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BIOLEACHING OF IRON ,
COPPER, GOLD, URANIUM
PRESENTED BY:
Mousami Jaria
St. Geeorge College of Management
and Science
MSc Microbiology
Semester 2
BIOLEACHING
• It is the extraction of metal from sulfide ores or
concentrates using materials found native to the
environment namely water, air, microorganisms.
• It is the leaching of sulfide minerals that
distinguishes bioleaching from conventional acid
leaching wherein only oxidized minerals are
leached.
• Biooxidation is an associated process,it is the
oxidation of sulfide minerals associated with but
not necessarily part of the mineral to be
extracted.
• Bioleaching is used to process ores of copper,
nickel, cobalt, zinc, uranoum whereas
biooxidation is used in gold processing .
• Widely used in countries like Australia,
Canada, Chile, China, Indonesia,US, Zambia.
• Started around 1940s.
OVERVIEW OF BIOLEACHING PLANT
MICROORGANISMS INVOLVED
• The commonly used microorganisms in
bioleaching are:
o Thiobacillus thiooxidans
o Thiobacillus ferrooxxidans
• FUNGI:
Aspergillus niger, Penicillium simplicissimum
• Others involved are : Bacillus licheniformis,
B. luteus, Pseudomonas fluorescence, Sulfolobus
acidocaldarius etc.
Cadmium sulfideThiobacillus
MECHANISM
1. DIRECT BIOLEACHING:
• In this bioleaching , bacteria directly oxidize
minerals and solubilize metals.
• A physical contact exists between bacteria
and ores and oxidation of minerals takes
place through enzymatically catalysed steps
• Eg: pyrite oxidised to ferric sulphate
2FeS2 +7O2 2FeSO4 + 2H2SO4
2. INDIRECT BIOLEACHING:
• In this type , bacteria produces the strong
oxidizing agent such as ferric ion and sulphuric
acid on oxidation of soluble iron or soluble
sulfur respectively.
• Acidic environment is absolutely essential in
order to keep ferric iron and other metals in
solution.
• Acidic environment is maintained by oxidation
of iron, sulfur, metal sufides or by dissolution of
carbonate ions
• Eg: bioleaching of uranium
UO2+ Fe(SO4) UO2SO4+2FeSO4
COMMERCIAL BIOMINING PROCESS
1. SLOPE LEACHING:
• Fine ore is kept in large slope shaped dump.
• A water solution made of inoculum is
continuously sprayed over the ore.
• After that , the leach liquor is gathered at
the bottom and processed for supplemental
metal recovery.
2. HEAP LEACHING:
• The ore is arranged in large heaps .
• An aqueous mixture of microorganisms is
sprinkled over the leach pile.
• Then solution is collected to help recover
even more metal.
3. IN–SITU LEACHING:
• Ore remains in natural state while leaching
process takes place.
• Water that contain Thiobacillus is pushed
through drilled passageways within the ore
• The leach fluid is then stored untill its time for
metal recovery.
ADVANTAGES
• Simple
• Inexpensive
• Recovery of metals from low grade ore
• To extract expensive metals.
• Ideal for low grade sulfide ores.
• Environment friendly process.
• Employed for collecting metals from waste
and drainages.
DISADVANTAGES
• Low yield of minerals
• Time consuming ,6-24 months or longer.
• Requires large open area for treatment.
• Heat generated from dissolving process can
kill bacteria.
• High risk of contamination.
BIOLEACHING OF COPPER
• Chalcopyrite(CuFeS2), Covellite (CuS),
Chalcolite(Cu2S) are ores of copper from which
copper is recovered.
• Carried out by heap leaching or Insitu leaching.
• Action of acidithiobacillus involves the oxidation
of CuFeS2.
CuFeS2 + 4O2 Cu2 + Fe2 + 2SO42-
• Sulphuric acid is the byproduct of this reaction . It
maintains necessary acidic environment for
extraction.
BIOLEACHING OF IRON
• Iron ores: Hematite(FeO3), Magnetite(Fe3O4),
Limonite(2FeO3.3H2O), Siderite(FeCO3).
• The oxygen must be removed from the iron
(Fe3) oxide in order to leave the iron behind.
• Acidithiobacillus ferrooxidans are used as
bacterial agents.
• Maximum extraction occurs at pH 1.3
Fe2O3+3CO 2Fe+3CO2
BIOLEACHING OF GOLD
• Gold ores: Calaverite ( AuTe2),
Sylvanite(Ag.Au)Te2, Petzite ( Ag3AuTe2).
• Gold cannot be extracted from low grade
sulfide ores.
• Iron and Sulfur acidophillic bacteria are able
to oxidize certain sulphidic ores. Thiobacillus
ferrooxidans is used in process
• Gold ore is first pretreated by roasting or
pressure oxidation.
4 Au+8NaCN + 2H2O+O2 4Na(Au(CN)2)+
4 NaOH.
2Na (Au(CN)2)+ Zn Na(Zn(CN)4)+2Au
• Heap leaching technology is used.
BIOLEACHING OF URANIUM
• Uranium ores : Uraninite or Pitchblende (UO2),
Brannerite(UTi2O6).
• Uranium ores occur in low grade ores and is
insoluble, converted to leachable form by
oxidation of ferric ion.
• Insitu bioleaching technique used.
UO2+Fe(SO4)3 UO2SO4+2FeSO4
• In this process T. ferroxidants acts on iron
oxidant and not directly on uranium.
• It acts on pyrite (FeS2) in uranium ore and
produces ferric sulphate and sulphuric acid
• The soluble form of uranium is in leach liquor
is extracted in organic solvents like trimethyl
phosphate, precipitated and recovered.
