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UNCONVENTIONAL
HYDROCARBON



         By-
         Swapnil Pal
         IMT Geological Technology
HEAVY OIL AND   • Known for a long time and was easy to
 TAR SANDS        exploit for use in small quantities.
INTRODUCTION    • In southern California oil was mined from
                  the early 1860s to the 1890s because the
                  heavy oil would not flow to the wells.
                • Tar sands are sandstone reservoirs which
                  have been filled with oil at shallow depth
                  <2 km (<70–80◦C) so that the oil has
                  become biodegraded. Reservoir rocks
                  which have been buried more deeply and
                  then uplifted before the oil migration may
                  be sterilized at higher temperatures and
                  are less likely to be biodegraded.
HEAVY OIL AND   • Tar sand contains asphaltic oil rich in
                  asphaltenes and resins. It has a high
 TAR SANDS        content of aromatics and naphthenes
INTRODUCTION      compared to paraffins, and a high con-
                  tent of nitrogen, sulphur and oxygen
                  (NSO).
                • Most of the hydrocarbon molecules
                  have more than 60 carbon atoms and
                  the boiling point and viscosity are
                  therefore very high.
                • The viscosity of the biodegraded oil is
                  very high and the oil must be heated so
                  that the viscosity is reduced before it
                  can be produced by drilling wells.
HEAVY OIL AND   • Heating of reservoir.
 TAR SANDS       heating can be achieved by soaking the
 METHODS OF       reservoir with injected steam. This is
 EXTRACTION       called cyclic steam injection.
                 burn some of the oil in the subsurface.
                 heat the oil electrically, possibly
                  powered by a nuclear reactor to reduce
                  the CO2 emissions from burning oil to
                  produce heat.
                • Freezing the ground at a distance from
                  the well.
TAR SAND    Oil are also extracted from tar sand.
            The tar sands in Alberta, Canada (Athabasca) of
             Middle Cretaceous age (Aptian, 100 million years)
             contains 1.7 trillion bbl (270×109m3) of bitumen in
             place, comparable in magnitude to the world’s total
             proven reserves of conventional petroleum.
            The oil (tar) is very viscous and may be denser than
             water (API<10). Only about 20% is close enough to
             the surface to be economically mined and the rest
             must be heated in place. A cubic meters of oil, mined
             from the tar sands, needs 2–4.5 m3 of water.
            Oil may be extracted by steam-assisted gravity
             drainage (SAGD).
HEAVY OIL RECOVERY METHODS


   Primary Recovery Method


   Cold EOR

   Thermal Production Method
THERMAL OIL RECOVERY

Cyclic Steam Stimulation   Steam Assisted Gravity Drainage
(CSS)                      (SAGD)
CYCLIC STEAM
        STIMULATION



Stage 1:
High pressure steam injected
Stage 2:
Major portion of reservoir is
thoroughly saturated
Stage 3:
Production phase
When production phase declines,
another cycle of stream injection
begins.
STEAM ASSISTED GRAVITY
DRAINAGE (SAGD)




 2 horizontal wells are drilled.
 Injected steam forms a “steam
  chamber”.
 Steam and gases rise filling the
  void left by oil.
 The condensed water and crude
  oil or bitumen is recovered to the
  surface by pumps
STEAM ASSISTED GRAVITY
DRAINAGE (SAGD)




 2 horizontal wells are drilled.
 Injected steam forms a “steam
  chamber”.
 Steam and gases rise filling the
  void left by oil.
 The condensed water and crude
  oil or bitumen is recovered to the
  surface by pumps
IL
SHALE
SALIENT FEATURES




• They are not oils!

• They are usually mudstones and shale, with
  a high organic content (TOC), which have
  not been buried deeply enough to become
  sufficiently mature for most of the
  hydrocarbons to be generated.

• The can produce oil after undergoing
  crushing and pyrolysis.
OIL SHALE   Oil Shale Resources V/s Oil Reserves
GEOLOGY




• Organic rich sedimentary rock, belongs to sapropel fuel group.
• Oil shale vary in mineral content, chemical composition, age, type of kerogen.
• Low solubility in low-boiling organic matter and generates liquid organic
  product on thermal decomposition.
• They differ from bitumen-impregnated rock, humic coals and carbonaceous
  shale.
• Maturation of oil shale does not exceed meso-catagenetic.
OIL SHALE EXTRACTION



                                          Clayey rock
• Oil shale must be mined.
• After excavation, oil shale must
  undergo retorting.
                                     Crushing
• Then it undergoes the process of
  pyrolysis.

