitable for various situations, economical and eco friendly.
This has led to the use of cementitious materials
such as fly ash, silica fume, metakaolin etc. which have
contributed towards higher performance, energy
conservation and economy.
The use of fly ash and metakaolinpartiallyreplacing
the cement in concrete results in reduction of cement used,
reduction in the emission of carbon dioxide (Co2),
conservation of existing resources along with the
enhancement in the strength and durability properties of
concrete.
Depletion of natural sand deposits in our country is
already causing serious threat to the environment as well as
society. This along with shortage in natural good quality
sand has made researchers to look for an alternative to river
sand. The M.sand produced under controlled and well
supervised conditions can a better substitute for river sand.
In use of fly ash for partially replacing the Portland cement
in concrete not only reduces the amount of cement used, but
also significantly enhances the properties of concrete,
reduces the emission of CO2, conserves the existing
resources and greatlyimprovesconsistency[3].Theaddition
of fly ash in concrete improves certain properties such as
workability, later age strength development and a few
durability characteristics [3].
Blending metakaolin with Portland cement
improves the properties of concrete by increasing
compressive and flexural strength, providing resistance to
chemical attack, reducing permeability substantially
preventing alkali silica reaction, reducing efflorescence and
shrinkage preventing corrosion of steel [1].
2.1. Materials
2.1.1 Cement: OPC 43- grade confirming to Indian
Standards is used in the present study and the test is
conducted to determine specific gravity. The results have
been tabulated in table2.1.
2.1.2 Fine aggregates: River sand with fineness modulus
3.1 conforming to zone II was used for the experimental
study and specific gravity is determined. The results have
been tabulated in table 1.
2.1.3 Coarse aggregates: Crushed granite with fineness
modulus 7.1 having size between 20 mm and 4.75 mm was
used for the experimental study and the tests were
conducted to evaluate specific gravity.Theresultshavebeen
tabulated in table 2. 1.
2.1.4 Water: Drinking water was used for the experimental
study
2.1.5 Fly ash: The specific gravity of fly ash was evaluated
for the experimental study. The results have been tabulated
in table 1.
2.1.6 Metakaolin: The specific gravity of metakaolin was
evaluated for the experimental study. The results have been
tabulated in table 2.1.
2. MATERIALS AND METHODS
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056
Volume: 04 Issue: 06 | June -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 2068
Table 2.1: Significant properties of materials used
Materials Specific gravity
Cement 3.12
Fine aggregates 2.62
Coarse aggregates 2.68
Fly ash 2.23
Metakaolin 2.4
Table 2.2: Mineral Composition of metakaolin
Major Minerals Percentage
Lime (Cao) 1.2
Silica (SiO2) 51.92
Alumina (Al2O3) 42.0
Iron oxide (Fe2O3) 0.93
Magnesium oxide (MgO) 0.06
Sodium oxide (Na2O) 0.04
2.2 Mix Proportion
For the present study M40 grade of concrete was used. The
mix proportion was evaluated confirming to the IS 10262-
2009. The variousmixproportionsforconventional concrete
(Control specimen) and fly ash based metakaolin concrete
(by partially replacing OPC with fly ash and metakaolin) are
presented in Table2.3.
Table 2.3: M40 Mix proportion
MixProportion
Cementcontent
(Kg/m3)
Metakaolin(MK)
(Kg/m3)
Flyash(Kg/m3)
F.A(Kg/m3)
C.A(Kg/m3)
W/C
Control
specimen
492 ……. ……. 673 108
0
0.4
MK 5% Fly
ash 15%
393.
6
73.8 24.6 673 108
0
0.4
MK 10% Fly
ash 15%
369 73.8 49.2 673 108
0
0.4
MK 15% Fly
ash 15%
344.
4
73.8 73.8 673 1080 0.4
MK 20% Fly
ash 15%
319.
8
73.8 98.4 673 1080 0.4
3. Experimental Program
3.1 Specimen
The experimental program consistedofcastingand
testing of M40 grade concrete specimens of cube (150 mm)
and cylinder (150 X 300 mm).
3.2 Compressive strength
Nine numbers of cubes were cast for each mix and
tested using 200T capacity Compression Testing Machine
(CTM).
3.3 Split Tensile strength
Nine numbers of cylinders were cast and tested
using 200T capacity Compression Testing Machine (CTM).
