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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056
Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1014
A STUDY ON SELF-CURING AND SELF-COMPACTING CONCRETE USING
POLYETHYLENE GLYCOL
1Dadaji B. Jadhav, 2Ranjana Ghate,
1Dadaji B Jadhav Is Currently Pursuing Master Degree Program In Structural Engineering And Construction, BIT
Ballarpur, Maharashtra, India.
2Ranjana Ghate Is An Astt. Prof. In Dept. Of Civil Engineering, BIT Ballarpur, Maharashtra, India.
---------------------------------------------------------------------***---------------------------------------------------------------------
Abstract - Self-curing is done in order to fulfill the water
requirements of concrete whereas self-compactingconcreteis
prepared so that it can be placed in difficult positions and
congested reinforcements. Thisinvestigationisaimedtoutilize
the benefits of both self-curing as well as self-compacting. The
present investigation involves the use of self-curing agent viz.,
polyethylene glycol (PEG) of molecular weight 4000 (PEG
4000) for dosages ranging between 0.1 to 1% by weight of
cement added to mixing water. Two mixes with different w/c
ratio were considered in the investigation. Workability tests
i.e. slump flow, T50, V-funnel, J-ring, L-box were conducted on
the fresh concrete whereas water retention and compressive
strength were evaluated to determine the properties of
hardened concrete. Comparative studies were carried out for
water retention and compressive strength for conventional
SCC and self-cured SCC. The compressive strengthofself-cured
SCC are comparable with traditionalcuredspecimensatlower
w/c ratio whereas does not provide satisfactory results at
higher w/c ratio.
Key Words: self-curing, polyethylene glycol (PEG),
water retention, compressive strength.
1. INTRODUCTION
This chapter deals with the introduction to different
methods of curing and the difficultiesinconventional curing.
It also deals with the introduction of self-compacting
concrete with its advantages anddisadvantages.Thechapter
focuses on the need of self-curing along withselfcompacting
along with its mechanism, materials and advantages.
1.1 Need for self–curing
When the mineral admixtures react completely in a blended
cement system, their demand for curing water (external or
internal) can be much greater than that in a conventional
ordinary Portland cement concrete. When this water is not
readily available, due to depercolation of the capillary
porosity, for example, significant autogenous deformation
and (early-age) cracking may result. Due to the chemical
shrinkage occurring during cement hydration, empty pores
are created within the cement paste, leading to a reduction
in its internal relative humidity and also to shrinkage which
may cause early-age cracking. This situation is intensified in
HPC (compared to conventional concrete) due to its
generally highercementcontent, reduced water/cement(w/
c) ratio and the pozzolanic mineral admixtures(flyash,silica
fume). The empty pores created during self-desiccation
induce shrinkage stresses and also influence the kinetics of
cement hydration process, limiting the final degree of
hydration. The strength achieved by IC could be more than
that possible under saturated curing conditions. Often
specially in HPC, it is not easily possible to provide curing
water from the top surface at the rate required to satisfy the
ongoing chemical shrinkage, due to the extremely low
permeabilities often achieved.
1.2 Mechanism of internal curing
Continuous evaporation of moisture takes place from an
exposed surface due to the difference in chemical potentials
(free energy) between the vapour and liquid phases. The
polymers added in the mix mainly form hydrogen bonds
with water molecules and reduce the chemical potential of
the molecules which in turn reduces the vapour pressure,
thus reducing the rate of evaporation from the surface.
1.3 Potential materials for self-curing
The following materials can provide internal water
reservoirs:
[1]Lightweight Aggregate (natural and synthetic, expanded
shale),
[2]LWS Sand (Water absorption =17 %)
[3]LWA 19mm Coarse (Water absorption = 20%)
[4]Super-absorbent Polymers (SAP) (60-300 mm size)
[5]SRA (Shrinkage Reducing Admixture) (propylene glycol
type i.e. polyethylene-glycol)
[6]Wood powder
1.4 Concrete deficiencies that self-curing can
address
The benefit from self-curing can be expected when
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056
Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1015
1. Cracking of concrete provides passageways
resulting in deterioration of reinforcing steel,
2. low early-age strength is a problem,
3. permeability or durability must be improved,
4. Need for: reduced construction time, quicker
turnaround time in precast plants, lower
maintenance cost, greater performance and
predictability.
1.5 Self-compacting concrete
Self-compacting concrete is basically a concrete which is
capable of flowing in to the formwork, without segregation,
to fill uniformly and completely every corner of it by its own
weight without any application of vibration or other energy
during placing. There is no standard self-compacting
concrete. Therefore each self-compacting concrete has tobe
designed for the particular structure to be constructed.
However working on the parameters which affects the basic
properties of self-compacting concrete such as plastic
viscosity, deformability, flowing ability and resistance to
segregation, self-compacting concrete may be proportioned
for almost any type of concrete structure. To establish an
appropriate mixture proportion for a self-compacting
concrete the performance requirements must be defined
taking into account the structural conditions such as shape,
dimensions, reinforcement density and construction
conditions. The construction conditions include methods of
transporting, placing, finishing and curing. The specific
requirement of self-compacting concrete is its capacity for
self-compaction, without vibration, in the fresh state. Other
performances such as strength and durability should be
established as for normal concrete.Thehighlyfluidnatureof
SCC makes it suitable for placingindifficultconditionsand in
sections with congested reinforcement. Use of SCC can also
help minimize hearing-related damagesonthe worksitethat
are induced by vibration of concrete. Another advantage of
SCC is that the time required to place large sections is
considerably reduced.
 Principles of SCC mixture design
Small sized and limited coarse aggregate reduce internal
stresses causing blockage. HRWRs increase the paste flow,
VMAs increase paste viscosity to reduce segregation and
mineral admixtures lowertheheatofhydrationandenhance
the stability.
