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F R   O T H F L O A T N T I O A PRESENTATION ON PREPARED BY:-   SWAPNIL  NIGAM GUIDED BY:- PROF. M.K.MANOJ
CONTENTS 1.HISTORY 2.INTRODUCTION 3.BASIC PRINCIPLES 4.MECHANICS OF FLOTATION 5.CHEMICALS OF FLOTATION 6.SCIENCE OF FLOTATION 7.ENGINEERING OF FLOTATION 8.REFERENCES
[object Object],[object Object],[object Object],HISTORY
NOW  LET US MOVE TO
INTRODUCTION ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object]
basic principles ,[object Object],[object Object],[object Object],[object Object],[object Object]
AIR IN MINERALISED FROTH PULP AIR BUBBLE CELL AGITATOR MINERALS’ PARTICLES ATTACHED TO BUBBLE
MECHANICS OF FLOTATION ,[object Object],[object Object],[object Object],[object Object]
BUBBLE SOLID WATER Γ W/A Γ S/W Γ S/A θ ,[object Object],Γ W/A   COS θ   Γ S/W Γ S/A = -
WHERE, in the above equation, Γ W/A ,  Γ S/A ,  Γ S/W  are the SURFACE ENERGIES between water-air, solid-air, solid-water interface and  θ  is the CONTACT ANGLE. NOW, let W S/A  is the  WORK OF ADHESION,  i.e. , the force required to break the particle-bubble interface, THEN, W S/A  =  Γ W/A   +  Γ S/W   –  Γ S/A W S/A  =  Γ W/A   -  Γ W/A  COS  θ W S/A  =  Γ W/A   (1- COS  θ )
From the above Equation, it can be seen that, Greater the Contact Angle ; Greater is the W S/A  , i.e.  WORK OF ADHESION  between particle and bubble and thus more resilient is the system to the disruptive forces. Contact Angle around 90° is sufficient. ,[object Object],[object Object]
chemicalS OF FLOTATION ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
COLLECTORS ,[object Object],[object Object],[object Object]
COLLECTORS NON-IONISING IONISING ANIONIC CATIONIC OXYHYDRYL SULPHYHYDRYL SULPHATES SULPHONATES DITHIOPHOSPHATES XANTHATES CARBONATES (LIQUID NON-POLAR  HYDROCARBONS, INSOLUBLE IN WATER.)
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
POLAR GROUP NON-POLAR GROUP MINERAL
[object Object],[object Object],[object Object],[object Object],[object Object]
NON-IONIC COLLECTORS ,[object Object],[object Object],IONIC COLLECTORS ,[object Object],[object Object]
Anionic Collectors ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
C C C C C C C C C C C C C C C C C O O Na POLAR GROUP NON-POLAR GROUP CATION ANION SODIUM OLEATE C
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
C O H C C H H H H S S Na SODIUM ETHYL XANTHATE CATION ANION POLAR GROUP NON-POLAR GROUP
[object Object],[object Object],[object Object],[object Object],[object Object],P S S RO RO Na(K)
Cationic Collectors N R R OH(X) R R ,[object Object],[object Object],[object Object],[object Object],[object Object]
FROTHERS ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
WATER AIR IN FROTHER
[object Object],[object Object],[object Object],[object Object],[object Object],CH 3 CH 3 OH CH 3 4-Methyl-2-pentanol (MIBC)
ACTIVATORS ,[object Object],[object Object],[object Object],[object Object],ZnS(s) Xanthate Zn Xanthate S(s)
[object Object],ZnS(s) CuSO 4 Cu S(s) Zn SO 4 ,[object Object],[object Object]
DEPRESSANTS ,[object Object],[object Object],[object Object],[object Object],[object Object]
INORGANIC DEPRESSANTS ,[object Object],[object Object],[object Object],[object Object],[object Object]
NaCN H O 2 CN H Na OH CN H H CN + ,[object Object],3CN Cu 2+ Cu (CN) 2 [ ] 1/2 C N 2 2 CUPRO-CYANIDE  (soluble complex)
