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Production of Zinc Diecastings for
          Electroplating
Relative costs of fabricating, finishing and plating
                  zinc diecastings
Some Design Rules
Mimimum crown of 0.15cm per cm
If flat surfaces required, use satin instead of bright finish to hide waviness
All edges should be rounded off to radius of at least 0.4mm, preferably
0.8mm
Reduce depth of concave recesses as much as possible, avoid depths greater
than 50% of width
If sharply angled grooves are needed, paint the bottom of the grooves, it is
cheaper than plating the bottom of the grooves
Slots and holes shown have widths at least 2X their depth
Spaces between slots should be spaced so that spacing between their
centers is 4X their width
Blind hole depths should be less than ½ their width and blind holes <5.6mm
diameter should be avoided
Threaded holes should be countersunk to minimize buildup on their outside
The height of fins and ribs should be reduced as much as possible with
radius>1.6mm at base
Parallel fins should be spaced so distance between centers is >4X fin width
Recessed letters preferred to raised letter. Raised letter heights should be
<50% of their width
If studs threaded before plating, max thickness is 5µm
Drain holes should be provided in cup-like contours to avoid hand rinsing
Design factors influencing platability of zinc
                 diecastings
Minimum radii for angles defined by indentations
Checklist for High Quality Castings


Properly designed and constructed dies
Smooth working, run-in casting machines
Correct alloy composition
Good melting and delivery practice, proper die
lubrication
Correct injection and trimming procedures
Die Design Guidelines


Plan for location of ejector pins to prevent marks
in visible areas, or place on areas that can be
easily polished
Fill thick sections before thin to allow progressive
cooling
Alloy should reach vents and overflows last to
allow complete die cavity filling
Place vents at parting line to allow easy removal
of flash
Surfaces required to slide on cavity during
ejection should be tapered
Castings with defects >50µm are not salvageable
Cross sections of rough
surface diecastings
plated with bright copper
in cyanide and acid
baths, then with leveling
duplex nickel
Casting Fluidity


• Zamak Alloys are more fluid than ZA
  Alloys.
• Aluminum increases fluidity for Zamak
  Alloys – keep Al to high side of range.
• Magnesium decreases fluidity, but not as
  much as aluminum changes.
Fluidity of Zinc Die Casting Alloys
Ragone Fluidity, Inches




                          Aluminum, Weight Percent
Solidification Ranges


Zamak alloys have smaller freezing ranges than ZA alloys



    Alloy             Solidification Range ºC ( ºF )
  Alloy 3                           6 (11)
   ZA-8                            29 (52)
  ZA-12                            55 (100)
  ZA-27                           112 (202)

      Therefore, shrinkage porosity rarely occurs in
                      Zamak alloys
Casting Limits


Integranular corrosion can be caused by high levels of Pb, Cd, Sn



                                 Casting Limits
                           Zamak 3                 Zamak 5
Pb (max)                    50 ppm                 50 ppm
Cd (max)                    40 ppm                 40 ppm
Sn (max)                    30 ppm                 30 ppm

               ZA contaminant levels are similar
Effect of humidity test on zinc-aluminum
         alloy containing cadmium



                                Discolored &
As cast plate                   Cracked
                                humidity-tested
                                panels
As-polished structure of humidity-tested zinc
aluminum alloy containing cadmium showing a
      crack and intergranular corrosion
Intermetallics


• Intermetallics are mostly Fe-Al:

  – Leave “comet tails” after buffing.
  – Can be removed by stirring, letting the
    bath stand and skimming.
  – Machining (tool wear) problems can also
    result.
Surface dross laden with large and smallFeAl3
            intermetallic particles
Tool Wear – ZA-27 Die Casting



                                  Many large FeAl3 particles




                                                                             Mean Wear Land Width (mm )
                                         (0.07% Fe)
Mean Wear Land Width (in.)