                                           pyrolysis




                                     Shale Oil
OIL SHALE EXTRACTION
PROBLEMS


                                           Clayey rock
o This process adds two extra steps
  to the conventional extraction
  process.
o Oil shale presents environmental    Crushing
  challenges as well.
o There's also the matter of the
  rocks.                                    pyrolysis




                                      Shale Oil
OIL SHALE EXTRACTION
SOLUTION



o Royal Dutch Shell Oil Company has
  come up with In Situ Conversion
  Process (ICP).
o The rock remains where it is.
o holes are drilled into an oil shale
  reserve and heaters are lowered
  into the earth.
o The kerogen seeps out which is
  collected on-site and pumped to the
  surface.
OIL SHALE EXTRACTION
SOLUTION
GAS
HYDRATES
WHAT ARE THEY?


 Gas hydrates are crystalline solids almost
  like ice, consisting of gas (mostly
  methane) surrounded by water.
 It is stable at high pressures and low
  temperatures.
 When gas hydrates dissolve (melt) one
  volume of gas hydrate produces 160
  volumes of gas.
 The source of the methane is mostly
  biogenic, from organic rich sediments,
  but gas hydrates may also fill the pores in
  sand beds.
 During the glaciations gas hydrates were
  more widespread than now and occurred
  also beneath the seafloor in basins like
  the North Sea.
 Gas hydrates are potentially a very
  important source of gas.
FEW SALIENT POINTS
ABOUT GAS HYDRATES

• Hydrates store immense amounts of methane, with major implications for
  energy resources and climate, but the natural controls on hydrates and their
  impacts on the environment are very poorly understood.
• The immense volumes of gas and the richness of the deposits may make
  methane hydrates a strong candidate for development as an energy
  resource.
• Results of USGS investigations indicate that methane hydrates possess
  unique acoustic properties.
• Methane, a "greenhouse" gas, is 10 times more effective than carbon dioxide
  in causing climate warming.
FEW SALIENT POINTS
ABOUT GAS HYDRATES


• USGS investigations indicate that gas hydrates may cause landslides on the
  continental slope.
COAL BED
METHANE
INTRINSIC PROPERTIES OF
AFFECTION GAS PRODUCTION



• Porosity: 0.1-10%
• Adsorption Capacity: 100-800
  SCF/ton
• Fracture Permeability
• Thickness of formation and initial
  reservoir pressure
SALIENT FEATURES




• Coal is the major source of
  methane gas.
• Coal is a low permeability
                                                 Coal
  reservoir. Almost all permeability            cleats
  is due to fractures, which in coal
  are in form of cleats and joints.

                                        Butt              Face
                                       cleats            cleats
PRODUCTION & EXTRACTION




• Coal beds are an attractive prospect for development because of their ability
  to retain large amounts of gas
• The amount of methane in a coal deposit depends on the quality and depth
  of the deposit.
• In CBM development, water is removed from the coal bed (by pumping),
  which decreases the pressure on the gas and allows it to detach from the
  coal and flow up the well.
• In the initial production stage of coal bed methane, the wells produce mostly
  water.
• Depending on the geological conditions, it may take several years to achieve
  full-scale gas production. Generally, the deeper the coal bed the less water
  present, and the sooner the well will begin to produce gas.
PRODUCTION & EXTRACTION




• The amount of water produced from most CBM wells is relatively high
  compared to conventional gas wells because coal beds contain many
  fractures and pores that can contain and move large amounts of water.
• CBM wells are drilled with techniques similar to those used for conventional
  wells.
• As with conventional gas wells, hydraulic fracturing is used as a primary
  means of stimulating gas flow in CBM wells.
• The methane desorption process follows a curve (of gas content vs. reservoir
  pressure) called a Langmuir isotherm.
• As production occurs from a coal reservoir, the changes in pressure are
  believed to cause changes in the porosity and permeability of the coal. This is
  commonly known as matrix shrinkage/swelling.
PRODUCTION & EXTRACTION




The potential of a particular coal bed
as a CBM source depends on the
following criteria:
 High Cleat density/intensity.
 Maceral composition.
 A high vitrinite composition is
    ideal for CBM extraction, while
    inertinite hampers the same.
SHALE GAS
The game changer!
INTRODUCTION




