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Abbas Al-Bawee 2022
Introduction to Physics of Semiconductors
1
Basic Physics of Semiconductors
 2.1 Semiconductor materials and their properties
 2.2 PN-junction diodes
 2.3 Reverse Breakdown
Semiconductor Physics

Semiconductor devices serve as heart of microelectronics.

PN junction is the most fundamentalsemiconductor
device.
CH2 Basic Physics of Semiconductors 3
Charge Carriers in Semiconductor

To understand PN junction’s IV characteristics, it is
important to understand charge carriers’ behavior in solids,
how to modify carrier densities, and different mechanisms
of charge flow.
CH2 Basic Physics of Semiconductors 4
Periodic Table
 This abridged table contains elements with three to five
valence electrons, with Si being the most important.
CH2 Basic Physics of Semiconductors 5
Silicon
 Si has four valence electrons. Therefore, it can form
covalent bonds with four of its neighbors.
 When temperature goes up, electrons in the covalent bond can
become free.
CH2 Basic Physics of Semiconductors 6
Electron-Hole Pair Interaction

With free electrons breaking off covalent bonds, holes are
generated.

Holes can be filled by absorbing other free electrons, so
effectively there is a flow of charge carriers.
CH2 Basic Physics of Semiconductors 7
Free Electron Density at a Given Temperature
CH2 Basic Physics of Semiconductors 8
 Eg, or bandgap energy determines how much effort is
needed to break off an electron from its covalent bond.
 There exists an exponential relationship between the free-
electron density and bandgap energy.
3
10
0
15
3/2
exp
electrons/ cm
2kT
i
i
g
3
i
6000
K ) 1.541015
electrons/ cm3
n (T 
n (T  300
K ) 1.0810
electrons/ cm

E
n
 5.210
T
Doping (N type)
 Pure Si can be doped with other elements to change its
electrical properties.
 For example, if Si is doped with P (phosphorous), thenit
has more electrons, or becomes type N (electron).
CH2 Basic Physics of Semiconductors 9
Doping (P type)
 If Si is doped with B (boron), then it has more holes,or
becomes type P.
CH2 Basic Physics of Semiconductors 10
Summary of Charge Carriers
CH2 Basic Physics of Semiconductors 11
Electron and Hole Densities
CH2 Basic Physics of Semiconductors 12
 The product of electron and hole densities is ALWAYS
equal to the square of intrinsic electron density regardless
of doping levels.
2
i
np  n
n 2
p  i
ND
p  NA
n  i
NA
n  ND
n 2
Majority Carriers :
Minority Carriers :
Majority Carriers :
Minority Carriers :
First Charge Transportation Mechanism: Drift
 The process in which charge particles move because of an
electric field is called drift.
 Charge particles will move at a velocity that is proportional
to the electric field.



ve  n E

vh   p E
CH2 Basic Physics of Semiconductors 13
Current Flow: General Case
 Electric current is calculated as the amount of charge in v
meters that passes thru a cross-section if the charge travel
with a velocity of v m/s.
I  vW hnq
CH2 Basic Physics of Semiconductors 14
Jtot
CH2 Basic Physics of Semiconductors 15
 n E  n  q  p E  p  q
 q(n n  p p)E
Jn  n E  n  q
Current Flow:
Drift

Since velocity is equal to E, drift characteristic is obtained
by substituting V with E in the general current equation.

The total current density consists of both electrons and
holes.
Velocity Saturation

A topic treated in more advanced courses is velocity
saturation.

In reality, velocity does not increase linearly with electric
field.
It will eventually saturate to a critical value.
E
b
v
vsat
sat
0
1
0 E
v


0
0
1 bE
 
CH2 Basic Physics of Semiconductors 16
Second Charge Transportation Mechanism:
Diffusion

Charge particles move from a region of high concentration
to a region of low concentration.
It is analogous to an every
day example of an ink droplet in water.
CH2 Basic Physics of Semiconductors 17
Current Flow: Diffusion

Diffusion current is proportional to the gradient of charge
(dn/dx) along the direction of current flow.

