WATER-BASED
PA1NT FORMULATIONS
Volume 4
by
Ernest W. Flick
NOYES PUBLICATIONS
Inp IWesWood, New Jersey, U.S.A.
Copyright 8 1997 by Ernest W. Flick
No patt of this book may be reproduced or utilized in
any fonn or by any means, electronic or mechanical
including photocopying, recording 01 by any informa-
tion stonge and retrieval system, without permission
in Writing from the Publisher.
Library of Congress Catalog Card Number: 75-2939
Printed in the United States
ISBN 0-8155-1415-8
Published in the United States of America by
Noyes Publications
369 Fairview Avenue
Westwood, New Jersey 07675
10 9 8 7 6 5 4 3 2 1
Library of Congress Cataloging-in-Publications Data
(Revised for vol. 4)
Flick, Ernest W.
Water-based paint formulations.
Vol. 4 published by Noyes Publications.
Includes index.
1. Paint--Patents. II. Title.
TP935.F62 1975 66T.63 75-2939
ISBN 0-8155-0571-X (v. 1)
ISBN 0-8155-1345-3 (v. 3)
ISBN 0-8155-1415-8 (v. 4)
In Memory
of
My Mother and Father
This collection of 232up-to-date water-based trade and industrial formulations
will be of value to technical and managerial personnel in paint manufacturing
companies and firms which supply raw materials or services to these
companies, and to those interested in less hazardous, environmentally safer
formulations. The book will be useful to both those with extensive experience
as well as those new to the field. This book includes new and different
formulations than those included in the previously published Industrial Water-
Based Paint Formulations and Water-Based Paint Formulations.
The data consist of selections of manufacturers' suggested formulations made at
no cost to, nor influence from, the makers or distributors of these materials.
The information given is presented as supplied; the manufacturer should be
contacted if there are any questions. Only the most recent data supplied us has
been included. Any solvent contained is minimal.
The table of contents is organized in such a way as to serve as a subject index.
The formulations described are divided into sections which cover exterior,
interior, and exterior and/or interior water-based paints, enamels, and coatings,
as indicated below:
I. Coatings and Topcoats
11. Coil Coatings
111. Enamels
IV. Enamels-Baking
V. Exterior Paints and Related Products
VI. Interior Paints and Related Products
VII. Lacquers
VIII. Primers
IX. Sealants and Related Compounds
X. Stains
XI. Miscellaneous
Each formula has been placed in the chapter which is most applicable. The
reader, if seeking a formula for a specific end use, should check each chapter
which could possibly apply.
vii
...
viii Preface
In addition to the above, there are two other sections which will be helpful to
the reader:
XI. A chemical trade name section where trade-named raw materials
are listed with a chemical description and the supplier's name. The
specifications which the raw materials meet are included if
applicable.
XIII. Main office addresses of the suppliers of trade-named raw materials
and/or formulations.
Included in the descriptive information for each formulations, where available,
the following properties may be listed: viscosity, solids, content, %
nonvolatiles, pigment volume concentration, density, pH, spatter, leveling, sag
resistance, scrub stability, freeze-thaw stability, ease of application, gloss
foaming, cratering, brightness, opacity, water spotting, adhesion to chalk, brush
clean-up, reflectance, and sheen.
Ernest W. Flick
Notice
To the best of our knowledge the information in this publications is
accurate; however, the Publisher does not assume any responsibility or
liability for the accuracy or completeness of, or consequence arising from,
such information. These formulations do not purport to contain detailed
manufacturing nor user instruction, and by its range and scope could not
possibly do so. Mention of trade names or commercial products does not
constitute endorsement or recommendation for use by the Author or
Publisher.
Water-based paint raw materials could be toxic, and therefore, due caution
should always be exercised in the use of these hazardous materials. Final
determination of the suitability of any information or product for use
contemplated by any user, and the manner of that use, is the sole
responsibility of the user. We strongly recommend that users seek and
adhere to a manufacturer's or supplier's current instructions for handling
each material they use.
The Author and Publisher have used their best efforts to include only the
most recent data available. The reader is cautioned to consult the supplier
in case of questions regarding current availability.
SECTION I: COATINGS AND TOPCOATS .................... 1
Clearcoat Modification ............................... 2
825/Rhoplex CL-104) ................................ 3
Ancamine 2410 High Solids Coating ........................ 4
2410/Ancamide 500 High Solids Coating . . . . . . . . . . . . . . . . . . 5
Cured with HMMM ................................. 6
Phenolic Clear Bake Coating .............................. 8
Clear Bake Coating ..................................... 9
Phenolic Clear Bake Coating .............................. 9
Clear Wood Coating-A & B & C K-Flex UD-320W Modified .... 10
Direct to Metal Acrylic Latex Coating Starting Point
Formulation ...................................... 11
Low Gloss VinyVABS Topcoat ........................... 12
Clear Topcoat for Flexible Substrates ....................... 12
. . . . . . . . . . 13
Lower Adhesion ................................... 13
Polyphobe Rheology Modifiers Formula C Good Leveling . . . . . 14
................................. 14
Acrylic EmulsiodUrea-Formaldehyde Wood
Aliphatic Wood Coating Formulation (Sancure
Exhibit 4 .Starting Formulation Ancamine
Black Single Coat K-Flex XM-4316 PU Dispersion
Clear Bake Coating ..................................... 7
Strippable Coating Sample Formulation A Unmodified
Strippable Coating Sample Formulation B
Strippable Coating Formulations Thickened with Ucar
Formula D High Build
Strippable Coating for Plastic Substrates ..................... 15
Strippable Coating Formulations .......................... 16
Topcoat for Prefinished Hardboard Siding .................... 17
Water-Borne Alkyd/Melamine Wood Clearcoat Modification . . . . . . 18
Waterborne Clear High Gloss Topcoat ...................... 20
White Gloss Maintenance Topcoat ......................... 21
White Gloss Topcoat . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
Wood Topcoat Model Formulations ........................ 23
ix
x Contents and Subject Index
SECTION 11: COIL COATINGS ............................ 24
Chromate Coil-Coating Primer ........................... 25
Low-Sheen Coil-Coating Topcoat ......................... 26
Medium-Gloss Coil-Coating Topcoat ...................... 27
Strippable Coil Coating ................................. 28
SECTION LII: ENAMELS ................................. 29
Acrylic Emulsion Enamel-B&C K-Flex UD-320W Modified . . . . . 30
Synergistic Effects of Combining Nacorr with Anti-
Corrosive Pigment in an Air Dry Water Reducible
Alkyd Modified Acrylic Enamel ....................... 31
Ancamide 2353 Fast Drying White Gloss Enamel . . . . . . . . . . . . . . 32
Ancamide 2353 Low VOC White Gloss Enamel . . . . . . . . . . . . . . . 33
Cary Gloss White Enamel ............................... 34
Clear Enamel (For Maximum Solvent and Abrasion
Resistance) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
Gloss Safety Red Enamel ............................... 37
Gloss Safety Yellow Enamel ............................. 38
Gloss White Enamel ................................... 39
Gloss White Enamel (Maximum Solvent and Abrasion
Resistance) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41
Green Air Dry Enamel for Flexible Substrates . . . . . . . . . . . . . . . . . 42
High-Hiding Eggshell Enamel ............................ 43
MacGregor Gloss Black Enamel .......................... 44
Pinehurst Gloss Green Enamel ............................ 45
Self-Priming Interior Semi-Gloss Enamel . . . . . . . . . . . . . . . . . . . 46
Exterior Maintenance-Type Coating ........................ 46
Semigloss Enamel ..................................... 47
Southern Pines Gloss White Enamel ........................ 49
Spensol I54 Orange Enamel ............................. 50
Waterborne Black Enamel Based on Epotuf 37-143/37-680
(Formula No. 3019-28A) ............................ 51
Waterborne Blue Enamel Based on Epotuf 37-143/37-680
(Formula No.3019-316) ............................ 52
Waterborne Dark Blue Enamel Based on Epotuf
37-143/37-680 (Formula No.3019-31D) . . . . . . . . . . . . . . . . . 53
Waterborne Green Enamel Based on Epotuf 37-143/37-680
(Formula No. 3019-3lF) ............................. 54
Waterborne Orange Enamel Based on Epotuf 37-143/37-680
(Formula 3019-310 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55
Waterborne Red Enamel Based on Epotuf 37-143/37-680
(Formula No. 3019-31B) ............................ 56
Waterborne Red Orange Enamel Based on Epotuf
37-143/37-680 (Formula No. 3019-31E) . . . . . . . . . . . . . . . . . 57
Contents and Subject Index xi
Waterborne Yellow Epoxy Enamel Based on Epotuf
37-143/37-680 (Formula No.3019-31C) . . . . . . . . . . . . . . . . . 58
Whispering Pines Semigloss White Enamel . . . . . . . . . . . . . . . . . . . 59
Anquamine 401 1:l White Gloss Enamel .................... 60
Gloss Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61
Anquamine 401/Solid Resin Dispersion 2:l White
SECTION IV: ENAMELS-BAKING ........................ 62
Clear Bake Coating .................................... 63
Phenolic Clear Bake Coating ............................. 63
Clear High Gloss. Baking Finish .......................... 64
Blue Metallic Urethane Enamel ........................... 64
Experimental Water-Reducible Polyester Gloss White
Baking Enamel Using Halox SZP-391 . . . . . . . . . . . . . . . . . . . 65
Waterborne Acrylic Bake Enamel
Water Reducible Polyester Baking Enamel
Spensol L54 White Baking Enamel
2-Component Waterborne System ......................... 69
......................... 66
. . . . . . . . . . . . . . . . . . . 67
........................ 68
SECTION V: EXTERIOR PAINTS AND RELATED PRODUCTS . . . 70
Exterior Flat House Paint with ZnO ........................ 71
Exterior Gloss White . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73
Exterior House Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74
Exterior House Paint .Tint Base .......................... 75
Exterior Semigloss Formulation ........................... 77
Exterior Tint Base Formulation ........................... 78
Exterior Trim Formulation Modified Vinyl Acrylic Paint . . . . . . . . . 79
Exterior Trim Formulation ............................... 80
Exterior White Flat House Paint ........................... 82
Exterior White Trim house Paint .......................... 83
Good Quality White Exterior Flat Paint for Masonry . . . . . . . . . . . . 84
Good Quality White Exterior Flat Paint for Wood . . . . . . . . . . . . . . 85
Gregson Drive Gloss White .............................. 86
High Quality Exterior Semi Gloss Paint ..................... 87
High Sheen White House Paint ........................... 88
Low VOC Exterior House Paint ........................... 89
Quality Exterior Flat Formulation .......................... 90
Quality Exterior Flat Paint ............................... 91
Quality White Exterior Trim Paint ......................... 92
Quality White House Paint with ZnO ....................... 94
Urethane Fortified Porch & Deck Enamel .................... 95
Weather Barrier Formulation ............................. 96
White Exterior Flat House Paint with Zinc Oxide . . . . . . . . . . . . . . 97
Exterior Semigloss .................................... 76
xii Contents and Subject Index
White Roof Coating ................................... 99
SECI'ION VI: INTERIOR PAINTS AND RELATED PRODUCTS . 100
Clear High Gloss Varnish .............................. 101
Fast-Dry Sealer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101
Economy Flat Wall Paint .............................. 102
Good Quality Interior Flat with <50g/L VOC . . . . . . . . . . . . . . . . 104
High Quality Super Flat Interior Paint ..................... 105
Interior Clear Wood Finish (Rhoplex CL-l04/Sancure 815) . . . . . . 106
Interior Sanding Sealer (Rhoplex CL-105) . . . . . . . . . . . . . . . . . . 106
Interior Contractor Flat ................................ 107
Interior Good Quality Flat for Roller and Brush
Application ..................................... 108
Interior Good Quality Flat .............................. 110
Interior Semigloss Formulation .......................... 111
Interior Vinyl Acrylic Eggshell for Roller and
Brush Application ................................. 112
Interior Vinyl Acrylic Semigloss ......................... 114
Intumescent Interior White Fire-Retardant Paint . . . . . . . . . . . . . . 115
Low VOC Interior Flat ................................ 116
Solvent Free Interior Satin Paint ......................... 117
White Interior Eggshell ................................ 118
SECTION VII: LACQUERS .............................. 119
Green Lacquer ...................................... 120
DIY Waterborne Lacquer ........................... 121
White Lacquer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 122
Foam Control with Agitan Additives in a High Gloss
SECI'ION VIII: PRIMERS ............................... 124
Acrylic Latex Tannin Block Primer Using Halox BW-100 . . . . . . 125
Alkyd Modified Latex Primer ........................... 126
Ancamide 2353 Curing Agent Anti-Corrosive Primer . . . . . . . . . . 127
Anquamine 401/Semi-solid Epoxy Dispersion Lead
and Chromate Free Red Iron Oxide Primer 128
Anquamine 401/Solid Resin Dispersion Lead and
Chromate Free Red Iron Oxide Primer . . . . . . . . . . . . . . . . . . 129
Corrosion Inhibitive Primer ............................. 130
Metal Wash Primer ................................... 130
Cost Effective 2K Water-Base Epoxy Primer Using
Halox SW-111 ................................... 131
Dipping Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 132
Experimental General Purpose Tannin-Stain Resistant
Water-Base Primer Using Halox Xtain A . . . . . . . . . . . . . . . . 133
. . . . . . . . . . . . . . .
Contents and Subject Index xiii
Experimental High Performance Tannin-Stain Resistant
Water-Base Primer Using Halox Xtain A . . . . . . . . . . . . . . . .
Experimental Waterbase Acrylic Red Iron Oxide Primer . . . . . . . . 135
Exterior House Paint Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . 138
Exterior House Paint Primer Based on Ucar Latex 163 . . . . . . . . . 139
General Purpose Latex Maintenance Primer . . . . . . . . . . . . . . . . . 140
General Purpose/Low Cost Water-Base Primer . . . . . . . . . . . . . . . 141
High Performance Bare Metal Primer ...................... 142
High Performance Galvanized Metal Primer . . . . . . . . . . . . . . . . . 143
High Performance 2K Water-Base Epoxy Primer 144
Halox SZP-391 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 145
High Solids Red Iron Oxide Epoxy Primer . . . . . . . . . . . . . . . . . . 147
House Paint Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 148
Lead and Chromate Free Primer .......................... 149
Lead and Chromate Free Red Iron Oxide Primer . . . . . . . . . . . . . . 150
Lead and Chromate Free Waterborne Epoxy Primer . . . . . . . . . . . 151
Lead Based Primer ................................... 152
Lead Silico Chromate Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153
Low Sheen Gray Primer ............................... 154
Non-Lead/Non-Chromate Primer ........................ 155
134
. . . . . . . . . . . . .
High Performance 2K Water-Base Epoxy Primer Using
Primer for Factory-Primer Hardboard Siding . . . . . . . . . . . . . . . . 156
Primer 20323D Based on Phosguard J-0853 and 10 ES
Wollastocoat Henkel's Waterpoxy 1401:701 System . . . . . . . . 157
Primer 203236 Based on Phosguard J-0813 and 10 ES
Wollastocoat Henkel's Waterpoxy 1401:701 System . . . . . . . . 158
Primer 20596F Based on Heucophos ZPZ and 10 ES
Wollastocoat Henkel's Waterpoxy 1401:701 System . . . . . . . . 159
Primer 20596G Based on Heucophos ZMP and 10 ES
Wollastocoat Henkel's Waterpoxy 1401:701 System . . . . . . . . 160
Primer 21102E Based on Molycoat 212 and 10 AS
Wollastocoat Henkel's Waterpoxy 1401:701 System . . . . . . . . 161
Primer 21105H Based on Phosguard J-0815 and 10 ES
Wollastocoat Henkel's Waterpoxy 1401:702 System . . . . . . . . 162
Primer 211051 Based on Nalzin 2 and 10 ES
Wollastocoat Henkel's Waterpoxy 1401:702 System . . . . . . . . 163
Primer 21109C Based on Strontium Chromate and 10 ES
Wollastocoat Henkel's Waterpoxy 1401:702 System . . . . . . . . 164
Rapid Dry Waterborne Epoxy Primer ...................... 165
Red Inhibitive Maintenance Primer ....................... 167
Red Iron Oxide Corrosion Resistant Epoxy Primer (Two
Component System) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 168
Red Iron Oxide Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 169
Red Iron Oxide Water Reducible Alkyd Primer . . . . . . . . . . . . . . . 171
xiv Contents and Subject Index
Rust Inhibitive Chromate Primer ......................... 172
Solvent Resistant. Water-Reducible Epoxy Primer . . . . . . . . . . . . 173
lT-P-1975 Federal Specification Metal Primer . . . . . . . . . . . . . . 174
Universal Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 175
Universal Primer Non-Lifting and High Salt Spray Resistance . . . . 176
Water-Base Acrylic Universal Primer Using Halox
Water-Base Acrylic Universal Primer Using Halox
SZP-391 & Xtain A ............................... 178
Waterborne Black Iron Oxide Primer Based on
Epotuf 37-143/37-680 (Formula No.3019-38A) . . . . . . . . . . 179
Waterborne Red Iron Oxide Primer Based on
Epotuf 37-143/37-680 (Formula No.2954-76A) . . . . . . . . . . 180
Waterborne Red Oxide Epoxy Primer ...................... 181
Waterborne Yellow Iron Oxide Primer Based on
Epotuf 37-143/37-680 (Formula No. 3019-39B) . . . . . . . . . . 182
Water Reducible Alkyd Yellow Iron Oxide Primer
Using Halox SZP-391 ............................. 183
Water Reducible Alkyd Yellow Iron Oxide Primer
Using Halox CW-491 .............................. 184
Water Reducible Epoxy-Ester Red Iron Oxide Primer . . . . . . . . . . 185
Water Reducible Epoxy-Ester Red Iron Oxide Primer
Using Halox CW-491 .............................. 187
White. Corrosion Resistant Latex Primer . . . . . . . . . . . . . . . . . . . 188
White Inhibitive Maintenance Primer ...................... 189
SZP-391 & BW-100 .............................. 177
SECTION IX:SEALANTS AND RELATED COMPOUNDS . . . . . . 190
Ancamide 2353 Curing Agent Aluminum Mastic . . . . . . . . . . . . . . 191
Clear Sealant ....................................... 192
High-Quality Exterior Latex Caulk ....................... 193
Patching Compound (Brushing Grade) ..................... 194
Patching Compound (Trowel Grade) ....................... 195
Pigmented Caulk Formulation based on 2:l Vinyl
AcrylidAcrylic Blend .............................. 196
Premium.Performance. Medium-Flexibility Caulk . . . . . . . . . . . . 197
Sealant Application ................................... 198
Translucent Caulk Formulation .......................... 199
ASTM C-920 Pigmented Caulk Formulation . . . . . . . . . . . . . . . . 200
Translucent Sealant ................................... 201
Vinyl Acrylic Sealant . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 202
Weather-Barrier Mastic ............................... 203
SECTION X: STAINS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 205
Brown Wiping Stain .................................. 206
Contents and Subject Index xv
Interior Wiping Stain (Emulsion E-2977) . . . . . . . . . . . . . . . . . . . 207
Light Redwood Wiping Stain ............................ 208
Stain Concentrate .................................... 209
Tannin Stain Blocking Formulation ....................... 210
Acrylic Tannin Stain-Blocking Primer ..................... 210
Water Reducible Redwood Solid Color Stain . . . . . . . . . . . . . . . . 211
Stain . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 207
SECI'ION XI: MISCELLANEOUS ......................... 212
Anquamine 401 Clear Coat Semi-Solid Epoxy Dispersion . . . . . . . 213
Anquamine 401 Clear Coat Solid Epoxy Dispersion . . . . . . . . . . . 214
Anquamine 401 Liquid Epoxy Clear Coat . . . . . . . . . . . . . . . . . . . 214
Aqueous Polyester-Urethane Pigment Dispersion . . . . . . . . . . . . . 215
Black Gloss Enamel .................................. 216
Clear Barriernie Coat for Vinyl ......................... 216
Clear Tint Base ..................................... 217
Clear Waterborne Cement Sealer ...................... 218
Waterborne Black Topcoat ............................. 218
Exterior/Interior Block Filler ............................ 219
High Solids Self Priming Alkyd .......................... 220
Masonry Block Fill . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 221
Masonry Blockfill .................................... 222
Water Reducible Alkyd ................................ 223
2-Component Waterborne System ........................ 224
FCA's for Waterborne Building Product Formulations
SECTION XII: TRADE NAMED RAW M A T E W S . . . . . . . . . . . 225
SECTION XIII: SUPPLIERS ADDRESSES . . . . . . . . . . . . . . . . . . 246
2 Water-Based Paint Formulations
A c r y l i c Eaulsion/Urea-Formaldehyde
Wood C l e a r c o a t M o d i f i c a t i o n
K-Flex UD-320W i s an a l i p h a t i c , s a t u r a t e d , water s o l u b l e r e s i n
m o d i f i e r . T h i s urethane d i o l m o d i f y i n g r e s i n i m p a r t s improved
s t a i n r e s i s t a n c e t o t h e f o r c e d d r y (thermoset) wood c l e a r c o a t
formul a t ion b e l ow.
What makes t h i s f o r m u l a t i o n unique, i s t h e absence o f n e u t r a l -
i z i n g amines. As a r e s u l t , a f r e e a c i d c a t a l y s t may be used
(Nacure 155) and lower temperature c u r e s may be achieved. A p o t
l i f e of 24-48 hours i s p o s s i b l e .
WB Wood C l e a r c o a t
Component:
B e e t l e 65
Methanol
S i l w e t t L-77
Rhopl ex AC-1024
Water
Exxate 700
Chemcor AS-35-3
K-Flex UD-320W
Nacure 155
Methanol
M o d i f i c a t i o n :
0%
24.5
2.4
0 . 4
49.2
7.2
1 . 4
4.1
0.0
4.9
5.9
%K-Flex UD-320W
-5% 10%
24.5 24.5
2.4 2 . 4
0 . 4 0 . 4
44.2 39.3
9 . 4 11.5
1.4 1 . 4
4 . 1 4.1
2.8 5.5
4.9 4.9
5.9 5.9
F o r m u l a t i on Procedure:
1. The components were added i n t h e o r d e r as presented, f o r
easi e r in c o r p o r a t i on.
2. The Nacure 155 c a t a l y s t was p r e - d i l u t e d w i t h t h e methanol
below i t i n t h e f o r m u l a t i o n b e f o r e i n c o r p o r a t i o n , w i t h a
Nacure 155/Methanol r a t i o o f 45.5/54.5.
S u b s t r a t e : B i r c h Faced Plywood
S e a l e r : S e l f Sealed ( 2 Coats, 2 bakes)
Sealer/Topcoat, WFT: 20-25u (0.8-1.0 m i l ) / C o a t
Sealer/Topcoat Bake: 10 min./71C (160F)
4 Hour Spot T e s t
S t a i n T e s t : 0% UD-320W 10% UD-320W
Acrylic/UD-320W/B-65 50/0/50 40/10/50
C o f f e e Severe Haze L i g h t S t a i n
M i l k Severe Haze No E f f e c t
Mustard
Water
Lemon J u i c e
No E f f e c t L i g h t S t a i n
Severe Haze No E f f e c t
S l i g h t Haze No E f f e c t
No e f f e c t was seen i n t h e 4 hour s p o t t e s t i n any o f t h e
f o r m u l a t i o n s w i t h ketchup, n a i l p o l i s h remover, i s o p r o p a n o l ,
l i q u i d c l e a n e r o r l i p s t i c k .
160F r e s u l t e d i n an H p e n c i l hardness and 100+ MEK double rubs.
SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n WR-26
Drawdowns made o v e r Aluminum p a n e l s and baked 10 minutes a t
Coatingsand Topcoats 3
A l i p h a t i c Wood Coatinn Formulation
JSancure 825/Rho~lexCL-104)
61end :
Rhoplex CL-104 (38% S o l i d s )
Water
Add f o l l o w i n g w i t h good a g i t a t i o n :
Dowanol DPM
Hexyl C a r b i t o l
Mix 10-15 minutes
Sancure 825 (34% S o l i d s )
Surfactant Package (Premix t h e f o l l o w i n g ) :
Surfynol 104H
Surfynol DF-l1OL
Mineral S p i r i t s
Surfynol DF-70
DC-14
Add and mix 30 minutes
Pounds
134.2
33.8
12.75
2.55
100.0
2.6
1 . 3
1.3
1.3
0.7
Adjust t o desired v i s c o s i t y using Acrysol RM825 (Rohm & Haas Co.)
I f required, f l o w i s enhanced by a d d i t i o n o f very low l e v e l s o f
Fluorad FC-129 (3M Corp.) as a 10% s o l u t i o n i n water.
NOTE: Avoid excessive use o f fluorocarbons, as sharp surface
tension drops can cause recoat problems and strong foaming
tendencies.
Always a d j u s t t o desired v i s c o s i t y range p r i o r t o evaluating
f l o w / l e v e l and deaeration p r o p e r t i e s . Low v i s c o s i t y can
y i e l d “Picture-Framing‘‘ and/or a “ F i sh-Eye“ e f f e c t . High
v i s c o s i t y can y i e l d poor deaeration p r o p e r t i es.
Surfynol a d d i t i v e s have been shown t o provide t h e f o l l o w i n g
benef it s :
*Color u n i f o r m i t y o f s t a i n s
*Early s t a i n 1appi ng resistance
*Consistent wetting, f l o w and l e v e l i n g on various woods
*Foam c o n t r o l
With no detrimental e f f e c t upon:
*Topcoat r e c o a t a b i l i t y and i n t e r c o a t adhesion
*Gloss r e t e n t i o n upon aging
*Tannin bleed r e s i stance
*Water s e n s i t i v i t y
*Chemical resistance
SOURCE: A i r Products & Chemicals, I n c . : Surfynol Surfactants:
Formulation A (B.F. Goodrich)
4 Water-Based Paint Formulations
Ancamine 2410 H i g h S o l i d s C o a t i n g
A S i d e :
DER 331
TS 610
50% FC430 i n Xylene
Disperse, t h e n reduce speed
S t a i n l e s s s t e e l f l a k e
BYK 320
Aromatic 100
B S i d e :
Ancami ne 2410
E t h y l A l c o h o l
D i s s o l v e , t h e n add:
C a b o s i l TS 720
W o l l a s t o c o a t 10ES
D i s p e r s e t o 6 n . s . u .
Methyl E t h y l Ketone
T y p i c a l P r o p e r t i e s :
Non V o l a t i l e by Weight: 0.75
Non V o l a t i l e by Volume: 0 . 6 0
PVC: 0 . 1 6
CPVC: 0 . 3 4
PVC/CPVC: 0 . 4 8
P i gment Content: 0.30
NVV on V e h i c l e : 0 . 6 4
VOC g/1: 3 2 7 . 9
VOC l b s / g a l : 2 . 7 4
&
330.9
7
3.5
176
79
7 . 1
1 5 0 . 5
37.7
8.8
133.3
152.3
Wei ght/Gal l o n Comp A :
Weight/Gallon Comp 0 :
M i x i n q R a t i o : 1 : l
Gals
34.1
0 . 4
0 . 4
3 . 2
1
1 0 . 9
1 5 . 5
5.8
0 . 5
5 . 5
22.7
1 2 . 0 6
9 . 6 5
Weight p e r G a l l o n : 1 0 . 8 5
I n i t i a l V i s c o s i t y : 580 cP
Pot L i f e : 4 . 5 h r
Dry t o Touch: 0.75 h r
Dry Hard: 4 h r
Ancamine 2410 Chemical Resistance: 7 Day Immersion R e s u l t s :
Reagent :
Acetone
Cyclohexanone
PM A c e t a t e
E t h y l A c e t a t e
Ethanol
Isodecanol
Aromatic 100
To1uene
DMF
THF
EP
R e s u l t :
No E f f e c t
No E f f e c t
No E f f e c t
No E f f e c t
No E f f e c t
No E f f e c t
No E f f e c t
No E f f e c t
No E f f e c t
No E f f e c t
No E f f e c t
Reagent:
NMP
C1o r o x
Skydro1
50% c a u s t i c
10% c a u s t i c
6% HC1 :
S u l f u r i c :
A c e t i c A c i d
D i e t h y l ami ne
50% phenol i n x y l e n
R e s u l t :
No E f f e c t
No E f f e c t
No E f f e c t
No E f f e c t
No E f f e c t
No E f f e c t
81is t e r e d
81 is t e r e d
B l i s t e r e d 0 1
i e D 0 4
SOURCE: A i r Products and Chemicals, I n c . : Ancamine 2410 C u r i n g
Agent: E x h i b i t 3 F o r m u l a t i o n
Coatings and Topcoats 5
E x h i b i t 4 - S t a r t i n g Formul-ation
Ancarni ne 241O/Ancami de 500 High. Sol i d s C o a t i n g
A S i d e :
DER 331
C a b o s i l TS-610
Lbs Gals
284.6 29.3
7.6 0.43
D i s p e r s e a t H i g h Speed
Reduce Speed, t h e n add:
A1 umi num L243 106 8.59
When u n i f o r m l y mixed, add:
E p o d i l 759
SF 69
B S i d e :
Ancami ne 2410
B e e t l e 216-8
Ancamide 500
E t h y l A l c o h o l
M e t h y l E t h y l Ketone
n B u t y l A l c o h o l
E t h y l A l c o h o l
T y p i c a l P r o p e r t i e s :
Non V o l a t i l e by Weight: 0.72
Non V o l a t i l e by Volume: 0.64
PVC: 0.056
CPVC: 0.31
PVC/CPVC: 0.17
Pigment Content: 0.09
NVV on V e h i c l e : 0.7
VOC g / l : 290.53
VOC l b s / g a l : 2.43
86.3 11.64
0.3 0.04
77.67 8.00
22.7 2.60
81.8 10.34
29.1 4.44
73.9 11.01
81.7 12.10
9.8 1.49
Weight/Gallon Comp A : 9.68
W e i g h t / G a l l o n Comp 0: 7.53
M i x i n g R a t i o : 1:l
Weight p e r G a l l o n : 8.61
I n i t i a l V i s c o s i t y : 270 CP
Pot L i f e : 3 h r
Dry t o Touch: 1.5 h r
Dry Hard: 4 h r
C o r r o s i o n Resi stance :
E x h i b i t 4 i s a p r e l im i n a r y s t a r t i n g f o r m u l a t i o n combi n i ng
Ancamine 2410 c u r i n g agent w i t h Ancamide 500 c u r i n g agent as t h e
B s i d e . C o r r o s i o n r e s i s t a n c e i s v e r y good. C l e v e l a n d h u m i d i t y
t e s t i n g showed no a t t a c k a f t e r 700 h o u r s . S a l t s p r a y r e s u l t s
on g r i t b l a s t e d s t e e l showed no a t t a c k i n t h e f i e l d and minor
a t t a c k a t t h e s c r i b e (8 r a t i n g ) a f t e r 700 h o u r s .
SOURCE: A i r P r o d u c t s and Chemicals, I n c . : Ancamine 2410
C u r i n g Agent: E x h i b i t 4
6 Water-Eased Paint Formulations
B l a c k S i n g l e Coat K-Flex-XM-4316 P U - D ~ s p e r s l o nCured w i t h HMMM
F o r m u l a t i o n WR-40 i s a h i g h performance h i g h g l o s s b l a c k
f o r m u l a t i o n based on K-Flex XM-4316 p o l y e s t e r - u r e t h a n e d i s p e r s i o n
c r o s s l i n k e d w i t h an amino r e s i n . The f o r m u l a t i o n o f f e r s a h i g h
g l o s s c o a t ing
Component:
Pigment G r i n d Paste, P a r t 1 :
K-F1 ex XM-2311
Water, d e i o n i z e d
Dimethylethanolamine ( 1 )
Monarch 1300
K-Sperse 152 MS
Dimethylethanolamine ( 2 )
Pigment Paste, P a r t 2 :
K-Flex XM-2311
K-F1 ex XM-4316
Water, d e i o n i z e d
Pigment Paste
K-F1 ex XM-4316
Water d e i o n i zed
Resimene 747
Nacure 2547
S i l w e t L7604/L7605 ( 1 : l ) 25% i n H20
Water as r e q u i r e d f o r v i s c o s i t y adjustment
F o r m u l a t i o n C h a r a c t e r i s t i c s :
Resi n/HMMM, r a t 10 : 75/25
N o n v o l a t i l e , c a l c u l a t e d , 'YO: 39.0
T h e o r e t i c a l VOC, g/L, ( l b / g a l l o n ) : 145, ( 1 .23)
B r o o k f i e l d V i s c o s i t y , 25C, s p i n d l e #16, 60 rpm, c p . :
Cure Schedule, temperature, t i m e : 150C, 15 m i n u t e s
Dry F i l m Thickness, m i l , ( m i c r o n ) : 1 . 0 ( 2 5 )
Gloss, 60, 20, 90: 91, 81
pH: 7 . 8 - 8 . 3
F i l m P r o p e r t i e s : S u b s t r a t e , aluminum
% W t
2 . 4 0
2.95
0.15
1 .oo
0.07
0 . 1 0
1.20
1 . 2 0
1 . 1 0
10.17
63.95
6 . 2 0
9 . 5 5
0 . 1 3
0.40
9 . 6 0
300-500
F o r m u l a t i o n Notes:
Pigment G r i n d Paste P a r t 1 : B l e n d t h e K-Flex XM-2311 p o l y u r e t h a n e
d i s p e r s a n t r e s i n w i t h water and d i m e t h y l e t h a n o l a m i n e ( 1 ) and add
t h e carbon b l a c k , premix and add t h e b l e n d o f K-Sperse w i t h
d i m e t h y l e t h a n o l a m i n e ( 2 ) , check t h e pH and add more d i m e t h y l e t h a -
nolamine i f pH i s below 9.2, d i s p e r s e i n a s t e e l b a l l m i l l t o
Hegman NS 8 r a t i n g .
Pigment Paste P a r t 2 : A f t e r g r i n d i n g i n t h e s t e e l b a l l m i l l add
t h e a d d i t i o n a l K-Flex XM-2311, XM-4316 and w a t e r t o t h e b a l l
m i l l , r u n f o r an a d d i t i o n a l 30 m i n u t e s . The pigment c o n c e n t r a t e
i s s t a b l e . A f t e r l o n g e r a g i n g a d d i t i o n o f s m a l l amounts o f amine
f o r pH adjustment m i g h t be r e q u i r e d .
Letdown Formula: L e t t h e pigment p a s t e down under a g i t a t i o n
w i t h remainder o f K-Flex XM-4316, w a t e r , melamine c r o s s l i n k e r
and c a t a l y s t . Add t h e s i l i c o n e s u r f a c t a n t and use t h e remainder
o f t h e w a t e r f o r v i s c o s i t y a d j u s t m e n t s . F i n a l pH o f t h e f o r m u l a -
t i o n s h o u l d be between 7.8 t o 8 . 3 .
SOURCE: K i n g I n d u s t r i e s : P r e l i m i n a r y F o r m u l a t i o n WR-40
Coatings and Topcoats 7
Clear Bake Coating
Materi a1 :
E p i -Re2 3522-W-60 Resin
~ _ _ _Pounds Gal 1ons
637.50 69.29
Thoroughly pre-nix t h e f o l l o w i n g and add t o t h e above under
g e n t l e a g i t a t i o n .
Cyme1 324
B u t y l O x i t o l Glycol Ether
2-Propoxyethanol
BYK-301 A n t i - c r a t e r i n g agent
Syntex 3981 Accelerator
53.10 5.71
22.50 3.00
40.20 5.00
2.00 0.25
2.75 0.37
Blend thoroughly. Dissolve f o l l o w i n g by warming t o 150F.
Add t o above under a g i t a t i o n before a l l o w i n g t o cool.
O i cyandi ami de
Dei oni zed water
Typical Coati ng Properties :
% N o n - v o l a t i l e - weight: 48.5
- volume: 43.2
V i s c o s i t y : 57 K.U.
pH: 7.0
Pounds/Gallon: 9.05
V o l a t i l e Composition:
Water
Organics
V o l a t i l e Organic Compounds (VOC):
Pounds/Gallon: 1.46
Grams/Li t e r : 175
13.50 0.41
133.00 15.97
_ _ _ _ _ _Pounds Gallons
388.0 46.50
62.7 8.00
F i l m Properties:*
Bake Schedule: Pencil Hardness Reverse Impact, i n . - l b s .
160
160
160
160
5 min. a t 450F 4H
30 min. a t 400F 5H
15 min. a t 400F 5H
30 min. a t 350F 4H
* Films cast #42 Myra Bar (0.75 m
f l a s h .
SOURCE: She11 Chemical Co. : S t a r t
E p i -Rez 3522-W-60 Resin
1 . ) on bonderite 1000; 10 min.
ng Formulation No. 2500:
8 Water-Based Paint Formulations
Clear Bake Coatinq
Materia1 : Pounds
Epi -Rez 3551-WY-43 Resi n 756.0
Add under a g i t a t i o n :
Ektapro EEP
Beetle 80
Water
Typical Coating Properties:
Total Weight Solids, %: 47.5
Total Volume Solids, %: 41.8
Pounds/Gallon: 8.96
Epoxy/Urea, based on s o l i d s
V o l a t i l e Organic Compounds
Pounds/Gal l o n : 1 .85
Grams/Li t e r : 222
V i s c o s i t y , B r o o k f i e l d #5 Sp
Dry F i l m Thickness: 1.0 m i l
Substrate: Bonderite 1000
Typical F i l m Properties:
21.2
86.8
31.5
%: 80/20
VOC) :
ndle, 20 rpm, cps: 1,400
Gal lons
84.00
2.68
9.54
3.78
Bake Schedule a t 350F, minutes: 20
Pencil Hardness: 3H
Reverse Impact, i n . l b s . : 80
S t a r t i n g Formulation No. 2501: Epi-Rez 3551-WY-43 Resin
Phenolic Clear Bake Coating
Pounds GallonsMateri a1 :
Water 115.5 13.87
Methylon 75108 162.5 16.75
B u t y l O x i t o l Glycol Ether 48.8 6.50
n-Butyl Alcohol 43.9 6.50
Syntex 3981 Accelerator 58.1 7.90
Typical Coating Properties:
~~
Epi-Rez 3540-WY-55 Resin 442.9 48.48
Premix and add slowly under a g i t a t i o n :
Total Weight Solids, %: 46.6
Total Volume Solids, %: 31.0
Pounds/Gallon: 8.72
Epoxy/Phenolic: 60:40
C a t a l y s t , a c t i v e on r e s i n s o l i d s , %: 3.3
V o l a t i l e Organic Compounds (VOC):
Pounds/Gallon: 2.68
Grams/Li t e r : 322
V i s c o s i t y , #4 Ford Cup, seconds: 40-60
pH: 6.4
Reduction f o r Conventional Spray A p p l i c a t i o n : None
Dry F i l m Thickness: 0 . 4 m i l s
Substrate: Bonderite 1000
Bake Schedule: 15 min. a t 450F
Pencil Hardness: 9H
Reverse Impact, i n . l b s . : >I60
MEK Resistance, double rubs: 100
Typical F i l m Properties:
S t a r t i n g Formulation No. 2502: Epi-Rez 3540-WY-55 Resin
SOURCE: Shell Chemical Co.: S t a r t i n g Formulations
Coatingsand Topcoats 9
Clear Bake Coating
Materi a1 :
Epi -Rez 3540-WY-55 Resin
Water
Premix and add:
Beetle Urea Formaldehyde Resin
n-Butyl Alcohol
Syntex 3981 Accelerator
Pounds
579.6
113.7
80.7
43.2
55.9
Gal l o n s
63.42
13.65
8.92
6.40
7.61
Typical Coating Properties:
Total Weight Solids, %: 45.7
Total Volume Solids, %: 42.6
Pounds/Gallon: 8.73
Epoxy/Urea: 80/20
C a t a l y s t , % ( A c t i v e on r e s i n s o l i d s ) : 2
V o l a t i l e Organic Compounds (VOC):
Pounds/Gal 1on: 2.19
Grams/Liter: 263
V i s c o s i t y , #4 Ford Cup, seconds: 60-80
pH: 7.1
S t a r t i n g Formulation No. 2506: Epi-Rez 3540-WY-55 Resin
Phenolic Clear Bake Coating
Materia1 :
Part A:
Epi -Rez 3551-WY-43 Resin
Premix and add under a g i t a t i o n :
Santol ink EP560
Ektapro EEP
Add under a g i t a t i o n :
Water
_ _ _ _ _ _Pounds Gal 1ons
662.1 73.56
93.1 10.18
80.6 10.16
5 0 . 8 6.10
Typical Coati ng P r o p e r t i es :
Total Weight Solids, %: 42.0
Total Volume Solids, %: 36.6
Pounds/Gallon: 8.87
Epoxy/Phenolic, based on s o l i d s , percent: 80/20
V o l a t i l e Organic Compounds (VOC):
Pounds/Gal 1on: 2.90
Grams/Liter: 348
Viscosity, #4 Ford Cup, seconds: 70-80
Dry F i l m Thickness: 0 . 5 m i l
Substrate: Bonderite 1000
Bake Schedule a t 350F. minutes: 20
Pencil Hardness: 5H
Reverse Impact, i n . l b s . : s160
MEK Resistance, Double Rubs: 100
Typi c a l F i 1m Properties :
S t a r t i n g Formulation No. 2505: €pi-Rez 3551-WY-43 Resin
SOURCE: S h e l l Chemical Co. : S t a r t i n g Formulations
10 Water-Based Paint Formulations
C l e a r Wood CoatinQ-A & B 8 C
_-K-F1 ex UD-320W Modi f ie d
The f o l l o w i n g wood c o a t i n g f o r m u l a t i o n e v a l u a t e s K-Flex
UD-320W a t 5 and 10% m o d i f i c a t i o n on s o l i d s . The system was
c a t a l y z e d w i t h K-Cure 129W. Cure response was examined on
c l e a n b a r e and 840 t r e a t e d Aluminum a t a r a p i d schedule o f 60
sec./82C. Hardness improvements were found a t a l l l e v e l s o f
m o d i f i c a t i o n (See f i l m p r o p e r t i e s ) . The t r e a t e d s u b s t r a t e gave
s o f t e r f i l m s i n i t i a l l y compared t o b a r e m e t a l , but improved
p r o p e r t i e s were observed a f t e r 24 h o u r s a g i n g . K-Flex UD-320W
m o d i f i c a t i o n i n c r e a s e d f i l m hardness b u t d i d n o t improve w a t e r
r e s i s t a n c e p r o p e r t i e s
Formul a t i on :
Rhoplex AC-1024
B e e t l e 65
K-Flex UD-320W
K-Cure 129W
A c r y l i c / P o l y o l / U r e a
% S o l i d s
F i l m P r o p e r t i e s :
FC-430
S u b s t r a t e : Aluminum (Clean Bare)
Cure: 60 sec./82C
F i l m Thickness: 0 . 7 + - 0 . 1 m i l DFT
W*
66.7
33.3
0 . 0
0 . 1 3
1 . 7
SO/-/50
6 6 . 7
A : 50,’-/50
I n i t i a l
24 Hours
0 : 45/5/50
I n i t i a l
24 Hours
C : 35/10/55
I n i t i a l
24 Hours
Penci 1 KHN25
HB-F 4.19
F-H 11.20
HB-F 6 . 2 5
H-2H 14.20
HB-F 5.41
H-2H 15.50
W- Wt%C
61 .8 51.4
34.3 40.4
3 . 9 8 . 2
0 . 1 3 0.13
1 . 7 1.8
45/5/50 35/10/55
6 7 . 5 72.2
Crosshatch
Adhesion
MEK Rubs (%Loss)
200 0
200 0
200 0
200 0
180 0
200 0
SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n UDW-10 A & B & C
Coatings and Topcoats 11
I n g r e d i e n t s :
Resin Phase:
Water
Maincote PR-71
Ammonia (28)
D i r e c t t o Metal A c r y l i c Latex Coating
S t a r t i n a P o i n t Formulation
Lbs Gals
45.9 5.510204
2.05 0.273333
481.2 55.31034
Set aside f o r l a t e r a d d i t i o n , i n t o a separate vessel add:
Water Phase:
Water
Bentone AD
Tamol 165
Drewpl us L-493
B u t y l Cel l o s o l v e
D i b u t y l Phthalate
Ammonia (28)
Premix:
Chrom. Grn. Oxide 5-5310
A c t i r o x 215
Nyad 1250
Disperse t o 5 n.s.u. Then
homogenization, add, whi
E t h y l Alcohol
15% NaN02 i n Water
20% QR-708 i n Water
150
1.4
11.2
1
36.6
7.3
n
47.9
89.8
116.3
l e t down w i t h r e s i n phase
e mixing, t h e f o l l o w i n g :
18
3.06
12.75
18.00720
0.064641
1.222707
0.133155
4 .a73501
0.8371 55
0.4
1.078828
3.368847
4.805785
4 f t e r
2.748091
0.337375
1 .514251
General Performance Benef t s :
E x c e l l e n t adhesion t o s t e e l , galvanized s t e e l and aluminum
S u i t a b l e f o r s i n g l e coat s e r v i c e
Excel 1ent recoatabi 1it y w i t h s o l v e n t based f i n i s h e s
High r e s i s t a n c e t o s a l t spray, 3000 hours from 2 d r y m i l s on
Appl icab1e under margi nal c o n d i t i o n s (40F)
c o l d r o l l e d s t e e l
SOURCE: Nyco Minerals, I n c . : Suggested Formulation
12 Water-Based Paint Formulations
Low Gloss Vinvl/ABS Topcoat
Materi a1
Spensol L53
D i sperse-Ayd
Surfynol 104H
Fl a t t ing Agent TS100
Lodyne S107B
Lbs. Gals .
808.7 92.85
6.6 0.75
6.0 0.75
25.0 1.so
1.4 0.15
Disperse a t high speed f o r 15-20 minutes, then premix and add:
M i cheml ube 737
Water
Anal y s i s:
Percent Sol i d s , Weight : 31 .8
Percent Solids, Volume: 28.4
V i s c o s i t y @ 25C, #2 Zahn, Secs.: 20-25
Gloss (60/20): 7/4
VOC (excluding water):
Grams/Li t e r : 288
Pounds/Gal 1on : 2.4
pH: 8.0-8.5
Formulation 2124-54C
16.4 2.0
16.7 2.0
Clear Topcoat for F l e x i b l e Substrates
Materia1 :
Spensol L53
Surfynol 104H
C o l l o i d 679
Ucar SCT 100
M i cheml ube 737
Water
Lbs. Gals.
826.5 95.00
4 . 0 0.50
1.9 0.25
2.3 0.25
16.4 2.00
16.7 2.00
Add t h e above m a t e r i a l s i n order under good a g i t a t i o n .
NOTE: An o p t i o n a l a z i r i d i n e c r o s s l i n k i n g agent can be added t o
t h e above formula a t a l e v e l o f 7-10 lbs./100 gallons.
Analysis:
Percent Sol ids, Wei ght : 29.8
Percent Solids, Volume: 28.6
V i s c o s i t y @ 25C, #4 Ford, Secs.: 65+-5
Pounds/Gallon: 8.7
VOC (excluding water):
Grams/Liter: 374
Pounds/Gallon: 3.1
PH: 8.5t-0.3
Formulation 2307-248
SOURCE: Reichhold Chemicals, I n c . : Spensol L: Formulations
Coatings and Topcoats 13
S t r i p p a b l e C o a t i n g Sample F o r m u l a t i o n A
_____Unmodi f ied
In n r e d i e n t s :
Ucar Latex 447
Ucar F i l m e r IBT
Foamaster VF
Water
C o a t i n g P r o p e r t i e s :
AMP-95
V i s c o s i t y , cP: 1060
Stormer V i s c o s i t y , KU: 70
pH Value: 6.6
T o t a l S o l i d s , % by w e i g h t : 59.3
Pounds
797.3
2 . 1
47.5
2.1
40.9
S t r i p p a b l e C o a t i n q Sample F o r m u l a t i o n B
-Lower- Adhesion
I n q r e d i e n t s :
Ucar Latex 447
AMP-95
Ucar F i l m e r IBT
Foamaster VF
Soya L e c i t h i n
Water
C o a t i n g P r o p e r t i e s :
V i s c o s i t y , cP: 1820
Stormer V i s c o s i t y , KU: 83
pH Value: 6 . 7
T o t a l S o l i d s , % by w e i g h t : 60.3
S u b s t r a t e S t r i p p a b i 1i t y :
S u b s t r a t e :
Galvanized S t e e l
A1 -Bonderi t e
A1-A1 o d i ne
Cold R o l l e d S t e e l
My1a r
G1ass
P o l y s t y r e n e
Gloss A1 kyd
P o l y e s t e r
X=peeled c l e a n and easi l y
_ _ ~Pounds
777.0
2 . 1
46.7
2.1
20.0
41.1
G a l l o n s
88.54
0.27
6.01
0.27
4.91
G a l l o n s
86.33
0.27
5.91
0.27
2.29
4.93
Formula A
X
X
X
X
X
X
X
X
X
Formula B
X
X
X
X
X
X
X
X
X
SOURCE: Ucar Emulsion Systems: Ucar Latex 447: F o r m u l a t i o n s A & B
14 Water-Based Paint Formulations
S t r i p p a b l e Coatina Formulations
Thickened w i t h Ucar Polyphobe Rheology M o d i f i e r s
Formula C
Good Leveling
Pounds Gal lonsI n g r e d i e n t s :
Ucar Latex 447 780.9 06.77
AMP-95 4.4 0.57
Ucar Filmer IBT 46.8 5.95
Foamaster VF 2.1 0.28
Water 40.6 4.89
Ucar Polyphobe 107 13.4 1.54
~~
Coating Properties:
V i s c o s i t y , cP: 2500
Stormer V i s c o s i t y , KU: 104
pH Value: 8.1
Total Solids, % by weight: 60.1
Formula D
High B u i l d
I n g r e d i e n t s :
Ucar Latex 447
Ucar Filmer IBT
Foamaster VF
Water
Ucar Polyphobe 102
Coating Properties:
AMP-95
V i s c o s i t y , cP: 3200
Stormer Viscosity, KU: 84
pH Value: 8.9
Total Solids, % by weight: 58.8
Substrate S t r i p p a b i 1it y :
Substrate:
Galvanized Steel
A1-Bonderi t e
A1-Alodi ne
Cold Rolled Steel
Mylar
G1ass
Polystyrene
Gloss Alkyd
Polyester
X=peeled clean and e a s i l y NT=not
~~Pounds Gal 1ons
702.7 06.97
4.8 0.62
46.9 5.94
2.1 0.27
40.6 4.07
11.6 1.33
Formula C Formula D
X X
X X
NT NT
X X
X X
X X
NT NT
X X
NT NT
t e s t e d
SOURCE: Ucar Emulsion Systems: Ucar Latex 447: Formulations
Coatingsand Topcoats 15
S t r i p p a b l e C o a t i n q f o r P l a s t i c S u b s t r a t e s
I n q r e d i e n t s :
Premix #1 :
Ucar V e h i c l e 441
Defoamer (1 )
Soya L e c i t h i n (2)
Premix #2:
T r i o c t y l Phosphate
S t r i p p i n g A i d (3)
Water
Premix #3:
T h i c k e n e r (4)
Water
Premix #4:
T r i e t h y l a m i n e
I s o p r o p a n o l , 91%
Water
Water
Pounds
603.8
9.1
10.1
40.2
13.9
39.2
27.1
27.2
7.2
8.6
14.3
48.3
Gal l o n s Wt%
69.80 71.12
1 .31 1.07
1.16 1.19
5.22 4.74
1.47 1.64
4.71 4.62
3.10 3.19
3.26 3.20
1.18 0.85
1.27 1.01
1.72 1 .68
5.80 5.69
i e r s :
) Defoamer - P a t c o t e 513 ( P a t t e r s o n Chemical) o r e q u i v a l e n t .
) Soya L e c i t h i n - K e l e c i n 1081 (Spencer K e l l o g g ) o r e q u i v -
a1e n t .
e q u i v a l e n t .
(3) S t r i p p i n g A i d - Strodex PK-90 ( D e x t e r Chemicals) o r
(4) T h i c k e n e r - A c r y s o l ASE-60 (Rohm and Haas) o r e q u i v a l e n t .
Procedure:
Blend Premix #1 f i r s t , i n t h e o r d e r shown, and t h e n add t h e
r e m a i n i n g Premixes i n numerical o r d e r . A l l o w f i v e t o 10 minutes
o f a g i t a t i o n between a d d i t i o n s o f Premixes. The l a s t increment
o f w a t e r , shown below Premix #4, can b e added i n stages t o a l l o w
p r o p e r a g i t a t i o n .
C o a t i n g P r o p e r t i e s :
T o t a l S o l i d s , % by w t : 40.1
pH: 8.6
V i s c o s i t y , B r o o k f i e l d , cP: 2410
V i s c o s i t y , Stormer, KU: 84
Heat-Age S t a b i l i t y , 2 wk a t 12OF: Pass
Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass
SOURCE: Ucar Emulsion Systems: Ucar V e h i c l e 441: F o r m u l a t i o n
Suggestion LP-1924
16 Water-Based Paint Formulations
S t r i p p a b l e C o a t i nq F o r m u l a t i o n s
Inqr e dient-s :
Ucar V e h i c l e 441
Thickener ( 1 ) (11% N . V )
B u t y l C a r b i t o 1 Sol v e n t
Water
C o a t i n g P r o p e r t i e s :
Weight p e r G a l l o n , l b : 8 . 6
p H 8 . 0
T o t a l S o l i d s , % by w t : 43.8
Formul a t ion LP-3760
I n g r e d i entg:
Ucar V e h i c l e 441
Thickener ( 1 ) (11% N.V.)
