This slide stack is a version of an online course looking at Lithium Battery fires. It looks at where you can find Lithium Batteries, why they catch fire, how to fight fires and how to prevent them.
Underwriters Laboratories (UL), a world leader in safety testing and certification released the first in a series of white papers that review evolving battery technology.
This paper explores many of the issues and opportunities associated with the new technology as well as current and recommended safety standards to address changes in the technology and use.
Lithium-ion battery technologies have evolved over the last two decades, with batteries now offering longer cycle life and improved reliability for products in the areas of consumer electronics, medical devices, industrial equipment and automotive applications. In the white paper, UL explains the need for risk assessment as part of the product design and development process to identify and address root causes of safety issues.
Part 1 of the tutorial on the Lithium Battery Explorer provides an overview of Li-ion battery technology and the properties that are relevant to battery researchers.
Interested viewers should refer to the following publications for more details:
1) Review: G. Ceder, G. Hautier, A. Jain, S. P. Ong. Recharging lithium battery research with first-principles methods. MRS Bulletin, 2011, 36, 185--191.
2) Computational Electrode Assessment: G. Hautier, A. Jain, S. P. Ong, B. Kang, C. Moore, R. Doe, and G. Ceder. Phosphates as Lithium-Ion Battery Cathodes: An Evaluation Based on High-Throughput ab Initio Calculations. Chemistry of Materials, 2011, 23(15), 3495-3508.
3) Predicting Battery Safety: S. P. Ong, A. Jain, G. Hautier, B. Kang, & G. Ceder. Thermal stabilities of delithiated olivine MPO4 (M=Fe, Mn) cathodes investigated using first principles calculations. Electrochemistry Communications, 2010, 12(3), 427--430.
A feasible way towards safer, better-performing batteries?
Conventional Li-ion battery technologies, based on flammable liquid electrolytes, are continuously improving. However, faster progress towards greater safety, higher performance, and better cost reduction is desired. A next-generation battery technology like solid-state battery, which uses solid electrodes and solid electrolytes, could potentially satisfy these objectives.
More information on : https://www.i-micronews.com/batteries-energy-mgmt/product/solid-state-battery.html
In this presentation we learn basics of how the lithium-ion works and reacts with the environment to produce a unique source of energy storage device called battery.
In this presentation we will deal with:
Introducing Lithium-Ion Battery
It’s Construction
It’s Working
It’s Cell Reactions
It’s Advantages & Disadvantages
It’s Application, etc.
Underwriters Laboratories (UL), a world leader in safety testing and certification released the first in a series of white papers that review evolving battery technology.
This paper explores many of the issues and opportunities associated with the new technology as well as current and recommended safety standards to address changes in the technology and use.
Lithium-ion battery technologies have evolved over the last two decades, with batteries now offering longer cycle life and improved reliability for products in the areas of consumer electronics, medical devices, industrial equipment and automotive applications. In the white paper, UL explains the need for risk assessment as part of the product design and development process to identify and address root causes of safety issues.
Part 1 of the tutorial on the Lithium Battery Explorer provides an overview of Li-ion battery technology and the properties that are relevant to battery researchers.
Interested viewers should refer to the following publications for more details:
1) Review: G. Ceder, G. Hautier, A. Jain, S. P. Ong. Recharging lithium battery research with first-principles methods. MRS Bulletin, 2011, 36, 185--191.
2) Computational Electrode Assessment: G. Hautier, A. Jain, S. P. Ong, B. Kang, C. Moore, R. Doe, and G. Ceder. Phosphates as Lithium-Ion Battery Cathodes: An Evaluation Based on High-Throughput ab Initio Calculations. Chemistry of Materials, 2011, 23(15), 3495-3508.
3) Predicting Battery Safety: S. P. Ong, A. Jain, G. Hautier, B. Kang, & G. Ceder. Thermal stabilities of delithiated olivine MPO4 (M=Fe, Mn) cathodes investigated using first principles calculations. Electrochemistry Communications, 2010, 12(3), 427--430.
A feasible way towards safer, better-performing batteries?
Conventional Li-ion battery technologies, based on flammable liquid electrolytes, are continuously improving. However, faster progress towards greater safety, higher performance, and better cost reduction is desired. A next-generation battery technology like solid-state battery, which uses solid electrodes and solid electrolytes, could potentially satisfy these objectives.
