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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 05 Issue: 11 | Nov 2018 www.irjet.net p-ISSN: 2395-0072
© 2018, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1795
3D-Printing in Additive Manufacturing
Ratikanta Sahoo1, Dambarudhar Das2, Ashish Tripathy3
1,2,3Assistant Professor, Department of Mechanical Engineering, REC, Bhubaneswar, Odisha, India
----------------------------------------------------------------------***---------------------------------------------------------------------
Keywords: Additivemanufacturing,3D printing,Mechanical
properties,,, and standards Polymer, Polymer nano
composites, Post-processing
1. INTRODUCTION
Additive Manufacturing (AM),3Dprinting,hasbeendrawing
increasing interest from industry,aswell astheresearchand
academic communities. Recently, cheaper and faster AM
techniques have been developed which can produce high
print qualities. Also, polymer materials for 3D printing are
now being produced with a wider range of properties.These
advancements continuously change how the products are
designed and manufactured and how they are being used by
consumers. Innovators and inventors can now easily
produce prototypes of their ideas as 3D printing greatly
simplifies prototype production. The design and fabrication
processes have actually been reduced from weeks to a few
hours essentially allowing to innovate on the fly. AM could
minimize production costs and improve the overall
efficiency in the manufacturing sector AM is now being
seriously considered to produce materials for several
applications, namely, construction , apparel , dentistry
,medicine , electronics ,automotive , robots , military ,
oceanography , aerospace , and others. Just recently, a3D-
printed satellite launching device won the design com-
petition sponsored by Mouser Electronics. For practical
applications, the 3D-printedpartsshouldwith-standvarious
amounts of mechanical and environmental stresses during
its use. It is important to know the required strengths for
each application under variousloadingconditions,andatthe
very least, the physical propertiesof3D-printedpartsshould
be similar to those manufactured by traditional methods,
such as injection molding. To limit the scope, this paper
is focused only on mechanical characterization of polymer
materials. Generally, plastics have lower strength than
metals but they have lower density and higher strainfailure.
In some cases, plastics will have higher strength per unit
weight than metals.Therefore,consideringitslowercost and
manufacturability with complex designs, plasticscouldhave
more advantages in many applications. It is thus not
surprising that in a recent survey, polymers account for
more than half of the parts currently produced by AM.
2. OVERVIEW OF ADDITIVE MANUFACTURING
Additive Manufacturing (AM) has been defined as the
process of joining materials to make parts from a 3-
dimensional model data one layer at a time. Fig. 3 shows the
general additive manufacturing process flow. As opposed to
milling or cutting a part from a block of material, AM builds
up the part, usually layer upon layer, using powders or
liquid. In the case of polymers, filaments are also widely
being used. Other terms synonymously used to AM are as
follows: 3D printing, direct digital manufacturing, freeform
fabrication, rapid prototyping, additive fabrication, additive
layer manufacturing. There are several diverse processes
used for AM. Based on the standard,AMprocesseshave been
classified into sevencategories:material extrusion,vatphoto
polymerization, powder bed fusion, binder jetting, sheet
lamination, material jetting and directed energy deposition
Usually, 3D printer manufacturers provide their own
software to slice the model in the STL file into individual
layers. The sliced file will then be sent to the Additive
Manufacturing device, printer. The printer will then print
one layer (2D) on top of the other, and thereby forming
three-dimensional object in the process. After forming the
Abstract:- 3D printing, more formally known as
Additive Manufacturing (AM), is already being adopted
for rapid prototyping and soon rapid manufacturing. The
commonly-used ASTM and ISO mechanical test standards
which have been used by various research groups to test the
strength of the 3D-printed parts have been reported. Also, a
summary of an exhaustive amount of literature regarding the
mechanical properties of 3D-printed parts is included,
specifically, properties under different loading types such
as tensile, bending, compressive, fatigue, impactandothers.
Propertiesat low temperatures havealso beendiscussed.
Further, theeffects of fillers as well as post-processing
on the mechanical properties have also been discussed.