 Need of Study
A very limited work is reported from this area having the
benefits of both self-curing as well as self-compaction. The
future for this type of concrete is very bright due to scarcity
of skilled man power, non-mechanization of construction
industry, abundant availability of construction materials
available at very low cost. The properties of this type of
concrete, if found satisfactory would be a great step in
concrete technology compiling the advantages of both
internal curing as well as self-consolidation
2. LITERATURE REVIEW
This chapter includes the literature review that has
been carried out in order to understand the concept behind
the topic and accordingly plan the experimental programme
for further research in the same field.
2.1 Self-Curing Concrete
Dhir et al. [1] focused on achieving optimum cure of
concrete without the need for applying external curing
methods. The chemical ability to reduce evaporation from
solution and to improve water retention in OPC was
measured by weight loss. Initial surface absorption and
compressive strength tests were made to determine surface
permeability and strength development. The scanning
electron microscope was used to determine the influence of
admixtures on cement paste microstructure.
Conclusion
 It is possible to improve water retention in cement
paste by means of a chemical addition to the mix.
 Improved water retention does not always leadtoa
proportionate increase in degree of cement
hydration and hence better concrete properties,
although in many cases it does.
 A number of chemicals improved concrete surface
characteristics. It appears that the presence of the
chemical is enhancing hydration beyond that
achieved by water retention.
Liang et al. [2] observed that a combination of wax
preferably paraffin wax and glycol preferably polyethylene
glycol(PEG),when added to concrete enables internal curing
which in many respects is equal to or superior to traditional
forms of curing concrete. The internal curing compound
used has 10%PEG, 57%paraffin wax, 33% water (comp. 2).
The curing compound was tested for the following
parameters
 Evaporation rate
 Porosity
 Shrinkage
 Weight loss
 Compressive strength
The test results were compared with two other curing
compounds, membrane curing and no curing condition.
The curing compounds used were
Compound 1- Water, wax emulsion & high MW
polyethylene oxide
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056
Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1016
Compound 2- Water, paraffin wax, PEG (current
invention)
Compound 3- Water based polyethers
The following conclusion has been reached
 Internal curing composition 2 exhibits moisture
retention characteristics similar to those of the
solvent borne resin membrane andperformsbetter
than 3 day water curing.
 Internal curing composition 1 & 2 give compressive
strength similar to those of the solvent borne resin
membrane, however composition 3 shows a
significantly lower strength at higher dosages.
 Porosity and absorption values of internal curing
compound are comparable withsolvent borne resin
membrane and 3 day water curing.
2.2 Self-Compacting Concrete
Nan-su et al. [3] proposed a new mix design method for
self-compacting concrete (SCC). First, the amount of
aggregates required isdetermined,andthepasteofbindersis
then filled into the voids of aggregates to ensure that the
concrete thus obtained has flowability, self-compacting
ability and other desired SCC properties. The amount of
aggregates, binders and mixing water, as well as type and
dosage of superplasticizer (SP) to be used are the major
factors influencing the properties of SCC. Slump flow, V-
funnel, L-flow, U-box and compressive strength tests were
carried out to examine the performance of SCC, and the
results indicate that the proposed method could produce
successfully SCC of high quality.
Conclusions
 The aggregate PF determines the aggregatecontent
and influences the strength, flowability and self-
compacting ability.
 SCC designed and produced with the proposed mix
design method contains more sand but less coarse
aggregates, thus the passing ability through gaps of
reinforcement can be enhanced.
Bingol et al. [4] studied the effect of air curing, watercuring
and steam curing on the compressive strength of Self
Compacting Concrete (SCC). For the study, SCC is produced
with using silica fume (SF) instead of cement by weight, by
the ratios of 5%, 10% and 15%, and fly ash (FA) with the
ratios of 25%, 40% and 55%.
Conclusions derived from the experiment were:
 The increase in the replacement percentage of SF
resulted in increases incompressivestrength; while
the increase of FA content affected the compressive
strength inversely. SCC mixes with 15% SF
replacementofcementcontentprovidedthehighest
compressive strength.
 The highest compressive strength values were
obtained from standard cured specimens (cured in
water for 28 days). The increase in the watercuring
duration resulted in increases in compressive
strength. Air curing caused compressive strength
decreases and the lowest strength values are
obtained from air cured specimens for all groups.
 Both SF and FA replacement groups gained more
strength according to control group without any
mineral admixture, at steam curing applications.
2.3 Conclusions
• Use of PEG as a self-curing agent resulted in better
hydration of concrete.
• It can give strength on par with concrete withconventional
curing methods.
• Good workability can be achieved with the use of PEG.
• Lower water loss and increased relative humidity can be
expected.
• Lower water permeability and sorptivity achieved.
• Reduces self dessication, autogenous shrinkage and
chemical shrinkage to a maximum extent.
• Overall better performance of concrete.
• Lower workability observed in case of Polyacrylamide
(PAM) due to the formation of gelatinous structure.
• Lower dosage of PEG more efficient than higher dosage.
• Lower molecular weight PEG more effective than higher
molecular weight PEG.
• SCC with silica fume performs satisfactory than SCC with
Fly Ash from strength point of view.
• SCC requires initial water curing to achieve desirable
properties.
 Research Significance
materials i.e. Light weight aggregate (LWA) and Super
absorbent polymers (SAP) it can be concluded that use of
these potential materials tend to decrease the mechanical
properties of concrete.
n the current program use of shrinkage reducing
admixture i.e. PEG has been made in order to get the
maximum efficiency in relation to mechanical properties.
institution the dosage has been reduced to 0 to 1% to make
the concrete more efficient.