More information on : https://www.i-micronews.com/batteries-energy-mgmt/product/solid-state-battery.html
In this presentation we learn basics of how the lithium-ion works and reacts with the environment to produce a unique source of energy storage device called battery.
In this presentation we will deal with:
Introducing Lithium-Ion Battery
It’s Construction
It’s Working
It’s Cell Reactions
It’s Advantages & Disadvantages
It’s Application, etc.
A lithium-ion battery (sometimes Li-ion battery or LIB) is a member of a family of rechargeable battery types in which lithium ions move from the negative electrode to the positive electrode during discharge and back when charging. Li-ion batteries use an intercalated lithium compound as one electrode material, compared to the metallic lithium used in a non-rechargeable lithium battery. The electrolyte, which allows for ionic movement, and the two electrodes are the constituent components of a lithium-ion battery cell.
High energy and capacity cathode material for li ion battriesNatraj Hulsure
Recent development in cathode materials for li-ion batteries drag the industries view towards it due to their high discharge rate compare to older ones.
Battery Testing 101 by Megger and TranscatTranscat
In this informative webinar, Andrew Sagl of Megger presents an overview of the various battery testing technologies available as well as how to properly maintain VRLA and VLA batteries.
A brief Seminar Presentation on the Hybrid Electric Vehicle (HEV) Powertrain Components, Architecture and Modes of Hybridisation. Also includes the Classification of HEV on the basis of Energy Flow.
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Shipping Lithium Battery in Safe way - Radharamanan Panicker (DGM India)ELSCC
DGM (Dangerous Goods Management Network) is a leading international organization acknowledged as experts in dangerous goods and hazardous materials.It guarantees global range of services based on regulatory knowledge, confidence and practical experience in compliance with dangerous goods regulations, safety standards and customer requirements.
A lithium-ion battery (sometimes Li-ion battery or LIB) is a member of a family of rechargeable battery types in which lithium ions move from the negative electrode to the positive electrode during discharge and back when charging. Li-ion batteries use an intercalated lithium compound as one electrode material, compared to the metallic lithium used in a non-rechargeable lithium battery. The electrolyte, which allows for ionic movement, and the two electrodes are the constituent components of a lithium-ion battery cell.
High energy and capacity cathode material for li ion battriesNatraj Hulsure
Recent development in cathode materials for li-ion batteries drag the industries view towards it due to their high discharge rate compare to older ones.
Battery Testing 101 by Megger and TranscatTranscat
In this informative webinar, Andrew Sagl of Megger presents an overview of the various battery testing technologies available as well as how to properly maintain VRLA and VLA batteries.
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Presentation on BEV ( Battery Operated Electric Vehicles) Pranav Mistry
Innovation done on BEV ( Battery Operated Electric Vehicles) with best in class miles/charge, Fast charging , Reduced price of maintenance , Suspension based charging etc
Shipping Lithium Battery in Safe way - Radharamanan Panicker (DGM India)ELSCC
DGM (Dangerous Goods Management Network) is a leading international organization acknowledged as experts in dangerous goods and hazardous materials.It guarantees global range of services based on regulatory knowledge, confidence and practical experience in compliance with dangerous goods regulations, safety standards and customer requirements.
If you're designing applications using lithium batteries, it is important to understand the impact of certifications and regulatory requirements so companies are prepared prior to entering their product to market.
In this webinar as we discuss the new UN 38.3 testing requirements and the recent IATA regulations changes required for lithium batteries. We will also review the challenges OEM's may face with the regulation changes.
To learn more about our custom battery pack solutions visit http://www.epectec.com/batteries/
Presentation from the New Mexico Regional Energy Storage and Grid Integration Workshop: Storage at the Threshold - Beyond Lithium-ion Batteries, presented by George Crabtree, Director, JCESR, Argonne National Laboratory, August 23-24.
Silicon is of great interest for use as the anode material in lithium-ion batteries due to its high
capacity. However, certain properties of silicon, such as a large volume expansion during the
lithiation process and the low diffusion rate of lithium in silicon, result in fast capacity
degradation in limited charge/discharge cycles, especially at high current rate. Therefore, the
use of silicon in real battery applications is limited. The idea of using porous silicon, to a large
extent, addresses the above-mentioned issues simultaneously. In this review, we discuss the
merits of using porous silicon for anodes through both theoretical and experimental study.