Lastly, several important questions to consider inthe
standardizationofmechanical test methods have been raised.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 05 Issue: 11 | Nov 2018 www.irjet.net p-ISSN: 2395-0072
© 2018, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1796
3D-object, it may need some post-processing depending on
the desired property. Post-processing may include curing
annealing, painting or others.
3. REVIEW OF ADDITIVE MANUFACTURING METHODS
FOR POLYMERS
(1)Fused deposition modeling (FDM)
Scott Crump, the co-founder of Stratasys,patentedtheFused
Deposition Modeling (FDM) in. FDM-based 3D print-ers are
presently the most popular consumer-level 3D printers for
printing polymer composites that is based on extrusion
additive manufacturing (AM) systems. Extrusion-based AM
generally follows the printing principle of extruding a
material and depositing onto a platform creating a two-
dimensional layer on top of another resulting to a tangible
three-dimensional object. Among other extrusion-based
techniques, FDM is a material-melting technique whichuses
a spool of thermoplastic filament such as PC, ABS and PLA
with varying diameters to be melted and extrudedthrougha
heated nozzle. Recently, thermoplastics with higher melting
temperatures such as PEEK can already be usedasmaterials
for desktop 3D printing.
(2) Stereo lithography (SLA)
This was one of the earliest AM techniques developed. The
basic concept of stereo lithography (SLA) is to print using a
photo curable resin, typically epoxy or acrylic, byexposing it
to ultraviolet (UV) light of specific wavelength so the
exposed 2D-patterned resin layers become solid through a
process called photo polymerization.
(3)Digital light processing (DLP)
Digital Light Processing (DLP) is another vat polymerization
technique quite similar to SLA, except that instead of using
scanning laser beam to solidify a layerofresin,a digital mask
is projected to create the pattern. Technically, DLP can print
an object with lesser time compared to SLA since each layer
is exposed entirely all at once bytheprojected pattern rather
than meticulously scanned by a laser. This is advantageous
when simultaneously printing multiple large compact
objects with less detail.
(4)Selective layer sintering (SLS)
Selective Laser Sintering (SLS) is a type of Powder Bed
Fusion(PBF) wherein a bed of powder polymer, resin or
metal is targeted partially (sintering) or fully (melting) by a
high-power directional heating source such as laser that
result to a solidified layer of fused powder . SLS, on the other
hand, does not need structural support since the powder
cake acts as support for the printed item; allowing
complicated objects to be printed with ease. The sintering
mechanism of SLS allows only thermoplastic polymers such
as polycaprolactone (PCL) and polyamide (PLA), ceramics
and metals to be printed; taking into consideration the
complex consolidation behavior and molecular diffusion
process. The surface smoothness of a print of an SLA is
better than SLS.
(5) Three-dimensional printing (3DP)
Three-Dimensional Printing (3DP)isanothertypeofPowder
Bed Fusion (PBF) additive manufacturing technology
developed at the MassachusettsInstituteofTechnology[81].
It is quite similar to SLS except that in 3DP, a liquid binding
material is deposited via binding jet over the powder bed,
which serves as a substrate, to bind the powder particles
together to create the two-dimensional shape of the layer. A
fresh layer of powder is rolled over the previouslayeraftera
lowering mechanism carries down the already printed
layers.
(6)Laminated object manufacturing (LOM)
Laminated Object Manufacturing is widely used in the
industry as a rapid prototyping and additive manufacturing
technique. As illustrated in Fig.9,theprintingcyclegenerally
consists of rolling out a heat-activated sheet material which
is then laminated onto a substrate via the heat roller; the
layer is formed by laser-cutting the pattern and cross-
hatches the non-part area to be disposed to the waste roll.
The platform moves down to prepare for the next layer
(7)PolyJet technology
PolyJet is considered an advanced inkjet technology where
instead of using ink, multiple print nozzles accurately spray
tiny droplets of liquid photopolymer or other liquid
materials, hence, the name poly jet. AUVlightinstantlycures
the droplets creating ultra-thin layers on the build platform
to form the 3D object. Complexprintsrequiresupport, which
should be removed manually. The post curing of the final
product is unnecessary. Its advantages include high
resolution and simultaneous multi-material printing. It can
also incorporate a selection of colors to produce multi-
colored final product.
