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HEAVY METAL POLLUTON
GROUP 4
1. ADEENA TANVEER (04021613001)
2. HADIA KHADIJA (04021613013)
3. MARIUM IQBAL (04021613017)
4. MARIA RASHEED (04021613040)
CONTENT
 INTRODUCTION
 SOURCES OF HEAVY METALS
 ENVIORNMENTAL IMPACTS OF HEAVY METALS
 EFFECTS OF HEAVY METAL CONTAMINATION
 MECHANISMS OF REMEDIATING HEAVY METALS
INTRODUCTION
Introduction
 There is no specific definition of a heavy metal, literature has defined it
as a naturally occurring element having a high atomic weight and high
density which is five times greater than that of water.
 Heavy metals are usually present in trace amounts in natural waters but
many of them are toxic even at very low concentrations.
 Metals such as arsenic, lead, cadmium, nickel, mercury, chromium,
cobalt, zinc and selenium are highly toxic even in minor quantity.
Sources of Heavy Metals
Sources of Heavy Metals
 Heavy metals can emanate from both natural and anthropogenic
processes and end up in different environmental compartments (soil,
water, air and their interface).
SOURCES
OF
HEAVY
METALS
MINNING
SMELTING
AGRICULTURE
AND
FORESTRY
FOSSIL FUEL
COMBUSTION
METALLURGICAL
INDUSTRIES
WASTE
DISOSAL
CORROISON
Natural Processes
 Under different and certain environmental conditions, natural emissions
of heavy metals occur.
 Such emissions include:
1. volcanic eruptions,
2. sea-salt sprays,
3. forest fires,
4. rock weathering,
5. biogenic sources
6. wind-borne soil particles.
Natural Processes
 Natural weathering processes can lead to the release of metals from their
endemic spheres to different environment compartments.
 The most common heavy metals are
1. lead (Pb),
2. nickel (Ni),
3. chromium (Cr),
4. cadmium (Cd),
5. arsenic (As),
6. mercury (Hg),
7. zinc (Zn)
8. copper (Cu).
Anthropogenic Processes
 Industries, agriculture, wastewater, mining and metallurgical processes,
and runoffs also lead to the release of pollutants to different
environmental compartments.
 Anthropogenic processes of heavy metals have been noted to go
beyond the natural fluxes for some metals.
Anthropogenic Processes
 Some important anthropogenic sources which significantly contribute to
the heavy metal contamination in the environment include
• automobile exhaust which releases lead
• smelting which releases arsenic, copper and zinc
• insecticides which release arsenic
• burning of fossil fuels which release nickel, vanadium, mercury,
selenium.
Impacts of Heavy Metals
Environmental Impacts of Heavy Metals
 The presence of heavy metals in the environment leads to a number of
adverse impacts.
 Such impacts affect all spheres of the environment, that is, hydrosphere,
lithosphere, biosphere and atmosphere.
 Until the impacts are dealt with, health and mortality problems break
out, as well as the disturbance of food chains.
ZINC
ARSENIC
MERCURY
LEAD
CADMIUM
BLOOD
KIDNEY
BRAIN
KIDNEY
LUNGS
Health
Impacts of
Heavy
Metals
Effects of Heavy Metals
Contamination
Effects of heavy metals contamination
 Heavy metals contamination is becoming a serious issue of concern
around the world as it has gained momentum due to the increase in the
use and processing of heavy metals during various activities to meet the
needs of the rapidly growing population.
 Soil, water and air are the major environmental compartments which are
affected by heavy metals pollution.
Effect on soil
 Emissions from activities and sources such as industrial activities, mine
tailings, disposal of high metal wastes, land application of fertilizers,
animal manures, sewage sludge, pesticides, wastewater irrigation, coal
combustion residues and lead to soil contamination by heavy metals.
 Soils have been noted to be the major sinks for heavy metals released
into the environment by anthropogenic activities.
 Most heavy metals do not undergo microbial or chemical degradation
because they are nondegradable, and consequently their total
concentrations last for a long time after being released to the
environment.
Effect on soil
 The presence of heavy metals in soils is a serious issue due to its
residence in food chains, thus destroying the entire ecosystem.
 There are various ways through which heavy metals present risks to
humans, animals, plants and ecosystems as a whole.
