Arteries carry oxygenated blood away from the heart to tissues throughout the body. As arteries branch into smaller vessels, they become capillaries that are only one cell thick, allowing for the exchange of oxygen and waste. Veins then carry deoxygenated blood back to the heart. Arteries have thicker walls than veins to withstand the force of blood being pumped from the heart. Capillaries form a network between arteries and veins and allow for chemical exchange through their thin, single-cell walls.