                                                Many small FeAl3 particles
                                                      (0.22% Fe)




                                    Drilling Time (min.)
Cosmetic Defects




•   Cold Shuts          • Flaking or waving
•   Blisters            • Solidification
•   Die Soldering         cracking
•   Surface Shrinkage   • Hot tearing
                        • Internal porosity
Cold Shuts


• Defined as surface lappings of
  solidified metal on die castings.
• Caused by premature solidification of
  flowing metal.
• Results in line defects at stream
  intersections
Cold Shuts


• Important Control Variables:
  –   Cavity fill time
  –   Gate velocity
  –   Die & metal temperatures
  –   Flow pattern in cavity.


• Cold shuts cannot be removed by
  intensification.
Cold Shut Regions



          ( a)                         (b)




(a)Surface view of a cold-   (b) Higher Magnification
Shut region of a casting      view of center field in
                             “(a)”
Cold shut in a zinc       Cold lap in a zinc
      diecasting        diecasting electroplated
    conventionally        conventionally after
 electroplated after       mechanical buffing
polishing and buffing
Eliminating Cold Shuts



• Cavity fill time should be 20 ms or less for
  casting 2 mm (0.080 in) or thinner for
  chrome plating.
• Painted castings can tolerate fill times up
  to 40 ms.
• Die temperature should be at least 200ºC
  (390ºF) on the surface.
• Runner and gates should be designed to
  produce uniform cavity fill.
Eliminating Cold Shuts




• Heat transfer can be retarded by auxiliary
  heaters, textured dies & die coatings.
• Cold shuts shallower than 0.05 mm (0.002
  in) can be removed by buffing.
• Excessive buffing or sanding can expose
  subsurface porosity.
• Cold shuts act like “notches” can cause
  brittle fracture.
Examples of thin laps being
Lifted by plating layer stresses
Views of shallow laps that usually
   can be removed by buffing
Blisters



• Caused by expansion of gases or
  corrosion products trapped in pores near
  plated surface.
• Gas in pores is nitrogen or hydrogen
  (from mold lubricant).
• Usually form during premature ejection
  from die or baking or heat treatment of
  casting.
• Blisters can also occur if a lap is not
  completely removed – plating stresses lift
  off the poorly-bonded joint.
Exfoliation of a zinc   Skin blister in a zinc
      diecasting               diecasting
conventionally plated        conventionally
  after mechanical        electroplated after
        buffing          polishing and buffing
Surface Porosity: Blisters

• Minimize blistering due to subsurface porosity
  by limiting ejection temperature.
• Minimize blistering due to gas porosity by
  minimizing trapped gases in casting. Improve
  feed system, eliminate sharp corners.
• Gas should be forced into less critical regions of
  the casting.
• Increase gate velocity to decrease size of
  pores.
• Cooler dies will make pores form more in
  center of casting.
Small surface pores in a   Large surface pores in
    zinc diecasting           a zinc diecasting
     conventionally             conventionally
  electroplated after        electroplated after
 polishing and buffing      polishing and buffing
Examples of blistering of casting
     during paint baking
Views of Castings with Extensive
        Surface Lapping




 As-Cast and Plated   After a paint baking
                        heat treatment
Die Soldering



• Defined as fusion of cast metal to die steel
  during casting – sometimes referred to as
  buildup.
• Can be caused by direct impingement of
  molten metal stream on a flat surface, die
  erosion, high die temperature or
  insufficient draft angles.
• Soldering due to die erosion usually occurs
  near the gate – eroded or pitted areas
  occur.
Die Soldering




• Insufficient draft angles or high die
  temperatures can also roughen the die
  surface, encouraging soldering.
• Best solution is to use a good die
  lubricant, combined with good metal flow
  and uniform die temperatures.
Defects Cause by Hot Spots



• High die temperatures used to improve surface
  quality.
   – Each increase in die temperature of 11ºC
     (20ºF) above 200ºC (390ºF) has same effect as
     increasing fill time by 2 ms.

• Defects include:
  1. Surface Shrinks     3. Solidification cracking
  2. Laking or Waving    4. Hot tears
Surface Shrinkage



• Usually coincides with hot surface spots on
  die.
• Caused by delayed solidification in this
  area compared to surrounding
  areas, hence increased contraction.
• Shrinkage areas are shiny on Zamak
  alloys, frosty on ZA alloys.
Views of Surface Shrinks on a ZA Casting




    Surface Shrinks    Close-up View of
                       Surface within a
                        Shrinkage area
Laking or Waving




• Defined as large, irregular patches on die
  casting surface – can be sunken or raised.
• Vary in size & shape, but always in same
  general area of casting – can have height
  difference of 0.025 mm (0.001 in.)
• Higher lakes are more rapidly cooled than
  surrounding areas.
Laking or Waving (Cont’d.)