4. Results and discussions
4.1 Compressive strength:
The compressive strength was determined after normal
curing for 3days, 7 days and 28 days. The results are
presented in Table 4.1 and are also depicted graphically in
figure 4.1.
Table 4.1 Compressive Strength Test results
specifications
Compressive strength
(N/mm2)
3 days 7
days
28 days
Control
specimen
18.5 29 44.5
Fly ash 5% MK
15%
20 32 47
Fly ash 10% MK
15%
22 35 53
Fly ash 15% MK
15%
27 39 61
Fly ash 15% MK
20%
29 45 66
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056
Volume: 04 Issue: 06 | June -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 2069
Fig. 4.1 Compressive strength test results
4.2 Split Tensile strength
The split tensile strength was determined after
normal curing for 28 days. TheresultsarepresentedinTable
4.2.
Table 4.2 Split tensile test results
Specifications
Split Tensile
Strength (N/mm2)
Control specimen
2.61
MK 5% Fly ash 15%
2.78
MK 10% Fly ash
15%
3.18
MK 15% Fly ash
15%
3.65
MK 20% Fly ash
15%
3.87
The results indicate that there is a substantial
increase in the compressive strength with the increase in %
of Metakaolin replacing cement.
5. Conclusions
The present study led to the following conclusions.
1. Addition of Metakaolin and flyash has resulted in
enhanced early strength and ultimate strength of
concrete.
2. The reduction in the Emission of green gases is a
major benefitfromenvironmentsustainabilitypoint
of view.
3. the cost reduction can be achieved due to the easy
availability of metakaolin and fly ash.
REFERENCES
1. Mohammad Azhar, Mohammed MoshinAliQureshi,
“Strength Development in Concrete by
Incorporating Metakaolin” International Journal of
Advanced Trends in Computer Science and
Engineeering, -2013,Vol.2, pp 634-639.
2. Nova John, “ Strength Properties of Metakaolin
Admixed Concrete” IJSRP, volume 3, Issue 6.
3. M. Nazeer, R. Arun Kumar, “Strength Studies on
Metakaolin Blended High-Volume Fly Ash
Concrete”, IJEAT-August 2014 Vol. 3, pp-176-179.
4. Murali.G., Sruthee P., “Experimental study of
concrete with Metakaolin as Partial replacement of
cement”, International Journal of Emerging trends
in Engineering and development,Issue2,Vol.4,May
2012, ISSN 2249-6149.
5. Vikas Srivastava., Rakesh Kumar., Agarwal V.C.,
“Metakaolin inclusion: Effect on mechanical
properties of concrete”, J. Acad.Indus.Res.Vol.1(5),
pp. 251-253, October 2012, ISSN: 2278-5213.
6. IS 10262:2009 Concrete Mix Proportioning
Guidelines - Code of Practice, Bureau of Indian
Standard, New Delhi 110002.
7. IS 456:2000 Indian Standard, Plain and Reinforced
Concrete - Code of Practice, Bureau of Indian
Standard, New Delhi 110002.
8. Sabir B.B, Wild S, Bai J, “Metakaolin and calcined
clay as pozzolans for concrete :a review” Cement
and concrete composite 23, (2001),pp.441-454.
9. Jiping Bai, Albinas Gailius “Consistency of fly ash
and metakaolin concrete” journal of civil
engineeringandmanagement15(2):(2009),pp.131–
135.
10. Pacheco Torgal F, Arman Shasavandi, Said Jalali
“Using metakaolin to improve the compressive
strength and the durability of fly ash based
concrete” Invaco2: International seminar,
innovation & valorization in civil engineering &
construction materials,Rabat-Morocco, 23-25
November( 2011), ISBN 987-9954-30-595-9.

