Carnot's idealized steam engine cycle showed that a heat engine cannot convert all heat into work and some heat must be rejected. This led to the second law of thermodynamics. Rudolf Clausius defined entropy as the "transformation content" of a body and introduced the concept that heat cannot spontaneously flow from cold to hot. Ludwig Boltzmann described entropy on a molecular level in terms of molecular kinetic energy. Josiah Willard Gibbs defined available energy, now called Gibbs free energy, as the maximum work obtainable from a system at constant temperature and pressure.