4. SCOPE AND OBJECTIVE OF INVESTIGATION
 The objective of the investigation istousethewater
soluble polymeric glycol, selected from a group
consisting of polyethylene glycol (PEG) of average
molecular weight (M.W) from 200 to 10000 as self-
curing agent and to decide the optimum dosage for
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056
Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1017
different curing conditions under arid atmospheric
conditions.
 The objective is to study the compressive strength
and water retention by varying the percentage of
PEG from 0% to 1% by weight of cement for self-
compacting concrete and compare it with
conventional SCC. Concrete weight loss with time
was evaluated to determine the water retention
capacity. Slump flow test, J ring test, L box test and
V-Funnel test were carriedoutonthefreshconcrete
to evaluate the workability of concrete.
 Two mixes of self-compacting concrete were
considered for the study. Polyethylene glycol (PEG)
of molecular weight 4000 was used as a self-curing
agent in concrete. The concrete mix with and
without Self curing agent were subjected to
different types of curing i.e. conventional and
indoor curing to study the above mention
parameters.
 Other objectives were to compare the effect
Polyethylene glycol (PEG) on other grades of SCC
and to find out the optimum dosage for each grade.
5. EXPERIMENTAL PROGRAMME
The experimental program is designed to investigate the
strength of self-curing self-compacting concrete by adding
poly ethylene glycol PEG4000 @ 0.1%, 0.5% and 1% by
weight of cement to the concrete.Theexperimental program
is aimed to study the workability, compressive strength and
water retention capacity. The slump flow test, J ring test, U
box test, L box and V-Funnel test were conducted for all
mixes to know the fresh property of concrete. Compressive
strength test was conducted at 7 and 28 days. The cubes
were weighed for 3, 7,14,21,28 and 56 days from the date of
demoulding to investigate the water retention capacity. In
this investigation the maximum dosage of self-curing agent
was restricted to 1% and minimum dosage to 0.1%. Two
different mixes with 28 days cube compressive strengths of
concrete were aimed i.e. 70MPa & 50MPa.Atotal of90cubes
were cast for the experimental programme.
 Nomenclature for specimen
MIX A - 28 days cube compressive strength of about 70
MPa
MIX C - 28 days cube compressive strength of about 50 MPa
O - Ordinary Portland cement (OPC)
PEG - Polyethylene Glycol
H - PEG 4000(Higher Molecular Weight)
I - Indoor Curing
W - Wet/Conventional Curing
SP - Superplasticizer
S.C.A - Self-Curing Agent
SCC - Self-Compacting Concrete
i. For example sample with name AOW represents SCC
Mix A with PEG 4000 and dosage of 0% by weightof
cement subjected to wet curing.
ii.Sample AOI represents SCC Mix A with PEG 4000 and
dosage of 0% by weight of cement subjected to
indoor curing.
iii. Sample AH1 represents SCC Mix A with PEG 4000
and dosage of 1% by weight of cement subjected to
indoor curing.
5.1 Materials used
The different materials used in this investigation are:
1.Cement
2.Fine aggregate
3.Coarse aggregate.
4.Polyethylene Glycol(PEG-4000)
5.Polycarboxylate Ether (superplasticizer)
6.Fly Ash
7.Silica Fume
8.Water
5.2 Mix design by Nan-Su Method
The principal consideration oftheproposedmethod
is to fill the paste of binders into voids of the aggregate
framework piled loosely. The loose unit weight of the
aggregate is according to the shoveling procedure of ASTM
C29, except discharging the aggregate at a height of 30cm
above to the top of the measure. Usually, the volume ratio of
aggregate is about 52–58%, in other words, the void in the
loose aggregate is about 42–48% according to ASTM C29.
The strength of SCC is provided by the aggregate binding by
the paste at hardened state, while the workability of SCC is
provided by the binding paste at fresh state. Therefore, the
contents of coarse andfineaggregates,binders,mixingwater
and SP will be the main factors influencing the properties of
SCC. With the proposed method, all we need to do istoselect
the qualified materials, do the calculations, conduct mixing
tests and make some adjustments, and SCC with good
flowability and segregation resistance can be obtained with
self-compacting ability as specified by the JSCE. The
procedures of the proposed mix design method can be
summarized in the following steps.
5.3 Conclusions
After analyzing the results obtained from the
experimental programme,thefollowingconclusionscouldbe
made regarding the use of PEG-4000 in case of self-
compacting concrete with low as well as high w/c ratios
5.3.1 For Water Retention

Increasing the percentage dosage of PEG-4000
increases the weight loss for lower w/c ratio. Thus
lower dosage showing better water retention for
lower w/c ratio.

Increasing the percentage dosage of PEG-4000
decreases the weight loss for higher w/c ratio.Thus
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056
Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1018
for higher w/c ratio higher dosage shows better
water retention.

Weight loss is more in initial ages comparedtolater
ages for both the grades of concrete. However the
loss is more in initial ages for lower grade
compared to higher grade. This may be attributed
to better sealing of lower w/c ratio in higher grade
of concrete.

With increase in age of curing, there is general
increase in the weight loss. However the loss is
more at lower grade as compared to high grade.

Water retention of SCC with low w/c ratioimproves
with the addition of PEG-4000 and the optimum
dosage is found to be 0.1%

Water retention of SCC with high w/c ratio
improves only at high dosage ofPEG-4000.Thusthe
optimum dosage for high w/c ratio is found to be
1%
5.3.2 For Compressive Strength

Compressive strength of SCC with lower w/c ratio
improves with the addition of PEG-4000 and is
almost equivalent to wet curing. Thus PEG-4000
inclusion proves to be beneficial. The optimum PEG
dosage at lower w/c ratio was found to be 0.1%.

