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Functional Coatings on Steel in the Built Environment
-Current and Future Technologies
Dr Sanjay Ghosh
Research Officer
Sanjayghosh.uk@gmail.com
Bangor University
Functional coating is all about material that do things
Application of Functional Coating on Steel
Energy efficiency
1. Photovoltaic electricity generation
2. Solar heating
3. Electroluminescent display
Healthcare and safety
1. Intumescent coating for fire protection
2. Anti-microbial coating for health
Key area :
Intumescent Coating on Exposed Structural Steelwork
Festival Place, Basingstoke and City Point, London (Leigh’s Paints)1. Corrosion resistance paint
Weather Protection
Solar Cell Fabrication on Low Cost Rough Steel Surface
0.3mm
400nm
200nm
2.5-3mm
400nm
500nm
Organic photovoltaic (OPV) Amorphous silicon solar cell (a-Si:H)
Functional coating: SU8 compatible for OPV,
Sol-gel, SiOx compatible for a-Si:H & OPV
PCE = 3%
PCE = 6%
Sol. Energy Mater. Sol. Cell 2016, 157, 305 Sol. Energy 2016, 124, 216
Characterisation of Steel + Functional coating (IL) for PV
Leakage current
 For solar applications : Ra~0.03μm, Rz~0.3μm
Steel (Roughness high) Steel +IL (Roughness low)
Functional coating
Steel +
IL
Electrical
insulation
Diffusion
barrier
Mechanical &
Thermal
stability
Surface
leveling
Pencil method
4
Sol-gel (SiOx) Formulation and Development
SiOx mix = Tetraethylorthosilicate (TEOS) + Methyltriethoxysilane (MTES) + Polyethylene Glycole (PEG) + HNO3 + H2O
 SiOx coating is compatible with both vacuum and non vacuum deposition method
Spray coat, bar coat, PVD deposition
Temperature of curing = 100 -300 oC for PV application
SU8 (IL) Formulation and Development
Gamma Butyrolactone) 22-60%
Mixed Triarylsulfonium/ Hexafluoroantimonate Salt 1-2%
Propylene Carbonate
Epoxy Resin (Formaldehyde, polymer with 2-
(chloromethyl)oxirane and 4,4'-
(1-methylethylidene)bis[phenol])
35-75%
Volume
1-5%
Substrate (steel)
cleaning
coat (K-bar)
Soft bake,
125 -150 oC,
10 min
Develop, 15 min
Hard bake,
230-250 oC,
15 min
SU8 Mix
Processing steps
 Surface coverage = 70 g/m2, 60 um thickness film, Bar coat
Economic Viability of Low Carbon Steel + IL as substrate for PV
 Cost Steel + ILs should be below 0.175 €/Wp for PV
Annu. Rev. Mater. Res. 2011, 41, 297Sol. Energy 2016, 124, 216
Solar Heater
Ren. Sus. Energy Rev. 2016, 58, 574
Evacuated-tube Solar Collector (Riomay)
Evacuated-tube Solar Collector (Espionoza Energy)
Fe2O3/Stainless Steel at Different temperature
High Temperature Solar Absorber on Steel
Author Coat Technique Absorptance
α
Emittance
ε
Remarks
Ambriosini et al.
2010
FeCo2O4
NiCo2O4
Spin coat 0.88
0.82
0.59
0.46
Thermal stability above 600 oC
Liu et al.
2012
NbTiON/SiON Magnetron
sputtering
0.95 0.07 Thermal stability above 500 oC
Valleti et al.
2014
TiAlCrN/TiAlN/AlSiN Cathodic arc
PVD
0.91 0.07 Degrade at high temperature
Cespedes et al.
2014
Mo-Si3N4 Magnetron
sputtering
0.93 0.02 Potential to be used for CSP
Liu et al.
2014
Cr-Al-O Cathodic arc
ion plating
0.92 0.21 Suitable for collector at higher
temperature
Liu et al.
2017
TiC-WC
TiC-WC/Al2O3
Magnetron
sputtering
0.78
0.92
0.11
0.11
Stable up to 500 oC
Wu et al.
2017
Fe2O3 Thermal
oxidation
0.91 0.18 Stable up to 900 oC
Future Trend of Functional Coatings
Example: Acronal® Pro 7600 - latest innovation for corrosion protection
for industrial metal coatings presented at the European Coatings Show
this month.
 Conventional to sustainable technology-water based environmental friendly
 With VOC regulations at 50 g/L and below,
 Self healing, self cleaning properties, sensing abilities, etc.
April 2017, Germany
Chem. Mater., 2010, 22 , 4406
Anti-corrosion paint (BASF)
Thank you

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Functional Coatings on Steel in the Built Environment -Current and Future Technologies