Recent progress in the preparation of porous silicon through the template-assisted approach
and the non-template approach have been highlighted. The battery performance in terms of
capacity and cyclability of each structure is evaluated.
Basic awareness for the transport of lithium batteries by air, this introduction will get you started.
For assistance and to organise a lithium battery seminar for your personnel or clients or to book training on the safe transport of lithium batteries by air, visit www.professionaltraining.co.za
This presentation was prepared for the 2015 Benchmark Minerals Intelligence Battery Raw Materials | Supply Chain 20/20 World Tour and was presented in NYC and Toronto by CEO Paul Gorman.
DOT and IATA regulations must be followed while shipping lithium batteries. These 5 crucial factors can be used to comply with the DOT HMR criteria and the IATA Dangerous Goods Regulations when shippers and carriers transport lithium metal and lithium ion batteries via highway (road), rail, air (aircraft), and water (vessel).
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A beginner's guide to drone batteries can help you make the most of your drone. By understanding how batteries work and how to care for them, you can extend the life of your drone and keep it flying smoothly.
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3. Introduction
Lithium Batteries have become common in modern day life.
They are in your laptop, mobile phone, tablet computer, camera etc.
They give thousands of hours of reliable service and for power to weight they
are difficult to beat.
Unfortunately they have a problem…….
This presentation is based on information from the ICAO, the UK CAA & FAA
5. We will cover the following subjects:
What are Lithium Batteries ?
Where Lithium Batteries are
Why they catch fire !
Preventing fires
Fighting fires
Conclusions
7. What are Lithium Batteries
Lithium Batteries are a family of batteries that use the chemical Lithium as
metal or Lithium compounds.
They are chosen for the high energy to density capacity, that is they can store
large amounts of energy for their size.
They also have high discharge capacity in that they can provide very high
current for short periods.
8. Portable Electronic Devices (PED)
2 main types of Lithium battery;
Both types can catch fire.
Lithium – Disposable.
Lithium Ion – Rechargeable.
9. Lithium Batteries are most often found as:
Single Cells – used in consumer items.
Or
Battery Packs – found in larger items like laptops.
Or
Conformal Batteries – found in some tablets & phones
10. Difference between a Cell & a Battery
We have been using the words cell and battery to describe batteries, so what is
the difference.
We should call a distinct
unit a battery cell as with
this picture.
This is one cell, and as it is
by itself then it is also
known as a battery.
11. Difference between a Cell & a Battery
We have been using the words cell and battery to describe batteries, so what is
the difference.
So a cell is a self contained battery.
As we have seen some batteries, especially larger
ones, are made up of a number of smaller
batteries to make up the larger capacity battery,
these individual batteries are called cells, and the
container it is in is called the battery.
12. Difference between a Cell & a Battery
A larger battery made up of many cells is
called a battery, the individual batteries
it contains are called cells.
So if a battery is only made up
of one distinct cell it can be
called a battery cell or just cell
or just battery.
Clear as Mud!!!
13. PEDs
Many of the items you carry around (known as
Personal Electronic Devices or PED’s in the
industry) have Lithium Batteries in them.
18. Why do they catch Fire ?
Lithium Battery Fires
19. Why they catch fire !
There are Four main reasons for Lithium Batteries catching fire;
• Manufacture defect.
• Damage
• Rapid charging.
• Rapid discharge.
20. Damage to Packages
It is unusual for batteries to overheat and
catch fire unless they are damaged.
21. Thermal Runaway
Increased
Current
Fire is caused by something called
"Thermal Runaway" this is where
increased current causes increased
chemical reaction rate in the lithium.
Increased
Chemical
Reaction
25. Thermal Runaway
Internal temperature
reaches 130oC
Heat
Increased
Current
Increased
Chemical
Reaction
Normally when a battery reaches an
internal temperature of around 130
degrees centigrade, this loop becomes
self sustaining – this is known as Thermal
Runaway.
Some of the heat is
naturally given off but
not quick enough to
reduce the rate.
27. Single Cells
AA size cells have very small amounts of Lithium and should burn out in
around 1 minute.
Battery will spray molten Lithium as they burn.
This can spread the fire.
28. Lithium Ion Cells
Battery Packs are used in larger PEDs, especially laptops.
The packs are normally made up of individual cells but you cannot see them
as they are encased in plastic.