• Buffing reveals transition lines between
  different solidified zones.
• Usually caused by over-heated
  dies, inadequate filling, poor die
  lubrication.
• Better fill times can also reduce laking
Views of Lake Areas in Casting



A                     B




Example of a lake     Microstructure in
on a plated casting      lake area of
                      casting in Fig. “A”
Surface waviness on a    Small nodules on a zinc
 zinc diecasting after         diecasting
  electroplating with      electroplated with
 leveling copper and      leveling copper and
         nickel                  nickel
Solidification Cracking



• Occurs if feeding of area is restricted.
• Usually occurs when thick sections are
  fed by thin ones – shrinkage occurs in
  the last area to freeze (hottest area).
• Rare in Zamak alloys because of low
  freezing range & normal presence of
  entrapped gas. Gas maintains pressure
  and feeding
Solidification Cracking



A                         B




Solidification cracking   Solidification cracks at
of a bulky & complex         inside surface of
casting                     casting in Fig. “A”
Hot Tearing



• Begins along inside corners of casting if
  thermal contraction is hindered
• Occurs when an outside corner of the die
  is over-heated
• Solidification of the corner is retarded,
  freezing & contraction of metal on either
  side applies stress, resulting in cracks to
  semi-solid metal
Hot Tearing (Cont’d.)




• Can occur with bosses and along length of
  a gate, where it is confused with trimming
  damage
• To eliminate, control die temperature, die
  cooling methods, make part inside radii as
  large as possible
• A minimum radius of 2 mm (0.08 in.) is
  desired
Hot tear crack along the base of a ridge on
                 a casting


                       A   B




        As-polished            Higher magnification
       View of crack           etched view of crack
                                  at lower arrow
                                location in Fig. “A”
Hot tear cracks




                                                          B

A
Edge view of hot-tear crack      View of similar casting
 along the length of a gate   as shown in Fig. “A” but with
      after trimming                 gate attached
Internal Porosity


• Distinct from subsurface porosity that
  causes blisters
• Internal porosity revealed by trimming,
  machining. Must be removed before
  plating
• Can also cause leaks in fluid handling
  components.
• Important factors for porosity size and
  distribution are metal flow system,
  venting & die temperature
Internal Porosity (Cont’d.)



• Fill patterns must be uniform.
• Gate velocity should exceed 35 m/s (115
  ft/sec) for atomized flow
• Vents remove entrapped gas.
• Die & metal temperature, together with
  cooling system, also affect porosity.
• Rapid solidification traps gas throughout
  the casting.
Gate pores exposed
By trimming




Gate pore with
small opening; no
plating of inner
surface




Gate pore with
plating of inner
surfaces & corrosion
lower down
Gate Pores (cont’d.)




                                                                B


                                    Large gate pores in water
    Original small gate pore
                                    Hose gun casting exposed
      Enlarged by action of
                                    By machining to create a
   Accelerated corrosion test.
                                         “leaker.” (X10)
Upper polished view (X100); lower
       Etched view (X200)
The depth of surface defects in a sample of
        defective zinc diecastings
Inspecting Zn Diecastings

Need to identify defects requiring excessive polishing or
buffing
Inspection should be nondestructive and rapid
Dye penetrant is best of non-visual methods, but
improved lighting techniques allow visual inspection to
be preferred method
Best for first inspection to occur after trimming. Need to
sort into
-Diecastings with no plating problems
-Salvageable castings using economical
polishing, buffing or vibratory milling
-Castings that would still show defects after finishing
and plating that should be scrapped
Evaluation of 9 nondestructive methods for
inspecting zinc diecastings for surface defects
Recommended
lighting
arrangements for
as-cast surfaces




