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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 10 | Oct 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 200
Strength Development of Fly Ash based Geopolymer Concrete
Dr. M.B. Chougule
Associate Professor and H.O.D. in Civil Engineering, Textile and Engineering Institute, Ichalkaranji, Maharashtra, India
------------------------------------------------------------------------***-----------------------------------------------------------------------
Abstract:- In recent time, the importance and use of fly ash in
concrete has grown so much that it has almost become a
common ingredient in concrete, particularly for making high
strength and high performance concrete. Extensive research
has been done all over the world on the benefits that could be
accrued in the utilization of fly ash as a supplementary
cementitious material. High volume fly ash concrete as a
subject of current interest all over the world. The use of fly
ash a concrete admixture not only extends technical
advantages to the properties of concrete but also contributes
to the environmental pollution control. In India alone, we
produce about 100 million tons of fly ash per year, the
disposal of which has become a serious environmental
problem. The effective utilization of fly ash in concrete
making is, therefore attracting serious considerations of
concrete technologies and government departments.
Keywords:- Fly ash, ASTM Class F fly ash, Alkaline liquid, Geo
polymer concrete
1. INTRODUCTION
Geo polymer concrete show several advantages and
disadvantages over conventional concrete. Now a days the
concrete is one of the most widely used construction material,
it is usually associated with Portland cement as the main
component for making the concrete. The demand for
concrete as a construction material is increasing day by day.
The several efforts are in progress to reduce the use of
Portland cement in concrete in order to address the global
warming issues. In this respect the geo polymer technology
shows considerable promise for application in concrete
industry as an alternative binder to the Portland cement.
The scope of this project work is explained with the help of
methodology, research strategy and research design.
1.1 Methodology
The aim of present work is to study the physical, chemical
and mechanical properties of ingredients of fly ash based geo
polymer concrete. Also to study the structural behavior of
geo polymer concrete regarding to tensile and compressive
strength and design the concrete mix of geo polymer concrete
as well as to compare the geopolymer concrete with ordinary
Portland cement concrete according experimental analysis.
This research work is explained with the help of following
points:
1) Introduction to fly as based Geo polymer concrete.
2) To study the physical, chemical & mechanical properties of
ingredients.
3) Preparing the mix design for fly ash based geo polymer
concrete with different proportions.
4) Preparing blocks, cylinders & beams of concrete.
5) Testing the compressive and tensile strength of concrete.
6) To study experimental analysis and to find optimum
proportion for best concrete results.
2. RESEARCH STRATEGY
Considering the research objectives of the work, the focus is
on empirical evidence of the use of concrete in India in the
recent years. In order to give an actual and overall picture of
the use of Geo polymer concrete in India, the research needs
a strategy that can effectively provide depth of information.
Therefore a research strategy combines study of properties
of geo polymer concrete, material used for making it, actual
mix design of geo polymer concrete adopted to acquire
integrated and in-depth data. The data and material needed
in this research is mainly obtained by three methods: The
theoretical framework of Fly ash based Geo- polymer
concrete is derived from literature including previous studies
and research, the publications of the related agencies, social
institution and academic organizations.
3. MATERIAL USED
Geopolymer is an inorganic allumino-silicate polymer
synthesized from predominantly silicon (Si) and alluminum
(Al) materials of geological origin or by-product materials
such as fly ash. The term geopolymer was introduced by
Davidovits to represent the mineral polymers resulting from
geochemistry. The process involves a chemical reaction
under highly alkaline conditions on Si-Al minerals, yielding
polymeric Si-O-Al-O bonds in amorphous form. It has been
reported that geopolymer material does not suffer from
alkali-aggregate reaction even in the presence of high
alkalinity and possesses excellent fire resistant. Geopolymer
is used as the binder, instead of cement paste, to produce
concrete. The geopolymer paste binds the loose coarse
aggregates, fine aggregates and other un-reacted materials
together to form the geopolymer concrete. The manufacture
of geopolymer concrete is carried out using the usual
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 10 | Oct 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 201
concrete technology methods. As in the Portland cement
concrete, the aggregates occupy the largest volume, i.e. about
75-80 % by mass, in geopolymer concrete. The silicon and the
alluminium in the fly ash are activated by a combination of
sodium hydroxide and sodium silicate solutions to form the
geopolymer paste that binds the aggregates and other un-
reacted materials. Geopolymer-based materials are
environmentally friendly, and need only moderate energy to
produce. They can be made using industrial by-products,
such as fly ash, as the source material. In geopolymer
concrete, the geopolymer paste serves to bind the coarse and
fine aggregates, and any un-reacted material. Geopolymer
concrete can be utilized to manufacture precast concrete
structural and non-structural elements, to make concrete
pavements, to immobilize toxic wastes, and to produce
concrete products that are resistant to heat and aggressive
environments.
Fig. 1: Preparation of concrete
Geopolymer concrete is concrete which does not utilize any
Portland cement in its production. Rather, the binder is
produced by the reaction of an alkaline liquid with a source
material that is rich in silica and alumina. Geo polymers were
developed as a result of research into heat resistant materials
after a series of catastrophic fires. The research yielded non-
flammable and non-combustible geopolymer resins and
binders. Geopolymer is being studied extensively and shows
promise as a greener alternative to Portland cement concrete.
Research is shifting from the chemistry domain to
engineering applications and commercial production of
geopolymer. It has been found that geopolymer concrete has
good engineering properties.
3.1 Fly Ash
Fly ash is divided mainly into two categories based mainly on
its calcium content. ASTM Class F fly ash is low in calcium and
mainly pozzolanic (i.e., they react with calcium hydroxide in
moist condition to produce cementitious compounds),
whereas class C fly ash has higher fraction of calcium oxides,
which give them cementitious characteristics. Class C fly ash
is often marketed directly in many countries and finds easy
application in concrete as a part replacement of cement. Class
F fly ash (most Indian fly ash fall in this category) is primarily
used as a cement replacement under certain conditions of
quality in terms of chemical composition, particle size
distribution and loss on ignition (which is an indicator of
carbon content).
Table 1: Chemical Composition Class F Fly Ash
Oxides Quantity (%)
SiO2 50.18
Al2O3 26.31
Fe2O3 13.68
CaO 2.63
MgO 1.29
SO3 0.02
Na2O 0.32
K2O 0.53
TiO 1.66
SrO 0.30
P2O5 1.55
Mn2O3 0.09
The use of fly ash has additional environment advantages.
The annual production of fly ash in Australia in 2007 was
approximately 14.5 million tonnes of which only 2.3 million
tonnes were utilized in beneficial ways; principally for the
partial replacement of Portland cement . Development of
geopolymer technology and applications would see a
further increase in the beneficial use of fly ash, similar to
what has been observed in the last 14 years with the use
of fly ash in concrete and other building materials.