29. Lithium Ion Cells
Heat in battery packs spreads from cell to cell, each one running away and
spreading to the next cell.
31. Understand where Lithium Batteries are!
First line of defence is to know where the batteries can be found.
Lithium Batteries can be found in many everyday items, including:
Photographic & Film Equipment
Building equipment (cordless equipment)
Scuba equipment (Lights)
Models (Aircraft / Cars / Boats)
Oxygen concentrators
Medical equipment
PED’s
32. Overheating
One of the reasons the batteries catch fire is due to overheating!
Don’t put your phone or tablet
computer somewhere that it is not
ventilated.
This can cause thermal runaway and cause it to catch fire!!!!
Don’t put it under your pillow!!!
33. Damaged Batteries
If you drop or damage a PED be very aware that on
rare occasions it could catch fire.
Keep it in a place where you can monitor it.
34. Damage to containers
Most battery fires can be
traced back to damage to the
package that the batteries
were stored in.
35. E Cigarettes
There have been cases of eCigarettes catching
fire due to being charged with incorrect
chargers.
Always use the charger that came with your
device.
36. Precautions
• Buy batteries from reputable sources and only use batteries approved for
your device - avoid counterfeits!
• Look for the mark of an independent testing or standards organization,
such as Underwriters Laboratories (UL) or International Electrotechnical
Commission (IEC).
• Do not carry recalled or damaged batteries on aircraft. Check battery
recall information at the manufacturer's website.
• Only charge batteries which you are sure are rechargeable! Non-
rechargeable batteries are not designed for recharging, and become
hazardous if placed in a battery charger. A non-rechargeable battery
placed in a charger may overheat or cause damage later.
• Only use a charger compatible with your rechargeable battery - don't mix
and match!
37. Precautions
• If original packaging is not available for spare batteries, effectively
insulate battery terminals by isolating the batteries from contact with
other batteries and metal.
• Place each battery in its own protective case, plastic bag, or package, or
place tape across the battery's contacts to isolate terminals. Isolating
terminals prevents short-circuiting.
• Take steps to prevent crushing, puncturing, or putting a high degree of
pressure on the battery, as this can cause an internal short-circuit,
resulting in overheating.
• If you must carry a battery-powered device in any baggage, package it to
prevent inadvertent activation.
38. Lithium Batteries Carried in Equipment
Batteries that are carried in equipment must be protected from inadvertent
activation.
Use trigger lock or tape switch in the OFF
position.
40. Spare Batteries
When transporting spare lithium batteries they should be in the original
packaging or if this is not possible then the exposed terminals must be insulated,
for example the terminals are tapped over or placed into separate plastic bags.
When transporting them by air they must not be put in the baggage that is
checked in but they can be carried in your hand baggage provided that they are
between 100Wh and 160Wh and no more than 2 batteries person. The rules state
that the total number of spares carried must be reasonable.
It is best that you check with the check in staff.
All must be in Carry on baggage NOT hold baggage.
41. Batteries in Baggage
Remember batteries must not be packed in baggage you are going to check
in. They can, in small quantities, be carried in carry on baggage.
Carry On Bag Checked In Bag
42. Larger Quantities
For larger quantities of cells these must be carried via the Dangerous Goods
system.
Lithium Batteries must not be carried as freight in passenger carrying
aircraft, to or from the USA.
44. Transporting Lithium Batteries by Road
No special requirements required if only carrying 4 cells or 2 batteries.
If transporting larger quantities then you must meet the requirements of:
• The 2011 edition of the ADR in ADR affiliated countries (i.e. Europe): Special
Provision 188
• Any relevant local legislation in non ADR countries (i.e. Rest of the World)
46. Transport by Sea
No special requirements if only carrying 4 cells or 2 batteries.
If carrying larger quantities then you need to
comply with the 2010 edition of the IMDG
Code: Special Provision 188
47. Lithium Batteries in the Post
And what about sending Lithium Batteries in the Post?
48. Lithium Batteries in the Post
In the UK the following are NOT allowed in International mail.
Lithium Ion / Polymer / Metal / Alloy batteries sent on their own or sent with
but not connected to a device such as a mobile phone, MP3 player or digital
camera.
Check with your local postal provider,
what is allowed in the post.
49. Allowed in the Mail
The following ARE allowed in the International mail:
Electronic devices containing Lithium batteries.
