Lithium-ion batteries were first proposed in the 1970s but were not successfully created until the mid-1980s. The first commercial lithium-ion battery was launched by Sony in 1991. Lithium-ion batteries use lithium compounds in the anode and a lithium cobalt oxide or lithium iron phosphate cathode. During discharge, lithium ions move from the anode to the cathode and back during charging through an electrolyte. Lithium-ion batteries have a high energy density and output voltage, long cycle life, and are more environmentally friendly than alternatives. However, they are also more expensive and require temperature monitoring and sealing to prevent issues.
A lithium-ion battery (sometimes Li-ion battery or LIB) is a member of a family of rechargeable battery types in which lithium ions move from the negative electrode to the positive electrode during discharge and back when charging. Li-ion batteries use an intercalated lithium compound as one electrode material, compared to the metallic lithium used in a non-rechargeable lithium battery. The electrolyte, which allows for ionic movement, and the two electrodes are the constituent components of a lithium-ion battery cell.
Part 1 of the tutorial on the Lithium Battery Explorer provides an overview of Li-ion battery technology and the properties that are relevant to battery researchers.
Interested viewers should refer to the following publications for more details:
1) Review: G. Ceder, G. Hautier, A. Jain, S. P. Ong. Recharging lithium battery research with first-principles methods. MRS Bulletin, 2011, 36, 185--191.
2) Computational Electrode Assessment: G. Hautier, A. Jain, S. P. Ong, B. Kang, C. Moore, R. Doe, and G. Ceder. Phosphates as Lithium-Ion Battery Cathodes: An Evaluation Based on High-Throughput ab Initio Calculations. Chemistry of Materials, 2011, 23(15), 3495-3508.
3) Predicting Battery Safety: S. P. Ong, A. Jain, G. Hautier, B. Kang, & G. Ceder. Thermal stabilities of delithiated olivine MPO4 (M=Fe, Mn) cathodes investigated using first principles calculations. Electrochemistry Communications, 2010, 12(3), 427--430.
A lithium-ion battery (sometimes Li-ion battery or LIB) is a member of a family of rechargeable battery types in which lithium ions move from the negative electrode to the positive electrode during discharge and back when charging. Li-ion batteries use an intercalated lithium compound as one electrode material, compared to the metallic lithium used in a non-rechargeable lithium battery. The electrolyte, which allows for ionic movement, and the two electrodes are the constituent components of a lithium-ion battery cell.
Part 1 of the tutorial on the Lithium Battery Explorer provides an overview of Li-ion battery technology and the properties that are relevant to battery researchers.
Interested viewers should refer to the following publications for more details:
1) Review: G. Ceder, G. Hautier, A. Jain, S. P. Ong. Recharging lithium battery research with first-principles methods. MRS Bulletin, 2011, 36, 185--191.
2) Computational Electrode Assessment: G. Hautier, A. Jain, S. P. Ong, B. Kang, C. Moore, R. Doe, and G. Ceder. Phosphates as Lithium-Ion Battery Cathodes: An Evaluation Based on High-Throughput ab Initio Calculations. Chemistry of Materials, 2011, 23(15), 3495-3508.
3) Predicting Battery Safety: S. P. Ong, A. Jain, G. Hautier, B. Kang, & G. Ceder. Thermal stabilities of delithiated olivine MPO4 (M=Fe, Mn) cathodes investigated using first principles calculations. Electrochemistry Communications, 2010, 12(3), 427--430.
Status of Rechargeable Li-ion Battery Industry 2019 by Yole DéveloppementYole Developpement
E-mobility continues strongly driving the Li-ion battery demand.
More information on https://www.i-micronews.com/products/status-of-rechargeable-li-ion-battery-industry-2019/
The lithium-ion batteries are first made safe for mechanical treatment, with plastics, aluminum, and copper separated and directed to their own recycling processes. Moreover, the incredible efforts are being made to develop electrode materials, electrolytes, and separators for energy storage devices to meet the needs of emerging technologies such as electric vehicles, decarbonizes electricity, and electrochemical energy storage.