 Such ways include direct ingestion, absorption by plants, food chains,
consumption of contaminated water and alteration of soil pH, porosity,
color and its natural chemistry which in turn impact on the soil quality.
Effect on water
 Although there are many sources of water contamination,
industrialization and urbanization are two of the culprits for the
increased level of heavy metal water contamination.
 Heavy metals are transported by runoff from industries, and urban
areas. Most of these metals end up accumulating in the soil and
sediments of water bodies.
Effect on water
 Heavy metals can be found in traces in water sources and still be very
toxic and impose serious health problems to humans and other
ecosystems.
 This is because the toxicity level of a metal depends on factors such as
the organisms which are exposed to it, its nature, its biological role and
the period at which the organisms are exposed to the metal.
Effect on water
 The contamination of water by heavy metals actually affects all
organisms.
 Humans, an example of organisms feeding at the highest level, are more
prone to serious health problems because the concentrations of heavy
metals increase in the food chain.
Effects on air
 Industrialization and urbanization, due to rapid world population
growth, have recently made air pollution as a major environmental
problem around the world. The air pollution was reported to have been
accelerated by dust and particulate matters (PMs).
 Natural processes which release particulate matters into air include dust
storms, soil erosion, volcanic eruptions and rock weathering, while
anthropogenic activities are more industrial and transportation related.
Effect on air
 They can lead to serious health problems such as skin and eyes irritation,
respiratory infections, premature mortality and cardiovascular diseases.
 These pollutants also cause deterioration of infrastructure, corrosion,
formation of acid rain, eutrophication and haze.
Mechanisms of Remediating
Heavy Metals
Mechanisms of Remediating Heavy Metals
 In order to protect the human health, plants, animals, soil and all the
compartments of the environment, proper and careful attention should
be given to remediation technologies of heavy metals.
 Most physical and chemical heavy metal remediation technologies
require handling of large amounts of sludge, destroy surrounding
ecosystems and are very expensive
Precipitation
 A variety of alkaline chemical reagents have been used over the years
for neutralization of acid mine drainage (AMD) in order to increase the
pH and consequently precipitate and recover the metals.
 The most common alkaline reagents used for sequential recovery of
minerals resources from AMD are limestone (CaCO3), caustic soda
(NaOH), soda ash (Na2CO3), quicklime (CaO), slaked lime (Ca(OH)2) and
magnesium hydroxide (Mg(OH)2)
Adsorption
 Adsorption occurs when an adsorbate adheres to the surface of an
adsorbent. Due to reversibility and desorption capabilities, adsorption is
regarded the most effective and economically viable option for the
removal of metals from aqueous solution.
 Although efficient, adsorption is not effective with very concentrated
solution as the adsorbent easily gets saturated with the adsorbate.
 It is only feasible for very dilute solutions, is labor intensive because it
requires frequent regeneration and it is not selective in terms of metal
attenuation. Adsorption is therefore not applied in a large scale of metal
remediation.
Ion exchange
 Ion exchange is the exchange of ions between two or more electrolyte
solutions. It can also refer to exchange of ions on a solid substrate to soil
solution.
 High cation exchange capacity clay and resins are commonly used for
the uptake of metals from aqueous solutions.
 Natural and synthetic clays, zeolites and synthetic resins have been used
for removal and attenuation of metals from wastewater.
Biosorption
 Biosorption refers to the removal of pollutants from water systems using
biological materials, and it entails the absorption, adsorption, ion
exchange, surface complexation and precipitation.
 Bio sorbents have an advantage of accessibility, efficiency and capacity.
This process is readily and easily available.
 Regeneration is easy, hence making it very favorable.
 However, when the concentration of the feed solution is very high, the
process easily reaches a breakthrough, thus limiting further pollutant
removal.
Membrane technologies
 The use of membrane technologies for the recovery of acid mine
drainage is very effective for water that has high concentration of
pollutants.
 It uses the concentration gradients phenomenon or the opposite which
is reverse osmosis.
 There are different types of membranes that are used for mine water
treatment including: ultrafiltration, Nano-filtration, reverse osmosis,
microfiltration and particle filtration.
Filtration
 A chemically modified cellulose filter paper with
ethylenediaminetetraacetic acid (EDTA) is described as a device for metal
remediation.
