This document describes a study of 16 massive galaxies at z ~ 2 selected from the 3D-HST spectroscopic survey based on the detection of a strong 4000 Angstrom break in their spectra. Spectroscopy and imaging from HST/WFC3 are used to determine accurate redshifts, stellar population properties, and structural parameters. The sample significantly increases the number of spectroscopically confirmed evolved galaxies at z ~ 2 with robust size measurements. The analysis populates the mass-size relation and finds it is consistent with local relations but with smaller sizes by a factor of 2-3. A model is presented where the observed size evolution is explained by quenching of increasingly larger star-forming galaxies at a rate set by