B u t y l Carbi t o 1 S o l v e n t
Soya L e c i t h i n
W e t t i n g Agent ( 2 )
Water
C o a t i n g P r o p e r t i e s :
Weight p e r G a l l o n , l b : 8.6
p H : 8 . 0
T o t a l S o l i d s , % by w t : 44.4
F o r m u l a t i o n LP-3761
I n g r e d i e n t s :
i c a r V e h i c l e 441
Thickener ( 1 ) (11% N.V.)
B u t y l C a r b i t o l S o l v e n t
Soya L e c i t h i n
W e t t i n g Agent ( 2 )
Water
C o a t i n g P r o p e r t i e s :
Weight p e r G a l l o n , l b : 8 . 6
pH: 8 . 0
T o t a l S o l i d s , % by w t : 44.6
F o r m u l a t i o n LP-3762
I n g r e d i e n t s :
Ucar V e h i c l e 441
Thickener ( 1 ) (11% N.V.)
B u t y l C a r b i t o 1 S o l v e n t
Soya L e c i t h i n
W e t t i n g Agent ( 2 )
Water
C o a t i n g P r o p e r t i e s :
Weight p e r G a l l o n , l b : 8.6
pH: 8 . 0
T o t a l S o l i d s , % by w t : 45.0
F o r m u l a t i o n LP-3763
~-Pounds
840.0
5 . 4
8 . 4
10.0
-~Gal 1ons
9 7 . 1
0.7
1 . o
1 . 2
Pounds Gal 1ons
830.0 9 5 . 9
5.4 0 . 7
8 . 4 1 . o
6 . 6 0 . 8
3.3 0 . 4
10.0 1 . 2
Pounds G a l l o n s
827.0 9 5 . 6
5.4 0 . 7
8 . 4 1 . o
10.0 1 . I
3 . 3 0 . 4
1 0 . 0 I . 2
Pounds Gal 1ons
820.0 94.8
5 . 2 0 . 6
8 . 2 1 .o
16.4 1 . 9
3.3 0 . 4
1 0 . 7 1 . 3
Suppl ie r s :
( 1 ) Thickener - A c r y s o l G-110 (Rohm and Haas) o r e q u i v a l e n t .
( 2 ) W e t t i n g Agent - I n t e r w e t #33 ( I n t e r s t a b ) o r e q u i v a l e n t .
Note: I n c l u d e a s u i t a b l e p r e s e r v a t i v e i n each f o r m u l a s u g g e s t i o n .
SOURCE: Ucar Emulsion Systems: Ucar V e h i c l e 441: F o r m u l a t i o n s
Coatingsand Topcoats 17
Topcoat f o r Prefin ished Hardboard S i d i n g
Inqredients:
PiQment Or4 nd:
Water
T e r g i t o l Nonionic Surfactant
Tamol 731
Foamaster VF
T i -Pure R-960
Nytal 400
S i l c r o n G-601
Nuocide 960
Letdown :
Ucar Vehicle 462
Cyme1 325
Arcosol ve PP Sol vent
Cycat 4040
Foamaster VF
CAO-1 Anti-Oxidant
Tinuvin 328 UV Absorber
NP-10
Pounds
134.8
4.7
9.3
1.o
174.4
46.5
46.5
4.5
Gal lons
16.2
0.6
1 .o
0.2
5.2
2.7
2.0
0.6
535.4 60.8
45.2 4.4
36.1 4.9
2.8 0.3
1.1 0.1
3.0 0.3
6.5 0.7
Paint Properties:
Pigment Volume Concentration, %: 28
Crosslinker, phr: 15
Cosolvent, phr: 15
Volume Solids, %: 41
Weight per Gallon, l b : 10.6
SOURCE: Ucar Emulsion Systems: Ucar Vehicle 462: Formulation
Suggestion
18 Water-Based Paint Formulations
Water-Borne A1 kvd/Mel ami ne
Kood C l e a r c o a t M o d i f i c a t i o n
K-Flex XM-2304 i s an e x p e r i m e n t a l p r i m a r y h y d r o x y l c o n t a i n i n g
a l i p h a t i c , s a t u r a t e d u r e t h a n e r e s i n m o d i f i e r . T h i s water-borne
alkyd/melamine wood c l e a r c o a t f o r m u l a t i o n demonstrates improved
s t a i n r e s i s t a n c e and f l o w / l e v e l i n g u s i n g t h i s p r o d u c t .
%K-Flex XM-2304
Component: 0% 5% 10%
C a r g i l l 7412
Resimene 747
I s o p r o p a n o l
Water
K-Flex XM-2304
Nacure 155
K-F1 ex XM-2304:
% S o l i d s ( C a l c u l a t e d )
W e t t i n g
Alkyd/XM-Z304/HMMM
31 . 5 2 8 . 3 25.1
31 . 5 31.5 31.5
14.8 1 4 . 8 14.8
1 5 . 7 15.6 1 5 . 6
0 . 0 3 . 5 6 . 5
6 . 5 6.5 6 . 5
0% 5% 10%
66.6 6 6 . 5 66.4
5 0 / 0 / 5 0 45/5/50 40/10/50
Poor Good Best
S u b s t r a t e : Sanded and Sealed B i r c h Faced Plywood
S e a l e r : Commerci a1 V i n y l Sander/Sealer
Topcoat, WFT: 20-25u ( 0 . 8 - 1 . 0 m i l )
Topcoat Bake: 10 min./71C (160F)
4 Hour Spot T e s t
S t a i n Test
Mustard
Ketchup
C o f f e e
Homog. M i l k
Lemon J u i c e
L i q u i d C1eaner
N a i l P o l i s h Remover
0% XM-2304
M i l d A t t a c k
S t a i n
Severe S t a i n
Severe A t t a c k
M i l d A t t a c k
Severe A t t a c k
Severe Atack
5% XM-2304 10% XM-2304
M i l d A t t a c k No E f f e c t
No E f f e c t No E f f e c t
M i l d S t a i n M i l d S t a i n
M i l d A t t a c k M i l d A t t a c k
M i l d A t t a c k No E f f e c t
Severe A t t a c k / M i l d A t t a c k
No E f f e c t No E f f e c t
W h i l e a l l 3 f o r m u l a s were u n a f f e c t e d i n t h e 4 hour s p o t t e s t
by b l e a c h and m i n e r a l o i l , t h e y a l l e x h i b i t e d a m i l d a t t a c k by
Peps1 Cola; s t a i n i n g f r o m water; and a severe a t t a c k f r o m
i s o p r o p a n o l .
W i t h t h e above c u r e c o n d i t i o n a l l t h r e e f o r m u l a s gave an
H-2H p e n c i l hardness and 100+ MEK d o u b l e r u b s a t 23 u ( 0 . 9
m i 1) on A1umi num.
SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n WR-24
Coatings and Topcoats 19
Water-Borne Alkyd/Melamine
Wood Clearcoat Modification
K-Flex UD-320W i s an a l i p h a t i c , s a t u r a t e d , water s o l u b l e
r e s i n m o d i f i e r . T h i s u r e t h a n e d i o l m o d i f y i n g r e s i n i m p a r t s
s t a i n r e s i s t a n c e t o t h e f o r c e d d r y ( t h e r m o s e t ) alkyd/melamine
wood c l e a r c o a t f o r m u l a t i o n below.
What makes t h i s f o r m u l a t i o n unique i s t h e absence o f n e u t r a l -
i z i n g amines. As a r e s u l t , a f r e e a c i d c a t a l y s t may be used
(Nacure 155) and lower t e m p e r a t u r e c u r e s may be achieved. The
b i n d e r r e s i n ( a l k y d ) i s water d i l u t a b l e w i t h t h e a d d i t i o n o f
a c o s o l v e n t such as i s o p r o p a n o l . A p o t l i f e o f 8-10 hours i s
p o s s i b l e .
WB Wood C 1e a r c o a t -Modi f ic a t i o n
Component:
C a r g i l l 7412
Resimene 747
I s o p r o p a n o l
Water
K-F1 ex UD-320W
Nacure 155
K-Flex UD-320W:
% Sol i d s ( C a l c u l a t e d )
A1 kyd/K-F1 ex UD-32OW/HMMM
% K-Flex UD-320W
0% 5% 10%
31 . 5 28.3 25.1
31 . 5 31.5 3 1 . 5
14.8 14.8 14.8
15.7 15.4 15.0
0 . 0 3 . 5 7 . 1
6.5 6.5 6 . 5
0% 5% 10%
6 6 . 6 66.5 66.4
50/0/50 45/5/50 40/10/50
S u b s t r a t e : Sanded and Sealed B i r c h Faced Plywood
S e a l e r : Commerci a1 V i n y l Sander/Seal e r
Topcoat, WFT: 20-25u ( 0 . 8 - 1 . 0 m i l )
Topcoat, Bake: 10 min./71C (160F)
S t a i n T e s t
Mustard
Ketchup
C o f f e e
Homog. M i l k
Lemon J u i c e
Pepsi Cola
N a i l P o l i s h Remover
4 Hour Spot Test
0% UD-320W 5% UD-320W
M i l d A t t a c k M i l d A t t a c k
Severe S t a i n Severe S t a i n
S t a i n No E f f e c t
Severe A t t a c k No E f f e c t
M i l d A t t a c k Severe A t t a c k
M i l d A t t a c k M i l d A t t a c k
Severe A t t a c k No E f f e c t
10% UD-320W
No E f f e c t
No E f f e c t
M i l d S t a i n
No E f f e c t
Severe A t t a c k
No E f f e c t
No E f f e c t
W h i l e a l l 3 f o r m u l a s were u n a f f e c t e d i n t h e 4 hour s p o t t e s t
by b l e a c h and m i n e r a l o i l , t h e y a l l e x h i b i t e d s t a i n i n g from water
and a severe a t t a c k f r o m i s o p r o p a n o l and l i q u i d c l e a n e r
W i t h t h e above c u r e c o n d i t i o n a l l t h r e e f o r m u l a s gave an H-2H
p e n c i l hardness and 100+ MEK double r u b s a t 23u ( 0 . 9 m i l ) on
A1umi num.
SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n WR-25
20 Water-Based Paint Formulations
Waterborne Clear Hiqh Gloss Topcoat
Edaplan LA-402 was used i n a Waterborne High Gloss Wood
Topcoat t o improve w e t t i n g and l e v e l i n g . I n combination w i t h
Agitan 315 foam c o n t r o l agent, superior f i l m p r o p e r t i e s are
ach ieved .
Materi a1 : &
Rhoplex E-3188 (Rohm & Haas) 608.00 71 .77
Water 101.33 11.96
Adjust pH t o 8.5-9.0
Ammonia (28%) 5.27 0.62
Premix and add slowly:
Water
Dowanol PnB (DOW Chemical)
Arcosolve DPM (Arco Chemical)
Arcosolve DPt8 (Arco Chemical)
Tributoxyethyl phosphate
Add f o l l o w i n g w h i l e mixing:
FCA (Foam Control Agent)
Wetting Agent
Michem 392-25 (Michelman)
Adjust v i scosit y
Acrysol RM-825 (Rohm & Haas)
Water
Properties:
% N o n v o l a t i l e (by weight): 31.2
% N o n v o l a t i l e (by volume): 29.4
Weight per Gallon (pounds): 8.48
Theoretical VOC ( g r a m s / l i t e r ) : 106
V i s c o s i t y (cPs): 150+-10%
14.79 1.75
14.79 1.75
14.79 1.75
9.93 1.17
9.93 1.17
0.49 0.06
2.47 0.29
14.11 1.67
0.51 0.06
50.67 5.98
SOURCE: King I n d u s t r i e s : WR-31: A d d i t i v e s f o r Waterborne Wood
Formulations
Coatings and Topcoats 21
White Gloss Maintenance Topcoat
I n q r e d i e n t s :
Pigment G r i nd:
Methyl C a r b i t o l Solvent
Water
Bentone LT
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
Tamol 681
T r i t o n Nonionic S u r f a c t a n t CF-10
Nuosept 95
DeeFo HG-12
Acrysol RM-2020
Acrysol SCT-275
Tronox CR-828
Letdown :
Methyl C a r b i t o l Solvent )Premix
Acrysol SCT-275 1
Ucar Vehicle 435
Ucar F i l m e r IBT
Troysan Polyphase AF-1
DeeFo HG-12
Sodium N i t r i t e , 15% Aqueous S o l u t i o n
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
Adjust t o minimum pH 8.7
Pounds
59.6
18.4
1.o
1.8
18.2
2.2
2.3
1.9
17.2
8.6
225.0
8.5
8 . 6
626.9
15.8
4.9
1.9
9.0
1.8
Pai n t P r o p e r t i es :
Pigment Volume Concentration (PVC), %: 18.3
T o t a l Solids, %:
pH Value, i n i t i a l : 8.7
V i s c o s i t y :
Stormer, KU: 78
I C I , poise: 1.1
by volume: 36.1
Weight per Gallon, l b : 10.3
Freeze-Thaw S t a b i l i t y , 3 cycles: Pass
Heat S t a b i l i t y , 2 weeks a t 140F: Pass
F i l m Properties:
Contrast Ratio, 6-mil wet drawdown: 0.958
Gloss, 60: 70
Gloss, 20: 25
Gal 1ons
7.00
2.21
0.06
0.25
2.00
0.25
0.25
0.25
2.00
1 .oo
6.59
1.oo
1.oo
72.06
2.00
0.50
0.25
1.08
0.25
SOURCE: Ucar Emulsion Systems: Ucar Vehicle 435: Formulation
Suggestion M-2453
22 Water-Based Paint Formulations
White Gloss Topcoat
____M a t e r i a1 :
A r o l o n 580-W-42
Tamol SG-1
T r i t o n CF-10
C o l l o i d 694
E t h y l e n e G l y c o l
B u t y l Carbi t o 1
D o w i c i l 75
Water
Mix a t low speed:
T i t a n o x 2101
G r i n d under h i g h shear 15-20 m i n u t e s .
Under low shear, add letdown.
Water
Col l o i d 694
A r o l o n 820-W-49
Propylene G l y c o l
B u t y l Carbi t o 1 A c e t a t e
C o b a l t Hydrocure I1
Hydroxyethyl C e l l u l o s e QP-300 (10% S o l n )
Ammonia
*lo% QP-300 i n E t h y l e n e G l y c o l
A n a l y s i s :
Pigment Volume Concentration, Percent: 20.0
Pigment/Binder R a t i o : 0.94/1
Percent S o l i d s , Weight: 57.4
Percent S o l i d s , Volume: 44.0
V i s c o s i t y @ 25C, KU: 72-76
Pounds/Gallon: 11.08
VOC ( e x c l u d i n g w a t e r ) :
Grams/Li t e r : 144
Pounds/Gallon: 1.2
pH: 8.8-9.0
Lbs. Gals.
65.0 7.30
5.0 0.52
3.0 0.34
2.5 0.35
23.0 2.48
10.0 1.26
1 .o 0.08
18.0 2.16
300.0 8.57
20.0 2.40
2.5 0.35
598.0 67.95
18.0 2.08
8 . 0 0.98
0 . 4 0.05
5.0 0.53
1 .o 0.13
SOURCE: R e i c h h o l d Chrmicals, I n c . : A r o l o n 820: Formula 194-2
Coatings and Topcoats 23
Wood Topcoat Model Formulations
Rohm and Haas: Wt%
Rhoplex WL-96 (42%) 73.9
Patcote 519 0 . 2
B u t y l Carbi t o 1 ) 6.2
Dowanol PNB ) Premix 3.1
Michem Lube 110 (25% S o l i d s ) 2.9
Ammonia (14%) Adjust t o pH 8.0 0.1
Water 13.6
S.C. Johnson: Wt%
Joncryl 554 90.9
Ektasolve EB 3.6
Jonwax 26 4.5
Water 1.o
Goodyear : Wt%
Ektasolve EP 8 . 5
S a n t i c i z e r 160 2.7
D i e t h y l ami ne 1.1
Drew L-475 0.2
Water 9 . 1
P l i o l i t e 7104 (44%) 58.5
W i tcobond 234 19.9
Sanncor : Wt%
Water 16.1
Dowanol DPM 4.9
Rhoplex WL-96 (42%) 35.3
Sancure 815 42.3
Dehydran 1293 0.5
BYK 306 0.5
Acrysol RM-825 0.3
Ammonia ( 14%) Approx. 0.1
Evaluation i n Clear Topcoats:
Surfynol 104 s u r f a c t a n t was evaluated i n waterborne c l e a r
topcoats t o c o n f i r m i t s m u l t i p l e b e n e f i t s i n actual wood
c o a t i n g formulas. Since t h e most s t r i n g e n t performance require-
ments are r e l a t e d t o high-end wood coatings. Model topcoat
formulations o f t h i s type were selected f o r study.
Surfynol 104 s u r f a c t a n t was added a t 1% t o t h e model topcoat
formulations.
I n order t o evaluate a p p l i c a t i o n and f i l m property b e n e f i t s ,
Surfynol 104 s u r f a c t a n t ' s b e n e f i t s include:
*Improved f 1ow and 1eve1 ing
*Superior substrate w e t t i n g
*Low foam, and o f t e n defoaming performance
*Rapid d i spl acement o f a i r bubbles
*Mi n imal r e s o l ubi 1izat ion in water
SOURCE: A i r Products 8 Chemicals, I n c . : Surfynol Surfactants:
Suggested Formulations
Coil Coatings 25
Chromate Coi 1-Coati na Primer
I n g r e d i e n t s :
Pigment Grind:
Deio n i zed Water
Ethylene G1ycol
N,N-Dimethylethanolamine
Foamaster VF
T e r g i t o l Nonionic S u r f a c t a n t NP-10
Polywet ND-2
L-203-D Strontium Chromate
233 Basic Zinc Chromate
T i -Pure R-900
Letdown :
N, N-Di methyl ethanol ami ne
Ucar Vehicle 462
Carbi t o 1 Solvent
Arcosolve PP Solvent
Cyme1 303
Foamaster VF
Deionized Water
~ _ _ _Pounds Gallons
46.0 5.54
3.8 0.41
0.6 0.09
0.3 0.03
3.8 0.45
15.3 1.63
25.6 0.83
25.6 0.81
204.5 5.96
5.9 0.79
629.5 71.85
16.1 1.88
16.1 2.15
35.5 3.55
1.8 0.22
31.7 3.81
Wei sht%
4.33
0.35
0.06
0.03
0.35
1.44
2.41
2.41
19.25
0.56
59.26
1.52
1.52
3.42
0.17
2.92
Procedure:
order l i s t e d . Thoroughly mix l i q u i d components b e f o r e adding
pigments. Add pigments s l o w l y and s t i r u n t i l uniform. Grind a t
h i g h speed f o r 10 minutes o r u n t i l g r i n d reaches about 50C.
For t h e letdown, add t h e i n g r e d i e n t s i n t h e order shown,
making sure t h e mix i s uniform a f t e r each a d d i t i o n . For a l e s s
c r i t i c a l procedure, premix f i l m i n g a i d s w i t h c r o s s l i n k e r and
water. Mix p a i n t a t l e a s t 10 minutes a f t e r t h e f i n a l a d d i t i o n .
P a i n t P r o p e r t i 8s:
Charge t h e f i r s t s i x g r i n d components t o a Cowles mixer i n
Pigment:Binder Ratio: 0 . 8 : l .O
T o t a l N o n v o l a t i l e s , % by weight: 54.3
Resin:Me1ami ne: 89; 11
Organic i n E f f l u e n t , % by volume: 10
V i s c o s i t y , B r o o k f i e l d , cP: 300
pH Value: 9
SOURCE: Ucar Emulsion Systems: Ucar Veh
Suggestion LP-3821
9
c l e 462: Formulation
26 Water-Based Paint Formulations
Low-Sheen Coil-Coatinq Topcoat
I n q r e d ie n t s :
Pigment G r i nd:
Ethylene Glycol
Polywet ND-2
T e r g i t o l Nonionic S u r f a c t a n t NP-10
Foamaster VF
N, N-Di methyl ethanol ami ne
Dei o n i zed Water
S i l c r o n G-601
T i -Pure R-960 o r Zopaque RCL-6
Letdown :
Foamaster VF
Deionized Water
N,N-Dimethylethanolamine
Ucar V e h i c l e 462
Pigment G r i nd
Arcosolve PP Solvent
Cyme1 303
Procedure:
_ _ _ ~Pounds Gallons
2.42 0.26
9.69 1.03
2.39 0.27
1.17 0.15
0.30 0.04
95.87 11.53
48.46 2.77
193.80 5.82
2.11 0.27
22.10 2.65
3.26 0.44
585.18 66.80
354.10 21.87
30.20 4.02
39.50 3.95
Weight%
0.23
0.93
0.23
0.11
0.03
9.25
4.68
18.70
0.20
2.13
0.32
56.47
34.16
2.91
3.81
Charge t h e f i r s t s i x g r i n d components t o a Cowles mixer tank
i n t h e order l i s t e d . Mix a t low speed f o r 5 minutes. Slowly add
t h e pigments and s t i r u n t i l uniform. Grind a t h i g h speed f o r
10 minutes o r u n t i l g r i n d reaches 50C.
blend i n t o Ucar Vehicle 462 w i t h slow a g i t a t i o n . Reduce t h e
pigment g r i n d w i t h t h e n e u t r a l i z e d l a t e x and s t i r a t low speed
f o r 10 minutes. Add t h e melamine r e s i n and s o l v e n t . S t i r a t
moderate speed f o r 10 minutes.
P a i n t P r o p e r t i e s :
For t h e letdown, combine t h e antifoam, water, and t h e amine;
Pigment:Binder R a t i o : 0 . 8 : l .O
Pigment Volume Concentration, %: 19.7
T o t a l N o n v o l a t i l e s , % by weight: 53.6
Organic i n E f f l u e n t , % by volume: 10.5
Resi n:Mel ami ne: 87: 13
SOURCE: Ucar Emulsion Systems: Ucar V e h i c l e 462: Formulation
Suggestion LP-3794
Coil Coatings 27
Medium-Gloss Coil-Coating Topcoat
I n g r e d i e n t s :
Pigment Grind:
Ethylene Glycol
T e r g i t o l Nonionic S u r f a c t a n t NP-
Foamaster VF
Polywet ND-2
N,N-Dimethylethanolamine
Deionized Water
Ti-Pure R-960 o r Zopaque RCL-6
Letdown :
Foamaster VF
Deionized Water
N,N-Dimethylethanol ami ne
Ucar Vehicle 462
Pigment G r i nd
Arcosolve PP Solvent
Cyme1 303
Deionized Water
Pounds
2.48
10 2.53
0.47
10.06
0.35
52.89
253.28
4.29
4.61
2.97
630.31
322.06
31.57
35.22
26.02
Gal 1ons
0.27
0.29
0.06
1.07
0.05
6.36
7.61
Wei qht%
0.23
0.24
0.04
0.95
0.03
5.00
23.96
0.55 0.41
0.55 0.44
0.40 0.28
71.96 59.64
15.69 30.45
4.20 2.99
3.52 3.33
3.13 2.46
Procedure:
Charge t h e f i r s t s i x g r i n d components t o a Cowles mixer tank
i n t h e order l i s t e d . Mix a t low speed f o r 5 minutes. Slowly add
t h e t i t a n i u m d i o x i d e and s t i r u n t i l uniform. Grind a t h i g h speed
f o r 10 minutes o r u n t i l g r i n d reaches 50C.
For t h e letdown, combine t h e f i r s t increment o f water, t h e
antifoam, and t h e amine; blend i n t o t h e Ucar Vehicle 462 w i t h
slow a g i t a t i o n . Reduce t h e pigment g r i n d w i t h t h e n e u t r a l i z e d
l a t e x and s t i r a t low speed f o r 10 minutes. Add t h e remaining
water, melamine r e s i n , and s o l v e n t . S t i r a t moderate speed f o r
10 minutes.
P a i n t P r o p e r t i e s :
Pigment:Binder R a t i o : 0.8:l .O
Pigment Volume Concentration (PVC): 18.9
T o t a l Nonvolatiles, % by weight: 53.1
Organic i n E f f l u e n t , % by volume: 10.5
Resin:Melami ne: 89: 11
pH Value: 9
SOURCE: Ucar Emulsion Systems: Ucar Vehicle 462: Formulation
Suggestion LP-3793
28 Water-Based Paint Formulations
I n g r e d i e n t s :
Pigment G r i nd:
D i spersant (1 )
Soya L e c i t h i n (2)
Ethylene Glycol
Water
Defoamer (3)
Calcium Carbonate (4)
Titanium D i o x i d e (5)
Let Down:
Ucar V e h i c l e 441
Dispersant ( 1 )
Soya L e c i t h i n
Defoamer (3)
Melamine ( 6 )
B u t y l C e l l o s o l v e Solvent
Thickener (7)
Blue T i n t Paste ( 8 )
S u o ~ lie r s :
Pounds
3.3
3.1
4.7
74.3
0.7
263.0
25.6
630.2
3 . 1
4 . 9
1.6
5.6
14.4
6.3
2.6
Gallons
0.33
0.33
0.50
8.93
0.09
11.69
0.73
72.86
0.31
0.53
0.20
0.56
1.92
0.73
0.29
Wei qht%
0.32
0.30
0.45
7.12
0.07
25.21
2.46
60.38
0.30
0.47
0.15
0.54
1.38
0.60
0.25
Dispersant - Strodex PK-90 (Dexter Chemical) o r e q u i v a l e n t
Dispersant - Ross and Rowe 551 (Ross and Rowe Chemicals)
o r e q u i v a l e n t .
Defoamer - Foamaster VF (Diamond Shamrock) o r e q u i v a l e n t .
Calcium Carbonate - Atomite (Thompson, Weinman) o r equiv-
a l e n t .
Titanium Dioxide - Ti-Pure R-900 (duPont) o r e q u i v a l e n t .
Me1ami ne - Cyme1 350 (American Cyanamid) o r e q u i v a l e n t .
Thickener - Acrysol G-110, 22% (Rohm and Haas) o r equiv-
a1e n t .
Aqueous Dispersion - Thalo Blue (Tenneco) o r e q u i v a l e n t .
Procedure:
order l i s t e d . Mix a t low speed f o r one minute. Slowly add p i g -
ments and s t i r u n t i l uniform. Grind a t h i g h speed u n t i l d e s i r e d
g r i n d f ineness has been accompl ished.
For t h e letdown, pre-blend Ucar V e h i c l e 441, Strodex PK-90,
soya l e c i t h i n , and defoamer. With slow a g i t a t i o n , add t o t h e
pigment g r i n d . S t i r a t low speed f o r 5 t o 10 minutes. Pre-blend
B u t y l C e l l o s o l v e Solvent and melamine and add t o l e t down. S t i r
f o r f i v e minutes. Add b l u e t i n t paste and t h i c k e n e r and s t i r
f o r 5 t o 10 minutes. If done s l o w l y and c a r e f u l l l y , l e t down
Charge t h e f i r s t f i v e components t o a Cowles mixer tank i n t h e
components may be added s e q u e n t i a l l y .
Coating P r o p e r t i e s :
N o n v o l a t i l e s , %: 54 t o 55
pH: 8 . 0
Pigment/Binder R a t i o : 1 . O
V i s c o s i t y a t 25C ( B r o o k f i e l d LVT, 60 r p m ) , cP: 200
SOURCE: Ucar Emulsion Systems: Ucar V e h i c l e 441: Formu
Suggestion LP-3024
o 300
a t i on
30 Water-Based Paint Formulations
A c r y l ic Emu1s i o n Enamel -B&C
K-F1 ex UD-320W M o d i f i e d
K-F1 ex UD-320W modi f i c a t 1on o f t h i s w h i t e a c r y l ic/melami ne
emulsion f o r g e n e r a l i n d u s t r i a l a p p l i c a t i o n s demonstrated s e v e r a l
advantages in c l u d i ng: improved f l o w / l e v e l ing, h i g h e r g l o s s ,
improved g l o s s r e t e n t i o n on QUV exposure-higher s o l i d s ( l o w e r
VOC) and lower c o s t p e r pound on a s o l i d s b a s i s .
G r i n d Composition:
J o n c r y l 540
S u r f y n o l 104
T i - P u r e R-960
Water
( G r i n d t o 6+ Hegman on t h e B a l l M i l l )
Letdown Composition:
G r ind
J o n c r y l 540
HMMM
K-Flex UD-320W
Nacorr 1552
Water
Enamel C h a r a c t e r i s t i c s :
AMP-95
V i s c o s i t y , cps (25C): 200-205
Pigment/Binder R a t i o : 0 . 7 6 : l . O
pH: 8.70-8.75
Q
41.8
1. o
1 .o
4 8 . 6
7 . 6
Wt%-B Wt04-&
100.0 100.0
50.9 39.1
1 9 . 9 2 9 . 1
3 . 6 7.2
1 . 3 1 . 3
23.0 25.0
A p p l i c a t i o n and Cure:
S u b s t r a t e : B o n d e r i t e 1000 ( i r o n phosphated CRS)
Cure Schedule: 15'/300F (150C)
DFT ( m i l s ) : 0.9+-0.01 ( 2 2 . 5 ~ )
F i l m P r o p e r t i e s :
A c r y l ic/K-Flex/HMMM:
Penci 1 Hardness
Knoop Hardness (259)
MEK R e s i s t a n c e (2X)
Crosshatch Adhesion
Impact R e s i s t a n c e :
D i r e c t ( i n l b s ) :
Reverse ( i n l b s ) :
C1eve1 and H u m i d i t y (55C)
0 C
65/5/30 57/16/33
4H-5H 4H-5H
17.0 1 8 . 4
100 100
100% 100%
100-110 100-110
20- 30 20 -30
9/M 9/MD
SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n UDW-12 B & C
Enamels 31
S y n e r g i s t i c E f f e c t s o f Combinina Nacorr w i t h
A n t i - C o r r o s i v e Pinment i n an A i r Dry Water R e d u c i b l e
A1kyd M o d i f i e d A c r y l i c Enamel
Improvements i n t h e c o r r o s i o n r e s i s t a n c e o f a w a t e r r e d u c i b l e
a i r d r y a c r y l i c enamel a r e p o s s i b l e u s i n g Nacorr r u s t and c o r r -
o s i o n i n h i b i t o r s , When used i n c o m b i n a t i o n w i t h a c a l c i u m s t r o n t -
ium p h o s p h o s i l i c a t e c o r r o s i o n i n h i b i t i n g pigment (Halox SW-1111,
a d e f in i t e improvement in c o r r o s i o n r e s i s t a n c e was o b t a i ned.
S a l t spray t e s t i n g was c a r r i e d o u t o v e r i r o n phosphated p a n e l s
( B o n d e r i t e 1000).
G r i n d :
Aquamac 1090
Nacorr
2-Butoxyethanol
N y t a l 400
Halox SW-111
Raven B l a c k 16
Hal ox
C o n t r o l SW-111
3 . 7 9 3.79
2.79 2.79
11.61 9 . 2 9
2.38
0.71 0.71
____ ----
____
Letdown: (Add g r a d u a l l y w h i l e on m i l l a t low rpm):
C o b a l t Hydrocure 0.06 0.06
Manganese Hydrocure 0.08 0.08
Water 15.85 15.85
Ammonium Hydroxide, 30% 0.28 0.27
Aquamac 640 (post-add 8 shake) 64.83 64.80
Hal ox
C h a r a c t e r i s t i c s : C o n t r o l SW-111
P i gment/Bi nder R a t i o 0.4 0.4
T o t a l Resin S o l i d s , % by w e i g h t 32.0 32.0
Halox, % based on t o t a l p a i n t w e i g h t -- 2 . 4
F i l m P r o p e r t i e s :
N o n - V o l a t i l e , % by w e i g h t 44.3 4 4 . 4
Nacorr, % based on t o t a l p a i n t w e i g h t -- __
S u b s t r a t e : B o n d e r i t e 1000 I r o n Phosphated CRS
Cure: 7 days a t room temperature (22-23C)
A p p l i c a t i o n : Spray
F i l m Thickness: 20-25 m i c r o n s
Hal ox
F o r m u l a t i o n T e s t Procedure: C o n t r o l SW-111
Penci 1 Hardness
Tukon Hardness, KHN25
2B-B 28-8
1.2 2 . 2
H a l o x t
Nacorr
3 . 7 6
0.78
2.77
9 . 2 1
2.36
0 . 7 0
0 . 0 6
0 . 0 8
15.72
0.27
64.29
H a l o x t
Nacorr
0.4
44.0
31.8
0 . 8
2 . 4
Halox+
Nacorr 1151
28-8
2 . 2
Crosshatch Adhesion, % removed 0 0 0
S a l t Spray, 100 h o u r s Light-med Very l i g h t No r u s t
S a l t Spray, 310 h o u r s Very Very Medi u m
r u s t r u s t
dense r u s t dense r u s t r u s t
The use o f N a c o r r s w i t h t h e a n t i - c o r r o s i v e pigment o f f e r e d t h e
b e s t c o r r o s i o n r e s u l t s i n t h i s s t u d y . They had l i t t l e o r no
d e l e t e r i o u s e f f e c t on o t h e r p a i n t p r o p e r t i e s .
SOURCE: K i n g I n d u s t r i e s : Nacorr WR-14
32 Water-Based Paint Formulations
Ancamide 2353 Fast Drvina White Gloss Enamel
Part A:
Grind Base:
DER 660x80 (Dow)
Nuosperse 657 ( H u l s America)
Beetle 216-8 (American Cyanamid)
Dowanol PM (Dow)
TiPure R-960 (DuPont)
Let Down:
High Flash Naphtha (Ashland)
Methyl Propyl Ketone (Eastman)
Part 8:
Ancamide 2353 ( A i r Products)
n-Butanol (Ashland)
Properties :
Part A V i s c o s i t y : 86KU
Part B V i s c o s i t y : 64KU
M i xed V i s c o s i t y : 80KU
PVC: 15.2%
Vo 1ume
SOURCE
S o l i d s : 62.2%
-Lb
472.55
3.54
2.84
47.26
307.16
73.72
14.18
131.44
34.78
VOC, @ 80KU: 2.8 l b / g a l
Mix Ratio: 4:l by Volume
I n d u c t i o n Time: 0
Pot L i f e , h r : 3
Dry Times:
Set t o Touch, min: 50
Dust Free, min: 75
Hard Dry: Overnight
60 Gloss: 104
Gal
51.47
0.42
0.34
6.20
9.44
10.03
2.10
14.86
5.14
A i r Products and Chemicals, I n c . : Ancamide 2353 Curing
Agent: Table 12 Formulation
Enamels 33
Ancamide 2353 Low VOC White Gloss Enamel
P a r t A:
Grind Base:
L i q u i d DGEBA Epoxy
Nuosperse 657 (Huls America)
Surfynol 740 ( A i r Products)
Dowanol PM (Dow)
TiPure R-960 (DuPont)
Let Down:
High Flash Naphtha (Ashland)
Methyl Propyl Ketone (Eastman)
Part 8 :
Ancamide 2353 ( A i r Products)
n-Butanol (Ashland)
Propert ies :
Part A V i s c o s i t y : 73 KU
Part B V i s c o s i t y : 64 KU
Mixed V i s c o s i t y : 70 KU
PVC: 17%
Volume S o l i d s : 70%
352.76 36.43
3.88 0.46
1.76 0.25
48.68 6.32
388.04 11.92
67.73 9.22
14.11 2.09
212.03 23.46
63.14 9.34
VOC, @ 70 KU: 2.2 l b / g a l
Mix Ratio: 2:l by Volume
I n d u c t i o n Time: 0
Pot L i f e , h r : 2
Dry Times:
Set t o Touch, h r : 5
Dust Free, h r : 7
Hard Dry: Overnight
60 Gloss: 102
SOURCE: A i r Products and Chemicals, I n c . : Ancamide 2353 Curing
Agent: Tab1e 11 Formulation
34 Water-Based Paint Formulations
Carv Gloss White Enamel
I n a r e d i e n t s :
Pigment Grind:
B u t y l C e l l o s o l v e Solvent
Water
Tamol 731
T r i t o n Nonionic S u r f a c t a n t CF-10
Byk 023
T i -Pure R-900
Natrosol Plus 330
Water
Nuosept 145
Letdown :
Ucar Latex 481
Water
B u t y l Carbi t o 1 Sol vent
Solvent 142HT
LE-410 Emulsion
Surfynol 104E
P a i n t P r o p e r t i e s :
Pigment Volume Concentration, %: 17.8
Volume S o l i d s , %: 40.6
Weight S o l i d s , %: 51.9
Stormer, KU: 85
I C I , Poise: 2.0
pH Value: 9-9.6
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 0.1
Heat-Age S t a b i l i t y , 120F, weeks passed: 4
VOC, grams per l i t e r : 196
Pounds
39.0
20.0
9 . 6
2.4
2.5
240.0
1.1
5.0
1 . 4
620.0
19.6
12.8
32.8
15.0
2.0
Gal 1ons
5.20
2.40
1.05
0.27
0.35
7.02
0.10
0.60
0.16
71.84
2.35
1.60
5.00
1.82
0.24
T y p i c a l T i t a n i u m Dioxide Pigment Performance
T i t a n i u m D i o i x d e Stormer I C 1 Gloss Values
KU Poise 60 20
T i -Pure R-900 85 2.0 85 52
T i -Pure R-902 83 2.1 79 41
T i -Pure R-960 86 2.0 79 41
T i -Pure R-706 82 1.7 90 60
Tronox CR-828
Tiona RCL-535
Kronos 2310
T i o x i d e TR 90
T i o x i d e TR 93
T i o x i d e TR 80
86 2.0 87 59
83 1.7 87 59
84 1.8 84 53
83
86
85
1.7 88 54
1 . 8 86 57
2.0 90 68
SOURCE: Ucar Emulsion Systems: Ultra-Gloss Latexes: Formulation
Suggestion E-2218C
Enamek 35
C a w Gloss White Enamel
I n g r e d i e n t s :
Pigment Grind:
B u t y l C e l l os01ve Solvent
Water
Tamol 731
T r i t o n Nonionic Surfactant CF-10
Byk 023
T i -Pure R-900
Water
Nuosept 145
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
Letdown :
Ucar Latex 481
B u t y l C a r b i t o l Solvent
Sol vent 142HT
LE-410 Emulsion
Ucar Polyphobe 102 Rheo. Mod.
Ucar Polyphobe 106HE Rheo. Mod.
Water
Surfynol 104E
P a i n t Properties:
Pigment Volume Concentration, %: 17.8
Volume Solids, %: 40.7
Weight Solids, %: 52.1
Stormer, KU: 86
ICI, Poise: 2.5
pH Value: 9-9.6
Freeze-Thaw S t a b i l i t y , cycles passed: 0-1
Heat-Age S t a b i l i t y , 120F, weeks passed: 4
VOC, grams per l i t e r : 196
F i 1m Properties :
Gloss, 60: 88
Gloss, 20: 47
Flow and Leveling: Excellent
Dry-to-Touch, hour: 1
Recoat, hours: 2-4
Water/Bl is t e r Resistance: Excel l e n t
Pounds
39.0
20.0
9.6
2.4
2 . 5
240.0
5.8
1.4
2.0
620.0
12.8
32.8
15.0
5.0
2.7
10.0
2.0
Gal 1ons
5.20
2.40
1.05
0.27
0.35
7.02
0.70
0.16
0.27
71.84
1.60
5.00
1.82
0.57
0.31
1.20
0.24
SOURCE: Ucar Emulsion Systems: Ultra-Gloss Latexes: Formulation
Suggestion E-221 6G
36 Water-Based Paint Formulations
C l e a r Enamel (For Maximum S o l v e n t and A b r a s i o n Resistance)
_ _ _ _ _ _Pounds Gal l o n sM a t e r i a1.L
P a r t A:
Epi-Rez 5522-WY-55 Resin 490.6 54.82
Michem Lube 743 Mar and S l i p Agent 41 . O 5.00
C y c l o Sol 63 32.3 4.37
E k t a s o l v e EP, 2-Propoxyethanol 33.2 4.37
Water 53.6 6.44
P a r t 0 :
Epi-Cure 8290-Y-60 C u r i n g Agent
DeeFo P I - 4 Concentrate Defoamer
Water
Composite Blend: V i s c o s i t y
P a r t A 58 K.U.
P a r t B 68 K.U.
P a r t s A and 0 85 K.U.
145.8 16.51
4.0 0.49
66.6 8.00
650.7 75.00
216.4 25.00
T y p i c a l C o a t i n g P r o p e r t i e s :
T o t a l Weight S o l i d s , %: 41.8
T o t a l Volume S o l i d s , %: 37.6
V o l a t i l e Organic Compounds (VOC):
Pounds/Gallon: 2.74
G r a m s / L i t e r : 329
I n d u c t i o n Time, minutes: 30
Resi n Composi ti on :
Epoxy Resin, %: 75.0
C u r i n g Agent, %: 25.0
T o t a l , %: 100.0
SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1802:
€pi-Rez 5522-WY-55 Resin/Epi-Cure 8290-Y-60 C u r i n g Agent
Enamels 37
Gloss Safety Red Enamel
I n g r e d i e n t s :
P i gment G r i nd :
Ucar Latex 481
T r i t o n Nonionic S u r f a c t a n t CF-10
T o l u i d i n e Red 10-6C-41-L100
Aquatrend I 1 Red I r o n Oxide Disp. 878-1046
Colanyl Carmine Disp. 13-3148 (Azo Red)
Foamaster 333
Natrosol Plus 330
Water
Nuosept 145
Letdown :
Ucar Latex 481
B u t y l C e l l o s o l v e Solvent
B u t y l C a r b i t o l Solvent
Solvent 140
LE-410 Emulsion
Aquatrend I 1 Red I r o n Oxide Disp. 878-1046
Colanyl Carmine Disp. 13-3148 (Azo Red)
Surfynol 104E
P a i n t P r o p e r t i e s :
Pigment Volume Concentration, %: 11 .O
Volume S o l i d s , %: 39.5
Weight Solids, %: 43.4
Stormer, KU: 88
ICI, Poise: 1.5
pH Value: 8.5-9.5
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5
Heat-Age S t a b i l i t y , 12OF, weeks passed: 4
VOC, grams per l i t e r : 210
F i l m P r o p e r t i e s :
Gloss, 60: 81
Gloss, 20: 40
Flow and Leveling: E x c e l l e n t
Dry-to-Touch, hour: I
Recoat, hours: 2-4
Water/Bl is t e r Resistance: Excel l e n t
Pounds
173.4
10.0
110.0
9.4
7.8
15.0
1 .o
8.3
1.2
416.9
38.3
12.4
32.8
15.0
5.0
3.0
2.0
Gal l o n s
20.09
1.14
11.58
0.59
0.76
2.00
0.09
1.oo
0.13
48.31
5.10
1.55
5.00
1.82
0.31
0.29
0.24
SOURCE: Ucar Emulsion Systems: Ultra-Gloss Latexes: Formulation
Suggestion E-2222C
38 Water-Based Paint Formulations
Gloss Safety Yellow Enamel
I n p r e dient s :
Pi ament G r i nd:
Pounds
BuTyl Cellosolve Solvent
Water
Tamol 731
T r i t o n Nonionic Surfactant CF-10
Foamaster 333
T i -Pure R-900
Natrosol Plus 330
Water
Nuosept 145
B u t y l Cellosolve Solvent
Letdown :
Ucar Latex 481
Water
Byk 026
B u t y l C a r b i t o l Solvent
Sol vent 142HT
LE-410 Emulsion
Aquis Dalamar Yellow Disp. YW-811D
Aquatrend I 1 Yellow I r o n Oxide Disp. 878-0012
Aquatrend I1 Lamp Black Disp. 878-9908
Surfynol 104E
Paint Properties:
Pigment Volume Concentration, %: 11.4
Volume Solids, %: 37.4
Weight Solids, %: 43.9
Stormer, KU: 89
ICI, Poise: 1.7
pH Value: 8.5-9.5
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5
Heat-Age S t a b i l i t y , 120F, weeks passed: 4
VOC, grams per l i t e r : 218
F i 1m P r o p e r t i es :
Gloss, 60: 86
Gloss, 20: 46
F1ow and Level ing : Excel 1e n t
Dry-to-Touch, hour: 1
Recoat, hours: 2-4
Water/Blister Resistance: E x c e l l e n t
12.8
10.0
5 . 0
10.0
15.0
66.3
2.8
5.0
1.2
24.8
572.9
24.0
2.0
12.8
32.8
15.0
76.2
12.1
0.1
2.0
Gallons
1.70
1.20
0.54
1.14
2.00
1.94
0.25
0.60
0.13
3.30
66.39
2.88
0.25
1.60
5.00
1.82
8.28
0.73
0.01
0.24
SOURCE: Ucar Emulsion Systems: Ultra-Gloss Latexes: Formulation
Suggestion E-2225C
Enameh 39
Gloss White Enamel
M a t e r ia1 :
P a r t A:
Epi -rez 3520-WY-55 Resin
Michemlube 182 Mar and S l i p Agent
Water
P a r t 0:
Epi-Cure 8537-WY-60 Curing Agent
Ektasolve DB Acetate
T r i e t h y l a m i n e
Patcote 519 Defoamer
Kronos 2020 o r Tronox CR-800
Pounds
411.6
27.8
13.7
160.0
8.2
3 . 7
4.0
250.0
Gal 1ons
45.03
3.33
1.64
17.70
1.oo
0.61
0.57
7.33
High Speed d i s p e r s e t o a t e x t u r e o f 10 P.C.S., then add:
Epi-Cure 8537-WY-60 Curing Agent
Water
42.4 4.69
150.0 18.10
Composi t e 81end :
P a r t A
P a r t B
P a r t s A and B
V i scosi t y
85 KU 453.1 50.00
110 KU 619.1 50.00
99 KU
T y p i c a l Coating P r o p e r t i e s :
T o t a l Weight S o l i d s , %: 55.8
T o t a l Volume S o l i d s , %: 42.3
PVC, %: 17.3
V o l a t i l e Organic Compounds (VOC):
Pounds/Gal 1on : 1.61
Grams/Li t e r : 187
Resin Composition (based on s o l i d s ) :
Epoxy Resin, %: 65.0
Curing Agent, %: 35.0
T o t a l , %: 100.0
Reduction f o r Conventional Spray (by volume):
P a r t s A and B: 17 P a r t s
Water: 1 Part
SOURCE: S h e l l Chemical Co.: S t a r t i n g Formulation No. 1606:
Epi-Rez 3520-WY-55 Resin/Epi-Cure 8537-WY-60 Curing
Agent
40 Water-Based Paint Formulations
Gloss W h i t e~ . . ~Enamel
M a tcr i_a 1-1
P a r t A :
Epi -Rez 3520-WY-55 Resin
Michemlube 182 Mar and S l i p Agent
Water
P a r t B :
Epi-Cure 8536-MY-60 C u r i n g Agent
Deefo P I - 4 Concentrate Defoamer
R u t i l e T i t a n i u m D i o x i d e , Kronos 2020 o r
Tronox CR-800
High speed d i s p e r s e t o a t e x t u r e o f 10 P . C . S
Epi-Cure 8536-MY-60 C u r i n g Agent
Water
T y p i c a l C o a t i n g P r o p e r t i e s :
T o t a l Weight S o l i d s , %: 5 1 . 5
T o t a l Volume S o l i d s , %: 3 7 . 6
PVC, % : 19.5
V o l a t i l e Organic Compounds (VOC):
Pounds/Gal l o n s : 1 .89
Grams/Li t e r : 227
Resin Composition (based on s o l i d s ) :
Epoxy Resin, %: 62.2
C u r i n g Agent, %: 37.8
~~Pounds
329.4
8 8 . 6
27.8
160.0
4 . 0
250.0
G a l l o n s
36.04
3 . 3 3
10.63
19.28
0 . 4 9
7.33
t h e n add:
2 2 . 5 2.71
168.2 20.19
Reduction f o r Conventional Spray (by volume):
None r e q u i r e d
SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1805:
Epi-Rez 3520-WY-55 Resin/Epi-Cure 8536-MY-60 C u r i n g
Agent
Enamels 41
G l o s s W h i t e Enamel (Maximum S o l v e n t and A b r a s i o n Resistance)
M a t e r i a1 :
P a r t A:
€pi-Rez 5522-WY-55 Resin
C y c l o Sol 63
E k t a s o l v e EP, 2-Propoxyethanol
Water
P a r t 8:
Epi -Cure 8290-Y-60 C u r i n g Agent
Deefo P I - 4 C o n c e n t r a t e Defoamer
T i - P u r e R-960 o r Kronos 2160
Water
H i g h speed d i s p e r s e t o a t e x t u r e o f 10 P . S . C
Water
G l a c i a l A c e t i c A c i d
Composite Blend: V i s c o s i t y
P a r t A 61 K . U .
P a r t B 103 K . U .
P a r t s A and B 83 K . U .
T y p i c a l C o a t i n g P r o p e r t i e s :
T o t a l Weight S o l i d s , Oh: 54.0
T o t a l Volume S o l i d s , %: 40.4
PVC, %: 1 9 . 2
V o l a t i l e Organic Compounds (VOC):
Pounds/Gallon: 2 . 3 4
G r a m s / L i t e r : 280
I n d u c t i o n Time, m i n u t e s : 30
Resin Composition (based on s o l i d s ) :
Epoxy Resin, %: 74.5
C u r i n g Agent, %: 2 5 . 5
~ _ _ _Pounds Gal 1ons
442.2 49.41
2 2 . 2 3 . 0 0
22.7 3.00
9 3 . 8 11 .26
135.1 15.30
4.0 0.49
250.0 7 . 7 4
1 2 . 5 1 .so
6 6 . 1 7.93
3 . 2 0.37
580.9 66.67
470.9 33.33
Reduction f o r Conventional Spray (by volume):
P a r t s A and B: 25 p a r t s
Water: 1 p a r t
SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1803:
Epi-Rez 5522-WY-55 Resin/Epi-Cure 8290-Y-60 C u r i n g Agent
42 Water-Based Paint Formulations
Green A i r Dry Enamel f o r Flexible Substrates
Materi a1 :
Spensol L53
Amrnoni um Hydroxi de
D i sperse-Ayd W28
C o l l o i d 679
Ucar SCT 100
Sunbrite Yellow 272-0558
Sunbri t e Green 264-8142
Titanox 2101
Mapico 1075
Lbs.
261.6
1.9
4.4
1.9
2.3
50.0
25.0
25.0
50.0
Gals.
30.00
0.25
0.50
0.25
0.25
4.69
1.43
0.75
1.48
Add the above i n order under good a g i t a t i o n , then pebble o r
sandmill g r i n d t o 7 Hegman.
Letdown:
Spensol L53 526.7 60.40
Analysis:
Pigment Volume Concentration, Percent: 24.7
Pigrnent/Binder Ratio: 0.6/l.O
Percent Solids, Weight: 41.2
Percent Sol ids, Vol ume: 33.8
V i s c o s i t y @ 25C, #2 Zahn, Secs.: 50-60
Pounds/Gallon: 9.5
VOC (excluding water):
Grams/Liter: 289
Pounds/Gallon: 2.4
pH: 8.5+-0.3
SOURCE: Reichhold Chemicals, I n c . : Spensol L: Formula 2316-62A
Enamels 43
H iqh-Hidinq Esashe11 Enamel
PoundsI n s r e d ie n t s :
Pigment Grind:
Water 226.7
Cel l o s i ze Hydroxyethyl C e l l u l ose ER-4400 2.0
Nuosept 145 2 . 3
Tamol 731 9.2
T r i t o n Nonionic S u r f a c t a n t N-57 2.3
AMP-95 1.o
Propylene Glycol 51.8
Col l o i d 643 1.9
Tronox CR-800 225.0
Optiwhi t e 100.0
Burgess No. 98 25.0
Letdown :
Ucar F i l m e r I B T
B u t y l Carbi t o 1 Solvent
Acrysol SCT-275
Ucar Latex 379G
Col l o i d 643
Pai n t P r o p e r t i e s
PVC, %: 35.6
Volume Sol ids
Weight Sol i d s
Weight per Ga
Stormer. KU:
I C I . n o i s e : 1
%: 37.6
%: 53.4
l o n , l b :
04
. 4
11.9
11.9
17.2
418.2
2 . 8
1 . 0 9
G a l 1ons
27.21
0.18
0.25
1.oo
0.25
0.13
6.00
0.25
6.54
5.46
1.15
1.50
1.50
2.00
46.21
0.37
I .
pH, i n i t i a l : 8.2
Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass
Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass
F i 1m P r o p e r t i e s :
Ref 1ectance, %: 91.9
Gloss, 60: 8
Sheen, 85: 22
Contrast R a t i o , 3-mil f i l m * : 0.968
Flow and l e v e l i n g , brushed: Good
*Opacity increased w i t h t o n i n g .
