Biodiesel is a form of diesel fuel derived from plants or animals and consisting of long-chain fatty acid esters. It is typically made by chemically reacting lipids such as animal fat (tallow), soybean oil, or some other vegetable oil with alcohol, producing a methyl, ethyl, or propyl ester.
2. A biofuel is a type of fuel whose
energy is derived from biological
carbon fixation.
In other words, Fuel which is produced
from renewable biological resources
such as plant biomass and treated
municipal and industrial waste .
Some commercially used biofuels:
Bioethanol, Biodiesel, Biogas
3. Chemically, biodiesel molecules are
mono-alkyl esters produced from
triglyceride esters by
transesterification.
Alternative fuel for diesel engines.
Made from vegetable oil and animal
fats.
Lower emissions.
Biodegradable.
4. The major steps required to synthesize
biodiesel are as follows:
Feedstock pretreatment
Common feedstock used are vegetable oil,
yellow grease and tallow.
Degumming is done to remove phospholipids
and other plant matters.
Water is removed to prevent triglyceride
production during base-catalyzed
transesterification.
Free fatty acids are removed by
transesterification or neutralization.
Reactions
Transesterification.
Base catalyzed transesterification.
Product purification
5. Transesterification is a chemical reaction where triglyceride is reacted with alcohol to
produce alkyl esters.
This reaction proceed exceedingly slow so heat as well catalysts are used.
Common catalysts used are :
Sodium hydroxide
Potassium hydroxide
Sodium methoxide
The reaction between the biolipid (fat or oil) and the alcohol is a reversible reaction so
excess alcohol must be added to ensure complete conversion.
6.
7. Catalyst-free method for transesterification.
Uses supercritical methanol at high
temperatures and pressures in a continuous
process.
In the supercritical state, the oil and methanol
are in a single phase, and reaction occurs
spontaneously and rapidly.
The process can tolerate water in the
feedstock, free fatty acids are converted to
methyl esters instead of soap.
High temperatures and pressures are
required, but energy costs of production are
similar or less than catalytic production
routes.
8. Ultra- and High Shear in-line or batch reactors
allow production of biodiesel continuously,
semi- continuously, and in batch-mode.
The reaction takes place in the high-energetic
shear zone of the Ultra- and High Shear mixer
by reducing the droplet size of the immiscible
liquids such as oil or fats and methanol.
9. Using an ultrasonic reactor for
biodiesel production drastically
reduces the reaction time,
reaction temperatures, and energy
input.
The ultrasonic waves cause the
reaction mixture to produce and
collapse bubbles constantly.
10. Researchers have found that very good yields could be obtained from crude and used
oils using lipases.
The use of lipases makes the reaction less sensitive to high free fatty-acid content.
Methyl acetate is used instead of methanol as methanol inactivate lipase after one
batch
11.
12. Advantages
High availability.
High combustion .
High biodegradability .
High energy safety.
Simple production .
Low sulphur content .
Low green house gas emission .
Disadvantages
High viscosity.
High pour point.
High Nox emission .
Low volatility.
Low energy content.
Cold ignition problem .
13. 3 degrees .
Five boro biofuels .
A2BE carbon capture LLC
AE biofuels inc formerly marwich II LTD.
AHL –TECH
Abundant biofuels
Acron technology corporation
Africa biomass company
Agni UK inc
Agrifuel company
Agribiofuels LLC
14. Recent Research and Developments in Biodiesel Production from Renew-able
Bioresources
Mohamed Chaker Ncibi* and Mika Sillanpää
Laboratory of Green Chemistry, Faculty of Technology, Lappeenranta University of
Technology, Sammonkatu 12, 50130, Mikkeli, Finland
Received: November 29, 2013 Revised: December 23, 2013 Accepted: December 24,
2013
Abstract: Research and development (R&D) in the field of biofuels in general and biodiesel
in particular are not new en-deavours. However, they gained momentum in the last couple
of decades due to the increasing economic concerns and environmental awareness about
the use of petroleum-derived fossil fuels. In this review article, recent patents and research
and studies dealing with the production of biodiesel from bioresources will be investigated
and discussed. The main objec-tive is to present the latest research undertakings, findings
and innovations in the scientific and industrial communities on biodiesel production for
various bioresources and wastes.