Only when the battery is connected to the device.
The package must not contain more than four cells or two batteries
connected to a device.
For Lithium Ion / Lithium Polymer batteries then the Watt hour rating must
not exceed 20Wh per cell or 100Wh per battery.
For Lithium Metal / Lithium Alloy batteries then the Lithium content must not
exceed 1g per cell or 2g per battery.
50. Sending by Courier
All couriers must comply with
the Dangerous Goods
Regulations the IMDG code or
the ADR, or the local
equivalents, dependent on the
mode of transport being used.
Some couriers are more
restrictive.
Contact the courier to find out
what the requirements are.
53. Thermal Runaway
Internal temperature
reaches 130oC
Heat
Increased
Current
Increased
Chemical
Reaction
Remember that the fire
will be caused by Thermal
runaway, our priorities
are to fight the fire and
then cool the battery.
54. Steps in Fighting a Lithium Battery Fire
1. Raise the Alarm
2. Move People away from the Fire
3. Remove power – if possible
4. Fight the fire
5. Cool the battery
55. Raise the Alarm
Set off the Fire Alarm.
Or
Call the Emergency Services
Shout loudly to warn other people.
The most important thing is the
preservation of Life !!!
58. If Safe to do so – Fight the Fire
Choose your Fire Extinguisher
or
Puts out the fire.
No Danger of Electrocution.
Does not cool the batteries.
Danger of Electrocution if
item is still plugged into the
power supply.
Cools the batteries.
Puts out the fire.
59. If Safe to do so – Fight the Fire
Choose your Fire Extinguisher
or
Puts out the fire.
No Danger of Electrocution.
Insulates the batteries.
Puts out the fire.
No Danger of Electrocution.
Insulates the batteries.
60. If Safe to do so – Fight the Fire
Choose your Fire Extinguisher
or
Puts out the fire.
No Danger of Electrocution.
Insulates the batteries.
Puts out the fire.
No Danger of Electrocution.
Insulates the batteries.
If these extinguishers are used you MUST cool the batteries immediately the fire is
extinguished.
61. Make sure the fire does not start again!
Once the fire is out – the emergency is not over!
Because the fire was caused by thermal runaway of a chemical reaction, the fire
will start again if we do not cool the battery.
62. Cool the Battery
• Dry Ice
• Ice
• Alcoholic Drinks
• Soft Drinks
• Water
• Non-Flammable Liquids.
We need to cool the battery cells, take a
moment to think which of the following items
can be used to cool the cells.
?
63. Use non Flammable Liquids
• Dry Ice
• Ice
• Alcoholic Drinks
• Soft Drinks
• Water
• Non-Flammable Liquids.
WARNING:
Do not try to cool the device with ice.
64. Do Not Use Ice
Ice insulates the battery and can cause a build up of heat.
Ice can cause the battery to explode!
65. Warnings
WARNING:
Do not attempt to pick up and move a
smoking or burning device.
WARNING:
Do not cover the device.
WARNING:
Do not try to cool the device with ice.
WARNING:
Do not put in burn bag.
66. Warning
Lithium Batteries are integral to the
device when in use.
This is not a Lithium Battery
This is a power supply
Treat as a normal electrical fire!
68. Conclusions
Lithium Batteries are very common in everyday items.
Lithium Battery Fires are rare but do happen.
The fire is caused by Thermal Runaway.
Thermal runaway is caused by;
• Manufacturers fault.
• Damage.
• Over Charging (Fault with charger).
• Over Discharging (Fault with PED).
69. Conclusions
Fight a Lithium Battery Fire By;
• Raise the Alarm.
• Clear people from the area.
• Remove power (if applicable).
• Extinguish fire using CO2 or Water Fire Extinguishers.
• Cool cells using non-alcoholic fluids.
70. Warnings
WARNING:
Do not attempt to pick up and move a
smoking or burning device.
WARNING:
Do not cover the device.
WARNING:
Do not try to cool the device with ice.
WARNING:
Do not put in burn bag.
71. Certificate
Want a certificate for taking this course?
To get a certificate, you need to take the exam, the exam can be found
at:
http://lbf.aviationtrain.com
Note: to access the exam you will need to log into the Learning Management System.
Any details captured by the system will not be used for anything but the recording and printing of your certificate.