Recommended
lighting
arrangements for
polished surfaces
Recommended
lighting
arrangements for
plated surfaces
As-cast surface illuminated to a
level of more than 2700 Lux (250
  foot candles) with a mixture of
      direct and diffused light
Well-diffused light source   Patterned light source


  Buffed surface illuminated to a level
   of more than 2700 Lux (250 foot
   candles) with a mixture of direct
           and diffused light
Visual Inspection

Almost all fissures and pits on a typical
diecasting are< 50µm, at limit of human eye,
but good lighting can allow visual inspection
Polarized light reduces glare but prevents
viewing of fissures and pits
Laser lighting produced granular surface
appearance, limiting its sensitivity
Smooth castings, including those inspected
after polishing and buffing, give high reflectivity
surfaces and therefore different lighting
requirements than as-cast surfaces.
Preparation for Electroplating
Design for Finishing
Position parting line, gates, vents, overflows
and ejectors on insignificant surfaces
Locate gates to produce sound castings with
good surface quality, in locations avoiding
marks left after breaking or shearing
Avoid sharp edges, corners or protrusions that
can cause excessive wear on polishing wheels
or belts
For barrel plating, avoid plain flat surfaces that
hay cause castings to stick together
Design for fixturing to allow use of automatic or
semi-automatic equipment
Die Preparation

Polishing of die to reduce roughness to maximum of
0.2µm will increase die cost moderarately but can
substantially reduce expensive polishing and buffing
Oxide films on the die surface are beneficial for
eliminating soldering and reducing heat loss
A thin crack-free Cr plating layer can be inexpensively
stripped and replaced. Cr plate must be compressively
stressed to prevent cracking and spalling. Solutions of
chromic, sulfuric and fluosilic acid used at 40-43°C to
deposit compressively stressed Cr with minimum
thickness of 10µm
Electroless Ni on clean die surfaces can also produce
durable surface
Polishing Belts and Wheels


Removal of metal with abrasive, especially rough edges
after trimming
Slurry finishing involves rapid movement of castings, ie
by spinning, in abrasive
Use of coarser (240 grit) abrasive followed by fine
allow for polishing of both jagged, wide burrs and finer
parting lines etc
Vibratory finishing faster than barrel tumbling
(abrasive-loaded plastic chips)
Finishes of 3-5µm possible with vibratory finishing, can
be reduced to 1-2µm by level plating
Conditions for mechanically polishing and buffing
                zinc diecastings
Buffing – moves metal from microprojections to
              microdepressions

  Surface temperature must be >120°C, preferably
  >150°C
  Surface roughness after buffing is 2-3µm
  Good vibratory finishing and levelling plating can
  make buffing unneccessary
  Removal of buffing compound from recesses can be
  difficult

  Electropolishing can be used to remove burrs and
  fissure-like defects up to 50-75µm, but can expose
  subsurface pores
  Subsurface pores can be completely filled with
  leveling copper
Surface roughness variations resulting from some
         polishing and buffing operations
    Surface roughnesses after plating refer to
         leveling electroplate in all cases
             1 microinch= 0.0254µm
Metal removal rate for salvaging defective
    diecastings in vibratory machines
Metal removal rate during vibratory finishing with
             chemical accelerators
Alkaline electropolishing
bath for zinc diecastings




Acid electropolishing
bath for zinc
diecastings
Alkaline cleaning solutions for zinc diecastings
Typical cycles for plating of zinc diecastings
Plating costs vs plating time to deposit a specified
                minimum thickness
The 4 basic kinds of plating rack construction
Single spline rack showing door handles jigged to
  prevent excessive buildup of plate at the tips
Thickness variations for electroplated nickel in a a
    groove with a width-to-depth ratio of 0.85
Variations in electroplate thickness over various
                     shapes
Effect of anode size and position on the thickness
             variations on electroplate
The cathode robbers
of each corner of the
workpiece are in
electrical contact
with the workpiece

