Arsenic is well known under desirable hand harmful due to its toxic nature, it poses the serious health hazard, which is present in medical substance, many qualitative and quantitative test for arsenic known, however Pharmacopoeia method is based on ‘Gutzeit Method’.
Concentration of arsenic beyond 0.01 mg/L in pollutant by the World Health Organization (WHO).
Reasons:
• Stannous chloride is used for complete evolution of arsine.
• Zinc, potassium iodide and stannous chloride is used as a reducing agent.
• Hydrochloride acid is used to make the solution acidic.
• Lead acetate pledger or papers are used to trap any hydrogen sulphide, which may be evolved along with arsine.
Volumetric Analysis
Types of titration
Acid- Base Theory
Reaction, End Point & Indicators
Acid- Base titration
Titration curve
Non- Aqueous Titration
Precipitation Titration
Complexometric Titration
Oxidation- Reduction Titration,
Calculation. Errors
General Informations,
What is Gravimetric analysis, stepes invloved in gravimetry, Filteration medium in gravimetry, gravimetric factor, application, organic and inorganic prepecating agents
complete details for performing limit test for chlorides its is very helpful for the B.pharmacy 1 year students for both analysis as well as inoganic chemistry.
Arsenic is well known under desirable hand harmful due to its toxic nature, it poses the serious health hazard, which is present in medical substance, many qualitative and quantitative test for arsenic known, however Pharmacopoeia method is based on ‘Gutzeit Method’.
Concentration of arsenic beyond 0.01 mg/L in pollutant by the World Health Organization (WHO).
Reasons:
• Stannous chloride is used for complete evolution of arsine.
• Zinc, potassium iodide and stannous chloride is used as a reducing agent.
• Hydrochloride acid is used to make the solution acidic.
• Lead acetate pledger or papers are used to trap any hydrogen sulphide, which may be evolved along with arsine.
Volumetric Analysis
Types of titration
Acid- Base Theory
Reaction, End Point & Indicators
Acid- Base titration
Titration curve
Non- Aqueous Titration
Precipitation Titration
Complexometric Titration
Oxidation- Reduction Titration,
Calculation. Errors
General Informations,
What is Gravimetric analysis, stepes invloved in gravimetry, Filteration medium in gravimetry, gravimetric factor, application, organic and inorganic prepecating agents
complete details for performing limit test for chlorides its is very helpful for the B.pharmacy 1 year students for both analysis as well as inoganic chemistry.
Generating a custom Ruby SDK for your web service or Rails API using Smithyg2nightmarescribd
Have you ever wanted a Ruby client API to communicate with your web service? Smithy is a protocol-agnostic language for defining services and SDKs. Smithy Ruby is an implementation of Smithy that generates a Ruby SDK using a Smithy model. In this talk, we will explore Smithy and Smithy Ruby to learn how to generate custom feature-rich SDKs that can communicate with any web service, such as a Rails JSON API.
GraphRAG is All You need? LLM & Knowledge GraphGuy Korland
Guy Korland, CEO and Co-founder of FalkorDB, will review two articles on the integration of language models with knowledge graphs.
1. Unifying Large Language Models and Knowledge Graphs: A Roadmap.
https://arxiv.org/abs/2306.08302
2. Microsoft Research's GraphRAG paper and a review paper on various uses of knowledge graphs:
https://www.microsoft.com/en-us/research/blog/graphrag-unlocking-llm-discovery-on-narrative-private-data/
Transcript: Selling digital books in 2024: Insights from industry leaders - T...BookNet Canada
The publishing industry has been selling digital audiobooks and ebooks for over a decade and has found its groove. What’s changed? What has stayed the same? Where do we go from here? Join a group of leading sales peers from across the industry for a conversation about the lessons learned since the popularization of digital books, best practices, digital book supply chain management, and more.
Link to video recording: https://bnctechforum.ca/sessions/selling-digital-books-in-2024-insights-from-industry-leaders/
Presented by BookNet Canada on May 28, 2024, with support from the Department of Canadian Heritage.
