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Biogeochemical Cycles
Vivek Srivasatava
Energy/Matter Flow
• Energy and matter flow through the
biosphere
• Sun >> autotroph >> heterotroph >> fossil
fuel storage >> human fuel consumption
• Biosphere < > lithosphere < > atmosphere
< > hydrosphere
• Elements cycle through both the biological
and geological world, hence
biogeochemical cycles
Elemental Cycles
• H, O, and C make up > 99 % of the Earth’s
biomass
• N, Ca, K, Mg, S, and P are significant
nutrients
• Cycling of C, O, N, P, and S are discussed
in this chapter
Concepts in Biogeo. Cycles
•
•
•
•

Reservoir - where material or mass is stored
Flux: rate of flow of material
Steady state: inflow = outflow
Dynamic state: fluxes are reservoirs are
changing with time
• Residence time: length of time a chemical
stays in a reservoir
• Feedback: positive and negative
Reservoirs of Carbon
•
•
•
•
•
•

Carbon is found in all four spheres
Biosphere - organic matter
Atmosphere - CO2, CH4
Hydrosphere - H2CO3 ,HCO3 - , CO3 =
Lithosphere - CaCO3 , coal, oil, and gas
Processes: photosynthesis, formation of
sediments, weathering, combustion, plate
tectonics
Carbon Cycle
Human Interference
• Human-induced processes
– Extraction and combustion of fossil fuels
(speeds up the medium-term cycling)
– Cement manufacturing
– Deforestation (biomass burning)

• All of these processes release CO2 into the
atmosphere and affect the natural cycling of
carbon
Oxygen Cycle
• Essential for aerobic life
• Closely linked to carbon cycle
• Very large reservoir (20% of gas in atm.),
not susceptible to human interference
• Also, not a greenhouse gas
• Reservoirs: atmosphere, surface organic
material (biosphere), and buried organic
matter (lithosphere)
Nitrogen Cycle
• Essential to life - important in forming
amino acids >> proteins
• Most abundant in the atmosphere (79%)
• Flows continuously through the spheres
• Reservoirs: atmosphere and biosphere (soil)
• Processes: Nitrogen fixation/ nitrification
and denitrification
• Atmosphere => soil => plants =>
atmosphere (fig. 5.7)
Nitrogen Cycle
• Nitrification/ nitrogen fixation: converts N 2
to forms usable by plants (NH3, and NO3-)
• Denitrification: is the conversion of NO 3back to N2 in the atmosphere or in gases in
the soil
• Symbiotic relationship: bacteria supply the
plant with usable nitrogen and feed off the
sugars and starches made by the plant
Nitrogen Cycle
• Human activities account for >50% of
nitrogen fixation (fertilizers, cultivation of
nitrogen fixing plants)
• Denitrification - done mainly by bacteria
not by humans.
• Despite the huge size of the atmospheric
reservoir of nitrogen, human activites
profoundly affect the nitrogen cycle
Nitrogen
Cycle
Eutrophication
• Consequence of excess nutrients (nitrates,
phosphates) entering bodies of water
• Produces algal blooms (over productivity)
• When these algae die they settle at the bottom of
the water column
• Decomposition process consumes oxygen and
depletes it from water
• This destroys the organisms that need oxygen
(fish)- Lions Lake, Warrensburg, source of
nutrient - goose droppings
Phosphorus Cycle
(Phosphorus is required for the manufacture
of ATP and all nucleic acids)

1. Reservoir – erosion transfers phosphorus to water and
soil; sediments and rocks that accumulate on
ocean floors return to the surface as a result of
uplifting by geological processes
2. Assimilation – plants absorb inorganic PO43(phosphate) from soils; animals obtain organic
phosphorus when they plants and other
animals
3. Release – plants and animals release phosphorus when
they decompose; animals excrete phosphorus
in their waste products
Phosphorus Cycle
• Long-term cycle: Burial of phosphate in
sediments => uplift => weathering =>
phosphate in soil or ocean
• Residence time ~108 yrs
• Extraction (mining) short-circuits the longterm cycle
Phosphorus Cycle
• Reservoirs: Hydrosphere (as phosphate
ion), lithosphere (phosphate minerals), and
biosphere (bones, teeth, shells)
• Short-term cycle: PO43- in soil or ocean =>
assimilation by plants => consumption by
animals => decay or excretion => recycled
to soil or ocean, residence time 100s of yrs
Phosphorus Cycle
• Atmosphere is not a source
• As with nitrate, phosphate is an important
nutrient in coastal upwelling zones
• As with nitrate, humans are doubling the
rate of transport of phosphate into the
environment through the application of
fertilizers
Nitrogen Cycle
Phosphorus Cycle