This presentation includes all the information regarding polymer batteries, lithium polymer batteries. Including animations and transitions this PowerPoint presentation is enough for you to understand all about Polymer batteries and cells.
A feasible way towards safer, better-performing batteries?
Conventional Li-ion battery technologies, based on flammable liquid electrolytes, are continuously improving. However, faster progress towards greater safety, higher performance, and better cost reduction is desired. A next-generation battery technology like solid-state battery, which uses solid electrodes and solid electrolytes, could potentially satisfy these objectives.
More information on : https://www.i-micronews.com/batteries-energy-mgmt/product/solid-state-battery.html
Title: Advancements in Electrode Materials for Automotive Batteries: A Comprehensive Review
Abstract:
The automotive industry is rapidly transitioning towards electric propulsion systems to mitigate environmental impacts and reduce dependency on fossil fuels. Central to this shift are advancements in battery technology, particularly in electrode materials, which play a critical role in determining battery performance, energy density, and lifespan. This comprehensive review explores the latest developments in electrode materials for automotive batteries, encompassing lithium-ion, solid-state, and beyond lithium-ion technologies. We delve into the fundamental principles governing electrode material selection, discuss current challenges, and analyze emerging trends such as silicon-based anodes, sulfur cathodes, and solid electrolytes. Through an extensive examination of recent research and commercial developments, we provide insights into the future direction of electrode materials for automotive batteries, highlighting key areas for further research and innovation.
1. Introduction:
- Overview of the importance of electrode materials in automotive batteries
- Transition towards electric vehicles (EVs) and the role of batteries
- Purpose and scope of the review
2. Fundamentals of Battery Electrodes:
- Electrochemical principles underlying battery operation
- Role of electrodes in battery performance
- Requirements for automotive applications: energy density, power density, longevity, and safety
3. Lithium-Ion Batteries:
- Overview of lithium-ion battery architecture
- Current electrode materials: graphite anodes, lithium cobalt oxide (LCO), lithium iron phosphate (LFP), etc.
- Challenges and limitations: capacity degradation, safety concerns, resource availability
- Recent advancements in electrode materials for lithium-ion batteries
4. Beyond Lithium-Ion Batteries:
- Need for higher energy density and sustainability
- Emerging alternatives: lithium-sulfur (Li-S), lithium-air (Li-O2), sodium-ion (Na-ion), potassium-ion (K-ion) batteries
- Electrode materials for non-lithium systems: sulfur cathodes, sodium-ion anodes, etc.
- Comparative analysis of different beyond lithium-ion technologies
5. Silicon-Based Anodes:
- Potential of silicon as a high-capacity anode material
- Challenges: volume expansion, cycling stability, Coulombic efficiency
- Strategies to mitigate silicon anode limitations: nanostructuring, alloying, coatings
- Progress in commercialization and integration into automotive batteries
6. Solid-State Batteries:
- Advantages of solid-state electrolytes over liquid electrolytes
- Materials for solid-state electrolytes: sulfides, oxides, polymers
- Solid-state electrode materials: lithium metal, sulfides, etc.
- Recent breakthroughs in solid-state battery technology and their implications for automotive applications
7. Challenges and Opportunities:
- Scalability
Status of Rechargeable Li-ion Battery Industry 2019 by Yole DéveloppementYole Developpement
E-mobility continues strongly driving the Li-ion battery demand.
More information on https://www.i-micronews.com/products/status-of-rechargeable-li-ion-battery-industry-2019/
The lithium-ion batteries are first made safe for mechanical treatment, with plastics, aluminum, and copper separated and directed to their own recycling processes. Moreover, the incredible efforts are being made to develop electrode materials, electrolytes, and separators for energy storage devices to meet the needs of emerging technologies such as electric vehicles, decarbonizes electricity, and electrochemical energy storage.
This presentation includes all the information regarding polymer batteries, lithium polymer batteries. Including animations and transitions this PowerPoint presentation is enough for you to understand all about Polymer batteries and cells.
A feasible way towards safer, better-performing batteries?