THANK YOU

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Bioleaching of iron, copper, gold. uranium

  • 1. BIOLEACHING OF IRON , COPPER, GOLD, URANIUM PRESENTED BY: Mousami Jaria St. Geeorge College of Management and Science MSc Microbiology Semester 2
  • 2. BIOLEACHING • It is the extraction of metal from sulfide ores or concentrates using materials found native to the environment namely water, air, microorganisms. • It is the leaching of sulfide minerals that distinguishes bioleaching from conventional acid leaching wherein only oxidized minerals are leached. • Biooxidation is an associated process,it is the oxidation of sulfide minerals associated with but not necessarily part of the mineral to be extracted.
  • 3. • Bioleaching is used to process ores of copper, nickel, cobalt, zinc, uranoum whereas biooxidation is used in gold processing . • Widely used in countries like Australia, Canada, Chile, China, Indonesia,US, Zambia. • Started around 1940s.
  • 5. MICROORGANISMS INVOLVED • The commonly used microorganisms in bioleaching are: o Thiobacillus thiooxidans o Thiobacillus ferrooxxidans • FUNGI: Aspergillus niger, Penicillium simplicissimum • Others involved are : Bacillus licheniformis, B. luteus, Pseudomonas fluorescence, Sulfolobus acidocaldarius etc.
  • 7. MECHANISM 1. DIRECT BIOLEACHING: • In this bioleaching , bacteria directly oxidize minerals and solubilize metals. • A physical contact exists between bacteria and ores and oxidation of minerals takes place through enzymatically catalysed steps • Eg: pyrite oxidised to ferric sulphate 2FeS2 +7O2 2FeSO4 + 2H2SO4
  • 8. 2. INDIRECT BIOLEACHING: • In this type , bacteria produces the strong oxidizing agent such as ferric ion and sulphuric acid on oxidation of soluble iron or soluble sulfur respectively. • Acidic environment is absolutely essential in order to keep ferric iron and other metals in solution. • Acidic environment is maintained by oxidation of iron, sulfur, metal sufides or by dissolution of carbonate ions • Eg: bioleaching of uranium UO2+ Fe(SO4) UO2SO4+2FeSO4
  • 9. COMMERCIAL BIOMINING PROCESS 1. SLOPE LEACHING: • Fine ore is kept in large slope shaped dump. • A water solution made of inoculum is continuously sprayed over the ore. • After that , the leach liquor is gathered at the bottom and processed for supplemental metal recovery.
  • 10. 2. HEAP LEACHING: • The ore is arranged in large heaps . • An aqueous mixture of microorganisms is sprinkled over the leach pile. • Then solution is collected to help recover even more metal. 3. IN–SITU LEACHING: • Ore remains in natural state while leaching process takes place.
  • 11. • Water that contain Thiobacillus is pushed through drilled passageways within the ore • The leach fluid is then stored untill its time for metal recovery.
  • 12. ADVANTAGES • Simple • Inexpensive • Recovery of metals from low grade ore • To extract expensive metals. • Ideal for low grade sulfide ores. • Environment friendly process. • Employed for collecting metals from waste and drainages.
  • 13. DISADVANTAGES • Low yield of minerals • Time consuming ,6-24 months or longer. • Requires large open area for treatment. • Heat generated from dissolving process can kill bacteria. • High risk of contamination.
  • 14. BIOLEACHING OF COPPER • Chalcopyrite(CuFeS2), Covellite (CuS), Chalcolite(Cu2S) are ores of copper from which copper is recovered. • Carried out by heap leaching or Insitu leaching. • Action of acidithiobacillus involves the oxidation of CuFeS2. CuFeS2 + 4O2 Cu2 + Fe2 + 2SO42- • Sulphuric acid is the byproduct of this reaction . It maintains necessary acidic environment for extraction.
  • 15.
  • 16. BIOLEACHING OF IRON • Iron ores: Hematite(FeO3), Magnetite(Fe3O4), Limonite(2FeO3.3H2O), Siderite(FeCO3). • The oxygen must be removed from the iron (Fe3) oxide in order to leave the iron behind. • Acidithiobacillus ferrooxidans are used as bacterial agents. • Maximum extraction occurs at pH 1.3 Fe2O3+3CO 2Fe+3CO2
  • 17. BIOLEACHING OF GOLD • Gold ores: Calaverite ( AuTe2), Sylvanite(Ag.Au)Te2, Petzite ( Ag3AuTe2). • Gold cannot be extracted from low grade sulfide ores. • Iron and Sulfur acidophillic bacteria are able to oxidize certain sulphidic ores. Thiobacillus ferrooxidans is used in process • Gold ore is first pretreated by roasting or pressure oxidation.
  • 18. 4 Au+8NaCN + 2H2O+O2 4Na(Au(CN)2)+ 4 NaOH. 2Na (Au(CN)2)+ Zn Na(Zn(CN)4)+2Au • Heap leaching technology is used.
  • 19. BIOLEACHING OF URANIUM • Uranium ores : Uraninite or Pitchblende (UO2), Brannerite(UTi2O6). • Uranium ores occur in low grade ores and is insoluble, converted to leachable form by oxidation of ferric ion. • Insitu bioleaching technique used. UO2+Fe(SO4)3 UO2SO4+2FeSO4 • In this process T. ferroxidants acts on iron oxidant and not directly on uranium.
  • 20. • It acts on pyrite (FeS2) in uranium ore and produces ferric sulphate and sulphuric acid • The soluble form of uranium is in leach liquor is extracted in organic solvents like trimethyl phosphate, precipitated and recovered.