3.2 Alkaline Liquids
Sodium Hydroxide
Generally the sodium hydroxides are available in solid state
by means of pellets and flakes. The cost of the sodium
hydroxide is mainly varied according to the purity of the
substance. Since our geopolymer concrete is homogenous
material and its main process to activate the sodium silicate,
so it is recommended to use the lowest cost i.e. up to 94% to
96% purity. In this investigation the sodium hydroxide
pellets were used. Whose physical and chemical properties
are given by the manufacturer is shown in Table 2 & 3.
Table 2: Physical Properties Sodium hydroxide
Colour less Specific Gravity
20% 1.22
30% 1.33
40% 1.43
50% 1.53
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
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Sodium hydroxide pellets are taken and dissolved in the
water at the rate of 16 molar concentrations. It is strongly
recommended that the sodium hydroxide solution must be
prepared 24 hours prior to use and also if it exceeds 36
hours it terminate to semi solid liquid state. So the prepared
solution should be used within this time.
Sodium Silicate
Sodium silicate is also known as water glass or liquid glass,
available in liquid (gel) form. In present investigation sodium
silicate 2.0 (ratio between Na2O to SiO2) is used. As per the
manufacture, silicates were supplied to the detergent
company and textile industry as bonding agent. Same sodium
silicate is used for the making of geopolymer concrete. The
chemical properties and the physical properties of the
silicates are given the manufacture is shown as below:-
Table 3: physical properties of the silicates
Assay -97%
Min Carbonate
(Na2CO3)
-2% Max
Chloride (Cl ) -0.01% Max
Sulphate (SO2) -0.05% Max
Lead (Pb ) -0.001% Max
Iron (Fe) -0.001% Max
Potassium (K) -0.1% Max
Zinc (Zn) -0.02% Max
Fig. 2: Alkali solutions
3.4 Preparation of Alkaline Liquid
Dissolution:- Initially the vitreous component of the fly ash
(allumino silicate glass) in contact with the alkali solution
Sodium Hydroxide and Sodium Silicate is dissolved,
forming a series of complex ionic species.
3.3 Morality calculation
The solids must be dissolved in water to make a solution with
the required concentration. The concentration of Sodium
hydroxide solution can vary in different Molar. The mass of
Noah solids in a solution varies depending on the
concentration of the solution. For instance, Noah solution
with a concentration of 16 Molar consists of 16 x 40 = 640
grams of Noah solids per liter of the water, were 40 is the
molecular weight of Noah. Note that the mass of water is the
major component in both the alkaline solutions. The mass of
Noah solids was measured as 444 grams per kg of Noah
solution with a Concentration of 16 Molar. Similarly, the mass
of Noah solids per kg of the solution for other concentrations
was measured as 10 Molar: 314 grams, 12 Molar: 361 grams,
and 14 Molar: 404 grams.
Fig. 3: Mixing of contents
Alkaline liquid:-
Sodium based alkaline solutions were used to react with
the fly ash to produce the binder. Sodium-silicate solution
was used for the concrete production. The chemical
composition. Sodium hydroxide solution was prepared by
dissolving sodium hydroxide pellets in water. The pellets are
commercial grade with 97% purity thus 16 molar
solutions were made by dissolving 444 grams of sodium
hydroxide pellets in 556 g of water. The sodium hydroxide
solution was prepared one day prior to the concrete
batching to allow the exothermically heated liquid to cool to
room temperature. The Sodium silicate solution and the
sodium hydroxide solution were mixed just prior to the
concrete batching. Generally alkaline liquids are prepared by
mixing of the sodium hydroxide solution and sodium silicate
at the room temperature. When the solution mixed together
the both solution start to react i.e. polymerization takes place
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 10 | Oct 2019 www.irjet.net p-ISSN: 2395-0072
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it liberate large amount of heat so it is recommended to leave
it for about 24 hours thus the alkaline liquid is get ready as
binding agent .
Fig. 4: Alkaline liquid is get ready as binding agent
Polymerization
These small molecules present in the dissolution can join
each other and form large molecules that precipitate in the
form of gel, in which some degree of short range structural
order can be identified (10). The composition and structure
of this alkali alumina silicate gel depends essentially on the
size, structure and concentration of the ionic species present
in the medium, as well as on the synthesis temperature on
the curing time, and the pH of the mixture. The hypothetical
evolution of this gel would be to form some sort of zeolite
crystal. However, due to the very low “alkaline solution / fly
ash” ratio used in the synthesis of this type of materials (or
prevailing under experimental conditions), this evolution is
extremely slow. The studies done up to today concerning the
manufacturing of mortars and/or concretes of activated fly
ash following the alkaline process (without Portland cement)
turned out into very promising results. The above mentioned
studies have demonstrated for example that the properties of
the concrete of alkali activated fly ash are influenced, like
those of the conventional concrete, by a set of factors related
to the dosing of the mixture and to the conditions of the
curing process. Nevertheless, these new concrete can manage
to develop very high mechanical strength within a few hours.
These strengths continue to grow more slowly with time.
Also, the mentioned studies have manifested the high
potential of these materials that could be used in the near
future in the construction industry, especially in the precast
industry. This is the reason why the goal of this work is
focused on the establishment of some engineering properties
for this type of materials (mechanical strength development,
matrix-steel adherence and shrinkage). Finally, there is a
specific case of an industrial application of these new
concrete for the manufacturing of pre-stressed mono-block
sleeper son railroads.
Fig. 5: Fly ash before and after activation
4. EXPERIMENTAL ANALYSIS
Proportions
AS PER IS-10262-2009 & DOE METHOD
Table 4: I.S. and DOE trials
TYPE CEMENT
(kg/M3)
FINE AGGR.
(kg//M3)
COURSE AGGR.
(kg//M3)
WATER (kg//M3)
IS TRIAL 1 475 661 1255 189
RATIO 1 1.38 2.63 0.39
IS TRIAL 2 525 645 1229 189
RATIO 1 1.21 2.33 0.35
DOE TRIAL 1 410 588 1396 205
RATIO 1 1.42 3.39 0.49
DOE TRIAL 2 456 574 1364 205
RATIO 1 1.26 3.00 0.45
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 10 | Oct 2019 www.irjet.net p-ISSN: 2395-0072
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Proportions
AS PER MODIFIED GUIELINE FOR GEOPOLYMER CONRETE MIX DESIGN USING INDIAN STANDARD (IS-10262-2009):-
Table 5: Grade and ratio
GRADE FLY ASH
(kg//M3)
FINE AGGR.
(kg//M3)
COURSE
AGGR.