 The high hydrophilicity of cellulose paper associated to the strong
chelating properties of the EDTA moieties for metals allow the treatment
of water samples containing various metal cations, including Ag, Ni, Zn,
Cd, Pb, Sn and Cu, with 90-95% removal efficiency.
THANK YOU!

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Heavy metal pollution

  • 2. GROUP 4 1. ADEENA TANVEER (04021613001) 2. HADIA KHADIJA (04021613013) 3. MARIUM IQBAL (04021613017) 4. MARIA RASHEED (04021613040)
  • 3. CONTENT  INTRODUCTION  SOURCES OF HEAVY METALS  ENVIORNMENTAL IMPACTS OF HEAVY METALS  EFFECTS OF HEAVY METAL CONTAMINATION  MECHANISMS OF REMEDIATING HEAVY METALS
  • 5. Introduction  There is no specific definition of a heavy metal, literature has defined it as a naturally occurring element having a high atomic weight and high density which is five times greater than that of water.  Heavy metals are usually present in trace amounts in natural waters but many of them are toxic even at very low concentrations.  Metals such as arsenic, lead, cadmium, nickel, mercury, chromium, cobalt, zinc and selenium are highly toxic even in minor quantity.
  • 7. Sources of Heavy Metals  Heavy metals can emanate from both natural and anthropogenic processes and end up in different environmental compartments (soil, water, air and their interface).
  • 9.
  • 10. Natural Processes  Under different and certain environmental conditions, natural emissions of heavy metals occur.  Such emissions include: 1. volcanic eruptions, 2. sea-salt sprays, 3. forest fires, 4. rock weathering, 5. biogenic sources 6. wind-borne soil particles.
  • 11. Natural Processes  Natural weathering processes can lead to the release of metals from their endemic spheres to different environment compartments.  The most common heavy metals are 1. lead (Pb), 2. nickel (Ni), 3. chromium (Cr), 4. cadmium (Cd), 5. arsenic (As), 6. mercury (Hg), 7. zinc (Zn) 8. copper (Cu).
  • 12. Anthropogenic Processes  Industries, agriculture, wastewater, mining and metallurgical processes, and runoffs also lead to the release of pollutants to different environmental compartments.  Anthropogenic processes of heavy metals have been noted to go beyond the natural fluxes for some metals.
  • 13. Anthropogenic Processes  Some important anthropogenic sources which significantly contribute to the heavy metal contamination in the environment include • automobile exhaust which releases lead • smelting which releases arsenic, copper and zinc • insecticides which release arsenic • burning of fossil fuels which release nickel, vanadium, mercury, selenium.
  • 15. Environmental Impacts of Heavy Metals  The presence of heavy metals in the environment leads to a number of adverse impacts.  Such impacts affect all spheres of the environment, that is, hydrosphere, lithosphere, biosphere and atmosphere.  Until the impacts are dealt with, health and mortality problems break out, as well as the disturbance of food chains.
  • 16.
  • 18.
  • 19. Effects of Heavy Metals Contamination
  • 20. Effects of heavy metals contamination  Heavy metals contamination is becoming a serious issue of concern around the world as it has gained momentum due to the increase in the use and processing of heavy metals during various activities to meet the needs of the rapidly growing population.  Soil, water and air are the major environmental compartments which are affected by heavy metals pollution.
  • 21.
  • 22. Effect on soil  Emissions from activities and sources such as industrial activities, mine tailings, disposal of high metal wastes, land application of fertilizers, animal manures, sewage sludge, pesticides, wastewater irrigation, coal combustion residues and lead to soil contamination by heavy metals.  Soils have been noted to be the major sinks for heavy metals released into the environment by anthropogenic activities.  Most heavy metals do not undergo microbial or chemical degradation because they are nondegradable, and consequently their total concentrations last for a long time after being released to the environment.
  • 23. Effect on soil  The presence of heavy metals in soils is a serious issue due to its residence in food chains, thus destroying the entire ecosystem.  There are various ways through which heavy metals present risks to humans, animals, plants and ecosystems as a whole.  Such ways include direct ingestion, absorption by plants, food chains, consumption of contaminated water and alteration of soil pH, porosity, color and its natural chemistry which in turn impact on the soil quality.