SOURCE: Ucar Emulsion Systems: Formulation Suggestion I-1998A
44 Water-Based Paint Formulations
MacGregor Gloss B1ack Enamel
I n g r e d i e n t s :
Pigment Grind:
Ucar Latex 481
Byk 023
T r i t o n Nonionic Surfactant CF-10
Aurasperse Carbon B1ack W-7012
Water
Nuosept 145
Ammoni urn Hydroxide, 28% Aqueous Sol u t i on
Letdown :
Ucar Latex 481
Dee Fo 102OF
Butyl C e l l osolve Sol vent
B u t y l C a r b i t o l Solvent
Sol vent 142HT
LE-410 Emu1s i on
Water
Ucar Polyphobe 102 Rheo. Mod.
Ucar Polyphobe 106HE Rheo. Mod.
Surfynol 104E
Pounds
88.0
2.5
10.0
45.0
8.3
1 . 2
2 . 4
556.0
5.0
39.0
12.4
32.8
15.0
15.0
8.3
4.5
2 . 0
Gallons
10.20
0.35
1.14
4.69
1.oo
0.13
0.29
64.43
0.68
5.21
1.57
5.00
1.80
1.80
0.95
0.52
0.24
Paint Properties:
Pigment Volume Concentration, %: 2.3
Volume Solids, %: 37.9
Weight Solids, %: 40.6
Stormer, KU: 90
I C I , Poise: 2.6
pH Value: 8.5-9
Freeze-Thaw S t a b i l i t y , cycles passed: 5
Heat-Age S t a b i l i t y , 120F, weeks passed: 4
VOC, grams per l i t e r : 204
F i l m Properties:
Gloss, 60: 91
Gloss, 20: 65
Flow and Leveling: Excel l e n t
Dry-to-Touch, hour: 1
Recoat, hours: 2
Water/Bl is t e r Resistance: Excel l e n t
SOURCE: Ucar Emulsion Systems: Ultra-Gloss Latexes: Formulation
Suggest ion E-2221 E
Enamels 45
Pinehurst Gloss Green Enamel
I n g r e d i e n t s :
Pigment Grind:
B u t y l Cellosolve Solvent
Water
Tamol 731
T r i t o n Nonionic Surfactant CF-10
Byk 023
Chromium Oxide Green W-6017
Aurasperse Carbon Black W-7012
Aurasperse Phthalo Green W-6013
Yellow I r o n Oxide 878-1812
Natrosol Plus 330
Water
Nuosept 145
Letdown :
Ucar Latex 481
Water
B u t y l C a r b i t o l Solvent
Solvent 142HT
B u t y l Cellosolve Solvent
Water
LE-410 Emulsion
Surfynol 104E
Pounds
7.5
5.8
5.0
10.0
2.5
53.3
3.2
25.4
7.0
2.0
4.2
1.2
640.0
8.3
12.4
32.8
31 . 5
8 . 8
15.0
2.0
Gal 1ons
1.oo
0.70
0.54
1.14
0.31
3.08
0.34
2.54
0.42
0.18
0.59
0.13
74.16
1 .oo
1.55
5.00
4.20
1.06
1.82
0.24
P a i n t Properties:
Pigment Volume Concentration, %: 4.6
Volume Solids, %: 37.1
Weight Solids, %: 42.0
Stormer, KU: 88
I C I , Poise: 2.3
pH Value: 8.5-9.5
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5
Heat-Age S t a b i l i t y , 120F, weeks passed: 4
VOC, grams per l i t e r : 221
F i l m Properties:
Gloss, 60: 88
Gloss, 20: 64
Flow and Level ing: Excel 1ent
Dry-to-Touch, hour: 1
Recoat. hours: 2-4
Water/Blister Resistance: E x c e l l e n t
SOURCE: Ucar Emulsion Systems: Ultra-Gloss Latexes: Formulation
Suggestion E-22429
46 Water-Based Paint Formulations
S e l f - P r i m i n a I n t e r i o r Semi-Gloss Enamel
Pigment G r i n d :
Water
Busperse 203
I g e p a l CTA-639
Bubreak 448
Water*
C e l l o s i z e QP 15,000*
Atomi t e
T i - P u r e R-900
Disperse 10-15 minutes on a high-speed m i l l
Add t h e f o l l o w i n g w i t h slow a g i t a t i o n .
L e t Down:
Rhopl ex R-AC-507
E t h y l e n e g l y c o l
Texanol
Water
*These i n g r e d i e n t s a r e premixed.
Lbs.
100.0
14.0
3 . 0
3.0
25.0
2.0
73.0
200.0
550.0
40.0
25.0
32.0
E x t e r i o r Maintenance-Type C o a t i n g
Pigment G r i n d :
Water
Tam01 -681
8ubreak 448
I g e p a l CTA-639
E-845
Ti-Pure R-900
Atomi t e
Mica
Kadox 911
Disperse 10-15 minutes on a high-speed m i 11.
Add t h e f o l l o w i n g w i t h slow a g i t a t i o n .
L e t Down:
Rhopl ex MV-23
Texanol
E t h y l e n e g l y c o l
Water
Lbs.
100.0
14.0
3.0
3.0
40.0
150.0
191.o
25.0
12.0
527.0
5.0
30.0
30.0
&&
9 . 3 7
1 .31
0.28
0.28
2 . 3 4
0.19
6.84
18.74
51.55
3.75
2.34
3.01
Wt%
8.85
1.24
0.27
0.27
3.54
13.27
16.90
2.21
1.06
46.64
0.44
2.65
2.66
SOURCE: Buckman L a b o r a t o r i e s : B u t r o l 35: F o r m u l a t i o n Suggestions
Enamels 47
Semigloss Enamel
Inqredients:
Piament Grind:
WaIer
C e l l o s i z e Hydroxyethyl Cellulose ER-15,000
Nuosept 145
Tamol 731
T r i t o n Nonionic Surfactant N-57
Propylene G1ycol
Byk 035
Tronox CR-800
Letdown :
Thickener; premix*
Ucar Latex 3796
Ucar Filmer IBT
Byk 035
T r i t o n Anionic Surfactant GR-7M
AMP-95
Pounds
268.2
2.0
2.4
9.2
2.1
1 .o
43.2
1.o
250.0
29.9
428.4
20.0
1.9
0.5
Gal 1ons
32.20
0.18
0.25
1 .oo
0.25
0.13
5.00
0.13
7.27
3.48
2.52
0.25
0.06
47.28
Pa
*Premix consists o f 1 : l : l blend o f Propylene Glycol; Rohm
and Haas' Acrysol SCT-275 thickener:water, respectively.
n t Properties:
PVC, %: 23.0
Volume Solids, %: 31.8
Weight Solids, %: 46.0
Weight per Gallon, l b : 10.60
Stormer, KU: 82
I C I , poise: 0 . 4
pH, i n i t i a l : 8.5
Freeze-thaw S t a b i l i t y , 3 cycles: Pass
Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass
F i 1m Properti es :
Reflectance, %: 89.5
Gloss, 60: 59
Contrast Ratio, 3-mil f i l m : 0.967
Flow and Leveling:
brushed: Very Good
drawdown, NYPC Blade: 8
SOURCE: Ucar Emulsion Systems: Formulation Suggestion I-1989A
48 Water-Eased Paint Formulations
Semiq loss Enamel
Ingredient s :
Pigment Grind:
Water
Propylene Glycol
Tamol 1124
Proxel GXL
Col 1o i d 640
T i -Pure R-900
T r i t o n Nonionic Surfactant N-101
ASP-1 70
Water
Letdown :
Water
C o l l o i d 640
NeoCar Latex 6040
Water
Ucar Filmer IBT
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
Ucar Polyphobe 102 Rheology M o d i f i e r
Water
Paint Properties:
PVC, %: 24.9
Volume Solids, %: 30.5
Weight Solids, %: 44.5
Weight per Gallon, l b : 10.47
Stormer, KU: 88-93
I C I , poise: 1.1
pH Value: 8.75-9.25
Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass
F i l m Properties:
Gloss, 20: 20
Gloss, 60: 65
Contrast Ratio, 3-mil f i l m : 0.980
ASTM Scrub Cycles, w i t h shim: 1600
Block Resistance, 1 day: Exc
Wet Adhesion, 4 hours: Exc
Flow and Leveling: Exc
S t a i n Removal : Exc
Pounds
15.0
55.0
5.0
1. o
2.0
230.0
4.0
15.0
50.0
39.9
1 .o
425.0
100.0
30.0
4.0
20.0
50.0
Gal 1ons
1.80
6.35
0.51
0.11
0.26
6.90
0.46
0.70
6.00
4.79
0.13
47.39
12.00
3.79
0.52
2.30
6.00
Source: Ucar Emulsion Systems: NeoCar Polymers: Formulation
Suggestion E-2481
Enamels 49
Southern P i n e s Gloss W h i t e Enamel
I n g r e d i e n t s :
Pigment G r i n d :
Propylene G l y c o l
Water
Tamol 731
T r i t o n N o n i o n i c S u r f a c t a n t CF-10
Byk 023
T i -Pure R-900
Nuosept 145
Water
Ammoni um Hydroxi de, 28% Aqueous Sol u t i on
Letdown :
Ucar L a t e x 481
B u t y l C a r b i t o l S o l v e n t
Sol v e n t 142HT
T r i t o n A n i o n i c S u r f a c t a n t GR-5M
Byk 026
LE-410 Emu1s i on
Ucar Polyphobe 102 Rheo. Mod.
Water
S u r f y n o l 104E
Pai n t P r o p e r t i e s :
Pigment Volume C o n c e n t r a t i o n , %: 1 7 . 6
Volume S o l i d s , %: 41.1
Weight S o l i d s , %: 53.1
Stormer, KU: 90
I C I , P o i s e : 1 . 9
pH Value: 8 . 5 - 9 . 5
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5
Heat-Age S t a b i l i t y , 12OF, weeks passed: 4
VOC, grams p e r l i t e r : 174
F i l m P r o p e r t i e s :
Gloss, 60: 88
Gloss, 20: 52
F1ow and Level ing : Excel 1e n t
Dry-to-Touch, h o u r : 2
Recoat, h o u r s : 4
Water/Bl is t e r Resistance: Excel 1e n t
___Pounds
40.0
2 0 . 0
9 . 6
2 . 4
2.5
240.0
1 . 4
1 1 . 1
2 . 0
620.0
1 2 . 8
2 0 . 0
1 . o
1 . o
1 5 . 0
20.0
1 1 . 9
2 . 0
G a l l o n s
4.62
2.40
1 . 0 5
0 . 2 7
0 . 3 5
7 . 0 2
0 . 1 6
1 . 3 3
0 . 2 4
71.84
1 . 6 2
3 . 0 5
0 . 1 2
0.14
1 . 8 2
2 . 3 0
1.43
0 . 2 4
SOURCE: Ucar Emulsion Systems: U l t r a - G l o s s Latexes: F o r m u l a t i o n
Suggestion E-2251 C
50 Water-Based Paint Formulations
Spensol L54 Oranqe Enamel
Materi a1 :
Water
Ammoni um Hydroxi de
Bentone EW
Lbs. Gals.
30.0 3.60
1.1 0.15
3.0 0.14
Premix the above three materials and Cowles grind 15-20 minutes
to fully disperse Bentone EW. Then add the following materials
under good agitation:
Spensol L54
Surfynol GA
Aerosol OT-75
Nalco 2300
Molybdate Orange
Water
Pebble or sand mill grind to 7 N . S .
Letdown :
_____Materi a1 :
Spensol L54
Surfynol 104H
15% Solution FC430 in Water
Ucar SCT-100
Analysis:
Pigment Volume Concentration,
Pigment/Binder Ratio: 0.5/1 .O
Percent Solids, Weight: 39.1
Percent Solids, Volume: 30.0
Viscosity, #4 Ford, Secs.: 80-
Pounds/Gallon: 9.7
VOC (excluding water):
Grams/Li ter : 303
Pounds/Gallon: 2.5
Gloss (60): 50-60
pH: 8.5+-0.3
Percent: 9.0
.90
87.3 10.00
4.4 0.50
2.3 0.25
0.5 0.06
125.0 2.70
41.7 5.00
Lbs.
670.9
2.0
2.1
2.3
Gals.
76.85
0.25
0.25
0.25
SOURCE: Reichhold Chemicals, Inc.: Spensol L: Formula 2154-59A
Enamels 51
Waterborne Black Enamel
Based on Eootuf 37-143/37-680
XForrula No. 3019-28A1
Component A:
Arcosolv PTB
2-Butoxy Ethanol
Dowanol PPH
Add f o l l o w i n g i n order under a g i t a t i o n :
Wollastokup 10 ES
Raven 410
High speed disperse t o 5 N.S.
Add f o l l o w i n g under a g i t a t i o n :
Epotuf 37-680
& Gals
78.91 8.91
24.41 3.34
3.68 0.49
7.37 0.04
48.40
20.02
2.00
1.38
Epotuf 37-680
2-Butoxy Ethanol
432.06 48.77
9.54 1.27
Component 0:
Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l uniform:
Epotuf 37-1 43 91.85 10.32
Epotuf 37-058 7.95 1.07
2-Butoxy Ethanol 73.09 9.84
Tap Water 98.04 11.77
Wei ght/Gal l o n (Lbs. ) : 8.96
Percent S o l i d s (Wt.): 57.50
Percent S o l i d s ( V o l . ) : 37.30
PVC (%): 46.30
VOC ( Lbs. /Gal 1on) : 2.80
SOURCE: Reichhold Chemicals, I n c . : Formula 3019-28A
52 Water-Based Paint Formulations
Waterborne Blue Enamel
Based On Epotuf 37-143/37-600
LFormula No. 3019-31Gl
Component A :
Epotuf 37-680
Arcosolv PTB
2-8utoxy Ethanol
Oowanol PPH
Add following in order under agitation:
Wollastokup 10 ES
Sunfast 81ue 248-3750
Tioxide TR92
High speed disperse to 5 N . S .
Add following under agitation:
j&S Gals
133.28 15.04
24.31 3.33
3.63 0.48
7.38 0 .84
64.54
34.37
22.02
Epotuf 37-600 368. 1
2.67
2.29
0.66
1.58
Component B:
Mix following under high-speed agitation until uniform:
EDotUf 37-143 88.91
Epotuf 37-058
2-Butoxy Ethanol
Tap Water
Weight/Gallon (Lbs.): 9.29
Percent Solids (Wt.) : 57.50
Percent Solids (Vol.): 37.30
PVC (%): 46.30
VOC (Lbs./Gallon): 2.83
9.99
7.62 1.03
91 .15 12.14
82.89 9.95
SOURCE: Reichhold Chemicals, Inc.: Formula No. 3019-31G
Enamels 53
Waterborne Dark Blue Enamel
Based on Epotuf 37-143/37-600
(Formula No. 3019-31Dl
Component A:
Arcosolv PTB
2-Butoxy Ethanol
Dowanol PPH
Add f o l l o w i n g i n order under a g i t a t i o n :
Wollastokup 10 ES
Sunfast Blue 248-3750
High speed disperse t o 5 N.S.
Add f o l l o w i n g under a g i t a t i o n :
Epotuf 37-680
!& Gals
134.16 15.14
24.47 3.35
3.65 0.49
7.43 0.84
64.97
34.60
Epotuf 37-680 370.85
Component 0 :
Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l uniform:
Epotuf 37-1 43
Epotuf 37-050
2-Butoxy Ethanol
Tap Water
89.50
7.67
91.75
83.44
Weight/Gallon ( L b s . ) : 9.12
Percent S o l i d s (Wt.): 57.50
Percent S o l i d s ( V o l . ) : 37.30
PVC (%): 46.30
VOC (Lbs/Gallon): 2.83
SOURCE: Reichhold Chemicals, I n c . : Formula No. 3019-31D
2.68
2.31
41 .86
10.06
1.04
12.22
10.02
54 Water-Based Paint Formulations
Waterborne Green Enamel
XFormula No. 3019-31F)
Based on E D O t U f 37-143/37-680
Component A:
Arcosolv PTB
2-Butoxy Ethanol
Dowanol PPH
Add f o l l o w i n g i n order under a g i t a t i o n :
Epotuf 37-680
Wollastokup 10 ES
S u n b r i t e Y e l l o w 75
Sunfast Blue 248-3750
T i o x i d e TR92
High speed disperse t o 5 N.S.
Add f o l l o w i n g under a g i t a t i o n :
Epotuf 37-680
2-Butoxy Ethanol
~ Lbs
165.99
23.12
3.47
8.05
78.51
23.71
9.68
9.21
295.72
29.74
Component B:
Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l uniform:
Epotuf 37-058 6.97
Tap Water 123.78
Epotuf 37-143 82.10
2-Butoxy Ethanol 59.85
Wei ght/Gal 1on (Lbs .) : 9.20
Percent Sol i d s (Wt .) : 57.50
Percent S o l i d s ( V o l . ) : 37.30
PVC (%): 46.30
VOC (Lbs./Gallon): 2.80
SOURCE: Reichhold Chemicals, I n c . : Formula No. 3019-31F
18.73
3.17
0.46
0.91
3.24
2.22
0.65
0.28
33.38
3.96
9.22
0.94
7.97
14.86
Enamels 55
Waterborne Oranqe Enamel
Based on E p o t u f 37-143/37-600
(Formula 3019-3111
Component A:
A r c o s o l v PTB
2-Butoxy Ethanol
Dowanol PPH
Add f o l l o w i n g i n o r d e r under a g i t a t i o n :
Wollastokup 10 ES
Sunbri t e Ye1 low 74
Novoperm Red F3RK-70
High speed d i s p e r s e t o 5 N . S .
Add f o l l o w i n g under a g i t a t i o n :
Epotuf 37-680
EpOtuf 37-680
2-Butoxy Ethanol
Lbs
179.20 20.23
22.73 3.11
3.41 0.45
8.36 0.95
78 * 45
26.52
8.20
282.39
30.04
Component B:
M i x f o l l o w i n g under high-speed a g i t a t i o n u n t i l u n i f o r m :
EpOtuf 37-143 82.02
Epotuf 37-058 7.80
2-Butoxy Ethanol 60.60
Tap Water 122.11
Wei ght/Gal 1on ( Lbs . ) : 9 . 1 2
Percent S o l i d s ( W t . ) : 57.50
Percent S o l i d s ( V o l . ) : 37.30
PVC (%): 46.30
VOC ( L b s . / G a l l o n ) : 2.80
SOURCE: Reichhold Chemicals, I n c . : Formula No. 3019-311
3.24
2.49
0 . 7 6
31.87
4 . 0 0
9 . 2 2
1.oo
8.07
14.66
56 Water-Based Paint Formulations
Waterborne Red Enamel
Based on Epotuf 37-143/37-6%0
(Formula No. 3019-3181
Component A :
Arcosolv PTB
2-Butoxy Ethanol
Dowanol PPH
Add f o l l o w i n g i n order under a g i t a t i o n :
Wollastokup 10 ES
Novoperm Red F3RK-70
High speed disperse t o 5 N . S .
Add f o l l o w i n g under a g i t a t i o n :
2-Butoxy Ethanol
Tap Water
Epotuf 37-680
Epotuf 37-680
!&
97.48 11.oo
25.04 3.43
3.73 0.50
9.29 1 .06
60.09 2.48
20.69 1.92
377.11
18.73
12.91
Component 8 :
Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l uniform:
Epotuf 37-1 43 80.34
Epotuf 37-058 7.88
2-Butoxy Ethanol 65.27
Tap Water 118.45
Wei ght/Gal 1on ( Lbs .) : 8.97
Percent Sol i d s (Wt .) : 57.50
Percent S o l i d s ( V o l . ) : 37.30
PVC (%): 46.30
VOC (Lbs./Gallon): 2.84
SOURCE: Reichhold Chemicals, I n c . : Formula No. 3019-318
42.56
2.49
1.55
9.03
1.06
14.22
8.69
Enamels 57
Waterborne Red Orange Enamel
Based on EDOtUf 37-143/37-600
I f o r m u l a No. 3019-31El
Component A:
Arcosolv PTB
2-Butoxy Ethanol
Dowanol PPH
Add f o l l o w i n g i n o r d e r under a g i t a t i o n :
Epotuf 37-680
Wol l a s t o k u p 10 ES
S u n b r i t e Yellow 74
Novoperm Red F3RK-70
T i o x i d e TR 92
High speed d i s p e r s e t o 5 N.S.
Add f o l l o w i n g under a g i t a t i o n :
Epotuf 37-680
2-Butoxy Ethanol
Arcosolv PTB
Lbs Gals
157.10 17.73
23.40 3.21
3.49 0.46
8.57 0.97
73.31
19.47
8.20
7.56
307.00
25.51
5.40
Component 8:
Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l uniform:
Epotuf 37-143 84.28
Epotuf 37-058 7.36
2-Butoxy Ethanol 57.28
Tap Water 124.03
Weight/Gallon ( L b s . ) : 9.12
Percent S o l i d s (Wt.): 57.50
Percent S o l i d s ( V o l . ) : 37.30
PVC (%I: 46.30
VOC ( L b s . / G a l l o n ) : 2.80
SOURCE: Reichhold Chemicals, I n c . : Formula No. 3019-31E
3.03
1.83
0.76
0.23
34.65
3.40
0.75
9.47
1.00
7.63
14.89
58 Water-Based Paint Formulations
Waterborne Y e l l o w EDOXY Enamel
Based on EDOtuf 37-143/37-680
(Formula No. 3019-31Cl
Component A:
Arcosolv PT8
2-Butoxy Ethanol
Dowanol PPH
Add f o l l o w i n g i n o r d e r under a g i t a t i o n :
Wollastokup 10 ES
S u n b r i t e Yellow 74
T i o x i d e TR-92
High speed d i s p e r s e t o 5 N.S.
Add f o l l o w i n g under a g i t a t i o n :
Epotuf 37-680
Epotuf 37-680
2-8utoxy Ethanol
Lbs Gal
198.55 22.41
22.56 3.09
3.36 0.45
8.21 0.93
83.03
32.49
12.63
3.43
3.05
0.38
263.53 29.74
26.43 3.52
Component 8 :
Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l uniform:
Epotuf 37-143 80.25 9.02
Epotuf 37-058 6.91 0.93
2-Butoxy Ethanol 65.03 8.66
Tap Water 119.86 14.39
Wei g h t / G a l l on (Lbs. ) : 9.23
Percent S o l i d s (Wt.): 57.50
Percent S o l i d s ( V o l . ) : 37.30
PVC (%): 46.30
VOC (Lbs./Gallon): 2.40
SOURCE: Reichhold Chemicals, I n c . : Formula 3019-31C
EnameLF 59
Whisoering Pines Semigloss White Enamel
Inqredients:
Pigment Grind:
Propylene Glycol
Water
6yk 023
Tamol 731
T i -Pure R-902
Path 9
Nuosept 145
Water
Ammoni um Hydroxi de,
Pounds
30.0
53.3
2.5
10.0
230.0
40.0
1.5
16.7
28% Aqueous Sol u t i on 2.0
Letdown :
Ucar Latex 461
Ucar Filmer I6T
Sol vent 142HT
LE-410 Emulsion
Ucar Polyphobe 102 Rheo. Mod
Water
Surfynol 104E
556.0
12.4
31.5
15.0
16.9
19.7
2.0
Gal 1ons
3.47
6.40
0.35
1.09
6.92
1.98
0.17
2.00
0.94
64.66
1.57
4.80
1.BO
1.94
2.37
0.24
P a i n t Properties:
Pigment Volume Concentration, %: 23.3
Volume Solids, %: 39.2
Weight Solids, %: 51.5
Stormer, KU: 93
I C I , Poise: 2.1
pH Value: 8.5-9.5
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5
Heat-Age S t a b i l i t y , 120F. weeks passed: 4
VOC, grams per l i t e r : 181
F i l m Properties:
Gloss, 60: 54
Gloss, 20: 14
Flow and Leveling: Excellent
Dry-to-Touch, hour: 2
Recoat, hours: 4
Water/61 is t e r Resistance: Excel l e n t
SOURCE: Ucar Emulsion Systems: Ultra-Gloss Latexes: Formulation
Suggestion E-2245C
60 Water-Based Paint Formulations
Anquamine 401 1 : l White Gloss Enamel
P a r t A: j& Gals
Epi -Rez 3520-WY-55 Epoxy Resin (She11) 363.24 39.20
DER 331 Epoxy Resin (Dow) 40.36 4.17
Water
S u r f y n o l DF-11OD ( A i r P r o d u c t s )
52.32 6 . 2 7
3.00 0.36
P a r t B:
Anquami ne 401 C u r i n g Agent ( A i r P r o d u c t s ) 90.46 9.90
Dowanol PM S o l v e n t (Dow) 40.87 5 . 3 7
Benzyl A l c o h o l 29.97 3.44
S u r f y n o l DF-l10D ( A i r P r o d u c t s ) 3.00 0 . 3 6
T i P u r e 960 (DuPont) 272.48 8.16
G l a c i a l A c e t i c A c i d ( A i r P r o d u c t s ) 5.31 0 . 6 1
Water 185.01 22.16
T y p i c a l P r o p e r t i e s :
W t S o l i d s ( % ) : 65.84 Resin S t o i c h i o m e t r y : 1.3:1
Volume S o l i d s (36): 40.95 VOC ( l b / g a l ) : 1.53
PVC ( % ) : 1 9 . 9 4 VOC ( g / l ) : 184
White G1oss Enamel P r o p e r ties :
Pot L i f e , h r : >4
Gloss, 60 spec, 1 day: >90
Gloss, 60 spec, 4 week: >90
M i x R a t i o : 1 : l
Mixed V i s c o s i t y , cP: 290
Tack F r e e Time, h r : 1
Hard Dry Time, h r : 6-8
P e n c i l Hardness, o v e r n i g h t : HB
P e n c i l Hardness, 7 days: H
Cross Hatch Adhesion: 5
1/8" Mandrel Bend: Pass
D i r e c t Impact Resistance, i n - l b s : 60
Reverse Impact Resistance, i n - l b s : 20
VOC, l b / g a l : 1 . 6
Volume S o l i d s , %: 41
PVC, Yo: 19.9
SOURCE: A i r P r o d u c t s and Chemicals, I n c . : Aquamine 401 C u r i n g
Agent: F o r m u l a t i o n 1
Enamels 61
Anquamixe-401/Sol i d R e s i n D i s p e r s i o n
2 :1 W h i t e -Gloss Enamel
P a r t A: Lbs G-a 1s
Epi -Rez 3520-WY-55 Epoxy Res1n (She1 1) 5 5 7 . 4 6 1 . 2 6
Water 4 5 . 1 5 . 4 1
P a r t B:
Anquamine 401 C u r i n g Agent ( A i r Products) 7 2 . 5 7 . 9 3
Dowanol PM S o l v e n t (00,)
Dowanol EPh S o l v e n t (Dow)
Defoamer
T i Pure R960 (DuPont)
G1a c i a1 A c e t i c A c i d ( A i r Products)
Water
2 6 . 0 3 . 4 2
1 7 . 0 1 . 8 5
4 . 0 0 . 5 0
2 2 7 . 7 6 . 8 2
2 . 0 0 . 2 3
1 0 5 . 0 1 2 . 5 8
T y p i c a l P r o p e r t i e s :
W t S o l i d s ( % ) : 7 4 . 2 6 Resin S t o i c h i o m e t r y : 1 . 5 8 : l
Volume Sol i d s (%) : 4 3 . 0 3 VOC ( l b / g a l ) : 1 . 2 6
PVC ( % I : 1 5 . 8 5 VOC ( g / l ) : 151
White Gloss Enamel P r o p e r t i e s :
Pot L i f e , h r : >6
Gloss, 60 spec, 1 day: >90
Gloss, 60 spec, 4 w k : > 9 0
M i x R a t i o : 2 : l
Mixed V i s c o s i t y , cP: 360
Tack Free Time, h r : 1
Hard D r y Time, h r : 6-8
P e n c i l Hardness, o v e r n i g h t : HB
P e n c i l Hardness, 7 days: H
Cross Hatch Adhesion: 5
1/8" Mandrel Bend: Pass
D i r e c t Impact Resistance, in-1 b s . : 60
Reverse Impact Resistance, i n - l b s . : 20
Taber Abrasion, mg loss/lOOO c y c l e s : 9 0
VOC, l b / g a l : 1 . 8
Volume Sol i d s , '%: 4 3
PVC, %: 1 6 . 5
SOURCE: A i r P r o d u c t s and Chemicals, I n c . : Anquamine 401 C u r i n g
Agent : Formul a t i on 2
Enamels-Baking 63
Clear Bake Coatins
Pounds Gal l o n sMateri a1 : _ _ _ ~
Epi -Rez 3551-WY-43 Resi n 617.04 68.56
Ektapro EEP 16.14 2.04
B e e t l e 80 188.87 20.87
Water 71 .OS 8.53
Typical Coating P r o p e r t i es :
Add under a g i t a t i o n :
T o t a l Weight Solids, %: 51.8
T o t a l Volume S o l i d s , %: 47.4
Pounds/Gallon: 8.93
Epoxy/Urea, based on s o l i d s , %: 60/40
V o l a t i l e Organic Compounds (VOC):
Pounds/Gallon: 1.47
Grams/Li t e r : 176
V i s c o s i t y , #4 Ford Cup, seconds: 60-70
Dry F i l m Thickness: 0.7 m i l
Substrate: Bonderite 1000
Bake Schedule a t 350F, minutes: 20
Pencil Hardness: 6H
Reverse Impact, i n . l b s . : 160
M€K Double Rubs: 100
Typical F i l m Properties:
S t a r t i n g Formulation No. 2503: Epi-Rez 3551-WY-43 Resin
Phenol ic Clear Bake Coating
Pounds Gal l o n sMateri a1 :
Epi -Rez 3540-WY-55 Resin 439.6 48.07
_ _ _ ~
Methyl I s o b u t y l Ketone 98.8 14.81
Dei oni zed Water 98.8 11.85
S i l w e t L-7604 S u r f a c t a n t 2.4 0.28
Santol i n k EP-560 193.3 21.15
Dimethylethanolamine 19.1 2.54
Syntex 3981 Accelerator 9.1 1.30
T y p i c a l Coating P r o p e r t i e s :
T o t a l Weight S o l i d s , %: 46.8
T o t a l Volume S o l i d s , %: 42.7
Pounds per Gallon: 8.61
Epoxy/Phenol ic, sol i d s : 60/40
Percent C a t a l y s t , Active, on Resins S o l i d s : 0.5
V o l a t i l e Organic Compounds (VOC):
Pounds/Gallon: 2.90
Grams/Li t e r : 348
V i s c o s i t y , B r o o k f i e l d , #5 Spindle a t 50 RPM, cps: 1,200
Dry F i l m Thickness: 0.5 m i l s
Substrate: Bonderite 1000
Bake Schedule: 10 minutes a t 400F
Pencil Hardness: 6H
Reverse Impact, i n . l b s . : 160
MEK Resistance, double rubs: 100
Typical F i l m Properties:
S t a r t i n g Formulation No. 2504: Epi-Rez 3540-WY-55 Resin
SOURCE: S h e l l Chemical Co.: S t a r t i n g Formulations
64 Water-Based Paint Formulations
Clear H i q h Gloss, Bakina F i n i s h
Materi a1 : Lbs.
Cymel 303 premi x--combi ne in t h e f o l l o w i n g o r d e r :
Cymel 303 57.6
Isopropanol 4.5
Nacure 2500-X 4 . 5
T r i e t h y l a m i n e 0.6
Water 28.8
Add i n f o l l o w i n g order w i t h a g i t a t i o n :
Spensol L51 768.1
Cymel 303 Premix 96.0
Aerosol OTS 5 . 4
Lodyne S107B 5.4
Byk 301 3.1
Cure f o r 2 hours a t 250F o r 30 minutes a t 300F.
A n a l y s i s :
R a t i o o f Spensol L51 t o Cymel 303: 80:20
Percent S o l i d s , Weight: 33.8
Percent S o l i d s , Volume: 30.1
VOC ( e x c l u d i n g water):
Grams/Li t e r : 189
Pounds/Gallon: 1.6
Formulation 2061-40D
B l u e Metal 1ic Urethane Enamel
M a t e r i a l : Lbs.
Component A--add i n f o l l o w i n g order w i t h a g i t a t i o n :
Spensol L51 707.9
Premix t h e f o l l o w i n g two m a t e r i a l s , then add:
A1umi num Paste #E2255 30.0
Water 31 .2
Add :
Aurasperse W4123 92.0
Surfynol 104H 4.0
Lodyne 51076 1.5
Component B:
XAMA-7 7.4
NOTE: Add t h e above Component B t o Component A p r i o r t o
A n a l y s i s :
t i o n and mix w e l l f o r 5 t o 10 minutes.
Percent Sol i d s , Weight : 31 .8
Percent S o l i d s , Volume: 28.4
V i s c o s i t y @ 25C, #2 Zahn, Secs.: 25-30
VOC ( e x c l u d i n g w a t e r ) : Grams/Liter: 408
pH: 8.0-8.5
Pounds/Gallon: 3 . 4
Formulation 2099-19
Gals.
5.76
0.68
0.55
0.10
3.46
87.88
10.55
0.63
0.56
0.38
Gals.
81 .oo
2.34
3.75
11.50
0.50
0.16
0.75
appl ica-
SOURCE: Reichhold Chemicals, I n c . : Spensol L: Formulations
Enamels-Baking 65
E x p e r i r e n t a l Water-Reducible Polyester Gloss White
Baking Enamel Usina Halox SZP-391
Grind:
W/R Polyester 72-7203
DMEA
Cyme1 303
Lbs./lOO Gals. Gms/Liter
170.0 204.0
10.0 12.0
50.0 60.0
Premix t h e next two raw m a t e r i a l s before adding.
n-Butyl Alcohol
Dow Corning 14
R-902 Ti02
Halox SZP-391
Deionized Water
High Speed Disperse t o 7 Hegman g r i n d .
Letdown :
W/R Polyester 72-7203
DMEA
n-Octyl Alcohol
Troysol LAC
n-Butyl Alcohol
Deionized Water
Mix u n t i l uniform - Do not aerate!
Hold f o l l o w i n g f o r v i s c o s i t y adjustment.
8.0 9.6
0.8 I . o
225.0 275.0
15.0 18.0
50.0 60.0
100.0 120.0
15.0 18.0
1.o 1.8
1.5 1.8
10.0 12.0
325.0 390.0
Deionized Water 55.0 66.0
Formula Constants:
% P i gment/Wt .: 23.16
% Pigment/Vol .: 7.25
% Solids/Wt.: 48.24
Formula P r o p e r t i e s :
Density 1bs. /gal .: 10.36
Density g/L: 1,249
Visc. #2 Zahn (sec.
% S o l i d s / V o l . : 33.12 pH @ R.T.: 8.5-9.0
% PVC: 21.85
VOC, l b s . / g a l . : 2.03
VOC, g/L: 304.5
SOURCE: Halox Pigments: Suggested Formulation PEG39
: 50-60
66 Water-Based Paint Formulations
Waterborne A c r y l i c Bake Enamel
The WR-17 study was conducted t o demonstrate t h e improved
corrosion resistance afforded a waterborne system by choosing
a more hydrophobic c a t a l y s t , Nacure 155 (DNNDSA), over a more
h y d r o p h i l i c c a t a l y s t , K-Cure 1040 (p-TSA). Free a c i d c a t a l y s t ,
r a t h e r than t h e blocked versions, were used i n t h i s study,
since t h e formula already contained a n e u t r a l i z i n g amine. A
summary o f the formulation, i t s physical p r o p e r t i e s and t e s t
r e s u l t s are l i s t e d below.
G r i nd Composition :
Titanox 2020
Acrysol WS-68
2-Butoxyethanol
n-Butanol
DMEA
0.1. Water
(Pebble M i l l Grind t o 7 t on Hegman)
Letdown Composi t ion :
Acrysol WS-68
n-Butanol
Hexamethoxymethylmelamine
2-Butoxyethanol
*DMEA (10% i n water)
* O . I . Water
*Used t o a d j u s t pH and v i s c o s i t y
C h a r a c t e r i s t i c s :
P i gment/Bi nder : 40/60
Acryl ic/Mel ami ne: 80/20
Total S o l i d s , %: 37.7
Total Resin Solids, %: 22.6
Wt./gal. C 25C ( l b / g a l ) : 9.65
V.O.C. (Measured) l b . / g a l . : 1.84
A p p l i c a t i o n and Cure:
Substrate: Bonderite 1000 ( i r o n phosphated CRS)
Cure Schedule: 15' a t 149C (300F)
F i 1m Thickness : 0.7-0.8 m i 1
Wt%
15.07
3.97
0.67
0.63
0.90
4.69
43.63
0.54
4.51
3.90
2.20
20.10
F i l m Properties: Control K-Cure 1040 Nacure 155
p-TSA DNNDSA
Pencil Hardness H-2H
Tukon Hardness, KNH25 13.2
MEK Rubs (2X) 24
Impact Resistance, ( i n - l b s . )
Reverse 90-100
O i r e c t 40-50
Crosshatch Adhesion, % Loss 100
S a l t Spray, 150 h r s . (ASTM 8117)
mm Creep/Blister: 6-7mm/10 6
H-2H H-2H
13.2 13.0
42 50
20-1 30 90-1 00
30-40 30-40
100 100
7mm/lO 3-4mm/ 0
SOURCE: King I n d u s t r i e s : Formulation WR-17
Enamels-Baking 67
Water Reducible P o l v e s t e r Baking Enamel
I n t h i s s t u d y Nacorr c o r r o s i o n i n h i b i t o r s were i n c o r p o r a t e d
i n t o a pigmented waterborne p o l y e s t e r system c r o s s l i n k e d w i t h a
h i g h -NH t y p e melamine r e s i n . The Nacorrs were added a t a l e v e l
o f 3%, based on t h e t o t a l f o r m u l a w e i g h t . S i n c e t h e Nacorrs a l s o
f u n c t i o n as d i s p e r s i n g agents, t h e r e i s a d e f i n i t e advantage i n
in c o r p o r a t i ng them in t o t h e d i s p e r s i ng stage.
G r i n d (Pebble M i l l ) :
T i -Pure R-960
Cargi 11 72-7203
2-Butoxyethanol
Nacorr
Water
DMEA
Letdown :
Cargi 11 72-7203
DMEA
Cyme1 327
S i l w e t 7605 (10% i n 2-butoxyethanol)
Water
C o n t r o l Nacorr
24.00 24.00
18.00 17.81
4.00 2.50
---- 3.00
1.31
0.69
6.00 6.19
1.oo 1 .69
6.67 6.67
1.oo 1.oo
37.33 37.14
----
----
C h a r a c t e r i s t i c s : C o n t r o l Nacorr
Pol yester/Mel ami ne R a t i o 75/25 75/25
Pigment, % 24 24
T o t a l Resin S o l i d s , % by weight 24 24
A d d i t i v e l e v e l , % based on t o t a l weight o f p a i n t -- 3.0
F i l m P r o p e r t i e s :
Pigment/Bi nder R a t i o 1/ I 1/ I
S u b s t r a t e : B o n d e r i t e 1000 I r o n Phosphated CRS
Cure: 10 minutes/300F (149C)
F i l m Thickness: 16-21 microns
P e n c i l Hardness
Tukon Hardness KHN25
C o n t r o l N-1151 N-1351
2H-3H 2H-3H H-2H
16.6 17.7 11 .o
MEK Rubs (2X) 65
Impact ( i nch 1bs. ) , Reverse 5-10
D i r e c t 70-80
Gloss, 60 9 1 . 4
S a l t Spray, 408 h r s . 13/D3
F i l m P r o p e r t i e s :
S u b s t r a t e : B o n d e r i t e 1000 I r o n Phosphated
Cure: 10 minutes/250F (121C)
F i l m Thickness: 16-21 microns
C o n t r o l
Penci 1 Hardness H-2H
Tukon Hardness KHN25 11.1
MEK Rubs (2x1 12
Impact ( inch 1bs. ) , Reverse (5
D i r e c t 60-70
Gloss, 60 93.3
S a l t Spray, 408 h r s . 13/MD4
SOURCE: K i n g I n d u s t r i e s : Nacorr WR-18
64
5-10
60-70
90.6
2/10
CRS
N-1151
H-2H
12.2
13
<5
60-70
94.7
2/10
24
5-10
60-70
92.2
2/F8
N-1351
HB-F
6 . 7
12
5-10
50-60
93.3
3F/2
68 Water-Based Paint Formulations
Spensol L54 White Bakina Enamel
____Materi a1 :
Speneol L54
Water
Ammonium Hydroxide
Surfynol GA
Aerosol OT-75
Foamki 11 639AA
Titanox 2101
Lbs.
87.3
75.0
1.9
4.4
2.3
1.1
200.0
Pebble o r sandmill g r i n d the above m a t e r i a l s t o 7+ N . S .
Letdown :
Spensol L54 536.9
Gals.
10.00
9.00
0.25
0.50
0.25
0.15
5.85
61.50
Premix t h e next f o u r materials, then add under good a g i t a t i o n .
Cyme1 385
DMEA
Isopropanol
Water
Add t h e f o l l o w i n g under good a g i t a t i o n :
Surfynol 104H
Versa-Flow 102
Bake schedule: 10 minutes a t 300F (150C).
Analysis:
Pigment Volume Concentration, Percent: 18
Pigment/Binder Ratio: 0.8/1 .O
Percent Solids, Weight: 44.7
Percent Solids, Volume: 32.6
V i s c o s i t y @ 25C, #4 Ford, Secs. : 30
Pounds/Gal l o n : 10.3
VOC ( e x c l udi ng water) :
Grams/Liter: 240
Pounds/Gal 1on : 2
Gloss (60): 60-70
pH: 8.3+-0.3
62.1 5.75
1.8 0.25
6.8 1.oo
41.7 5.00
2 . 0 0.25
2.0 0.25
SOURCE: Reichhold Chemicals, I n c . : Spensol L: Formula 2154-598
Enamels-Baking 69
?-Component Waterborne SysteE
Formulation WR-41 demonstrates t h e improved performance o f a
2-component waterborne system when m o d i f i e d w i t h K-Flex XM-4316,
a p o l y e s t e r - u r e t h a n e d i s p e r s i o n . A t b o t h NCO/OH r a t i o s , improve-
ments were made i n gloss, M E K r e s i s t a n c e , and f l e x i b i l i t y .
NCO/OH R a t i o : 1 . 1
A c r y l i c / P U - D i s p e r s i o n : 80/20
Component A:
Emulsion E-3275
K-F1 ex XM-4316
Sodium N i t r i t e (5% aq)
Proglyde DMM
Edaplan LA 402
S i l w e t 7001 (5% aq)
S i l w e t 7605 (25% aq)
S i l w e t 7604 (25% aq)
Dimethylethanolamine
Component 0:
Bayhydur XP-7063
Formulation C h a r a c t e r i s t i c s :
N o n v o l a t i l e , t h e o r e t i c a l , %: 46.3
T h e o r e t i c a l VOC, g/L, ( l b / g a l l o n ) : 60, ( 0 . 5 )
Formulation Propert
Gloss 60, %: 95
20, %: 69
Koenig Hardness
Pencil Hardness:
es, A i r - D r y 20-25C, 2 weeks:
s e c ) : 69
H-2H
Knoop Hardness: 2 . 4
MEK Double Rubs: 80
Impact, D i r e c t , i n c h . l b . : >160
Impact, Reverse, i n c h . l b . : >160
W t %
71 .38
17.40
0 . 0 0
0 . 8 9
0.07
0 . 0 0
0.25
0.25
0.73
9.03
Formulation P r o p e r t i e s , Bake 8OC 20 min. Post-cure 20-25C, 2
weeks :
Substrate: Bonderite 1000 c o l d r o l l e d s t e e l
F i l m thickness, micron (mi 1 .) : 32+-2 (1.3+-0.1)
NCO/OH R a t i o : 1 . 1 Knoop Hardness: 3.7
Gloss 60, %: 96 MEK Double Rubs: 120
Koenig Hardness ( s e c ) : 89 Impact, Reverse, i n c h x l b . : 160
Pencil Hardness: 2H
20, %: 66 Impact, Forward, i n c h x l b . : ,160
Formulation Preparation:
a g i t a t i o n f o r approx. 5 minutes.
SOURCE: King I n d u s t r i e s : P r e l i m i n a r y Formulation WR-41
Add component B t o component A under low shear mechanical
Exterior Paints and Related Products 71
E x t e r i o r F l a t House P a i n t w i t h ZnO
I n q r e d i e n t s :
Pi gment G r ind :
Water
Ucar Pol yphobe 9831 Rheology Modi f ie r
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
P r o x e l GXL
C o l l o i d 226/35
C o l l o i d 640
T r i t o n N o n i o n i c S u r f a c t a n t X-100
Propylene G1y c o l
Potassium T r i p o l y p h o s p h a t e (KTPP)
T i -Pure R-706
417-W Z i n c Oxide
Minex 4
N y t a l 300
___.Pounds
236.2
9 . 5
1 . 8
2.0
8 . 5
1 . 9
3 . 3
25.9
1 . 5
225.0
2 5 . 0
1 2 5 . 9
5 0 . 0
Letdown :
Ucar L a t e x 625 426.4
B u t y l C a r b i t o l S o l v e n t 1 0 . 7
C o l l o i d 640 1 . 9
Skane M-8 2 . 2
Ammonium Hydroxide, 28% Aqueous S o l u t i o n 0 . 9
P a i n t P r o p e r t i e s :
Pigment Volume C o n c e n t r a t i o n , %: 40.0
Volume S o l i d s , %: 38.0
Weight S o l i d s , %: 5 5 . 6
Weight p e r G a l l o n , l b : 11.59
Stormer, KU: 95
I C I , P o i s e : 1 . 1
pH Value: 8 . 9
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Age S t a b i l i t y , 120F, weeks passed: 2
F i 1m P r o p e r t ies :
C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.969
R e f l e c t a n c e , %: 9 1 . 9
Sheen, 8 5 : 8
Wet Adhesion, g l o s s a l k y d : E x c e l l e n t
Flow and L e v e l i n g : Good
Sag R e s i s t a n c e , m i l s : >12
Gal l o n s
28.30
1 . 1 0
0 . 2 0
0.20
0 . 8 0
0.30
0 . 4 0
3.00
0 . 1 0
6 . 6 0
0 . 6 0
5 . 8 0
2 . 1 0
48.40
1 . 4 0
0.30
0.30
0.10
SOURCE: Ucar Emulsion Systems: Ucar Polyphobe 9831 Rheology
M o d i f i e r : F o r m u l a t i o n Suggestion E-2483
72 Water-Based Paint Formulations
E x t e r i o r F l a t House P a i n t w i t h ZnO
I n q r e d i e n t s :
Pigment Grind:
Water
Ucar Polyphobe 102 Rheo. Mod.
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
Proxel GXL
Col 1o i d 226/35
C o l l o i d 640
T r i t o n Nonionic S u r f a c t a n t X-100
Propylene G1y c o l
Potassium Tripolyphosphate (KTPP)
T i -Pure R-706
417-W Zinc Oxide
Minex 4
N y t a l 300
Pounds
227.2
18.5
1.8
2 . 0
8.5
1.9
3.3
25.9
1.5
225.0
25.0
125.9
50.0
Letdown :
Ucar Latex 625 426.4
Ucar F i l m e r I B T 10.7
C o l l o i d 640 1.9
Skane ME 2.2
Ammonium Hydroxide, 28% Aqueous S o l u t i o n 0.9
Pai n t Propert ies :
P i gment Vol ume Concentration, %: 40.0
Volume Solids, %: 38.0
Weight S o l i d s , %: 55.6
V i s c o s i t y , equi 1ib r a t e d :
Stormer, KU: 98
I C I , Poise: 1.5
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Aged S t a b i l i t y , 120F, weeks passed: 2
F i l m P r o p e r t i e s :
Contrast R a t i 0, 6 - m i 1 wet drawdown : 0.968
Reflectance, %: 91.9
Sheen, 85: 7
Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass
Wet Adhesion, g l o s s alkyd: E x c e l l e n t
Gal l o n s
27.30
2.10
0.20
0.20
0.80
0.30
0.40
3.00
0.10
6.60
0.60
5.80
2.10
48.40
1.40
0.30
0.30
0.10
SOURCE: Ucar Emulsion Systems: Ucar Latex 625: Formulation
Suggestion E-2463
Exterior Paints and Related Products 73
E x t e r i o r Gloss White
I n q r e d i e n t s :
Pigment Grind:
Water
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
Sol vent 142HT
Tamol 165
Potassium Tripolyphosphate (KTPP)
T r i t o n Nonionic S u r f a c t a n t CF-10
Proxel GXL
Byk 023
T i -Pure R-706
Letdown :
Ucar Latex 481
Solvent 142HT
Byk 025
B u t y l C a r b i t o l Solvent
Water
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
Ucar Polyphobe 9831 Rheology Modi f ie r
P a i n t P r o p e r t i e s :
Pigment Volume Concentration, %: 19.8
Volume S o l i d s , %: 33.9
Weight S o l i d s , %: 45.8
Weight per Gallon, l b : 10.28
Stormer, KU: 95
I C I , Poise: 1.8
pH Value: 9-9.5
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 0-1
Heat Age S t a b i l i t y , 120F, weeks passed: 4
V o l a t i l e Organic Content, g/L: 120
F i l m P r o p e r t i e s :
Gloss, 60: 77
Gloss, 20: 34
F1ow and Level ing : Excel 1e n t
Dry-to-Touch, hours: 2
Recoat, hours: 4-6
Water/Bl is t e r Resi stance: Good
Pounds
112.0
1.o
10.0
13.7
0.5
3.0
2.0
2.5
225.0
519.0
10.0
2.0
26.0
8 5 . 6
1.o
14.8
G a l l o n s
13.40
0.10
1.50
1.50
0.03
0.40
0.20
0.30
6.80
58.60
1.50
0.30
3.30
10.10
0.10
1.70
SOURCE: Ucar Emulsion Systems: Ucar Polyphobe 9831 Rheology
Modi f ie r : Formulation Suggestion E-2482
74 Water-Based Paint Formulations
E x t e r i o r House P a i n t
Materi a1 :
Grind:
Water
Nuosept 95 (Nuodex)
Tamol 731 (Rohm and Haas)
Igepal CO-630 (GAF)
Ti-Pure R-902 (DuPont)
Beaverwhite 325 Talc (Cyprus)
325 W.G. Mica (Unimin)
FCA (Foam Control Agent)
Premix and add:
Ethylene Glycol
Texanol (Eastman)
Natrosol Plus 330 PA (Aqualon)
Letdown :
Water
248-5809 (McWhorter)
FCA (Foam Control Agent)
Water
Properties:
Pigment Volume Content, %: 31.2
% N o n v o l a t i l e (by weight): 54.6
% N o n v o l a t i l e (by volume): 39.3
VOC. g / l : 126
Stormer Viscosity. K.U.: 90+-5
I C 1 V i s c o s i t y , Poise: 1+-0.1
Gloss a t 60, %: 0-5
Recommended Products:
Agitan 260, 315 o r 731
-Lbs
101.6 12.20
1.5 0.16
7.5 0.82
3.4 0.38
213.3 6.23
111.7 1.07
25.4 4.99
4.5 0.20
23.6 2.54
5.9 0.74
4.0 0.36
125.0 15.01
437.8 48.03
3.0 0.39
50.0 6.10
SOURCE: King I n d u s t r i e s : Formulation WR-39: FCA's f o r Trade Sales
P a i n t
Exterior Paints and Related Products 75
E x t e r i o r House P a i n t - T i n t Base
Inaredients:
Pigment Grind:
Water
Ucar Polyphobe 102 Rheo. Mod.
