&
ADSORPTION
By SYEDA MARYAM HASSNY
DEFINITION
ABSORPTION ADSORPTION
 The process by which
one substance takes up
another substance through
minute pores or spaces
between them
 involves the whole
volume of material
 The process in which there
is adhesion of atoms , ions or
molecules from a gas , liquid
or dissolved solid to surface
 involves the surface
area of material
ADSORBATE
The substance that
gets adsorbed on to
the surface
ADSORBENT
The substance on the
surface of which
adsorption takes
place
EXAMPLE
If a gas is adsorbed
onto the surface of
the solid , then the
gas is termed as
ADSORBATE and
the solid is termed as
ADSORBENT
ABSORBENT
A material having
capacity or
tendency to
absorb another
substance
ABSORBATE
A material that
has been or is
capable of being
absorbed
ABSORBENT
ABSORBATE
ABSORBENT ABSORBATE
ADSORPTION - Vs - ABSORPTION
ADSORPTION ABSORPTION
 PHENOMENON
It is a surface phenomenon
 HEAT EXCHANGE
It is exothermic reaction
 TEMPRATURE
It is favored by low temp.
 RATE OF REACTION
It is steadily increases and
reaches equilibrium
 CONCENTRATION
Concentration on the
surface of adsorbent is
different from that in bulk
 PHENOMENON
It is a bulk phenomenon
 HEAT EXCHANGE
It is Endothermic reaction
 TEMPRATURE
It is generally not affected by
temp.
 RATE OF REACTION
It occurs at uniform rate
 CONCENTRATION
It is same throughout the
material
ADSORPTION ABSORPTION
 PROCESS
It is sorption process.
The process is sill unclear.
Adsorption is generally
classified into physisorption
(weak Vander wall forces )
and chemisorption (
covalent bond).It can also be
caused by electrostatic
attraction .
The molecules are held on
the surface of the adsorbent
and can be removed.
 PROCESS
It is sorption process
occurs when atoms passes
through or enter bulky
material .
During it molecules are
entirely dissolved or diffused
in the absorbent to form a
solution .
Once the molecules are
absorbed ,it become difficult
to separate it from absorbent
ABSORPTION ADSORPTION
TYPES OF ADSORPTION
PHYSICAL
ADSORPTION
CHEMICAL
ADSORPTION
TYPES OF ABSORPTION
PHYSICAL
ABSORPTION
CHEMICAL
ABSORPTION
PHYSICAL ADSORPTION
CHEMICAL
ADSORPTION
Caused by intermolecular forces
Caused by chemical bond
formation
Heat of adsorption is small Heat of adsorption is large
Decrease with increase in
temperature
Increase with pressure increase
Forms multimolecular layer
Increase with increase in
temperature
Change of pressure has no effect
Forms unimolecular layer
CHEMICAL PHYSICAL
ABSORPTION ABSORPTION
 Chemical
absorption is a
chemical reaction
between absorbed
and the absorbing
substance
 Physical absorption
is in which the
absorbent and
absorbate develops
weak Vander wall
force and it can be
reversible
EXAMPLES
OF
ADSORBENT
KOALIN ACTIVATED CHARCOAL
ALUMINA CREAM
FULLER’S EARTH
USES OF ADSORPTION
In TREATMENT of
DIARRHEA
In GAS MASK in adsorbing
ABNOXIOUS GASES
In CLARIFICATION of
SUGAR
In PAINT INDUSTRY
In adsorption of EXCESSIVE
GAS in the
GASTROINTESTINAL
TRACT and BACTERIAL
TOXIN
EXAMPLES
OF
ABSORBENT
COTTON
GRANULAR
INDUSTRIAL ABSORBENT
ABSORBENT PULP
ABSORBENT POLYMER
USES OF ABSORPTION
Used in ABSORPTION
CHILLERS for SPACE
COOLING APPLICATION
Use in CLEAN BURNING of
FUELS
The process of gas absorption
by a liquid is used in
HYDROGENATION OF OILS
Used in CARBONATION
Absorption and Adsorption

Absorption and Adsorption

  • 1.
  • 2.
    DEFINITION ABSORPTION ADSORPTION  Theprocess by which one substance takes up another substance through minute pores or spaces between them  involves the whole volume of material  The process in which there is adhesion of atoms , ions or molecules from a gas , liquid or dissolved solid to surface  involves the surface area of material
  • 4.
    ADSORBATE The substance that getsadsorbed on to the surface ADSORBENT The substance on the surface of which adsorption takes place EXAMPLE If a gas is adsorbed onto the surface of the solid , then the gas is termed as ADSORBATE and the solid is termed as ADSORBENT
  • 5.
    ABSORBENT A material having capacityor tendency to absorb another substance ABSORBATE A material that has been or is capable of being absorbed ABSORBENT ABSORBATE ABSORBENT ABSORBATE
  • 6.
    ADSORPTION - Vs- ABSORPTION
  • 7.
    ADSORPTION ABSORPTION  PHENOMENON Itis a surface phenomenon  HEAT EXCHANGE It is exothermic reaction  TEMPRATURE It is favored by low temp.  RATE OF REACTION It is steadily increases and reaches equilibrium  CONCENTRATION Concentration on the surface of adsorbent is different from that in bulk  PHENOMENON It is a bulk phenomenon  HEAT EXCHANGE It is Endothermic reaction  TEMPRATURE It is generally not affected by temp.  RATE OF REACTION It occurs at uniform rate  CONCENTRATION It is same throughout the material
  • 8.
    ADSORPTION ABSORPTION  PROCESS Itis sorption process. The process is sill unclear. Adsorption is generally classified into physisorption (weak Vander wall forces ) and chemisorption ( covalent bond).It can also be caused by electrostatic attraction . The molecules are held on the surface of the adsorbent and can be removed.  PROCESS It is sorption process occurs when atoms passes through or enter bulky material . During it molecules are entirely dissolved or diffused in the absorbent to form a solution . Once the molecules are absorbed ,it become difficult to separate it from absorbent
  • 9.
  • 10.
    TYPES OF ADSORPTION PHYSICAL ADSORPTION CHEMICAL ADSORPTION TYPESOF ABSORPTION PHYSICAL ABSORPTION CHEMICAL ABSORPTION
  • 11.
    PHYSICAL ADSORPTION CHEMICAL ADSORPTION Caused byintermolecular forces Caused by chemical bond formation Heat of adsorption is small Heat of adsorption is large Decrease with increase in temperature Increase with pressure increase Forms multimolecular layer Increase with increase in temperature Change of pressure has no effect Forms unimolecular layer
  • 13.
    CHEMICAL PHYSICAL ABSORPTION ABSORPTION Chemical absorption is a chemical reaction between absorbed and the absorbing substance  Physical absorption is in which the absorbent and absorbate develops weak Vander wall force and it can be reversible
  • 15.
  • 16.
    USES OF ADSORPTION InTREATMENT of DIARRHEA In GAS MASK in adsorbing ABNOXIOUS GASES In CLARIFICATION of SUGAR In PAINT INDUSTRY In adsorption of EXCESSIVE GAS in the GASTROINTESTINAL TRACT and BACTERIAL TOXIN
  • 17.
  • 18.
    USES OF ABSORPTION Usedin ABSORPTION CHILLERS for SPACE COOLING APPLICATION Use in CLEAN BURNING of FUELS The process of gas absorption by a liquid is used in HYDROGENATION OF OILS Used in CARBONATION