Versions of this course are also available as online training for Airline Crew &
Staff, visit the website above for details.
72. FAA Video
The FAA has a very good video that is available on YouTube
Click on the link below to view the FAA video.
www.youtube.com/watch?v=gcd34tt8YPU
The video is 10 min 41 seconds but is worth watching.
73. Course Developer
This PowerPoint presentation was brought to you by www.aviationtrain.com
Providers of eLearning for Aviation and other industries.
For PowerPoint or online versions of this course then please contact us at
contact@aviationtrain.com
Welcome to this short course on Fires involving Lithium Batteries. The procedures in this course are for guidance only and are obtained from best practices, however when your company has a procedure for such an emergency then the companies procedures must be followed in preference to what is presented in this course.
The procedures in this course are for guidance only and are obtained from best practices, however when your company has a procedure for such an emergency then the companies procedures must be followed in preference to what is presented in this course.
Lithium batteries have become very common in modern day life, they are in your laptop, mobile telephone, tablet computer, camera and so on. They give thousands of hours of reliable service and for power to weight ratio they are very difficult to beat, but unfortunately they have a problem.
They can Catch Fire!!
We will cover the following subjects:
What are Lithium Batteries
Where Lithium Batteries are
Why they catch fire
Preventing fires
Fighting fires
Conclusions
Before we look at the reasons for the the fires and how to tackle them, we will look at what Lithium batteries are and what items contain them.
So what are Lithium batteries? Lithium batteries are a family of batteries that use the chemical Lithium as metal or in compounds. They are chosen for the high energy to density capacity, that is they can store large amounts of energy for their size.They also have high discharge capacity in that they can provide very high current for short periods.
The two most common types of Lithium batteries are disposable batteries and rechargeable battery packs, both types of battery can catch fire.
Lithium Batteries are most often found as:
Single Cells – used in consumer items.
Or
Battery Packs – found in larger items like laptops.
Or
Conformal Batteries – found in some tablets & phones
We have been using the words cell and battery to describe batteries, so what is the difference.
We should call a distinct unit a battery cell as with this picture.
This is one cell, and as it is by itself then it is also known as a battery.
We have been using the words cell and battery to describe batteries, so what is the difference.
So a cell is a self contained battery.
As we have seen some batteries, especially larger ones, are made up of a number of smaller batteries to make up the larger capacity battery, these individual batteries are called cells, and the container it is in is called the battery.
So if a battery is only made up of one distinct cell it can be called a battery cell or just cell or just battery.
A larger battery made up of many cells is called a battery, the individual batteries it contains are called cells.
Lithium batteries can be found in many personal electronic devices, also known as PED's, some examples are shown here.
They have many larger uses, including bicycles and electric cars.
One of the most common large capacity lithium battery packs are those in laptop computers.
Most eCigarettes contain Lithium Batteries.
They are moved around the world to manufacturers of PEDs and for other industrial uses. Often by airfreight!
We have seen where Lithium batteries are so we will now look at why they catch fire.
So why do Lithium batteries catch fire? There are four main reasons, these are Manufacturing faults, where small amounts of metal lithium have contaminated the layers of the batteries and cause local short circuits which concentrate current and cause heating. Because of damage to the battery in use, by being dropped, or punctured or some other way. From rapid charging which is normally a fault with the charger and finally by rapid discharging, but this last one is normally caused by damage to the batteries.
It is unusual for a battery to catch fire unless it has been damaged in some way.
Fire is caused by something called "Thermal Runaway" this is where increased current causes increased chemical reaction rate in the lithium, these chemical reactions cause increased heat which in turn causes increased current, that causes increased reaction rate that causes increased heat and so on, this normally occurs when the internal temperature of the battery reaches 130 degrees centigrade. Some of the heat is naturally given off but not quick enough to reduce the rate.
These chemical reactions cause increased heat which in turn causes increased current, that causes increased reaction rate that causes increased heat and so on, this normally occurs when the internal temperature of the battery reaches 130 degrees centigrade. Some of the heat is naturally given off but not quick enough to reduce the rate.
Fire is caused by something called "Thermal Runaway" this is where increased current causes increased chemical reaction rate in the lithium, these chemical reactions cause increased heat which in turn causes increased current, that causes increased reaction rate that causes increased heat and so on, this normally occurs when the internal temperature of the battery reaches 130 degrees centigrade. Some of the heat is naturally given off but not quick enough to reduce the rate.