Ammoni um Hydroxide, 28% Aqueous Sol u t i on
Proxel GXL
Tamol 1124
C o l l o i d 640
T r i t o n Nonionic Surfactant N-101
Propylene Glycol
Tronox CR-828
Minex 4
H y d r i t e F l a t D
Pounds
209.6
19.6
1.8
2.0
5 . 0
1.9
3.2
25.9
150.0
125.0
75.0
Gal 1ons
25.20
2.10
0.20
0.20
0.50
0.30
0.40
3.00
4.40
5.80
3.50
Letdown :
Ucar Latex 625 455.9 51.80
Ucar Filmer IBT 11.4 1.40
C o l l o i d 640 1.9 0.30
Troysan Polyphase AF-1 7.3 0.80
Ammonium Hydroxide, 28% Aqueous S o l u t i o n 0.9 0.10
P a i n t Properties:
Pigment Volume Concentration, %: 35.8
Volume Solids, %: 38.0
Weight Solids, %: 53.2
V i s c o s i t y , e q u i l i b r a t e d :
Stormer, KU: 91
I C I , poise: 1.4
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Aged S t a b i l i t y , 120F, weeks passed: 2
F i l m Properties:
Contrast Ratio, 6-mil wet drawdown: 0.956
Reflectance, %: 90.1
Sheen, 85: 7
Color Acceptance: E x c e l l e n t
Color F l o a t : Good
Wet Adhesion, 4-hr: E x c e l l e n t
Flow and Leveling, ASTM D-4062: 8
F i l m B u i l d , s q . f t . / g a l . : 411
Low Temperature Coalescence:
sealed: 10
unsealed: 10
SOURCE: Ucar Emulsion Systems: Ucar Latex 625: Formulation
Suggestion E-2460
76 Water-Based Paint Formulations
E x t e r i o r Senialoss
~ _ _ _Pounds Gal 1onsI n q r e d ie n t s :
Pigment Grind:
Water
Nuosept 95
Propylene G1ycol
Tamol 1124
Ammonium Hydroxide (28% Aqueous S o l u t i o n )
T r i t o n Nonionic S u r f a c t a n t N-57
C o l l o i d 653
T i -Pure R-700
Letdown :
Water
Ucar Pol yphobe 102 Rheology Modi f ie r
Ucar Latex 2300
Ucar F i l m e r IBT
Col l o i d 653
Troysan Polyphase AF-1
T r i t o n Anionic S u r f a c t a n t GR-7M
P a i n t P r o p e r t i e s :
Pigment Volume Concentration, %: 22.0
Volume Solids, %: 32.6
Weight S o l i d s , %: 47.2
Weight per Gallon, l b : 10.43
Stormer, KU: 99
I C I , Poise: 1 .26
pH Value: 8.0
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 7
F i l m P r o p e r t i e s :
Gloss, 60: 78.3
Gloss, 20: 39.6
Contrast R a t i o , 6-mil wet drawdown: 0.964
Reflectance, %: 91.8
Scrub Resistance, c y c l e s passed: 161
150.0 18.96
2.3 0.25
60.5 7.00
7.4 0.75
2.0 0.25
2.1 0.25
1.9 0.25
250.0 7.16
91.5 10.99
13.1 1 .so
447.7 50.88
11.2 1.41
2.8 0.37
7.3 0.75
1.1 0.13
SOURCE: Ucar Emulsion Systems: Formulation Suggestion E-2263
Exterior Paints and Related Products 77
E x t e r i o r Semisloss Formulation
I n q r e d i e n t s :
P igment G r ind:
Water
Ucar Polyphobe 102 Rheology M o d i f i e r
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
Propylene Glycol
Troysan 586
Tamol 1124
C o l l o i d 643
T r i t o n Nonionic Surfactant N-57
Tronox CR-828
Polygloss 90
Pounds
190.0
17.4
1.8
60.5
1.8
5.3
1.8
2.1
250.0
25.0
Letdown:
Water 1 5.5
Ucar Polyphobe 102 Rheology M o d i f i e r ) Premix 4.4
NeoCar Latex 2300 474.4
C o l l o i d 643 1.8
Ucar Filmer I B T 15.8
Troysan Polyphase AF-1 7.4
T r i t o n Anionic Surfactant GR-7M 1 . 1
Ammonium Hydroxide, 28% Aqueous S o l u t i o n 1.8
Gal 1ons
22.80
2.00
0.23
6.99
0.19
0.54
0.23
0.25
7.50
1.15
0.66
0.51
53.61
0.23
1.99
0.74
0.13
0.23
Note: If wet adhesion i s desired, blending w i t h an a c r y l i c
r e s i n , such as Ucar Latex 625, i s recommended.
Pai n t P r o p e r t ies :
PVC, %: 23.6
Volume Solids, %: 38.7
Weight Solids, %: 52.6
Weight per Gallon, l b : 10.68
Stormer, KU: 99
I C I , poise: 1.5
pH Value: 8.7
Freeze-Thaw S t a b i l i t y , 3 cycles: Pass
Heat-Aged S t a b i l i t y , 4 weeks a t 140F: pass
Fi 1m Properties :
Reflectance, %: 92.3
Gloss, 20: 19
Gloss, 60: 59.5
Flow and Leveling: Exc
Color Acceptance: Exc
SOURCE: Ucar Emulsion Systems: NeoCar Polymers: Formulation
Suggest ion E-2264
78 Water-Based Paint Formulations
E x t e r i o r T i n t Base Formulation
Inqredient s :
Pigment Grind:
Water
Ucar Polyphobe 102 Rheology Modi f ie r
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
Troysan 586
Tamol 1124
C o l l o i d 640
T r i t o n Nonionic S u r f a c t a n t N-101
Propylene G1ycol
Tronox CR-828
Minex 4
H y d r i t e F l a t D
Pounds
197.4
15.2
1.8
2.0
5.0
1.9
3.2
25.9
150.0
125.0
75.0
Letdown :
Water 3.8
Ucar Latex 625 319.2
Ucar Latex 461 145.5
Ucar F i l m e r IBT 11.4
C o l l o i d 640 1.9
Troysan Polyphase AF-1 7 . 3
Ammonium Hydroxide, 28% Aqueous S o l u t i o n 0.9
Pai n t Propert ies :
Pi gment Vol ume Concentrat ion, %: 35.8
Volume S o l i d s , %: 38.0
Weight per Gallon, l b : 10.9
Stormer, KU: 83
I C I , Poise: 0.95
pH Value: 9.6
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Age S t a b i l i t y , 12OF, weeks passed: 2
R a t i o o f Ucar Latexes 625:461: 70:30
F i lrn P r o p e r t i e s :
Sheen. 85: 9 . 2
Gal l o n s
23.7
1.7
0 . 3
0.2
0.5
0.3
0.4
3.0
4.4
5.8
3.5
0.5
36.3
16.9
1.4
0.3
0.8
0.1
Contrast Ratio, 6-mil wet drawdown: 0.952
Dry Adhesion ( u n t r e a t e d aluminum, galvanized s t e e l , a1kyd
Wet Adhesion ( u n t r e a t e d aluminum, galvanized s t e e l , a l k y d
B1is t e r i ng ( u n t r e a t e d a1umi num, g a l vani zed s t e e l , a1kyd
and l a t e x c h a l k ) : Exc
and l a t e x chalk, g l o s s a l k y d ) : Exc
and l a t e x c h a l k ) : Exc
SOURCE: Ucar Emulsion Systems: Ucar Latex 461: Formulation
E-2474
Exterior Paints and Related Products 79
E x t e r i o r T r i m F o r m u l a t i o n
Modi f ied V i nvl A c r v l ic P a i n t
I n q r e d i e n t s :
P i ament G r i nd:
WaTer
Ucar Polyphobe 102 Rheology Modi f ie r
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
Propylene G l y c o l
Nuosept 95
Tamol 1124
C o l l o i d 643
T r i t o n N o n i o n i c S u r f a c t a n t N-57
Tronox CR-828
P o l y g l o s s 90
Letdown :
Water
Ucar Polyphobe 114 Rheology Modi f ie r
B u t y l C a r b i t o l S o l v e n t
Ucar F i l m e r I 8 T
Ucar Latex 3796
Ucar Latex 633G
C o l l o i d 643
Troysan Polyphase AF-1
Byk 346
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
Pai n t P r o p e r t ias :
Pigment Volume C o n c e n t r a t i o n , %: 24.2
Volume S o l i d s , %: 35.0
Weight p e r G a l l o n , l b : 10.7
Stormer, KU: 96
I C I , P o i s e : 1.2
pH Value: 7.6
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Age S t a b i l i t y , 120F, weeks passed: 2
R a t i o o f Ucar Latexes 379G:6336: 70:30
F i l m P r o p e r t i e s :
Gloss, 60: 46
Gloss, 20: 10
C o n t r a s t R a t i o , 6-mil wet drawdown: 0.967
Reflectance, %: 91.8
B l o c k Resistance: 8
Pounds
98.5
19.3
1.8
59.6
2.3
7.3
1 . 9
2 . 1
246.3
24.6
78.0
6 . 5
20.5
10.2
316.1
162.0
2 . 8
7.2
1 . 1
1 . 8
Gal 1ons
11.8
2.2
0.3
6 . 9
0.2
0.7
0 . 3
0.2
7.2
1 . 1
9 . 4
0 . 7
2.6
1 . 3
34.9
18.4
0.4
0.7
0 . 1
0 . 3
Dry Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a1kyd
Wet Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a l k y d
B l i s t e r i n g ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a l k y d
and l a t e x c h a l k ) : Exc
and l a t e x c h a l k , g l o s s a l k y d ) ; Exc
and l a t e x c h a l k ) : Exc
SOURCE: Ucar Emulsion Systems: Ucar L a t e x 0336: F o r m u l a t i o n
E-2471
80 Water-Based Paint Formulations
E x t e r i o r T r i m Formulation
I n g r e d i e n t s :
Pigment Grind:
Water
Ucar Pol yphobe 102 Rheology Modi f ie r
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
Propylene Glycol
Troysan 586
Tamol 1124
C o l l o i d 643
T r i t o n Nonionic S u r f a c t a n t N-57
Tronox CR-828
Polygloss 90
Letdown :
Water
NeoCar Latex 2300
Ucar Latex 6336
C o l l o i d 643
Ucar Filmer IBT
Troysan Polyphase AF-1
T r i t o n A n i o n i c S u r f a c t a n t GR-7M
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
P a i n t P r o p e r t i e s :
Pigment Volume Concentration, %: 24.0
Volume S o l i d s , %: 35.5
Weight per Gallon, l b : 1 0 . 7
Stormer, KU: 93
I C I , Poise: 1 . 4
pH Value: 8.9
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Age S t a b i l i t y , 12OF, weeks passed: 2
Pounds
190.6
21.8
1 . 8
60.5
1 . 8
5.3
1 . 8
2 . 1
250.0
25.0
7.2
365.4
107.8
1.8
15.8
7 . 4
1 . 1
1 . 8
Gal 1ons
22.9
2.5
0.3
7 . 0
0.2
0.5
0.3
0.2
7 . 3
1.1
0.9
41.3
12.3
0.3
2.0
0.8
0 . 1
0.3
F i l m P r o p e r t i e s :
Gloss, 60: 77
Gloss, 20: 28
Contrast R a t i o , 6-mil wet drawdown: 0.977
Reflectance, %: 92.2
Block Resistance, 1-week d r y , RT: 8
Dry Adhesion ( u n t r e a t e d aluminum, galvanized s t e e l ,
Wet Adhesion ( u n t r e a t e d aluminum, galvanized s t e e l ,
61 is t e r i ng ( u n t r e a t e d a1umi num, galvanized s t e e l , a1kyd
a l k y d c h a l k ) : Exc
a l k y d chalk, g l o s s a l k y d ) : Good
c h a l k ) : Good
SOURCE: Ucar Emulsion Systems: Ucar Latex 6336: Formulation
E-2472
Exterior Paints and Related Products 81
E x t e r i o r T r i m F o r m u l a t i o n
I n a r e d i e n t s :
Pigment G r i n d :
Water
Ucar Polyphobe 102 Rheology M o d i f i e r
Ammoni um Hydroxi de, 28% Aqueous Sol u t i on
Propylene G1y c o l
Nuosept 95
Tamol 1124
C o l l o i d 643
T r i t o n N o n i o n i c S u r f a c t a n t N-57
Tronox CR-828
P o l y g l o s s 90
Pounds
98.5
1 9 . 3
1 . 8
5 9 . 6
2 . 3
7 . 3
1 . 9
2 . 1
2 4 6 . 3
2 4 . 6
Letdown :
Water
B u t y l C a r b i t o l S o l v e n t
Ucar F i l m e r I 8 T
Ucar L a t e x 626
Ucar L a t e x 471
C o l l o i d 643
Troysan Polyphase AF-1
Byk 346
Ammonium Hydroxide, 28%
47.2
2 0 . 5
1 0 . 2
372.5
129.4
2 . 8
7 . 2
1 . 1
Aqueous Sol u t i on 1 . 8
P a i n t P r o p e r t i e s :
Pigment Volume C o n c e n t r a t i o n , %: 2 4 . 2
Volume S o l i d s , %: 35.0
Weight p e r G a l l o n , l b : 10.5
Stormer, KU: 89
I C I , P o i s e : 1 . 5
p H Value: 8 . 8
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Age S t a b i l i t y , 120F, weeks passed: 2
R a t i o o f Ucar Latexes 626:Ucar 471: 70:30
F i 1m P r o p e r t ies :
Gloss, 60: 53
Gloss, 20: 15
C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.97
R e f l e c t a n c e , %: 92.2
B l o c k R e s i s t a n c e : 9
G a l l o n s
11 . 8
2 . 2
0.3
6 . 9
0 . 2
0.7
0 . 3
0 . 3
7 . 2
1 . 1
5.7
2.6
1 . 3
42.8
1 4 . 9
0.4
0 . 8
0 . 1
0 . 3
Dry Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a l k y d
B l i s t e r i n g ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l ,
and l a t e x c h a l k ) : Exc
l a t e x c h a l k ) : Exc
l a t e x c h a l k , g l o s s a l k y d ) : Exc
Wet Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e
SOURCE: Ucar Emulsion Systems: Ucar L a t e x 471: Formu
E-2475
a l k y d and
, a l k y d and
a t i o n
82 Water-Based Paint Formulations
E x t e r i o r White F l a t House P a i n t
I n q r e d ients:
P igment G r ind:
Water
Ucar Polyphobe 102 Rheo. Mod.
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
Proxel GXL
Tamol 1124
Col l o i d 640
T r i t o n Nonionic Surfactant N-101
Propylene G1ycol
T i -Pure R-706
Minex 4
Nytal 300
Pounds
234.5
19.6
1.8
2.0
5.0
1.9
2.1
25.9
225.0
135.4
75.0
Letdown :
Ucar Latex 625 408.6
Ucar Filmer IBT 10.2
C o l l o i d 640 1.9
Troysan Polyphase AF-1 7.3
Ammonium Hydroxide, 28% Aqueous S o l u t i o n 1.8
Paint Properties:
Pigment Volume Concentration, %: 42.5
Volume Solids, %: 38.0
Weight Solids, %: 5 5 . 7
V i s c o s i t y , equi 1ibrated:
Stormer, KU: 90
I C I , Poise: 1 . 3
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Aged S t a b i l i t y , 120F, weeks passed: 2
F i l m Properties:
Contrast Ratio, 6-mil wet drawdown: 0.965
Reflectance, %: 91.9
Wet Adhesion, gloss alkyd: E x c e l l e n t
Chalk Adhesion, ASTM #5: G o o d
Gal 1ons
28.20
2.30
0.20
0.20
0.50
0.30
0.30
3.00
6.60
6.20
3.20
46.40
1.30
0.30
0.80
0.20
SOURCE: Ucar Emulsion Systems: Ucar Latex 625: Formulation
Suggestion E-2459
Exrenor Paints and Related Products 83
E x t e r i o r White T r i m House P a i n t
I n q r e d i e n t s :
P i Qment G r i nd:
Water
Ucar Polyphobe 102 Rheo. Mod.
Ammonium Hydroxide, 28% Aqueous
Troy 586
Tamol 1124
C o l l o i d 640
T r i t o n N o n i o n i c S u r f a c t a n t N-57
Propylene G1y c o l
T i -Pure R-902
P o l y g l o s s 90
Letdown :
Ucar Latex 625
Ucar F i l m e r IBT
Pounds
208.1
19.6
S o l u t i o n 1 . 8
2.0
7.4
1 . 9
2.1
60.5
237.5
50.0
Gal 1ons
24.90
2.30
0.20
0.20
0.70
0.30
0.20
7 . 0 0
7.10
2.30
459.3 52.20
11.5 1 .50
C o l l o i d 640 2.8 0.40
Troysan Polyphase AF-1 7.3 0.80
Ammonium Hydroxide, 28% Aqueous S o l u t i o n 0.9 0.10
Byk 346 1 . 1 0.10
P a i n t P r o p e r t i e s :
Pigment Volume C o n c e n t r a t i o n , %: 27.0
Volume S o l i d s , %: 34.0
Weight S o l i d s , %: 48.6
V i s c o s i t y , e q u i l i b r a t e d :
Stormer, KU: 91
I C I , Poise: 1 . 3
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Aged S t a b i l i t y , 120F, weeks passed: 2
F i l m P r o p e r t i e s :
C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.968
R e f l e c t a n c e , %: 9 3 . 4
Gloss, 60: 40
Wet Adhesion, g l o s s a l k y d , 4-hr: E x c e l l e n t
Adhesion, 1 week, ASTM D3359 ( w e t ) :
a l k y d : 4A
aluminum: 5A
Chalk Adhesion, ASTM #5: Good
B l i s t e r i n g , 24 h r s . :
aluminum: 10
a l k y d c h a l k (ASTM #5): 8F
Flow and L e v e l i n g , brushed: 7
SOURCE: Ucar Emulsion Systems: Ucar L a t e x 025: F o r m u l a t i o n
Suggestion E-2402
84 Water-Based Paint Formulations
Good Q u a l i t y White E x t e r i o r F l a t P a i n t for Masonry
I n a r e d i e n t s :
P i gment G r i nd :
Water
C e l l o s i z e Hydroxyethyl C e l l u l o s e QP-15,000
Potassium T r i p o l y p h o s p h a t e (KTPP)
Nuosept 95
C o l l o i d 643
T r i t o n N o n i o n i c S u r f a c t a n t N-101
Tamol 850
Ti-Pure R-902
Eagle 417W
Snowf 1ake
Minex 4
AMP-95
Pounds
199.9
2.5
2.0
1.5
2.0
3.0
1 .o
7.0
220.0
25.0
100.0
131.7
G a l l o n s
24.00
0.22
0.09
0.16
0.26
0.34
0.13
0.71
6.60
0.53
4.44
6.07
Disperse a t h i g h speed f o r 15 minutes. Do n o t exceed 120F.
D i s p e r s i o n s h o u l d be 3-4 on Hegman.
Letdown :
Water 1 127.1 15.26
Propylene G1y c o l ) Premi x 40.0 4.62
C e l l o s i z e Hydroxyethyl C e l l u l o s e )
QP-15,000 ) 2.3 0.20
C o l l o i d 643 2.0 0.26
NeoCar Latex 2300 305.0 34.47
Ucar F i l m e r IBT 13.0 1.64
P a i n t P r o p e r t i e s :
PVC, %: 50.0
Volume S o l i d s , %: 35.3
Weight S o l i d s , %: 54.6
Weight p e r G a l l o n , l b : 11.98
Stormer, KU: 88-93
I C I , p o i s e : 0.8-1.0
pH Value: 8.0-8.5
Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass
F i l m P r o p e r t i e s :
R e f l e c t a n c e , %: 89.4
Gloss, 60: 2
Sheen, 85: 3
C o n t r a s t R a t i o , 3-mil f i l m : 0.970
ASTM Scrub Cycles, w i t h shim F a i l u r e : >3000
SOURCE: Ucar Emulsion Systems: NeoCar Polymers: F o r m u l a t i o n
Suggest ion E-2252
Exterior Paints and Related Products 85
Good Q u a l i t y White E x t e r i o r F l a t P a i n t f o r Wood
I n g r e d i e n t s :
Pigment G r i nd:
Water
C e l l o s i z e Hydroxyethyl C e l l u l o s e QP-
Potassium Tripolyphosphate (KTPP)
Nuosept 95
C o l l o i d 643
T r i t o n Nonionic Surfactant N-101
Tamol 850
T i -Pure R-902
Eagle 417W
Snowf 1ake
Minex 4
AMP-95
Pounds
195.8
15,000 2.5
2.0
1.5
2.0
3.0
1.o
7.0
245.0
50.0
70.0
85.0
Gallons
23.50
0.22
0.09
0.16
0.26
0.34
0.13
0.71
7.35
1.07
3.11
3.92
Disperse a t h i g h speed f o r 15 minutes. Do not exceed 120F.
Dispersion should be 3-4 on Hegman.
Letdown :
Water ) 51 .5 6.17
Propylene G1ycol 1 40.0 4.62
C e l l o s i z e Hydroxethyl C e l l u l o s e ) Premix
QP-15,OOO 1 2.0 0.17
C o l l o i d 643 2.0 0.26
NeoCar Latex 2300 405.0 45.77
Ucar Filmer I B T 17.0 2.15
Note: I f wet adhesion i s desired, blending w i t h an a c r y l i c
r e s i n , such as Ucar Latex 625, i s recommended.
P a i n t Properties:
PVC, %: 39.8
Volume Solids, %: 38.8
Weight Solids, %: 56.6
Weight per Gallon, l b : 11.82
Stormer, KU: 88-93
I C I , poise: 0.8-1 .O
pH value: 8.0-8.5
Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass
Reflectance, %: 90.8
Gloss, 60: 3
Sheen, 85: 6
Contrast Ratio, 3-mil f i l m : 0.976
ASTM Scrub Cycles, w i t h shim F a i l u r e : >3000
F i 1m Properties :
SOURCE: Ucar Emulsion Systems: NeoCar Polymers: Formulation
Suggestion E-2253
86 Water-Based Paint Formulations
Ingrediernrs;
Pigment G r i nd:
Water
Ucar Polyphobe
Ammoni um Hydrox
Solv e n t 142HT
Tamol 165
P o t a s s i um T r i po
T r i t o n N o n i o n i c
Proxel GXL
Byk 023
Ti-Pure R-706
Greqson D r i v e Gloss White
Pounds
112.0
02 Rheo. Mod. 10.0
de, 28% Aqueous S o l u t i o n 1 .o
1 0 . 0
1 3 . 7
yphosphate (KTPP) 0 . 5
S u r f a c t a n t CF-10 3 . 0
2 . 0
2.5
2 2 5 . 0
Letdown :
Ucar L a t e x 481 519.0
Sol v e n t 142HT 10.0
Byk 025 2 . 0
B u t y l C a r b i t o l S o l v e n t 26.0
Water 76.4
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 1.o
Ucar Polyphobe 106HE Rheo. Mod. 14.0
P a i n t P r o p e r t i e s :
Pigment Volume C o n c e n r t a t i o n , %: 1 9 . 8
Volume S o l i d s , %: 33.9
Weight S o l i d s , %: 45.8
Stormer, KU: 87
I C I , P o i s e : 1 . 0
pH Value: 9-9.5
Freeze-Thaw Stab
Heat-Age S t a b i l i
VOC, grams p e r 1
F i l m P r o p e r t i e s :
Gloss, 60: 90
G l o s s . 20: 70
l i t y , c y c l e s passed: 0-1
y. 12OF, weeks passed: 4
t e r : 120
Gal l o n s
13.40
1.20
0.10
1 . 5 0
1.50
0 . 0 3
0 . 4 0
0 . 2 0
0 . 3 0
6.80
____
58.60
1.50
0.30
3.30
9.17
0.10
1 .60
F1ow and Level ing : Excel 1e n t
Dry-to-Touch, h o u r s : 2
Recoat, h o u r s : 4-6
W a t e r / B l i s t e r R e s i s t a n c e : Good
SOURCE: Ucar Emulsion Systems: U l t r a - G l o s s Latexes: F o r m u l a t i o n
Suggestion E-2256
Exterior Points and Related Products 87
H i g h Q u a l i t y E x t e r i o r Semi Gloss P a i n t
M a t e r ia1 :
Grind:
Water
Natrosol Plus (Aqualon)
Acrysol RM 1020 (Rohm and Haas)
Acrysol RM 825 (Rohm and Haas)
Pigment Disperser NL (BASF)
TKPP (10% i n water)
Proxel GXL ( I C 1 B i o c i d e s )
FCA (Foam Control Agent)
Kronos 2310 (Kronos)
Letdown :
Propylene g l y c o l
Dowanol DPnB (Dow)
Mineral S p i r it s
Acronal DS 6183 (BASF)
FCA (Foam Control Agent)
Water
Propert i es :
Pigment Volume Content, %: 25.5
% N o n v o l a t i l e (by weight): 45.2
% N o n v o l a t i l e (by volume): 32.1
VOC, g / l : 107.0
Stormer V i s c o s i t y , K . U . : 105t-5
I C 1 V i s c o s i t y , Poise: 1.5+-2
Gloss a t 60, %: 67.0
Weight p e r Gallon, l b s / g a l l o n :
% foam on manufacturing:
Recommended Product:
A l t e r n a t i v e Products:
SOURCE: King I n d u s t r i e s : Formulat
Agitan 731: High performance w
A g i t a n 260 o r A g i t a n 315
62.50 5.99
0.52 0.05
31.32 3.00
7.31 0.70
1.04 0.10
3.13 0.30
2.09 0.20
3.13 0.30
261 .02 25.02
41.76 4.00
10.44 1.oo
10.44 1.oo
417.63 40.00
3.13 0.30
188.46 18.04
Agitan 731
10.6
0.66
t h excel l e n t p e r s i stency
on WR-39-2
88 Water-Based Paint Formulations
High Sheen White House P a i n t
I n q r e d i e n t s : Pounds
Pigment Grind:
Water 203.9
Ucar Polyphobe 102 Rheo. Mod. 15.2
Ammoni um Hydroxi de, 28% Aqueous Sol u t i on 1.8
Troy 586 2.0
Tamol 1124 4.9
C o l l o i d 643 1 . 9
T r i t o n Nonionic S u r f a c t a n t N-101 2.1
Propylene Glycol 34.6
Kronos 2310 225.0
Minex 10 71 .O
Burgess No. 98 75.0
Letdown :
Ucar Latex 625
Ucar F i lmer IBT
Col l o i d 643
Troysan Polyphase AF-1
Byk 346
Ammmonium Hydroxide, 28% Aqueous S o l u t
P a i n t P r o p e r t i e s :
Pigment Volume Concentration, %: 35
Volume S o l i d s , %: 38.1
Weight S o l i d s , %: 54.0
V i s c o s i t y , equi 1ib r a t e d :
Stormer, KU: 88
I C I , Poise: 1.O
461.9
11.5
1.9
7.3
1.1
on 0.9
2
Gallons
24.48
1.75
0.25
0.20
0.48
0.25
0.25
4.00
6.75
3.27
3.42
52.19
1.45
0.25
0.75
0.13
0.13
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Aged S t a b i l i t y , 120F, weeks passed: 2
F i l m P r o p e r t i e s :
Contrast Ratio, 6-mil wet drwadown: 0.984
Reflectance, %: 92.2
Sheen, 85: 64.0
Wet Adhesion, g l o s s alkyd: E x c e l l e n t
Chalk Adhesion, ASTM #5: Good
SOURCE: Ucar Emulsion Systems: Ucar Latex 625: Formulation
Suggestion E-2461
Exterior Paints and Related Products 89
Low VOC E x t e r i o r House P a i n t
M a t e r i a1 :
G r i n d :
N a t r o s o l 250 MHR 2.5% (Aqualon)
Water
Tamol 731 (Rohm and Haas)
KTPP
T r i t o n CF-10 (Rohm and Haas)
Kathon LX 1.5% (Rohm and Haas)
FCA (Foam C o n t r o l Agent)
T i -Pure R-902 ( DuPont )
Eagle Z i n c 417W (Eagle)
Minex 4 (Indusmin)
A t t a g e l 50 (Englehard)
Letdown :
Emulsion E-3122 (Rohm and Haas)
FCA (Foam C o n t r o l Agent)
A c r y s o l RM-2020 (Rohm and Haas)
N a t r o s o l 250 MHR 2.5% (Aqualon)
Skane M-8 (Rohm and Haas)
Water
Lbs
127.0
85.0
16.0
1 .o
1.o
1.7
2.0
250.0
25.0
144.0
5.0
301 .O
2.0
15.0
29.0
2.0
149.0
%Wt
1 5 . 2
10.2
1.8
0.1
0.1
0 . 2
0.3
7.5
0 . 5
6 . 6
0 . 2
34.0
0.3
0.2
1.7
3 . 5
17.9
P r o p e r t i e s :
Pigment Volume Content, %: 43.5
% N o n v o l a t i l e (by w e i g h t ) : 52.4
% N o n v o l a t i l e (by volume): 34.3
Stormer V i s c o s i t y , K.U.: 9 2 t - 5
I C 1 V i s c o s i t y , Poise: 1.3+-2
Recommended Product:
A g i t a n 731: S u p e r i o r performance i n b o t h a p p l i c a t i o n and
p r o d u c t i o n o f p a i n t . F i n e t u n i n g w i l l o p t i m i z e
performance and may p r o v i d e a c o s t advantage.
A g i t a n 315: E x c e l l e n t foam c o n t r o l i n a l l aspects o f p a i n t
manufacture and a p p l i c a t i o n . Lower c o s t a l t e r -
n a t i v e t o 731.
A l t e r n a t i v e Product: A g i t a n 260
SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n WR-39-4
90 Water-Based Paint Formulations
Q u a l i t y E x t e r i o r F l a t Formulation
I n g r e d i e n t s :
Pigment G r i nd:
Water
C e l l o s i z e Hydroxyethyl C e l l u l o s e QP-15,000
Potassium Tripolyphosphate (KTPP)
Drewplus L-475
T r i t o n Nonionic Surfactant N-101
Tamol 850
AMP-95
T i -Pure R-902
Eagle 417W
I m s i l A25
C e l i t e 499
Water
Letdown :
Water 1
Natrosol Plus 330 ) premix
Propylene Glycol
Drewplus L-475
Ucar Latex 6390
NeoCar Latex 2300
Ucar Filmer I8T
P a i n t Properties:
Pigment Volume Concentration, %: 48.7
Volume Solids, %: 30.0
Weight per Gallon, l b : 11.5
Stormer, KU: 83-88
I C I , Poise: 0.9
pH Value: 8.9
Low Temperature Coalescence: Pass
F i l m Properties:
Gloss, 60: 2
Sheen, 85: 2
Contrast Ratio, 6-mil wet drawdown: 0.990
Reflectance, %: 88.4
Scrub Resistance, cycles passed: >1500
Dry Adhesion, crosshatch tape p u l l : Pass
Wet Adhesion, c y c l e s passed: >2000
50-mil Mudcracking: Pass
Pounds
183.3
2.5
2.0
2.0
4.0
7.0
1.5
220.0
50.0
130.0
20.0
16.7
188.2
4 . 0
30.0
2.0
65.0
208.0
14.0
Gal 1ons
22.0
0 . 2
0.1
0.3
0.5
0.7
0.2
6.6
1.1
5.9
1 .o
2.0
22.6
0.4
3.5
0.3
7.4
23.5
1.7
SOURCE: Ucar Emulsion Systems: Ucar Latex 8390: Formulation
E-2477
Exterior Paints and Related Products 91
Qual i ty Exterior Flat Paint
Inaredients;
Pigment Grind:
Water
Cellosize Hydroxyethyl Cellulose ER-30,000
Nuosept 145
Tamol 960
Potassium Tripolyphosphate (KTPP)
Triton Nonionic Surfactant N-101
Propylene G1 ycol
Colloid 640
Ti -Pure R-900
Eagle 417W
Mica 325WG
~ ~ p - 9 5
IT-325
Letdown:
Ucar Latex 379G
Ucar Filmer IBT
Skane M-8
Colloid 640
Paint Properti8s:
PVC, %: 40.1
Volume Solids, %: 39.3
Weight Solids, %: 57.7
Weight per Gallon, lb: 11.9
Stormer, KU: 100
ICI, poise: 0.9
pH, initial: 8.9
Freeze-thaw Stability, 3 cycles: Pass
Heat-Aged Stability, 2 weeks at 120F: Pass
Film Properties:
Ref1 ectance, %: 90.5
Sheen, 85: 5.1
Contrast Ratio, 3-mil film: 0.966
Pounds
252.1
4.0
2.3
10.5
2.0
2.2
1 .o
34.5
1.9
225.0
25.0
25.0
175.0
408.3
17.8
2.2
1.9
Gal 1 ons
30.27
0.36
0.25
1 .oo
0.10
0.25
0.13
4.00
0.25
6.54
0.54
1.07
7.37
45.12
2.25
0.25
0.25
SOURCE: Ucar Emulsion Systems: Formulation Suggestion E-19928
92 Water-Based Paint Formulations
Q u a l i t y White E x t e r i o r Trim P a i n t
I n a r e d i e n t s :
Pigment Grind:
Water
Ucar Polyphobe 9831 Rheology Modi f ie r
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
Propylene Glycol
Nuosept 95
Tamol 1124
Col l o i d 643
T r i t o n Nonionic S u r f a c t a n t N-57
Tronox CR-828
Polygloss 90
Pounds
98.5
5.0
1.8
59.6
2.3
7.3
1.9
2.1
246.3
24.6
Letdown :
Water
Ucar Polyphobe 9831 Rheology M o d i f i e r )
Water ) Premix
B u t y l C a r b i t o l Solvent
Ucar Latex 626
Col l o i d 643
Troysan Polyphase AF-1
T r i t o n A n i o n i c S u r f a c t a n t GR-7M
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
16.7
5.8
44.7
30.7
496.7
2.8
7.2
1.1
0 . 9
Gallons
11.79
0.60
0.20
6.90
0.30
0.69
0.30
0.30
7.39
1.18
1.99
0.69
5.38
3.04
57.08
0.39
0.79
0.10
0.10
P a i n t P r o p e r t i e s :
Pigment Volume Concentration, %: 24.2
Volume S o l i d s , %: 35.0
Weight S o l i d s , %: 49.7
Weight per Gallon, l b : 10.56
Stormer, KU: 95
I C I , Poise: 1.4
pH Value: 8.9
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Age S t a b i l i t y , 12OF. weeks passed: 2
F i l m P r o p e r t i e s :
Gloss, 60: 71
Gloss, 20: 26
Color Acceptance: E x c e l l e n t
Flow and Leveling: E x c e l l e n t
Wet Adhesion, 24-hr d r y : E x c e l l e n t
SOURCE: Ucar Emulsion Systems: Ucar Polyphobe Q83l Rheology
M o d i f i e r : Formulation Suggestion E-2484
I n g r e d i e n t s :
Pigment Grind:
Water
Ucar Polyphobe
Ammoni um Hydrox
Propylene G1yco
Nuosept 95
Tamol 1124
Col l o id 643
T r i t o n Nonionic
Tronox CR-828
Polygloss 90
Letdown :
Water
Exterior Paints and Related Products 93
Q u a l i t y White E x t e r i o r Trim P a i n t
02 Rheology Modi f ie r
de, 28% Aqueous Solut
S u r f a c t a n t N-57
on
Ucar Polyphobe 102 Rheology Modi f ie r ) Premi x
Water 1
B u t y l Carbi t o 1 Sol vent
Ucar Filmer IBT
Ucar Latex 626
C o l l o i d 643
Troysan Polyphase AF-1
T r i t o n Anionic S u r f a c t a n t GR-7M
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
P a i n t Properties:
Pigment Volume Concentration, %: 24.2
Volume Solids, %: 35.0
Weight Solids, %: 49.7
Weight per Gallon, l b : 10.56
Stormer, KU: 90-95
I C I , Poise: 1.4
pH Value: 8.9
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Age S t a b i l i t y , 12OF, weeks passed: 2
F i l m P r o p e r t i e s :
Gloss, 60: 62
Gloss, 20: 15
Color Acceptance: E x c e l l e n t
Flow and Leveling: Excel l e n t
Wet Adhesion, 24-hr d r y : E x c e l l e n t
Pounds Gal 1ons
98.5 11.79
10.7 1.28
1.8 0.20
59.6 6.90
2.3 0.30
7.3 0.69
1.9 0.30
2.1 0.30
246.3 7.39
24.6 1.18
8 . 2 0.98
8.6 1.02
44.7 5.38
20.5 2.56
10.2 1.28
496.7 57.08
2.8 0.39
7.2 0.79
1.1 0.10
0.9 0.10
SOURCE: Ucar Emulsion Systems: Formulation Suggestion E-2458
94 Water-Based Paint Formulations
Q u a l i t y White House P a i n t w i t h ZnO
I n q r e d ients:
Pigment G r i nd:
Water
C e l l o s i z e Hydroxyethyl C e l l u l o s e ER-30,000
Nuosept 95
Propylene Glycol
Col l o i d 226/35
Potassium Tripolyphosphate (KTPP)
T r i t o n Nonionic Surfactant N-101
Col l o i d 653
T i -Pure R-902
XX503R
Nytal 300
Minex 4
Pounds
295.6
4.0
2.3
25.9
10.3
1 .o
2.2
1.9
225.0
25.0
100.0
96.4
Letdown :
Ucar Latex 624 364.2
Ucar Filmer I8T 9.1
Skane M8 2.2
C o l l o i d 653 2.8
Ammoni um Hydroxi de, 28% Aqueous Sol u t ion 2.0
Paint Properties:
Pigment Volume Concentration, %: 45.0
Volume Solids, %: 35.4
V i s c o s i t y , equi 1ibrated:
Stormer, KU: 82
I C I , poise: 0.85
Weight per Gallon, l b : 11.70
Freeze-thaw S t a b i l i t y , 3 cycles: Pass
Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass
F i 1m Propert ies :
Contrast Ratio, 6-mil wet drawdown: 0.951
Reflectance, %: 91 . 1
Sheen, 85: 4.0
Flow and Leveling, brushed: Good
Wet Adhesion: E x c e l l e n t
Gal l o n s
35.49
0.36
0.25
3.00
1 .oo
0.05
0.25
0.25
6.75
0.54
4.21
4.44
41.39
1 .I5
0.25
0.37
0.25
SOURCE: Ucar Emulsion Systems: Ucar Latex 624: Formulation
Suggestion E-2426
Exterior Paints and Related Products 95
Urethane F o r t i f i e d Porch & Deck Enamel
M a t e r i a1 :
A r o l o n 840-W-39
Water
C o l l o i d 679
Cel l o s i ze QP4400
Ammonium Hydroxide
D i sperse-Ayd W28
Kroma Red RO 7097
T i t a n o x 2101
Durami t e
Lbs.
130.5
5 0 . 0
1 . 9
1 . o
1 . 9
4 . 4
5 0 . 0
5 . 0
1 5 0 . 0
Gals .
15.00
6 . 0 0
0 . 2 5
0.09
0.25
0 . 5 0
1.23
0 . 1 5
6 . 6 1
Add t h e above i n o r d e r under good a g i t a t i o n , t h e n pebble o r sand
m i l l g r i n d t o 7 Hegman.
Letdown :
A r o l o n 840-W-39
Spensol L51
Ucar SCTI 00
u s I Gals_
304.5 35.00
304.1 34.75
2 . 3 0 . 2 5
A n a l y s i s :
Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 22.0
Pigment/Binder R a t i o : 0 . 8 / 1 . O
Percent S o l i d s , Weight: 46.9
Percent S o l i d s , Volume: 36.4
V i s c o s i t y (a 25C, KU: 85-95
Pounds/Gal l o n : I O . 1
VOC ( e x c l u d i n g w a t e r ) :
Grams/Li t e r : 150
Pounds/Gallon: 1 . 3
pH: 8 . 5 + - 0 . 3
SOURCE: R e i c h h o l d Chemicals, I n c . : Spensol L: Formula 2262-80
96 Water-Based Paint Formulations
Weather B a r r i e r Formulat-
I l r p d E n t s :
Pigment G r i n d :
Water
C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-52M
D i s p e r s a n t ( 1 )
P o t a s s i um T r i p o l y p h o s p h a t e (KTPP)
E t h y l e n e G l y c o l
W e t t i n g Agent ( 2 )
A n t i f o a m ( 3 )
T i t a n i u m D i o x i d e ( 4 )
C a l c i um Carbonate ( 5 )
Z i n c Oxide ( 6 )
M i l d e w c i d e ( 7 )
Pounds
143.3
4.0
8 . 0
2.0
20.0
1 . 2
1 . 5
1 0 3 . 0
385.0
40.6
5 . 0
Letdown :
Ucar L a t e x 123 496.6
Ucar F i lmer IBT 6 . 0
A n t i f o a m ( 3 ) 2.0
Ammonium Hydroxide, 28% Aqueous S o l u t i o n 2 . 5
Gal l o n s
17.3
0 . 3
0 . 8
2.2
0 . 2
0.2
3 . 2
1 7 . 1
0.9
0 . 5
---
5 5 . 9
0 . 8
0 . 3
0 . 3
S,uppli
( 1 )
e r s :
D i s p e r s a n t - C o l l o i d 226/35 (Rhone-Poulenc) o r e q u i v a l e n t .
W e t t i n g Agent - S u r f y n o l 104 ( A i r P r o d u c t s ) o r e q u i v a l e n t .
A n t i f o a m - C o l l o i d 643 (Rhone-Poulenc) o r e q u i v a l e n t .
T i t a n i u m D i o x i d e - T i - P u r e R-960 (DuPont) or e q u i v a l e n t .
Calcium Carbonate - A t o m i t e (ECC) o r e q u i v a l e n t .
( 6 ) Z i n c Oxide - Kadox 915 (Cookson) o r e q u i v a l e n t .
( 7 ) M i l d e w c i d e - Nopcocide N-96 (Henkel) o r e q u i v a l e n t .
P a i n t P r o p e r t i e s :
Pigment Volume C o n c e n t r a t i o n (PVC), %: 40
T o t a l S o l i d s , %:
by Volume: 53.8
by Weight: 6 8 . 5
Stormer V i s c o s i t y , KU: 110
F i 1m P r o p e r t i es* :
T e n s i l e :
S t r a i n Rate, i n / m i n : 2.0
S t r e s s , p s i : 108
E l o n g a t i o n , %: 1070
S t r a i n Rate, i n / m i n : 2 . 0
S t r e s s , p s i : 52
E l o n g a t i o n , %: 1650
Water Transmission a t 24 Hours, mg: 90
180 Bend a t -2OC: No C r a c k i n g
T e n s i l e a f t e r 24-hour Water immersion:
Water Pondi ng:
Low Temperature F l e x i b i l i t y :
* D r i e d and C o n d i t i o n e d 7 Days a t 72F (22C) and 50% RH
SOURCE: Ucar Emulsion Systems: Ucar L a t e x 123: F o r m u l a t i o n WB-120
Exterior Paints and Related Products 97
White E x t e r i o r F l a t House P a i n t w i t h Z i n c Oxide
Pounds GallonsI n q r e d ients: _ _ _ ~
Pigment Grind:
Water 249.1 29.90
C e l l o s i z e Hydroxyethyl C e l l u l o s e ER-30,000 4.0 0.40
Nuosept 95 2.3 0.25
Propylene G1ycol 25.9 2.98
Tamol 850 4.0 0.40
T r i t o n Nonionic Surfactant N-101 2.1 0.24
C o l l o i d 640 1.9 0.25
T i -Pure R-706 200.0 5.90
Minspar 4 100.0 4.63
Nytal 300 75.0 3.16
Letdown :
Water 75.0 9.00
Ucar Latex 353 251 .O 27.50
Ucar Latex 6390 88.7 10.08
Ucar Filmer IBT 23.8 3.01
Col l o i d 640 3.8 0.51
Ammonium Hydroxide, 28% Aqueous S o l u t i o n 3.0 0.40
Potassium Tripolyphosphate (KTPP) 2.0 0.20
Eagle 417W 50.0 1.11
P a i n t Properties:
PVC, %: 41 .1
Volume Solids, %: 36.0
Weight Solids, %: 59.6
Weight per Gallon, l b : 11.61
Stormer, KU: 93
I C I , poise: 0.9
pH, i n i t i a l : 9.4
Freeze-thaw S t a b i l i t y , 5 cycles: Pass
Heat-Aged S t a b i l i t y :
1 week a t 140F: Pass
2 weeks a t 120F: Pass
R o l l e r S t a b i l i t y , 1 week*: Pass
F i 1m Properti es :
Reflectance, %: 88.2
Contrast Ratio, 3-mil f i l m : 0.951
Wet Adhesion, 24-hr., cycles: >2000
Chalk Adhesion:
Dry: Exc
Wet: Exc
Acceptance: Exc
Development : Exc
F l o a t : Exc
Color*:
*Tinted w i t h 2% by weight phthalo b l u e (Huls 888-7124)
SOURCE: Ucar Emulsion Systems: Ucar Latex 353: Formulation
Suggestion E-1519
98 Water-Bared Paint Formulations
White E x t e r i o r F l a t House P a i n t w i t h Zinc Oxide
I n g r e d i e n t s :
P igrnent O r ind:
Cel l o s i ze Hydroxyethyl C e l l u l o s e QP-4400
Water
Propylene Glycol
Tamol 960
Potassi urn Tripolyphosphate (KTPP)
T r i t o n Nonionic S u r f a c t a n t CF-10
Col l o i d 643
T i -Pure R-902
Eagle 417W
Minex 4
Optiwhi t e
A t t a g e l 50
AMP-95
Pounds
123.1
98.1
59.0
7.1
1.5
2.5
1.o
1.o
225.0
25.0
145.0
50.0
5.0
Letdown :
NeoCar Latex 6035 378.0
Ucar F i l m e r IBT 20.0
Skane M-8 1 .o
C o l l o i d 643 1 . 5
Ammonium Hydroxide, 28% Aqueous S o l u t i o n 2.0
Cel l o s i z e Hydroxyethyl C e l l u l o s e QP-4400 43.0
Pai n t Propert ies :
PVC, %: 45.0
Volume S o l i d s , %: 37.0
Weight S o l i d s , %: 54.7
Weight per Gallon, l b : 11.7
Stormer, KU: 97
ICI, poise: 0.8-1.0
pH Value: 8.5-9.0
Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass
F i l m P r o p e r t i e s :
Reflectance, %: 89.7
Gloss, 60: 3
Sheen, 85: 4
Contrast Ratio, 3-mil f i l m : 0.969
ASTM Scrub Cycles, w i t h shim F a i l u r e : >lo00
Chalk Adhesion: Exc
Gal 1ons
14.78
11.78
6.86
0.72
0.15
0.28
0.14
0.13
6.76
0.54
6.68
2.73
0.25
41.77
2.53
0.12
0.21
0.24
5.16
SOURCE: Ucar Emulsion Systems: NeoCar Polymers: Formulation
Suggestion E-2272
Exterior Paints and Related Products 99
White R o o f C o a t i n g
M a t e r i a1 :
Water
Ammonia (28%)
Potassium T r i p o l y p h o s p h a t e
AZO-33 Z i n c Oxide
Durami t e
T i t a n o x 2160
Bubble Breaker 3295
Bubble Breaker 776-P
Methocel 312MS
Texanol
Disperse under h i g h shear f o r 10-15 minutes.
Add letdown:
A r o l o n 820-W-49
A n a l y s i s :
PMA-100
Pigment Volume C o n c e n t r a t i o n , Percent: 47.5
Pigment/Binder R a t i o : 2.26/1
Percent S o l i d s , Weight: 63.18
Percent S o l i d s , Volume: 47.33
V i s c o s i t y @ 25C, KU: 80-90
Gloss: F l a t
Pounds/Gallon: 11.91
VOC ( e x c l u d i n g w a t e r ) :
Grams/Liter: 64.0
Pounds/Gallon: 0.53
pH: 8.8-9.2
Lbs. Gals.
172.60 20.72
1 .80 0 . 0 9
0.90 0.12
1.92 0.09
22.83 0.49
466.65 20.74
24.31 0.73
3.30 0.44
3.30 0.44
4.14 0.36
17.93 2.27
470.89 53.51
SOURCE: R e i c h h o l d Chemicals, I n c . : A r o l o n 820: Formula 2185-40A
Interior Paints and Related Products 101
Clear High Gloss Varnish
M a t e r i a l :
Spensol L51
Ammonium Hydroxide
Surfynol 104H
Byk 321
C o l l o i d 679
Arolon 840-W-39
M icheml ube 02925
Lodyne S107B
Lbs. Gals.
651.9 74.50
1.9 0.25
4.0 0.50
1.9 0.25
I .9 0.25
167.5 19.25
31 .1 3.75
1.o 0.10
Add t h e above m a t e r i a l s i n order under good a g i t a t i o n , then add
t h e f o l l o w i n g c u r i n g agent j u s t p r i o r t o use and m i x w e l l f o r
a t l e a s t 10 minutes.
XAMA- 7 11.4 1.15
Analysis:
Percent Sol i d s , Weight : 30.9
Percent Solids, Volume: 28.0
V i s c o s i t y @ 25C #2 Zahn, Secs.: 20
Gloss (60): 100+
Pounds/Gallon: 8.7
VOC (excluding water): Grams/Liter: 290
pH: 8.5+-0.3
Pounds/Gallon: 2 . 4
Formulation 2307-22A
Fast-Dry Sealer
Materi a1 :
Spensol L51
Premix and add:
Water
Ammoni um Hydroxi de
Add i n f o l l o w i n g order w i t h a g i t a t i o n :
Arolon 840-W-39
Surfynol 104H
Lodyne SI07
Analysis:
R a t i o of Spensol L51 t o Arolon 840: 75:25
Percent Solids, Weight: 32.1
Percent Solids, Volume: 29.5
V i s c o s i t y @ 25C, #2 Zahn, Secs.: 23t-4
Pounds/Gallon: 8.73
VOC (excluding water): Grams/Liter: 286
pH: Bt-0.5
Pounds/Gallon: 2.4
Forrnul a t i o n 2061-91A
Lbs. Gal s .
687.2 78.63
1.4 0.17
0.4 0.06
176.2 20.25
5.2 0.66
2 . 2 0.23
S0URCE:Reichhold Chemicals, I n c . : Spensol L51: Formulations
102 Water-Based Paint Formulations
Economv F l a t W a l l P a i n t
I n q r e d i e n t s :
P i gment G r i nd :
Water
C e l l o s i z e Hydroxyethyl C e l l u l o s e ER-30,000
Nuosept 95
Tamol 731
T r i t o n N o n i o n i c S u r f a c t a n t N-101
T e r g i t o l N o n i o n i c S u r f a c t a n t NP-40
Propylene G1y c o l
Drewplus L-475
Tronox CR-813
ASP NC2
No. 1 White
C e l i t e 281
Letdown:
Water
Ucar Latex 353
Ucar F i l m e r IBT
Drewpl us L-475
P a i n t P r o p e r t i e s :
PVC, %: 70.0
Volume S o l i d s , %: 29.8
Weight S o l i d s , %: 50.2
Weight p e r G a l l o n , l b : 11.32
Stormer, KU: 9 4
I C I , p o i s e : 0.9
pH, i n i t i a l : 8 . 3
Freeze-thaw S t a b i l i t y , 5 c y c l e s : Pass
Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass
AMP-95
Pounds
484.5
6.0
2.3
4.6
2.2
2.2
1 .o
13.0
1.o
75.0
200.0
150.0
25.0
Gal l o n s
58.16
0.55
0.25
0.50
0.25
0.25
0.13
I .50
0.13
2.34
9.30
6.65
1.30
30.2 3.63
125.4 13.78
8.1 1.03
1 . 9 0.25
F i l m P r o p e r t i e s :
R e f l e c t a n c e , %: 91.2
Sheen, 85: 1 . 1
C o n t r a s t R a t i o , 3-mil f i l m : 0.959
ASTM Scrub Cycles, w i t h shim f a i l u r e , 10%: 102
C o l o r * :
Acceptance: Exc
Development: Exc
* T i n t e d w i t h 2% b y w e i g h t p h t h a l o b l u e ( H u l s 888-7214) o r
r e d i r o n o x i d e ( H u l s 888-1045).
SOURCE: Ucar Emulsion Systems: Ucar L a t e x 353: F o r m u l a t i o n
Suggestion 1-2469
Interior Paints and Related Products 103
Economy F l a t Wall P a i n t
I n g r e d i e n t s :
Pigment G r i n d :
Water
Cel l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-30,000
Nuosept 95
Tamol 731
T r i t o n N o n i o n i c S u r f a c t a n t N-101
T e r g i t o l N o n i o n i c S u r f a c t a n t NP-40
AMP-95
Propylene G l y c o l
Drewplus L-475
Tronox CR-813
ASP NC2
No. 1 White
C e l i t e 281
Letdown:
Water
Ucar Latex 353
Ucar F i l m e r IBT
Orewplus L-475
P a i n t P r o p e r t i e s :
PVC, %: 70.0
Volume S o l i d s , %: 29.8
Weight S o l i d s , %: 50.2
Weight p e r G a l l o n , l b : 11.32
Stormer, KU: 94
I C I . o o i s e : 0 . 9
Pounds
484.5
6.0
2.3
4.6
2.2
2 . 2
1 .o
13.0
1 .o
75.0
200.0
150.0
25.0
30.2
125.4
8 . 1
1.9
Gal l o n s
58.16
0 . 5 5
0.25
0.50
0.25
0.25
0.13
1.50
0.13
2.34
9.30
6.65
1.30
3.63
13.78
1.03
0.25
. .
pH, i n i t i a l : 8 . 3
Freeze-thaw S t a b i l i t y , 5 c y c l e s : Pass
Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass
F i 1m P r o p e r t ies :
R e f l e c t a n c e , %: 91.2
Sheen, 85: 1 . 1
C o n t r a s t R a t i o , 3-mil f i l m : 0.959
ASTM Scrub Cycles, w i t h shim f a i l u r e , 10%: 102
C o l o r * :
Acceptance: Exc
Development : Exc
* T i n t e d w i t h 2% b y weight p h t h a l o b l u e ( H u l s 888-7214) o r
r e d i r o n o x i d e ( H u l s 888-1045).