Compressive strength of SCC with high w/c ratio
does not show favorable results and were observed
to be less than indoor curing for all the dosages.
Thus addition of PEG-4000 for high w/c ratio is
insignificant
6. COMPARATIVE STUDY OF TEST RESULTS
In this chapter with reference to the similar work
carried on PEG-4000 for 28 days cube compressive strength
of about 60MPa i.e. Mix B, the comparison has beenmadefor
water retention and compressivestrengthsothataddition of
PEG-4000 can be analyzed.
6.1 Water retention
The average weight loss for all the mixes i.e. Mix A,
Mix B, Mix C are given in Tables 7.1, 7.2, 7.3 respectively at
the ages of 3, 7, 14, 21, 28, 56 days. The w/c ratios used for
Mix A, Mix B, Mix C are 0.38, 0.45 and 0.52 respectively.
The conclusions that can be drawn in terms of water
retention are:
 Increasing the percentage dosage of PEG-4000
increases the weight loss for lower w/c ratio i.e.
Mix A. whereas increasing the percentage dosage
of PEG-4000 decreases the weight loss for higher
w/c ratio i.e. Mix B and Mix C.
 For lower w/c ratio lower dosage of PEG-4000
gives better water retention whereas for higher
w/c ratios higher dosage shows better water
retention.
 Weight loss is more in initial ages compared to
later ages for all the grades of concrete. However
the loss is more in initial ages for lower grades
compared to higher grade. This may be attributed
to better sealing of lower w/c ratio in highergrade
of concrete.
6.2 Compressive Strength
The compressive strength values at the age of 7 and 28
days for all the mixes i.e. Mix A, Mix C.
The conclusions arrived are:

Compressive strength of SCC with lower w/c ratio
(Mix A) improves with the addition of PEG-4000
and is almost equivalent to wet curing. Thus PEG-
4000 inclusion proves to be beneficial. The
optimum PEG dosage at lower w/c ratio was found
to be 0.1% for Mix A.

Compressive strength of SCC with high w/c ratio
(Mix B) improves with the addition of PEG-4000
and is higher than indoor curing at all dosages of
PEG-4000. The optimum dosage was found to be
1%.

Compressive strength of SCC with high w/c ratio
(Mix C) does not show favorable results and were
observed to be less than indoor curing for all the
dosages. Thus addition of PEG-4000 for high w/c
ratio is insignificant.
ACKNOWLEDGEMENT
With immensepleasureandgreatrespectItakethis
opportunity to express my deep sense of gratitude toward
my guide Miss. R. M. Ghate, Assistant professor and M-tech
co-ordinator, Mr. M.K. Ghumde, Assistant Professor, Civil
Engineering Department, BIT, Ballarpur for invaluable
guidance, inspiration, constant encouragement and
motivation throughout the project work.
I am grateful to Prof. S. B. Sohoni, Head of
Department, Civil Engineering, B.I.T, Ballarpur forproviding
the amicable environment and allowing me to useful
available facilities in this department during the course of
this study. We thankful to Dr. M. Basavaraj our beloved
principal, for his encouragement and providing all facilities
needed in our project.
I am thankful to Prof. R. M. Ghate and all the respected
Professor from the department of Civil Engineering, BIT,
Ballarpur, who helped me to understand basic
methodologies of my project.
I am very thankful to my friend and well-wisherwho
directly or indirectly helped me at every stage to complete
this work.
Last but not least, I would like to thanks my family
and almighty without their good wishes and blessing this
dissertation work could not have been completed.
DADAJI BHAGWAT JADHAV
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056
Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1019
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BIOGRAPHIES
Dadaji B. Jadhav Is Currently
Pursuing Master Degree Program
In Structural Engineering And
Construction, BIT Ballarpur,
Maharashtra, India.

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A Study On Self-Curing And Self-Compacting Concrete using Polyethylene Glycol

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1014 A STUDY ON SELF-CURING AND SELF-COMPACTING CONCRETE USING POLYETHYLENE GLYCOL 1Dadaji B. Jadhav, 2Ranjana Ghate, 1Dadaji B Jadhav Is Currently Pursuing Master Degree Program In Structural Engineering And Construction, BIT Ballarpur, Maharashtra, India. 2Ranjana Ghate Is An Astt. Prof. In Dept. Of Civil Engineering, BIT Ballarpur, Maharashtra, India. ---------------------------------------------------------------------***--------------------------------------------------------------------- Abstract - Self-curing is done in order to fulfill the water requirements of concrete whereas self-compactingconcreteis prepared so that it can be placed in difficult positions and congested reinforcements. Thisinvestigationisaimedtoutilize the benefits of both self-curing as well as self-compacting. The present investigation involves the use of self-curing agent viz., polyethylene glycol (PEG) of molecular weight 4000 (PEG 4000) for dosages ranging between 0.1 to 1% by weight of cement added to mixing water. Two mixes with different w/c ratio were considered in the investigation. Workability tests i.e. slump flow, T50, V-funnel, J-ring, L-box were conducted on the fresh concrete whereas water retention and compressive strength were evaluated to determine the properties of hardened concrete. Comparative studies were carried out for water retention and compressive strength for conventional SCC and self-cured SCC. The compressive strengthofself-cured SCC are comparable with traditionalcuredspecimensatlower w/c ratio whereas does not provide satisfactory results at higher w/c ratio. Key Words: self-curing, polyethylene glycol (PEG), water retention, compressive strength. 1. INTRODUCTION This chapter deals with the introduction to different methods of curing and the difficultiesinconventional curing. It also deals with the introduction of self-compacting concrete with its advantages anddisadvantages.Thechapter focuses on the need of self-curing along withselfcompacting along with its mechanism, materials and advantages. 