Nucleophilic Substitution Fall 09

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Nucleophilic Substitution

Nucleophilic Substitutions (S N 1, S N 2) of Halides S – Substitution N – Nucleophilic 1 – Unimolecular 2 – Bimolecular r.d.s. – Rate Determine Step

S N 1 Reaction (1) (2) ,[object Object]

S N 1 Reaction ,[object Object],[object Object],[object Object],[object Object],[object Object],X

The Bimolecular (S N 2) Reaction (1) (2) ,[object Object]

S N 2 reaction ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],X

Experiment: Structural Effects Possible S N 1 Products Reactant Possible S N 2 Products S N 1 S N 2

Experiment ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]

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Nucleophilic Substitution Fall 09

1. Nucleophilic Substitution

2. Nucleophilic Substitutions (S N 1, S N 2) of Halides S – Substitution N – Nucleophilic 1 – Unimolecular 2 – Bimolecular r.d.s. – Rate Determine Step

3.

4.

5.

6.

7. Experiment: Structural Effects Possible S N 1 Products Reactant Possible S N 2 Products S N 1 S N 2

8.