SOURCE: Ucar Emulsion Systems: Ucar Latex 353: F o r m u l a t i o n
Suggestion 1-2460
104 Water-Based Paint Formulations
Good Q u a l i t y I n t e r i o r F l a t w i t h <50g/L VOC
I n q r e d ie n t s :
P i gment G r i nd :
Water
Propylene Glycol
Proxel GXL
Col l o i d 226/35
T r i t o n Nonionic S u r f a c t a n t N-101
Drewplus L-475
Ucar Polyphobe 102 Rheology M o d i f i e r
Sodium Hydroxide (50% S o l u t i o n )
T i -Pure R-902
Snowf 1ake
Minex 4
Letdown :
Ucar Latex 3796
Ucar F i l m e r IBT
Drewplus L-475
Ucar Polyphobe 102 Rheology M o d i f i e r
Water
Pounds
358.0
10.0
0.5
6.0
2.2
4.0
15.0
2.5
200.0
175.0
175.0
200.0
3.0
4.0
17.3
50.0
Gal 1ons
43.00
1.16
0.05
0.59
0.25
0.52
1.72
0.19
6.00
7.75
8.05
22.10
0.38
0.52
1.98
6.01
P a i n t P r o p e r t i e s :
PVC, %: 63.1
Volume Solids, %: 34.5
Weight S o l i d s , %: 55.1
Weight per Gallon, l b : 12.18
Stormer, KU: 87
I C I , p o i s e : 2.1
pH, i n i t i a l : 9.2
Freeze-Thaw Stabi 1it y , 1 c y c l e : Pass
Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass
V o l a t i l e Organic Content, g/L: 45.6
F i 1m Properties :
Ref 1ectance, %: 90.0
Sheen, 85: 2
Contrast Ratio, 3-mil f i l m : * 0.961
ASTM Scrub Cycles, w i t h shim F a i l u r e : 330
C o l o r : *
Acceptance: Excel l e n t
Development: E x c e l l e n t
Low Temperature Coalescence I O - m i l drawdown a t 40F: Pass
Mudcracki ng, 30-mi 1 on sheetrock: Pass
* T i n t e d w i t h 2% by weight p h t h a l o b l u e (Huls 888-7214)
o r r e d i r o n o x i d e (Huls 888-1045).
SOURCE: Ucar Emulsion Systems: Formulation Suggestion I-2230A
Interior Paints and Related Products 105
Hiah-Quality Super F l a t I n t e r i o r P a i n t
I n g r e d i e n t s :
P i Qment Grind:
Water
Propylene G1y c o l
Proxel GXL
Col 1o i d 226/35
T r i t o n Nonionic S u r f a c t a n t N-10
C o l l o i d 640
Ucar Polyphobe 102 Rheology Mod
T i -Pure R-902
Snowf 1ake 960
Minex 4
Letdown :
Ucar Latex 3796
Ucar Filmer IBT
C o l l o i d 640
AMP-95
f i e r
Ucar Pol yphobe 102 Rheology Modi f ie r
Water
Pounds
150.0
25.9
0.5
8.0
2.2
3.5
15.0
5.0
250.0
125.0
125.0
Gal l o n s
18.02
3.00
0.05
0.78
0.25
0.47
1.72
0.63
7.51
5.54
5.76
419.8 46.64
16.8 2.11
3.5 0.50
7.5 0.86
51.3 6.16
Pai n t P r o p e r t i es :
PVC, %: 43.3
Volume S o l i d s , %: 43.4
Weight S o l i d s , %: 61.0
Weight per Gallon, l b : 12.09
Stormer. KU: 90
I C I , poise: 2.0
pH, i n i t i a l : 9.2
Freeze-Thaw S t a b i l i t y , 3 cycles: Pass
Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass
F i 1m Properties :
Reflectance, %: 92.5
Sheen, 85: 7
Contrast Ratio, 3-mil f i l m * : 0.962
ASTM Scrub Cycles, w i t h shim F a i l u r e : >2000
Color*:
Acceptance: Excel 1ent
Development : Excel 1ent
*Tinted w i t h 2% by weight phthalo b l u e (Huls 888-7214) or
red i r o n oxide (Huls 888-1045).
SOURCE: Ucar Emulsion Systems: Formulation Suggestion I-2227A
106 Water-Based Paint Formulations
I n t e r i o r Clear Wood F i n i s h
(RhoDlex CL-l04/Sancure 8151
B1end :
Rhopl ex CL-104 (38.5%)
Sancure 815 (35.0%)
Surfynol DF-62
Surfynol 104PG-50
Mix above f o r 10 minutes before adding t h e f o l l o w i n g :
Hexyl Carbi to1
Propylene Glycol
Acrysol RM-1020
Water
Michem 39235
Aqueous Ammonia ( 14%)
Formulation B (Rohm and Haas)
I n t e r i o r Sandina Sealer
(RhoDlex CL-1051
E lend :
Rhopl ex CL-105 (37.0%)
Surfynol DF-62
Water
Aqueous Ammonia (14%)
Mix above f o r 10 minutes before adding t h e f o l l o w i n g :
Propasol B
Hexyl Carbi to1
Acrysol RM-2020
Water
Aqueous Ammonia (7%)
Surfynol 104DPM
Formulation C (Rohm & Haas)
Pounds
540.0
148.5
1.4
3.0
20.8
30.0
18.0
66.0
22.3
2.5
Pounds
709.3
1.3
32.9
8.0
45.2
22.3
4.1
30.8
2.6
3.0
Surfynol a d d i t i v e s have been shown t o provide t h e f o l l o w i n g
benef it s :
*Color u n i f o r m i t y o f s t a i n s
*Early s t a i n 1appi ng resistance
*Consistent wetting, f l o w and l e v e l i n g on various woods
*Foam c o n t r o l
*Topcoat r e c o a t a b i l i t y and i n t e r c o a t adhesion
*Gloss r e t e n t i o n upon aging
*Tannin bleed r e s i stance
*Water s e n s i t i v i t y
*Chemical resistance
Formulas
With no detrimental e f f e c t upon:
SOURCE: A i r Products 8, Chemicals, Inc.: Surfynol Surfactants:
Interior Paints and Related Products 107
I n t e r i o r Contractor F l a t
I n g r e d i e n t s :
Pigment Grind
Water
Propylene G1ycol
Tamol 1124
T r i t o n Nonionic Surfactant X-405
C o l l o i d 643
AMP-95
T i -Pure R-901
Optiwhite
Duramit e
C e l i t e 281
Letdown :
Ucar Latex 379G
Ucar Filmer I B T
C o l l o i d 643
Water
Ucar Polyphobe 10
Water
Paint Properties:
PVC, %: 71.4
Volume Sol i d s ,
Wei ght Sol ids,
Weight per Gal
pti, i n i t i a l : 8
Pounds
184.0
26.0
10.0
2.0
1.5
2.0
100.0
150.0
190.0
20.0
148.0
8.0
2.5
50.0
Rheology Modi f ie r 21 .o-.
217.5
%: 40.3
%: 29.4
on, l b : 11.3
5-9.0
Gal 1ons
22.09
3.02
1.01
0.23
0.21
0.25
3.33
8.20
8.41
1.04
16.35
1.01
0.34
6.00
2.41
26.11
Ucar Polyphobe 107:
NVM lb/100 g a l : 5.3
Stormer, KU: 90/98
I C I , poise: 0.7
Scrub Cycles: 140
SOURCE: Ucar Emulsion Systems: Formulation Suggestion I-2231A
108 Water-Based Paint Formulations
I n t e r i o r Good Quality F l a t
f o r R o l l e r and Brush A p p l i c a t i o n
I n Q r e d ients:
Pigment Grind:
Water
Propylene G1ycol
Tamol 1124
T r i t o n Nonionic Surfactant X-405
Col l o i d 643
AMP-95
T i -Pure R-901
Opt iwhi t e
Durami t e
Letdown :
Ucar Latex 379
Ucar Filmer IBT
C o l l o i d 643
Water
Ucar Polyphobe 103 Rheology M o d i f i e r
Water
Paint Properties:
Pigment Volume Concentration, %: 58.0
Volume Solids, %: 34.4
Weight Solids, %: 51.9
Weight per Gallon, l b : 11.3
pH, i n i t i a l : 8.5-9.0
Thickener Comparison:
Ucar Polyphobe 103:
NVM lb/100 g a l : 5 . 7
Stormer, KU: 91/98
I C I , P: 1.5
Scrub Cycles: 1102
Flow/Leveling: Excellent
50-mi 1 Mudcrack: Pass
R o l l er/Spatter : M i n i mal
NVM lb/110 g a l : 7.0
Stormer, KU: 86/96
I C I , P: 1.8
Scrub Cycles: 1200
Flow/Leveling: Excel l e n t
50-mi 1 Mudcrack: Pass
R o l l er/Spatter : M i n i mal
Ucar Polyphobe 102/104 blend:
NVM lb/100 g a l : 3.7/2.3
Stormer. KU: 95/101
Ucar Polyphobe 102:
~I ~ ~I ~
I C I , P: 1.4
Scrub Cycles: 1200
Pounds
184.0
26.0
9.0
2.0
1.5
2.0
100.0
150.0
190.0
254.0
16.0
2.5
50.0
22.8
119.2
Flow/Leveling: Good
50-mi 1 Mudcrack: Pass
R o l l er/Spatter : M i n i mal
SOURCE: Ucar Emulsion Systems: Formulation Suggestion
Gal 1ons
22.09
3.02
0.91
0.23
0.21
0.25
3.33
8.20
8.41
28.07
2.03
0.34
6.00
2.62
14.31
1-2232
Interior Paints and Related Products 109
I n t e r i o r Good Q u a l i t y F l a t
f o r R o l l e r and Brush A p p l i c a t i o n
I n g r e d i e n t s :
Pigment Grind:
Water
Propylene Glycol
Tamol 1124
T r i t o n Nonionic Surfactant X-405
C o l l o i d 643
Ti-Pure R-901
Opt iwhi t e
Durami t e
Letdown :
Ucar Latex 379
Ucar F i l m e r I B T
C o l l o i d 643
Water
Ucar Polyphobe 9831 Rheology M o d i f i e r
Water
AMP-95
Pounds
184.0
26.0
9.0
2.0
1.5
2.0
100.0
150.0
190.0
254.0
16.0
2 . 5
60.3
12.5
119.2
Gal 1ons
22.09
3.02
0.91
0.23
0.21
0.25
3.33
8.20
8.41
20.07
2.03
0.34
7.20
1.40
14.31
P a i n t P r o p e r t i e s :
Pigment Volume Concentration, %: 58.0
Volume S o l i d s , %: 34.4
Weight S o l i d s , %: 51.9
Weight per Gallon, l b : 11.3
Stormer, KU: 95
I C I , Poise: 1.6
pH Value: 8.5-9.0
V o l a t i l e Organic Content, g/L: 139
Sheen, 85: 1.8
Flow and Leveling: Good
Sag Resistance, m i l s : 7
F i l m P r o p e r t i e s :
SOURCE: Ucar Emulsion Systems: Ucar Polyphobe 9831 Rheology
M o d i f i e r : Formulation Suggestion 1-2240
110 Water-Based Faint Formulations
I n t e r i o r Good Q u a l i t y F l a t
I n g r e d i e n t s :
Pi gment G r i nd :
Water
Propylene G1ycol
Proxel GXL
Tamol 1124
T r i t o n Nonionic Surfactant X-405
C o l l o i d 643
T i -Pure R-901
O p t i whi t e
Ourami t e
Letdown :
Ucar Latex 3796
Ucar Filmer IBT
Col l o i d 643
Water
Ucar Polyphobe 103 Rheology Modi f ier
Water
Paint Properties:
PVC, %: 58.0
Volume Solids, %: 34.4
Weight Solids, %: 51.9
Weight per Gallon, l b : 11.3
pH, i n i t i a l : 8.5-9.0
AMP-95
Thickener Comparison:
Ucar
NVM, lb/100 gal
Stormer, KU
I C I , p o i s e
Scrub Cycles
Flow/Level ing
50-mi 1 Mudcracki ng
Pounds
184.0
26.0
0.5
9.0
2.0
1.5
2.0
100.0
150.0
190.0
254.0
16.0
2.5
50.0
22.8
119.2
Polyphobe Ucar
02
7.0
Gal 1ons
22.09
3.02
0.05
0.91
0.23
0.21
0.25
3.33
8.20
8.41
28.07
2.03
0.34
6.00
2.62
14.31
Polyphobe
03
5.7
86/96
1.8
1200
Exc
Pass
91/98
1.5
1102
Exc
Pass
SOURCE: Ucar Emulsion Systems: Formulation Suggestion I-2232A
Interior Paints and Related Products 111
I n t e r i o r Semigloss Formulation
I n g r e d i e n t s :
Pigment G r i nd:
Water
Ucar Polyphobe 102 Rheology M o d i f i e r
Ammoni um Hydroxi de, 28% Aqueous Sol u t i on
Propylene G1ycol
Proxel GXL
Tamol 1124
Col l o i d 643
T r i t o n Nonionic Surfactant N-57
Tronox CR-828
Burgess No. 98
Letdown :
Water
Ucar Polyphobe 102 Rheology M o d i f i e r
B u t y l C a r b i t o l Solvent
Ucar Filmer IBT
Ucar Latex 379G
Ucar Latex 6030
C o l l o i d 643
Byk 346
Ammoni um Hydroxide, 28% Aqueous Sol u t i on
Pounds
125.0
19.6
1.8
43.2
2.3
7.3
1.9
2.1
250.0
19.7
24.8
2.2
23.8
11.9
346.8
184.0
2.8
1.1
1.8
Gal 1ons
15.0
2.3
0.3
5.0
0.2
0.7
0.3
0.2
7.3
0.9
3.0
0.3
3.0
1.5
38.3
20.9
0.4
0.1
0 . 3
P a i n t Properties:
Pigment Volume Concentration, %: 22.5
Volume Solids, 96: 36.4
Weight per Gallon, l b : 10.7
Stormer, KU: 83
I C I , Poise: 1.9
pH Value: 8.7
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Age S t a b i l i t y , 120F. weeks passed: 2
R a t i o o f Ucar Latexes 379:6030: 70:30
F i l m Properties:
Gloss, 60: 64
Gloss, 20: 18
Contrast Ratio, 6-mil wet drawdown: 0.972
Reflectance, %: 91.9
Block Resistance: 9
Flow and Leveling: Good
Low Temperature Coalescence: 10
Washability, s t a i n removal*: 10
(crayon, f e l t pen, l i p s t i c k , p e n c i l )
% gloss retained: 92
*Washed w i t h Fantastik; lO=complete s t a i n removal
Wet Adhesion, gloss alkyd: Exc
SOURCE : Ucar Emulsion Systems:
1-2473
Ucar Latex 0030: Formulation
112 Water-Based Pain? Formidations
_ _ _ ~I n t e r i o r V i n y l A c r y l i c Eggshell
f o r R o l l e r and Brush A p p l i c a t i o n
I n q r e d ie n t s :
Pigment Grind:
Water
Propylene G1ycol
Tamol 1124
T r i t o n Nonionic S u r f a c t a n t X-100
C o l l o i d 643
Proxel GXL
T i -Pure R-900
Omyacarb UF
AMP-95
ASP-1 70
Letdown :
Ucar Latex 379
Ucar F i l m e r IBT
Col l o i d 643
Ucar Polyphobe 9831 Rheology M o d i f i e r
Water
P a i n t P r o p e r t i e s :
AMP-95
Pigment Volume Concentration, %: 36.4
Volume S o l i d s , %: 37.4
Weight S o l i d s , %: 54.4
Weight per Gallon, l b : 11.3
Stormer, KU: 95
I C I , Poise: 1 . 2
pH Value: 8.5-9.0
V o l a t i l e Organic Content, g/L: 121
F i l m P r o p e r t i e s :
Gloss, 60: 35
Flow and Leveling: Good
Sag Resistance, m i l s : 12
Pounds
100.0
26.0
8.0
2.0
1.5
1.5
2.0
230.0
100.0
50.0
420.0
12.0
2.5
2.0
11.o
168.0
Gallons
12.00
3.02
0.81
0.23
0.21
0.15
0.25
6.91
4.42
2.33
46.41
1.52
0.34
0.25
1.27
20.07
SOURCE: Ucar Emulsion Systems: Ucar Polyphobe 9831 Rheology
Modi f ie r : Formulation Suggestion 1-2241
I n t e r i o r V i n y l A c r y l ic Eqashel1
f o r R o l l e r and Brush A p p l i c a t i o n
Ingredients:
Pigment G r i nd :
Water
Propyl ene G1ycol
Tamol 1124
T r i t o n Nonionic Surfactant
C o l l o i d 643
Proxel GXL
T i -Pure R-900
Omyacarb UF
AMP-95
ASP- 170
x-1 00
Pounds
100.0
26.0
8.0
2.0
1.5
1.5
2.0
230.0
100.0
50.0
Letdown :
Ucar Latex 379 420.0
Ucar Filmer IBT 12.0
C o l l o i d 643 2.5
AMP-95 2.0
Ucar Polyphobe 102 Rheology Modi f ie r 30.0
Water 149.0
Paint Properties:
Pigment Volume Concentration, %: 36.4
Volume Solids, %: 37.4
Weight Solids, %: 54.4
Weight per Gallon, l b : 11.3
pH, i n i t i a l : 8.5-9.0
Thickener Comparison:
Ucar Polyphobe 114:
NVM lb/100 g a l : 5.0
Stormer, KU: 93
I C I , P: 0.5
Flow/Leveling: Poor
Sag Resistance: 24+
Ucar Polyphobe 102:
NVM l b / l 0 0 g a l : 7.5
Stormer, KU: 92
I C I , P: 1.8
Flow/Level ing: Excellent
Sag Resistance: 12
Ucar Polyphobe 102/114 blend ( 4 : l ) :
NVM lb/100 aal : 4.0 l b o f Ucar Poly. 102
Storme;, KUT 97
I C I , P: 1.6
F1ow/Level ing : Very Good
Sag Resistance: 14
Gallons
12.00
3.02
0.81
0.23
0.21
0.15
0.25
6.91
4.42
2.33
46.41
1.52
0.34
0.25
3.45
17.89
Interior Paints and Related Products 113
SOURCE: Ucar Emulsion Systems: Formulation Suggestion 1-2237
114 Water-Based Paint Formulations
I n t e r i o r V i n y l A c r y l i c Semigloss
I naredients :
Pigment Grind:
Water
Polywet ND-35
T i -Pure R-902
Drewpl us L-475
Letdown :
Ucar Latex 367
Water
Ucar F i l m e r I B T
Nuosept 95
T r i t o n Nonionic S u r f a c t a n t GR-5M
Drewpl us L-475
Water ( a d j u s t according t o Polyphobe
Ucar Polyphobe 114 Rheology M o d i f i e r
AMP-95
Pounds
104.9
4.0
205.0
2.0
423.0
33.3
23.8
2.0
1.o
5.0
4.0
l e v e l ) 214.5
26.5
Gal l o n s
12.59
0.39
6.16
0.28
47.00
4.00
3.01
0.21
0.12
0.64
0.56
25.75
3.05
P a i n t P r o p e r t i e s :
Pigment Volume Concentration, %: 20.4
Volume S o l i d s , 96: 40.3
Weight Solids, %: 54.2
Weight per Gallon, l b : 10.5
Thickener Compari son :
Ucar Polyphobe 114:
NVM lb/100 g a l : 6.6
B r o o k f i e l d , 0.3, P: 680
I C I , P: 0.5
60 Gloss: 79
Ucar Polyphobe 102:
NVM lb/100 g a l : 10.7
Brookfield,-0.3, P: 186
ICI, P: 2.2
60 Gloss: 74
Ucar Polyphobe 103:
NVM lb/100 gal : 8.2
B r o o k f i e l d , 0.3, P: 336
I C I , P: 1.5
60 Gloss: 69
Ucar Polyphobe 107;
NVM lb/100 g a l : 5.1
B r o o k f i e l d , 0.3, P: 226
I C I , P: 0.7
60 Gloss: 67
NVM lb/100 g a l : 5.6
B r o o k f i e l d , 0.3, P: 2,086
I C I , P: 0.7
60 Gloss: 70
Ucar Polyphobe 106HE:
SOURCE: Ucar Emulsion Systems: Formulation Suggestion 1-2239
Interior Paints and Related Products 115
Intumescent I n t e r i o r White F ire-Retardant Paint
I ngredients :
Pigment Grind:
Water
Potassium Tripolyphosphate (KTPP)
Surfactol 365
Ucar Latex 367
C o l l o i d 677
Phos-Chek PI30
Aero Melamine (powdered grade)
D i pentaerythri t o 1 (powdered grade)
Nuosept 6351
T i -Pure R-900
Chlorez 700
Pounds
290.0
3.0
4.0
75.0
3.0
260.0
80.0
75.0
1 .o
60.0
40.0
Gal 1ons
34.8
0.3
0.4
8.2
0.3
17.3
6.8
6.4
0.1
1 .8
2.9
Letdown :
C e l l o s i z e Hydroxyethyl Cellulose QP-15,OOOH
(1.5% aqueous s o l u t i o n ) 45.0 5.2
Ucar Latex 367 145.0 16.0
C o l l o i d 677 1.o 0.1
Procedure:
t h e order l i s t e d . Completely disperse each ingredient before
adding t h e next. When t h e pigment g r i n d s l u r r y i s complete,
a g i t a t e f o r an a d d i t i o n a l f i v e minutes; t r a n s f e r t o a pebble
m i l l and g r i n d t o Hegman 3. Under a g i t a t i o n , prepare t h e f i n a l
letdown i n t h e order l i s t e d . Under a g i t a t i o n , add t h e pigment
g r i n d slowly t o t h e letdown. Note: Protect thickener s o l u t i o n s
w i t h preservative during processing and storage.
Paint Properties:
Under a g i t a t i o n , add a l l ingredients o f t h e pigment g r i n d i n
Pigment Volume Concentration, %: 74
Total Solids, % by weight: 60
Weight per Gallon, l b : 10.8
Stormer. KU: 75-80
Contrast Ratio: 0.87
SOURCE: Ucar Emulsion Systems: Ucar Latex 367: Formulation
Suggestion 1-1338
116 Water-Based Paint Formulations
Low VOC I n t e r i o r F l a t
_ _ _ _ _ _ _Pounds GallonsI n q r e d ie n t s :
Pigment Grind:
Water
Kathon LX
Tamol 1124
T r i t o n Nonionic S u r f a c t a n t N-101
Drewpl us L-475
Ucar Polyphobe 102 Rheology M o d i f i e r
Sodi um Hydroxide
Ti-Pure R-902
Duramit e
Iceberg
Water
Letdown :
Ucar Latex 379
Water
Drewplus L-475
Ucar F i l m e r IBT
Ucar Polyphobe 102 Rheology M o d i f i e r
P a i n t P r o p e r t i e s :
Pigment Volume Concentration, %: 64.9
Volume S o l i d s , %: 32.3
Weight S o l i d s , %: 53.1
Weight per Gallon, l b : 12.1
Stormer, KU: 92
VOC, grams per l i t e r : 26.09
F i l m P r o p e r t i e s :
Gloss, 60: 2
Sheen, 85: 3
Contrast R a t i o , 6-mil wet drawdown: 0.977
Reflectance, %: 91 .8
Scrub Resistance, c y c l e s passed: 161
333.3 40.00
1.7 0.20
5.1 0.52
2.0 0.23
2.0 0.26
15.0 1.73
3.0 0.15
190.0 5.70
185.0 8.21
155.0 7.07
50.0 6.00
200.7 22.18
39.4 4.73
2 . 5 0.33
7.7 0.96
15.0 1.73
SOURCE: Ucar Emulsion Systems: Formulation Suggestion 1-2238
Interior Paints and Related Products 117
-S o l v e n t Free I n t e r i o r S a t i n P a i n t
M a t e r i a l :
G r i n d :
Water
KTPP (100%)
Tamol 731 (Rohm and Haas)
T r i t o n CF-10 (Rohm and Haas)
Kathon LX 1.5% (Rohm and Haas)
FCA (Foam C o n t r o l Agent)
Ti-Pure R-900 (DuPont)
N y t a l 300 ( R . T . V a n d e r b i l t )
C a l c i um Carbonate
Letdown :
Rovace SF-091 (Rohm and Haas)
Rovaque OP-62 L O (Rohm and Haas)
FCA (Foam C o n t r o l Agent)
A c r y s o l RM-2020 (Rohm and Haas)
A c r y s o l TT-935 (Rohm and Haas)
Sodium Carbonate
Water
P r o p e r t i e s :
Pigment Volume Content, %: 37.0
% N o n v o l a t i l e (by volume): 34.0
Stormer V i s c o s i t y , K.U.: 95+-5
I C 1 V i s c o s i t y . Poise: 1.1+-2
Gloss a t 60,-%: 13.0
Recommended P r o d u c t :
A g i t a n 315: E f f i c i e n t . F i n e
A l t e r n a t i v e Products:
A g i t a n 260: E f f i c i e n t , c o s t
A g i t a n 731: E f f i c i e n t , z e r o
SOURCE: K i n g I n d u s t r i e s : Formu
!&
260.0
1.5
7.0
2.5
1 . 7
1.o
170.0
40.0
70.0
372.2
45.0
2.0
15.0
12.5
24.0
57.5
%wt
31.20
0.07
0 . 7 6
0.28
0.20
0.13
5.10
1.68
3.11
41.50
5.22
0.26
1.65
1.42
2.52
6.90
t u n i ng w i 11 p r o v i d e c o s t b e n e f i t s .
e f f e c t i v e .
voc .
a t i o n WR-39-3
118 Water-Based Paint Formulations
White I n t e r i o r Eqsshell
I n q r e d i e n t s : ~~Pounds Gal l o n s
Pigment Grind:
Water 226.7 27.21
Ucar Polyphobe 9831 Rheology M o d i f i e r 8.5 0.97
Nuosept 145 2.3 0.25
Tamol 731A
T r i t o n Nonionic Surfactant N-57
AMP-95
Propylene Glycol
Col l o i d 640
Tronox CR-800
Opt iwh it e
Burgess No. 98
Letdown :
AMP-95
Ucar Filmer IBT
Water
Ucar Latex 353
Col l o i d 640
P a i n t Properties:
PVC, %: 35.8
Volume Solids, %: 38.2
Weight Solids, %: 52.4
Weight per Gallon, l b : 11.04
Stormer, KU: 95
I C I , poise: 1.4
pH, i n i t i a l : 9.0
Freeze-thaw S t a b i l i t y , 5 cyc
Heat-Aged S t a b i l i t y , 2 weeks
F l m Properties:
Reflectance, %: 91.4
Gloss, 60: 6.3
Sheen, 85: 22.6
Contrast Ratio, 3-mil f i l m : .969
Color*:
Acceptance : Exc
Development: Exc
*Tinted w i t h 2% by weight phthalo
i r o n oxide (Huls 888-1045).
11.5 1.25
2.3 0.25
2.0 0.26
51.8 6.00
1.9 0.25
225.0 6.54
100.0 5.46
25.0 1.15
2.0 0.27
22.5 2.85
78.7 9.45
341 .O 37.47
2.8 0.37
es: Pass
a t 120F: Pass
SOURCE: Ucar Emulsion Systems: Formu
b l u e (Huls 888-7124) o r red
a t i o n Suggestion 1-1520
120 Water-Based Paint Formulations
Green Lacquer
I n s r e d i e n t s :
P i ament G r i nd :
Water
Ethylene Glycol
Dispersant ( 1)
T e r g i t o l Surfactant NP-10
Antifoam (2)
Phthalo Green (3)
Medium Chrome Yellow ( 4 )
Let Down:
Ucar Vehicle 443
B u t y l C a r b i t o l Solvent
T r i butoxyethyl Phosphate
Phthalo Green (3)
Deionized Water
Pounds
45.00
0.65
6.26
0.62
1.oo
50.00
33.04
Gal l o n s
5.40
0.07
0.68
0.07
0.13
4.95
0.67
666.11 75.19
13.26 1.67
13.26 1.58
51.50 5.10
26.55 3.19
Suppl i e r s :
( 1 ) Dispersant - C o l l o i d 107 ( C o l l o i d s ) o r e q u i v a l e n t .
( 2 ) Antifoam - C o l l o i d 675 ( C o l l o i d s ) o r e q u i v a l e n t .
(3) Phthalo Green - T i nt-Ayd WD-2744 D i spersi on (Daniel
( 4 ) Medium Chrome Yellow - X-3356 C.P. Medium Y (Ciba-Geigy)
Products) o r e q u i v a l e n t .
o r e q u i v a l e n t .
Lacquer P r o p e r t i as :
by Weight: 37
by Volume: 31
Pi gment/Bi nder Ratio : 0.25/ 1
Solids, %:
pH: 8.5
V i s c o s i t y , No. 4 Ford Cup, sec: 25
SOURCE: Ucar Emulsion Systems: Ucar Vehicle 443: Formulation
Suggestion LP-3812
Lacquers 121
Foam Control w i t h Agitan A d d i t i v e s i n a
Hiah Gloss DIY Waterborne Lacquer
The choice o f coalescing agents can s i g n i f i c a n t l y i n f l u e n c e
t h e generation o f foam i n a waterborne formulation as w e l l as
a f f e c t t h e performance o f t h e foam c o n t r o l agent (FCA).
Component:
Rhoplex CL-104 (Rohm and Haas)
DC-14 (Dow Corning A d d i t i v e s )
FCA (Foam Control Agent)
Michem 39235 (Michelman)
Adjust pH t o 7-8
Aqueous Ammonia 28%
Propylene Glycol
Coalescent
Water
Adjust t o v i s c o s i t y
Water
j& %Wt
642.8 76.83
24.7 2.95
1.3 0.16
21 . e 2.61
3
24.7
37.6
29.2
51.5
0.36
2.95
4.49
3.49
6.16
Properties:
% N o n v o l a t i l e (by weight): 30.7
% N o n v o l a t i l e (by volume): 29.1
V i s c o s i t y #2 Zahn, 25C (seconds): 20-26
Theoretical VOC (pounds/gallon): 2.07
Theoretical VOC (grams/l it e r ) : 249
This study has demonstrated t h a t d i f f e r e n t coalescents can
pH, 25C: 7.5-8.0
s i g n i f i c a n t l y a f f e c t foam generation and hence t h e performance
o f t h e foam c o n t r o l agent. However, Agitan 295 performed
e q u a l l y w e l l i n both systems, regardless o f t h e coalescing
agent used.
For optimum foam prevention and f i l m p r o p e r t i e s , Agitan 305
i s recommended w i t h t h e Texanol, w h i l e Agitan 731 i s recommended
f o r t h e DPnB.
SOURCE: King I n d u s t r i e s : WR-32: FCA's f o r Waterborne Wood
Formulations
122 Water-Based Paint Formulations
White Lacauer
I n a r e d i e n t s :
Pigment G r i nd :
Ucar Vehicle 443
D i spersant (1 )
S u r f a c t a n t ( 2 )
T e r g i t o l S u r f a c t a n t NP-10
Antifoam ( 3 )
Titanium Dioxide (4)
Pebble M i l l o v e r n i g h t .
Let Down:
Ucar Vehicle 443
Antifoam ( 3 )
Proposol Solvent B
T r i butoxyethyl Phosphate
Mar-Resi s t a n t A i d (5)
Ammonium Benzoate, 10% Aqueous S o l u t i o n
Dei oni zed Water
Pounds
149.9
5.9
2.1
2.1
0.9
187.4
421.3
0.9
40.9
20.4
0.9
10.0
150.8
Gal l o n s
17.2
0.7
0.3
0 . 2
0.1
5.5
48.2
0.1
5.6
2 . 4
0.1
1.1
18.1
Suppliers:
( 1 ) Dispersant - Disperbyk (Byk-Mallinckrodt) o r e q u i v a l e n t .
(2) S u r f a c t a n t - Surfynol 104 ( A i r Products) o r equivalent.
( 3 ) Antifoam - Hodag PX-218 (Hodag) o r e q u i v a l e n t .
( 4 ) Titanium Dioxide - Zopaque RCL-9 (SCM) o r e q u i v a l e n t .
(5) Mar-Resistant A i d - Byk 301 ( B y k - M a l l l i n c k r o d t ) o r
e q u i v a l e n t .
Lacquer P r o p e r t i e s :
Pigment/Binder Ratio: 0.8/1
T o t a l S o l i d s , %: 42.4
pH: 8 . 6
V i s c o s i t y , No. 4 Ford Cup, sec:
I n i t i a l : 20
A f t e r 10 days a t 140F: 20
SOURCE: Ucar Emulsion Systems: Ucar Vehicle 443: Formulation
Suggestion LP-3846
Lacquers 123
White Lacquer
I n a r e d ients:
P igment G r i nd:
Ethylene Glycol
Dispersant (1 )
T e r g i t o l S u r f a c t a n t NP-10
Antifoam (2)
Ammonium Hydroxide, 28% Aqueous
Deionized Water
T i t a n i um Dioxide (3)
Pounds
3.16
6.31
1.59
0.23
S o l u t i o n 0.44
28.20
156.52
Gal 1ons
0.34
0.70
0.18
0.03
0.05
3.39
4.59
Grind f o r 15 minutes a t h i g h speed i n a high-shear mixer.
Let Down:
Ucar Vehicle 443
T r i butoxyethyl Phosphate
Filmer (4)
B u t y l C a r b i t o l Solvent
Ammonium Benzoate
Deionized Water
546.84 62.00
4.60 0.55
11.19 1.42
11.20 1.41
0.74 0.07
210.25 25.29
Suppl iers:
(1) Dispersant - Disperbyk (Byk-Mgllinckrodt) o r equivalent
(2) Antifoam - C o l l o i d 675 ( C o l l o i d s ) o r e q u i v a l e n t .
(3) Titanium Dioxide - Titanox 2060 (NL I n d u s t r i e s ) o r
( 4 ) Filmer - Texanol (Eastman) or e q u i v a l e n t .
e q u i v a l e n t .
Lacquer P r o p e r t i e s :
Pigment/Binder Ratio: 0.67/1
S o l i d s , %:
by Weight: 38.5
by Volume: 28.1
pH: 8 . 5
V i s c o s i t y . No. 4 Ford Cup, sec: 35
SOURCE: Ucar Emulsion Systems: Ucar Vehicle 443: Formulation
Suggestion LP-3813
Primers 125
fi
Halox BW-100
Grind:
Water
Propylene G1ycol
Dowicil 75
C o l l o i d 111
St rodex PK-95G
Surfynol 104E
Drewplus L-475
Texanol
Polyphobe 102
Aqua Ammonia (28%)
Lbs./100 Gals. Gms/Liter
250.0 300.0
15.0 18.0
1.o 1.2
5.0 6.0
3.5 4.2
4.0 4.8
2.0 2.4
10.0 12.0
16.0 19.2
4.0 4.8
Add t h e f o l l o w i n g a t high speed and disperse t o 4+ Hegman g r i n d .
T i -Pure R-902
Halox BW-100
Beaverwhi t e 325
Snowf 1ake
Letdown :
CL 27NA
Drewpl us L-475
175.0 210.0
100.0 120.0
50.0 60.0
185.0 222.0
340.0 408.0
2.0 2.4
Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l uniform.
Premix t h e f o l l o w i n g 2 raw m a t e r i a l s and add under good a g i t a t i o n
DO NOT AERATE!
Water
Pol yphobe 106E
Mix u n t i l uniform.
Formula Constants:
% P i gment/Wt .: 42.91
% P i gment/Vol .: 20.07
% Solids/Wt.: 57.79
% Solids/Vol.: 39.51
% PVC: 50.79
VOC, l b s . / g a l . : 1.01
VOC. g/L: 120.97
25.0 30.0
2.0 2.4
Formula Properti 8s:
Density l b s . / g a l . : 11.90
Density g/L: 1,427.4
KU Visc. I3 R.T.: 85-90
pH I3 R.T.: 8.5-9.0
SOURCE: Halox Pigments: SugQested Formulation DOW/BW-100
126 Water-Based Paint Formulations
A l k v d M o d i f i e d Latex Primer
I n g r e d i e n t :
Pigment G r i n d :
Water
Busperse 39/Dispersant
Bubreak 448/Defoamer
(Premix n e x t 2 items)
Water
QP-15000 Cellosize/Hydroxyethyl
I g e p a l CTA 639/Surfactant
Aroplaz 1271/Long O i 1 A1kyd
B u t r o l 23/Modified Barium Meta-
b o r a t e
Ti-Pure R-SOO/Titanium Dioxide-
R u t i l e
M i ca-325
Atomi t e / C a l c i um Carbonate
N y t a l 300/Talc-Magnesium S i l i c a t e
L e t Down:
Rhoplex MV-23/Acrylic Emulsion
Texanol/Ester Alcohol
Ethylene G l y c o l
Water
Pai n t P r o p e r t ies :
T o t a l V e h i c l e 60.27
Pigment 39.73
V o l a t i l e 42.67
Organic Solvent 7.59
Non-Volati l e 57.33
Non-Volati 1e V e h i c l e 17.60
Density (lb/U.S. gal): 11.99
S p e c i f i c G r a v i t y : 1.44
P.V.C.: 43.42%
P/B R a t i o : 2.258
Spread @ 1 M i l : 624 F2
Coating VOC: 220 G/L
M a t e r i a l VOC: 109 G/L
C e l l u l o s e
-Lb
100.10
8.01
3.00
25.02
1 .oo
6.01
42.04
100.10
200.19
25.02
75.07
75.07
483.46
5.00
30.03
20.02
w
83.10
16.90
61.07
10.58
38.93
22.02
Gal
12.02
0.74
0.44
3.00
0.09
0.68
5.01
3.25
6.01
1.06
3.32
3.17
54.94
0.63
3.23
2.40
Wt%
8.35
0.67
0.25
2.09
0.08
0.50
3.51
8.35
16.69
2.09
6.26
6.26
40.32
0.42
2.50
1.67
SOURCE: Buckman L a b o r a t o r i e s : Formulat on Sugges ion: KR-01
Primers 127
Ancamide 2353 Curina Aaent Anti-Corrosive Primer
Preliminary Formulation
P a r t A:
L i q u i d DGEBA Epoxy
MPA-1078 (Rheox)
Mix w e l l , then add a t h i g h speed:
T i Pure R-900 ( DuPont)
10 Wollastekup AS (Nyco)
Disperse t o 5 Hegman and 125F.
Reduce speed and add:
!&J
233.7
4.0
25.0
370.0
Xylene (Ashland) 45.0
Part B:
Ancamide 2353 ( A i r Products)
MPA-1078 (Rheox)
Beetle 216-8 (Cyanamid)
125.54
4.0
15.0
Mix w e l l a t high speed, then add:
Red I r o n Oxide 5-3100 (Mineral Pigments) 60.0
Beaverwhite 325 (Cyprus) 96.7
Phospl us 5-0866 (Mi neral Pigments) 141.4
Disperse t o 5 Hegman and 125F.
Reduce speed and add:
Diacetone Alcohol (Union Carbide)
Super High F1ash Naphtha (Ash1and)
31.3
106.8
Gal
24.093
0.541
0.751
15.289
6.207
15.212
0.541
1.724
1.441
4.204
5.065
3.997
14.691
Properties:
Volume Sol i d s : 71.8% VOC: <2.1 l b / g a l
PVC: 39.7% Mixing Ratio: 1:l by Volume
CPVC: 54.6% Pot L i f e , h r : 3
PVC/CVPC : 0.725 Dry t o Touch, h r : 1
Weight/gallon. Part A: 14.45 Dry Through, h r : 6
Weight/gallon, Part B: 12.45
Weight/gal lon: 13.45
SOURCE: A i r Products and Chemicals, I n c . : Ancamide 2353 Curing
Agent: Table 9 Formulation
I28 Water-Based Paint Formulations
Anquami ne 401/Semi -sol i d Epox D i s p e r s i on
___Lead and Chromate F r e e Red IronYOxide P r i m e r
P a r t A*
Dow XUS19000.01 Epoxy Resin
Benzyl A l c o h o l
Water
P a r t B:
Anquamine 401 C u r i n g Agent
Water
G l a c i a l A c e t i c A c i d ( A i r P r
Red I r o n Oxide**
LVT 400 T a l c ( B a r r e t t )
W a l l a s t o k u p I O E S (Nyco)
Zeospheres 400 (3M)
Halox SZP 391
Dowanol PM S o l v e n t (Dow)
Dowanol PnP S o l v e n t (Dow)
& @&
223.79 23.11
1 1 . 1 7 1.28
213.66 25.60
( A i r P r o d u c t s ) 111.95
80.05
o d u c t s ) 2 . 1 0
62.98
125.94
139.95
62.98
76.96
32.18
33.59
1 2 . 2 5
9 . 5 9
0 . 2 4
I . 5 7
5.29
5 . 7 8
3.43
3.07
4.23
4.55
* A l t e r n a t e l y use Epi-Rez 3515-W-60 a t same l o a d i n g
* * A l t e r n a t i v e l y use T i 0 2 f o r o f f - w h i t e p r i m e r
T y p i c a l P r o p e r t i e s :
W t S o l i d s ( % ) : 6 5 . 9 6
Volume S o l i d s (%): 51.17
PVC ( % ) : 37.4
Resin S t o i c h i o m e t r y : 1 . 6 : 1
VOC ( l b / g a l ) : 1 . 2 1
VOC ( g / l ) : 145
A n t i c o r r o s i v e Primer P r o p e r t i e s :
Pot L i f e , h r : 4
M i x R a t i o : 1 : l
Tack Free Time, h r : 1 . 0
Hard D r y Time, h r : 6
VOC, l b / g a l : 1 . 2
Volume S o l i d s , %: 51
PVC, %: 37
Cross Hatch Adhesion: 5
1/4" Mandrel Bend: Fai 1
D i r e c t Impact Resi stance, in-1 bs: 20
D i r e c t Impact Resi stance, in-1 bs: (5
SOURCE: A i r P r o d u c t s and Chemicals, I n c . : Anquamine 401 C u r i n g
Agent: F o r m u l a t i o n 3
Primers 129
Anquami ne 401/Soli d Resi n D ispersi on
Lead and Chromate Free Red I r o n Oxide Primer
Part A:
Epi-Rez 3520-WY-55 Epoxy Resin ( S h e l l )
Benzyl Alcohol
Surfynol DF-58 Defoamer ( A i r Products)
Water
Red I r o n Oxide
Barium S u l f a t e
lOES Wollastokup (Nyco)
Halox SW-1116
Zeosphere 4007 (3M)
Water Ground Mica
!=&
342.6
8.9
4.0
61.6
73.0
72.8
109.4
100.0
73.0
10.3
High speed disperse t o a t e x t u r e of N.S., then add:
Epi -Rez 3520-WY-55 Epoxy Resi n (She11) 129.3
Water 22.1
Part 8 :
Anquamine 401 Curing Agent ( A i r Products) 60.7
Water 111.8
Typical Properties:
W t S o l i d s (%I: 63.1
Volume S o l i d s (%): 47.3
PVC (%): 35.1
Resin Stoichiometry (on equivalents): 1.6:1
VOC ( l b / g a l ) : 1.02
voc ( g / l ) : 122.5
Pot L i f e , h r : 4
Mix Ratio: 4 : l
Tack Free Time, h r : 0.5
Hard Dry Time, h r : 6
VOC, l b / g a l : 1 . 0
Volume S o l i d s , %: 47
PVC, %: 35
Cross Hatch Adhesion: 4
Pencil Hardness, overnight: HB
Pencil Hardness, 7 days: H
1/4” Mandrel Bend: F a i l
D i r e c t Impact Resistance, i n - l b s : 35
Reverse Impact Resistance, i n - l b s : t5
A n t i c o r r o s i v e Primer Properties:
SOURCE: A i r Products and Chemicals, I n c . : Anquamine 401
Agent: Formulation 4
37.65
1.03
0.48
7.39
1.79
1.99
4.52
4.20
3.65
0.44
14.21
2.65
6.58
13.42
Curing
130 Water-Based Paint Formulations
Corrosion Inhibitive Primer
Material: j&
Add to mixer with agitation:
Water 98.6
Bubreak 448--Defoamer 2.0
Busperse 39--Dispersant 5 . 0
Igepal CTA-639 2.0
Premix and add the following:
Natrosol 250HR 2.0
Water 6.0
Stir in the following pigments:
Atomite 135.0
Ti-Pure R-900 100.0
Busan 11-M1 50.0
High speed disperse to minimum 5.0 NS grind
Let down with the following materials:
Aquamac 700 570.0
Texanol 69.0
Butrol 35--Flash rust inhibitor 7.0
Parameters: Properties:
Weight Solids: 52.9% Viscosity: 80-85 KU
Volume Solids: 40.5% DH: 8.4-8.6
Gals
11.83
0.30
0.46
0.23
0.40
0.72
5.97
3.08
1.82
65.82
8.75
0.63
Pigment Weight: 27.4% Gloss (a 60: 18-22
PVC: 27.9%
P/B Ratio: 1.08
VOC Level: 174 g/L
Metal Wash Primer
With today‘s concern over coatings containing chromate pig-
ments, there is a need for a chromate-free metal wash primer.
Buckman Laboratories has developed a metal wash primer made
with Busan 1 1 4 1 , which is a non-lead, non-chromate anticorrosive
pigment. This formula is based on the military specification
coating MIL-P-15328C entitled “Primer (Wash) Pretreatment Blue.”
This specification is the same a s the U . S . Navy Formula 117-8
for metals. The Busan 11-M1 based primer has performed well in
tests versus the traditional zinc chromate primer. The formula
is as follows:
Resin Component (80 gal lonsl: Lbs/100 Gals
Polyvinyl-Butyral Resin (Ucar XYHL) 56
Busan ll-Ml 50
Ti-Pure R-900, Titanium Dioxide 50
Copper-Phthalocyanine Blue 17
Butyl Alcohol, Normal 125
Isopropyl Alcohol 341
Water 15
Acid Component (20 aallons):
Phosphoric Acid, 85% 28
Water 25
Isopropyl Alcohol 99
Package separately: The mixed container must be used within
SOURCE: Buckman Laboratories: Suggested Formulations
8 hours after mixing.
Primers 131
Cost E f f e c t i v e 2K Water-Base Epoxv Primer
Usina Halox SW-111
Component A: Lbs./100 G a l s . Grams/Li t e r
Add t h e f o l l o w i n g i n o r d e r l i s t e d :
€pi-Rez 5522-WY-55 450.0 540.0
D i acetone A l c o h o l 7.0 8.4
Water 100.0 120.0
Nopco NDW 2.0 2 . 4
Mix f o r 5 minutes and add t h e f o l l o w i n g w h i l e m i x i n g a t h i g h
speed :
R . I . O . R-4098
Halox SW-111
Wol 1astokup 1OES
Sparmi t e
100.0
50.0
150.0
100.0
120.0
60.0
180.0
120.0
High speed d i s p e r s e t o 5+ Hegman g r i n d . Then add t h e f o l l o w i n g
s l o w l y w h i l e m i x i n g . Do n o t a e r a t e !
Epi r e z 5522-WY-55
Water
Component B:
Mix a t l o w speed:
€ p i -Cure 8290-Y-60
Nacorr 1754
30.0 36.0
25.0 30.0
Lbs. / l o 0 Gals. Grams/L ite r
60.0 72.0
3 . 0 3.6
A d d t h e f o l l o w i n g raw m a t e r i a l s i n o r d e r l i s t e d w h i l e m i x i n g a t
h i g h speed:
Zeeospheres 400
325 Mesh W.G. Mica
100.0
10.0
120.0
12.0
High speed d i s p e r s e t o 4+ Hegman g r i n d . Then add t h e f o l l o w i n g
s l o w l y w h i l e m i x i n g . Do n o t a e r a t e !
Water
M i x r a t i o : * Component A -
Component B -
*TO o b t a i n optimum r e s u
p r i o r t o a p p l i c a t i o n .
Formula Constants:
% P i gment/Wt. : 41.65
% Pigment/Vol.: 18.78
% S o l i d s / W t . : 65.81
% Sol i d s / V o l . : 49.66
% PVC: 37.81
P/B R a t i o : 1.72
VOC, l b s . / g a l . : 1.25
voc, g/L: 150.00
40.0 48.0
80% by volume.
20% by volume.
t s , a l l o w 20-30 minutes i n d u c t i o n t me
Formula P r o p e r t i e s :
D e n s i t y l b s . / g a l . : 12.25
D e n s i t y g/L: 1,470.0
Set-to-touch: 30 minutes
Dry Hard: Overnight
SOURCE: Halox Pigments: Suggested F o r m u l a t i o n
I32 Water-Based Paint Formulations
D ippi na Primer
I n g r e d i e n t s :
P i oment Grind:
Oeioni zed Water
Ammoni um Hydroxi de, 28% Aqueous Sol u t i on
Dispersant ( 1)
T e r g i t o l Surfactant NP-10
Antifoam (2)
T i t a n i um Dioxide (3)
Barytes (4)
Strontium Chromate ( 5 )
Let Down:
Ucar Vehicle 443
Antifoam ( 2 )
B u t y l Cellosolve Solvent
B u t y l C a r b i t o l Solvent
Hexamethoxymethylmelamine (6)
Ammonium Benzoate, 10% Aqueous S o l u t i o n
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
Oeioni zed Water
Suppliers:
Pounds
41.6
0.2
1.6
3.2
0 . 7
50.0
53.1
57.7
500.0
0.8
51.5
20.6
54.7
8.5
6.5
127.1
Gal l o n s
5.00
0.02
0.22
0.36
0.09
1.so
1.45
1.87
57.52
0.11
6.86
2.60
5.47
0.93
0.74
15.26
o r equi valent .
(Oavis/MPC) o r equivalent.
Cyme1 303 (American Cyanamid)
(1) Dispersant - Bykumen WS (Byk-Mallinckrodt) o r equivalent.
( 2 ) Antifoam - Hodag PX-218 (Hodag) o r equivalent.
(3) Titanium Dioxide - Ti-Pure R-960 (Du Pont) o r equivalent.
(4) Barytes - Sparmite ( P f i z e r )
(5) Strontium Chromate - 5-1365
(6) Hexamethoxymethylmelamine -
o r equivalent.
Primer Properties:
Solids, % by w t : 37.4
pH: 9.5
V i s c o s i t y , B r o o k f i e l d , cP: 800
Add Water t o 18 sec (#3 Zahn Cup) f o r dipping.
Primer Performance:*
Bake Cycle, min: S a l t Spray:
Flash Time: 10 Hours Exposed: 565
Bake a t 200F: 2.5 Rusting Rating: 9
F i n a l Bake a t 300F: 10 B l i s t e r Rating: 9M
Pencil Hardness: 2H Creepage, i n : 1/8
Gloss, 60: 30
Impact Resistance, i n - l b :
D i r e c t : 45
Reverse: 5
*Substrate - Bonderite 1000
SOURCE: Ucar Emulsion Systems: Ucar Vehicle 443: Formulation
Suggestion C-2030
Primers 133
Experimental General Purpose Tannin-Stain Resistant
Water-Base Primer Usina Halox X t a i n A
Grind:
Water
Natrosol 250 MR
Aqua Ammonia (28%)
Ethylene G1ycol
Tamol 681
T r i t o n CF-10
Foamaster VL
Halox X t a i n A
Snowf 1ake
R-902
Lbs. / l o 0 Gals. Gms/Li t e r
100.00 120.00
0.75 0.90
1.oo 1.20
30.00 36.00
15.00 18.00
3.00 3.60
2.00 2.40
150.00 180.00
15.00 18.00
220.00 264.00
High speed disperse t o 4+ NS g r i n d .
Water 25.00 30.00
Letdown :
Mor-Lok 1035
Skane M-8
Aqua Ammonia (28%)
Texanol
Foamaster VL
467.00 560.40
2.00 2.40
1 .oo 1.20
5.00 6.00
1.oo 1.20
Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l uniform.
QR-708
Water
Add t h e f o l l o w i n g w h i l e mixing and mix u n t i l uniform
5.50
79.00
Properties:
l b s . / g a l . : 1
Formula Constants:
% P i gment/Wt .: 34.36
% Pigment/Vol .: 15.03
% Solids/Wt.: 55.81
% S o l i d s / V o l . : 40.73
% PVC: 36.89
VOC, l b s . / g a l . : 1.10
VOC, gms./l.: 132.04
Formula
Density
Density
PH @ R.
KU Visc
SOURCE: Halox Pigments: Suggested Formu
.23
gms./i.: 1,346.7
.: 9.0-9.5
@ R . T . : 95-100
a t i o n MOR-1035-A
6.60
94.80
134 Water-Based Paint Formulations
ExDerirenta1 Hiph Performance Tanni n-Stai n Resistant
Water-Base Primer Usina Halox X t a i n A
Grind: Lbs./100 Gals. Gms/Liter
Water 125.00 150.00
Natrosol 250 MR
Aqua Ammonia (28%)
E t h y l ene G1ycol
Tamol 681
T r i t o n CF-10
Foamaster VL
Halox X t a i n A
Snowf 1ake
High speed disperse t o 4+ NS g r i n d
Water
Letdown :
Mor-Lok 1043
Skane M-8
Aqua Ammonia (28%)
Texanol
Foamaster VL
R-902
0.75
1.00
30.00
18.00
3.00
2.00
150.00
5.00
277.00
25.00
434.00
2.00
1 .oo
4.75
1 .oo
0.90
1.20
36.00
21 - 6 0
3.60
2.40
180.00
6.00
332.40
30.00
520.80
2.40
1.20
5.70
1.20
Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l uniform.
Add t h e f o l l o w i n g w h i l e mixing and mix u n t i l uniform.
QR-708
Water
Formula Constants:
% P i gment/Wt .: 37.60
% P i gment/Vol .: 17.11
% Solids/Wt.: 57.21
% S o l i d s / V o l . : 41.18
% PVC: 41.55
VOC, l b s . / g a l . : 1.13
VOC, gms./l.: 134.92
5.50 6.60
66.00 79.20
Formula P r o p e r t i e s :
Density 1bs. / g a l . : 11.51
Density gms. /l.: 1,381.2
KU Visc. @ R.T.: 90-95
pH @ R.T.: 9.0-9.5
SOURCE: Halox Pigments: Suggested Formulation MOR-1043-A
Primers 135
Experimental Waterbase A c r y l i c Red I r o n Oxide Primer
G r i n d :
Water
Methyl Carbi t o 1
Tamol 165
T r i t o n CF-10
Drew L-493
Snowf 1ake
AMP-95
R . I . O . R0-4097
Lbs./100 Gals. Gms/Liter
63.0 75.6
52.0 62.4
10.0 12.0
3.0 3 . 6
3.0 3 . 6
1.o 1 . 2
50.0 60.0
250.0 300.0
0 40.0Halox SZP-391 33.