 Shale gas refers to natural gas that is trapped within shale formations.
  Organic-rich shale which have been buried to depths where most of the oil
  and gas has been generated and expelled may nevertheless contain
  considerable amount of gas.
 The gas remaining in these shale is present in very small pores and may also
  be partly adsorbed on remaining organic matter or its residue (coke) and on
  clay minerals.
 The shales have been uplifted and may therefore have small extensional
  fractures, but they must be hydro fractured by water injection to increase the
  permeability.
EXTRACTION




• The gas deposits are usually found in
  rocks that have low permeability, ruling
  out the possibility of regular drilling.
• The most commonly used method is
  called fracking (hydraulic fracturing).
• As opposed to vertical drilling for
  traditional gas, in this case horizontal
  drilling is carried out.
• What “changed the game” was the
  recognition that one could “create a
  permeable reservoir” and high rates of
  gas production by using intensively
  stimulated horizontal wells.
TWO MAJOR DRILLING TECHNIQUES ARE USED TO
PRODUCE SHALE GAS



Horizontal Drilling                        Hydraulic Fracturing
Horizontal drilling is used to provide     It is a technique in which water,
greater access to the gas trapped deep     chemicals, and sand are pumped into the
in the producing formation. First, a       well to unlock the hydrocarbons trapped
vertical well is drilled to the targeted   in shale formations by opening cracks
rock formation. At the desired depth,      (fractures) in the rock and allowing
the drill bit is turned to bore a well     natural gas to flow from the shale into
that stretches through the reservoir       the well. When used in conjunction with
horizontally, exposing the well to more    horizontal drilling, hydraulic fracturing
of the producing shale.                    enables gas producers to extract shale gas
                                           at reasonable cost.
CONCLUSION




• Conventional oil production has peaked and is now on a terminal, long-run global
  decline. However, contrary to conventional wisdom, which many embraced
  during back-to-back oil crises in the 1970s, oil is not running out. It is, instead,
  changing form—geographically, geologically, chemically, and economically.
• We are approaching the end of easily accessible, relatively homogeneous oil, and
  many experts claim that the era of cheap oil may also be ending.
• Many new breeds of petroleum fuels are nothing like conventional oil.
  Unconventional oils tend to be heavy, complex, carbon laden, and locked up deep
  in the earth, tightly trapped between or bound to sand, tar, and rock.
  Unconventional oils are nature’s own carbon-capture and storage device, so
  when they are tapped, we risk breaking open this natural carbon-fixing system.
  Generally speaking: the heavier the oil, the larger the expected carbon footprint.
CONCLUSION




From extraction through final use, these new oils will require a greater amount of
energy to produce than conventional oil. And as output ramps up to meet
increasing global demand for high-value petroleum products, unconventional oils
will likely deliver a higher volume of heavier hydrocarbons, require more intensive
processing and additives, and yield more byproducts that contain large amounts of
carbon.