Conventional Li-ion battery technologies, based on flammable liquid electrolytes, are continuously improving. However, faster progress towards greater safety, higher performance, and better cost reduction is desired. A next-generation battery technology like solid-state battery, which uses solid electrodes and solid electrolytes, could potentially satisfy these objectives.
More information on : https://www.i-micronews.com/batteries-energy-mgmt/product/solid-state-battery.html
Title: Advancements in Electrode Materials for Automotive Batteries: A Comprehensive Review
Abstract:
The automotive industry is rapidly transitioning towards electric propulsion systems to mitigate environmental impacts and reduce dependency on fossil fuels. Central to this shift are advancements in battery technology, particularly in electrode materials, which play a critical role in determining battery performance, energy density, and lifespan. This comprehensive review explores the latest developments in electrode materials for automotive batteries, encompassing lithium-ion, solid-state, and beyond lithium-ion technologies. We delve into the fundamental principles governing electrode material selection, discuss current challenges, and analyze emerging trends such as silicon-based anodes, sulfur cathodes, and solid electrolytes. Through an extensive examination of recent research and commercial developments, we provide insights into the future direction of electrode materials for automotive batteries, highlighting key areas for further research and innovation.
1. Introduction:
- Overview of the importance of electrode materials in automotive batteries
- Transition towards electric vehicles (EVs) and the role of batteries
- Purpose and scope of the review
2. Fundamentals of Battery Electrodes:
- Electrochemical principles underlying battery operation
- Role of electrodes in battery performance
- Requirements for automotive applications: energy density, power density, longevity, and safety
3. Lithium-Ion Batteries:
- Overview of lithium-ion battery architecture
- Current electrode materials: graphite anodes, lithium cobalt oxide (LCO), lithium iron phosphate (LFP), etc.
- Challenges and limitations: capacity degradation, safety concerns, resource availability
- Recent advancements in electrode materials for lithium-ion batteries
4. Beyond Lithium-Ion Batteries:
- Need for higher energy density and sustainability
- Emerging alternatives: lithium-sulfur (Li-S), lithium-air (Li-O2), sodium-ion (Na-ion), potassium-ion (K-ion) batteries
- Electrode materials for non-lithium systems: sulfur cathodes, sodium-ion anodes, etc.
- Comparative analysis of different beyond lithium-ion technologies
5. Silicon-Based Anodes:
- Potential of silicon as a high-capacity anode material
- Challenges: volume expansion, cycling stability, Coulombic efficiency
- Strategies to mitigate silicon anode limitations: nanostructuring, alloying, coatings
- Progress in commercialization and integration into automotive batteries
6. Solid-State Batteries:
- Advantages of solid-state electrolytes over liquid electrolytes
- Materials for solid-state electrolytes: sulfides, oxides, polymers
- Solid-state electrode materials: lithium metal, sulfides, etc.
- Recent breakthroughs in solid-state battery technology and their implications for automotive applications
7. Challenges and Opportunities:
- Scalability
Electrolyte Solutions for Rechargeable Li-Ion Batteries Based on Fluorinated ...AMAL THOMAS
High voltage lithium ion batteries have been a focus in the current energy storage research due to their
potential application as high energy density batteries for electric vehicles. With more energy stored in
a system with the same weight and volume, the impact of battery fabrication and its utilization on the
environment will be minimized .Electrolyte solutions based on fluorinated solvents were studied in
high-voltage Li-ion cells using lithium as the anode has a great enhancement over conventional
electrolyte and Li1.2Mn0.56Co0.08Ni0.16O2 as the cathode provides excellent voltage stability on the 5.0
V at both ambient and elevated temperatures. Performance can be reach peak by replacing convectional
alky carbonate solvents in electrolyte solution by fluorinated cosolvents. Fluorinated electrolyte
solution act as a buffering surface film which is highly reactive electrophilic alkyl carbonates, from
continuous detrimental reactions with solution species. Excellent cyclic performance was recorded in
solution containing fluorinated solvents. The extraordinary electrochemical stability of this electrolyte
solution makes it a suitable candidate for other high-voltage cathode materials.