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Effect of Partial Replacement of Cement by Fly Ash and Metakaolin on Concrete Strength With M. Sand As Fine Aggregate

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 04 Issue: 06 | June -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 2067 Effect of Partial Replacement of Cement by Fly Ash and Metakaolin on Concrete Strength with M. Sand as Fine Aggregate Rajendra T N1 ,Surendra . B.V2, 1 Assistant Professor, Department of Civil Engineering New Horizon college of Engineering, Bengaluru, Karnataka, India 560103 2Associate Professor, Department of Civil Engineering New Horizon college of Engineering, Bengaluru, Karnataka, India 560103 ---------------------------------------------------------------------***--------------------------------------------------------------------- Abstract – Due to rapid, worldwide growth in construction, there is a tremendous increase in usage of concrete that has resulted in heavy production of cement and scarcity of river sand. Production of cement leads to environmental pollution due to emission of carbon dioxide (Co2). Extraction of river sand results into lowering of the water head affecting ground water level. It also leads to erosion of nearby land. The aim of the present investigation is to study the variation in compressive strength and split tensile strength properties by replacing cement partially with fly ash and metakaolin and by using M.Sand in place of river sand. The Experimental study consisting of the concrete specimen containing cement 15% with metakalin and fly ash at 5%, 10%, 15% and 20% and using M.Sand as fine aggregates has been carried out. The results indicated that there was an improvement in the strength properties. Key Words: Cement concrete, Metakaolin, Fly ash, M.Sand Compressive Strength, Split tensile strength. 1. INTRODUCTION The demand for concrete is next only towater. With the advancement of technology and increased field of application of concrete and mortars, various properties of the ordinary concrete needed modification to make it more suitable for various situations, economical and eco friendly. This has led to the use of cementitious materials such as fly ash, silica fume, metakaolin etc. which have contributed towards higher performance, energy conservation and economy. The use of fly ash and metakaolinpartiallyreplacing the cement in concrete results in reduction of cement used, reduction in the emission of carbon dioxide (Co2), conservation of existing resources along with the enhancement in the strength and durability properties of concrete. Depletion of natural sand deposits in our country is already causing serious threat to the environment as well as society. This along with shortage in natural good quality sand has made researchers to look for an alternative to river sand. The M.sand produced under controlled and well supervised conditions can a better substitute for river sand. In use of fly ash for partially replacing the Portland cement in concrete not only reduces the amount of cement used, but also significantly enhances the properties of concrete, reduces the emission of CO2, conserves the existing resources and greatlyimprovesconsistency[3].Theaddition of fly ash in concrete improves certain properties such as workability, later age strength development and a few durability characteristics [3]. Blending metakaolin with Portland cement improves the properties of concrete by increasing compressive and flexural strength, providing resistance to chemical attack, reducing permeability substantially preventing alkali silica reaction, reducing efflorescence and shrinkage preventing corrosion of steel [1]. 2.1. Materials 2.1.1 Cement: OPC 43- grade confirming to Indian Standards is used in the present study and the test is conducted to determine specific gravity. The results have been tabulated in table2.1. 2.1.2 Fine aggregates: River sand with fineness modulus 3.1 conforming to zone II was used for the experimental study and specific gravity is determined. The results have been tabulated in table 1. 2.1.3 Coarse aggregates: Crushed granite with fineness modulus 7.1 having size between 20 mm and 4.75 mm was used for the experimental study and the tests were conducted to evaluate specific gravity.Theresultshavebeen tabulated in table 2. 1. 2.1.4 Water: Drinking water was used for the experimental study 2.1.5 Fly ash: The specific gravity of fly ash was evaluated for the experimental study. The results have been tabulated in table 1. 2.1.6 Metakaolin: The specific gravity of metakaolin was evaluated for the experimental study. The results have been tabulated in table 2.1. 2. MATERIALS AND METHODS