  • 24. Effect on water  Although there are many sources of water contamination, industrialization and urbanization are two of the culprits for the increased level of heavy metal water contamination.  Heavy metals are transported by runoff from industries, and urban areas. Most of these metals end up accumulating in the soil and sediments of water bodies.
  • 25. Effect on water  Heavy metals can be found in traces in water sources and still be very toxic and impose serious health problems to humans and other ecosystems.  This is because the toxicity level of a metal depends on factors such as the organisms which are exposed to it, its nature, its biological role and the period at which the organisms are exposed to the metal.
  • 26. Effect on water  The contamination of water by heavy metals actually affects all organisms.  Humans, an example of organisms feeding at the highest level, are more prone to serious health problems because the concentrations of heavy metals increase in the food chain.
  • 27.
  • 28.
  • 29. Effects on air  Industrialization and urbanization, due to rapid world population growth, have recently made air pollution as a major environmental problem around the world. The air pollution was reported to have been accelerated by dust and particulate matters (PMs).  Natural processes which release particulate matters into air include dust storms, soil erosion, volcanic eruptions and rock weathering, while anthropogenic activities are more industrial and transportation related.
  • 30. Effect on air  They can lead to serious health problems such as skin and eyes irritation, respiratory infections, premature mortality and cardiovascular diseases.  These pollutants also cause deterioration of infrastructure, corrosion, formation of acid rain, eutrophication and haze.
  • 32.
  • 33. Mechanisms of Remediating Heavy Metals  In order to protect the human health, plants, animals, soil and all the compartments of the environment, proper and careful attention should be given to remediation technologies of heavy metals.  Most physical and chemical heavy metal remediation technologies require handling of large amounts of sludge, destroy surrounding ecosystems and are very expensive
  • 34. Precipitation  A variety of alkaline chemical reagents have been used over the years for neutralization of acid mine drainage (AMD) in order to increase the pH and consequently precipitate and recover the metals.  The most common alkaline reagents used for sequential recovery of minerals resources from AMD are limestone (CaCO3), caustic soda (NaOH), soda ash (Na2CO3), quicklime (CaO), slaked lime (Ca(OH)2) and magnesium hydroxide (Mg(OH)2)
  • 35. Adsorption  Adsorption occurs when an adsorbate adheres to the surface of an adsorbent. Due to reversibility and desorption capabilities, adsorption is regarded the most effective and economically viable option for the removal of metals from aqueous solution.  Although efficient, adsorption is not effective with very concentrated solution as the adsorbent easily gets saturated with the adsorbate.  It is only feasible for very dilute solutions, is labor intensive because it requires frequent regeneration and it is not selective in terms of metal attenuation. Adsorption is therefore not applied in a large scale of metal remediation.
  • 36. Ion exchange  Ion exchange is the exchange of ions between two or more electrolyte solutions. It can also refer to exchange of ions on a solid substrate to soil solution.  High cation exchange capacity clay and resins are commonly used for the uptake of metals from aqueous solutions.  Natural and synthetic clays, zeolites and synthetic resins have been used for removal and attenuation of metals from wastewater.
  • 37. Biosorption  Biosorption refers to the removal of pollutants from water systems using biological materials, and it entails the absorption, adsorption, ion exchange, surface complexation and precipitation.  Bio sorbents have an advantage of accessibility, efficiency and capacity. This process is readily and easily available.  Regeneration is easy, hence making it very favorable.  However, when the concentration of the feed solution is very high, the process easily reaches a breakthrough, thus limiting further pollutant removal.
  • 38. Membrane technologies  The use of membrane technologies for the recovery of acid mine drainage is very effective for water that has high concentration of pollutants.  It uses the concentration gradients phenomenon or the opposite which is reverse osmosis.  There are different types of membranes that are used for mine water treatment including: ultrafiltration, Nano-filtration, reverse osmosis, microfiltration and particle filtration.
  • 39. Filtration  A chemically modified cellulose filter paper with ethylenediaminetetraacetic acid (EDTA) is described as a device for metal remediation.  The high hydrophilicity of cellulose paper associated to the strong chelating properties of the EDTA moieties for metals allow the treatment of water samples containing various metal cations, including Ag, Ni, Zn, Cd, Pb, Sn and Cu, with 90-95% removal efficiency.