In this presentation we learn basics of how the lithium-ion works and reacts with the environment to produce a unique source of energy storage device called battery.
In this presentation we will deal with:
Introducing Lithium-Ion Battery
It’s Construction
It’s Working
It’s Cell Reactions
It’s Advantages & Disadvantages
It’s Application, etc.
High energy and capacity cathode material for li ion battriesNatraj Hulsure
Recent development in cathode materials for li-ion batteries drag the industries view towards it due to their high discharge rate compare to older ones.
This is the academic presentation by Rahmandhika Firdauzha Hary Hernandha for Materials for Energy Storage and Conversion Device course in National Chiao Tung University, Taiwan. The slides based on an academic paper in Electrochem. Soc. Interface, 2016, 25(3), 85-87 by Stefano Passerini and Bruno Scrosati with other 10 papers as supporting information and images.
A Lithium Ion Capacitor is a hybrid device which combines the intercalation mechanism of a Lithium battery with the [cathode] of an electric double-layer capacitor (EDLC).
Multi-source connectivity as the driver of solar wind variability in the heli...Sérgio Sacani
The ambient solar wind that flls the heliosphere originates from multiple
sources in the solar corona and is highly structured. It is often described
as high-speed, relatively homogeneous, plasma streams from coronal
holes and slow-speed, highly variable, streams whose source regions are
under debate. A key goal of ESA/NASA’s Solar Orbiter mission is to identify
solar wind sources and understand what drives the complexity seen in the
heliosphere. By combining magnetic feld modelling and spectroscopic
techniques with high-resolution observations and measurements, we show
that the solar wind variability detected in situ by Solar Orbiter in March
2022 is driven by spatio-temporal changes in the magnetic connectivity to
multiple sources in the solar atmosphere. The magnetic feld footpoints
connected to the spacecraft moved from the boundaries of a coronal hole
to one active region (12961) and then across to another region (12957). This
is refected in the in situ measurements, which show the transition from fast
to highly Alfvénic then to slow solar wind that is disrupted by the arrival of
a coronal mass ejection. Our results describe solar wind variability at 0.5 au
but are applicable to near-Earth observatories.
Professional air quality monitoring systems provide immediate, on-site data for analysis, compliance, and decision-making.
Monitor common gases, weather parameters, particulates.
Nutraceutical market, scope and growth: Herbal drug technologyLokesh Patil
As consumer awareness of health and wellness rises, the nutraceutical market—which includes goods like functional meals, drinks, and dietary supplements that provide health advantages beyond basic nutrition—is growing significantly. As healthcare expenses rise, the population ages, and people want natural and preventative health solutions more and more, this industry is increasing quickly. Further driving market expansion are product formulation innovations and the use of cutting-edge technology for customized nutrition. With its worldwide reach, the nutraceutical industry is expected to keep growing and provide significant chances for research and investment in a number of categories, including vitamins, minerals, probiotics, and herbal supplements.
Richard's entangled aventures in wonderlandRichard Gill
Since the loophole-free Bell experiments of 2020 and the Nobel prizes in physics of 2022, critics of Bell's work have retreated to the fortress of super-determinism. Now, super-determinism is a derogatory word - it just means "determinism". Palmer, Hance and Hossenfelder argue that quantum mechanics and determinism are not incompatible, using a sophisticated mathematical construction based on a subtle thinning of allowed states and measurements in quantum mechanics, such that what is left appears to make Bell's argument fail, without altering the empirical predictions of quantum mechanics. I think however that it is a smoke screen, and the slogan "lost in math" comes to my mind. I will discuss some other recent disproofs of Bell's theorem using the language of causality based on causal graphs. Causal thinking is also central to law and justice. I will mention surprising connections to my work on serial killer nurse cases, in particular the Dutch case of Lucia de Berk and the current UK case of Lucy Letby.
Seminar of U.V. Spectroscopy by SAMIR PANDASAMIR PANDA
Spectroscopy is a branch of science dealing the study of interaction of electromagnetic radiation with matter.