Fire is caused by something called "Thermal Runaway" this is where increased current causes increased chemical reaction rate in the lithium, these chemical reactions cause increased heat which in turn causes increased current, that causes increased reaction rate that causes increased heat and so on, this normally occurs when the internal temperature of the battery reaches 130 degrees centigrade. Some of the heat is naturally given off but not quick enough to reduce the rate.
Fire is caused by something called "Thermal Runaway" this is where increased current causes increased chemical reaction rate in the lithium, these chemical reactions cause increased heat which in turn causes increased current, that causes increased reaction rate that causes increased heat and so on, this normally occurs when the internal temperature of the battery reaches 130 degrees centigrade. Some of the heat is naturally given off but not quick enough to reduce the rate.
Eventually the thermal runaway causes the battery to catch fire!
Single cells, either disposable or rechargeable found in items like cameras have very small amounts of lithium in them and should burn out in about one minute, however they will spray molten lithium as they burn, this molten lithium can spread the fire to the surroundings or to adjacent batteries.
Battery packs used in larger PEDs, especially laptops consist of individual cells but you cannot see them as they are encased in plastic.
Heat in battery packs spreads from cell to cell, each one running away and spreading to the next cell.
Preventing fires
First line of defence is to know where the batteries can be found.
Lithium Batteries can be found in many everyday items, including:
Photographic & Film Equipment
Building equipment (cordless equipment)
Scuba equipment (Lights)
Models (Aircraft / Cars / Boats)
Oxygen concentrators
Medical equipment
PED’s
One of the reasons the batteries catch fire is due to overheating!
Don’t put your phone or tablet computer somewhere that it is not ventilated.
This can cause thermal runaway and cause it to catch fire!!!!
Don’t put it under your pillow!!!
If you drop or damage a PED be very aware that on rare occasions it could catch fire.
Keep it in a place where you can monitor it.
Most battery fires can be traced back to damage to the package that the batteries were stored in.
There have been cases of eCigarettes catching fire due to being charged with incorrect chargers.
Always use the charger that came with your device.
Buy batteries from reputable sources and only use batteries approved for your device - avoid counterfeits!
Look for the mark of an independent testing or standards organization, such as Underwriters Laboratories (UL) or International Electrotechnical Commission (IEC).
Do not carry recalled or damaged batteries on aircraft. Check battery recall information at the manufacturer's website.
Only charge batteries which you are sure are rechargeable! Non-rechargeable batteries are not designed for recharging, and become hazardous if placed in a battery charger. A non-rechargeable battery placed in a charger may overheat or cause damage later.
Only use a charger compatible with your rechargeable battery - don't mix and match!
If original packaging is not available for spare batteries, effectively insulate battery terminals by isolating the batteries from contact with other batteries and metal.
Place each battery in its own protective case, plastic bag, or package, or place tape across the battery's contacts to isolate terminals. Isolating terminals prevents short-circuiting.
Take steps to prevent crushing, puncturing, or putting a high degree of pressure on the battery, as this can cause an internal short-circuit, resulting in overheating.
If you must carry a battery-powered device in any baggage, package it to prevent inadvertent activation.
Batteries that are carried in equipment must be protected from inadvertent activation.
Use trigger lock or tape switch in the OFF position.
We will now look at carrying Lithium Batteries on-board aircraft.
When transporting spare lithium batteries they should be in the original packaging or if this is not possible then the exposed terminals must be insulated, for example the terminals are tapped over or placed into separate plastic bags.
When transporting them by air they must not be put in the baggage that is checked in but they can be carried in your hand baggage provided that they are between 100Wh and 160Wh and no more than 2 batteries person. The rules state that the total number of spares carried must be reasonable.
It is best that you check with the check in staff.
Remember batteries must not be packed in baggage you are going to check in. They can, in small quantities, be carried in carry on baggage.
For larger quantities of cells these must be carried via the Dangerous Goods system.
Lithium Batteries must not be carried as freight in passenger carrying aircraft, to or from the USA.
And now about carrying them in road vehicles.
No special requirements required if only carrying 4 cells or 2 batteries.
If transporting larger quantities then you must meet the requirements of:
The 2011 edition of the ADR in ADR affiliated countries (i.e. Europe): Special Provision 188
Any relevant local legislation in non ADR countries (i.e. Rest of the World)
And now carrying the batteries by sea.