4 curved plastic
shields are
placed one at
each corner of
the workpiece
Plating rack with integrated, hinged current
 shields for improving coating thickness of
               electrodeposits
Integrated plating rack showing auxiliary anode
  for obtaining uniform coating thickness on a
                    diecasting
Section of plating
Section of rack           rack equipped
equipped with auxiliary   with auxiliary
nickel anodes             nickel anodes to
 to increase coating      improve thickness
thickness of Ni and Cr    uniformity on
around                    automobile
headlamp doors            handles
Distribution of nickel on an automobile door
handle resulting in 400% waste of metal on high
              current density areas
Copper-nickel-chromium coatings on zinc
             diecastings (ASTM B456)
All applied on undercoat of copper or yellow brass
      with thickness of at least 5µm (0.2mil)
Recommendations for plating zinc diecastings

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Defects and electroplating

  • 1. Production of Zinc Diecastings for Electroplating
  • 2. Relative costs of fabricating, finishing and plating zinc diecastings
  • 3. Some Design Rules Mimimum crown of 0.15cm per cm If flat surfaces required, use satin instead of bright finish to hide waviness All edges should be rounded off to radius of at least 0.4mm, preferably 0.8mm Reduce depth of concave recesses as much as possible, avoid depths greater than 50% of width If sharply angled grooves are needed, paint the bottom of the grooves, it is cheaper than plating the bottom of the grooves Slots and holes shown have widths at least 2X their depth Spaces between slots should be spaced so that spacing between their centers is 4X their width Blind hole depths should be less than ½ their width and blind holes <5.6mm diameter should be avoided Threaded holes should be countersunk to minimize buildup on their outside The height of fins and ribs should be reduced as much as possible with radius>1.6mm at base Parallel fins should be spaced so distance between centers is >4X fin width Recessed letters preferred to raised letter. Raised letter heights should be <50% of their width If studs threaded before plating, max thickness is 5µm Drain holes should be provided in cup-like contours to avoid hand rinsing
  • 4. Design factors influencing platability of zinc diecastings
  • 5. Minimum radii for angles defined by indentations
  • 6. Checklist for High Quality Castings Properly designed and constructed dies Smooth working, run-in casting machines Correct alloy composition Good melting and delivery practice, proper die lubrication Correct injection and trimming procedures
  • 7. Die Design Guidelines Plan for location of ejector pins to prevent marks in visible areas, or place on areas that can be easily polished Fill thick sections before thin to allow progressive cooling Alloy should reach vents and overflows last to allow complete die cavity filling Place vents at parting line to allow easy removal of flash Surfaces required to slide on cavity during ejection should be tapered Castings with defects >50µm are not salvageable
  • 8. Cross sections of rough surface diecastings plated with bright copper in cyanide and acid baths, then with leveling duplex nickel
  • 9.
  • 10. Casting Fluidity • Zamak Alloys are more fluid than ZA Alloys. • Aluminum increases fluidity for Zamak Alloys – keep Al to high side of range. • Magnesium decreases fluidity, but not as much as aluminum changes.
  • 11. Fluidity of Zinc Die Casting Alloys Ragone Fluidity, Inches Aluminum, Weight Percent
  • 12. Solidification Ranges Zamak alloys have smaller freezing ranges than ZA alloys Alloy Solidification Range ºC ( ºF ) Alloy 3 6 (11) ZA-8 29 (52) ZA-12 55 (100) ZA-27 112 (202) Therefore, shrinkage porosity rarely occurs in Zamak alloys
  • 13. Casting Limits Integranular corrosion can be caused by high levels of Pb, Cd, Sn Casting Limits Zamak 3 Zamak 5 Pb (max) 50 ppm 50 ppm Cd (max) 40 ppm 40 ppm Sn (max) 30 ppm 30 ppm ZA contaminant levels are similar
  • 14. Effect of humidity test on zinc-aluminum alloy containing cadmium Discolored & As cast plate Cracked humidity-tested panels
  • 15. As-polished structure of humidity-tested zinc aluminum alloy containing cadmium showing a crack and intergranular corrosion
  • 16. Intermetallics • Intermetallics are mostly Fe-Al: – Leave “comet tails” after buffing. – Can be removed by stirring, letting the bath stand and skimming. – Machining (tool wear) problems can also result.