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Unconventional hydrocarbons

  • 1.
  • 2. UNCONVENTIONAL HYDROCARBON By- Swapnil Pal IMT Geological Technology
  • 3. HEAVY OIL AND • Known for a long time and was easy to TAR SANDS exploit for use in small quantities. INTRODUCTION • In southern California oil was mined from the early 1860s to the 1890s because the heavy oil would not flow to the wells. • Tar sands are sandstone reservoirs which have been filled with oil at shallow depth <2 km (<70–80◦C) so that the oil has become biodegraded. Reservoir rocks which have been buried more deeply and then uplifted before the oil migration may be sterilized at higher temperatures and are less likely to be biodegraded.
  • 4. HEAVY OIL AND • Tar sand contains asphaltic oil rich in asphaltenes and resins. It has a high TAR SANDS content of aromatics and naphthenes INTRODUCTION compared to paraffins, and a high con- tent of nitrogen, sulphur and oxygen (NSO). • Most of the hydrocarbon molecules have more than 60 carbon atoms and the boiling point and viscosity are therefore very high. • The viscosity of the biodegraded oil is very high and the oil must be heated so that the viscosity is reduced before it can be produced by drilling wells.
  • 5. HEAVY OIL AND • Heating of reservoir. TAR SANDS  heating can be achieved by soaking the METHODS OF reservoir with injected steam. This is EXTRACTION called cyclic steam injection.  burn some of the oil in the subsurface.  heat the oil electrically, possibly powered by a nuclear reactor to reduce the CO2 emissions from burning oil to produce heat. • Freezing the ground at a distance from the well.
  • 6. TAR SAND  Oil are also extracted from tar sand.  The tar sands in Alberta, Canada (Athabasca) of Middle Cretaceous age (Aptian, 100 million years) contains 1.7 trillion bbl (270×109m3) of bitumen in place, comparable in magnitude to the world’s total proven reserves of conventional petroleum.  The oil (tar) is very viscous and may be denser than water (API<10). Only about 20% is close enough to the surface to be economically mined and the rest must be heated in place. A cubic meters of oil, mined from the tar sands, needs 2–4.5 m3 of water.  Oil may be extracted by steam-assisted gravity drainage (SAGD).
  • 7. HEAVY OIL RECOVERY METHODS  Primary Recovery Method  Cold EOR  Thermal Production Method
  • 8. THERMAL OIL RECOVERY Cyclic Steam Stimulation Steam Assisted Gravity Drainage (CSS) (SAGD)
  • 9. CYCLIC STEAM STIMULATION Stage 1: High pressure steam injected Stage 2: Major portion of reservoir is thoroughly saturated Stage 3: Production phase When production phase declines, another cycle of stream injection begins.
  • 10. STEAM ASSISTED GRAVITY DRAINAGE (SAGD)  2 horizontal wells are drilled.  Injected steam forms a “steam chamber”.  Steam and gases rise filling the void left by oil.  The condensed water and crude oil or bitumen is recovered to the surface by pumps
  • 11. STEAM ASSISTED GRAVITY DRAINAGE (SAGD)  2 horizontal wells are drilled.  Injected steam forms a “steam chamber”.  Steam and gases rise filling the void left by oil.  The condensed water and crude oil or bitumen is recovered to the surface by pumps
  • 13. SALIENT FEATURES • They are not oils! • They are usually mudstones and shale, with a high organic content (TOC), which have not been buried deeply enough to become sufficiently mature for most of the hydrocarbons to be generated. • The can produce oil after undergoing crushing and pyrolysis.
  • 14. OIL SHALE Oil Shale Resources V/s Oil Reserves
  • 15. GEOLOGY • Organic rich sedimentary rock, belongs to sapropel fuel group. • Oil shale vary in mineral content, chemical composition, age, type of kerogen. • Low solubility in low-boiling organic matter and generates liquid organic product on thermal decomposition. • They differ from bitumen-impregnated rock, humic coals and carbonaceous shale. • Maturation of oil shale does not exceed meso-catagenetic.
  • 16. OIL SHALE EXTRACTION Clayey rock • Oil shale must be mined. • After excavation, oil shale must undergo retorting. Crushing • Then it undergoes the process of pyrolysis. pyrolysis Shale Oil
  • 17. OIL SHALE EXTRACTION PROBLEMS Clayey rock o This process adds two extra steps to the conventional extraction process. o Oil shale presents environmental Crushing challenges as well. o There's also the matter of the rocks. pyrolysis Shale Oil
  • 18. OIL SHALE EXTRACTION SOLUTION o Royal Dutch Shell Oil Company has come up with In Situ Conversion Process (ICP). o The rock remains where it is. o holes are drilled into an oil shale reserve and heaters are lowered into the earth. o The kerogen seeps out which is collected on-site and pumped to the surface.
  • 21. WHAT ARE THEY?  Gas hydrates are crystalline solids almost like ice, consisting of gas (mostly methane) surrounded by water.  It is stable at high pressures and low temperatures.  When gas hydrates dissolve (melt) one volume of gas hydrate produces 160 volumes of gas.  The source of the methane is mostly biogenic, from organic rich sediments, but gas hydrates may also fill the pores in sand beds.  During the glaciations gas hydrates were more widespread than now and occurred also beneath the seafloor in basins like the North Sea.  Gas hydrates are potentially a very important source of gas.
  • 22. FEW SALIENT POINTS ABOUT GAS HYDRATES • Hydrates store immense amounts of methane, with major implications for energy resources and climate, but the natural controls on hydrates and their impacts on the environment are very poorly understood. • The immense volumes of gas and the richness of the deposits may make methane hydrates a strong candidate for development as an energy resource. • Results of USGS investigations indicate that methane hydrates possess unique acoustic properties. • Methane, a "greenhouse" gas, is 10 times more effective than carbon dioxide in causing climate warming.