(kg//M3)
ALKALINE LIQUID EXTRA WATER
(kg//M3)SODIUM SILICATE
(kg//M3)
SODIUM
HYDROXIDE
(kg//M3)
M 500 500 487 1011 217.86 87.14 15
RATIO 1 0.96 2.01 0.60 0.03
M 550 550 445.2 924.65 239.64 95.86 16.5
RATIO 1 0.80 1.67 0.60 0.03
M 600 600 403.53 838.10 261.43 104.57 18
RATIO 1 0.63 1.32 0.60 0.03
M 650 650 361.87 751.58 283.21 113.28 19.5
RATIO 1 0.55 1.15 0.60 0.03
Compression test results of Indian standard method:-
Table 6: Compression Test IS Trial 1
DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT
CUBE 1 CUBE 2 CUBE 3 CUBE 1 CUBE 2 CUBE 3 CUBE 1 CUBE 2 CUBE 3
3 284.5 325.14 252.69 12.65 14.46 11.24 12.78 8903 8879 8851
7 661.96 672.76 627.08 29.43 29.91 27.88 29.07 8865 8938 9006
28 866.93 925.43 908.33 38.53 41.13 40.37 40.01 8970 9037 8957
Table 7: Compression Test IS Trial 2
DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT
CUBE 1 CUBE 2 CUBE 3 CUBE 1 CUBE 2 CUBE 3 CUBE 1 CUBE 2 CUBE 3
3 322.89 380.31 314.56 14.36 16.90 13.99 15.08 8851 8686 8983
7 693.9 699.99 635.19 30.85 31.12 28.24 30.07 8639 8764 8603
28 1021 975.16 957.83 45.34 43.35 42.58 43.75 8766 8426 8563
Compression test results of doe method
Table 8: Compression Test DOE Trial 1
DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT
CUBE 1 CUBE 2 CUBE 3 CUBE 1 CUBE 2 CUBE 3 CUBE 1 CUBE 2 CUBE 3
3 277.89 372.16 359.56 12.36 16.55 15.99 14.96 8866 8953 8637
7 502.89 465.99 505.9 22.36 20.72 22.49 21.85 8851 8855 8470
28 941 931.6 1022 41.78 41.41 45.38 42.85 8837 8790 8949
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Table 9: Compression Test DOE Trial 2
DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT
CUBE 1 CUBE 2 CUBE 3 CUBE 1 CUBE 2 CUBE 3 CUBE 1 CUBE 2 CUBE 3
3 303.59 344.03 375.4 13.68 15.30 16.69 15.22 8966 9036 8992
7 638.34 562.06 629.2 28.38 24.99 27.97 27.01 9081 8769 8986
28 1004.7 980.79 1047.7 44.66 43.60 46.57 44.94 8957 8866 8797
RESULTS GRAPH AS PER IS-10262-2009 & DOE METHOD
In experimental work for ordinary concrete design we
have taken IS method and DOE method for mix design. In
which two trials of each methods have done and the best
one strength result is taken for comparison with
geopolymer concrete. From the graph at 3rd day the IS
trial (2) got maximum compressive strength then it
increases gradually. At 28 the day the DOE trial (2) got
maximum strength. Hence the DOE trial (2) result is taken
for the comparison with geopolymer concrete.
Chart 1: IS-10262-2009 & DOE Method
GEOPOLYMER CONCRETE RESULTS OF COMPRESSION FOR 16 M:-
Table 10: Geopolymer Concrete Results of Compression for 16 M for M 500
DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT
TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2
1 415.6 - 18.47 - 19.47 7.210 -
3 645.01 661.01 28.68 29.39 29.04 7.330 7.370
7 843.01 915.6 37.47 40.69 39.08 7.460 7.510
14 947.6 926.6 42.12 41.18 41.65 7.590 7.530
28 981.01 1056.6 43.61 46.96 45.29 7.730 7.640
Table 11: Geopolymer Concrete Results of Compression for 16 M for M 550
DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT
TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2
1 435.5 - 19.35 - 19.35 7.680 -
3 529.5 448.0 23.53 20.10 21.82 7.700 7.460
7 547.5 543.5 24.33 24.16 24.24 7.480 7.260
14 632 673 28.08 29.91 29.00 7.400 7.260
28 743 747 33.04 33.22 33.13 7.540 7.480
Table 12: Geopolymer Concrete Results of Compression for 16 M for M 600
DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT
TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2
1 556.5 - 24.75 - 24.74 7.410 -
3 697.5 664.95 30.98 29.90 30.45 7.450 7.430
7 713.5 684.90 31.69 31.48 31.59 7.290 7.330
14 905.5 809.55 40.23 36.99 38.61 7.470 7.450
28 987.5 946.05 43.88 42.05 42.98 7.430 7.470
0
10
20
30
40
50
3 7 28
STRENGTH(N/MM2)
DAYS
IS TRAIL 1
IS TRAIL 2
DOE TRAIL
1
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
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Table 13: Geopolymer Concrete Results of Compression for 16 M for M 650
DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT
TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2
1 446.5 - 19.85 - 19.83 7.340 -
3 595.0 670.55 26.45 29.81 28.14 7.350 7.370
7 672.5 693.8 29.93 30.83 30.39 7.010 7.070
14 844.5 781.5 37.54 34.73 36.12 6.770 6.830
28 854.5 810.5 37.96 36.05 36.98 6.810 6.770
RESULTS GRAPH OF FLY ASH BASED GEOPOLYMER CONCRETE OF 16M COMPRESSIVE STRENGTH:-
In experimental work for geopolymer concrete design we
have taken IS method for mix design. In which four trials
are taken with 16 molar sodium hydroxide concentration
i.e. M 500, M 550, M 600, M 650. In which we have changed
the variation in the fly ash content. In this we have taken
tests for 1,3,7,14,28th days. At 1st day mix M 600 got the
maximum strength but after 28th day it gets lower strength
than M 500. The compressive strength of M 500 after 28
days is 45.28 N/mm
Chart 2: Fly Ash Based Geopolymer Concrete of 16M Compressive Strength
GEOPOLYMER CONCRETE RESULTS OF TENSILE STRENGTH FOR 16 M
Table 14: Geopolymer Concrete Results of Tensile Strength for 16 M for M 500
DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT (kg)
TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2
21 161.5 181.5 7.20 8.05 7.65 11.80 11.65
Table 15: Geopolymer Concrete Results of Tensile Strength for 16 M for M 550
DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT (kg)
TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2
21 155 175.5 6.85 7.85 7.35 11.14 11.24
Table 16: Geopolymer Concrete Results of Tensile Strength for 16 M for M 600
DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT (kg)
TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2
21 170.5 152.5 7.55 6.75 7.15 11.65 11.05
Table 17: Geopolymer Concrete Results of Tensile Strength for 16 M for M 650
DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT (kg)
TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2
21 133.5 155.5 5.89 6.87 6.38 11.23 11.85
0
10
20
30
40
50
1 3 7 14 28
STRENGTH(N/MM2)
DAYS
M 500
M 550
M 600
M 650
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RESULTS GRAPH OF FLY ASH BASED GEOPOLYMER CONCRETE OF 16M TENSILE STRENGTH
From the of tensile strength we get that the strength of
M500 is 7.6 N /mm2 at 21st day which is higher than other
proportion .For the ordinary concrete it is 3 to 5 N /mm2
REPLACING MOLARITY OF NAOH 16 M TO 10 M:-
For 16 Molar solutions, the mass of Noah solid was
measured as 444 grams per kg of Noah solution. Similarly,
for 10 Molar, the mass of Noah solid was measured as 314
grams per kg of Noah solution.