  • 17. Surface dross laden with large and smallFeAl3 intermetallic particles
  • 18. Tool Wear – ZA-27 Die Casting Many large FeAl3 particles Mean Wear Land Width (mm ) (0.07% Fe) Mean Wear Land Width (in.) Many small FeAl3 particles (0.22% Fe) Drilling Time (min.)
  • 19. Cosmetic Defects • Cold Shuts • Flaking or waving • Blisters • Solidification • Die Soldering cracking • Surface Shrinkage • Hot tearing • Internal porosity
  • 20. Cold Shuts • Defined as surface lappings of solidified metal on die castings. • Caused by premature solidification of flowing metal. • Results in line defects at stream intersections
  • 21. Cold Shuts • Important Control Variables: – Cavity fill time – Gate velocity – Die & metal temperatures – Flow pattern in cavity. • Cold shuts cannot be removed by intensification.
  • 22. Cold Shut Regions ( a) (b) (a)Surface view of a cold- (b) Higher Magnification Shut region of a casting view of center field in “(a)”
  • 23. Cold shut in a zinc Cold lap in a zinc diecasting diecasting electroplated conventionally conventionally after electroplated after mechanical buffing polishing and buffing
  • 24. Eliminating Cold Shuts • Cavity fill time should be 20 ms or less for casting 2 mm (0.080 in) or thinner for chrome plating. • Painted castings can tolerate fill times up to 40 ms. • Die temperature should be at least 200ºC (390ºF) on the surface. • Runner and gates should be designed to produce uniform cavity fill.
  • 25. Eliminating Cold Shuts • Heat transfer can be retarded by auxiliary heaters, textured dies & die coatings. • Cold shuts shallower than 0.05 mm (0.002 in) can be removed by buffing. • Excessive buffing or sanding can expose subsurface porosity. • Cold shuts act like “notches” can cause brittle fracture.
  • 26. Examples of thin laps being Lifted by plating layer stresses
  • 27. Views of shallow laps that usually can be removed by buffing
  • 28. Blisters • Caused by expansion of gases or corrosion products trapped in pores near plated surface. • Gas in pores is nitrogen or hydrogen (from mold lubricant). • Usually form during premature ejection from die or baking or heat treatment of casting. • Blisters can also occur if a lap is not completely removed – plating stresses lift off the poorly-bonded joint.
  • 29. Exfoliation of a zinc Skin blister in a zinc diecasting diecasting conventionally plated conventionally after mechanical electroplated after buffing polishing and buffing
  • 30. Surface Porosity: Blisters • Minimize blistering due to subsurface porosity by limiting ejection temperature. • Minimize blistering due to gas porosity by minimizing trapped gases in casting. Improve feed system, eliminate sharp corners. • Gas should be forced into less critical regions of the casting. • Increase gate velocity to decrease size of pores. • Cooler dies will make pores form more in center of casting.
  • 31. Small surface pores in a Large surface pores in zinc diecasting a zinc diecasting conventionally conventionally electroplated after electroplated after polishing and buffing polishing and buffing
  • 32. Examples of blistering of casting during paint baking
  • 33. Views of Castings with Extensive Surface Lapping As-Cast and Plated After a paint baking heat treatment
  • 34. Die Soldering • Defined as fusion of cast metal to die steel during casting – sometimes referred to as buildup. • Can be caused by direct impingement of molten metal stream on a flat surface, die erosion, high die temperature or insufficient draft angles. • Soldering due to die erosion usually occurs near the gate – eroded or pitted areas occur.
  • 35. Die Soldering • Insufficient draft angles or high die temperatures can also roughen the die surface, encouraging soldering. • Best solution is to use a good die lubricant, combined with good metal flow and uniform die temperatures.
  • 36. Defects Cause by Hot Spots • High die temperatures used to improve surface quality. – Each increase in die temperature of 11ºC (20ºF) above 200ºC (390ºF) has same effect as increasing fill time by 2 ms. • Defects include: 1. Surface Shrinks 3. Solidification cracking 2. Laking or Waving 4. Hot tears
  • 37. Surface Shrinkage • Usually coincides with hot surface spots on die. • Caused by delayed solidification in this area compared to surrounding areas, hence increased contraction. • Shrinkage areas are shiny on Zamak alloys, frosty on ZA alloys.
  • 38. Views of Surface Shrinks on a ZA Casting Surface Shrinks Close-up View of Surface within a Shrinkage area