This part summarizes research works aimed at
understanding the mechanical properties of additively
manufactured parts. For utilization of 3D printed parts in
real world applications, its strength in all aspects should be
similar to the part that it will replace, or to those produced
by conventional processing methods(e.g.injection molding).
It should be noted that the mechanical propertiesofadditive
manufactured parts can be affected by both the unprinted
material properties and the manufacturing method.
Moreover, polymers with defined functional andmechanical
properties also have to be developed. Usually,
reinforcements/fillers are incorporated in polymers to
4. MECHANICAL PROPERTIES OF 3D-PRINTED
POLYMERS
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 05 Issue: 11 | Nov 2018 www.irjet.net p-ISSN: 2395-0072
© 2018, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1797
enhance their mechanical properties, or by post processing.
.Layered processing of polymeric materials, as isthecasefor
3Dprinting, has many issues that limititsapplications.These
issues must be addressed for additively manufactured parts
to have broad adoption in rapid prototyping and rapid
manufacturing, i.e. to employ 3D printing for the
manufacture of high quality and reliable end-use parts.
5. SEVERAL POST-PROCESSING METHODS FOR SLS-
PRINTED PARTS IN 3D HUBS
1) Media Tumbled (vibro polish) – polishingisdoneinmedia
tumblers or vibro machines. These devices contain small
ceramic chips responsible for gradually eroding the surface
of the part
2) Dyeing – the part is soaked in a hot color bath.
3) Spray paint or lacquering
4) Water tightness – silicones and vinyl acrylatesareusually
used to enhance water resistance.
5) Metal coating – metallic materials such as stainless steel,
cop-per, nickel, gold and chrome are being coated on the
surface of the parts in order to improve the mechanical and
electrical properties.
6. ASSESSMENT OF TEST METHODS
The mechanical properties of 3D-printed parts vary
depending on the following factors: material used (brand,
density, molecular weight, quality, etc),AMtechnologyused,
infill %, printing orientation (build and raster), layer height
(resolution), infill pat-tern, cross-sectional area, post-
processing (method and time), build number, and others. It
is quite complicated and difficulttopredicthowa partwould
behave given a certain mechanical load.
7. SUMMARY AND CONCLUSION
Additive manufacturing technologies have gained
significant advancement through the years andtheproducts
of which are now being considered to replace those
parts/materials that were manufactured through
conventional methods. This report gave a brief overview of
Additive Manufacturing (AM) and AM Technologies. The
commonly-used ASTM and ISO mechanical test standards
which have been used by various research groups to testthe
strength of the 3D-printed parts have also been reported.
Lastly, a comprehensive review of the mechanical
characteristics of partsproducedbythevariousAMmethods
have been discussed. These include results from different
mechanical tests such as tensile, bending, compression,
fatigue, impact and others. Properties at cryogenic
temperatures have also been included. Effects of nano filler
additions have been briefly discussed. Also, the effects of
post-processing on the mechanical properties have been
detailed for most of the AM methods.
3D-printed materials havelargeanisotropyespeciallyforthe
FDM- and SLS-printed parts. The effects of post-processing
on the mechanical properties are also significant especially
in the case of SLA parts. Although it is still not possible to
replace parts with the same material considering the
anisotropy and the relatively lower strength of Additively
Manufactured parts, there is a strong possibility that, with
the wide variety of materials available for AM , the needed
material properties could still be satisfied. And in some
cases, exceed the original parts or those produced via
traditional methods. With the different additive
manufacturing technologies, print-ing parameters and
considerations, it seems that we will not be seeing a single
standard for a particular mechanical test. In the end, what is
important is to have test standards in order to set a
foundation to make the products more reproducible.
REFERENCES
[1] M. Chapiro, Current achievements and future outlook for
composites in 3Dprinting, Reinf. Plast. 60 (6) (2016) 372–
375.
(2) T. Koslow, 30 Greatest 3D Printed Houses&Structures in
the World,ALL3DP, 16 April 2017. [Online], 2017, Available:
https://all3dp.com/1/3d-printed-house-homes-buildings-
3d-printing-construction.