Chart 3: Fly Ash Based Geopolymer Concrete of 16M Tensile Strength
Table 18: Geopolymer Concrete Results of Compression for 10 M for M 500
DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT
TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2
1 329.5 - 14.62 - 14.61 7.450 -
3 403 388 17.85 17.23 17.55 7.830 7.510
7 436.5 515 19.37 22.88 21.13 7.930 7.690
14 624.5 590.5 28.54 26.23 27.39 7.610 7.510
28 645.5 690.5 28.68 30.67 29.69 7.650 7.390
Table 19: Geopolymer Concrete Results of Compression for 10 M for M 600
DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT
TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2
1 382.5 - 16.98 - 16.98 7.301 -
3 424.3 470.1 18.85 20.89 19.87 7.141 7.361
7 598.1 547.50 26.58 24.34 25.46 7.221 7.383
14 719.1 714.5 31.96 31.74 31.85 8.102 7.201
28 728.2 758.4 32.35 33.68 33.03 7.403 7.382
RESULTS GRAPH OF FLY ASH BASED GEOPOLYMER CONCRETE 10M:-
Chart 4: Fly Ash Based Geopolymer Concrete 10M
For the further work, we have taken the 2 proportions M
500 and M 600. In which we have replaced the morality of
Noah from 16 molar to 10 molar for checking the variation
in compressive strengths. From the graph of compressive
strength we can say that the strength of concrete decreases
with the morality of Noah decreases.
5. CONCLUSIONS
Geopolymer concrete cubes and cylinders were made and
tested. The test result were compared with the prediction of
the methods of calculations available for Portland cement
concrete and the design provision given in the Indian
Standard for concrete structure.
Based on test results, the following conclusions are
drawn:
1. The geopolymer concrete achieves 50% to 75%
compressive strength within 1 day of heat curing.
5.5
6
6.5
7
7.5
8
21
STRENGTH(N/MM2)
DAYS
M 500
M 550
M 600
M 650
0
10
20
30
40
1 3 7 14 28
STRENGTH(N/MM2)
DAYS
M 500
M 600
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2. The tensile strength of geopolymer concrete is
comparatively more than the ordinary concrete; it is
7.60 N / mm2 for M 30 design strength of geopolymer
concrete.
3. The strength of geopolymer concrete increases with
increase in molarity of sodium hydroxide solution.
4. The geopolymer concrete is lighter in weight as
compared to ordinary concrete.
5. Individually geopolymer concrete is costly due to the
alkaline liquid (sodium silicate & sodium hydroxide)
but if we consider the Carbon Credit the geopolymer
concrete is economical.
6. The strength of geopolymer concrete increases with
increase in curing temperature as well as duration.
6. REFERENCES
[1] “Introducing Fly Ash-Based Geopolymer Concrete:
Manufacture and Engineering Properties” by D
Hardjito, S E Wallah, B.V. Rangan, D M J Sumajouw,
published in 30th Conference on our world in
concrete & structures(23–24 august 2005),
Singapore, page no(1 to 9)
[2] “Workability and Strength of Coarse High Calcium Fly
Ash Geopolymer” by P. Chindaprasirt , T. Chareerat ,
V. Sirivivatnanon published in - Cement & Concrete
Composites 29 (2007) 224–229, page no(1 to 9)
[3] “Recent Research Geopolymer Concrete” by Nguyen
Van Chanh1, Bui Dang Trung, Dang Van Tuan,
published in - 3rd ACF International Conference-
ACF/VCA (2008), page no(1 to 7)
[4] “Compressive Strength and Degree of Reaction of
Biomass- And Fly Ash-Based Geopolymer ” by,
Smith Songpiriyakij a, Teinsak Kubprasit b, Chai
Jaturapitakkul b, Prinya Chindaprasirt published in -
c Construction and Building Materials 24 (2010)
236–240 page no(1 to 5)
[5] “Geopolymer Concrete : A Review of Development
and Opportunities” by N A Lloyd*, B V Rangan,
published in -35th Conference on our world in
concrete & structures:( 25 - 27 August 2010),
Singapore, page no(1 to 5)
[6] “Review on Fly Ash-Based Geopolymer Concrete
Without Portland Cement” by Mohd Mustafa Al
Bakri1, H. Mohammed, H. Kamarudin, I. Khairul Niza
and Y. Zarina, published in- Journal of Engineering
and Technology Research Vol. 3(1), pp. 1-4, (January
2011), page no(1 to 4)
[7] “The Effects of Na2o/Sio2 Molar Ratio, Curing
Temperature and Age on Compressive Strength,
Morphology and Microstructure Of Alkali-Activated
Fly Ash-Based Geopolymers” by Alexander Silva de
Vargas , Denise C.C. Dal Molin b, Antônio C.F. Vilela c,
Felipe José da Silva d, Bruno Pavão e, Hugo Veit,
published in- Cement & Concrete Composites 33
(2011) 653–660 ,page no(1 to 8)
[8] “Modified Guidelines for Geopolymer Concrete Mix
Design Using Indian Standard” by R. Anuradha*a, V.
Sreevidyaa, R. Venkatasubramania and B.V. Ranganb
published in- asian journal of civil engineering
(building and housing) vol. 13, no. 3 (2012) pages(
353-364)
[9] “Influence of aggregate content on the behaviour of
fly ash based geopolymer concrete” by Benny Joseph
a , G. Mathew, published in- Scientia
IranicaTransactions A: Civil Engineering(2012) ,page
no(1 to 7)
[10] P.R.Vora and U.V.Dave “paramtric studies on
compressive strength of geopolymer concrete” in
chemical, civil and mechanical engineering tracks of
3rd Nirma university international conference on
engineering (NUICONE-2012) Ahmadabad (2013).
[11] L.V.G and A.Viswan “experimental investigation on
the strength aspects of fly ash based geopolymer
concrete” international journal of engineering
research and applications (IJERA),ISSN:2248-
9622,pp.55-58,24th-25th January 2014.
[12] V.B.Rangan, “geopolymer concrete for environmental
protection” the Indian concrete journal,pp.41-
59,April 2014.