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 04 Issue: 06 | June -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 2068 Table 2.1: Significant properties of materials used Materials Specific gravity Cement 3.12 Fine aggregates 2.62 Coarse aggregates 2.68 Fly ash 2.23 Metakaolin 2.4 Table 2.2: Mineral Composition of metakaolin Major Minerals Percentage Lime (Cao) 1.2 Silica (SiO2) 51.92 Alumina (Al2O3) 42.0 Iron oxide (Fe2O3) 0.93 Magnesium oxide (MgO) 0.06 Sodium oxide (Na2O) 0.04 2.2 Mix Proportion For the present study M40 grade of concrete was used. The mix proportion was evaluated confirming to the IS 10262- 2009. The variousmixproportionsforconventional concrete (Control specimen) and fly ash based metakaolin concrete (by partially replacing OPC with fly ash and metakaolin) are presented in Table2.3. Table 2.3: M40 Mix proportion MixProportion Cementcontent (Kg/m3) Metakaolin(MK) (Kg/m3) Flyash(Kg/m3) F.A(Kg/m3) C.A(Kg/m3) W/C Control specimen 492 ……. ……. 673 108 0 0.4 MK 5% Fly ash 15% 393. 6 73.8 24.6 673 108 0 0.4 MK 10% Fly ash 15% 369 73.8 49.2 673 108 0 0.4 MK 15% Fly ash 15% 344. 4 73.8 73.8 673 1080 0.4 MK 20% Fly ash 15% 319. 8 73.8 98.4 673 1080 0.4 3. Experimental Program 3.1 Specimen The experimental program consistedofcastingand testing of M40 grade concrete specimens of cube (150 mm) and cylinder (150 X 300 mm). 3.2 Compressive strength Nine numbers of cubes were cast for each mix and tested using 200T capacity Compression Testing Machine (CTM). 3.3 Split Tensile strength Nine numbers of cylinders were cast and tested using 200T capacity Compression Testing Machine (CTM). 4. Results and discussions 4.1 Compressive strength: The compressive strength was determined after normal curing for 3days, 7 days and 28 days. The results are presented in Table 4.1 and are also depicted graphically in figure 4.1. Table 4.1 Compressive Strength Test results specifications Compressive strength (N/mm2) 3 days 7 days 28 days Control specimen 18.5 29 44.5 Fly ash 5% MK 15% 20 32 47 Fly ash 10% MK 15% 22 35 53 Fly ash 15% MK 15% 27 39 61 Fly ash 15% MK 20% 29 45 66
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 04 Issue: 06 | June -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 2069 Fig. 4.1 Compressive strength test results 4.2 Split Tensile strength The split tensile strength was determined after normal curing for 28 days. TheresultsarepresentedinTable 4.2. Table 4.2 Split tensile test results Specifications Split Tensile Strength (N/mm2) Control specimen 2.61 MK 5% Fly ash 15% 2.78 MK 10% Fly ash 15% 3.18 MK 15% Fly ash 15% 3.65 MK 20% Fly ash 15% 3.87 The results indicate that there is a substantial increase in the compressive strength with the increase in % of Metakaolin replacing cement. 5. Conclusions The present study led to the following conclusions. 1. Addition of Metakaolin and flyash has resulted in enhanced early strength and ultimate strength of concrete. 2. The reduction in the Emission of green gases is a major benefitfromenvironmentsustainabilitypoint of view. 3. the cost reduction can be achieved due to the easy availability of metakaolin and fly ash. REFERENCES 1. Mohammad Azhar, Mohammed MoshinAliQureshi, “Strength Development in Concrete by Incorporating Metakaolin” International Journal of Advanced Trends in Computer Science and Engineeering, -2013,Vol.2, pp 634-639. 2. Nova John, “ Strength Properties of Metakaolin Admixed Concrete” IJSRP, volume 3, Issue 6. 3. M. Nazeer, R. Arun Kumar, “Strength Studies on Metakaolin Blended High-Volume Fly Ash Concrete”, IJEAT-August 2014 Vol. 3, pp-176-179. 4. Murali.G., Sruthee P., “Experimental study of concrete with Metakaolin as Partial replacement of cement”, International Journal of Emerging trends in Engineering and development,Issue2,Vol.4,May 2012, ISSN 2249-6149. 5. Vikas Srivastava., Rakesh Kumar., Agarwal V.C., “Metakaolin inclusion: Effect on mechanical properties of concrete”, J. Acad.Indus.Res.Vol.1(5), pp. 251-253, October 2012, ISSN: 2278-5213. 6. IS 10262:2009 Concrete Mix Proportioning Guidelines - Code of Practice, Bureau of Indian Standard, New Delhi 110002. 7. IS 456:2000 Indian Standard, Plain and Reinforced Concrete - Code of Practice, Bureau of Indian Standard, New Delhi 110002. 8. Sabir B.B, Wild S, Bai J, “Metakaolin and calcined clay as pozzolans for concrete :a review” Cement and concrete composite 23, (2001),pp.441-454. 9. Jiping Bai, Albinas Gailius “Consistency of fly ash and metakaolin concrete” journal of civil engineeringandmanagement15(2):(2009),pp.131– 135. 10. Pacheco Torgal F, Arman Shasavandi, Said Jalali “Using metakaolin to improve the compressive strength and the durability of fly ash based concrete” Invaco2: International seminar, innovation & valorization in civil engineering & construction materials,Rabat-Morocco, 23-25 November( 2011), ISBN 987-9954-30-595-9.