Its total current density consists of both electrons and
holes.
n
dx
n
n
dx
J
 qD
dn
I  AqD
dn
n
dx
p
dx
CH2 Basic Physics of Semiconductors 18
tot
p
dx
p
J
 q(D
dn
 D
dp
)
J
 qD
dp
Example: Linear vs. Nonlinear Charge Density
Profile

Linear charge density profile means constant diffusion
current, whereas nonlinear charge density profile means
varying diffusion current.
n
n
d
d
n n
dx
L
dx
L
L
J
 qD
dn
 qD

N
J  qD
dn

 qDn N
exp
 x
CH2 Basic Physics of Semiconductors 19
Einstein's Relation

While the underlying physics behind drift and diffusion
currents are totally different, Einstein’s relation provides a
mysterious link between the two.
D

kT

q
CH2 Basic Physics of Semiconductors 20
PN Junction (Diode)

When N-type and P-type dopants are introduced side-by-
side in a semiconductor, a PN junction or a diode is formed.
CH2 Basic Physics of Semiconductors 21
Diode’s Three Operation Regions

In order to understand the operation of a diode, it is
necessary to study its three operation regions:
equilibrium,
reverse bias, and forward bias.
CH2 Basic Physics of Semiconductors 22
Current Flow Across Junction: Diffusion
CH2 Basic Physics of Semiconductors 23

Because each side of the junction contains an excess of
holes or electrons compared to the other side, there exists
a large concentration gradient.
Therefore, a diffusion
current flows across the junction from each side.
Depletion Region

As free electrons and holes diffuse across the junction, a
region of fixed ions is left behind.
This region is known as
the “depletion region.”
CH2 Basic Physics of Semiconductors 24
Current Flow Across Junction: Drift

The fixed ions in depletion region create an electricfield
that results in a drift current.
CH2 Basic Physics of Semiconductors 25
Current Flow Across Junction: Equilibrium

At equilibrium, the drift current flowing in one direction
cancels out the diffusion current flowing in the opposite
direction, creating a net current of zero.

The figure shows the charge profile of the PN junction.
Idrift , p Idiff , p
Idrift ,n  Idiff ,n
CH2 Basic Physics of Semiconductors 26
Built-in Potential

Because of the electric field across the junction, there
exists a built-in potential.
Its derivation is shown above.

p
x
p 
p
pp
p
pn
dp
dV D
p
dx
2
x1

q pE  qD
dp
p
p
D
pp
dx
p
dx
p
pn
V(x2 ) V (x1) 
ln


p
dV
 D
dp
0
CH2 Basic Physics of Semiconductors 27
0
i
A
D
n
p
n 2
q
kT
N
N
p
q
p
kT
,V

ln
V

ln
Diode in Reverse Bias

When the N-type region of a diode is connected to a higher
potential than the P-type region, the diode is under reverse
bias, which results in wider depletion region and larger
built-in electric field across the junction.
CH2 Basic Physics of Semiconductors 28
Reverse Biased Diode’s Application: Voltage-
Dependent Capacitor

The PN junction can be viewed as a capacitor.
By varying
VR, the depletion width changes, changing its capacitance
value; therefore, the PN junction is actually a voltage-
dependent capacitor.
CH2 Basic Physics of Semiconductors 29
Voltage-Dependent Capacitance

The equations that describe the voltage-dependent
capacitance are shown above.
V
D
0
A
j0
Cj 0
j
2
N
 N
V
C

C

1 R
V0
siq
NA ND
1
CH2 Basic Physics of Semiconductors 30
Voltage-Controlled Oscillator

A very important application of a reverse-biased PN
junction is VCO, in which an LC tank is used in an
oscillator.
By changing VR, we can change C, whichalso
changes the oscillation frequency.
fres
2
LC

1 1
CH2 Basic Physics of Semiconductors 31
Diode in Forward Bias

When the N-type region of a diode is at a lower potential
than the P-type region, the diode is in forward bias.

The depletion width is shortened and the built-inelectric
field decreased.
CH2 Basic Physics of Semiconductors 32
Minority Carrier Profile in Forward Bias

Under forward bias, minority carriers in each region
increase due to the lowering of built-in field/potential.
Therefore, diffusion currents
increase to supply these
minority carriers.
VT
V
V
p

pp, f
n, f
exp 0
F
VT
CH2 Basic Physics of Semiconductors 33
V
pp,e
n,e
exp 0
p

Diffusion Current in Forward Bias

Diffusion current will increase in order to supply the
increase in minority carriers.
The mathematics are shown
above.
exp 0 T
p
V
VT
V
ND
n

exp 0 T
n
V
(exp
VF
1)
VT
V
NA
(exp
VF
1)
p

2
D
p
A
n
n
i
s
D
N
L
N
L
D
p
)
I
 Aqn
(
1)
T
V
V
Itot  Is (exp
exp 0
CH2 Basic Physics of Semiconductors 34
exp 0
1)
T
T
tot
V
(exp
VF
1)
VT
V
ND
V
(exp
VF
VT
F
V
NA
I

Minority Charge Gradient

Minority charge profile should not be constant along thex-
axis; otherwise, there is no concentration gradient and no
diffusion current.

