The document discusses MAC (Media Access Control) addresses, which are unique identifiers for network interfaces. It explains that MAC addresses are usually assigned by the manufacturer and stored in the network interface card. The standard format for MAC addresses is six groups of two hexadecimal digits separated by hyphens or colons. While intended to be permanent, it is possible to change or "spoof" the MAC address. MAC addresses are used to identify devices on a local network segment and can be queried using ARP or NDP protocols to map addresses between layers.