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Biogeocycles

  • 2. Energy/Matter Flow • Energy and matter flow through the biosphere • Sun >> autotroph >> heterotroph >> fossil fuel storage >> human fuel consumption • Biosphere < > lithosphere < > atmosphere < > hydrosphere • Elements cycle through both the biological and geological world, hence biogeochemical cycles
  • 3. Elemental Cycles • H, O, and C make up > 99 % of the Earth’s biomass • N, Ca, K, Mg, S, and P are significant nutrients • Cycling of C, O, N, P, and S are discussed in this chapter
  • 4. Concepts in Biogeo. Cycles • • • • Reservoir - where material or mass is stored Flux: rate of flow of material Steady state: inflow = outflow Dynamic state: fluxes are reservoirs are changing with time • Residence time: length of time a chemical stays in a reservoir • Feedback: positive and negative
  • 5. Reservoirs of Carbon • • • • • • Carbon is found in all four spheres Biosphere - organic matter Atmosphere - CO2, CH4 Hydrosphere - H2CO3 ,HCO3 - , CO3 = Lithosphere - CaCO3 , coal, oil, and gas Processes: photosynthesis, formation of sediments, weathering, combustion, plate tectonics
  • 7. Human Interference • Human-induced processes – Extraction and combustion of fossil fuels (speeds up the medium-term cycling) – Cement manufacturing – Deforestation (biomass burning) • All of these processes release CO2 into the atmosphere and affect the natural cycling of carbon
  • 8. Oxygen Cycle • Essential for aerobic life • Closely linked to carbon cycle • Very large reservoir (20% of gas in atm.), not susceptible to human interference • Also, not a greenhouse gas • Reservoirs: atmosphere, surface organic material (biosphere), and buried organic matter (lithosphere)
  • 9. Nitrogen Cycle • Essential to life - important in forming amino acids >> proteins • Most abundant in the atmosphere (79%) • Flows continuously through the spheres • Reservoirs: atmosphere and biosphere (soil) • Processes: Nitrogen fixation/ nitrification and denitrification • Atmosphere => soil => plants => atmosphere (fig. 5.7)
  • 10. Nitrogen Cycle • Nitrification/ nitrogen fixation: converts N 2 to forms usable by plants (NH3, and NO3-) • Denitrification: is the conversion of NO 3back to N2 in the atmosphere or in gases in the soil • Symbiotic relationship: bacteria supply the plant with usable nitrogen and feed off the sugars and starches made by the plant
  • 11. Nitrogen Cycle • Human activities account for >50% of nitrogen fixation (fertilizers, cultivation of nitrogen fixing plants) • Denitrification - done mainly by bacteria not by humans. • Despite the huge size of the atmospheric reservoir of nitrogen, human activites profoundly affect the nitrogen cycle
  • 13. Eutrophication • Consequence of excess nutrients (nitrates, phosphates) entering bodies of water • Produces algal blooms (over productivity) • When these algae die they settle at the bottom of the water column • Decomposition process consumes oxygen and depletes it from water • This destroys the organisms that need oxygen (fish)- Lions Lake, Warrensburg, source of nutrient - goose droppings
  • 14. Phosphorus Cycle (Phosphorus is required for the manufacture of ATP and all nucleic acids) 1. Reservoir – erosion transfers phosphorus to water and soil; sediments and rocks that accumulate on ocean floors return to the surface as a result of uplifting by geological processes 2. Assimilation – plants absorb inorganic PO43(phosphate) from soils; animals obtain organic phosphorus when they plants and other animals 3. Release – plants and animals release phosphorus when they decompose; animals excrete phosphorus in their waste products
  • 15. Phosphorus Cycle • Long-term cycle: Burial of phosphate in sediments => uplift => weathering => phosphate in soil or ocean • Residence time ~108 yrs • Extraction (mining) short-circuits the longterm cycle
  • 16. Phosphorus Cycle • Reservoirs: Hydrosphere (as phosphate ion), lithosphere (phosphate minerals), and biosphere (bones, teeth, shells) • Short-term cycle: PO43- in soil or ocean => assimilation by plants => consumption by animals => decay or excretion => recycled to soil or ocean, residence time 100s of yrs
  • 17. Phosphorus Cycle • Atmosphere is not a source • As with nitrate, phosphate is an important nutrient in coastal upwelling zones • As with nitrate, humans are doubling the rate of transport of phosphate into the environment through the application of fertilizers