Recombination of the minority carriers with the majority
carriers accounts for the dropping of minority carriers as
they go deep into the P or N region.
CH2 Basic Physics of Semiconductors 35
Forward Bias Condition: Summary

In forward bias, there are large diffusion currents of
minority carriers through the junction.
However, as we go
deep into the P and N regions, recombination currentsfrom
the majority carriers dominate.
These two currents add up
to a constant value.
CH2 Basic Physics of Semiconductors 36
IV Characteristic of PN Junction

The current and voltage relationship of a PN junction is
exponential in forward bias region, and relatively constant
in reverse bias region.
1)
T
D
V
V
ID
 IS (exp
CH2 Basic Physics of Semiconductors 37
Parallel PN Junctions

Since junction currents are proportional to the junction’s
cross-section area.
Two PN junctions put in parallel are
effectively one PN junction with twice the cross-section
area, and hence twice the current.
CH2 Basic Physics of Semiconductors 38
Constant-Voltage Diode Model

Diode operates as an open circuit if VD< VD,on and a
constant voltage source of VD,on if VD tends to exceedVD,on.
CH2 Basic Physics of Semiconductors 39
Example: Diode Calculations

This example shows the simplicity provided by a constant-
voltage model over an exponential model.

For an exponential model, iterative method is needed to
solve for current, whereas constant-voltage model requires
only linear equations.
S
X
I
I
X
X
1 I
R V
ln
V
 I
R V

X
IX
 0.2mA
I
 2.2mA X
D
X
1
T
for
V
 3V
for
VX
1V
CH2 Basic Physics of Semiconductors 40
Reverse Breakdown

When a large reverse bias voltage is applied, breakdown
occurs and an enormous current flows through the diode.
CH2 Basic Physics of Semiconductors 41
Zener vs. Avalanche Breakdown

Zener breakdown is a result of the large electric fieldinside
the depletion region that breaks electrons or holes off their
covalent bonds.

Avalanche breakdown is a result of electrons or holes
colliding with the fixed ions inside the depletion region.
CH2 Basic Physics of Semiconductors 42

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Introduction to physics of-semiconductors