BIOGRAPHIES
Dr. M.B. Chougule received the B.E. and
M.E. degrees in Civil Engineering from
Shivaji University, Kolhapur. He is
committee member of Institution of
Engineers Kolhapur Local Centre. He
is recipient of Gold medal in Civil
Engineering. Completed his Ph.D. from
Solapur University (M.S.). He is
working as Associate Professor and
H.O.D. in Civil Engineering at Textile
and Engineering Institute, Ichalkaranji.
He is member of various technical
bodies and many awards to his credit.
thor

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IRJET- Strength Development of Fly Ash based Geopolymer Concrete

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 10 | Oct 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 200 Strength Development of Fly Ash based Geopolymer Concrete Dr. M.B. Chougule Associate Professor and H.O.D. in Civil Engineering, Textile and Engineering Institute, Ichalkaranji, Maharashtra, India ------------------------------------------------------------------------***----------------------------------------------------------------------- Abstract:- In recent time, the importance and use of fly ash in concrete has grown so much that it has almost become a common ingredient in concrete, particularly for making high strength and high performance concrete. Extensive research has been done all over the world on the benefits that could be accrued in the utilization of fly ash as a supplementary cementitious material. High volume fly ash concrete as a subject of current interest all over the world. The use of fly ash a concrete admixture not only extends technical advantages to the properties of concrete but also contributes to the environmental pollution control. In India alone, we produce about 100 million tons of fly ash per year, the disposal of which has become a serious environmental problem. The effective utilization of fly ash in concrete making is, therefore attracting serious considerations of concrete technologies and government departments. Keywords:- Fly ash, ASTM Class F fly ash, Alkaline liquid, Geo polymer concrete 1. INTRODUCTION Geo polymer concrete show several advantages and disadvantages over conventional concrete. Now a days the concrete is one of the most widely used construction material, it is usually associated with Portland cement as the main component for making the concrete. The demand for concrete as a construction material is increasing day by day. The several efforts are in progress to reduce the use of Portland cement in concrete in order to address the global warming issues. In this respect the geo polymer technology shows considerable promise for application in concrete industry as an alternative binder to the Portland cement. The scope of this project work is explained with the help of methodology, research strategy and research design. 1.1 Methodology The aim of present work is to study the physical, chemical and mechanical properties of ingredients of fly ash based geo polymer concrete. Also to study the structural behavior of geo polymer concrete regarding to tensile and compressive strength and design the concrete mix of geo polymer concrete as well as to compare the geopolymer concrete with ordinary Portland cement concrete according experimental analysis. This research work is explained with the help of following points: 1) Introduction to fly as based Geo polymer concrete. 2) To study the physical, chemical & mechanical properties of ingredients. 3) Preparing the mix design for fly ash based geo polymer concrete with different proportions. 4) Preparing blocks, cylinders & beams of concrete. 5) Testing the compressive and tensile strength of concrete. 6) To study experimental analysis and to find optimum proportion for best concrete results. 2. RESEARCH STRATEGY Considering the research objectives of the work, the focus is on empirical evidence of the use of concrete in India in the recent years. In order to give an actual and overall picture of the use of Geo polymer concrete in India, the research needs a strategy that can effectively provide depth of information. Therefore a research strategy combines study of properties of geo polymer concrete, material used for making it, actual mix design of geo polymer concrete adopted to acquire integrated and in-depth data. The data and material needed in this research is mainly obtained by three methods: The theoretical framework of Fly ash based Geo- polymer concrete is derived from literature including previous studies and research, the publications of the related agencies, social institution and academic organizations. 3. MATERIAL USED Geopolymer is an inorganic allumino-silicate polymer synthesized from predominantly silicon (Si) and alluminum (Al) materials of geological origin or by-product materials such as fly ash. The term geopolymer was introduced by Davidovits to represent the mineral polymers resulting from geochemistry. The process involves a chemical reaction under highly alkaline conditions on Si-Al minerals, yielding polymeric Si-O-Al-O bonds in amorphous form. It has been reported that geopolymer material does not suffer from alkali-aggregate reaction even in the presence of high alkalinity and possesses excellent fire resistant. Geopolymer is used as the binder, instead of cement paste, to produce concrete. The geopolymer paste binds the loose coarse aggregates, fine aggregates and other un-reacted materials together to form the geopolymer concrete. The manufacture of geopolymer concrete is carried out using the usual
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 10 | Oct 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 201 concrete technology methods. As in the Portland cement concrete, the aggregates occupy the largest volume, i.e. about 75-80 % by mass, in geopolymer concrete. The silicon and the alluminium in the fly ash are activated by a combination of sodium hydroxide and sodium silicate solutions to form the geopolymer paste that binds the aggregates and other un- reacted materials. Geopolymer-based materials are environmentally friendly, and need only moderate energy to produce. They can be made using industrial by-products, such as fly ash, as the source material. In geopolymer concrete, the geopolymer paste serves to bind the coarse and fine aggregates, and any un-reacted material. Geopolymer concrete can be utilized to manufacture precast concrete structural and non-structural elements, to make concrete pavements, to immobilize toxic wastes, and to produce concrete products that are resistant to heat and aggressive environments. Fig. 1: Preparation of concrete Geopolymer concrete is concrete which does not utilize any Portland cement in its production. Rather, the binder is produced by the reaction of an alkaline liquid with a source material that is rich in silica and alumina. Geo polymers were developed as a result of research into heat resistant materials after a series of catastrophic fires. The research yielded non- flammable and non-combustible geopolymer resins and binders. Geopolymer is being studied extensively and shows promise as a greener alternative to Portland cement concrete. Research is shifting from the chemistry domain to engineering applications and commercial production of geopolymer. It has been found that geopolymer concrete has good engineering properties. 3.1 Fly Ash Fly ash is divided mainly into two categories based mainly on its calcium content. ASTM Class F fly ash is low in calcium and mainly pozzolanic (i.e., they react with calcium hydroxide in moist condition to produce cementitious compounds), whereas class C fly ash has higher fraction of calcium oxides, which give them cementitious characteristics. Class C fly ash is often marketed directly in many countries and finds easy application in concrete as a part replacement of cement. Class F fly ash (most Indian fly ash fall in this category) is primarily used as a cement replacement under certain conditions of quality in terms of chemical composition, particle size distribution and loss on ignition (which is an indicator of carbon content). Table 1: Chemical Composition Class F Fly Ash Oxides Quantity (%) SiO2 50.18 Al2O3 26.31 Fe2O3 13.68 CaO 2.63 MgO 1.29 SO3 0.02 Na2O 0.32 K2O 0.53 TiO 1.66 SrO 0.30 P2O5 1.55 Mn2O3 0.09 The use of fly ash has additional environment advantages. The annual production of fly ash in Australia in 2007 was approximately 14.5 million tonnes of which only 2.3 million tonnes were utilized in beneficial ways; principally for the partial replacement of Portland cement . Development of geopolymer technology and applications would see a further increase in the beneficial use of fly ash, similar to what has been observed in the last 14 years with the use of fly ash in concrete and other building materials. 3.2 Alkaline Liquids Sodium Hydroxide Generally the sodium hydroxides are available in solid state by means of pellets and flakes. The cost of the sodium hydroxide is mainly varied according to the purity of the substance. Since our geopolymer concrete is homogenous material and its main process to activate the sodium silicate, so it is recommended to use the lowest cost i.e. up to 94% to 96% purity. In this investigation the sodium hydroxide pellets were used. Whose physical and chemical properties are given by the manufacturer is shown in Table 2 & 3. Table 2: Physical Properties Sodium hydroxide Colour less Specific Gravity 20% 1.22 30% 1.33 40% 1.43 50% 1.53
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 10 | Oct 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 202 Sodium hydroxide pellets are taken and dissolved in the water at the rate of 16 molar concentrations. It is strongly recommended that the sodium hydroxide solution must be prepared 24 hours prior to use and also if it exceeds 36 hours it terminate to semi solid liquid state. So the prepared solution should be used within this time. Sodium Silicate Sodium silicate is also known as water glass or liquid glass, available in liquid (gel) form. In present investigation sodium silicate 2.0 (ratio between Na2O to SiO2) is used. As per the manufacture, silicates were supplied to the detergent company and textile industry as bonding agent. Same sodium silicate is used for the making of geopolymer concrete. The chemical properties and the physical properties of the silicates are given the manufacture is shown as below:- Table 3: physical properties of the silicates Assay -97% Min Carbonate (Na2CO3) -2% Max Chloride (Cl ) -0.01% Max Sulphate (SO2) -0.05% Max Lead (Pb ) -0.001% Max Iron (Fe) -0.001% Max Potassium (K) -0.1% Max Zinc (Zn) -0.02% Max Fig. 2: Alkali solutions 3.4 Preparation of Alkaline Liquid Dissolution:- Initially the vitreous component of the fly ash (allumino silicate glass) in contact with the alkali solution Sodium Hydroxide and Sodium Silicate is dissolved, forming a series of complex ionic species. 3.3 Morality calculation The solids must be dissolved in water to make a solution with the required concentration. The concentration of Sodium hydroxide solution can vary in different Molar. The mass of Noah solids in a solution varies depending on the concentration of the solution. For instance, Noah solution with a concentration of 16 Molar consists of 16 x 40 = 640 grams of Noah solids per liter of the water, were 40 is the molecular weight of Noah. Note that the mass of water is the major component in both the alkaline solutions. The mass of Noah solids was measured as 444 grams per kg of Noah solution with a Concentration of 16 Molar. Similarly, the mass of Noah solids per kg of the solution for other concentrations was measured as 10 Molar: 314 grams, 12 Molar: 361 grams, and 14 Molar: 404 grams. Fig. 3: Mixing of contents Alkaline liquid:- Sodium based alkaline solutions were used to react with the fly ash to produce the binder. Sodium-silicate solution was used for the concrete production. The chemical composition. Sodium hydroxide solution was prepared by dissolving sodium hydroxide pellets in water. The pellets are commercial grade with 97% purity thus 16 molar solutions were made by dissolving 444 grams of sodium hydroxide pellets in 556 g of water. The sodium hydroxide solution was prepared one day prior to the concrete batching to allow the exothermically heated liquid to cool to room temperature. The Sodium silicate solution and the sodium hydroxide solution were mixed just prior to the concrete batching. Generally alkaline liquids are prepared by mixing of the sodium hydroxide solution and sodium silicate at the room temperature. When the solution mixed together the both solution start to react i.e. polymerization takes place
  • 4. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 10 | Oct 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 203 it liberate large amount of heat so it is recommended to leave it for about 24 hours thus the alkaline liquid is get ready as binding agent . Fig. 4: Alkaline liquid is get ready as binding agent Polymerization These small molecules present in the dissolution can join each other and form large molecules that precipitate in the form of gel, in which some degree of short range structural order can be identified (10). The composition and structure of this alkali alumina silicate gel depends essentially on the size, structure and concentration of the ionic species present in the medium, as well as on the synthesis temperature on the curing time, and the pH of the mixture. The hypothetical evolution of this gel would be to form some sort of zeolite crystal. However, due to the very low “alkaline solution / fly ash” ratio used in the synthesis of this type of materials (or prevailing under experimental conditions), this evolution is extremely slow. The studies done up to today concerning the manufacturing of mortars and/or concretes of activated fly ash following the alkaline process (without Portland cement) turned out into very promising results. The above mentioned studies have