  • 23. FEW SALIENT POINTS ABOUT GAS HYDRATES • USGS investigations indicate that gas hydrates may cause landslides on the continental slope.
  • 25. INTRINSIC PROPERTIES OF AFFECTION GAS PRODUCTION • Porosity: 0.1-10% • Adsorption Capacity: 100-800 SCF/ton • Fracture Permeability • Thickness of formation and initial reservoir pressure
  • 26. SALIENT FEATURES • Coal is the major source of methane gas. • Coal is a low permeability Coal reservoir. Almost all permeability cleats is due to fractures, which in coal are in form of cleats and joints. Butt Face cleats cleats
  • 27. PRODUCTION & EXTRACTION • Coal beds are an attractive prospect for development because of their ability to retain large amounts of gas • The amount of methane in a coal deposit depends on the quality and depth of the deposit. • In CBM development, water is removed from the coal bed (by pumping), which decreases the pressure on the gas and allows it to detach from the coal and flow up the well. • In the initial production stage of coal bed methane, the wells produce mostly water. • Depending on the geological conditions, it may take several years to achieve full-scale gas production. Generally, the deeper the coal bed the less water present, and the sooner the well will begin to produce gas.
  • 28. PRODUCTION & EXTRACTION • The amount of water produced from most CBM wells is relatively high compared to conventional gas wells because coal beds contain many fractures and pores that can contain and move large amounts of water. • CBM wells are drilled with techniques similar to those used for conventional wells. • As with conventional gas wells, hydraulic fracturing is used as a primary means of stimulating gas flow in CBM wells. • The methane desorption process follows a curve (of gas content vs. reservoir pressure) called a Langmuir isotherm. • As production occurs from a coal reservoir, the changes in pressure are believed to cause changes in the porosity and permeability of the coal. This is commonly known as matrix shrinkage/swelling.
  • 29. PRODUCTION & EXTRACTION The potential of a particular coal bed as a CBM source depends on the following criteria:  High Cleat density/intensity.  Maceral composition.  A high vitrinite composition is ideal for CBM extraction, while inertinite hampers the same.
  • 30. SHALE GAS The game changer!
  • 31. INTRODUCTION  Shale gas refers to natural gas that is trapped within shale formations. Organic-rich shale which have been buried to depths where most of the oil and gas has been generated and expelled may nevertheless contain considerable amount of gas.  The gas remaining in these shale is present in very small pores and may also be partly adsorbed on remaining organic matter or its residue (coke) and on clay minerals.  The shales have been uplifted and may therefore have small extensional fractures, but they must be hydro fractured by water injection to increase the permeability.
  • 32. EXTRACTION • The gas deposits are usually found in rocks that have low permeability, ruling out the possibility of regular drilling. • The most commonly used method is called fracking (hydraulic fracturing). • As opposed to vertical drilling for traditional gas, in this case horizontal drilling is carried out. • What “changed the game” was the recognition that one could “create a permeable reservoir” and high rates of gas production by using intensively stimulated horizontal wells.
  • 33. TWO MAJOR DRILLING TECHNIQUES ARE USED TO PRODUCE SHALE GAS Horizontal Drilling Hydraulic Fracturing Horizontal drilling is used to provide It is a technique in which water, greater access to the gas trapped deep chemicals, and sand are pumped into the in the producing formation. First, a well to unlock the hydrocarbons trapped vertical well is drilled to the targeted in shale formations by opening cracks rock formation. At the desired depth, (fractures) in the rock and allowing the drill bit is turned to bore a well natural gas to flow from the shale into that stretches through the reservoir the well. When used in conjunction with horizontally, exposing the well to more horizontal drilling, hydraulic fracturing of the producing shale. enables gas producers to extract shale gas at reasonable cost.
  • 34. CONCLUSION • Conventional oil production has peaked and is now on a terminal, long-run global decline. However, contrary to conventional wisdom, which many embraced during back-to-back oil crises in the 1970s, oil is not running out. It is, instead, changing form—geographically, geologically, chemically, and economically. • We are approaching the end of easily accessible, relatively homogeneous oil, and many experts claim that the era of cheap oil may also be ending. • Many new breeds of petroleum fuels are nothing like conventional oil. Unconventional oils tend to be heavy, complex, carbon laden, and locked up deep in the earth, tightly trapped between or bound to sand, tar, and rock. Unconventional oils are nature’s own carbon-capture and storage device, so when they are tapped, we risk breaking open this natural carbon-fixing system. Generally speaking: the heavier the oil, the larger the expected carbon footprint.
  • 35. CONCLUSION From extraction through final use, these new oils will require a greater amount of energy to produce than conventional oil. And as output ramps up to meet increasing global demand for high-value petroleum products, unconventional oils will likely deliver a higher volume of heavier hydrocarbons, require more intensive processing and additives, and yield more byproducts that contain large amounts of carbon.