  • 1. Abbas Al-Bawee 2022 Introduction to Physics of Semiconductors
  • 2. 1 Basic Physics of Semiconductors  2.1 Semiconductor materials and their properties  2.2 PN-junction diodes  2.3 Reverse Breakdown
  • 3. Semiconductor Physics  Semiconductor devices serve as heart of microelectronics.  PN junction is the most fundamentalsemiconductor device. CH2 Basic Physics of Semiconductors 3
  • 4. Charge Carriers in Semiconductor  To understand PN junction’s IV characteristics, it is important to understand charge carriers’ behavior in solids, how to modify carrier densities, and different mechanisms of charge flow. CH2 Basic Physics of Semiconductors 4
  • 5. Periodic Table  This abridged table contains elements with three to five valence electrons, with Si being the most important. CH2 Basic Physics of Semiconductors 5
  • 6. Silicon  Si has four valence electrons. Therefore, it can form covalent bonds with four of its neighbors.  When temperature goes up, electrons in the covalent bond can become free. CH2 Basic Physics of Semiconductors 6
  • 7. Electron-Hole Pair Interaction  With free electrons breaking off covalent bonds, holes are generated.  Holes can be filled by absorbing other free electrons, so effectively there is a flow of charge carriers. CH2 Basic Physics of Semiconductors 7
  • 8. Free Electron Density at a Given Temperature CH2 Basic Physics of Semiconductors 8  Eg, or bandgap energy determines how much effort is needed to break off an electron from its covalent bond.  There exists an exponential relationship between the free- electron density and bandgap energy. 3 10 0 15 3/2 exp electrons/ cm 2kT i i g 3 i 6000 K ) 1.541015 electrons/ cm3 n (T  n (T  300 K ) 1.0810 electrons/ cm  E n  5.210 T
  • 9. Doping (N type)  Pure Si can be doped with other elements to change its electrical properties.  For example, if Si is doped with P (phosphorous), thenit has more electrons, or becomes type N (electron). CH2 Basic Physics of Semiconductors 9
  • 10. Doping (P type)  If Si is doped with B (boron), then it has more holes,or becomes type P. CH2 Basic Physics of Semiconductors 10
  • 11. Summary of Charge Carriers CH2 Basic Physics of Semiconductors 11
  • 12. Electron and Hole Densities CH2 Basic Physics of Semiconductors 12  The product of electron and hole densities is ALWAYS equal to the square of intrinsic electron density regardless of doping levels. 2 i np  n n 2 p  i ND p  NA n  i NA n  ND n 2 Majority Carriers : Minority Carriers : Majority Carriers : Minority Carriers :
  • 13. First Charge Transportation Mechanism: Drift  The process in which charge particles move because of an electric field is called drift.  Charge particles will move at a velocity that is proportional to the electric field.    ve  n E  vh   p E CH2 Basic Physics of Semiconductors 13
  • 14. Current Flow: General Case  Electric current is calculated as the amount of charge in v meters that passes thru a cross-section if the charge travel with a velocity of v m/s. I  vW hnq CH2 Basic Physics of Semiconductors 14
  • 15. Jtot CH2 Basic Physics of Semiconductors 15  n E  n  q  p E  p  q  q(n n  p p)E Jn  n E  n  q Current Flow: Drift  Since velocity is equal to E, drift characteristic is obtained by substituting V with E in the general current equation.  The total current density consists of both electrons and holes.
  • 16. Velocity Saturation  A topic treated in more advanced courses is velocity saturation.  In reality, velocity does not increase linearly with electric field. It will eventually saturate to a critical value. E b v vsat sat 0 1 0 E v   0 0 1 bE   CH2 Basic Physics of Semiconductors 16
  • 17. Second Charge Transportation Mechanism: Diffusion  Charge particles move from a region of high concentration to a region of low concentration. It is analogous to an every day example of an ink droplet in water. CH2 Basic Physics of Semiconductors 17
  • 18. Current Flow: Diffusion  Diffusion current is proportional to the gradient of charge (dn/dx) along the direction of current flow.  Its total current density consists of both electrons and holes. n dx n n dx J  qD dn I  AqD dn n dx p dx CH2 Basic Physics of Semiconductors 18 tot p dx p J  q(D dn  D dp ) J  qD dp
  • 19. Example: Linear vs. Nonlinear Charge Density Profile  Linear charge density profile means constant diffusion current, whereas nonlinear charge density profile means varying diffusion current. n n d d n n dx L dx L L J  qD dn  qD  N J  qD dn   qDn N exp  x CH2 Basic Physics of Semiconductors 19
  • 20. Einstein's Relation  While the underlying physics behind drift and diffusion currents are totally different, Einstein’s relation provides a mysterious link between the two. D  kT  q CH2 Basic Physics of Semiconductors 20
  • 21. PN Junction (Diode)  When N-type and P-type dopants are introduced side-by- side in a semiconductor, a PN junction or a diode is formed. CH2 Basic Physics of Semiconductors 21
  • 22. Diode’s Three Operation Regions  In order to understand the operation of a diode, it is necessary to study its three operation regions: equilibrium, reverse bias, and forward bias. CH2 Basic Physics of Semiconductors 22
  • 23. Current Flow Across Junction: Diffusion CH2 Basic Physics of Semiconductors 23  Because each side of the junction contains an excess of holes or electrons compared to the other side, there exists a large concentration gradient. Therefore, a diffusion current flows across the junction from each side.