demonstrated for example that the properties of the concrete of alkali activated fly ash are influenced, like those of the conventional concrete, by a set of factors related to the dosing of the mixture and to the conditions of the curing process. Nevertheless, these new concrete can manage to develop very high mechanical strength within a few hours. These strengths continue to grow more slowly with time. Also, the mentioned studies have manifested the high potential of these materials that could be used in the near future in the construction industry, especially in the precast industry. This is the reason why the goal of this work is focused on the establishment of some engineering properties for this type of materials (mechanical strength development, matrix-steel adherence and shrinkage). Finally, there is a specific case of an industrial application of these new concrete for the manufacturing of pre-stressed mono-block sleeper son railroads. Fig. 5: Fly ash before and after activation 4. EXPERIMENTAL ANALYSIS Proportions AS PER IS-10262-2009 & DOE METHOD Table 4: I.S. and DOE trials TYPE CEMENT (kg/M3) FINE AGGR. (kg//M3) COURSE AGGR. (kg//M3) WATER (kg//M3) IS TRIAL 1 475 661 1255 189 RATIO 1 1.38 2.63 0.39 IS TRIAL 2 525 645 1229 189 RATIO 1 1.21 2.33 0.35 DOE TRIAL 1 410 588 1396 205 RATIO 1 1.42 3.39 0.49 DOE TRIAL 2 456 574 1364 205 RATIO 1 1.26 3.00 0.45
  • 5. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 10 | Oct 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 204 Proportions AS PER MODIFIED GUIELINE FOR GEOPOLYMER CONRETE MIX DESIGN USING INDIAN STANDARD (IS-10262-2009):- Table 5: Grade and ratio GRADE FLY ASH (kg//M3) FINE AGGR. (kg//M3) COURSE AGGR. (kg//M3) ALKALINE LIQUID EXTRA WATER (kg//M3)SODIUM SILICATE (kg//M3) SODIUM HYDROXIDE (kg//M3) M 500 500 487 1011 217.86 87.14 15 RATIO 1 0.96 2.01 0.60 0.03 M 550 550 445.2 924.65 239.64 95.86 16.5 RATIO 1 0.80 1.67 0.60 0.03 M 600 600 403.53 838.10 261.43 104.57 18 RATIO 1 0.63 1.32 0.60 0.03 M 650 650 361.87 751.58 283.21 113.28 19.5 RATIO 1 0.55 1.15 0.60 0.03 Compression test results of Indian standard method:- Table 6: Compression Test IS Trial 1 DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT CUBE 1 CUBE 2 CUBE 3 CUBE 1 CUBE 2 CUBE 3 CUBE 1 CUBE 2 CUBE 3 3 284.5 325.14 252.69 12.65 14.46 11.24 12.78 8903 8879 8851 7 661.96 672.76 627.08 29.43 29.91 27.88 29.07 8865 8938 9006 28 866.93 925.43 908.33 38.53 41.13 40.37 40.01 8970 9037 8957 Table 7: Compression Test IS Trial 2 DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT CUBE 1 CUBE 2 CUBE 3 CUBE 1 CUBE 2 CUBE 3 CUBE 1 CUBE 2 CUBE 3 3 322.89 380.31 314.56 14.36 16.90 13.99 15.08 8851 8686 8983 7 693.9 699.99 635.19 30.85 31.12 28.24 30.07 8639 8764 8603 28 1021 975.16 957.83 45.34 43.35 42.58 43.75 8766 8426 8563 Compression test results of doe method Table 8: Compression Test DOE Trial 1 DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT CUBE 1 CUBE 2 CUBE 3 CUBE 1 CUBE 2 CUBE 3 CUBE 1 CUBE 2 CUBE 3 3 277.89 372.16 359.56 12.36 16.55 15.99 14.96 8866 8953 8637 7 502.89 465.99 505.9 22.36 20.72 22.49 21.85 8851 8855 8470 28 941 931.6 1022 41.78 41.41 45.38 42.85 8837 8790 8949
  • 6. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 10 | Oct 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 205 Table 9: Compression Test DOE Trial 2 DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT CUBE 1 CUBE 2 CUBE 3 CUBE 1 CUBE 2 CUBE 3 CUBE 1 CUBE 2 CUBE 3 3 303.59 344.03 375.4 13.68 15.30 16.69 15.22 8966 9036 8992 7 638.34 562.06 629.2 28.38 24.99 27.97 27.01 9081 8769 8986 28 1004.7 980.79 1047.7 44.66 43.60 46.57 44.94 8957 8866 8797 RESULTS GRAPH AS PER IS-10262-2009 & DOE METHOD In experimental work for ordinary concrete design we have taken IS method and DOE method for mix design. In which two trials of each methods have done and the best one strength result is taken for comparison with geopolymer concrete. From the graph at 3rd day the IS trial (2) got maximum compressive strength then it increases gradually. At 28 the day the DOE trial (2) got maximum strength. Hence the DOE trial (2) result is taken for the comparison with geopolymer concrete. Chart 1: IS-10262-2009 & DOE Method GEOPOLYMER CONCRETE RESULTS OF COMPRESSION FOR 16 M:- Table 10: Geopolymer Concrete Results of Compression for 16 M for M 500 DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 1 415.6 - 18.47 - 19.47 7.210 - 3 645.01 661.01 28.68 29.39 29.04 7.330 7.370 7 843.01 915.6 37.47 40.69 39.08 7.460 7.510 14 947.6 926.6 42.12 41.18 41.65 7.590 7.530 28 981.01 1056.6 43.61 46.96 45.29 7.730 7.640 Table 11: Geopolymer Concrete Results of Compression for 16 M for M 550 DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 1 435.5 - 19.35 - 19.35 7.680 - 3 529.5 448.0 23.53 20.10 21.82 7.700 7.460 7 547.5 543.5 24.33 24.16 24.24 7.480 7.260 14 632 673 28.08 29.91 29.00 7.400 7.260 28 743 747 33.04 33.22 33.13 7.540 7.480 Table 12: Geopolymer Concrete Results of Compression for 16 M for M 600 DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 1 556.5 - 24.75 - 24.74 7.410 - 3 697.5 664.95 30.98 29.90 30.45 7.450 7.430 7 713.5 684.90 31.69 31.48 31.59 7.290 7.330 14 905.5 809.55 40.23 36.99 38.61 7.470 7.450 28 987.5 946.05 43.88 42.05 42.98 7.430 7.470 0 10 20 30 40 50 3 7 28 STRENGTH(N/MM2) DAYS IS TRAIL 1 IS TRAIL 2 DOE TRAIL 1
  • 7. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 10 | Oct 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 206 Table 13: Geopolymer Concrete Results of Compression for 16 M for M 650 DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 1 446.5 - 19.85 - 19.83 7.340 - 3 595.0 670.55 26.45 29.81 28.14 7.350 7.370 7 672.5 693.8 29.93 30.83 30.39 7.010 7.070 14 844.5 781.5 37.54 34.73 36.12 6.770 6.830 28 854.5 810.5 37.96 36.05 36.98 6.810 6.770 RESULTS GRAPH OF FLY ASH BASED GEOPOLYMER CONCRETE OF 16M COMPRESSIVE STRENGTH:- In experimental work for geopolymer concrete design we have taken IS method for mix design. In which four trials are taken with 16 molar sodium hydroxide concentration i.e. M 500, M 550, M 600, M 650. In which we have changed the variation in the fly ash content. In this we have taken tests for 1,3,7,14,28th days. At 1st day mix M 600 got the maximum strength but after 28th day it gets lower strength than M 500. The compressive strength of M 500 after 28 days is 45.28 N/mm Chart 2: Fly Ash Based Geopolymer Concrete of 16M Compressive Strength GEOPOLYMER CONCRETE RESULTS OF TENSILE STRENGTH FOR 16 M Table 14: Geopolymer Concrete Results of Tensile Strength for 16 M for M 500 DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT (kg) TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 21 161.5 181.5 7.20 8.05 7.65 11.80 11.65 Table 15: Geopolymer Concrete Results of Tensile Strength for 16 M for M 550 DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT (kg) TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 21 155 175.5 6.85 7.85 7.35 11.14 11.24 Table 16: Geopolymer Concrete Results of Tensile Strength for 16 M for M 600 DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT (kg) TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 21 170.5 152.5 7.55 6.75 7.15 11.65 11.05 Table 17: Geopolymer Concrete Results of Tensile Strength for 16 M for M 650 DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT (kg) TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 21 133.5 155.5 5.89 6.87 6.38 11.23 11.85 0 10 20 30 40 50 1 3 7 14 28 STRENGTH(N/MM2) DAYS M 500 M 550 M 600 M 650