Ultraviolet-visible spectroscopy refers to absorption spectroscopy or reflect spectroscopy in the UV-VIS spectral region.
Ultraviolet-visible spectroscopy is an analytical method that can measure the amount of light received by the analyte.
2.
Lithium-Ion batteries were
first proposed in the 1970s,
but the technology to
successfully create them
wasn’t invented until the
mid 1980s. The first
commercial Lithium-Ion
(Li-ion) battery was
launched by Sony in late
1991.
2
3.
3
Lithium
Lithium is the lightest of
metal
High capacity of storage
of energy: 370 – 300
Wh/cm3
High electrochemical
reduction potential
Highly reactive material
Spread thermal range
-25˚C_+40˚C
4.
Primary batteries
In primary batteries, the
electrochemical reaction
is not reversible
In lithium batteries, a
pure lithium metallic
element is used as
anode & CFx or MnO2
as cathode
1.5_3.0 V
4
5.
The electrochemical reaction
is reversible
Such cells can be discharged
and recharged many times
4.0 V
Secondary batteries
5
13.
13
Solid Electrolyte Interphase
(SEI)
The layer formed
instantaneously
upon contact of the
electrode with the
solution, consists of
insoluble and
partially soluble
reduction products
of electrolyte
components.
15.
15
Liquid electrolyte
Polar groups such as carbonyl
(C=O), nitrile (C=N), sulfonyl
(S=O), and ether-linkage (-O-)
It should have a high dielectric
constant (ε)
low viscosity (η)
It should remain inert to all cell
components
Its melting point (Tm) should be
low and its boiling point (Tb) high
High flash point (Tf), nontoxic,
and economical
18.
18
Lithium salt
Complete dissociation high conductivity
Oxidative/reductive stability
Thermal stability (high Tdecomposition)
Chemical stability towards all cell components
23.
23
Electrolyte additives
1) Those used for improving the ion conduction
properties in the bulk electrolytes
2) Those used for SEI chemistry modifications
3) Those used for preventing overcharging of the cells
27. 27
Under overcharge
conditions, the voltage of
the cell containing
ferrocene as an additive
leveled off at 3.25 V,
corresponding well to its
redox potential of 3.18 3.50
V, while the reference cell
without additive was
overcharged up to 5.0 V,
corresponding to the
decomposition of THF.
29.
29
Electrolyte Filled Separator
Electrolyte-filled
cathode/separator/
anode stack
A separator based on
polyolefin films
possess sufficient
flexibility, and
limitations on the
geometric shapes of
lithium cells
electrolyte reservoir
35.
35
Advantages of Using
Li-Ion Batteries
POWER – High energy density means greater
power in a smaller package
HIGHER VOLTAGE – a strong current allows it to
power complex mechanical devices
ENVIRONMENTALLY PREFERRED
LONG CYCLE-LIFE – only 5% discharge loss per
month
10% for NiMH, 20% for NiCd
36.
36
Disadvantages of Li-Ion
EXPENSIVE -- 40% more than NiCd
DELICATE -- battery temp must be
monitored from within (which raises the
price), and sealed particularly well
Class 9 miscellaneous hazardous material
LiCoO2 exhaustion
40.
40
Li2B12F12-xHx-based electrolytes possess several
advantages over conventional LiPF6-based
electrolyte.
Graphite/Li1.1[Ni1/3Mn1/3Co1/3]0.9O2 cells using
Li2B12F9H3-based electrolyte, using lithium
difluoro(oxalato)borate as the electrolyte additive
41.
Kang Xu, Chem. Rev. 2004, 104, 4303−4417
Zonghai Chen,
Y. P. Wu, C. Wan, C. Jiang and S. B. Fang, Chemical Industry
Press, Beijing, 2002.
John R. Owen. Chemical Society Reviews, 1997, volume 26,
259.
Mohammad Eftekhari, journal of knowledge of science, 16
(1389).
NATURE COMMUNICATIONS | DOI: 10.1038/ncomms2518
41
References: