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FERTILIZER REACTIONS IN SOIL
FERTILIZER
Materials having
 definite chemical composition
 higher analytical value
 capable of supplying plant nutrients
in available form
NITROGENOUS FERTILIZER
Ammonical form (Eg. Ammonium sulphate – 20% N)
Nitrate form
Eg: NaNO3– 16% N
Both Ammonium- Nitrate
Eg: CAN – 20% N
Amideform
Eg:Urea -46% N
Reaction of Ammonium sulphate in soil
1. In Upland condition:
Cation exchange - NH4
+ displaces some other cations.
2. In calcareous soil:
When (NH4)2SO4 applied as
Broadcast – losses of Nitrogen is appreciable
Drilled - losses of nitrogen is not appreciable
REACTION OF UREA IN SOIL
Urea undergoes enzymatic hydrolysis to produce
ammonium carbamate.
NH3 converted to NH4
+
Further reaction is similar to
Ammoniacal form
•High concentration of urea – combined toxic effect of
NH3 and NO2
• Higher concentration of NH3
increases
•Due to low population of Nitrobacter
inhibited
REACTION OF SLOW RELEASE NITROGENOUS FERTILIZER
PHOSPHATIC FERTILIZERS
Water soluble
Eg: SSP – 16% P2O5
Citric acid soluble
Eg: Dicalcium
phosphate- 34 % P2O5
Both insoluble
Eg: Rock phosphate-
20-40% P2O5
REACTION OF SUPERPHOSPHATE IN SOIL
Superphosphate applied to moist soil
• Dissolved in soil moisture
• Within short time gets precipitated
• SSP not leached from soil by Rainfall
REACTION OF SSP IN ACID SOIL
Combines with Fe and Al – forms insoluble phosphate
- becomes unavailable
REACTION OF SSP IN NEUTRAL AND CALCAREOUS SOIL
Monocalcium phosphate converted to Tricalcium phosphate
Tricalcium phosphate converted to insoluble compounds like apatite
REACTION OF SSP IN ALKALI SOIL
SSP reacts with sodium and forms monosodium phosphate
Monosodium phosphate – highly soluble and become
available to plants
REACTION OF POTASSIC FERTILIZER IN SOIL
Both KCl and K2SO4
– soluble in water
-on application in soil they ionize to K+, Cl-, SO4
2-
- available to plants
REACTION OF POLYPHOSPHATE FERTILIZER IN SOIL
LOSS AND GAIN OF NUTRIENTS
Fate of
applied
fertilizer
Taken up by the crop
Reacts with soil
minerals and
organic matter
Can leach from the
root zone with water
lost to the atmosphere
as a gas
Can move from
the field through
soil erosion and
water runoff
•REFERENCE :
•W. L. Lindsay ,H. F. Stephenson. Nature of the Reactions of Monocalcium Phosphate
Monohydrate in Soils: The Solution That Reacts with the Soil. Soil Science Society of
America Journal . Vol. 23 No. 1, p. 12-18

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Fertilizer reaction in soil (1)

  • 2. FERTILIZER Materials having  definite chemical composition  higher analytical value  capable of supplying plant nutrients in available form
  • 3. NITROGENOUS FERTILIZER Ammonical form (Eg. Ammonium sulphate – 20% N) Nitrate form Eg: NaNO3– 16% N Both Ammonium- Nitrate Eg: CAN – 20% N Amideform Eg:Urea -46% N
  • 4. Reaction of Ammonium sulphate in soil 1. In Upland condition: Cation exchange - NH4 + displaces some other cations.
  • 5. 2. In calcareous soil: When (NH4)2SO4 applied as Broadcast – losses of Nitrogen is appreciable Drilled - losses of nitrogen is not appreciable
  • 6. REACTION OF UREA IN SOIL Urea undergoes enzymatic hydrolysis to produce ammonium carbamate. NH3 converted to NH4 + Further reaction is similar to Ammoniacal form
  • 7. •High concentration of urea – combined toxic effect of NH3 and NO2 • Higher concentration of NH3 increases •Due to low population of Nitrobacter inhibited
  • 8.
  • 9. REACTION OF SLOW RELEASE NITROGENOUS FERTILIZER
  • 10. PHOSPHATIC FERTILIZERS Water soluble Eg: SSP – 16% P2O5 Citric acid soluble Eg: Dicalcium phosphate- 34 % P2O5 Both insoluble Eg: Rock phosphate- 20-40% P2O5
  • 11. REACTION OF SUPERPHOSPHATE IN SOIL Superphosphate applied to moist soil • Dissolved in soil moisture • Within short time gets precipitated • SSP not leached from soil by Rainfall
  • 12. REACTION OF SSP IN ACID SOIL Combines with Fe and Al – forms insoluble phosphate - becomes unavailable
  • 13. REACTION OF SSP IN NEUTRAL AND CALCAREOUS SOIL Monocalcium phosphate converted to Tricalcium phosphate Tricalcium phosphate converted to insoluble compounds like apatite REACTION OF SSP IN ALKALI SOIL SSP reacts with sodium and forms monosodium phosphate Monosodium phosphate – highly soluble and become available to plants
  • 14.
  • 15. REACTION OF POTASSIC FERTILIZER IN SOIL Both KCl and K2SO4 – soluble in water -on application in soil they ionize to K+, Cl-, SO4 2- - available to plants
  • 16. REACTION OF POLYPHOSPHATE FERTILIZER IN SOIL
  • 17. LOSS AND GAIN OF NUTRIENTS
  • 18. Fate of applied fertilizer Taken up by the crop Reacts with soil minerals and organic matter Can leach from the root zone with water lost to the atmosphere as a gas Can move from the field through soil erosion and water runoff
  • 19. •REFERENCE : •W. L. Lindsay ,H. F. Stephenson. Nature of the Reactions of Monocalcium Phosphate Monohydrate in Soils: The Solution That Reacts with the Soil. Soil Science Society of America Journal . Vol. 23 No. 1, p. 12-18