(3) A. De Leon, Q. Chen, N. Palaganas, J. Palaganas, J.
Manapat, R. Advincula, High performance polymer nano
composites for additive manufacturing applications, React.
Funct. Polym. 103 (2016) 141–155.

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IRJET- 3D-Printing in Additive Manufacturing

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 11 | Nov 2018 www.irjet.net p-ISSN: 2395-0072 © 2018, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1795 3D-Printing in Additive Manufacturing Ratikanta Sahoo1, Dambarudhar Das2, Ashish Tripathy3 1,2,3Assistant Professor, Department of Mechanical Engineering, REC, Bhubaneswar, Odisha, India ----------------------------------------------------------------------***--------------------------------------------------------------------- Keywords: Additivemanufacturing,3D printing,Mechanical properties,,, and standards Polymer, Polymer nano composites, Post-processing 1. INTRODUCTION Additive Manufacturing (AM),3Dprinting,hasbeendrawing increasing interest from industry,aswell astheresearchand academic communities. Recently, cheaper and faster AM techniques have been developed which can produce high print qualities. Also, polymer materials for 3D printing are now being produced with a wider range of properties.These advancements continuously change how the products are designed and manufactured and how they are being used by consumers. Innovators and inventors can now easily produce prototypes of their ideas as 3D printing greatly simplifies prototype production. The design and fabrication processes have actually been reduced from weeks to a few hours essentially allowing to innovate on the fly. AM could minimize production costs and improve the overall efficiency in the manufacturing sector AM is now being seriously considered to produce materials for several applications, namely, construction , apparel , dentistry ,medicine , electronics ,automotive , robots , military , oceanography , aerospace , and others. Just recently, a3D- printed satellite launching device won the design com- petition sponsored by Mouser Electronics. For practical applications, the 3D-printedpartsshouldwith-standvarious amounts of mechanical and environmental stresses during its use. It is important to know the required strengths for each application under variousloadingconditions,andatthe very least, the physical propertiesof3D-printedpartsshould be similar to those manufactured by traditional methods, such as injection molding. To limit the scope, this paper is focused only on mechanical characterization of polymer materials. Generally, plastics have lower strength than metals but they have lower density and higher strainfailure. In some cases, plastics will have higher strength per unit weight than metals.Therefore,consideringitslowercost and manufacturability with complex designs, plasticscouldhave more advantages in many applications. It is thus not surprising that in a recent survey, polymers account for more than half of the parts currently produced by AM. 2. OVERVIEW OF ADDITIVE MANUFACTURING Additive Manufacturing (AM) has been defined as the process of joining materials to make parts from a 3- dimensional model data one layer at a time. Fig. 3 shows the general additive manufacturing process flow. As opposed to milling or cutting a part from a block of material, AM builds up the part, usually layer upon layer, using powders or liquid. In the case of polymers, filaments are also widely being used. Other terms synonymously used to AM are as follows: 3D printing, direct digital manufacturing, freeform fabrication, rapid prototyping, additive fabrication, additive layer manufacturing. There are several diverse processes used for AM. Based on the standard,AMprocesseshave been classified into sevencategories:material extrusion,vatphoto polymerization, powder bed fusion, binder jetting, sheet lamination, material jetting and directed energy deposition Usually, 3D printer manufacturers provide their own software to slice the model in the STL file into individual layers. The sliced file will then be sent to the Additive Manufacturing device, printer. The printer will then print one layer (2D) on top of the other, and thereby forming three-dimensional object in the process. After forming the Abstract:- 3D printing, more formally known as Additive Manufacturing (AM), is already being adopted for rapid prototyping and soon rapid manufacturing. The commonly-used ASTM and ISO mechanical test standards which have been used by various research groups to test the strength of the 3D-printed parts have been reported. Also, a summary of an exhaustive amount of literature regarding the mechanical properties of 3D-printed parts is included, specifically, properties under different loading types such as tensile, bending, compressive, fatigue, impactandothers. Propertiesat low temperatures havealso beendiscussed. Further, theeffects of fillers as well as post-processing on the mechanical properties have also been discussed. Lastly, several important questions to consider inthe standardizationofmechanical test methods have been raised.