  • 8. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 10 | Oct 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 207 RESULTS GRAPH OF FLY ASH BASED GEOPOLYMER CONCRETE OF 16M TENSILE STRENGTH From the of tensile strength we get that the strength of M500 is 7.6 N /mm2 at 21st day which is higher than other proportion .For the ordinary concrete it is 3 to 5 N /mm2 REPLACING MOLARITY OF NAOH 16 M TO 10 M:- For 16 Molar solutions, the mass of Noah solid was measured as 444 grams per kg of Noah solution. Similarly, for 10 Molar, the mass of Noah solid was measured as 314 grams per kg of Noah solution. Chart 3: Fly Ash Based Geopolymer Concrete of 16M Tensile Strength Table 18: Geopolymer Concrete Results of Compression for 10 M for M 500 DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 1 329.5 - 14.62 - 14.61 7.450 - 3 403 388 17.85 17.23 17.55 7.830 7.510 7 436.5 515 19.37 22.88 21.13 7.930 7.690 14 624.5 590.5 28.54 26.23 27.39 7.610 7.510 28 645.5 690.5 28.68 30.67 29.69 7.650 7.390 Table 19: Geopolymer Concrete Results of Compression for 10 M for M 600 DAYS LOAD STRENGTH AVG. STRENGTH WEIGHT TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 TRIAL 1 TRIAL 2 1 382.5 - 16.98 - 16.98 7.301 - 3 424.3 470.1 18.85 20.89 19.87 7.141 7.361 7 598.1 547.50 26.58 24.34 25.46 7.221 7.383 14 719.1 714.5 31.96 31.74 31.85 8.102 7.201 28 728.2 758.4 32.35 33.68 33.03 7.403 7.382 RESULTS GRAPH OF FLY ASH BASED GEOPOLYMER CONCRETE 10M:- Chart 4: Fly Ash Based Geopolymer Concrete 10M For the further work, we have taken the 2 proportions M 500 and M 600. In which we have replaced the morality of Noah from 16 molar to 10 molar for checking the variation in compressive strengths. From the graph of compressive strength we can say that the strength of concrete decreases with the morality of Noah decreases. 5. CONCLUSIONS Geopolymer concrete cubes and cylinders were made and tested. The test result were compared with the prediction of the methods of calculations available for Portland cement concrete and the design provision given in the Indian Standard for concrete structure. Based on test results, the following conclusions are drawn: 1. The geopolymer concrete achieves 50% to 75% compressive strength within 1 day of heat curing. 5.5 6 6.5 7 7.5 8 21 STRENGTH(N/MM2) DAYS M 500 M 550 M 600 M 650 0 10 20 30 40 1 3 7 14 28 STRENGTH(N/MM2) DAYS M 500 M 600
  • 9. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 10 | Oct 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 208 2. The tensile strength of geopolymer concrete is comparatively more than the ordinary concrete; it is 7.60 N / mm2 for M 30 design strength of geopolymer concrete. 3. The strength of geopolymer concrete increases with increase in molarity of sodium hydroxide solution. 4. The geopolymer concrete is lighter in weight as compared to ordinary concrete. 5. Individually geopolymer concrete is costly due to the alkaline liquid (sodium silicate & sodium hydroxide) but if we consider the Carbon Credit the geopolymer concrete is economical. 6. The strength of geopolymer concrete increases with increase in curing temperature as well as duration. 6. REFERENCES [1] “Introducing Fly Ash-Based Geopolymer Concrete: Manufacture and Engineering Properties” by D Hardjito, S E Wallah, B.V. Rangan, D M J Sumajouw, published in 30th Conference on our world in concrete & structures(23–24 august 2005), Singapore, page no(1 to 9) [2] “Workability and Strength of Coarse High Calcium Fly Ash Geopolymer” by P. Chindaprasirt , T. Chareerat , V. Sirivivatnanon published in - Cement & Concrete Composites 29 (2007) 224–229, page no(1 to 9) [3] “Recent Research Geopolymer Concrete” by Nguyen Van Chanh1, Bui Dang Trung, Dang Van Tuan, published in - 3rd ACF International Conference- ACF/VCA (2008), page no(1 to 7) [4] “Compressive Strength and Degree of Reaction of Biomass- And Fly Ash-Based Geopolymer ” by, Smith Songpiriyakij a, Teinsak Kubprasit b, Chai Jaturapitakkul b, Prinya Chindaprasirt published in - c Construction and Building Materials 24 (2010) 236–240 page no(1 to 5) [5] “Geopolymer Concrete : A Review of Development and Opportunities” by N A Lloyd*, B V Rangan, published in -35th Conference on our world in concrete & structures:( 25 - 27 August 2010), Singapore, page no(1 to 5) [6] “Review on Fly Ash-Based Geopolymer Concrete Without Portland Cement” by Mohd Mustafa Al Bakri1, H. Mohammed, H. Kamarudin, I. Khairul Niza and Y. Zarina, published in- Journal of Engineering and Technology Research Vol. 3(1), pp. 1-4, (January 2011), page no(1 to 4) [7] “The Effects of Na2o/Sio2 Molar Ratio, Curing Temperature and Age on Compressive Strength, Morphology and Microstructure Of Alkali-Activated Fly Ash-Based Geopolymers” by Alexander Silva de Vargas , Denise C.C. Dal Molin b, Antônio C.F. Vilela c, Felipe José da Silva d, Bruno Pavão e, Hugo Veit, published in- Cement & Concrete Composites 33 (2011) 653–660 ,page no(1 to 8) [8] “Modified Guidelines for Geopolymer Concrete Mix Design Using Indian Standard” by R. Anuradha*a, V. Sreevidyaa, R. Venkatasubramania and B.V. Ranganb published in- asian journal of civil engineering (building and housing) vol. 13, no. 3 (2012) pages( 353-364) [9] “Influence of aggregate content on the behaviour of fly ash based geopolymer concrete” by Benny Joseph a , G. Mathew, published in- Scientia IranicaTransactions A: Civil Engineering(2012) ,page no(1 to 7) [10] P.R.Vora and U.V.Dave “paramtric studies on compressive strength of geopolymer concrete” in chemical, civil and mechanical engineering tracks of 3rd Nirma university international conference on engineering (NUICONE-2012) Ahmadabad (2013). [11] L.V.G and A.Viswan “experimental investigation on the strength aspects of fly ash based geopolymer concrete” international journal of engineering research and applications (IJERA),ISSN:2248- 9622,pp.55-58,24th-25th January 2014. [12] V.B.Rangan, “geopolymer concrete for environmental protection” the Indian concrete journal,pp.41- 59,April 2014. BIOGRAPHIES Dr. M.B. Chougule received the B.E. and M.E. degrees in Civil Engineering from Shivaji University, Kolhapur. He is committee member of Institution of Engineers Kolhapur Local Centre. He is recipient of Gold medal in Civil Engineering. Completed his Ph.D. from Solapur University (M.S.). He is working as Associate Professor and H.O.D. in Civil Engineering at Textile and Engineering Institute, Ichalkaranji. He is member of various technical bodies and many awards to his credit. thor