High speed d i s p e r s e t o 4+ NS g r i n d .
Water 25.
Letdown :
Mai n c o t e HG-54
Texanol
D i b u t y l P h t h a l a t e
Drew L-493
Aqua Ammonia (28%)
Raybo 60
510.
4.
12
3
1
5
Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l un
A c r y s o l RM-1020
Water
M i x u n t i l u n i f o r m .
Formula Constants:
% Pigment/Wt.: 31.58
% Pigment/Vol.: 13.81
% S o l i d s / W t . : 52.35
% S o l i d s / V o l . : 38.97
?6 PVC: 35.41
VOC, l b s . / g a l . : 1.72
VOC. g/L: 206.40
0 30.0
0 612.0
0
9
5
5
0
form.
10.0
26.0
Formula P r o p e r t i e s :
D e n s i t y l b s . / g a l . : 10.63
D e n s i t y g/L: 1,275.9
KU V i s c . B R.T.: 90-95
pH @ R.T.: 8.0-9.0
4.8
15.5
4.2
1.8
6.0
12.0
31.2
SOURCE: Halox Pigments: Suggested F o r m u l a t i o n HG54-391
136 Water-Based Paint Formulations
Experimental Waterbase A c r y l i c
G r i n d :
Water
Methyl Carbi t o 1
Tamol 165
T r i t o n CF-10
Drew L-493
Red I r o n Oxide
S n o w f 1ake
Halox BW-191
L e t Down:
Mai n c o t e HG54
Texanol
O i b u t y l P h t h a l a t e
Drew L-493
Ammoni um Hydroxi de
Sodium N i t r i t e
Water
Ucar Thickener SCT
28%
200
Red Iron Oxide P r i m e r
~ _ _Pounds _____G a l l o n s
63.00 7.56
52.00 6.11
12.30 1 .26
3.00 0.34
1 .oo 0 . 1 4
57.40 1.34
192.60 8 . 5 6
100.00 4.21
510.00 60.00
4.00 0 . 5 0
12.90 1.48
3 . 6 0 0.50
1 . 7 0 0.24
8 . 4 0 1 . 0 1
49.00 5.90
7.50 0 . 8 5
D e n s i t y l b s / g a l : 10.78
% W t . S o l i d s : 5 3 . 5
% V o l . S o l i d s : 40.0
% PVC: 3 5 . 0
V i s c o s i t y : 90-95 KU @ 77F
SOURCE: Halox Pigments: Suggested F o r m u l a t i o n
Primers 137
ExDerimental Waterbase A c r y l i c Red I r o n Oxide P r i m e r
G r i n d :
Water
Methyl C a r b i t o l
Tamol 165
T r i t o n CF-10
Drew L-493
Snowflake
AMP-95
R. I.0 . R0-4097
Halox CW-491
Lb.s Jl_O 0. G31-s .. Gms/ L1 t_er
6 3 . 0 75.6
5 2 . 0 6 2 . 4
10.0 1 2 . 0
3 . 0 3.6
3 . 0 3 . 6
1 . o 1 . 2
5 0 . 0 6 0 . 0
225.0 270.0
6 6 . 0 7 9 . 2
H i g h speed d i s p e r s e t o 4+ NS g r i n d
Water 2 5 . 0 30 t 0
Letdown :
Mai n c o t e HG-54
Texanol
D i b u t y l P h t h a l a t e
Drew L-493
Aqua Ammonia (28%)
Raybo 60
.310.0 6 1 2 . 0
4 . 0 4 . 0
12 9 1 5 . 5
3 . 5 4 . 2
1 . 5 1 . 8
5 . 0 6.0
Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l un7form.
A c r y s o l RM-1020
Water
Mix a n t i i u n i f o r m
Formula Constants:
% Pigment/Wt.: 31 .99
% Pigment/Vol . : 13.93
% S o l i d s / W t . : 52.62
% S o l i d s / V o l . : 39.05
% PVC: 35.66
VOC, l b s . / g a l : 1 . 7 0
VOC, g/L: 204.00
1 0 . 0 12.0
26.0 31 . 2
Formula P r o p e r t i e s :
D e n s i t y l b s . / g a l . : 10.71
D e n s i t y g/L: 1,285.1
KU V i s c . @ R.T.: 95-100
pH @ R . T . : 8 . 0 - 9 . 0
SOURCE: Halox Pigments: Suggested F o r m u l a t i o n HG54-491
138 Water-Based Paint Formulations
E x t e r i o r House P a i n t Primer
Iflared> entss:
Pigment G r i n d :
Water
Ucar Polyphobe 102 Rheo. Mod.
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
Nuosept 95
Col l o i d 226/35
Propylene Glycol
C o l l o i d 640
T r i t o n Nonionic S u r f a c t a n t N-101
Kronos 2310
Halox BW-100
Nicron 400
Letdown :
Water )
Ucar Polyphobe 102 )Premix
Ucar Latex 625
C o l l o i d 640
B u t y l Carbi t o 1 Sol vent
NuoCide 404-D
T r i t o n Nonionic S u r f a c t a n t CA
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
P a i n t P r o p e r t i e s :
Pigment Volume Concentration, %: 32.0
Volume S o l i d s , %: 40.0
Weight S o l i d s , %: 54.5
V i s c o s i t y , e q u i l i b r a t e d :
Stormer, KU: 90
I C I , Poise: 1.45
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Aged S t a b i l i t y , 120F, weeks passed: 2
F i l m P r o p e r t i e s :
Contrast R a t i o , 6-mil wet drawdown: 0.96
Ref1ectance, %: 88.3
Sheen, 85: 19.9
Tannin S t a i n Resistance:
Cedar and Redwood: Very Good
Pounds
150.4
8.7
1.9
2 . 3
10.2
25.9
1 . 9
2.1
125.0
100.0
113.5
8.3
8 . 7
508.6
1 . 9
12.7
10.3
2.1
1 . 9
Gal l o n s
18.05
1.oo
0.25
0.25
1.oo
3.00
0.25
0.25
3.65
4.37
4.78
1 .oo
1 .oo
57.80
0.25
1.60
1 .oo
0.25
0.25
SOURCE: U c a r Emulsion Systems: U c a r Latex 625: Formulation
Suggestion E-2456
Primers 139
E x t e r i o r House P a i n t Primer Based On Ucar Latex 163
I nqredie n t s :
Pigment Grind:
Water
C e l l o s i z e Hydroxyethyl C e l l u l o s e
Nuosept 95
Col 1o i d 226/35
C o l l o i d 640
T r i t o n Nonionic S u r f a c t a n t N-101
Propylene Glycol
Tronox CR-828
Nicron 400 Talc
Halox EW-100
~~Pounds Gal l o n s
244.7 29.37
ER-30,000 3.5 0.32
2 . 3 0.25
10.5 I .oo
1 . 9 0.25
2.1 0.25
25.9 3.00
125.0 3.65
113.5 4.76
100.0 4.37
Letdown :
Ucar Latex 163 437.5 49.16
Ucar F i l m e r IET 12.7 1.60
C o l l o i d 640 1.9 0.25
NuoCi de 404-D 10.3 1 .oo
T r i t o n Nonionic S u r f a c t a n t CA 2 . 1 0.25
Ammonium Hydroxide, 28% Aqueous S o l u t i o n 3.8 0.50
P a i n t P r o p e r t i e s :
Pigment Volume Concentration, %: 32.0
Volume S o l i d s , %: 40.0
Weight S o l i d s , %: 54.0
Weight per Gallon, l b : 11.0
Stormer, KU: 86
I C I . poise: 1 .O
pH, i n i t i a l : 8 . 5
Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass
Heat S t a b i l i t y , 2 weeks a t 120F: Pass
F i l m P r o p e r t i e s :
Reflectance, %: 88.3
Sheen, 85: 11.6
Contrast R a t i o , 6-mil bar: 0.96
Tannin S t a i n Resistance cedar and redwood: Very Good
SOURCE: Ucar Emulsion Systems: Formulation Suggestion E-2457
140 Water-Based Paint Formulations
General Purpose Latex Maintenance Primer
-Ingredients:
Pigment Grind:
Water
Busperse 39/Dispersant
Bubreak 448/Defoamer
!&
105.91
8.47
3.18
(Premix next 2 items)
Water 26.48
QP-15000 Cellosize/Hydroxyethyl
Cellul ose 1.06
Igepal CTA 639/Surfactant 6.35
Aroplaz 1271/Long Oi 1 A1 kyd 40.47
Butrol 23/Modified Barium MetaboratelO5.91
Ti -Pure R-SOO/Titanium Dioxide-
Rutile 211.83
Mi ca-325/Potassium A1 uminum Si 1 i cate 26.48
Atomite/Calcium Carbonate 17.71
Nytal 3OO/Talc-Magnesium Silicate 17.71
Let Down:
Rhoplex MV23/Acrylic Emulsion 511.57
Texanol/Ester Alcohol 5.30
Ethylene Glycol 31 .77
Water 21 .18
Paint Properties: %wt .__%VOl
Total Vehicle 66.65 87.45
Pigment 33.35 12.55
Volatile 47.08 64.15
Organic Solvent 8.08 10.71
Non-Volatile 52.92 35.85
Non-Volatile Vehicle 19.56 23.20
Density (lb/U.S. gal): 11.41
Specific Gravity: 1 .37
P.V.C.: 35.00%
P/B Ratio: 1.705
Spread I3 1 M i l : 575 F2
Coating VOC: 237 G/L
Material VOC: 1 1 1 G/L
Gal
12.71
0.79
0.47
3.18
0.09
0.72
4.82
3.44
6.36
1.13
0.78
0.75
58.13
0.67
3.41
2.54
Wt%
9.28
0.74
0.28
2.32
0.09
0.56
3.55
9.28
18.56
2 . 3 2
1.55
1.55
44.82
0.46
2.78
1 .86
SOURCE: Buckman Laboratories: Formulation Suggestion: KR-02
Primers 141
General PurposeJL0.w C o s t Water-Base Primer
G r i n d :
Water
B u t y l C e l l o s o l v e
Tamol 165
T r o y s o l LAC
Drew L-493
AMP-95
Lbs./100 G a l s . G m s i l i t e r
150.0 180.0
2 9 . 0 3 4 . 8
1 5 . 0 1 8 . 0
3 . 0 3 . 6
3 . 0 3 . 6
1 . o 1.2
Add t h e f o l l o w i n g a t h i g h speed and d i s p e r s e t o 5 Hegman g r i n d .
Y . I . O . YO-2087
Halox CW-491
N y t a l 400
Letdown :
Water
Mai n c o t e PR-71
D i b u t y l P h t h a l a t e
Aqua Ammonia (28%)
Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t
add t h e f o l l o w i n g i n o r d e r l i s t e d :
Ethanol 95%
Raybo 60
Add s l o w l y w h i l e m i x i n g a t h i g h speed. Do n o t
QR-700
A c r y s o l RM-1020
Mix u n t i l u n i f o r m .
5 0 . 0 60.0
100.0 1 2 0 . 0
2 5 0 . 0 300.0
9 3 . 0 111 . 6
380.0 456.0
5 . 7 6 . 8
3 . 0 3 . 6
1 u n i f o r m . Then
14.5 1 7 . 4
5 . 0 6 . 0
a e r a t e !
5 . 0 6 . 0
2 . 0 2 . 4
Formula C o n s t a n t s :
% P i gment/Wt . : 36.05
% P i g m e n t / V o l . : 16.29
% S o l i d s / W t . : 54.20
% S o l i d s / V o l . : 31 .35
% PVC: 42.63
VOC, l b s . / g a l . : 1 . 5 4
VOC, g/L: 184.68
Formula P r o p e r t i e s :
D e n s i t y 1b s . / g a l . : 11 .09
D e n s i t y g/L: 1 , 3 3 1 . 0
KU V i s c . @ R . T . : 90-95
p H @ R . T . : 9 . 0 - 9 . 5
SOURCE: Halox Pigments: Suggested F o r m u l a t i o n PR-71/491A
142 Water-Based Paint Formulations
H i q h Performance Bare M e t a l Primer
G r i nd :
Water
B u t y l C e l l o s o l v e
Tamol 165
T r o y s o l LAC
Drew L-493
AMP-95
Lbs./100 Gals. Gms/Liter
92.0 110.0
35.0 42.0
10.0 1 2 . 0
2.0 2 . 4
3 . 0 3 . 6
1.o 1.2
Add t h e f o l l o w i n g a t h i g h speed and d i s p e r s e t o 5 Hegman g r i n d .
Y . I . O . YO-209
Halox SZP-391
N y t a l 400
Letdown :
Water
Mai n c o t e PR-7
D i b u t y l Phtha
Aqua Ammonia
a t e
28%)
50.0 60.0
50.0 60.0
125.0 150.0
112.0 134.5
470.0 564.0
7.0 8 . 4
3.0 3 . 6
Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l u n i f o r m . Then
add t h e f o l l o w i n g i n o r d e r l i s t e d .
Ethanol 95%
Raybo 60
18.0 2 1 . 6
5.0 6 . 0
Add s l o w l y w h i l e m i x i n g a t h i g h speed. Do n o t a e r a t e !
QR-708
A c r y s o l RM-1020
Mix u n t i l u n i f o r m .
Formula Constants:
% P i gment/Wt. : 22.51
% P i gment/Vol .: 8.76
% S o l i d s / W t . : 47.26
% Sol ids/Vol . : 35.78
% PVC: 24.48
VOC, l b s . / g a l . : 1.85
VOC, g/L: 222.13
12.0 14.4
5 . 0 6.0
Formula P r o p e r t i e s :
D e n s i t y Lbs ./ g a l . : 10.00
D e n s i t y g/L: 1,199.7
KU ViSc. @ R.T.: 90-95
PH @ R.T.: 9.0-9.5
SOURCE: Halox Pigments: Suggested F o r m u l a t i o n PR-71/391BM
Primers 143
Hitah Performance Galvanized Metal Primer
Grind:
Water
Butyl Cellosolve
Tamol 165
Troysol LAC
AMP-95
Drew L-493
Lbs./100 Gals. Gms/Liter
92.0 110.0
35.0 42.0
1 0 . 0 1 2 . 0
2 . 0 2 . 4
3 . 0 3 . 6
1.o 1 . 2
Add the following at high speed and disperse to 5 Hegman grind.
Y.I.O. YO-2087
Halox SZP-391
Shieldex
Nytal 400
Letdown :
Water
Mai ncote PR-71
Dibutyl Phthalate
Aqua Ammonia (28%)
50.0 60.0
50.0 6 0 . 0
25.0 30.0
100.0 120.0
106.5 128.0
470.0 564.0
7 . 0 8 . 4
3 . 0 3 . 6
Add grind portion under agitation and mix until uniform. Then add
the following in order listed:
Ethanol 95%
Raybo 60
18.0 21 . 6
5.0 6 . 0
Add slowly while mixing at high speed. Do not aerate!
OR-708
Acrysol RM-1020
Mix until uniform.
Formula Constants:
% P i gment/Wt .: 22.63
% Pigment/Vol . : 9 . 3 7
% Solids/Wt.: 47.50
% Solids/Vol.: 36.59
% PVC: 25.75
VOC, lbs./gal.: 1 . 8 3
VOC, g/L: 219.19
1 2 . 0 1 4 . 4
5 . 0 6 . 0
Formula Properties:
Density lbs./gal.: 9 . 9 5
Density g/L: 1 , 1 9 3 . 2
KU Visc. @ R.T.: 90-95
pH @ R.T.: 9.0-9.5
SOURCE: Halox Pigments: Suggested Formulation PR-71/391GM
144 Water-Based Paint Formulations
H i g h Performance 2 K Water-Base Epoxy P r i m e r
Component A :
Add t h e f o l l o w i n g i n o r d e r l i s t e d
O i a c e t o n e A l c o h o l
Water
Nopco NDW
M i x f o r 5 m i n u t e s and add t h e f o l
speed.
Eai-Rez 5522-WY-55
R . I . O . R-4098
H a l o x SZP-391
Wol 1a s t o k u p 1 OES
Sparmi t e
Lbs. / l o 0 G a l s . Gms(L1 t e r
450.0 540.0
7.0 8 . 4
1 0 0 . 0 1 2 0 . 0
2 . 0 2 . 4
o w i n g w h i l e m i x i n g a t h i g h
1 0 0 . 0 120.0
5 0 . 0 6 0 . 0
1 5 0 . 0 180.0
1 0 0 . 0 1 2 0 . 0
H i g h speed d i s p e r s e t o 5+ Hegman g r i n d . Then add t h e f o l l o w i n g
s l o w l y w h i l e m i x i n g . DO NOT AERATE'
Epi-Rez 5522-WY-55
Water
Component 8 :
M i x a t l o w speed:
Epi -Cure 8290-Y-60
N a c o r r 1754
3 0 . 0 3 6 . 0
2 5 . 0 30.0
Lbs. / l o 0 Gal s . Gms/Li t e r
6 0 . 0 7 2 . 0
3 . 0 3 . 6
Add t h e f o l l o w i n g raw m a t e r i a l s i n o r d e r l i s t e d w h i l e m i x i n g a t
h i g h speed:
Zeeospheres 400 1 0 0 . 0 120.0
325 Mesh W.G. M i c a 1 0 . 0 1 2 . 0
H i g h speed d i s p e r s e t o a 4 t Hegman g r i n d . Then add t h e f o l l o w i n g
s l o w l y w h i l e m i x i n g . DO NOT AERATE!
Water 4 0 . 0 48.0
M i x R a t i o : * Component A : 80% b y volume.
Component 8 : 20% b y volume.
*To o b t a i n optimum r e s u l t s , a l l o w 20-30 m i n u t e s i n d u c t i o n t i m e
p r i o r t o a p p l i c a t i o n .
Formula C o n s t a n t s :
% Pigment/Wt. : 41.63
% P i g m e n t / V o l . : 1 8 . 7 0
% S o l i d s / W t . : 6 5 . 7 7
% Sol id s / V o l . : 49.5%
% PVC: 3 7 . 7 1
P / B R a t i o : 1 . 7 2
VOC, l b s . / g a l . : 1.32
VOC, g / L : 1 5 8 . 4 0
Formul a P r o p e r t i es :
D e n s i t y l b s . / g a l . : 1 2 . 2 5
D e n s i t y g / L : 1 , 4 7 0 . 0
S e t - t o - t o u c h : 30 m i n u t e s
D r y H a r d : O v e r n i g h t
SOURCE: H a l o x Pigments: Suggested F o r m u l a t i o n Epi-Rez/BBl
Primers 145
Hiah Performance 2K Water-Base EDOXV Primer
Using Halox SZP-391
Component A: Lbs./lOO Gals. Grams/Li t e r
Add t h e f o l l o w i n g i n o r d e r l i s t e d :
Waterpoxy 1401
E k t a s o l v e EP
375.0 450.0
30.0 36.0
M i x f o r 5 minutes and add t h e f o l l o w i n g w h i l e m i x i n g a t h i g h
speed.
R . I . O . R-4098
Halox SZP-391
Wollastokup 10ES
N y t a l 400
100.0
75.0
100.0
150.0
120.0
90.0
120.0
180.0
High speed d i s p e r s e t o 5+ Hegman g r i n d . Then add t h e f o l l o w i n g
s l o w l y w h i l e m i x i n g . Do n o t a e a r a t e !
Deionized water 240.0 288 * 0
Component 0 :
Mix a t low speed.
Waterpoxy 701
E k t a s o l v e EP
Lbs./100 Gals. Grams/Li t e r
80.0
5.0
96.0
6.0
Mix r a t i o : * Component A - 90% b y volume.
Component B - 10% b y volume.
*To o b t a i n optimum r e s u l t s , a l l o w 20-30 minutes i n d u c t i o n t i m e
p r i o r t o a p p l i c a t i o n .
Formula Constants:
% P i gment/Wt .: 36.75
% Pigment/Vol. : 15.80
% S o l i d s / W t . : 60.10
% Sol ids/Vol .: 43.96
% PVC: 35.93
P/B R a t i o : 1.57
VOC, l b s . / g a l . : 1.57
voc, g/L: 188.40
Formula P r o p e r t i e s :
D e n s i t y 1bs. / g a l . : 11 .56
D e n s i t y g/L: 1,387.2
Set-to-touch: 30 minutes
Dry Hard: Overnight
SOURCE: Halox Pigments: Suggested F o r m u l a t i o n
146 Water-Based Paint Formulations
H i g h Performance 2K Water-Base Epoxy P r i m e r
Usinq H a l o x SZP-391
Component A: Lbs./100 Gals. Grams/Li t e r
A d d t h e f o l l o w i n g i n o r d e r l i s t e d :
Epi-Rez 5522-WY-55 450.0 540.0
D i acetone A l c o h o l 7.0 8.4
Water 100.0 120.0
Nopco NDW 2.0 2.4
Mix f o r 5 m i n u t e s and add t h e f o l l o w i n g w h i l e m i x i n g a t h i g h
speed :
R . 1 . O . R-4098
Halox SZP-391
W o l l a s t o k u p lOES
Sparmi t e
100.0
50.0
150.0
100.0
120.0
60.0
180.0
120.0
H i g h speed d i s p e r s e t o 5+ Hegman g r i n d . Then add t h e f o l l o w i n g
s l o w l y w h i l e m i x i n g . Do n o t a e r a t e !
E p i -Rez 5522-WY-55
Water
Component 8 :
Mix a t l o w speed:
€ p i -Cure 8290-Y-60
30.0 36.0
25.0 30.0
Lbs./100 Gals. Grams/Li t e r
60.0 72.0
3.6Nacorr 1754 3 . 0
Add t h e f o l l o w i n g raw m a t e r i a l s i n o r d e r l i s t e d w h i l e mix
h i g h speed:
Zeeospheres 400 100.0
325 Mesh W.G. Mica 10.0
ng a t
20.0
12.0
H i g h speed d i s p e r s e t o 4+ Hegman g r i n d . Then add t h e f o l l o w i n g
s l o w l y w h i l e m i x i n g . Do n o t a e r a t e !
Water 40.0 48.0
M i x R a t i o : * Component A - 80% b y volume.
Component B - 20% b y volume.
*To o b t a i n optimum r e s u l t s , a l l o w 20-30 m i n u t e s i n d u c t i o n
t i m e p r i o r t o a p p l i c a t i o n .
Formula C o n s t a n t s : Formula P r o p e r t i e s :
96 P i gment/Wt. : 41.63 D e n s i t y l b s . / g a l : 12.25
% Pigment/Vol . : 18.70 D e n s i t y g/L: 1,470.0
% S o l i d s / W t . : 65.77 S e t - t o - t o u c h : 30 m i n u t e s
% Sol i d s / V o l . 49.58 Dry Hard: Over night
% PVC: 37.71
P/B R a t i o : 1.72
VOC, l b s . / g a l . : 1.32
voc, g/L: 158.40
SOURCE: Halox Pigments: Suggested F o r m u l a t i o n
Primers 147
H i q h S o l i d s Red I r o n Oxide EDOXY Primer
M a t e r i a1 :
P a r t A:
Epon Resin 874-CX-90
B e e t l e 216-8
S h e l l Xylene
S h e l l MIBK
PGME A c e t a t e
Z i n c Phosphate 5-0852
10 ES Wollastokup
Sparmi t e
M i croMi ca C-3000
Copperas R-5098
High Speed Disperse t o a T e x t u r e o f 5-6 N.S
Bentone SD-2
P a r t B:
Epi-Cure C u r i n g Agent 3140
S h e l l Xylene
She11 n-Butanol
Composite Blend:
P a r t A
P a r t B
P a r t s A and B: V i s c o s i t y : 85 K.U.
T y p i c a l C o a t i n g P r o p e r t i e s :
T o t a l weight s o l i d s , p e r c e n t : 81.2
T o t a l v o l ume s o l i d s , p e r c e n t : 65.4
PVC, p e r c e n t : 35.0
I n d u c t i o n t i m e , minutes: 30
V o l a t i l e Organic Compounds (VOC):
Pounds p e r g a l l o n : 2.43
Grams p e r l i t e r : 292
F i 1m ProDert ies :
Pounds
263.0
12.0
75.5
60.4
15.1
176.5
176.5
233.5
38.8
38.7
9 . 3
132.0
42.9
18.4
1099.3
193.3
Gal l o n s
28.85
1.41
10.49
9.10
1 . 8 6
6 . 7 4
7.29
6.35
1.36
0.90
0 . 6 5
16.32
5.95
2.73
75.00
25.00
(Drawdown on CRS. Cured f o r 7 days a t 77F, 55% R.H.)
Pigment: b i n d e r r a t i o : 1.72
C u r i n g agent p h r , on s o l i d s : 56
Pot l i f e ( h r s ; f r o m 85-130 KU): 6
Pounds/gallon: 12.92
Dry f i l m t h i c k n e s s : 1.5 m i l s
S e t - t o - t o u c h d r y , h r s . : 1 . 0
C o t t o n - f r e e d r y , h r s . : 7.5
Through-dry, h r s . : 1 8 . 0
P e n c i l hardness: H
Impact r e s i s t a n c e , (Di r ./Rev. ) : 52/4
F l e x i b i l i t y : Pass 1/4"
Adhesion: SA
S a l t spray t e s t i n g (500 h r s ) : 2F-2M
Water r e s i s t a n c e (500 h r s a t 160F): 4M
SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1819:
Epon Resin 874-CX-Q0/Epi -Cure C u r i n g Agent 3140
148 Water-Based Paint Formulations
House P a i n t Primer
I n g r e d i e n t s :
Pigment Grind:
Water
C e l l o s i z e Hydroxyethyl C e l l u l o s e ER-30,000
Nuosept 95
Propylene Glycol
Col 1o i d 226/35
T r i t o n Nonionic S u r f a c t a n t N-101
C o l l o i d 650
T i -Pure R-902
325 Mesh White Waterground Mica
N y t a l 300
Letdown :
Ucar Latex 624
Ucar F i l m e r IBT
NuoCide 404D
C o l l o i d 650
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
Pai n t Propert ies :
Pigment Volume Concentration, %: 30.0
Volume Solids, %: 32.6
V i s c o s i t y , equi 1ibrated:
Stormer, KU: 80
I C I , poise: 0.7
Weight per Gallon, l b : 10.54
Pounds
283.8
3.5
2.3
25.9
6.4
2.2
1 . 9
150.0
25.0
100.0
426.7
10.7
10.3
2.0
2.0
Gal 1ons
34.07
0.32
0.25
3.00
0.62
0.25
0.25
4.50
1.07
4.21
48.49
1.35
1 .oo
0.37
0.25
Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass
Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass
F i l m P r o p e r t i e s :
Contrast R a t i o , 6-mil wet drawdown: 0.948
R e f 1ectance, %: 88.7
Sheen, 85: 7.0
Flow and Leveling, brushed: Good
Wet Adhesion: E x c e l l e n t
Chalk Adhesion: E x c e l l e n t
SOURCE: Ucar Emulsion Systems: Ucar Latex 824: Formulation
Suggestion E-2425
Primers 149
Lead
M a t e r i a l :
P a r t A:
Epi -Rez 5522-WY-55 Res
D i acetone Alcohol
Col 1o i d 640 Defoamer
Water
R0-4097 Kroma Red
Sparmi t e
l O E S Wollastokup
Halox SW-111
and Chromate Free Primer
n
High speed disperse t o a t e x t u r e o f 6-7 N . S .
Epi -Rez 5522-WY-55 Resin
15% Sodium N i t r i t e S o l u t i o n (Water)
Water
P a r t B:
Epi-Cure 8290-Y-60 Curing Agent
Water
Zeeosphere 400
Water Ground Mica, 325 mesh
High speed d i s p e r s e t o a t e x t u r e o f 4-5 N.S.
Composite Blend: V i s c o s i t y
P a r t A 114 K.U.
P a r t B 101 K.U.
P a r t s A and B 106 K.U.
&
330.0
7.0
3 . 5
80.0
100.0
23.1
150.0
100.0
147.0
8.0
8 . 7
60.0
11.0
100.0
10.0
957.3
234.7
Gals
37.21
0.89
0.41
9.60
2.45
0.63
6.19
4.20
16.43
0.95
1 .04
6.80
1 .32
5.00
0.43
80.00
20.00
SOURCE: Shell Resins: S t a r t i n g Formulation No. 1818
I50 Water-Based Paint Formulations
Lead and Chromate Free Red I r o n Oxide Primer
M a t e r i a l :
P a r t A:
Epi -Rez 5522-WY-55 Resin
Oiacetone Alcohol
Col 1o i d 640 Defoamer
Water
R0-4097 Kroma Red
Sparmi t e
1OES Wol 1astokup
Halox SW-111
High speed disperse t o a t e x t u r e o f 5-6 P.C.S
Epi -Rez 5522-WY-55 Resin
Water
P a r t 8 :
Epi-Cure 8290-Y-60 Curing Agent
Water
Zeeosphere Type 400
Water Ground Mica, 325 mesh
High speed disperse t o a t e x t u r e o f 4-5 P.C.S
Water
Composite B
P a r t A
P a r t B
Parts A and
SOURCE: She
end :
8
V i s c o s i t y
82 K.U.
101 K.U.
85 K.U.
!=,&
330.0
7.0
3.5
80.0
100.0
100.0
150.0
50.0
147.0
16.6
60.0
11.0
100.0
10.0
53
984
234
1 Resins: S t a r t i n g Formulation No. 180
Gals
37.21
0.89
0.41
9.60
2.45
2.73
6.19
2.10
16.43
1.99
6.80
1.32
5.00
0.43
6.45
80.00
20.00
Primers 151
Lead and Chromate Free Waterborne EPOXY Primer
Materi a1 :
Part A:
Epi -Rez 5522-WY-55 Resin
D i acetone A1coho1
C o l l o i d 640 Defoamer
Water
R0-4097 Kroma Red, Red I r o n Oxide
Sparmite Barium S u l f a t e
lOES Wollastokup
Halox SW-111
Zeeosphere 400
Water Groumd Mica, 325 Mesh
High speed disperse t o t e x t u r e o f 5-6 N.S.
€ p i-Rez 5522-WY-55 Resin
15% Aqueous Sodium N i t r i t e S o l u t i o n
Water
P a r t 9:
Epi-Cure 8292-Y-60 Curing Agent
Water
Composit e 81end : V i scosi t y
P a r t A 122 K.U.
Part B (#4 Ford cup,
P a r t s A and B 68 K . U .
Typical Coating Properties:
15.1 Seconds)
T o t a l Weight S o l i d s , %: 62.1
T o t a l Volume S o l i d s , %: 46.3
P.V.C., %: 34.9
I n d u c t i o n Time, minutes: 30
V o l a t i l e Organic Compounds (VOC):
Pounds/Gallon: 1.23
Grams/Liter: 148
Resin Composition (on s o l i d s ) :
Epoxy Resin, %: 07.6
Curing Agent, %: 12.4
Pounds
330.0
7.0
3.5
60.0
71.1
71.1
106.7
100.0
71 .1
7.5
147.0
8.0
6.3
60.0
11c.o
989.3
170.0
Gal 1ons
37.21
0 . 8 9
0.41
7.20
1.74
1.94
4.40
4.20
3.55
0.32
16.43
0.95
0.76
6.80
13.20
80.00
20.00
SOURCE: S h e l l Chemical Co.: S t a r t i n g Formulation No. 1818:
Epi-Rez 5522-WY-55 Resin/Epi-Cure 8292-Y-60 Curing Agent
152 Water-Based Paint Formulations
Lead Based .Primer
Mater1 a1 :
P a r t A :
2-Propoxyethanol
T r i t o n X-100 S u r f a c t a n t
Tamol 731 S u r f a c t a n t
9-148 Defoamer
Bentone LT, 3% i n w a t e r
Blend w e l l and add:
Red I r o n Oxide
B a s i c Lead S i l i c o Chromate
C e l l t e 499 Diatomaceous E a r t h
Maonesi um S i 1 1 c a t e
Pounds
11.6
3 . 5
3.5
4.0
75.0
1 0 0 . 0
100.0
25.0
25.0
Gal 1ons
1.50
0 . 3 9
0.38
0.48
8.95
2 . 3 4
2.93
1.30
1 .05-I n c r e a s e d i s p e r s e r speed t o 3,000 RPM. Achieve g r i n d f i n e n e s s
o f 6-7 PCS. Add under reduced a g i t a t i o n :
Epi -Rez 3520-WY-55 Resin 260.0 30.00
Tap Water 297.0 35.68
P a r t B:
Epi-Cure 8536-MY-60 C u r i n g Agent
Composite B1end :
P a r t A
P a r t 8
124.5 1 5 . 0 0
904.6 85.00
124.5 15.00
T y p i c a l C o a t i n g P r o p e r t i e s :
V i s c o s i t y : P a r t A : 65 KU
P a r t 8: 90 KU
P a r t s A and 8: 94 KU
Wei g h t / G a l l l o n : I O . 29
A p p l i c a t i o n :
Brush: As i s
Spray: Reduce 10 p a r t s p a i n t t o 1 p a r t water t o a v i s c o s i t y
o f 80 Krebs U n i t s
P . V . C . , %: 25.2
V e h i c l e N o n - V o l a t i l e , %: 2 8 . 4
T o t a l Volume S o l i d s , %: 30.2
T o t a l Weight S o l i d s , %: 46.4
Resin Composition: Epoxy Resin, %: 67
V o l a t i 1e Composition: Pounds Gal 1ons
Water 465.0 55.81
C u r i n g Agent, %: 33
O r g a n i c 85.2 11.20
Dry C h a r a c t e r i s t i c s (Room Temperature C u r e ) :
Set t o t o u c h : 30-60 minutes
Dry t o handle: 60 minutes
Dry h a r d : 4 h o u r s
Dry t o r e c o a t : 20 h o u r s
SOURCE: S h e l l Chemical Co. : S t a r t i n g F o r m u l a t i o n No. 1809:
Epi-Rez 3520-WY-55 Resin/Epi-Cure 8536-MY-60 C u r i n g Agent
Primers 153
Lead Silico Chromate Primer
M a t e r i a l :
P a r t A:
Epi -Rez 5522-WY-55 Resin
D i acetone A1coho1
T r i t o n X-100 S u r f a c t a n t
Water
C o l l o i d 640 Defoamer
RO-4097 Kroma Red, Red I r o n
Zeeospheres Type 400
B a s i c Lead S i l i c o Chromate
Oxide
Pebble m i l l a p p r o x i m a t e l y 18 hours
E p i -Rez 5522-WY-55 Resin
Water
P a r t 8:
Epi -Cure 8290-Y-60 C u r i n g Agent
Water
Zeeospheres Type 400
High speed d i s p e r s e t o a t e x t u r e o f 6 PC
Pounds
200.0
6 . 6
5.0
84.8
3.5
104.4
194.6
83.5
266.8
10.2
45.3
35.0
150.0
Water 26.4
Composi t e 81end : V i s c o s i t y
P a r t A 87 K . U .
P a r t B 140 K.U.
P a r t s A and B 90 K.U.
T y p i c a l C o a t i n g P r o p e r t i e s :
T o t a l Weight S o l i d s , %: 67.1
T o t a l Volume Sol i d s , %: 5 1 . 4
P.V.C., %: 43.1
V o l a t i l e Organic Compounds (VOC):
Pounds/Gal 1on : 1 .01
Grams/Liter: 121
I n d u c t i o n Time, minutes: 30
Resin Composition (based on s o l i d s ) :
Epoxy Resin, %: 90.0
C u r i n g Agent, %: 1 0 . 0
T o t a l , %: 100.0
Reduction f o r Conventional Spray (by volume):
P a r t s A and B: 20 p a r t s
Water: 1 p a r t
959.4
256.7
Gal 1ons
22.35
0.84
0.56
10.18
0.41
2.45
9.73
2.45
29.81
1.22
5.13
4.20
7.50
3.17
80.00
20.00
SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1813:
€pi-Rez 5522-WY-55 Resin/Epi-Cure 8290-Y-60 C u r i n g Agent
154 Water-Based Paint Formulations
Low Sheen Gray Primer
Materi a1 :
P a r t A:
Epi -Rez 5522-WY-55 Resin
Water
P a r t 8:
Epi -Cure 8290-Y-60 Curing Agent
Kronos 2020
SP Black 4 Powder
Patcote 847 Def
P a r t A
Part B
Parts A
Typical
Tota
Tota
PVC ,
Vola
Water
High Speed D
Water
Composite Blend
and B
Coati nQ
amer
sperse t o 7-8 N.S. Texture.
V i scosi t y
48 K . U .
76 K.U.
62 K.U.
Prooerties :
Weigh: Sol;ds, %: 51.1
Weight Solids, %: 39.5
%: 14.2
i l e Organic Compounds (VOC):
Pounds/Gallon: 1 .51
Grams/Liter: 181
I n d u c t i o n Time, minutes: 30
Pounds
522.1
69.4
82.1
191 .o
0.3
2.0
25.0
126.2
592.5
426.6
Gal 1ons
58.34
8.33
9.30
5.58
0.02
0.28
3.00
15.15
66.67
33.33
Resin Composition (based on s o l i d s ) :
Epoxy Resin, %: 85.0
Curing Agent, %: 15.0
Reduction f o r Conventional Spray (by volume):
( V i s c o s i t y = 55 K.U.)
P a r t s A and B : 11 p a r t s
Water: 1 p a r t
SOURCE: S h e l l Chemical Co.: S t a r t i n g Formulation No. 1812:
€pi-Rez 5522-WY-55 Resin/Epi-Cure 8290-Y-60
Primers 155
M a t e r i a l :
Water
I g e p a l CO-630
Tamol 731
Foamaster VL
S u r f y n o l 104H
D i e t h y l e n e G l y c o l
T i t a n o x 2101
Raven 1020
Halox BW-191
QP-4400
#on-Lead/Non-Chromate Primer
Monomethyl E t h e r
Lbs.
83.89
2.54
0.87
10.70
1.10
1.66
35.32
58.50
0.65
148.69
High speed Cowles 15-20 minutes t o a 3-4 Hegman g r i n d .
Add letdown:
A r o l o n 820-W-49 540.36
Premix:
Dalpad A
Water
Premix:
Aroplaz 1271
C o b a l t Hydrocure I 1
C a l c i um Hydrocem
Z i r c o n i um Hydrocem
Then add:
S u r f y n o l 104H
Skane M-8
Premi x :
OR-708
Water
13.24
58.26
37.99
3.79
3.79
1.88
3.31
2.20
0.17
2.26
Gals.
10.06
0.29
0.07
1.23
0.14
0.21
4.14
1.75
0.03
6.27
61.40
1.43
6 . 9 9
4.54
0.49
0.46
0.22
0.17
0.15
0.02
0 . 2 6
A n a l y s i s :
Pigment Volume Concentration, Percent: 18.85
Pigment/Binder R a t i o : 0.69/1
Percent Sol i d s , Weight : 50.54
Percent S o l i d s , Volume: 34.52
V i s c o s i t y C 25C, KU: 85-89
Gloss (60): F l a t
Pounds/Gallon: 10.08
VOC ( e x c l u d i n g w a t e r ) :
pH: 8.7-9.2
Grams/Liter: 70.8
Pounds/Gallon: 0.6
SOURCE: Reichhold Chemicals, I n c . : A r o l o n 820: Formula 2025-80-1
156 Water-Based Paint Formulations
Primer f o r Factory-Pri med Hardboard S i d i ng
I n g r e d i e n t s :
Pigment Grind:
Water
T e r g i t o l Nonionic Surfactant NP-10
Tamol 731
Foamaster VF
T i -Pure R-960
ASP 400
Letdown :
Ucar Vehicle 462
Ucar A c r y l i c 515
Cyme1 325
Foamaster VF
Nuocide 960
Arcosolve PP Solvent
Propylene Glycol
Pounds
164.3
6.0
17.6
2.6
96.5
289.4
325.0
118.2
31.3
0.9
5 . 1
31 . 3
35.3
Gallons
19.8
0.6
1.9
0 . 3
2.9
13.5
37.0
13.0
3.0
0.1
0.6
3.0
4.3
P a i n t P r o p e r t i e s :
Pigment Volume Concentration, %: 42
C r o s s l i n k e r , p h r : 12
Cosolvent, phr: 15
Volume Solids, %: 40
Weight per Gallon, l b : 11.2
SOURCE: Ucar Emulsion Systems: Ucar Vehicle 462: Suggested
Formu1a t ion
Primers 157
Primer 20323D Based on Phosguard J - O m
and 10 ES W o l l a s t o c o a t
Henkel ‘ s Waterpoxy 1401:701 _Sysrem
Component A:
Waterpoxy 1401
Ektasolve EP
10 ES Wol l a s t o c o a t
Red I r o n Oxide 5-3106
Phosguard 5-0853
Disperse t o 5 n . s . u . , reduce speed and add:
Methyl Amyl Ketone
Water
Component 8 :
Waterpoxy 701
Ektasolve EP
Formulation Constants:
&
452.05
10.44
255.50
137.40
147.89
55.00
74.60
100.00
10.40
Non V o l a t i l e by Weight: 0.70 VOC g r m s / l i t r e :
Non V o l a t i l e by Volume: 0.53 VOC l b s . / g a l . :
PVC : 0.36 Weight/Gallon Comp A :
CPVC : 0.46 Weight/Gallon Comp 0 :
PVC/CPVC : 0.79 M i x i n g R a t i o :
Pigment Content: 0.44 Weight per Gallon:
NVV by W t . o f Vehicle: 0.47
SOURCE: Nyco Minerals, I n c . : Primer 20323D
Gals
49.95
1 .38
10.56
3.30
5.22
8.09
8.96
11.17
1.37
236.82
1.98
12.96
8.80
6.97
12.43
1.58 Water-Based Paint Formulations
Primer 203236 Based on Phosguard 5-0813
and 10 ES W o l l a s t o c o a t
Henkel ‘sWaterpoxy 1401:701 System
Component A :
Waterpoxy 1401
E k t a s o l v e EP
10 ES W o l l a s t o c o a t
Red I r o n Oxide 5-3106
Phosguard 5-0813
Disperse t o 5 n . s . u . , reduce speed and add:
Methyl Amyl Ketone
Water
Component B:
Waterpoxy 701
E k t a s o l v e EP
F o r m u l a t i o n Constants
Lbs
452.05
10.44
255.50
137.40
130.49
55.00
74.60
100.00
10.40
PVC : 0.36 Wei ght/Gai
CPVC : 0.46 Weight/Gal
PVC/CPVC : 0.79 M i x i n g Rat
Pigment Content; 0.43 Weight p e r
NVV by W t . o f V e h i c l e : 0 . 4 7
Non V o l a t i l e by Weight: 0.70 VOC g r m s / l i t r e :
Non V o l a t i l e by Volume: 0.53 VOC l b s . / g 1 . :
on Comp A: 12.76
on Comp 9: 8.80
0: 6.97
G a l l o n : 12.26
Gals
49.95
1 . 3 8
10.56
3.30
5.22
8.09
8.96
11.17
1.37
236.82
1.98
SOURCE: Nyco M i n e r a l s , I n c . : Primer 203230
Primers 159
Primer 20596F Based on Heucophos ZPZ
~~and 10 ES Wollasto-
_ _ ~ _Henkel's -Waterpoxy 1401:701 System
Component A:
Waterpoxy 1401
Ektasolve EP
10 ES Wol 1 astocoat
Red Iron Oxide 5-3106
Heucophos ZPZ
Disperse to 5 n.s.u., reduce speed and add:
Methyl Amyl Ketone
Water
Component 0 :
Waterpoxy 701
Ektasolve EP
Formulati on Constants
Lbs &lls
452.05 49.95
1 0 . 4 4 1 . 3 8
255.50 1 0 . 5 6
137.40 3 . 3 0
152.48 5 . 2 2
5 5 . 0 0 8 . 0 9
74.60 8 . 9 6
100.00 1 1 . 1 7
10.40 1 . 3 7
Non Volatile by Weight: 0 . 7 0 VOC grms/litre: 236.82
Non Volatile by Volume: 0 . 5 3 VOC 1bs./gal . : 1 . 9 8
PVC: 0 . 3 6 Weight/Gallon Comp A : 13.01
cpvc: 0 . 5 5 Weight/Gallon Comp 6 : 8 . 8 0
PVC/CPVC : 0.67 Mixing Ratio: 6 . 9 7
Pigment Content: 0 . 4 4 Weight per Gallon: 12.48
NVV by Wt. o f Vehicle: 0 . 4 7
SOURCE: Nyco Minerals, Inc.: Primer 20596F
I60 Water-Based Paint Formulations
Primer 205966 Based On HeucoDhos ZMP
and 10 ES Wollastocoat
Henkel's Waterpoxy 1401:701 System
Component A:
Waterpoxy 1401
Ektasolve EP
10 ES Wollastocoat
Red I r o n Oxide 5-3106
Heucophos ZMP
Disperse t o 5 n.s.u., reduce speed and add:
Methyl Amyl Ketone
Water
Component B:
Waterpoxy 701
Ektasolve EP
Formulation Constants
& Gals
452.05 49.95
10.44 1 .38
255.50 10.56
137.40 3.30
152.48 5.22
55.00 8.09
74.60 8.96
100.00 11.17
10.40 1.37
Non V o l a t i l e by Weight: 0.70 VOC g r m s / l i t r e : 236.82
PVC : 0.36 Weight/Gallon Comp A: 13.01
CPVC: 0.53 Weight/Gallon Comp 8 : 8.80
PVC/CPVC : 0.68 M i x i n g R a t i o : 6.97
Pigment Content : 0.44 Weight per Gallon: 12.48
NVV by W t . o f Vehicle: 0.47
SOURCE: Nyco Minerals, I n c . : Primer 205966
Non V o l a t i l e by Volume: 0.53 VOC l b s . / g a l . : 1.98
Primers 161
Primer 21102E Based on Molycoat 212
and 10 AS W o l l a s t o c o a t
H e n k e l ' s Waterpoxy 1401:701 System
Component A:
Waterpoxy 1401
E k t a s o l v e EP
10 AS W o l l a s t o c o a t
Red I r o n Oxide 5-3106
M o l y w h i t e 212
Disperse t o 5 n . s . u . , reduce speed and add:
Methyl Amyl Ketone
Water
Component 9:
Waterpoxy 701
E k t a s o l v e EP
&
452.05
10.44
255.50
137.40
130.39
55.00
74.60
100.00
10.40
F o r m u l a t i o n Constants
Non V o l a t i l e b y Weight: 0.70 VOC g r m s / l i t r e :
Non V o l a t i l e bv Volume: 0.53 VOC l b s . / a a l . 3:
&3&
49.95
1.38
10.56
3.30
5.22
8.09
8 . 9 6
11.17
1.37
236.82
1.98
PVC : 0.36 Weight/Gailon Comp A: 12.76
CPVC: 0.55 Weight/Gallon Comp 8: 8.80
PVC/CPVC : 0.66 M i x i n g R a t i o : 6.97
Pigment Content: 0.43 Weight p e r G a l l o n : 12.26
NVV b y W t . of V e h i c l e : 0.47
SOURCE: Nyco M i n e r a l s , I n c . : Primer 21102E
162 Water-Based Paint Formulations
Primer 21105H Based on Phosauard 5-0815
and 10 ES W o l l a s t o c o a t
Henkel's Waterpoxy 1401:702 System
Component A:
Waterpoxy 1401
Ektasolve EP
10 ES Wol l a s t o c o a t
Red Iron Oxide 5-3106
Phosguard 5-081 5
Disperse t o 5 n.s.u., reduce speed and add:
Methyl Amyl Ketone
Water
Component 0:
Waterpoxy 702
Ektasolve EP
Formulation Constants
!& Gals
452.05 49.95
10.44 1.38
255.50 10.56
137.40 3.30
139.19 5.22
55.00 8.09
74.60 8.96
45.28 5.27
23.41 3.08
Non V o l a t i l e by Weight: 0.69 VOC g r m s / l i t r e : 237.36
Non V o l a t i l e by Volume: 0.51 VOC l b s . / g a l . : 1 . 9 8
PVC: 0.39 Weight/Gallon Comp A: 12.86
CPVC : 0 . 5 0 Weight/Gallon Comp B: 8.23
PVC/CPVC : 0.79 M i x i n g R a t i o : 10.47
Pigment Content : 0.45 Weight per Gallon: 12.45
NVV by W t . o f Vehicle: 0.44
SOURCE: Nyco Minerals, I n c . : P r i m e r 21105H
Primers 163
Primer 211051 Based On N a l z i n 2
and 10 ES Wollastocoat
Henkel 's Waterpoxy 1401 :702 System
Component A:
Waterpoxy 1401
Ektasolve EP
10 ES Wol l a s t o c o a t
Red I r o n Oxide 5-3106
N a l z i n 2
Disperse t o 5 n.s.u., reduce speed and add:
Methyl Amyl Ketone
Water
Component 8 :
Waterpoxy 702
Ektasolve EP
Formulation Constants
&
452.05
10.44
255.50
137.40
172.32
55.00
74.60
45.28
23.41
Non V o l a t i l e by Weight: 0.70 VOC g r m s / l i t r e :
Non V o l a t i l e by Volume: 0.51 VOC l b s . / g a l . :
PVC: 0.39 Weight/Gallon Comp A:
CPVC: 0.54 Weight/Gallon Comp 8:
PVC/CPVC : 0.73 Mixing Ratio:
Pigment Content : 0.46 Weight per Gallon:
NVV by W t . o f Vehicle: 0.43
SOURCE: Nyco Minerals, I n c . : Primer 211051
Gals
49.95
1.38
10.56
3.30
5.22
8.09
8.96
5.27
3.08
237.36
1.98
13.23
8.23
10.47
12.80
164 Water-Based Paint Formulations
Primer 21109C Based on S t r o n t i u m Chromate
and 10 ES Wollastocoat
Henkel's Waterpoxy 1401:702 System
Component A:
Waterpoxy 1401
Ektasolve EP
10 ES Wollastocoat
Red I r o n Oxide 5-3106
S t r o n t i u m Chromate
Disperse t o 5 n . s . u . , reduce speed and add:
Methyl Amyl Ketone
Water
Component B :
Waterpoxy 702
Ektasolve EP
Formulation Constants
* L
453.17
10.47
256.20
137.75
166.40
55.10
74.79
68.04
35.18
Non V o l a t i l e bv Weiaht: 0.69 VOC a r m s / l i t r e :
CPVC : 0.54 Wei ght/Gal 1on
PVC/CPVC : 0 . 7 0 M i x i n g R a t i o :
Pigment Content: 0.45 Weight per Ga
NVV by W t . o f Vehicle: 0.44
50.07
1.38
10.59
3.31
5.27
8.10
8.98
7.91
4.64
250.17
2.09Non V o l a t i l e b; V o l h e : 0.51 VOC i b s . / g a l . :
PVC : 0.38 Weight/Gallon Comp A: 13.16
Comp B: 8.23
6.99
l o n : 12.54
SOURCE: Nyco Minerals, I n c . : Primer 21109C
Primers 165
Rapid Dry Waterborne Epoxy Primer
M a t e r i a l :
P a r t A:
E p i -Rez 5522-WY-55 Resin
D i acetone A1coho1
C o l l o i d 640 Defoamer
Water
R0-4097 Kroma Red, Red I r o n Oxide
lOES Wollastokup
Halox SW-111
High Speed Disperse t o a Texture o f 5-6 N.S
Epi -Rez 5522-W-55 Resin
E p i -Rez 3540-WY-55 Resin
15% Aqueous s o l u t i o n o f sodium n i t r i t e
Water
P a r t B:
Epi-Cure 8290-Y-60 Curing Agent
Water
Zeeosphere 400 t y p e
Water Ground Mica, 325 Mesh
High Speed Disperse t o a t e x t u r e o f 4-5 N.S
Water
G l a c i a l A c e t i c A c i d
Composite Blend: V i s c o s i t y
P a r t A 64 K.U.
P a r t 0 70 K.U.
P a r t s A and B 62 K.U.
T y p i c a l Coating P r o p e r t i e s :
T o t a l Weight S o l i d s , %: 59.1
T o t a l Volume S o l i d s , %: 43.8
P.V.C., %: 36.2
I n d u c t i o n Time, minutes: 30
V o l a t i l e Organic Compounds (VOC):
Pounds/Gallon: 1.19
Grams/Liter: 142.8
Res4 n ComDosi tion :
Epoxy Resin, %: 89.6
C u r i n g Agent, %: 10.4
Reduction t o Spray V i s c o s i t y : None r e q u i r e d
Pounds
258.7
5.4
2.7
59.4
77.6
116.6
116.6
114.3
74.1
6.2
79.7
46.7
8.6
77.0
7.7
78.5
0.4
911.4
219.7
Gal 1ons
28.92
0.69
0.32
7.13
1.90
4.81
4.90
12.77
8.24
0.74
9.58
5.29
1.03
3.89
0.33
9.42
0.04
80.00
20 * 00
SOURCE: S h e l l Chemical Co.: S t a r t i n g Formulation No. 1814:
Epi-Rez 5522-WY-55 Resin/Epi-Rez 3540-WY-55 Resin/
Epi-Cure 8290-Y-60 Curing Agent
166 Water-Based Paint Formulations
Rapid D r y Waterborne Epoxy Primer
M a t e r i a l P a r t A:
Epi-Rez 5522-WY-55 Waterborne Resin
Epi-Rez 3540-WY-55 Waterborne Resin
C o l l o i d 640
Water
Bentone LT
High Speed Mix f o r 15 minutes
Water
D i acetone Alcohol
R0-4097 Kroma Red, Red I r o n Oxide
Halox SW-111
Sparmi t e
325 Mesh Wet Ground Mica
399 Lo-Mi c r o n
High Speed Disperse t o a t e x t u r e of 5-6 N.S.