1.1 Need for self–curing When the mineral admixtures react completely in a blended cement system, their demand for curing water (external or internal) can be much greater than that in a conventional ordinary Portland cement concrete. When this water is not readily available, due to depercolation of the capillary porosity, for example, significant autogenous deformation and (early-age) cracking may result. Due to the chemical shrinkage occurring during cement hydration, empty pores are created within the cement paste, leading to a reduction in its internal relative humidity and also to shrinkage which may cause early-age cracking. This situation is intensified in HPC (compared to conventional concrete) due to its generally highercementcontent, reduced water/cement(w/ c) ratio and the pozzolanic mineral admixtures(flyash,silica fume). The empty pores created during self-desiccation induce shrinkage stresses and also influence the kinetics of cement hydration process, limiting the final degree of hydration. The strength achieved by IC could be more than that possible under saturated curing conditions. Often specially in HPC, it is not easily possible to provide curing water from the top surface at the rate required to satisfy the ongoing chemical shrinkage, due to the extremely low permeabilities often achieved. 1.2 Mechanism of internal curing Continuous evaporation of moisture takes place from an exposed surface due to the difference in chemical potentials (free energy) between the vapour and liquid phases. The polymers added in the mix mainly form hydrogen bonds with water molecules and reduce the chemical potential of the molecules which in turn reduces the vapour pressure, thus reducing the rate of evaporation from the surface. 1.3 Potential materials for self-curing The following materials can provide internal water reservoirs: [1]Lightweight Aggregate (natural and synthetic, expanded shale), [2]LWS Sand (Water absorption =17 %) [3]LWA 19mm Coarse (Water absorption = 20%) [4]Super-absorbent Polymers (SAP) (60-300 mm size) [5]SRA (Shrinkage Reducing Admixture) (propylene glycol type i.e. polyethylene-glycol) [6]Wood powder 1.4 Concrete deficiencies that self-curing can address The benefit from self-curing can be expected when
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1015 1. Cracking of concrete provides passageways resulting in deterioration of reinforcing steel, 2. low early-age strength is a problem, 3. permeability or durability must be improved, 4. Need for: reduced construction time, quicker turnaround time in precast plants, lower maintenance cost, greater performance and predictability. 1.5 Self-compacting concrete Self-compacting concrete is basically a concrete which is capable of flowing in to the formwork, without segregation, to fill uniformly and completely every corner of it by its own weight without any application of vibration or other energy during placing. There is no standard self-compacting concrete. Therefore each self-compacting concrete has tobe designed for the particular structure to be constructed. However working on the parameters which affects the basic properties of self-compacting concrete such as plastic viscosity, deformability, flowing ability and resistance to segregation, self-compacting concrete may be proportioned for almost any type of concrete structure. To establish an appropriate mixture proportion for a self-compacting concrete the performance requirements must be defined taking into account the structural conditions such as shape, dimensions, reinforcement density and construction conditions. The construction conditions include methods of transporting, placing, finishing and curing. The specific requirement of self-compacting concrete is its capacity for self-compaction, without vibration, in the fresh state. Other performances such as strength and durability should be established as for normal concrete.Thehighlyfluidnatureof SCC makes it suitable for placingindifficultconditionsand in sections with congested reinforcement. Use of SCC can also help minimize hearing-related damagesonthe worksitethat are induced by vibration of concrete. Another advantage of SCC is that the time required to place large sections is considerably reduced.  Principles of SCC mixture design Small sized and limited coarse aggregate reduce internal stresses causing blockage. HRWRs increase the paste flow, VMAs increase paste viscosity to reduce segregation and mineral admixtures lowertheheatofhydrationandenhance the stability.  Need of Study A very limited work is reported from this area having the benefits of both self-curing as well as self-compaction. The future for this type of concrete is very bright due to scarcity of skilled man power, non-mechanization of construction industry, abundant availability of construction materials available at very low cost. The properties of this type of concrete, if found satisfactory would be a great step in concrete technology compiling the advantages of both internal curing as well as self-consolidation 2. LITERATURE REVIEW This chapter includes the literature review that has been carried out in order to understand the concept behind the topic and accordingly plan the experimental programme for further research in the same field. 2.1 Self-Curing Concrete Dhir et al. [1] focused on achieving optimum cure of concrete without the need for applying external curing methods. The chemical ability to reduce evaporation from solution and to improve water retention in OPC was measured by weight loss. Initial surface absorption and compressive strength tests were made to determine surface permeability and strength development. The scanning electron microscope was used to determine the influence of admixtures on cement paste microstructure. Conclusion  It is possible to improve water retention in cement paste by means of a chemical addition to the mix.  Improved water retention does not always leadtoa proportionate increase in degree of cement hydration and hence better concrete properties, although in many cases it does.  A number of chemicals improved concrete surface characteristics. It appears that the presence of the chemical is enhancing hydration beyond that achieved by water retention. Liang et al. [2] observed that a combination of wax preferably paraffin wax and glycol preferably polyethylene glycol(PEG),when added to concrete enables internal curing which in many respects is equal to or superior to traditional forms of curing concrete. The internal curing compound used has 10%PEG, 57%paraffin wax, 33% water (comp. 2). The curing compound was tested for the following parameters  Evaporation rate  Porosity  Shrinkage  Weight loss  Compressive strength The test results were compared with two other curing compounds, membrane curing and no curing condition. The curing compounds used were Compound 1- Water, wax emulsion & high MW polyethylene oxide