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 11 | Nov 2018 www.irjet.net p-ISSN: 2395-0072 © 2018, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1796 3D-object, it may need some post-processing depending on the desired property. Post-processing may include curing annealing, painting or others. 3. REVIEW OF ADDITIVE MANUFACTURING METHODS FOR POLYMERS (1)Fused deposition modeling (FDM) Scott Crump, the co-founder of Stratasys,patentedtheFused Deposition Modeling (FDM) in. FDM-based 3D print-ers are presently the most popular consumer-level 3D printers for printing polymer composites that is based on extrusion additive manufacturing (AM) systems. Extrusion-based AM generally follows the printing principle of extruding a material and depositing onto a platform creating a two- dimensional layer on top of another resulting to a tangible three-dimensional object. Among other extrusion-based techniques, FDM is a material-melting technique whichuses a spool of thermoplastic filament such as PC, ABS and PLA with varying diameters to be melted and extrudedthrougha heated nozzle. Recently, thermoplastics with higher melting temperatures such as PEEK can already be usedasmaterials for desktop 3D printing. (2) Stereo lithography (SLA) This was one of the earliest AM techniques developed. The basic concept of stereo lithography (SLA) is to print using a photo curable resin, typically epoxy or acrylic, byexposing it to ultraviolet (UV) light of specific wavelength so the exposed 2D-patterned resin layers become solid through a process called photo polymerization. (3)Digital light processing (DLP) Digital Light Processing (DLP) is another vat polymerization technique quite similar to SLA, except that instead of using scanning laser beam to solidify a layerofresin,a digital mask is projected to create the pattern. Technically, DLP can print an object with lesser time compared to SLA since each layer is exposed entirely all at once bytheprojected pattern rather than meticulously scanned by a laser. This is advantageous when simultaneously printing multiple large compact objects with less detail. (4)Selective layer sintering (SLS) Selective Laser Sintering (SLS) is a type of Powder Bed Fusion(PBF) wherein a bed of powder polymer, resin or metal is targeted partially (sintering) or fully (melting) by a high-power directional heating source such as laser that result to a solidified layer of fused powder . SLS, on the other hand, does not need structural support since the powder cake acts as support for the printed item; allowing complicated objects to be printed with ease. The sintering mechanism of SLS allows only thermoplastic polymers such as polycaprolactone (PCL) and polyamide (PLA), ceramics and metals to be printed; taking into consideration the complex consolidation behavior and molecular diffusion process. The surface smoothness of a print of an SLA is better than SLS. (5) Three-dimensional printing (3DP) Three-Dimensional Printing (3DP)isanothertypeofPowder Bed Fusion (PBF) additive manufacturing technology developed at the MassachusettsInstituteofTechnology[81]. It is quite similar to SLS except that in 3DP, a liquid binding material is deposited via binding jet over the powder bed, which serves as a substrate, to bind the powder particles together to create the two-dimensional shape of the layer. A fresh layer of powder is rolled over the previouslayeraftera lowering mechanism carries down the already printed layers. (6)Laminated object manufacturing (LOM) Laminated Object Manufacturing is widely used in the industry as a rapid prototyping and additive manufacturing technique. As illustrated in Fig.9,theprintingcyclegenerally consists of rolling out a heat-activated sheet material which is then laminated onto a substrate via the heat roller; the layer is formed by laser-cutting the pattern and cross- hatches the non-part area to be disposed to the waste roll. The platform moves down to prepare for the next layer (7)PolyJet technology PolyJet is considered an advanced inkjet technology where instead of using ink, multiple print nozzles accurately spray tiny droplets of liquid photopolymer or other liquid materials, hence, the name poly jet. AUVlightinstantlycures the droplets creating ultra-thin layers on the build platform to form the 3D object. Complexprintsrequiresupport, which should be removed manually. The post curing of the final product is unnecessary. Its advantages include high resolution and simultaneous multi-material printing. It can also incorporate a selection of colors to produce multi- colored final product. This part summarizes research works aimed at understanding the mechanical properties of additively manufactured parts. For utilization of 3D printed parts in real world applications, its strength in all aspects should be similar to the part that it will replace, or to those produced by conventional processing methods(e.g.injection molding). It should be noted that the mechanical propertiesofadditive manufactured parts can be affected by both the unprinted material properties and the manufacturing method. Moreover, polymers with defined functional andmechanical properties also have to be developed. Usually, reinforcements/fillers are incorporated in polymers to 4. MECHANICAL PROPERTIES OF 3D-PRINTED POLYMERS