Pounds Gal 1ons
205.0 22.78
_ _ _ ~
61.9 6.88
5.0 0.60
140.0 16.81
3.0 0.20
30.0 3.60
7.8 1 .oo
65.5 1.60
93.8 3.94
46.7 1.28
46.9 2.00
85.0 3.78
Epi-Rez 5522-WY-55 Resin 18.8 2.09
15% Aqueous s o l u t i o n o f potassium n i t r i t e 8.0 0.95
Water 104.0 12.49
M a t e r i a l P a r t 8:
Epi -Cure 8292-Y-60 Curing Agent
Ektasolve EP
Water
27.0 3.08
37.9 5.00
99.3 11.92
Composite Blend: V i s c o s i t y
P a r t A 102 K.U. 921.4 80.00
P a r t 8 10.5 secs (Ford #4) 164.2 20.00
P a r t s A and 8 68 K.U.
T y p i c a l Coating P r o p e r t i e s :
Resin/Curing Agent R a t i o ( s o l i d s b a s i s ) :
Epoxy Resin: 88.1
Curing Agent: 11.9
T o t a l weight s o l i d s , %: 47.6
T o t a l volume s o l i d s , %: 33.2
P.V.C., %: 40.8
I n d u c t i o n time, minutes: 30
V o l a t i l e Organic Compounds (VOC):
Pounds/gal 1on : 1.95
G r a m s / l i t e r : 234
SOURCE: S h e l l Chemical Co.: S t a r t i n g Formulation No. 1821:
Epi-Rez 5522-WY-55 Waterborne Resin/Epi-Rez 3540-WY-55
Waterborne Resin/Epi-Cure 8292-Y-60 Curing Agent
Primers 167
Red I n h i b i t i v e Maintenance Primer
I n a r e d i ents:
Pigment Grind:
Water
Bentone LT
Methyl C a r b i t o l Solvent
Tamol 681
Nuosept 95
DeeFo HG-12
T r i t o n Nonionic S u r f a c t a n t CF-10
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
Acrysol RM-2020
Heucophos ZBZ
Atomite
Letdown :
Methyl C a r b i t o l Solvent
Acrysol SCT-275
Ucar Vehicle 435
Ucar F i l m e r I B T
Troysan Polyphase AF-1
Foamex 825
Sodium N i t r i t e , 15% Aqueous S o l u t i o n
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
5-3103
Adjust t o minimum pH 8.7
Pounds
151.5
1.o
25.5
18.2
2.3
2.1
2 . 2
1.8
17.2
50.0
75.0
145.8
8 . 5
8.6
505.1
11.4
4.9
2.1
9.0
1.8
Gallons
18.19
0.06
3.00
2.00
0.25
0.25
0.25
0.25
2.00
1.20
2.51
6.46
1.oo
1.oo
58.06
1.44
0.50
0.25
1.08
0.25
P a i n t Properties:
Pigment Volume Concentration (PVC), %: 30.0
T o t a l Solids, %:
by volume: 34.0
pH Value, i n i t i a l : 8.7
V i s c o s i t y :
Stormer. KU: 80
I C I , poise: 0.7
Weight per Gallon, l b : 10.4
Freeze-Thaw S t a b i l i t y , 3 cycles: Pass
Heat S t a b i l i t y , 2 weeks a t 140F: Pass
SOURCE: Ucar Emulsion Systems: Ucar Vehicle 435: Formulation
SugQestion M-2452
168 Water-Based Paint Formulations
Red I r o n Oxide C o r r o s i o n R e s i s t a n t EPOXY Primer
(Two Component System)
Ingredients: -Lb
(Prepare P a r t # l & P a r t #2 s e p a r a t e l y )
P a r t #l
E p o t u f 37-618/Epoxy Resin Hardener 147.91
X y l o l / X y l e n e 95.36
Ye1 k i ns-TS/Soya L e c i t h i n 3.89
B u t r o l 2 3 / M o d i f i e d Barium Meta-
b o r a t e 194.62
Red I r o n Oxide 194.62
N y t a l 300/Talc-Magnesium S i l i c a t e 18.49
P a r t #2:
E p o t u f 38-501/Epoxy Resin
Methyl I s o b u t y l Ketone
X y l o l /Xylene
272.91
70.06
105.10
M i x two components i n 1 : l r a t i o and w a i t f o r
p a i n t a p p l i c a t i o n .
Pigment
Vol a t i 1e
Organi c Solvent
Non-Vol a t i1e
N o n - V o l a t i l e Veh
D e n s i t y (lb/U.S.
S p e c i f i c G r a v i t y
P.V.C.: 47.19%
P/B R a t i o : 1.323
P a i n t P r o p e r t i es : %Wt %vel
T o t a l V e h i c l e 63.03 87.92
36.97 12.08
35.09 74.41
35.09 74.41
64.91 25.59
c l e 27.94 13.52
g a l ) : 11.03
1.32
18.96 13.41
13.19 8.65
0.46 0.35
6.32 17.65
4.98 17.65
0.78 1.68
30.29 24.74
10.49 6.35
14.54 9.53
30 minutes b e f o r e
Spread @ 1 M i l : 411 F2
C o a t i n g VOC: 464 G/L
M a t e r i a l VOC: 464 G/L
SOURCE: Buckman L a b o r a t o r i e s : F o r m u l a t i o n Suggestion: KQ-23
Primers 169
Red I r o n Oxide Primer
M a t e r i a l :
P a r t A:
2-Propoxyethanol
T r i t o n X-100 S u r f a c t a n t
Tamol 731 S u r f a c t a n t
91 48 Defoamer
Bentone LT, 3% i n water
Blend w e l l and add:
Red I r o n Oxide
C e l i t e 499 Diatomaceous E a r t h
Magnesi um S i 1ic a t e
Pounds G a l l o n s
11.6 1.50
3.5 0.39
3 . 5 0.38
4.0 0.48
75.0 8.95
~ _ _ _
100.0 2.34
25.0 I .30
100.0 4.22
D i s p e r s e t o a g r i n d f i n e n e s s o f 6-7 P.C.S., t h e n add under
a g i t a t i o n :
Epi -Rez 3520-WY-55 Resin
Tap Water
P a r t B:
Epi -Cure 8536-MY-60 C u r i ng Agent
Composite 81end :
P a r t A
P a r t 8
276.0 30.00
295.0 35.44
124.5 15.00
893.6 85.00
124.5 15.00
T y p i c a l C o a t i n g P r o p e r t i e s :
V i s c o s i t y : P a r t A: 68 Krebs U n i t s
P a r t B: 90 Krebs U n i t s
P a r t s A and B: 98 Krebs u n i t s
Pounds/Gal l o n : 10.18
A p p l i c a t i o n :
Brush: as i s
Spray: Reduce 10 p a r t s p a i n t t o 1 p a r t water t o a v i s c o s i t y
o f 83 Krebs U n i t s
P.V.C., %: 25.2
V e h i c l e N o n - V o l a t i l e , %: 29.2
T o t a l Volume S o l i d s , %: 31.3
T o t a l Weight S o l i d s , %: 45.3
Resin Composition: Epoxy Resin, %: 67
Vol a t i 1e Composi t i on Pounds G a l l o n s
Water 467.0 56.14
C u r i n g Agent, %: 33
Organics 85.2 11.20
V o l a t i l e Organic Compounds (VOC):
Pounds/Gallon: 2.05
G r a m s / L i t e r : 246
SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1806:
Epi-Rez 3520-WY-55 Resin/Epi-Cure 8536-MY-60 C u r i n g Agent
170 Water-Based Paint Formulations
Red Iron Oxide Primer
I n g r e d i e n t s : -Lb
P iOment O r ind:
Water 117.69
Busperse 39/Dispersant 5.65
Bubreak 448/Defoamer 2.82
Zinc S u l fate-Heptahydrate 1.88
I g e p a l CTA 639/Surfactant 2.82
(Mix 10 minutes and add)
B u t r o l 23/Modi f ied B a r i um Meta-
b o r a t e 47.08
Red I r o n Oxide 94.15
N y t a l 300/Talc-Magnesi um S i 1ic a t e 94.15
Let Down:
(Premix a l l t h e f o l l o w i n g i n g r e d i e n t s and t h
Beckosol 13-402/Water Reducible
A1 kyd 282.46
B u t y l C e l l o s o l v e 84.74
Ammonium Hydroxide-28% 22.60
Water 233.50
Act iv-8/Dri e r 0.94
Z i r c o n i urn 6%/Dri e r 5.65
Cobalt Naphthenate-G%/Drier 1.88
A n t i s k i n n i n g Agent 1.88
P a i n t P r o p e r t i e s : %vel
T o t a l V e h i c l e 76.27 91.98
Pigment 23.73 8.02
V o l a t i l e 54.56 68.54
Organic Solvent 19.43 26.38
Non-Volati l e 45.44 31.46
N o n - V o l a t i l e V e h i c l e 21.72 23.44
Density (lb/U.S. g a l ) : 10.00
Speci f ic G r a v i t y : 1 .20
P.V.C.: 25.50%
P/B R a t i o : 1.093
Spread @ 1 M i l : 505 F2
Coating VOC: 403 G/L
M a t e r i a l VOC: 233 G/L
en
__Ga1
14.13
0.53
0.42
0.11
0.32
1.53
2.41
3.97
add t o
32.84
11.28
3.01
28.03
0.12
0.26
0.79
0.25
Wt%
11.77
0.56
0.28
0.19
0.28
4.71
9.42
9.42
t h e g r i n d )
28.25
0.47
2.26
23.35
0.09
0.19
0.56
0.19
SOURCE: Buckman Laboratories: Formulation Suggestion: KP-10
Primers 171
Red I r o n Oxide Water R e d u c i b l e A l k v d Primer
I n q r e d i e n t s : -Lb
Pigment G r i n d :
Water 154.98 1
Busperse 39/Dispersant 5.81
Bubreak 448/Oefoamer 2.91
I g e p a l CTA 6 3 9 / S u r f a c t a n t 2.91
Zinc S u l f a t e - H e p t a h y d r a t e 1.94
B u t r o l 2 3 / M o d i f i e d Barium Meta-
b o r a t e 48.43
Red I r o n Oxide 98.86
N y t a l 300/Talc-Magnesium S i l i c a t e 193.72
Gal
18.60
0.54
0.43
0.33
0.12
1.57
2.48
8.17
Wt%
14.64
0.55
0.27
0.27
0.18
4.57
9.15
18.30
L e t Down:
(Premix a l l t h e f o l l o w i n g i n g r e d i e n t s and t h e n add t o t h e g r i n d . )
C a r g i l l 7464/Water R e d u c i b l e A l k y d 248.93 28.78 23.51
Secondary B u t y l A l c o h o l 86.21 12.81 8.14
Ammonium Hydroxide-28% 9.69 1.29 0.91
Water 200.50 24.07 18.94
C o b a l t Naphthenate-6%/Orier 1.94 0.26 0.18
Z i r c o n i um 6%/Dri e r 3.87 0.54 0.37
Pai n t P r o p e r t i as:
T o t a l V e h i c l e 67. ao 87.66
Pigment 32.20 12.34
V o l a t i 1e 49.71 67.42
Organic S o l v e n t 16.14 24.74
Non-Vol a t i 1e 50.29 32.58
N o n - V o l a t i l e V e h i c l e 18.08 20.24
D e n s i t y (lb/U.S. g a l ) : 10.59
S p e c i f i c G r a v i t y : 1.27
P.V.C.: 37.88%
P/B R a t i o : 1.781
Spread I3 1 M i l : 523 F2
C o a t i n g VOC: 357 G/L
M a t e r i a l VOC: 205 G/L
SOURCE: Buckman L a b o r a t o r i e s : F o r m u l a t i o n Suggestion: KP-09
I72 Water-Based Paint Formulations
Rust Inhibitive Chromate Primer
Material:
Water
Tamol 731
Triton CF-10
Nopco NDW
Ethylene Glycol
Dowicil 75
Kelecin 1081
Mix at low speed:
Titanox 2101
Zinc Chromate Y539D
Oncor M50
Mica 325
Snowf1 ake
Lampblack #877
QP-4400
Lbs. Gals .
136.0 16.33
16.0 1.85
3.0 0.34
2.0 0.27
26.0 2.80
0.5 0.02
2.0 0.24
200.0 6.01
15.0 0.52
30.0 0.88
33.0 1.41
100.0 4.43
4.0 0.37
1.2 0:1 1
Grind under high shear 15-20 minutes.
NOTE: Do not allow temperature to exceed llOF during grind.
Under low speed add letdown:
Nopco NDW 1.5 0.20
Arolon 820-W-49 500.0 57.08
Ammoni a 7.0 0.84
Diethylene Glycol Monobutyl Ether 6.0 0.76
Diethylene Glycol Monobutyl Ether Acetate 6.0 0.73
Preblend :
Aroplaz 1271 or 1272
Triton CF-10
Water
25.7 3.08
1.3 0.15
4.0 0.48
Analysis:
Pigment/Binder Ratio: 1.37/1
Pounds/Gallon: 11.33
Percent Nonvolatile, Weight: 58.5
Percent Nonvolatile, Volume: 43.4
Pigment Volume Concentration, Percent: 31 .O
pH: 8.8
Viscosity @ 25C, KU: 75-78
60/20 Gloss: Flat
Grind Hegman: 4-5
VOC (excluding water):
Grams/Liter: 1 1 3.0
Pounds/Gallon: 0.94
SOURCE: Reichhold Chemicals, Inc.: Arolon 820: Formula 5-3
Primers 173
S o l v e n t R e s i s t a n t , Water-Reducible EPOXV Primer
M a t e r i a l :.
P a r t A:
Epi -Rez 5522-W-55 Resin
D i acetone A1coho1
T r i t o n X-100 S u r f a c t a n t
Water
C o l l o i d 640 Defoamer
R0-4097 Kroma Red, Red I r o n Oxide
Zeeospheres Type 600
Pebble m i l l a p p r o x i m a t e l y 18 hours
Epi -Rez 5522-WY-55 Resin
Water
P a r t 6:
Epi-Cure 8290-Y-60 C u r i n g Agent
Water
Composite Blend: V i s c o s i t y
P a r t A 64 K.U.
P a r t 0 58 K.U.
P a r t s A t B 85 K.U.
Pounds
200.0
6 . 6
5.0
84.8
3 . 5
104.4
307.1
187.2
39.5
118.3
55.0
938.1
173.3
Gal 1ons
22.35
0.84
0 . 5 6
10.18
0.41
2 . 4 5
17.55
20.92
4.74
13.40
6.60
80.00
20.00
T y p i c a l C o a t i n g P r o p e r t i e s :
T o t a l Weight S o l i d s , %: 6 2 . 6
T o t a l Volume S o l i d s , %: 49.2
P.V.C., %: 40.7
V o l a t i l e Organic Compounds (VOC):
Pounds/Gal 1on : 1 .37
Grams/Li t e r : 164
I n d u c t i o n Time, minutes: 30
Resin Composition (based on s o l i d s ) :
Epoxy Resin, %: 75.0
C u r i n g Agent, %: 25.0
T o t a l , %: 100.0
Reduction f o r Conventional Spray (by volume):
P a r t s A and 6 : 36 p a r t s
Water: 1 p a r t
SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1808:
Epi-Rez 5522-W-55 Resin/Epi-Cure 8290-Y-60 C u r i n g Agent
174 Water-Based Paint Formulations
TT-P-1975 Federal S D e c i f i c a t i o n Metal Primer
I n q r e d i e n t s :
Pigment Grind:
Water
C e l l o s i ze Hydroxyethyl C e l l u l ose ER-15M
Dispersant ( 1 )
Nonionic Surfactant (2)
Ethylene Glycol
B u f f e r (3)
Antifoam (4)
Preservative ( 5 )
Titanium Dioxide (6)
I n h i b i t i v e Pigment (7)
Mica (8)
Calcium Carbonate (9)
Pounds
266.4
1.o
15.2
2.7
26.8
2.0
2.4
2.7
133.9
89.2
35.7
46.5
Gal l o n s
32.0
0.1
1.7
0.3
2.9
0.3
0.3
0.3
3.9
2.7
1.5
2.1
Let Down:
B u t y l C a r b i t o l Solvent--Premix w i t h : 7.2 0.9
Ucar Thickener SCT-275 8.2 1 .o
Ucar Latex 163 423.6 47.6
Antifoam (4) 4.8 0.6
Mildewcide (IO) 5.8 0.6
Ammonium Hydroxide, 28% Aqueous S o l u t i o n 9.0 1.2
Suppl ie r s :
(1) Dispersant - C o l l o i d l l l M ( C o l l o i d s ) o r equivalent.
(2) Nonionic Surfactant - T r i t o n CF-10 (Rohm and Haas) o r
(3) B u f f e r - AMP 95 (Angus) o r equivalent.
(4) Antifoam - C o l l o i d 770 ( C o l l o i d s ) o r equivalent.
(5) Preservative - Nuosept 95 (Huls) o r equivalent.
(6) Titanium Dioxide - Ti-Pure R-900 (DuPont) o r equivalent.
(7) I n h i b i t i v e Pigment - N a l z i n 2 (NL Chemicals) o r equivalent
(8) Mica - 325 WG Mica (KMG Minerals) o r e q u i v a l e n t .
(9) Calcium Carbonate - Snowflake (Thompson, Weinman) o r
equivalent.
equi Val ent .
(IO) Mildewcide - Polyphase AF-1 (Troy) o r equivalent
Paint Properties:
Pigment Volume Concentration (PVC), %: 27.9
T o t a l Solids, % by Volume: 36.5
SOURCE: Ucar Emulsion Systems: Ucar Latex 163: Formulat
Suggestion LP-2085
on
Rimers 175
Universal Primer
I n q r e d i e n t s :
P i gment Grind:
Water
Methyl C a r b i t o l Solvent
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
Tamol 165
Surfynol CT-111
Drewplus L-475
Aerosi 1 R-972
T i -Pure R-900
M i c r o t a l c MP 12-50
Busan 11-MI
Water
Letdown :
B u t y l C a r b i t o l Solvent
Ucar Latex 461
Ucar F i l m e r I B T ) Premix
S a n t i c i z e r 160 )
Sodium N i t r i t e ) Premix
Water 1
Water
Ammoni um Hydroxide, 28% Aqueous Sol u t i on
Ucar Polyphobe 102 Rheology M o d i f i e r
Pai n t P r o p e r t i es :
Arcosolv PNB 1
Pigment Volume Concentration, %: 22.4
Volume Solids, %: 38.0
Weight S o l i d s , %: 49.5
Weight per Gallon, l b : 10.2
Stormer, KU: 85
I C I , Poise: 0.9
pH value: 8.5-9.5
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5
Heat-Age S t a b i l i t y , 120F, weeks passed: 4
VOC, grams per l i t e r : 225
Pounds
51 . 5
50.4
2.0
8.1
4.0
2.0
3.0
121.o
61 .7
50.0
60.8
21.2
521.2
10.1
10.1
2.3
2.4
20.2
10.7
1.5
5.5
Gallons
6.18
5.93
0.26
0.92
0.48
0.27
0.19
3.57
2.74
2.08
7.30
2.66
59.91
1.37
1.27
0.24
0.14
2.42
1.28
0.20
0.59
F i l m P r o p e r t i e s :
Sheen, 85: 5 max
Prohesion Corrosion Weathering Cycle, hours passed: 800
Cleveland Humidity, hours passed: 800
Tanning/Stai n i ng Resistance: Good
Tape Adhesion (ASTM 0-33): E x c e l l e n t
S a l t Fog, hours: 48 max
SOURCE: Ucar Emulsion Systems: Formulation Suggestion E-18138
176 Water-Based Paint Formulations
Universal Primer
Non-Li f t ing and H i g h S a l t Spray Resistance
I n s r e d i e n t s :
Aroplaz 3859-2-80
Calcium Chem-All 8%
Premix:
Red I r o n Oxide 5-3106
Phosguard 5-0806
10 AS Wollastocoat
399 Talc
Methyl I s o b u t y l Ketone
Disperse t o 135F and 5 n.s.u.
MPA-1078
To1uene
VM & P Naphtha
Aroplaz 3859-2-80
Cobalt Chem-A1 1 12%
Z i r c o n i um Chem-All 12%
nButyl Alcohol
Skino #2
PM Acetate
& Gals
245.30 27.72
6.00 0.81
9.00 1.13
100.00 2.40
138.60 5.20
121.oo 5.00
103.50 4.60
133.30 19.99
13.50 1.86
68.80 11.24
123.20 13.92
1 .25 0.15
3.75 0.47
25.80 3.82
3.00 0.39
16.53 2.16
Formulation Constants
Non V o l a t i l e by Weight: 0.69 VOC g r a m s / l i t r e : 410.71
Non V o l a t i l e by Volume: 0.48 VOC l b s . / g a l . : 3.43
PVC : 0.35 Weight per Gallon: 11.03
CPVC: 0.45 P i gment Content: 0.42
PVC/CPVC : 0.79
1. Can be re-coated w i t h powerful s o l v e n t - c o n t a i n i n g topcoats.
2. Very h i g h s a l t spray r e s i s t a n c e - 3000 hours a t 3 m i l s .
3. Fast d r y i n g i n t h i n f i l m s .
4. Must be f u l l y cured before t o p coated.
5. Ready t o spray w i t h o u t d i l u t i o n .
6. Touch d r y i n approximately 8 minutes.
SOURCE: Nyco Minerals, Inc.: Suggested Formulation
N o n - l i f t i n g epoxies, urethanes, and alkyds.
Primers 177
Water-Base Acrylic Universal Primer Using
Halox SZP-391 & EJW-100
Grind: Lbs./100 Gals. Gms/Liter
Add t h e f o l l o w i n g i n order l i s t e d w h i l e mixing a t low speed:
Water 125.0 150.0
Nopco NDW 1.5 1.8
Natrosol 250MBR 1 .o 1.2
Aqua Ammonia 28% 1 .o 1.2
Mix f o r 5 minutes then add t h e f o l l o w i n g raw material i n order
l i s t e d :
Ethylene G1ycol
Tamol 681
T r i t o n CF-10
T i -Pure R-902
Zinc Oxide
Halox SZP-391
Halox BW-100
Snowf 1ake
High speed disperse t o 5+ Hegman g r i n d
Letdown :
Rhopl ex MV-23
Texanol
Skane M-8
Nopco NDW
30.0 36.0
18.5 27.8
3.0 3.6
150.0 180.0
10.0 12.0
50.0 60.0
50.0 60.0
130.0 156.0
490.0 588.0
8.0 9.6
2.0 2.4
1 .o 1.2
Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l uniform. Then
slowly add t h e f o l l o w i n g raw material w h i l e mixing a t high
speed. Do not aerate!
OR-708 Thickener 5.5 6.6
Mix u n t i l uniform and add t h e following:
Water 58.0 70.0
Mix u n t i l uniform.
Formula Constants:
% Pigment/Wt. : 34.55
% Pigment/Vol.: 14.76
% Solids/Wt.: 54.55
96 Sol ids/Vol .: 38.71
46 PVC: 38.14
VOC. l b s . / g a l . : 1.14
VOC, g/L: 136.82
Formula Properties:
Density 1bs. /gal. : 1 1 .35
Density g/L: 1 ,367.4
KU Visc. @ R.T.: 90-95
pH @ R.T.: 9.0-9.5
SOURCE: Halox Pigments: Suggested Formulation MV-23/391-100
178 Water-Based Paint Formulations
Water-Base A c r y l i c U n i v e r s a l Primer Using
Halox SZP-391 (L X t a i n A
Q r i nd: Lbs./100 Gals Gms/Liter
Add t h e f o l l o w i n g i n order l i s t e d w h i l e mixing a t low speed.
Water
Nopco NDW
Natrosol 250MBR
Aqua Ammonia 28%
125.0 150.0
1.5 1.8
1.o 1.2
1.o 1.2
Mix f o r 5 minutes then add t h e f o l l o w i n g raw m a t e r i a l i n order
l i s t e d :
Ethylene G1ycol
Tamol 681
T r i t o n CF-10
T i -Pure R-902
Zinc Oxide
Halox SZP-391
Halox X t a i n A
Snowf 1ake
High speed disperse t o 5+ Hegman g r i n d
Letdown :
Rhoplex MV-23
Texanol
Skane M-8
Nopco NDW
30.0 36.0
18.5 27.8
3.0 3 . 6
150.0 180.0
10.0 12.0
50.0 60.0
5.0 6.0
175.0 210.0
490.0 588.0
8.0 9 . 6
2.0 2.4
1.o 1.2
Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l uniform. Then
s l o w l y add t h e f o l l o w i n g raw m a t e r i a l w h i l e m i x i n g a t h i g h
speed. Do n o t a e r a t e !
QR-708 Thickener 5.5 6.6
Mix u n t i l u n i f o r m and add t h e f o l l o w i n g :
Water 58.0 70.0
Mix u n t i l uniform.
Formula Constants:
% P i gment/Wt .: 34.56
% Pigment/Vol .: 14.81
% Solids/Wt.: 54.57
% Solids/Vol .: 38.76
% PVC: 38.20
VOC, l b s . / g a l . : 1.14
VOC, g/L: 136.69
Formula P r o p e r t i e s :
Density l b s . / g a l . : 11.35
Density g/L: 1,367.4
KU V i s c . @ R.T.: 90-95
pH @ R.T.: 9.0-9.5
SOURCE: Halox Pigments: Formulation MV-23/3BlXA
Primers 179
Waterborne Black Iron Oxide Primer
Based on EDotuf 37-143/37-680
(Formula No. 3019-38A)
Component A:
Arcosolv PTB
Dowanol PPH
Add f o l l o w i n g i n order under a g i t a t i o n :
Epotuf 37-680
BK-5099
Wollastokup 10 ES
High speed disperse t o 5 N.S.
Add f o l l o w i n g under a g i t a t i o n :
Epotuf 37-680
Arcosolv PTB
Tap Water
Lbs
183.82
38.54
10.79
85.85
285.60
214.59
25.73
92.72
Component 8 :
Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i 1 uniform:
Epotuf 37-143 77.43
Mineral S p i r i t s 24.71
Aromatic 150 24.71
Tap Water 33.32
Weight/Gallon (Lbs.): 10.98
Percent S o l i d s (Wt.): 55.56
Percent S o l i d s ( V o l . ) : 38.67
PVC (%I: 35.88
VOC (Lbs./Gallon): 2.50
SOURCE: Reichhold Chemicals, I n c . : Formula No. 3019-38A
Gals
20.75
5.28
1.23
2.07
11 .80
24.22
3.52
11.13
8.80
3.85
3.35
4.00
180 Water-Based Paint Formulations
Waterborne Red I r o n Oxide Primer
Based on EDotuf 37-143/37-680
I f o r m u l a No. 2954-76A)
Component A:
Arcosolv PTB
Dowanol PPH
Add f o l l o w i n g i n order under a g i t a t i o n :
R5098 Red I r o n Oxide
Wollastokup 10 ES
High speed disperse t o 5 N.S.
Add f o l l o w i n g under a g i t a t i o n :
Epotuf 37-680
Epotuf 37-680
Arcosolv PTB
Tap Water
Lbs
172.36
34.47
10.34
87.04
290.42
209.42
24.99
112.88
Component 0 :
Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l uniform:
Epotuf 37-143 72.91
Mineral S p i r i t s 24.13
Aromatic 150 24.13
Tap Water 39.07
Weight/Gallon (Lbs.): 11.02
Percent Sol i d s (Wt. ) : 54.89
Percent S o l i d s ( V o l . ) : 37.68
PVC (%I: 37.25
VOC (Lbs./Gallon): 2.46
SOURCE: Reichhold Chemicals, I n c . : Formula No. 2954-76A
Gals
19.45
4.72
1.18
2.03
12.00
23.64
3.42
13.55
8.28
3.76
3.28
4.69
Primers 181
Waterborne Red Oxide Epoxy Primer
Materi a1 :
P a r t A:
Epi -Rez 5522-WY-55 Resin
D i acetone A1coho1
Col 1o i d 640 Defoamer
Water
R0-4097 Kroma Red, Red I r o n Oxide
Sparmite Barium S u l f a t e
1OES Wollastokup
Halox SW-111
Zeeosphere 400
Water Ground Mica, 325 Mesh
High Speed Disperse t o a T e x t u r e o f 5-6 N.S
€ p i -Rez 5522-WY-55 Resin
Water
P a r t 8 :
€pi-Cure 8290-Y-60 Curing Agent
Water
Composi t e 61end: V i s c o s i t y
P a r t A
P a r t B
P a r t s A and B 70 K.U.
T y p i c a l Coating P r o p e r t i e s :
T o t a l Weight S o l i d s , %: 62.0
T o t a l Volume S o l i d s , %: 46.2
P . V . C . , %: 35.0
I n d u c t i o n Time, minutes: 30
V o l a t i l e Organic Compounds (VOC):
Pounds/Gallon: 1.23
Grams/Li t e r : 148
Resin Composi t i on :
Epoxy Resin, %: 87.6
Curing Agent, %: 12.4
T o t a l , %: 100.0
Pounds
330.0
7.0
3.5
60.0
71.1
71 . I
106.7
100.0
71 . 1
7.5
147.0
14.2
60.0
110.0
989.2
170.0
Gal l o n s
37.21
0 . 8 9
0.41
7.20
1.74
1 . 9 4
4.40
4.20
3.55
0.32
16.43
1 .71
6.80
13.20
80.00
20.00
Source: S h e l l Chemical Co.: S t a r t i n g Formulation No. 1810:
Epi-Rez 5522-WY-55 Resin/Epi-Cure 8290-Y-60 Curing Agent
182 Water-Based Paint Formulations
Waterborne Y e l l o w I r o n Oxide Primer
Based on EDotuf 37-143/37-680
(Formula No. 3019-396)
Component A:
A r c o s o l v PTB
Dowanol PPH
Add f o l l o w i n g i n order under a g i t a t i o n :
Epotuf 37-680
YD-2288
Wollastokup 10 ES
High speed disperse t o 5 N.S.
Add f o l l o w i n g under a g i t a t i o n :
Epotuf 37-680
A r c o s o l v PTB
Tap Water
&
183.41
38.45
10.77
69.43
284.95
214.11
25.88
93.71
Component 8 :
Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l uniform:
Epotuf 37-143 77.25
Mineral S p i r it s 24.55
Aromatic 150 24.55
Tap Water 33.90
Weight/Gallon ( L b s . ) : 10.81
Percent Sol i d s (Wt. ) : 54.80
Percent S o l i d s ( V o l . ) : 38.50
PVC (%): 35.89
VOC ( Lbs./Gal 1on) : 2.50
SOURCE: Reichhold Chemicals. I n c . : Formula No. 3019-398
Gals
20.70
5.72
1.22
2.07
11.77
24.17
3.55
11.25
8.78
3.82
3.33
4.07
Primers 183
Water Reducible Alkyd Yellow I r o n Oxide Primer
Using Halox SZP-391
Grind:
Chempol 10-0091
Butyl Cel losolve
DMEA
Aqua Ammonia (28%)
Y.I.O. YO-2087
Halox SZP-391
Beaverwhit e 325
Snowf1ake
Bentone SD-1
Disperse a t high speed t o 4+ NS grind.
Letdown :
Chempol 10-0091
DMEA
Aqua Ammonia (28%)
Cobalt Hydro-Cure 5%
Cal c i um Hydro-Cure 5%
Zirconium Hydro-Cure 12%
Active 8
Byk 301
n-Butanol
Add slowly while mixing.
Water
Lbs./100 Gals. Gms/Liter
200.0 240.0
55.0 66.0
4 . 0 4 . 8
4 . 0 4 . 8
75.0 90.0
33.0 40.0
75.0 90.0
75.0 90.0
1 .o 1.2
50.0
4 . 0
4 . 0
2 . 0
3 . 5
2 . 0
1.o
1 .o
25.0
60.0
4 . 8
4 . 8
2 . 4
4 . 2
2 . 4
1 . 2
1 . 2
30.0
400.0 480.0
Formula Constants:
% P i gment/Wt .: 25.67
% Pigment/Vol .: 10.24
% Solids/Wt.: 44.75
% S o l i ds/Vol .: 31.35
% PVC: 32.65
VOC, lbs./gal.: 2.93
VOC, g/L: 351.68
Formula Properties:
Density lbs./gal.: 10.15
Density g/L: 1,217.8
KU V i sc. @ R.T. : 80-85
pH @ R.T.: 9.0-9.5
SOURCE: Halox Pigments: Suggested Formulation WRA-301
184 Water-Based Paint Formulations
Water R e d u c i b l e A l k y d Y e l l o w I r o n Oxide Primer
U s i n s Halox CW-491
G r i n d :
Chempol 10-0091
B u t y l C e l l o s o l v e
DMEA
Aqua Ammonia (28%)
Halox CW-491
Y.I.O. YO-2087
Beaverwhi t e 325
Snowf 1ake
Bentone SD-1
D i s p e r s e a t h i g h speed t o 4+ NS g r i n d .
Letdown :
Chempol 10-0091
DMEA
Aqua Ammonia (28%)
C o b a l t Hydro-cure 5%
Calcium Hydro-cure 5%
Z i r c o n i u m Hydro-cure 12%
A c t i v e 8
Byk 301
n-Butanol
Add s l o w l y w h i l e m i x i n g .
Water
M i x u n t i l u n i f o r m .
Formula Constants:
% Pigment/Wt.: 25.67
% P i gment/Vol .: 10.24
% S o l i d s / W t . : 44.75
% Sol i d s / V o l .: 31 .35
% PVC: 32.65
VOC, l b s . / g a l . : 2.93
VOC, g/L: 351.68
Lbs./lOO Gals. Gms/Liter
200.0 240.0
55.0 66.0
4.0 4.8
4.0 4.8
75.0 90.0
33.0 40.0
75.0 90.0
75.0 90.0
1.0 1.2
50.0
4.0
4.0
2.0
3.5
2.0
1 .o
1.o
25.0
60.0
4.8
4.8
2.4
4.2
2 . 4
1 . 2
1.2
30.0
400.0 480.0
Formula P r o p e r t i e s :
D e n s i t y l b s . / g a l . : 10.15
D e n s i t y g/L: 1,217.8
KU V i s c . @ R.T.: 80-85
pH C R.T.: 9.0-9.5
SOURCE: Halox Pigments: Suggested F o r m u l a t i o n WRA-491
Primers I85
Water Reducible EDoxv-Ester Red I r o n Oxide Primer
Grind:
W/R Epoxy Ester Resin
B u t y l C e l l os01ve
Aqua Ammonia (28%)
Red I r o n Oxide
Halox SZP-391
Talc
AMP-95
Lbs/100 Gals. Gms/Liter
340.0 408.0
25.0 30.0
3.0 3 . 6
3.0 3.6
100.0 120.0
42.0 50.4
791 .O 229.2
High speed d i s p e r s e t o 4+ NS G r i n d
Letdown :
W/R Epoxy Ester Resin
B u t y l Cel l o s o l ve
Aqua Ammonia (28%)
Cobalt Hydrocure (13%)
Manganese Hydrocure (12%)
A c t i v 8
N-Butanol
Byk 301
Add s l o w l y w h i l e mixing and mix u n t i l uniform.
125.0
25.0
3.0
2.5
2.5
1.o
25.0
2.0
150.0
30.0
3 . 6
3.0
3.0
1.2
30.0
2.4
Water 175.0 210.0
Formula Constants:
% P i gment/Wt. : 31 .24
% Pigment/Vol.: 12.15
% Solids/Wt.: 52.28
% S o l i d s / V o l . : 34.70
% PVC: 34.70
VOC, l b s . / g a l . : 4.13
voc, g/L: 494.87
Formula P r o p e r t i e s :
Density l b s . / g a l . : 10.65
Oensity g / l . : 1,278.4
KU Visc. @ R.T.: 80-85
pH @ R.T.: 9.0-9.5
SOURCE: Halox Pigments: Suggested Formulation WREE39lH
186 Water-Based Paint Formulations
Water Reducible Eooxv-Ester Red I r o n Oxide Primer
Grind:
W/R Epoxy Ester Resin
Butyl Cellosolve
Aqua Ammonia (28%)
Red I r o n Oxide
Halox CW-191
Talc
AMP-95
Lbs./100 Gals. Gms/Liter
340.0 408.0
25.0 30.0
3.0 3.6
3.0 3.6
100.0 120.0
42.0 50.0
190.0 228.0
High speed disperse t o 4+ NS grind.
Letdown :
W/R Epoxy Ester Resin
Butyl Cellosolve
Aqua Ammonia (28%)
Cobalt Hydrocure (12%)
Manganese Hydrocure (12%)
A c t i v e 8
N-Butanol
BYK 301
Add slowly w h i l e mixing and mix u n t i l uniform.
125.0 150.0
25.0 30.0
3.0 3.6
2.5 3.0
2.5 3.0
1.o 1.2
25.0 30.0
2.0 2.4
Water 175.0 210.0
Formula Constants:
% P i gment/Wt .: 31 ,55
% P i gment/Vol .: 12.35
% Sol ids/Wt. : 52.54
% Solids/Vol.: 34.90
% PVC: 35.39
VOC, l b s . / g a l . : 4.12
VOC, g/L: 493.60
Formul a Properti 8s :
Density l b s . / g a l . : 10.64
Density g/L: 1,276.4
KU Visc. @ R.T.: 80-85
pH @ R.T.: 9.0-9.5
SOURCE: Halox Pigments: Suggested Formulation WREE491
Primers 187
Water Reducible Epoxy-Ester
Red Iron Oxide Primer
Using Halox CW-491
Grind:
W/R Epoxy Ester Resin
B u t y l C e l l o s o l v e
Aqua Ammonia (28%)
Red I r o n Oxide
Halox CW-491
Talc
AMP-95
Lbs. / l o 0 Gals. Gms/Li t e r
340.0 408.0
25.0 30.0
3.0 3.6
3.0 3.6
100.0 120.0
42.0 50.0
190.0 228.0
High speed disperse t o 4+ NS g r i n d .
Letdown :
W/R Epoxy Ester Resin
B u t y l C e l l o s o l v e
Aqua Ammonia (28%)
Cobalt Hydrocure (12%)
Manganese Hydrocure (12%)
A c t i v e 8
N- Butano1
Byk 301
Add slowly w h i l e mixing and mix u n t i l uniform.
125.0
25.0
3.0
2.5
2.5
1.o
25.0
2.0
150.0
30.0
3.6
3.0
3.0
1.2
30.0
2.4
Water 175.0 210.0
Formula Constants:
% P i gment/Wt .: 31 .55
% P i gment/Vol .: 12.35
% Solids/Wt.: 52.54
% S o l i d s / V o l . : 34.90
% PVC: 35.39
VOC, l b s . / g a l . : 4.12
VOC, g/L: 493.60
Formula P r o p e r t i e s :
Density l b s . / g a l . : 10.64
Density g/L: 1,276.4
KU Visc. @ R . T . : 80-85
pH @ R.T.: 9.0-9.5
SOURCE: Halox Pigments: Suggested Formulation WREE491
188 Water-Based Paint Formulations
White. Corrosion Resistant Latex Primer
Innredient s :
Pigment G r i nd:
Water
Busperse 39/Dispersant
Bubreak 448/Defoamer
Igepal CTA 639/Surfactant
C e l l o s i z e QP-l500O/Hydroxyethyl
Water
B u t r o l 23/Modified Barium Meta-
T i -Pure R-SOO/Titanium Dioxide-
Atomite/Calcium Carbonate
Mica-325 Mesh/Water Ground
Let Down:
Rhoplex MV-23/Acryl i c Emu1sion
Texanol/Ester Alcohol
Ethylene Glycol
Water
Pai n t Propert ies :
Total Vehicle 63.19
Pigment 36.81
V o l a t i l e 44.32
Organic Solvent 4.23
Non-Volatile 55.68
Non-Volatile Vehicle 18.87
Density (lb/U.S g a l ) : 11.61
S p e c i f i c G r a v i t y : 1.39
P.V.C.: 40.65%
P/B Ratio: 1.951
Spread @ 1 M i l : 617 F2
Coating VOC: 134 G/L
M a t e r i a l VOC: 59 G/L
C e l l u lose
borate
R u t i l e
!& Gal
100.12 12.02
10.01 0.93
3.00 0.44
3.00 0.34
2.00 0.17
25.03 3.00
100.12 3.25
150.19 4.51
150.19 6.65
25.03 1.07
500.62 56.89
7.01 0.89
30.04 3.23
55.07 6.61
%vel
84.36
15.64
61 .52
5.63
38.48
22.84
a
8.62
0.86
0.26
0.26
0.17
2.16
8.62
12.93
12.93
2.16
43.10
0.60
2.59
4.74
SOURCE: Buckman Laboratories: Formulation Suggestion: KP-08
Primers 189
White I n h i b i t i v e Maintenance Primer
I n a r e d i e n t s :
Pigment G r i n d :
Water
Eentone LT
Methyl C a r b i t o l S o l v e n t
Tamol 681
Nuosept 95
DeeFo HG-12
T r i t o n N o n i o n i c S u r f a c t a n t CF-10
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
A c r y s o l RM-2020
Tronox CR-828
Heucophos ZBZ
Atomi t e
Letdown :
Methyl C a r b i t o l S o l v e n t
A c r y s o l SCT-275
Ucar V e h i c l e 435
Ucar F i l m e r IET
Troysan Polyphase AF-1
Foamex 825
Sodium N i t r i t e , 15% Aqueous S o l u t i o n
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
Pounds
151.5
1 . o
25.5
18.2
2 . 3
2.1
2 . 2
1.8
17.2
100.0
50.0
125.7
8 . 5
8 . 6
505.1
1 1 . 4
4.9
2 . 1
9 . 0
1.8
loris
8.19
0 . 0 6
3.00
2.00
0.25
0.25
0.25
0.25
2.00
2.93
1.67
5.57
1.oo
1 .oo
58.06
1 . 4 4
0.50
0.25
1.08
0.25
A d j u s t t o minimum p H 8 . 7
Pai n t P r o p e r t i es :
Pigment Volume C o n c e n t r a t i o n (PVC) , %: 30.0
T o t a l S o l i d s , %:
by volume: 34.0
pH Value, i n i t i a l : 8 . 7
V i s c o s i t y :
Stormer, KU: 80
I C I , p o i s e : 0.8
Weight p e r G a l l o n , l b : 10.5
Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass
Heat S t a b i l i t y , 2 weeks a t 140F: Pass
SOURCE: Ucar Emulsion Systems: Ucar V e h i c l e 435: F o r m u l a t i o n
Suggestion M-2451
Sealants and Related Compounds 191
Ancamide 2353 Curina Aaent Aluminum Mastic
P r e l im inary Formulation
Part A:
L i q u i d DGEBA Epoxy
MPA-1078 (Rheox)
10 Wollastekup AS (Nyco)
Disperse t o 6 Hegman and 130F:
Epodil L ( A i r Products)
High Flash Naphtha
Beetle 216-8 (Cyanamid)
Lansford L243 ( S i 1b e r l i n e )
Diacetone Alcohol (Union Carbide)
Cabosil TS 720 (Cabot)
Part 8 :
Ancamide 2553 ( A i r Products)
-Lb Gal
307 31.7
8 1.0
250 10.3
35 4.0
120 16.5
25 2.8
125 10.2
24 3.0
10 0.4
169 20
Properties:
Volume S o l i d s : 71 .9% VOC: t2.5 l b gal
PVC: 20.0% Mixing Ratio 4:l by Volume
CPVC: 47.1% Pot L i f e , h r 5
PVC/CPVC: 0.426 Dry t o Touch, h r : 3
Weight/gallon, Part A: 11.29 Dry Through, h r : 7
Weight/gallon, Part B: 8.45
Wei ght/gal lon: 10.73
SOURCE: A i r Products and Chemicals, I n c . : Ancamide 2353 Curing
Agent: Table 10 Formula
192 Water-Based Paint Formulations
Clear Sealant
Inaredients :
Ucar Latex 100
T e r g i t o l Nonionic Surfactant NP-4
Nopco NXZ
Proxel GXL
Ucar Filmer I B T
Cosan 158
Propylene Glycol
Ucar Thickener 146
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
Acrysol SCT-275
Weight%
95.15
0.16
0.36
0.24
0.85
0.42
0.85
0.48
0.64
0.85
M i x i ng Procedure:
A high-shear, low-speed vacuum mixer o f t h e double-bladed
planetary type o r t h e double-bladed sigma type i s recommended.
Charge t h e l a t e x t o t h e mixer. Add t h e remaining i n g r e d i e n t s
slowly i n t h e order l i s t e d t o t h e mixer w i t h a g i t a t i o n . The
mix w i l l thicken when t h e NH40H i s added. S t i r f o r f i v e minutes
and then add associative thickener. Mixing time should be >30
m i nutes.
Sealant Properties:
Nonvolati les, % by weight: 61.9
pH Value: 8.8
Viscosity, Brookfield, P: 24,000
Semco Gunnability, g/sec: 28
ASTM C731: Pass
Tooling Time, min: >5
Boeing Slump, i n : 0 . 0
Elongation a t Break, %: 1000
Tensile Strength, max, p s i : 230
Time f o r 180-mil Bead t o D r y Clear, days: 7
Shore "A" Hardness, 7 days a t 50% R.H.: 48
SOURCE: Ucar Emulsion Systems: Ucar Latex 100: Formulation
Suggestion CC-1010
Sealants and Related Compounds 193
High-Qual it y E x t e r i o r Latex Caulk
I n g r e d i e n t s :
C o l l o i d 677
Propyl ene G1yco
T e r g i t o l Nonion
Composi t ion T
Potassium T r i p o
Tamol 983
T i -Pure R-900
Ucar Latex 100
S a n t i c i z e r 160
Organofuntional
Camel Carb
Snowf1ake
Camel Cal
Mineral Spi r its
Nuosept 95
Skane M8
Acrysol SCT-275
c Surfactant NP-40
yphosphate (KTPP)
Silane A-187
Ammoni um Hydroxi de, 14% Aqueous
Sol u t i on
Caulk Properties:
T o t a l Solids, %:
bv weiaht: 84.7
Pounds
1.8
13.6
5.5
3.0
0.5
0.9
12.7
418.0
0.5
109.0
0.6
521.6
172.7
58.2
22.7
1 . 8
2.3
5.5
Gallons
0.3
1.6
0.6
0.1
0.0
0.1
0.4
46.9
0.1
11.8
0.1
23.0
7 . 7
2.6
3.5
0.2
0.3
0 . 7
Wt%
0.13
1.01
0.40
0.22
0.04
0.07
0.94
30.94
0.03
8.07
0.05
38.63
12.78
4.31
1.68
0.13
0.17
0.40
-by volume: 74.4
Weight per Gallon, t h e o r e t i c a l , l b : 13.5
V i s c o s i t y , B r o o k f i e l d , P:
I n it i a1 : 2800
A f t e r 5 freeze-thaw cycles: 2150
Pigment Volume Concentration, %: 45
Boeing Slump: None
O F Bend: Pass
Shore "A" Hardness, 72F a t 50% R.H. :
1-day: 10
3-day: 33
7-day: 50
i n i t i a l : 9.5
a f t e r 5 freeze-thaw cycles: 9.0
Stress-Strain Properties: 32F -OF
t e n s i l e strength, max, p s i 54 67 330
elongation a t break, % 230 155 87
Semco Gunnability, g/sec:
Adhesion P r o p e r t i es : 180 Peel Adhesion*, p l i
Substrate Drv 24-hr. Water Soak
G1ass 20.7 (COH) 15.1 (COH)
A1umi num 21.9 (COH) 13.2 (COH)
Concrete 20.5 (COH) 12.7 (AO/COH)
Hypalon Sheet 13.8 (COH) 12.9 (COH)
* COH=cohesive f a i 1ure
A 0 =adhesive f a i 1ure
SOURCE: Ucar Emulsion Systems: Ucar Latex 100: Formulation
Suggestion CP-1001
194 Water-Based Paint Formulatiom
Patchina C o l w u n d (Brushina Grader
I n q r e d i e n t s :
Pi gment G r i nd :
Ucar Latex 163
Wetting Agent (1) S l u r r y o f :
Water
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
Antifoam (2)
Dispersant (3)
Preservative ( 4 )
Calcium Carbonate (5)
Mica ( 6 )
Titanium Dioxide ( 7 )
M i 1dewci de (9)
Let Down:
Coarse S i l i c a (10)
Mineral Spi r it s
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
Ethylene Glycol
Suppl ie r s :
*Post Added
Pounds
667.5
1.7
8.3
1 . 5
3.9
3.1
0 . 8
90.0
25.8
65.6
4.5
286.7*
3.4
3.4
17.6
Gallons
75.0
0.2
1.o
0.2
0.5
0.3
0.1
4.0
1.1
2.1
0.3
12.2
0.6
0.5
1.9
Wetting Agent - Surfynol 104 ( A i r Products) o r equivalent.
Antifoam - C o l l o i d 770 ( C o l l o i d s ) o r equivalent.
Dispersant - C o l l o i d 226/35 ( C o l l o i d s ) o r equivalent.
Preservative - Cosan 101 (Cosan) o r equivalent.
Calcium Carbonate - Duramite (Thompson, Weinman) or
equivalent.
Mica - 325 WG Mica (KMG Minerals) o r equivalent.
Titanium Dioxide - Ti-Pure R-901 (DuPont) o r equivalent.
S i l i c a - C e l i t e 281 (Johns-Manville) o r equivalent.
Mildewcide - Nopcocide N-96 (Diamond Shamrock) o r
equivalent.
Coarse S i l i c a - Ruff B u f f (Tammsco) o r equivalent.
Patching Compound P r o p e r t i8s:
Pigment Volume Concentration (PVC) , %: 31 .7
Total Solids, %:
by Volume: 60.4
by Weight: 71.6
SOURCE: Ucar Emulsion Systems: Ucar Latex 163: Formulation
Suggestion V-2084
Sealants andRelated Compounds 195
Patchins Compound (Trowel Gradel
I n a r e d i e n t s :
Pigment Grind:
Ucar Latex 163
Wetting Agent (1) S l u r r y o f :
Water
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
T e r g i t o l Nonionic Surfactant NP-40
Antifoam (2)
Dispersant (3)
Preservative ( 4 )
Calcium Carbonate (5)
Mica (6)
Titanium Diox
S i l i c a (8)
Mildewcide (9
Let Down:
Coarse S i 1i c a
Pounds
685.3
8.6
1.7
1 .l
1.7
3.5
0.8
219.3
-----
Gallons
77.0
1 .o
0.2
0.1
0.2
0.3
0.1
9.7
----
25.8 1.1
64.4 2.1
64.6 3.4
5.1 0.3
34.5 1.6
3.4 0.5Mineral S p i r i ~
Ammonitim Hvdrnxida. 3R% A a t i e n u s S n l u t i n n 3 . 4 0 . 5........-.. . -... ..,-. -...--, --.- . .------ -- . - - .-.. - . .
Ethylene Glycol 17.2 1.9
Suppliers:
( 1 ) Wetting Agent - Surfynol 104 ( A i r Products) o r equivalent
(2) Antifoam - C o l l o i d 770 ( C o l l o i d s ) o r equivalent.
(3) Dispersant - C o l l o i d 226/35 ( C o l l o i d s ) o r equivalent.
(4) Preservative - Cosan 101 (Cosan) o r equivalent.
(5) Calcium Carbonate - Duramite (Thompson, Weinman) o r
(6) Mica - 325 WG Mica (KMG Minerals) o r equivalent.
(7) Titanium Dioxide - Ti-Pure R-901 (DuPont) o r equivalent.
(8) S i l i c a - C e l i t e 281 (Johns-Manville) o r equivalent.
(9) Mildewcide - Nopcocide N-96 (Diamond Shamrock) o r
(10) Coarse S i l i c a - Ruff B u f f (Tammsco) o r equivalent.
equivalent.
equivalent.