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1016 Compound 2- Water, paraffin wax, PEG (current invention) Compound 3- Water based polyethers The following conclusion has been reached  Internal curing composition 2 exhibits moisture retention characteristics similar to those of the solvent borne resin membrane andperformsbetter than 3 day water curing.  Internal curing composition 1 & 2 give compressive strength similar to those of the solvent borne resin membrane, however composition 3 shows a significantly lower strength at higher dosages.  Porosity and absorption values of internal curing compound are comparable withsolvent borne resin membrane and 3 day water curing. 2.2 Self-Compacting Concrete Nan-su et al. [3] proposed a new mix design method for self-compacting concrete (SCC). First, the amount of aggregates required isdetermined,andthepasteofbindersis then filled into the voids of aggregates to ensure that the concrete thus obtained has flowability, self-compacting ability and other desired SCC properties. The amount of aggregates, binders and mixing water, as well as type and dosage of superplasticizer (SP) to be used are the major factors influencing the properties of SCC. Slump flow, V- funnel, L-flow, U-box and compressive strength tests were carried out to examine the performance of SCC, and the results indicate that the proposed method could produce successfully SCC of high quality. Conclusions  The aggregate PF determines the aggregatecontent and influences the strength, flowability and self- compacting ability.  SCC designed and produced with the proposed mix design method contains more sand but less coarse aggregates, thus the passing ability through gaps of reinforcement can be enhanced. Bingol et al. [4] studied the effect of air curing, watercuring and steam curing on the compressive strength of Self Compacting Concrete (SCC). For the study, SCC is produced with using silica fume (SF) instead of cement by weight, by the ratios of 5%, 10% and 15%, and fly ash (FA) with the ratios of 25%, 40% and 55%. Conclusions derived from the experiment were:  The increase in the replacement percentage of SF resulted in increases incompressivestrength; while the increase of FA content affected the compressive strength inversely. SCC mixes with 15% SF replacementofcementcontentprovidedthehighest compressive strength.  The highest compressive strength values were obtained from standard cured specimens (cured in water for 28 days). The increase in the watercuring duration resulted in increases in compressive strength. Air curing caused compressive strength decreases and the lowest strength values are obtained from air cured specimens for all groups.  Both SF and FA replacement groups gained more strength according to control group without any mineral admixture, at steam curing applications. 2.3 Conclusions • Use of PEG as a self-curing agent resulted in better hydration of concrete. • It can give strength on par with concrete withconventional curing methods. • Good workability can be achieved with the use of PEG. • Lower water loss and increased relative humidity can be expected. • Lower water permeability and sorptivity achieved. • Reduces self dessication, autogenous shrinkage and chemical shrinkage to a maximum extent. • Overall better performance of concrete. • Lower workability observed in case of Polyacrylamide (PAM) due to the formation of gelatinous structure. • Lower dosage of PEG more efficient than higher dosage. • Lower molecular weight PEG more effective than higher molecular weight PEG. • SCC with silica fume performs satisfactory than SCC with Fly Ash from strength point of view. • SCC requires initial water curing to achieve desirable properties.  Research Significance materials i.e. Light weight aggregate (LWA) and Super absorbent polymers (SAP) it can be concluded that use of these potential materials tend to decrease the mechanical properties of concrete. n the current program use of shrinkage reducing admixture i.e. PEG has been made in order to get the maximum efficiency in relation to mechanical properties. institution the dosage has been reduced to 0 to 1% to make the concrete more efficient. 4. SCOPE AND OBJECTIVE OF INVESTIGATION  The objective of the investigation istousethewater soluble polymeric glycol, selected from a group consisting of polyethylene glycol (PEG) of average molecular weight (M.W) from 200 to 10000 as self- curing agent and to decide the optimum dosage for
  • 4. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1017 different curing conditions under arid atmospheric conditions.  The objective is to study the compressive strength and water retention by varying the percentage of PEG from 0% to 1% by weight of cement for self- compacting concrete and compare it with conventional SCC. Concrete weight loss with time was evaluated to determine the water retention capacity. Slump flow test, J ring test, L box test and V-Funnel test were carriedoutonthefreshconcrete to evaluate the workability of concrete.  Two mixes of self-compacting concrete were considered for the study. Polyethylene glycol (PEG) of molecular weight 4000 was used as a self-curing agent in concrete. The concrete mix with and without Self curing agent were subjected to different types of curing i.e. conventional and indoor curing to study the above mention parameters.  Other objectives were to compare the effect Polyethylene glycol (PEG) on other grades of SCC and to find out the optimum dosage for each grade. 