  • 1. Functional Coatings on Steel in the Built Environment -Current and Future Technologies Dr Sanjay Ghosh Research Officer Sanjayghosh.uk@gmail.com Bangor University
  • 2. Functional coating is all about material that do things Application of Functional Coating on Steel Energy efficiency 1. Photovoltaic electricity generation 2. Solar heating 3. Electroluminescent display Healthcare and safety 1. Intumescent coating for fire protection 2. Anti-microbial coating for health Key area : Intumescent Coating on Exposed Structural Steelwork Festival Place, Basingstoke and City Point, London (Leigh’s Paints)1. Corrosion resistance paint Weather Protection
  • 3. Solar Cell Fabrication on Low Cost Rough Steel Surface 0.3mm 400nm 200nm 2.5-3mm 400nm 500nm Organic photovoltaic (OPV) Amorphous silicon solar cell (a-Si:H) Functional coating: SU8 compatible for OPV, Sol-gel, SiOx compatible for a-Si:H & OPV PCE = 3% PCE = 6% Sol. Energy Mater. Sol. Cell 2016, 157, 305 Sol. Energy 2016, 124, 216
  • 4. Characterisation of Steel + Functional coating (IL) for PV Leakage current  For solar applications : Ra~0.03μm, Rz~0.3μm Steel (Roughness high) Steel +IL (Roughness low) Functional coating Steel + IL Electrical insulation Diffusion barrier Mechanical & Thermal stability Surface leveling Pencil method 4
  • 5. Sol-gel (SiOx) Formulation and Development SiOx mix = Tetraethylorthosilicate (TEOS) + Methyltriethoxysilane (MTES) + Polyethylene Glycole (PEG) + HNO3 + H2O  SiOx coating is compatible with both vacuum and non vacuum deposition method Spray coat, bar coat, PVD deposition Temperature of curing = 100 -300 oC for PV application
  • 6. SU8 (IL) Formulation and Development Gamma Butyrolactone) 22-60% Mixed Triarylsulfonium/ Hexafluoroantimonate Salt 1-2% Propylene Carbonate Epoxy Resin (Formaldehyde, polymer with 2- (chloromethyl)oxirane and 4,4'- (1-methylethylidene)bis[phenol]) 35-75% Volume 1-5% Substrate (steel) cleaning coat (K-bar) Soft bake, 125 -150 oC, 10 min Develop, 15 min Hard bake, 230-250 oC, 15 min SU8 Mix Processing steps  Surface coverage = 70 g/m2, 60 um thickness film, Bar coat
  • 7. Economic Viability of Low Carbon Steel + IL as substrate for PV  Cost Steel + ILs should be below 0.175 €/Wp for PV Annu. Rev. Mater. Res. 2011, 41, 297Sol. Energy 2016, 124, 216
  • 8. Solar Heater Ren. Sus. Energy Rev. 2016, 58, 574 Evacuated-tube Solar Collector (Riomay) Evacuated-tube Solar Collector (Espionoza Energy) Fe2O3/Stainless Steel at Different temperature
  • 9. High Temperature Solar Absorber on Steel Author Coat Technique Absorptance α Emittance ε Remarks Ambriosini et al. 2010 FeCo2O4 NiCo2O4 Spin coat 0.88 0.82 0.59 0.46 Thermal stability above 600 oC Liu et al. 2012 NbTiON/SiON Magnetron sputtering 0.95 0.07 Thermal stability above 500 oC Valleti et al. 2014 TiAlCrN/TiAlN/AlSiN Cathodic arc PVD 0.91 0.07 Degrade at high temperature Cespedes et al. 2014 Mo-Si3N4 Magnetron sputtering 0.93 0.02 Potential to be used for CSP Liu et al. 2014 Cr-Al-O Cathodic arc ion plating 0.92 0.21 Suitable for collector at higher temperature Liu et al. 2017 TiC-WC TiC-WC/Al2O3 Magnetron sputtering 0.78 0.92 0.11 0.11 Stable up to 500 oC Wu et al. 2017 Fe2O3 Thermal oxidation 0.91 0.18 Stable up to 900 oC
  • 10. Future Trend of Functional Coatings Example: Acronal® Pro 7600 - latest innovation for corrosion protection for industrial metal coatings presented at the European Coatings Show this month.  Conventional to sustainable technology-water based environmental friendly  With VOC regulations at 50 g/L and below,  Self healing, self cleaning properties, sensing abilities, etc. April 2017, Germany Chem. Mater., 2010, 22 , 4406 Anti-corrosion paint (BASF)

Editor's Notes

  1. Talk about the intermediate coating as functional material. Its characterisation and development And test strategy Dielectric property, insulation , robustness, and stability
  2. The cost for ‘rough’ substrate can be 30-40% reduced as compared to high roughness grade. For solar applications the surface roughness of substrates should be generally very low: Ra~0.03μm, Rt~0.3μm Al (100 nm) deposited by thermal evaporation using Edward thermal evaporator. Talk about the intermediate coating as functional material. Its characterisation and development And test strategy Dielectric property, insulation , robustness, and stability
  3. Talk about the intermediate coating as functional material. Its characterisation and development And test strategy Dielectric property, insulation , robustness, and stability
  4. Talk about the intermediate coating as functional material. Its characterisation and development And test strategy Dielectric property, insulation , robustness, and stability
  5. 10% efficiency module
  6. Talk about the intermediate coating as functional material. Its characterisation and development And test strategy Dielectric property, insulation , robustness, and stability
  7. Talk about the intermediate coating as functional material. Its characterisation and development And test strategy Dielectric property, insulation , robustness, and stability
  8. With VOC regulations at 50 g/L and below, formulators are looking for ways to achieve this goal while maintaining performance properties Self healing, self cleaning properties, sensing abilities, etc., will require new material chemistries and processes that will require extensive vetting of performance and durability through comprehensive testing Talk about the intermediate coating as functional material. Its characterisation and development And test strategy Dielectric property, insulation , robustness, and stability
  9. Talk about the intermediate coating as functional material. Its characterisation and development And test strategy Dielectric property, insulation , robustness, and stability