[object Object],[object Object],[object Object],[object Object]
ORGANIC DEPRESSANTS ,[object Object],[object Object],[object Object],[object Object],[object Object]
pH MODIFIERS ,[object Object],[object Object],[object Object]
[object Object],[object Object],COLLECTOR’S CONCENTRATION (in mg/L) pH VALUE 0 100 300 400 500 600 700 200 2 5 6 7 8 3 4 9 10 11 PYRITE GALENA CHALCOPYRITE
SCIENCE OF FLOTATION ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],k = P R f S b
[object Object],[object Object],S b = 6 J g d b Where, J g  = Superficial Gas Velocity (m/s) and  d b  = Sauter Mean Bubble Diameter (m)
ENGINEERING OF FLOTATION ,[object Object],[object Object],[object Object]
[object Object],[object Object]
FEED TAILINGS SCAVENGERS CELLS FINAL  CONCENTRATES ,[object Object]
SCAVENGERS ROUGHERS CLEANER FEED TAILINGS FINAL  CONCENTRATES TAILINGS CLEANER'S
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],FLOTATION M/C(s)
WASHWATER FROTH PHASE  (CLEANING ZONE) FEED INLET AIR INLET TAILINGS OUTLET PULP  PHASE  (RECOVERY  ZONE) CONCENTRATE  OUTLET
[object Object]
[object Object]
REFERENCES ,[object Object],[object Object],[object Object]
THANK YOU  FOR YOUR CO-ORDINATION

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FROTH FLOTATION- SWAPNIL NIGAM

  • 1. F R O T H F L O A T N T I O A PRESENTATION ON PREPARED BY:- SWAPNIL NIGAM GUIDED BY:- PROF. M.K.MANOJ
  • 2. CONTENTS 1.HISTORY 2.INTRODUCTION 3.BASIC PRINCIPLES 4.MECHANICS OF FLOTATION 5.CHEMICALS OF FLOTATION 6.SCIENCE OF FLOTATION 7.ENGINEERING OF FLOTATION 8.REFERENCES
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  • 4. NOW LET US MOVE TO
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  • 8. AIR IN MINERALISED FROTH PULP AIR BUBBLE CELL AGITATOR MINERALS’ PARTICLES ATTACHED TO BUBBLE
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  • 11. WHERE, in the above equation, Γ W/A , Γ S/A , Γ S/W are the SURFACE ENERGIES between water-air, solid-air, solid-water interface and θ is the CONTACT ANGLE. NOW, let W S/A is the WORK OF ADHESION, i.e. , the force required to break the particle-bubble interface, THEN, W S/A = Γ W/A + Γ S/W – Γ S/A W S/A = Γ W/A - Γ W/A COS θ W S/A = Γ W/A (1- COS θ )
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  • 15. COLLECTORS NON-IONISING IONISING ANIONIC CATIONIC OXYHYDRYL SULPHYHYDRYL SULPHATES SULPHONATES DITHIOPHOSPHATES XANTHATES CARBONATES (LIQUID NON-POLAR HYDROCARBONS, INSOLUBLE IN WATER.)
  • 16.
  • 17. POLAR GROUP NON-POLAR GROUP MINERAL
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  • 21. C C C C C C C C C C C C C C C C C O O Na POLAR GROUP NON-POLAR GROUP CATION ANION SODIUM OLEATE C
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  • 23. C O H C C H H H H S S Na SODIUM ETHYL XANTHATE CATION ANION POLAR GROUP NON-POLAR GROUP
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  • 27. WATER AIR IN FROTHER
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  • 43. SCAVENGERS ROUGHERS CLEANER FEED TAILINGS FINAL CONCENTRATES TAILINGS CLEANER'S
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  • 45. WASHWATER FROTH PHASE (CLEANING ZONE) FEED INLET AIR INLET TAILINGS OUTLET PULP PHASE (RECOVERY ZONE) CONCENTRATE OUTLET
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  • 49. THANK YOU FOR YOUR CO-ORDINATION