  • 39. Laking or Waving • Defined as large, irregular patches on die casting surface – can be sunken or raised. • Vary in size & shape, but always in same general area of casting – can have height difference of 0.025 mm (0.001 in.) • Higher lakes are more rapidly cooled than surrounding areas.
  • 40. Laking or Waving (Cont’d.) • Buffing reveals transition lines between different solidified zones. • Usually caused by over-heated dies, inadequate filling, poor die lubrication. • Better fill times can also reduce laking
  • 41. Views of Lake Areas in Casting A B Example of a lake Microstructure in on a plated casting lake area of casting in Fig. “A”
  • 42. Surface waviness on a Small nodules on a zinc zinc diecasting after diecasting electroplating with electroplated with leveling copper and leveling copper and nickel nickel
  • 43. Solidification Cracking • Occurs if feeding of area is restricted. • Usually occurs when thick sections are fed by thin ones – shrinkage occurs in the last area to freeze (hottest area). • Rare in Zamak alloys because of low freezing range & normal presence of entrapped gas. Gas maintains pressure and feeding
  • 44. Solidification Cracking A B Solidification cracking Solidification cracks at of a bulky & complex inside surface of casting casting in Fig. “A”
  • 45. Hot Tearing • Begins along inside corners of casting if thermal contraction is hindered • Occurs when an outside corner of the die is over-heated • Solidification of the corner is retarded, freezing & contraction of metal on either side applies stress, resulting in cracks to semi-solid metal
  • 46. Hot Tearing (Cont’d.) • Can occur with bosses and along length of a gate, where it is confused with trimming damage • To eliminate, control die temperature, die cooling methods, make part inside radii as large as possible • A minimum radius of 2 mm (0.08 in.) is desired
  • 47. Hot tear crack along the base of a ridge on a casting A B As-polished Higher magnification View of crack etched view of crack at lower arrow location in Fig. “A”
  • 48. Hot tear cracks B A Edge view of hot-tear crack View of similar casting along the length of a gate as shown in Fig. “A” but with after trimming gate attached
  • 49. Internal Porosity • Distinct from subsurface porosity that causes blisters • Internal porosity revealed by trimming, machining. Must be removed before plating • Can also cause leaks in fluid handling components. • Important factors for porosity size and distribution are metal flow system, venting & die temperature
  • 50. Internal Porosity (Cont’d.) • Fill patterns must be uniform. • Gate velocity should exceed 35 m/s (115 ft/sec) for atomized flow • Vents remove entrapped gas. • Die & metal temperature, together with cooling system, also affect porosity. • Rapid solidification traps gas throughout the casting.
  • 51. Gate pores exposed By trimming Gate pore with small opening; no plating of inner surface Gate pore with plating of inner surfaces & corrosion lower down
  • 52. Gate Pores (cont’d.) B Large gate pores in water Original small gate pore Hose gun casting exposed Enlarged by action of By machining to create a Accelerated corrosion test. “leaker.” (X10) Upper polished view (X100); lower Etched view (X200)
  • 53. The depth of surface defects in a sample of defective zinc diecastings
  • 54. Inspecting Zn Diecastings Need to identify defects requiring excessive polishing or buffing Inspection should be nondestructive and rapid Dye penetrant is best of non-visual methods, but improved lighting techniques allow visual inspection to be preferred method Best for first inspection to occur after trimming. Need to sort into -Diecastings with no plating problems -Salvageable castings using economical polishing, buffing or vibratory milling -Castings that would still show defects after finishing and plating that should be scrapped
  • 55. Evaluation of 9 nondestructive methods for inspecting zinc diecastings for surface defects
  • 58. As-cast surface illuminated to a level of more than 2700 Lux (250 foot candles) with a mixture of direct and diffused light
  • 59. Well-diffused light source Patterned light source Buffed surface illuminated to a level of more than 2700 Lux (250 foot candles) with a mixture of direct and diffused light