5. EXPERIMENTAL PROGRAMME The experimental program is designed to investigate the strength of self-curing self-compacting concrete by adding poly ethylene glycol PEG4000 @ 0.1%, 0.5% and 1% by weight of cement to the concrete.Theexperimental program is aimed to study the workability, compressive strength and water retention capacity. The slump flow test, J ring test, U box test, L box and V-Funnel test were conducted for all mixes to know the fresh property of concrete. Compressive strength test was conducted at 7 and 28 days. The cubes were weighed for 3, 7,14,21,28 and 56 days from the date of demoulding to investigate the water retention capacity. In this investigation the maximum dosage of self-curing agent was restricted to 1% and minimum dosage to 0.1%. Two different mixes with 28 days cube compressive strengths of concrete were aimed i.e. 70MPa & 50MPa.Atotal of90cubes were cast for the experimental programme.  Nomenclature for specimen MIX A - 28 days cube compressive strength of about 70 MPa MIX C - 28 days cube compressive strength of about 50 MPa O - Ordinary Portland cement (OPC) PEG - Polyethylene Glycol H - PEG 4000(Higher Molecular Weight) I - Indoor Curing W - Wet/Conventional Curing SP - Superplasticizer S.C.A - Self-Curing Agent SCC - Self-Compacting Concrete i. For example sample with name AOW represents SCC Mix A with PEG 4000 and dosage of 0% by weightof cement subjected to wet curing. ii.Sample AOI represents SCC Mix A with PEG 4000 and dosage of 0% by weight of cement subjected to indoor curing. iii. Sample AH1 represents SCC Mix A with PEG 4000 and dosage of 1% by weight of cement subjected to indoor curing. 5.1 Materials used The different materials used in this investigation are: 1.Cement 2.Fine aggregate 3.Coarse aggregate. 4.Polyethylene Glycol(PEG-4000) 5.Polycarboxylate Ether (superplasticizer) 6.Fly Ash 7.Silica Fume 8.Water 5.2 Mix design by Nan-Su Method The principal consideration oftheproposedmethod is to fill the paste of binders into voids of the aggregate framework piled loosely. The loose unit weight of the aggregate is according to the shoveling procedure of ASTM C29, except discharging the aggregate at a height of 30cm above to the top of the measure. Usually, the volume ratio of aggregate is about 52–58%, in other words, the void in the loose aggregate is about 42–48% according to ASTM C29. The strength of SCC is provided by the aggregate binding by the paste at hardened state, while the workability of SCC is provided by the binding paste at fresh state. Therefore, the contents of coarse andfineaggregates,binders,mixingwater and SP will be the main factors influencing the properties of SCC. With the proposed method, all we need to do istoselect the qualified materials, do the calculations, conduct mixing tests and make some adjustments, and SCC with good flowability and segregation resistance can be obtained with self-compacting ability as specified by the JSCE. The procedures of the proposed mix design method can be summarized in the following steps. 5.3 Conclusions After analyzing the results obtained from the experimental programme,thefollowingconclusionscouldbe made regarding the use of PEG-4000 in case of self- compacting concrete with low as well as high w/c ratios 5.3.1 For Water Retention  Increasing the percentage dosage of PEG-4000 increases the weight loss for lower w/c ratio. Thus lower dosage showing better water retention for lower w/c ratio.  Increasing the percentage dosage of PEG-4000 decreases the weight loss for higher w/c ratio.Thus
  • 5. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1018 for higher w/c ratio higher dosage shows better water retention.  Weight loss is more in initial ages comparedtolater ages for both the grades of concrete. However the loss is more in initial ages for lower grade compared to higher grade. This may be attributed to better sealing of lower w/c ratio in higher grade of concrete.  With increase in age of curing, there is general increase in the weight loss. However the loss is more at lower grade as compared to high grade.  Water retention of SCC with low w/c ratioimproves with the addition of PEG-4000 and the optimum dosage is found to be 0.1%  Water retention of SCC with high w/c ratio improves only at high dosage ofPEG-4000.Thusthe optimum dosage for high w/c ratio is found to be 1% 5.3.2 For Compressive Strength  Compressive strength of SCC with lower w/c ratio improves with the addition of PEG-4000 and is almost equivalent to wet curing. Thus PEG-4000 inclusion proves to be beneficial. The optimum PEG dosage at lower w/c ratio was found to be 0.1%.  Compressive strength of SCC with high w/c ratio does not show favorable results and were observed to be less than indoor curing for all the dosages. Thus addition of PEG-4000 for high w/c ratio is insignificant 6. COMPARATIVE STUDY OF TEST RESULTS In this chapter with reference to the similar work carried on PEG-4000 for 28 days cube compressive strength of about 60MPa i.e. Mix B, the comparison has beenmadefor water retention and compressivestrengthsothataddition of PEG-4000 can be analyzed. 6.1 Water retention The average weight loss for all the mixes i.e. Mix A, Mix B, Mix C are given in Tables 7.1, 7.2, 7.3 respectively at the ages of 3, 7, 14, 21, 28, 56 days. The w/c ratios used for Mix A, Mix B, Mix C are 0.38, 0.45 and 0.52 respectively. The conclusions that can be drawn in terms of water retention are:  Increasing the percentage dosage of PEG-4000 increases the weight loss for lower w/c ratio i.e. Mix A. whereas increasing the percentage dosage of PEG-4000 decreases the weight loss for higher w/c ratio i.e. Mix B and Mix C.  For lower w/c ratio lower dosage of PEG-4000 gives better water retention whereas for higher w/c ratios higher dosage shows better water retention.  Weight loss is more in initial ages compared to later ages for all the grades of concrete. However the loss is more in initial ages for lower grades compared to higher grade. This may be attributed to better sealing of lower w/c ratio in highergrade of concrete. 6.2 Compressive Strength The compressive strength values at the age of 7 and 28 days for all the mixes i.e. Mix A, Mix C. The conclusions arrived are:  Compressive strength of SCC with lower w/c ratio (Mix A) improves with the addition of PEG-4000 and is almost equivalent to wet curing. Thus PEG- 4000 inclusion proves to be beneficial. The optimum PEG dosage at lower w/c ratio was found to be 0.1% for Mix A.  