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Group -> 14 ↓  Period 2 6 C 3 14 Si 4 32 Ge 5 50 Sn 6 82 Pb 7 114 Uuq Catenation of chemical bonds leads to the formation of inorganic polymers. However, inorganic polymers are mostly solids in the form of crystals. Typical inorganic polymers are diamond, graphite, silicates, and other solids in which all atoms are connected by covalent bonds. ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Molecular Formula SiCl 4 Molar Mass 169.90 g·mol -1 Appearance Colourless liquid Density 1.483 g/cm 3 Boiling point 57.65 °C Melting Point − 68.74 °C Solubility in water decomposes This colorless volatile liquid compound is prepared by the treatment of silicon with chlorine: Si + 2 Cl 2  -> SiCl 4 Silicon tetrachloride is sometimes used as an intermediate in the manufacture of extremely pure silicon, since it has a boiling point convenient for purification by repeated fractional distillation; it can be reduced to silicon by hydrogen gas, or hydrolysed to SiO 2  as a precursor for extremely pure synthetic fused silica. Very pure silicon derived from silicon tetrachloride is used in large amounts in the semiconductor industry, and also in the production of photovoltaic cells.  Pure silicon has a negative temperature coefficient of resistance, since the number of free charge carriers increases with temperature. The electrical resistance of single crystal silicon significantly changes under the application of mechanical stress due to the piezoresistive effect. In its crystalline form, pure silicon has a gray color and a metallic luster. It is similar to glass in that it is rather strong, very brittle, and prone to chipping. Both silicon and (in certain aspects) carbon are semiconductors, readily either donating or sharing their four outer electrons allowing many different forms of chemical bonding. The outer electron orbitals (half filled subshell holding up to eight electrons) have the same structure as in carbon and the two elements are sometimes similar chemically. Even though it is a relatively inert element, silicon still reacts with halogens and dilute alkalis, but most acids (except for some hyper-reactive combinations of nitric acid and hydrofluoric acid) do not affect it.  Having four bonding electrons however gives it, like carbon, many opportunities to combine with other elements or compounds under the right circumstances. ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Buckey Balls and Nanotubes During the past 25 years we have discovered that carbon can for hollow structures similar to geodesic domes referred to informally as "Bucky Balls". In fact carbon atoms can form not only domes but also tubes, which when used as fibres they have the potential to help us create composite materials with strength to weight ratios which far exceed steel. An important potential application for this material could be the development of a "space elevator".  Diamond Diamond is one of the hardest materials in the world and ranks a 10 on  Mohs scale of hardness  for minerals. In its pure form it is clear and colorless.  Graphite Commonly seen as the "lead" in lead pencils. Graphite is so soft that we have used its propencity to 'rub off', to make writing instruments since the middle of the 16th century. Lamp Black Lamp black is a fine powder left behind by the burning of a flame. It is extremely black and is used to absorb light in situations where the absorbtion of the light must be as complete as possible as well as independent the light frequency. Atoms and their nuclei In order to understand the covalent bond, we must take a look at the structure of atoms. During the 20th century, the investigation of the material world turned to the very heart of material world - the structure of atoms. The discovery of electrons in 1897 by J.J. Thomson showed that there were more fundamental particles present in the atoms. Fourteen years later, Rutherford discovered that most of the mass of an atom resides in a tiny nucleus whose radius is 100,000 times smaller than that of an atom. In the mean time, light beams were discovered to be made of photons which are equivalent to particles of wave motion. These discoveries created new concepts. When these concepts and discoveries are integrated, new ideas emerge. The result is quantum theory. This theory gives good interpretations of the phenomena of the atomic and subatomic world. In this microscopic world, distances are measured in nanometers (10 -9  or 1e-9 meter) and fantometers (1e-15 meter, also called fermi, in honour of Fermi who built the first nuclear reactor). ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Chemistry  Class 11 th Book By Shubham goyal Shubham singh Vatan Tina Nehan

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Shubham

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