  • 60. Visual Inspection Almost all fissures and pits on a typical diecasting are< 50µm, at limit of human eye, but good lighting can allow visual inspection Polarized light reduces glare but prevents viewing of fissures and pits Laser lighting produced granular surface appearance, limiting its sensitivity Smooth castings, including those inspected after polishing and buffing, give high reflectivity surfaces and therefore different lighting requirements than as-cast surfaces.
  • 62. Design for Finishing Position parting line, gates, vents, overflows and ejectors on insignificant surfaces Locate gates to produce sound castings with good surface quality, in locations avoiding marks left after breaking or shearing Avoid sharp edges, corners or protrusions that can cause excessive wear on polishing wheels or belts For barrel plating, avoid plain flat surfaces that hay cause castings to stick together Design for fixturing to allow use of automatic or semi-automatic equipment
  • 63. Die Preparation Polishing of die to reduce roughness to maximum of 0.2µm will increase die cost moderarately but can substantially reduce expensive polishing and buffing Oxide films on the die surface are beneficial for eliminating soldering and reducing heat loss A thin crack-free Cr plating layer can be inexpensively stripped and replaced. Cr plate must be compressively stressed to prevent cracking and spalling. Solutions of chromic, sulfuric and fluosilic acid used at 40-43°C to deposit compressively stressed Cr with minimum thickness of 10µm Electroless Ni on clean die surfaces can also produce durable surface
  • 64. Polishing Belts and Wheels Removal of metal with abrasive, especially rough edges after trimming Slurry finishing involves rapid movement of castings, ie by spinning, in abrasive Use of coarser (240 grit) abrasive followed by fine allow for polishing of both jagged, wide burrs and finer parting lines etc Vibratory finishing faster than barrel tumbling (abrasive-loaded plastic chips) Finishes of 3-5µm possible with vibratory finishing, can be reduced to 1-2µm by level plating
  • 65. Conditions for mechanically polishing and buffing zinc diecastings
  • 66. Buffing – moves metal from microprojections to microdepressions Surface temperature must be >120°C, preferably >150°C Surface roughness after buffing is 2-3µm Good vibratory finishing and levelling plating can make buffing unneccessary Removal of buffing compound from recesses can be difficult Electropolishing can be used to remove burrs and fissure-like defects up to 50-75µm, but can expose subsurface pores Subsurface pores can be completely filled with leveling copper
  • 67. Surface roughness variations resulting from some polishing and buffing operations Surface roughnesses after plating refer to leveling electroplate in all cases 1 microinch= 0.0254µm
  • 68. Metal removal rate for salvaging defective diecastings in vibratory machines
  • 69. Metal removal rate during vibratory finishing with chemical accelerators
  • 70. Alkaline electropolishing bath for zinc diecastings Acid electropolishing bath for zinc diecastings
  • 71. Alkaline cleaning solutions for zinc diecastings
  • 72. Typical cycles for plating of zinc diecastings
  • 73. Plating costs vs plating time to deposit a specified minimum thickness
  • 74. The 4 basic kinds of plating rack construction
  • 75. Single spline rack showing door handles jigged to prevent excessive buildup of plate at the tips
  • 76. Thickness variations for electroplated nickel in a a groove with a width-to-depth ratio of 0.85
  • 77. Variations in electroplate thickness over various shapes
  • 78. Effect of anode size and position on the thickness variations on electroplate
  • 79. The cathode robbers of each corner of the workpiece are in electrical contact with the workpiece 4 curved plastic shields are placed one at each corner of the workpiece
  • 80. Plating rack with integrated, hinged current shields for improving coating thickness of electrodeposits
  • 81. Integrated plating rack showing auxiliary anode for obtaining uniform coating thickness on a diecasting
  • 82. Section of plating Section of rack rack equipped equipped with auxiliary with auxiliary nickel anodes nickel anodes to to increase coating improve thickness thickness of Ni and Cr uniformity on around automobile headlamp doors handles
  • 83. Distribution of nickel on an automobile door handle resulting in 400% waste of metal on high current density areas
  • 84. Copper-nickel-chromium coatings on zinc diecastings (ASTM B456) All applied on undercoat of copper or yellow brass with thickness of at least 5µm (0.2mil)
  • 85. Recommendations for plating zinc diecastings