Compressive strength of SCC with high w/c ratio (Mix B) improves with the addition of PEG-4000 and is higher than indoor curing at all dosages of PEG-4000. The optimum dosage was found to be 1%.  Compressive strength of SCC with high w/c ratio (Mix C) does not show favorable results and were observed to be less than indoor curing for all the dosages. Thus addition of PEG-4000 for high w/c ratio is insignificant. ACKNOWLEDGEMENT With immensepleasureandgreatrespectItakethis opportunity to express my deep sense of gratitude toward my guide Miss. R. M. Ghate, Assistant professor and M-tech co-ordinator, Mr. M.K. Ghumde, Assistant Professor, Civil Engineering Department, BIT, Ballarpur for invaluable guidance, inspiration, constant encouragement and motivation throughout the project work. I am grateful to Prof. S. B. Sohoni, Head of Department, Civil Engineering, B.I.T, Ballarpur forproviding the amicable environment and allowing me to useful available facilities in this department during the course of this study. We thankful to Dr. M. Basavaraj our beloved principal, for his encouragement and providing all facilities needed in our project. I am thankful to Prof. R. M. Ghate and all the respected Professor from the department of Civil Engineering, BIT, Ballarpur, who helped me to understand basic methodologies of my project. I am very thankful to my friend and well-wisherwho directly or indirectly helped me at every stage to complete this work. Last but not least, I would like to thanks my family and almighty without their good wishes and blessing this dissertation work could not have been completed. DADAJI BHAGWAT JADHAV
  • 6. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1019 REFERENCES [1] R.K. Dhir, P.C. Hewlett and T.D. Dyer, “An investigation into the feasibility of formulating'self- cure' concrete”, Materials and Structures Vol.27(1994), 606-615. [2] R.K. Dhir, P.C. Hewlettand T.D.Dyer,”Durabilityof „Self-Cure Concrete”,Cement andConcreteResearch, Vol. 25. No. 6, 1153-1158, 1995. [3] Roland Tak Yong Liang, Robert Keith Sun, “Compositions and Methods for Curing Concrete”, Patent No.: US 6,468,344 B1, Date of Patent Oct. 22, 2002. [4] Mario Collepardi, Antonio Borsoi, Silvia Collepardi, Jean Jacob Ogoumah Olagot, Roberto Troli, “Effects of shrinkage reducing admixture in shrinkage compensating concrete under non-wet curing conditions”, Cement & Concrete Composites vol. 27 (2005) 704–708. [5] M. Collepardi, A. Borsoi, S. Collepardi, R. Troli and M. Valente, “Self-Curing, Shrinkage-Free Concrete”, ACI Material Journal SP 234-47 (2006) 755-764. [6] A.S.El-Dieb, “Self-curing Concrete: WaterRetention, hydration and moisturetransport”,Constructionand Building Materials Vol.21 (2007) 1282-1287. [7] Wen-Chen Jau, “Self-curing Concrete”,UnitedStates Patent Application Publication, Pub. No: U.S. 2008/0072799 A1, Pub. date: Mar. 27, 2008. [8] Bart Craeye , Matthew Geirnaert , Geert De Schutter, “Super absorbing polymers as an internal curing agent for mitigation of early-age cracking of high-performance concrete bridge decks”, Construction and Building Materials vol. 25 (2011) 1–13. [9] Garje Rajesh Kumar, “Self Curing Concrete”, International RILEM conference on advances in construction materials through science and engineering, Hong Kong, China 5-7 September2011, pp.116-123. [10] Raghavendra Y.B and Aswath M.U,”Experimental investigation on concrete cured with various curing Methods-A Comparative Study”, International Journal of Advanced Scientific Research and Technology, Issue: 2, Vol.3 (2012) 577-584. [11] Jagannadha Kumar M.V, Srikanth M, Rao K.Jagannadha, ”Strength Characteristics of Self- curing Concrete”, International Journal of Research in Engineering & Technology,Issue:1,Vol.1(2012)51 -57. [12] A.S. El-Dieb, T.A. El-Maaddawy and A.A.M. Mahmoud, “Water-Soluble Polymers as Self-Curing Agent in Silica Fume Portland Cement Mixes”, ACI Material Journal Vol.278 (2011) 1-18. [13] Ozawa K, Maekawa K, Kunishima M & Okamura H, “Development of high performance concrete based on the durability design of concrete structures”, EASEC-2, Vol. 1, 1989, pp.445-450. [14] Okamura H & Ozawa K, “Mix-design for self- compacting concrete”, Concrete Library of JSCE, No. 25, June 1995, pp.107-120. [15] Nan Su, Kung-Chung Hsu, His-Wen Chai, “A simple mix design method for self-compacting concrete”, Cement and Concrete Research, 6 June 2001, pp1799-1807. [16] A.M.M. Sheinn, C.T. Tam, F.L. Rodrigo, “Comparative study on hardened properties of self- compacting concrete (SCC) with normal slump concrete (NSC)”,29thconferenceOur World in Concrete and Structures (OWICs) ,2004 [17] SalihYazicioglu, SinanCaliskan, Kazim Turk, “Effect of curing conditions on the engineering properties of self-compacting concrete”, Indian Journal of Engineering & Materials Sciences, Vol. 13, February 2006 [18] A. FerhatBingol , IlhanTohumcu, “Effects of different curingregimesonthecompressivestrength properties ofself-compactingconcreteincorporating fly ash and silica fume”, Materials and Design 51 (2013) 12–18 [19] Pamnani Nanak J., Verma A.K., Bhatt Darshana R., “Comparison OfCompressiveStrengthOfMedium Strength Self Compacted Concrete By Different Curing Techniques”, International Journal of Engineering Trends and Technology (IJETT) - Volume4Issue5- May 2013, ISSN: 2231-5381 [20] Text book on “ Concrete Technology- “Theory and Practice” by M.S.SHETTY [21] EFNARC, “Specification and Guidelines for Self- Compacting Concrete”, EFNARC, Association House, UK, February 2005. [22] IS-383-1970, “Specification for coarse and fine aggregates from natural sources for concrete”. [23] IS: 516–1956 (Reaffirmed 1999), “Indian Standard Methods of Tests for StrengthofConcrete”. [24] IS: 12269:1987, “Specifications for 53 grade ordinary Portland cement”. [25] IS: 2386, “Method of test for aggregate for concrete”, reprinted 1997. [26] IS: 456-2000, Code of practice for plain and reinforced concrete. Bureau of Indian Standards, 2000. BIOGRAPHIES Dadaji B. Jadhav Is Currently Pursuing Master Degree Program In Structural Engineering And Construction, BIT Ballarpur, Maharashtra, India.