Connector Corner: Automate dynamic content and events by pushing a buttonDianaGray10
Here is something new! In our next Connector Corner webinar, we will demonstrate how you can use a single workflow to:
Create a campaign using Mailchimp with merge tags/fields
Send an interactive Slack channel message (using buttons)
Have the message received by managers and peers along with a test email for review
But there’s more:
In a second workflow supporting the same use case, you’ll see:
Your campaign sent to target colleagues for approval
If the “Approve” button is clicked, a Jira/Zendesk ticket is created for the marketing design team
But—if the “Reject” button is pushed, colleagues will be alerted via Slack message
Join us to learn more about this new, human-in-the-loop capability, brought to you by Integration Service connectors.
And...
Speakers:
Akshay Agnihotri, Product Manager
Charlie Greenberg, Host
Neuro-symbolic is not enough, we need neuro-*semantic*Frank van Harmelen
Neuro-symbolic (NeSy) AI is on the rise. However, simply machine learning on just any symbolic structure is not sufficient to really harvest the gains of NeSy. These will only be gained when the symbolic structures have an actual semantics. I give an operational definition of semantics as “predictable inference”.
All of this illustrated with link prediction over knowledge graphs, but the argument is general.
GDG Cloud Southlake #33: Boule & Rebala: Effective AppSec in SDLC using Deplo...James Anderson
Effective Application Security in Software Delivery lifecycle using Deployment Firewall and DBOM
The modern software delivery process (or the CI/CD process) includes many tools, distributed teams, open-source code, and cloud platforms. Constant focus on speed to release software to market, along with the traditional slow and manual security checks has caused gaps in continuous security as an important piece in the software supply chain. Today organizations feel more susceptible to external and internal cyber threats due to the vast attack surface in their applications supply chain and the lack of end-to-end governance and risk management.
The software team must secure its software delivery process to avoid vulnerability and security breaches. This needs to be achieved with existing tool chains and without extensive rework of the delivery processes. This talk will present strategies and techniques for providing visibility into the true risk of the existing vulnerabilities, preventing the introduction of security issues in the software, resolving vulnerabilities in production environments quickly, and capturing the deployment bill of materials (DBOM).
Speakers:
Bob Boule
Robert Boule is a technology enthusiast with PASSION for technology and making things work along with a knack for helping others understand how things work. He comes with around 20 years of solution engineering experience in application security, software continuous delivery, and SaaS platforms. He is known for his dynamic presentations in CI/CD and application security integrated in software delivery lifecycle.
Gopinath Rebala
Gopinath Rebala is the CTO of OpsMx, where he has overall responsibility for the machine learning and data processing architectures for Secure Software Delivery. Gopi also has a strong connection with our customers, leading design and architecture for strategic implementations. Gopi is a frequent speaker and well-known leader in continuous delivery and integrating security into software delivery.
Accelerate your Kubernetes clusters with Varnish CachingThijs Feryn
A presentation about the usage and availability of Varnish on Kubernetes. This talk explores the capabilities of Varnish caching and shows how to use the Varnish Helm chart to deploy it to Kubernetes.
This presentation was delivered at K8SUG Singapore. See https://feryn.eu/presentations/accelerate-your-kubernetes-clusters-with-varnish-caching-k8sug-singapore-28-2024 for more details.
Dev Dives: Train smarter, not harder – active learning and UiPath LLMs for do...UiPathCommunity
💥 Speed, accuracy, and scaling – discover the superpowers of GenAI in action with UiPath Document Understanding and Communications Mining™:
See how to accelerate model training and optimize model performance with active learning
Learn about the latest enhancements to out-of-the-box document processing – with little to no training required
Get an exclusive demo of the new family of UiPath LLMs – GenAI models specialized for processing different types of documents and messages
This is a hands-on session specifically designed for automation developers and AI enthusiasts seeking to enhance their knowledge in leveraging the latest intelligent document processing capabilities offered by UiPath.
Speakers:
👨🏫 Andras Palfi, Senior Product Manager, UiPath
👩🏫 Lenka Dulovicova, Product Program Manager, UiPath
FIDO Alliance Osaka Seminar: The WebAuthn API and Discoverable Credentials.pdf
Sodium hydroxide preparation and standardization
1. Standardization of Sodium
Hydroxide Solution
Presented By
Mrs.Smita P.Shelke
Assistant Professor, Department of Pharmaceutical Chemistry,
GES’s Sir Dr.M.S.Gosavi College of Pharmaceutical Education and
Research, Nashik-05.(Maharashtra
2. Experiment No: 01
Title: To prepare and standardization of 0.1 M sodium hydroxide
solution (NaOH) using the primary standard potassium hydrogen
phthalate.