No special requirements if only carrying 4 cells or 2 batteries.
If carrying larger quantities then you need to comply with the 2010 edition of the IMDG Code: Special Provision 188
And what about sending Lithium Batteries in the Post?
In the UK the following are NOT allowed in International mail.
Lithium Ion / Polymer / Metal / Alloy batteries sent on their own or sent with but not connected to a device such as a mobile phone, MP3 player or digital camera.
Check with your local postal provider, what is allowed in the post.
The following ARE allowed in the International mail:
Electronic devices containing Lithium batteries.
Only when the battery is connected to the device.
The package must not contain more than four cells or two batteries connected to a device.
For Lithium Ion / Lithium Polymer batteries then the Watt hour rating must not exceed 20Wh per cell or 100Wh per battery.
For Lithium Metal / Lithium Alloy batteries then the Lithium content must not exceed 1g per cell or 2g per battery.
All couriers must comply with the Dangerous Goods Regulations the IMDG code or the ADR, or the local equivalents, dependent on the mode of transport being used.
Some couriers are more restrictive.
Contact the courier to find out what the requirements are.
So we have looked at why the batteries catch fire but now we need to look at how to fight them in the rare occasions that they do.
What are you going to do ?
Remember that the fire will be caused by Thermal runaway, our priorities are to fight the fire and then cool the battery.
We will now look at the steps in fighting a Lithium Battery Fire
Raise the Alarm
Move People away from the Fire
Remove power – if possible
Fight the fire
Cool the battery
Set off the Fire Alarm.
Or
Call the Emergency Services
Shout loudly to warn other people.
The most important thing is the preservation of Life !!!
Move people away from the fire.
If possible, unplug the power.
Choose your Fire Extinguisher
CO2 or Water Fire Extinguishers
The advantages of the CO2 are that it puts out the fire and there is no danger of electrocution but the disadvantage is that it does not cool the batteries.
The advantages of the Water extinguisher is that it also puts out the fire and it also cools the batteries, but the major disadvantage is that there is a danger of electrocution it the item is still plugged into the power supply.
Choose your Fire Extinguisher
Foam or Powder Fire Extinguishers
The advantages of the Foam is that it puts out the fire and there is no danger of electrocution but the disadvantage is that it does not cool the batteries, in fact it insulates them.
The advantages of the Powder is that it puts out the fire and there is no danger of electrocution but the disadvantage is that it does not cool the batteries, in fact it insulates them.
If these extinguishers are used you MUST cool the batteries immediately the fire is extinguished.
Make sure the fire does not start again!
Once the fire is out – the emergency is not over!
Because the fire was caused by thermal runaway of a chemical reaction, the fire will start again if we do not cool the battery.
We need to cool the battery cells, take a moment to think which of the following items can be used to cool the cells.
Dry Ice
Ice
Alcoholic Drinks
Soft Drinks
Water
Non-Flammable Liquids.
You must use liquids that will not feed a fire – non-flammable liquids.
WARNING:
Do not try to cool the device with ice.
Do not use ice
Ice insulates the battery and can cause a build up of heat.
Ice can cause the battery to explode!
WARNING:
Do not attempt to pick up and move a smoking or burning device.
WARNING:
Do not cover the device.
WARNING:
Do not put in burn bag.
WARNING:
Do not try to cool the device with ice.
Lithium Batteries are integral to the device when in use.
This is not a Lithium Battery
This is a power supply
Treat as a normal electrical fire!
We will now look at Precautions & Conclusions
Lithium Batteries are very common on aircraft in PED’s& Cargo .
Lithium Battery Fires are rare but do happen.
The fire is caused by Thermal Runaway
Thermal runaway is caused by;
Manufacturers fault.
Damage.
Over Charging (Fault with charger).
Over Discharging (Fault with PED).
Fight a Lithium Battery Fire By;
Raise the Alarm.
Clear people from the area.
Remove power (if applicable).
Extinguish fire using CO2 or Water Fire Extinguishers.
Cool cells using non-alcoholic fluids.
WARNING:
Do not attempt to pick up and move a smoking or burning device.
WARNING:
Do not cover the device.
WARNING:
Do not put in burn bag.
WARNING:
Do not try to cool the device with ice.
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