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 11 | Nov 2018 www.irjet.net p-ISSN: 2395-0072 © 2018, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1797 enhance their mechanical properties, or by post processing. .Layered processing of polymeric materials, as isthecasefor 3Dprinting, has many issues that limititsapplications.These issues must be addressed for additively manufactured parts to have broad adoption in rapid prototyping and rapid manufacturing, i.e. to employ 3D printing for the manufacture of high quality and reliable end-use parts. 5. SEVERAL POST-PROCESSING METHODS FOR SLS- PRINTED PARTS IN 3D HUBS 1) Media Tumbled (vibro polish) – polishingisdoneinmedia tumblers or vibro machines. These devices contain small ceramic chips responsible for gradually eroding the surface of the part 2) Dyeing – the part is soaked in a hot color bath. 3) Spray paint or lacquering 4) Water tightness – silicones and vinyl acrylatesareusually used to enhance water resistance. 5) Metal coating – metallic materials such as stainless steel, cop-per, nickel, gold and chrome are being coated on the surface of the parts in order to improve the mechanical and electrical properties. 6. ASSESSMENT OF TEST METHODS The mechanical properties of 3D-printed parts vary depending on the following factors: material used (brand, density, molecular weight, quality, etc),AMtechnologyused, infill %, printing orientation (build and raster), layer height (resolution), infill pat-tern, cross-sectional area, post- processing (method and time), build number, and others. It is quite complicated and difficulttopredicthowa partwould behave given a certain mechanical load. 7. SUMMARY AND CONCLUSION Additive manufacturing technologies have gained significant advancement through the years andtheproducts of which are now being considered to replace those parts/materials that were manufactured through conventional methods. This report gave a brief overview of Additive Manufacturing (AM) and AM Technologies. The commonly-used ASTM and ISO mechanical test standards which have been used by various research groups to testthe strength of the 3D-printed parts have also been reported. Lastly, a comprehensive review of the mechanical characteristics of partsproducedbythevariousAMmethods have been discussed. These include results from different mechanical tests such as tensile, bending, compression, fatigue, impact and others. Properties at cryogenic temperatures have also been included. Effects of nano filler additions have been briefly discussed. Also, the effects of post-processing on the mechanical properties have been detailed for most of the AM methods. 3D-printed materials havelargeanisotropyespeciallyforthe FDM- and SLS-printed parts. The effects of post-processing on the mechanical properties are also significant especially in the case of SLA parts. Although it is still not possible to replace parts with the same material considering the anisotropy and the relatively lower strength of Additively Manufactured parts, there is a strong possibility that, with the wide variety of materials available for AM , the needed material properties could still be satisfied. And in some cases, exceed the original parts or those produced via traditional methods. With the different additive manufacturing technologies, print-ing parameters and considerations, it seems that we will not be seeing a single standard for a particular mechanical test. In the end, what is important is to have test standards in order to set a foundation to make the products more reproducible. REFERENCES [1] M. Chapiro, Current achievements and future outlook for composites in 3Dprinting, Reinf. Plast. 60 (6) (2016) 372– 375. (2) T. Koslow, 30 Greatest 3D Printed Houses&Structures in the World,ALL3DP, 16 April 2017. [Online], 2017, Available: https://all3dp.com/1/3d-printed-house-homes-buildings- 3d-printing-construction. (3) A. De Leon, Q. Chen, N. Palaganas, J. Palaganas, J. Manapat, R. Advincula, High performance polymer nano composites for additive manufacturing applications, React. Funct. Polym. 103 (2016) 141–155.