  • 24. Depletion Region  As free electrons and holes diffuse across the junction, a region of fixed ions is left behind. This region is known as the “depletion region.” CH2 Basic Physics of Semiconductors 24
  • 25. Current Flow Across Junction: Drift  The fixed ions in depletion region create an electricfield that results in a drift current. CH2 Basic Physics of Semiconductors 25
  • 26. Current Flow Across Junction: Equilibrium  At equilibrium, the drift current flowing in one direction cancels out the diffusion current flowing in the opposite direction, creating a net current of zero.  The figure shows the charge profile of the PN junction. Idrift , p Idiff , p Idrift ,n  Idiff ,n CH2 Basic Physics of Semiconductors 26
  • 27. Built-in Potential  Because of the electric field across the junction, there exists a built-in potential. Its derivation is shown above.  p x p  p pp p pn dp dV D p dx 2 x1  q pE  qD dp p p D pp dx p dx p pn V(x2 ) V (x1)  ln   p dV  D dp 0 CH2 Basic Physics of Semiconductors 27 0 i A D n p n 2 q kT N N p q p kT ,V  ln V  ln
  • 28. Diode in Reverse Bias  When the N-type region of a diode is connected to a higher potential than the P-type region, the diode is under reverse bias, which results in wider depletion region and larger built-in electric field across the junction. CH2 Basic Physics of Semiconductors 28
  • 29. Reverse Biased Diode’s Application: Voltage- Dependent Capacitor  The PN junction can be viewed as a capacitor. By varying VR, the depletion width changes, changing its capacitance value; therefore, the PN junction is actually a voltage- dependent capacitor. CH2 Basic Physics of Semiconductors 29
  • 30. Voltage-Dependent Capacitance  The equations that describe the voltage-dependent capacitance are shown above. V D 0 A j0 Cj 0 j 2 N  N V C  C  1 R V0 siq NA ND 1 CH2 Basic Physics of Semiconductors 30
  • 31. Voltage-Controlled Oscillator  A very important application of a reverse-biased PN junction is VCO, in which an LC tank is used in an oscillator. By changing VR, we can change C, whichalso changes the oscillation frequency. fres 2 LC  1 1 CH2 Basic Physics of Semiconductors 31
  • 32. Diode in Forward Bias  When the N-type region of a diode is at a lower potential than the P-type region, the diode is in forward bias.  The depletion width is shortened and the built-inelectric field decreased. CH2 Basic Physics of Semiconductors 32
  • 33. Minority Carrier Profile in Forward Bias  Under forward bias, minority carriers in each region increase due to the lowering of built-in field/potential. Therefore, diffusion currents increase to supply these minority carriers. VT V V p  pp, f n, f exp 0 F VT CH2 Basic Physics of Semiconductors 33 V pp,e n,e exp 0 p 
  • 34. Diffusion Current in Forward Bias  Diffusion current will increase in order to supply the increase in minority carriers. The mathematics are shown above. exp 0 T p V VT V ND n  exp 0 T n V (exp VF 1) VT V NA (exp VF 1) p  2 D p A n n i s D N L N L D p ) I  Aqn ( 1) T V V Itot  Is (exp exp 0 CH2 Basic Physics of Semiconductors 34 exp 0 1) T T tot V (exp VF 1) VT V ND V (exp VF VT F V NA I 
  • 35. Minority Charge Gradient  Minority charge profile should not be constant along thex- axis; otherwise, there is no concentration gradient and no diffusion current.  Recombination of the minority carriers with the majority carriers accounts for the dropping of minority carriers as they go deep into the P or N region. CH2 Basic Physics of Semiconductors 35
  • 36. Forward Bias Condition: Summary  In forward bias, there are large diffusion currents of minority carriers through the junction. However, as we go deep into the P and N regions, recombination currentsfrom the majority carriers dominate. These two currents add up to a constant value. CH2 Basic Physics of Semiconductors 36
  • 37. IV Characteristic of PN Junction  The current and voltage relationship of a PN junction is exponential in forward bias region, and relatively constant in reverse bias region. 1) T D V V ID  IS (exp CH2 Basic Physics of Semiconductors 37
  • 38. Parallel PN Junctions  Since junction currents are proportional to the junction’s cross-section area. Two PN junctions put in parallel are effectively one PN junction with twice the cross-section area, and hence twice the current. CH2 Basic Physics of Semiconductors 38
  • 39. Constant-Voltage Diode Model  Diode operates as an open circuit if VD< VD,on and a constant voltage source of VD,on if VD tends to exceedVD,on. CH2 Basic Physics of Semiconductors 39
  • 40. Example: Diode Calculations  This example shows the simplicity provided by a constant- voltage model over an exponential model.  For an exponential model, iterative method is needed to solve for current, whereas constant-voltage model requires only linear equations. S X I I X X 1 I R V ln V  I R V  X IX  0.2mA I  2.2mA X D X 1 T for V  3V for VX 1V CH2 Basic Physics of Semiconductors 40
  • 41. Reverse Breakdown  When a large reverse bias voltage is applied, breakdown occurs and an enormous current flows through the diode. CH2 Basic Physics of Semiconductors 41
  • 42. Zener vs. Avalanche Breakdown  Zener breakdown is a result of the large electric fieldinside the depletion region that breaks electrons or holes off their covalent bonds.  Avalanche breakdown is a result of electrons or holes colliding with the fixed ions inside the depletion region. CH2 Basic Physics of Semiconductors 42