3. Requirements
• Glasswares: Burette, burette stand, conical flask, volumetric pipette, beaker,
volumetric flask, funnel, glass rod, and wash bottle, etc.
• Chemicals: LR grade sodium hydroxide (NaOH), potassium hydrogen
phthalate (KHP), and phenolphthalein indicator, etc.
• Apparatus: Digital/analytical balance, and Ultrasonicator.
4. Theory:
To determine the exact concentration (Molarity/Normality) of NaOH solution
it needs to be standardized. Because solid NaOH is extremely hygroscopic, it
cannot be precisely weighed. The concentration of sodium hydroxide may be
determined extremely precisely by titrating a KHP sample of known
mass/mole with the NaOH solution.
5. Principle
Potassium hydrogen phthalate is directly titrated with sodium hydroxide to
determine its strength. Using phenolphthalein as an indication, the endpoint of
the titration is determined. The following is the reaction that is involved in this
titration.
7. Factor calculation
1mole of NaOH eqivalent to 1 mole of KHP
40 g of NaOH ≡ 204.2 g of KHP
1000 ml of 1 M NaOH ≡ 204.2g of KHP
100 ml of 1 M NaOH ≡ 20.42g of KHP
10 ml of 1 M NaOH ≡ 2.042g of KHP
1 ml of 1 M NaOH ≡ 0.2042g of KHP
1 ml of 0.1 M NaOH ≡ 0.02042 g KHP
8. Preparation of 0.1 M NaOH
The molecular weight of sodium hydroxide (NaOH) is 39.997 g/mol
40 g in 1000 ml solvent is 1 M solution
4 g in 1000 ml solvent is 0.1 M sloution
0.4 g in 100 ml solvent is 0.1 M
Procedure:
1. Weigh accurately 04.00 gm of sodium hydroxide in watch glass.
2. Add 50 ml of distilled water to it.
3. Mix it well.
4. Make up the volume upto 100 ml with distilled water.
9. Titration Procedure
1. All glassware should be cleaned and dried according to standard laboratory
procedures.
2. Before filling the burette for the titration, rinse it with distilled water and
then pre-rinse it with a portion of the titrant solution. Pre-rinsing is required to
make sure that all solution in the burette is the desired solution, not a
contaminated or diluted solution.
3. Take the sodium hydroxide stock solution of titrant in a clean and dry beaker
then fill the burette using the funnel.
4. Remove air bubbles from the burette and adjust the reading to zero.
10. Titration Procedure
5. Accurately weigh 0.2 gm of previously dried potassium hydrogen phthalate
and pour into a conical flask.
6. To dissolve adequately, add 25 ml distilled water and sonicate for 5 minutes
on a sonicator.
7. Add 2 drops of phenolphthalein indicator once it has been solubilized.
8. Titrate the sample solution with NaOH until the endpoint is reached. A pink
color appears and disappears, indicating that the endpoint is approaching, when
the solution is swirled for up to 10 seconds. The actual endpoint is indicated by
a pink color that lasts longer than 30 seconds.
11. Titration Procedure
9. Properly record the readings of the burette.
10. To get accurate results, repeat the titration three times.
11. Take their mean and calculate the molarity of NaOH.
12. Observations
Solution in Burette: Sodium hydroxide
Conical flask: 0.2 g of KHP in 25 ml DW
Indicator: Phenolpthalein
Colour Change: Colorless to Pink
Constant Burette readings:
Sr. No. Burette reading Volume of
titrant
1
2
3
Mean
13. Calculations:
1 ml of 0.1 M NaOH ≡ 0.02042 g KHP
C B R ml of X M NaOH = 0.2 g of KHP
Cross multiplication
1 x 0.1 x 0.2 = Avg C B R x X M x 0.02042
1 x 0.1 x 0.2
X M = ------------------------------------------
Avg C B R x 0.02042
14. Result:
The molarity of prepared sample of sodium hydroxide was found to be
--------------------- M.