Patching Compound Properties:
Pigment Volume Concentration (PVC), %: 29.7
Total Solids, %:
by Volume: 59.9
by Weight: 70.7
SOURCE: Ucar Emulsion Systems: Ucar Latex 163: Formulation
Suggestion V-2083
1% Water-Based Paint Formulations
PiQlented Caulk Formulation
based on 2:l V i n y l A c r v l i c / A c r v l i c Blend
I n a r e d i ents:
Ucar Latex 161
Ucar Latex 163
T r i t o n Nonionic Surfactant X-405
Nopco NXZ
Propylene G1ycol
Ammonium Hydroxide, 14% Aqueous S o l u t i o n
Cosan 234
Acrysol SCT-200
S a n t i c i z e r 160
S i l a n e A-187
Mineral Spi r it s
Pounds
269.5
127.7
5.0
1.6
12.5
0.4
6.0
0.5
99.8
0.6
20.8
Blend 10 minutes, then add t h e f o l l o w i n g :
Tamol 850 1.2
Composit ion T 3.3
T i -Pure CR-800 14.0
W i ngdal e White 576.2
Potassium Tripolyphosphate (KTPP) 0.5
Microwhite 25 254.0
Ammonium Hydroxide, 28% Aqueous S o l u t i o n 0.8
Gallons
30.12
14.40
0.60
0.20
1.50
0.05
0.70
0.06
10.70
0.07
3.20
0.15
0.40
0.81
25.50
0.02
11.40
0.12
Disperse a t h i g h speed u n t i l uniform i n consistency ( t y p i c a l l y
Typical Properties:
T o t a l Solids, %:
10-30 minutes) .
by weight: 83.9
by volume: 73.6
Pigment :B i nder Ratio: 3.2:1
P l a s t i c i z e r on Latex S o l i d s , 96: 44.9
SOURCE: Ucar Emulsion Systems: Ucar Latex 161: Formulation
JDD-995
Sealants and Related CompoundF 197
Premi um-Performance. Medium-F1 e x i b i 1it y Caul k
Inaredients:
Ucar Latex 163
Surfactant (1)
Surfactant (2)
P l a s t i c i z e r (3)
Tooling Agent (4)
Ethylene Glycol
Water
Cal c i um Carbonate (5)
T i t a n i um Dioxide (6)
Ammonium Hydroxide, 28%
Sol u t ion
Pounds
485.0
6 . 5
8 . 5
93.5
19.0
12.5
32.5
583.0
10.0
0 . 5
Aqueous
Gallons
54.5
0.7
0.4
10.1
2.9
1.4
3.9
25.8
0.3
---
K%
38.8
0.5
0 . 7
7.5
1.5
1.o
2.6
46.6
0.8
---
Suppl iers :
(1) Surfactant - T r i t o n X-405 (Rohm and Haas) o r equivalent.
(2) Surfactant - Composition R (Merck) o r equivalent.
(3) P l a s t i c i z e r - S a n t i c i z e r 160 (Monsanto) o r equivalent.
(4) Tooling Agent - Varsol No. 1 (Exxon) o r equivalent.
(5) Calcium Carbonate - Atomite (Thompson, Weinman) o r
(6) Titanium Dioxide - Ti-Pure R-901 (DuPont) o r equivalent.
equivalent.
Seal ant Properties :
Total Solids, % by w t : 79.0
Weight per Gallon ( t h e o r e t i c a l ) , l b : 12.5
F i l l e r / L a t e x Solids Ratio: 2.1/1.0
P l a s t i c i z e r (on t o t a l binder s o l i d s ) , % by w t : 26.0
Shore "A" Hardness ( 4 wks a t 73F, 50% RH): 27
Tensile Strength ( 2 w k s a t 73F, 50% RH), p s i : 13
Elongation ( 2 wks a t 73F, 50% RH), %: 460
180 Peel Adhesion (per i n ) :
Pinewood: 9 (adhesive)
Aluminum: 11 (cohesive)
Glass: 12 (cohesive)
Extrusion: Good g u n n a b i l i t y
ASTM Shrinkage (28 days a t 73F, 50% RH)
Slump a t Room Temperature: None
Recovery (25% Extension RT f o r 1/2 h r ) ,
SOURCE: Ucar Emulsion Systems: Ucar Latex
Suggestion K-2080
%: <25
%: >80
63: Formulation
198 Water-Based Paint Formulations
Sealant A ~ p l i c a t i o n
Inqredients:
Ucar Latex 163
Surfactant (1)
P l a s t i c i z e r (2
Tool ing Agent
Water
Ethvlene Glvco
3)
Calcium carbonate ( 4 )
Extender (5)
Surfactant (6)
Titanium Dioxide ( 7 )
Weiqht%
33.00
0.70
9.00
2.00
1.50
1 .oo
48.00
3.00
1.oo
0.80
Suppl ie r s :
( 1 ) Surfactant - T r i t o n X-405 (Rohm and Haas) o r equivalent.
(2) P l a s t i c i z e r - Benzoflex 9-88 ( V e l s i c o l ) or equivalent.
(3) Tooling Agent - Varsol No. 1 (Exxon) o r equivalent.
(4) Calcium Carbonate - Atomite (Thompson, Weinman) o r
(5) Extender - Barytes No. 1 (Williams) o r equivalent.
(6) Surfactant - Composition T (Merck) o r equivalent.
( 7 ) Titanium Dioxide - Ti-Pure R-901 (OuPont) o r equivalent.
equivalent.
Sealant Properties:
Nonvolatiles, %: 83.3
F i l l e r / L a t e x Solids Ratio: 2.6/1.0
P l a s t i c i z e r t o Latex Solids, %: 31.2
Weight per Gallon, l b : 12.5
24-hr Extrusion Rate, g/sec: 3
Shore "A" Hardness, 1 month: 22
Tensile Strength, p s i : 8
Elongation, %: 158
Accelerated Weathering, XW, Wooden Channel, 1000 h r :
Very good
SOURCE: Ucar Emulsion Systems: Ucar Latex 163: Formulation
Suggestion K-2079
Sealants and Related Compouna!s 199
Translucent Caulk Formulation
Inaredients: Lb/100 Gal Gallons
Ucar Latex 105 758.16 89.09
Antifoam (1) 0.59 0.08
Ucar Filmer IBT 6.18 0.87
Ammonium Hydroxide, 28% Aqueous S o l u t i o n 5.88 0.78
Ethylene Glycol 9.81 1.06
Nonionic Surfactant ( 2 ) 1.96 0.26
Dispersant (3) 1.96 0.22
S i l i c a (4) 24.52 1.34
P l a s t i c i z e r (5) 53.94 5.83
Union Carbide Organofunctional Silane A-187 3.92 0.44
Preservative (6) 2.94 0.39
T e r g i t o l Nonionic Surfactant NP-10 2.94 0.35
Suppl ie r s :
(1) Antifoam-Nopco NXZ (Henkel) o r equivalent.
(2) Nonionic Surfactant - Surfynol 104E ( A i r Products) o r
(3) Dispersant - Disperse-Ayd W-22 (Daniel) o r equivalent.
(4) S i l i c a - Cab-0-Si1 L-90 (Cabot) o r equivalent.
( 5 ) P l a s t i c i z e r - S a n t i c i z e r 160 (Monsanto) o r equivalent.
(6) Preservative - Nuosept 95 (Huls) o r equivalent.
equi Val ent .
Typical P r o p e r t i 8s:
pH Value: 7.2
T o t a l Solids, %:
by Weight: 60.2
by Volume: 55.1
B r o o k f i e l d V i s c o s i t y , P: 31,000
Typical Performance Properties:
Boei ng S1ump: Passed
Semco Gunnability, g/sec: 32
A f t e r 5 Freeze-Thaw Cycles: 11
A f t e r 14-day Heat Aging: 34
7-day d r y : 30
14-day d r y : 30
Shore A:
ASTM C679 Tack: Passed
ASTM C794 180 Peel Adhesion, p l i :
Dry Glass: 33.8
Dry Aluminum: 31.3
Wet Glass (7-day immersion): 15.0
Wet Aluminum: 14.0
ASTM C793: Passed
SOURCE: Ucar Emulsion Systems: Ucar Latex
Suggestion CT-2002
05: Formu a t i o n
200 Water-Based Paint Formulations
Translucent Caulk Formulation
Ingredients:
Ucar Latex 169
Nopco NXZ
Ammonium Hydroxide, 28% Aqueous
Ethylene G1ycol
Surfynol 104E
Daniels WO-22
Cab-0-Si 1 L-90
Santicizer 160
Organof u n c t i onal S i 1ane A-1 87
Nuosept 95
T e r g i t o l Nonionic Surfactant NP-
Pounds
758.5
0.6
Sol u t i on 6.3
14.4
2.1
2.1
26.4
58.2
4.2
3.2
,lo 3.2
Typical Properti8s:
Total Solids, % by weight: 63.5
pH: 7.2
Viscosity, Poise: 31,000
Tensile, p s i , maximum: 64
Elongation a t break, %: 990
Water Absorption, %, 7 days: 31.6
Formulation CT-2012
ASTM C-920 Pigmented Caulk Formulation
Ingredients:
Santicizer 160
Potassi um Tripolyphosphate (KTPP)
T r i t o n Nonionic Surfactant X-405
Oaxad 30-30
Pounds
106.1
1.8
13.5
Proxel GXL
Cosan 101
Ucar Latex 169
Snowf 1ake
T i -Pure R-902
Mineral S p i r i t s
Organofunctional S
Ammoni um Hydroxide
Methocel 856
Propylene G1ycol
Acrysol ASE-60
1.8
1 .o
1.5
481.1
532.7
12.9
25.1
lane A-187 1.2
28% Aqueous Solution 1.3
2.1
14.6
9.3
Gal 1ons
87.90
0.09
0.84
1.56
0.28
0.24
1.44
6.28
0.47
0.42
0.38
Gallons
11.46
0.08
1.53
0.19
0.13
0.19
55.48
23.65
0.39
3.97
0.14
0.17
0.18
1.68
1.06
Typical Properti 8s
Total Solids, %: Tensile, psi, maximum: 90
Pigment:Binder: 1.8:l Shore A Hardness: 30
SOURCE: Ucar Emulsion Systems: Ucar Latex 169: Suggested
by weight: 79.5 Elongation a t Break, %: 270
by volume: 70.7 Water Absorption, %, 7 days: 11.3
Formu1a tiono
Sealants and Related Compounds 201
Trans1ucent Seal ant
Inqredi ents:
Ucar Latex 100
Nopco NXZ
Ucar Filmer IBT
Ammoni um Hydroxi de, 14% Aqueous
Propyl ene G1ycol
Surfynol 104
D i sperse-ayd W-22
Cab-0-Si1 LM-130
Organofunctional Silane A-187
So1u t i on
Pounds
815.50
0.68
7.13
13.53
11.32
2.22
2.29
28.04
3.36
42
28
Nuisept 95 3.
T e r g i t o l Nonionic Surfactant NP-10 3
Caulk Properties:
Total Solids, % by weight: 61.2
pH Value: 9.4
Weight per Gallon, t h e o r e t i c a l , l b :
Viscosity, Brookfield, P: 27,800
Boeing Slump: None
Semco Gunnability, g/sec:
i n i t i a l : 24
a f t e r 5 freeze-thaw cycles: 24
glass: >50
a1umi num: >50
Hunter Lab Color:
L: +93.24
a: -0.59
180 Peel Adhesion, Dry, p l i :
b: -0.78
3.5
Gallons
92.67
0.09
1.oo
1.71
1.31
0.30
0.26
1.53
0.39
0.36
0.39
Wei qht%
91.47
0.08
0.80
1.52
1.27
0.25
0.25
3.16
0.40
0.40
0.40
Y I E : -0.93
ASTM C732 Weathering-500 Hours: no cracking
no d i s c o l o r a t i o n
no adhesion loss
SOURCE: Ucar Emulsion Systems: Ucar Latex 100: Formulation
Suggestion CT-2008
202 Water-Bared Paint Formulatwns
V i n y l Acrvl ic Seala n t
Ingredients :.
Ucar Latex 161
Kathon LX (1.5%) ( 1 )
Tamol 850
Ethylene Glycol
S a n t i c i z e r 160
Mineral S p i r i t s
Natrosol 250 MXR
Potassi um Tripolyphosphate (KTPP)
Camel F i l
T i -Pure R-902
T r i t o n Nonionic S u r f a c t a n t X-405
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
T y p i c a l P r o p e r t i e s :
T o t a l S o l i d s , %:
by weight: 82.2
by volume: 78.2
Pigment Volume Concentration (PVC): 46.9
Pigment:Binder R a t i o : 3:l
P l a s t i c i z e r on Latex S o l i d s , %: 40.0
Elongation a t Break, %: 722.0
Boeing Slump: Pass
ASTM C-731: Pass
ASTM C-732 Weathering: No bond l o s s
ASTM C-734 OF Bend: Pass
ASTM C-736 Extension-Recovery: Pass
Water Absorption, 7 days, %: 41.9
Pounds
450.0
1.3
1.3
12.4
99.0
20.0
3.0
1 .o
729.4
15.0
9.1
0.5
Gal 1ons
50.34
0.15
0.14
1.34
10.69
3.07
0.05
32.42
0.45
1 .oo
0.07
0.28
SOURCE: Ucar Emulsion Systems: Ucar Latex 161 : Formulation CM-294
Sealants and Related Compowrds 203
Weather-Barrier Mastic
I n a r e d i ents:
P igment G r ind:
Water
C e l l o s i z e Hydroxyethyl C e l l u l o s e
D i spersant ( 1)
Potassium Tripolyphosphate
E t h y l ene G1ycol
Antifoam (2)
Titanium Dioxide (3)
Calcium Carbonate (4)
Zinc Oxide (5)
M i ldewcide (6)
Let Down:
Ucar Latex 163
Ucar F i l m e r I B T
Antifoam (2)
Pounds
150.0
QP-4400H 4.0
4.0
1.o
20.0
1.5
62.0
407.0
40.0
5.0
Gallons
18.0
0.3
0.4
2.2
0.2
1.9
18.1
0.9
0.5
---
502.0 56.4
6.0 0.8
2.0 0.3
Suppl ie r s :
(1) Dispersant - C o l l o i d 226/35 ( C o l l o i d s ) o r equivalent.
(2) Antifoam - Nopco NXZ (Diamond Shamrock) o r equivalent.
(3) Titanium Dioxide - "Ti-Pure" R-960 (DuPont) o r equivalent
(4) Calcium Carbonate - "Atomite" (Thompson, Weinman) o r
(5) Zinc Oxide - AZO-55 (ASARCO) o r equivalent.
(6) Mildewcide - Nopcocide N-96 (Diamond Shamrock) o r equiv-
equi Val ent .
a1e n t .
Mastic P r o p e r t i e s :
Pigment Volume Concentration (PVC), %: 40.0
T o t a l Solids, %:
by Volume: 53.0
by Weight: 67.3
F i l m Properties*:
Tensi 1e Propert ies :
S t r a i n Rate, %: 20 100 200
Stress, p s i : 120 120 200
Elongation, %: 420 300 260
200S t r a i n Rate, in/min: --- ---
70Stress, p s i : --- ---
800Elongation, %: --- ---
T e n s i l e P r o p e r t i e s a f t e r 7 days water immersion:
Water Ponding: Water Transmission a t 24 h r : 210 mg water
Low-Temperature F l e x i b i l i t y : 180 Bend a t -4F: No c r a c k i n g
Water Vapor Transmission Rate f o r 336 h r , perms: 5.7
Adhesion t o Urethane Foam, 180 Peel, l b / i n :
Dry: 7.8 (Foam Cohesion F a i l u r e )
Wet-7 days immersion i n water: 2.2 (Foam Cohesion F a i l u r e )
*Dried and conditioned 7 days a t 72F and 50% RH
SOURCE: Ucar Emulsion Systems: Ucar Latex 183: Formulation
Suggestion WB-2081
204 Water-Based Paint Formulations
Weather-Barrier Mastic
The f o l l o w i n g formulation has undergone extensive e x t e r i o r
exposure and provides improved resistance t o d i r t and d a r l y
chal k i ng :
Inqredients:
Piament O r ind :
Wa:er
Dispersant ( 1)
Potassi um Tripolyphosphate
Wetting Agent (2)
Ethylene Glycol
Antifoam (3)
Titanium Dioxide (4)
Calcium Carbonate (5)
Zinc Oxide (6)
M i 1dewci de (7)
Water
Cel l o s i ze Hydroxyethyl Cellulose QP-15000
Let Down:
Ucar Latex 163
Ucar Filmer I 8 1
Antifoam (3)
Water
Pounds
95.8
8.9
1.o
1.2
19.3
1.5
112.5
420.3
44.3
2.5
33.3
3.9
496.9
5.8
1.9
2.5
Gal 1ons
11.5
0.9
0.2
2.1
0.2
3.5
18.7
I.o
0.3
4.0
0.3
---
55.8
0 . 8
0.3
0.3
Suppl iers :
(1) Dispersant - C o l l o i d 226/35 (Collods) o r equivalent.
(2) Wetting Agent - Surfynol 104 ( A i r Products) o r equivalent.
(3) Antifoam - C o l l o i d 643 ( C o l l o i d s ) or equivalent.
( 4 ) Titanium Dioxide - Ti-Pure R-960 (DuPont) o r equivalent.
(5) Calcium Carbonate - Atomite (Thompson, Weinman) o r equiv-
(6) Zinc Oxide - XX-503 (NJ Zinc) o r equivalent.
(7) Mildewcide - Skane M-8 (Rohm and Haas) o r equivalent.
a l e n t .
Mastic Properti8s :
Pigment Volume Concentration (PVC) %: 43.0
Total Solids, % by Volume: 55.0
SOURCE: Ucar Emulsion Systems: Ucar Latex 183: Formulation
Suggestion WB-2002
206 Water-Based Paint Formulations
Brown Wiping Stain
Materi a1 :
Kelsol 3931-WG4-45
2-Butoxy Ethanol
Patcote 531
Red Iron Oxide R-4098
Yellow Iron Oxide 1075A
Brown Iron Oxide 444
Syloid 234
Lbs.
261.00
18.00
7.50
7.30
4.50
14.90
25.00
Grind to a 5+ Hegman grind
Kel sol 3931-WG4-45 402.00
Premix the following, then add under agitation.
2-Butoxy Ethanol
Acti v-8
Cobalt Hydrocure I 1
Manganese Hydrocure I1
Pregel the following, then add under agitation:
4.00
2.40
3.80
6.00
Ammoni um Hydroxide
Carbopol 941
Water
Pol OX WSR-301
2.20
1.10
1.10
100.00
Analysis:
Figment Volume Concentration, Percent: 2.17
Pigment/Binder Concentration, Percent: 0.164
Percent Sol ids, Weight : 42.55
Percent Solids, Volume: 39.29
Pounds/Gallon: 8.59
VOC (excludi ng water) :
Grams/Liter: 229
Pounds/Gallon: 1.91
pH: 8.2-8.6
Gals.
31.45
2.39
1.09
0.17
0.13
0.38
1.50
48.43
0.53
0.30
0.50
0.71
0.29
0.11
0.11
12.00
SOURCE: Reichhold Chemicals, Inc.: Kelsol 3931: Formula 2581-81-A
Stains 207
I n t e r i o r Wiping S t a i n
I E n u l s i o n E-2977)
Blend:
Water
Aurasperse W-1021 Y I O
Aurasperse W-3041 R I O
Aurasperse W-7012 LB
Emu1s i on E-2977
Surfynol DF-37*
Propylene Glycol
Ammoni um Hydroxide (28%)
Acrysol ASE-601:1
Water/premi x
Water
Surfynol 104DPM
*Surfynol DF-58, 70 and 75
Formulation E (Rohm & Haas)
Pounds
150.0
22.5
7.6
3.3
372.0
1.3
39.0
6.3
64.0
64.0
133.8
4.4
defoamers are v i a b l e a l t e r n a t i v e s .
S t a i n
81end :
Joncryl 95
Ektasolve DB
Surfynol DF-37
Super Seatone Burnt Umber
Nuosept 95
Mix a t 1000 rpm f o r 10-15 minutes.
Premix t h e f o l l o w i n g and add w i t h a g i t a t i o n :
Letdown :
Water
Propylene Glycol
Natrosol 250 HBR
Ammonia
Surfynol 104DPM
Formulation F (S.C.Johnson)
Pounds
293.19
9.00
1.32
100.00
1.50
441 .32
30.24
3.00
1 .oo
8 . 8 0
Surfynol a d d i t i v e s have been shown t o provide t h e f o l l o w i n g
benef it s :
*Color u n i f o r m i t y o f s t a i n s
*Early s t a i n lapping resistance
*Consistent wetting, f l o w and l e v e l i n g on various woods
*Foam c o n t r o l
*Topcoat r e c o a t a b i l i t y and i n t e r c o a t adhesion
*G1oss r e t e n t i on upon aging
*Tannin bleed resistance
*Water s e n s i t i v i t y
*Chemical resistance
With no detrimantal e f f e c t upon:
SOURCE: A i r Products & Chemicals, I n c . : Surfynol Surfactants:
Suggested Formulations
208 Water-Based Paint Formulations
M a t e r i a1 :
Spensol L54
Water
D i sperse-Ayd W22
Foamki 11 639AA
Mapico 297
BK 5000
L i a h t Redwood Wipina S t a i n
Pebble m i l l g r i n d 16-24 h r s .
Then add i n f o l l o w i n g order w i t h a g i t a t i o n :
Letdown :
3% Bentone LT Pregel*
Spensol L54
Arolon 820-W-49
Lodyne S107
QR708B
Ammoni um Hydroxi de
*3% Bentone LT Pregel:
Water (deionized p r e f e r r e d )
Bentone LT
High speed d i sperser 15-20 m i nutes.
Analysis:
Ratio o f Spensol L54 t o Arolon 820: 50:50
Pigment Volume Concentration, Percent: 2.6
Pigment/Binder Ratio: 0.15/1 .0
Percent Solids, Weight: 26.5
Percent Solids, Volume: 24.3
Percent Vehicle Sol i d s . Weight : 20.8
Percent Vehicle Solids, Volume: 19.6
Pounds/Gallon: 8.44
VOC (excluding water):
Grams/Li t e r : 72
Pounds/Gallon: 0.60
pH: 8.Ot-0.5
Lbs. Gals.
51.9 5.94
51.8 6.22
0.5 0.06
0 . 8 0.10
24.5 0.60
1.7 0.04
288.0 34.12
254.2 29.12
187.4 21.29
1.7 0.18
17.5 2.10
1.7 0.23
818.9 98.31
25.4 1.69
SOURCE: Reichhold Chemicals, I n c . : Spensol L: Formulation
2099-81 D
Stains 209
S t a i n Concentrate
Component A:
Materia1 :
Kels o l 3931-WG4-45
2-Butoxy Ethanol
Water
Ammoni um Hydroxide
Patcote 531
Mapico 567
Mapico 1075
Atomi t e
S y l o i d 234
Pebble o r sand m i l l t o 6+ Hegman g r i n d .
Letdown :
Kels o l 3931-WG4-45
Cobalt Hydrocure I 1
Manganese Hydrocure I1
Activ-8
2-Butoxy Ethanol
Premix t h e next t h r e e m a t e r i a l s before adding:
Polyphase AF-1
2-Butoxy Ethanol
Aerosol OT-75
M i cheml ube 511
Water
Lbs.
207.5
7.5
34.7
1.9
1.8
50.0
25.0
50.0
10.0
166.0
1.9
2.1
0.2
3.8
9 . 8
3.8
2.3
32.0
37.5
Gal s.
25.00
1.oo
4.17
0.25
0.25
1.16
0.74
2.22
0.60
20.00
0.25
0.25
0.03
0.50
1.oo
0.50
0.25
4.00
4.50
Add t h e f o l l o w i n g amount o f water j u s t p r i o r t o use and mix w e l l .
Component 0:
Water
Analysis:
Pigment Volume Concentration, Percent
Pigment/Binder R a t i o
Percent Sol ids, Weight
Percent Solids, Volume
V i s c o s i t y @ 25C. #4 Ford, Secs.
Pounds/Gal 1on
VOC (excl udi ng water) :
Grams/Li t e r
Pounds/Gal 1on :
277.6 33.33
Comp. A
18
2.8/1 .O
49.0
39.3
110
9.72
169
1.4
Comp. A+B
18
0.0/1 .O
34.45
26.2
19
9.26
169
1.4
NOTE: T h i s type o f formulation might be b e n e f i c i a l t o p a i n t
manufacturers who s e l l d i r e c t l y t o b u i l d i n g o r p a i n t i n g
c o n t r a c t o r s . These s t a i n concentrates can be mixed w i t h
water a t t h e j o b s i t e .
SOURCE: Reichhold Chemicals, Inc.: Kelsol 3931: Formula 2210-44
210 Water-Based Paint Formulations
Tannin S t a i n Blockina Formulation
Pigment Grind:
Water
Bubond 357
Busperse 39
Bubreak 4400
Igepal CTA 639
Water
Cel l o s i ze QP-15000
TiPure R-900
Nytal 300
Let Down:
Ucar 376
Texanol
Ethylene Glycol
C e l l o s i ze QP-15000
Water
T i n t t o desired c o l o r
% by Weisht
9.2
1 . 0
0 . 6
0.3
0.3
2.3
0 . 2
18.3
9.9
39.2
2.0
2.7
0.2
13.8
A c r y l i c Tannin Stain-Blockinq Primer
Materi a1 :
Water
Busperse 39
T r i t o n X-100
Bubreak 448
Premix f o l l o w i n g , then add t o above:
Water
C e l l o s i ze QP-15000
S i f t i n f o l l o w i n g pigments:
T i -Pure R-900
Nytal 300
Busan 11-M1
High speed disperse t o Hegman 5.0. Reduce speed
as shown below:
Rhopl ex MV-23 Acryl ic Emu1s i o n
Water
Texanol
Ethylene G1ycol
% bv Weisaht
8.6
0.6
0.3
0.2
2.2
0.2
17.4
6.6
2.5
and l e t down
48.1
8.8
2.0
2.5
SOURCE: Buckman Laboratories, I n c . : Suggested Paint Formulations
Stains 211
Water Reducible Redwood S o l i d Color S t a i n
I n c o r p o r a t i o n o f Agitan 701 i n t o a water r e d u c i b l e wood s t a i n
g r i n d y i e l d s improved g r i n d v i s c o s i t y as w e l l as foam c o n t r o l i n
t h e letdown. A d d i t i o n o f t h i s s i l i c o n e type FCA has no e f f e c t
on r e c o a t a b i l i t y o f t h e topcoat.
Grind:
McWhorter 73-7358
Red I r o n Oxide
Aerosil R972 (Degussa)
FCA (Foam Control Agent)
& %Wt
70 8.13
50 5.80
2.5 0.29
2.5 0.29
High speed 15 Minutes t o 6 Hegman
Data on Imoroved V i s c o s i t v and Foam Control w i t h Aoitan:
Test No Agitan
Grind V i s c o s i t y , 25C, Poise 69
Grind Weight per Gallon (pounds) 10.06
Letdown :
Add w h i l e mixing:
McWhorter 73-7358
OK 412 (Degussa Corp.)
B u t y l C e l l os01ve
Premix and add:
Manganese Hydro Cure I 1 (Mooney)
Butyl Cellosolve
Polyphase AF-1 (Troy Chemical )
Add f o l l o w i n g w h i l e mixing:
Aqueous Ammonia 28%
Deionized Water
Aquabead 519 (Micro Powders)
Properties:
% N o n v o l a t i l e (by weight): 29.54
(by volume): 25.41
Pigment t o Binder Ratio: 0.44
Pigment Volume Concentration: 11.92
Weight per Gallon (pounds): 8.61
Theoretical VOC (pounds/gallon): 2.84
Water-Cosolvent Weight Ratio: 80.68:19.32
pH, 25C: 8.8
V i s c o s i t y , #2 Zahn Cup, 25C (seconds): 33
( g r a m s / l i t e r ) : 341
-
Agitan 701
58.5
11.11
&
90.0 10.45
25.0 2.90
8 0 . 0 9.29
9.5 1 . l o
24.0 2.79
8 . 0 0.93
11.5 1.33
468.4 54.38
20.2 2.32
SOURCE: King I n d u s t r i e s : WR-31: A d d i t i v e s f o r Waterborne Wood
Formulations
Miscellaneous 213
Anquamine 401 Clear Coat
Semi-Solid EDOXYDispersion
Part A:
Dow XUS19000.01 Epoxy Resin*
Benzyl Alcohol
Water
& Gals
346.93 38.70
17.35 1.99
216.83 25.98
Part 8 :
Anquami ne 401 Curing Agent (Ai r Products) 177.00 19.37
Water 35.40 4.24
Dowanol PM Solvent (Dow) 35.40 4.66
Benzyl Alcohol 44.25 5.07
* A l t e r n a t e l y use Epi-Rez 3515 a t same loading
Typical Properties:
W t s o l i d s (%): 57.45
VOC s o l i d s (%I: 52.43
VOC ( l b / g a l ) : 1.05
VOC ( g / l ) : 126
Anauamine 401 Clear Coat ProDerties:
Pot L i f e , h r : >4
Gloss, 60 spec, 1 day: 100
Gloss, 60 spec, 8 wk: >90
Mix Ratio: 2 : l
Mixed V i s c o s i t y , cP: 320
Tack Free Time, h r : 1.0
Hard Dry Time, h r : 6-8
Penci 1 Hardness, overnight
VOC, l b / g a l : 1.1
Volume Solids, %: 56
SOURCE: A i r Products and Chem
Agent: Formulation 5
F
cals, I n c . : Anquamine 401 Curing
214 Water-Based Paint Formulations
Anquamine 401 Clear Coat
S o l i d EDOXV Dispersion
Part A:
€pi-Rez 3520
Water
Part 8:
Anquami ne 401
Water
Defoamer
PnP Solvent
Typical Propert ies :
W t S o l i d s (%): 70.0
Volume S o l i d s (%): 41.35
VOC ( l b / g a l ) : 1.13
VOC ( g / l ) : 136
Pot L i f e , h r : >5
Gloss, 60 spec, 1 day: 100
Gloss, 60 spec, 8 wk: >SO
Mix Ratio: 4:l
Mixed V i s c o s i t y , CP: 390
Tack Free Time, h r : 0.5
Hard Dry Time: 6-8
Pencil Hardness, overnight: F
VOC, l b / g a l : 1 . 1
Volume Solids, %: 42
Anquami ne 401 C1ear Coat Propert ies:
Anquami ne 401
L i q u i d EDOXVClear Coat
Part A:
DER 331 Epoxy Resin (Dow)
Benzyl Alcohol
&
621.68
89.20
79.06
61.59
4.25
24.85
Lbs
411 .SO
65.04
Part B:
Anquami ne 401 Curing Agent (Ai r Products) 270.98
Water 169.91
Letdown :
Water 416.50
Typical Properties:
W t S o l i d s (%): 47.5 VOC ( l b / g a l ) : 0.47
Volume S o l i d s (%I: 44.2 VOC ( g / l ) : 56
Resin Stoichiometry: 1.6:l
Gloss, 60 specular: >90 Hard Dry: Overnight
Pot l i f e , h r : 1 VOC l b / g a l : 0.47
Set t o Touch, h r : 3
L i q u i d Epoxy C1ear Coat Properti8s:
69.30
10.69
8.74
7.38
0.53
3.36
Gals
42.54
7.46
29.65
20.36
50.00
SOURCE: A i r Products and Chemicals, I n c . : Anquamine 401 Curing
Agent: Formulations 8 & 7
Miscellaneous 215
Aaueous Polyester-Urethane P iqment D i s p e r s i on
K-Flex XM-2311 and K-Flex XM-4310 a r e b o t h experimental
a l i p h a t i c polyester-urethane aqueous d i s p e r s i o n s recommended
f o r thermoset water-borne c o a t i n g s . K-Flex XM-2311 provides
excel 1e n t p i gment w e t t i ng p r o p e r t i e s . K-F1 ex XM-4310 has a 1ower
a c i d number, higher hydroxyl number and i s recommended as a
modifying r e s i n f o r thermoset water-borne a c r y l i c s , p o l y e s t e r s ,
alkyds o r urethanes o r primary r e s i n f o r c r o s s l i n k i n g w i t h
ami nopl a s t r e s i ns.
Grind: (Cowles) Grind t o 8 N.S. Hegman Gauge:
Component: % by Weight
K-F1 ex XM-2311 10.00
Water 0.70
T i -Pure R-900 23.85
Letdown :
K-F1 ex XM-4310 43.89
HMMM 7.45
S i l i c o n e A (25%)* 0.18
S i l i c o n e B (25%)** 0.18
Water 9.45
Nacure 2547 0.30
Dimethylethanolamine 1.43
Water 2.57
Characteri s t i cs:
XM-2311/XM-4310/HMMM: 14/61/25
T o t a l Solids, %: 54.54
T h e o r e t i c a l VOC, g / l : 32.2
Pigment/Binder R a t i o : 0.8/1 .O
pH Value ( A s i s ) : 8.45
V i s c o s i t y , cps***: 200
***Brookfield, Spindle #16, 60 RPM
Substrate: I r o n Phosphated Cold R o l l e d S t e e l
Cure: 15 Minutes/l49C (300F)
Dry F i l m Thickness: 20-25 microns (0.8-1.0 m i l s )
Pencil Hardness: 2H
Knoop Hardness, 259: 4.4
MEK Double Rubs: 200+
Impact Resistance ( i n . l b s . ) : D i r e c t : 160+
60 Gloss, %: 94.10
Cleveland Humidity Resistance (325 Hours): 60 Gloss,%: 90.54
Taber Abrasion Index (CS 17, 5009): 274
F i l m P r o p e r t i e s :
Properties :
Reverse: 160+
Formulation Notes:
1. Slowly add n e u t r a l i z i n g amine (10% i n H20) under good a g i t a -
t i o n t o g r i n d and/or f i n a l f o r m u l a t i o n s f o r pH and v i s c o s i t y
adjustment.
2. Cosolvent i s n o t recommended f o r v i s c o s i t y adjustment.
3. C a t a l y s t l e v e l recommendation range: 0.1-0.25% a c t i v e p-TSA
5 . Immediate letdown o f g r i n d i s recommended.
SOURCE: King I n d u s t r i e s : Formulation WR-29
on t o t a l r e s i n s o l i d s . 4. Recommended pH i s 7.5-8.0.
* S i l w e t L-7604 **Si l w e t L-7605
216 Water-Based Paint Formulations
Black Gloss Enanel
Materi a1 :
Spensol L52
Aerosol OT-75
Surfynol 104H
Ammoni um Hydroxide
Regal 330 Carbon Black
Lbs. Gals.
175.4 20.00
2.3 0.25
2.0 0.25
1.9 0.25
15.0 1.oo
Add t h e above materials i n t h e order l i s t e d under good a g i t a t i o n ,
then pebble m i l l g r i n d t o 7 N.S.
Letdown :
Spensol L52
Add t h e f o l
use and mix
XAMA- 7
Anal y s i s:
owing cross
w e l l .
i n k i n g agent opt iona
679.7 77.50
) j u s t p r i o r t o
7.4
P;gment Volume Concentration, Percent: 3.5
Pigment/Binder Ratio: 0.6/1 . O
Percent Solids, Weight: 31.9
Percent Solids, Volume: 28.4
V i s c o s i t y @ 25C, #4 Ford, Secs.: 25-30
Pounds/Gal 1on : 8.82
VOC (excluding water):
Grams/Liter: 275
Pounds/Gallon: 2.3
pH: 8.5t-0.3
Formulation 2154-1 0
Clear B a r r i e r / T i e Coat f o r V i n y l
Material :
Arolon 840-W-39
Water
Carbi t o 1
Ammoni um Hydroxide
Spensol L54
Aerosol OT-75
Add t h e above m a t e r i a l s i n
Lbs.
599.2
33.3
35.0
1.9
194.8
2.9
order under good a g i t a t i o n .
0.75
Gal s.
68.87
4.00
4.25
0.25
22.31
0.32
Analysis:
Percent Solids, Weight: 33.9 Percent Solids, Volume: 31.2
V i s c o s i t y I3 25C, #2 Zahn. Secs.: 20-25
VOC (excluding water): Grams/Liter: 209
Pounds/Gallon: 8.7 PH: 8.5-9.0
Pounds/Gallon: 1.7
Formulation 2262-831)
SOURCE: Reichhold Chemicals, I n c . : Sponsol L: Formulations
Miscellaneous 217
Clear T i n t Base
M a t e r i a l :
Kels o l 3931-WG4-45
Strodex P-1 00
I n t e r c ide T-0
Lbs. Gals.
370.0 44.52
1.6 0.19
4.2 0.43
Premix t h e next t h r e e m a t e r i a l s i n order, then add under good
a g i t a t i o n :
Act iv-8
Cobalt Hydrocure I1
Manganese Hydrocure
Add t h e f o l l o w i n g i n order:
Polymekon SPP-W
Polyphase AFl
Water
Ammoni um Hydroxi de
Analysis:
Percent Solids, Weight: 23.3
2.1 0.36
1.3 0.17
5 . 0 0.66
33.3 4.16
8.4 0 . 8 1
405.9 48.73
0 . 5 0.07
Percent S o l i d s ] Volume: 21.6 (approx)
V i s c o s i t y @ 25C, #2 Zahn, Secs.: 20-25
VOC (excluding water):
Grams/Li t e r : 185
Pounds/Gal 1on : 1 .54
pH: 8.2-8.6
SOURCE: Reichhold Chemicals, I n c . : Kelsol 3931: Formula 2099-32
218 Water-Based Paint Formulations
FCA’s f o r Waterborne B u i l d i n g Product Formulations
Clear Waterborne Cement Sealer
Mater ia1 :
Rhoplex AC-3001 (Rohm and Haas)
FCA (Foam Control Agent)
B u t y l Cellosolve
Surfynol 104E ( A i r Products)
Properties :
% N o n v o l a t i l e (by weight): 45.78
V i s c o s i t y , CPS: 150+-10%
pH: 7.7-8.7
Waterborne Black Topcoat
Grind:
Water
Natrosol 250MR (Hercules)
Ammoni a (28%)
Tamol 731-25 (Rohm and Haas)
FCA (Foam Control Agent)
Bayferrox 318M ( M i l e s )
WG-325 Mica (KMG Minerals)
Grind a t h i g h speed f o r 15 minutes
Letdown :
Rhoplex AC-3001 (Rohm and Haas)
Butyl Cellosolve
Surfynol 104H ( A i r Products)
Water
Properties:
% N o n v o l a t i l e (by weight): 50.0
(by volume): 37.9
pH, 25C: approx. 9.0
V i s c o s i t y , #4 Ford cup, 25C, seconds: 18
Coalescent, % on polymer s o l i d s : 15
T h e r e t i c a l VOC ( g r a m s / l i t e r ) : 119.8
(pounds/gallon): 1.0
&
761.68
0.88
36.40
1.04
&
121.8
1.1
0.5
12.1
3.8
174.5
48.3
605.1
43.6
3.2
13.7
95.21
0.11
4.55
0.13
11.85
0.11
0.05
1.18
0.37
16.98
4.70
58.88
4.24
0.31
1.33
Results demonstrate the v e r s a t i l i t y o f Agitan 260 as a
p e r s i s t e n t foam c o n t r o l agent and i t s a b i l i t y t o improve c o l o r
(represented by t h e L Value and yellow index) and prevent
pigment f l o a t .
SOURCE: King I n d u s t r i e s : Formulation WR-33
Miscellaneous 219
E x t e r i o r / I n t e r i s r B l o c k F i l l e r
I n q r e d i e n t s :
Pigment G r i nd:
Water
Potassi um Tripolyphosphate (KTPP)
Drewplus L-475
Tamol 731
Propylene G1y c o l
T r i t o n Nonionic S u r f a c t a n t N-101
Kathon LX
T i -Pure R-900
ASP 400
325 Mesh White Waterground Mica
Minex 4
Snowf 1ake
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
Water
NeoCar Latex 2300
Ucar F i l m e r IBT
Water 1
C e l l o s i z e Hydroxyethyl C e l l u l o s e )Premix
ER-15,000 1
Pounds
240.0
2.0
3.0
10.0
20.0
3.0
1.5
40.0
150.0
50.0
100.0
400.0
2.0
25.0
230.0
15.0
22.0
4 . 0
Gal 1ons
28.80
0.09
0.39
1.09
2.31
0.34
0.18
1.20
6.97
2.12
4.61
17.76
0.26
3.00
25.99
1.89
2.63
0.35
P a i n t P r o p e r t i e s :
PVC. %: 70.6
Volume S o l i d s , %: 47.2
Weight S o l i d s , %: 67.0
Weight per Gal on, l b : 13.17
Stormer, KU: 115
I C I , p o i s e : 1.55
pH Value: 9.2
Freeze-Thaw S t a b i l i t y , 3 c y c l e s : F a i l
Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass
Reflectance, %: 83.5
Gloss, 60: 2.3
Mudcracking, 50 m i l : Pass
Sag Resistance, m i l s : 16
F i l l e d Appearance on Block: Exc
F i l m P r o p e r t i e s :
SOURCE: Ucar Emulsion Systems: NeoCar Polymers: Formulation
Suggestion K-2216
220 Water-Based Paint Formulations
High S o l i d s Self Priming A l k y d
I n a r e d i e n t s :
Pigment Grind:
C a r g i l l 57-5766/High S o l i d s Alkyd
Ye1k i ns-TS/Soya L e c i t h i n
Bentone 38
Methyl Alcohol
Ti-Pure R-SOO/Titanium Dioxide-
B u t r o l 23/Modi f i e d Bari um Meta-
Atomite/Calcium Carbonate
Nytal 300/Talc-Magnesium S i l i c a t e
Mineral S p i r i t s (Rule 66)
Let Down:
C a r g i l l 57-5766/High S o l i d s Resin
Z i rconium 6%
Cobalt Naphthenate-6%/Drier
A n t i s k i n n i ng Agent
Mineral S p i r i t s (Rule 66)
Paint P r o p e r t ies:
Total Vehicle 49.94
Pigment 50.06
Vol a t i 1e 15.95
Organic Solvent 15.95
Non-Volati l e 84.05
Non-Volatile Vehicle 33.98
Density (lb/U.S. g a l ) : 11.99
S p e c i f i c G r a v i t y : 1.44
P . V . C . : 31 .55%
P/B Ratio: 1.473
Spread @ 1 M i 1 : 1133 F2
Coating VOC: 229 G/L
M a t e r i a l VOC: 229 G/L
R u t i l e
borate
j& Gal
224.26 27.35
2.99 0.35
1.99 0.14
1.50 0.23
199.35 5.99
99.68 3.24
149.51 6.62
149.51 6.31
37 * 88 5.89
224.26 27.35
6.98 0.98
1.99 0.27
1.99 0.26
96.68 15.04
77.71
22.29
29.35
29.35
70.65
48.36
18.71
0.25
0.17
0.12
16.63
8.32
12.47
12.47
3.16
18.71
0.58
0.17
0.17
8.07
SOURCE: Buckman Laboratories: Formulation Suggestion: KQ-20
Miscellaneous 221
Masonry B l o c k
M a t e r i a1 :
P a r t A:
2-Propoxyet hanol
T r i t o n X-100 S u r f a c t a n t
Tamol 731 (25% N . V . ) S u r f a c t a n t
C o l l o i d 640 Defoamer
R u t i l e T i t a n i u m D i o x i d e
Atomi t e C a l c i um Carbonate
Water
Pounds
11.6
3 . 5
3.5
4 . 0
50.0
100.0
50.0
Gal l o n s
1.50
0.39
0.38
0.50
1.46
4 . 4 4
6.00
Mix a t h i g h speed 10 minutes; t h e n add and mix 3 m i n u t e s :
S h o r t S t u f f P o l y e t h y l e n e F i b e r s 7 . 0 0 . 9 3
Add under reduced speed:
Water
E p i -Rez 3520-WY-55 Resin
P a r t B:
€pi-Cure 8536-MY-60 C u r i n g Agent
ASP 170 Aluminum S i l i c a t e
325 Mesh Water Ground Mica
Water
48.6 5.83
260.0 28.57
124.5 15.00
50.0 2 . 3 8
100.0 4.24
166.0 20.00
Mix a t h i g h speed 10 minutes; t h e n add and mix 3 m i n u t e s :
S h o r t S t u f f P o l y e t h y l e n e F i b e r s
Water
T y p i c a l C o a t i n g P r o p e r t i e s :
T o t a l Volume S o l i d s , %: 41.7
T o t a l Weight S o l i d s , %: 57.7
PVC, 94: 45.6
V o l a t i l e O r g a n i c Compounds (VOC):
Pounds/Gallon: 1.60
Grams/Li t e r : 192
A p p l i c a t i o n : Brush and R o l l e r
Resin Composition ( s o l i d s ) :
Epoxy Resin, %: 65.7
C u r i n g Agent, %: 34.3
T o t a l , %: 100.0
Composite Blend: V i s c o s i t y
P a r t A 97 KU
P a r t 0 >141 KU
P a r t s A and B 131 KU
1 . o 0.13
22.4 2.69
Pounds Gal 1ons
538.2 50.00
588.9 50.00
SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1615:
Masonry B l o c k F i l l : Epi-Rez 3520-WY-55 Resin/Epi-Cure
8536-MY-60 C u r i n g Agent
222 Water-Based Paint Formulations
Masonry B l o c k f i 11
M a t e r i a1 :
P a r t A:
2-Propoxyethanol
T r i t o n X-100 S u r f a c t a n t
Tamol 731 S u r f a c t a n t
C o l l o i d 640 Defoamer
Tap Water
Mix and add:
R u t i l e Titanium Dioxide
Atomite Calcium Carbonate
ASP 170 Alumi num S i 1i c a t e
H i speed disperse 10 minutes; then add:
Short S t u f f Polyethylene F i b e r s
Tap Water
Add a t reduced speed:
Epi -Rez 3520-W-55 Resin
P a r t 8 :
Epi -Cure 8537-W-60 Curing Agent
Tap Water
Mix we1 1 and add:
ASP 170 Aluminum S i 1i c a t e
325 Mesh Water Ground Mica
Atomite Calcium Carbonate
H i speed disperse 10 minutes; then add:
Short S t u f f Polyethylene F i b e r s
Tap Water
Composi t e 81end :
P a r t A
Part B
T y p i c a l Coat
V i s c o s i t y
P . V . C . . %
Pounds
11.6
3.5
3.5
4.0
71 .O
50.0
75.0
35.0
7.0
11.4
260.0
129.0
166.0
50.0
100.0
125.0
1.o
28.7
532.0
599.7
ng P r o p e r t ies :
P a r t A: 128 Krebs U n i t s
P a r t B: 108 Krebs U n i t s
P a r t s A and B: Fresh: 108 Krebs U n i t s
42.2
T o t a l Weight S o l i d s , %: 67.4
T o t a l Volume S o l i d s , %: 46.2
Resin Composition: Epoxy Resin, %: 65
V o l a t i l e s Composition: Water. l b s . : 393.6
V o l a t i l e Organic Compounds (VOC):
Curing Agent, %: 35
Organic, l b s . : 63.6
Pounds/Gal 1on : 1.21
Grams/Liter: 145
A p p l i c a t i o n : Brush and R o l l e r
Gal 1ons
1.50
0.39
0.38
0.50
8.50
1.46
3.30
1.67
0.93
1.37
30.00
14.25
20.00
2.38
4.24
5.56
0.13
3.44
50.00
50.00
SOURCE: S h e l l Chemical Co.: S t a r t i n g Formulation No. 1616:
€pi-Rez 3520-WY-55 Resin/Epi-Cure 8537-WY-60 Curing
Agent
Miscellaneous 223
Water Reducible A1kyd
I n g r e d i e n t s : -Lb
Pigment G r i n d :
Water 132.72
Busperse 39/Dispersant 5.90
Bubreak 448/Defoamer 2.95
Z i n c S u l f a t e - H e p t a h y d r a t e 1.97
I g e p a l CTA 6 3 9 / S u r f a c t a n t 1.97
B u t r o l 2 3 / M o d i f i e d Barium Metaborate 49.16
Red I r o n Oxide 98.31
N y t a l 300/Talc-Magnesi um S i 1ic a t @ 196.63
L e t Down:
C a r g i l l 74-7450/Water Reducible
A1 kyd 252.67
n-Butyl A l c o h o l 84.55
Ammoni urn Hydroxi de-28% 9.83
Water 216.29
C o b a l t Napthenate-6%/Drier 1.97
Z i r c o n i u m 6% 3.93
P a i n t P r o p e r t i e s : %Wt
T o t a l V e h i c l e 67.32 87.47
P i grnent 32.68 12.53
Vol a t i1e 50.16 68.37
Organic S o l v e n t 17.20 26.47
N o n - V o l a t i l e 49.84 31.63
N o n - V o l a t i l e V e h i c l e 17.16 19.11
D e n s i t y (lb./U.S. g a l ) : 10.59
S p e c i f i c G r a v i t y : 1.27
P.V.C.: 39.60%
P/B R a t i o : 1.905
Spread F 1 M i l : 507 F2
C o a t i n g VOC: 376 G/L
M a t e r i a l VOC: 218 G/L
Gal 5
15.93 12.53
0.55 0.56
0.44 0.28
0.12 0.19
0.22 0.19
1.60 4.64
2.51 9.29
8.30 18.57
29.71 23.86
12.53 7.99
1.31 0.93
25.97 20.43
0.27 0.19
0.55 0.37
SOURCE: Buckman L a b o r a t o r i e s : F o r m u l a t i o n Suggestion: KQ-22
224 Water-Based Paint Formulations
2-Component Waterborne System
Formulation WR-41 demonstrates the improved performance o f a
2-component waterborne system when modified w i t h K-Flex XM-4316,
a polyester-urethane dispersion. A t both NCO/OH r a t i o s , improve-
ments were made i n gloss, MEK resistance, and f l e x i b i l i t y .
NCO/OH Ratio: 1.6
Acryl ic/PU-Di spersi on: 80/20
Component A :
Emulsion E-3275
K-Flex XM-4316
Sodium N i t r i t e (5% aq)
Proglyde DMM
Edaplan LA 402
S i l w e t 7001 (5% aq)
S i l w e t 7605 (25% aq)
S i l w e t 7604 (25% aq)
Dimethyl ethanol ami ne
Component B:
Bayhydur XP-7063
Formulation C h a r a c t e r i s t i c s :
Nonvolatile, t h e o r e t i c a l , %: 48.7
Theoretical VOC, g/L, ( l b . / g a l l o n ) : 48, (0.4)
Wt%
69.31
16.89
0.00
1 .23
0.07
0.00
0.00
0.00
0.00
12.50
Formulation Properties, A i r-Dry 20-25C, 2 weeks:
Substrate: Bonderite 1000 c o l d r o l l e d s t e e l
F i l m thickness, micron ( m i l . ) : 32+-2 (1.3+-0.1)
Dry Time (minutes): Set t o touch: 4.5
Surface d r y : 12
Through dry: 18
20, %: 74 MEK Double Rubs: 120
Gloss 60, %: 96 Knoop Hardness: 5 . 5
Koenig Hardness (sec): 108 Impact, D i r e c t , i n c h . l b . : >160
Pencil Hardness: 2H-3H Impact, Reverse, i n c h . l b . : >160
Formulation Properties, Bake 80C 20 min. Post-cure 20-25C,
2 weeks:
Substrate: Bonderite 1000 c o l d r o l l e d s t e e l
F i l m thickness, micron ( m i l . ) : 32+-2 (1.3+-0.1)
NCO/OH R a t i o : 1.6
Gloss 60, %: 100 Knoop Hardness: 7
Koenig Hardness (sec): 134 Impact, Forward, i n c h x lb.:>160
Pencil Hardness: 3H Impact, Reverse, i n c h x lb.:>160
20, %: 80 MEK Double Rubs: 135
Formulation Preparation:
a g i t a t i o n f o r approx. 5 minutes.
SOURCE: King I n d u s t r i e s : Preliminary Formulation WR-41
Add component B t o component A under low shear mechanical
226 Water-Eased Paint Formulations
RAW MATERIAL CHEMICAL DESCRIPTION SOURCE
AC 1024 Acryl ic r e s i n Rohm&
Acronal DS 6183 Copolymer a c r y l i c ester dispersion BASF
Acrysol ASE-60/G-110/ Water-soluble a c r y l i c r e s i n s Rohm&
RM-S25/RM-l02O/RM-2020/
TT-935/WS-68
SCT-200/SCT-275/
Act iv-8 D r i et-, accelerator, s t a b i 1izer RTVan
Aero Me1ami ne Powdered grade
Aerosi 1 R-972 Fumed s i l i c a
Aerosol OT-75/OTS Surface a c t i v e agent
A1umi num L243
A1umi num Paste #82255
AMP-95 Dispersant
Ancamide 500/2353/
2410
Anquami ne 401
Aquabead 519
Aquacat
Aquamac 640/700
Aquamac 1085/1090
Aqua-sperse 877-9907
Arcosolv DPM
Arcosolv DPNP
Arcosolv D P t B
Arcosolv PNB
Arcosolv PNP
AmCyan
Degussa
AmCyan
S i 1ber
A1coa
2-amino-2-methyl-1-propanol Angus
Curing agents f o r epoxy r e s i n s Paci f ic
L i q u i d polyamide c u r i n g agent Paci f ic
Micro
D r i e r c a t a l y s t U l t r a
A c r y l i c l a t e x
e a l k y dWater-sol ub
.ampblack Co
D i propylene
Sol vent
Coalescent
Solvent
Solvent
McWhort
McWhort
o r Dispersant Hul s
g l y c o l monomethyl ether Arc0
Arco
Arc0
Arc0
Arc0
TradeNamed Raw Materials 227
RAW MATERIAL
Arcosolv PP
Arcosolv PTB
Arolon 500-W-42
A r o l on 020-W-49
Arolon 840-W-39
Aromatic 100
Aromatic 150
Atomi t e
Aroplaz 1271
Aroplaz 1272
Aroplaz 3859-2-80
ASA 35.3
ASP-NCP/ASP-l70/
ASP-400
Atomi t e
A t t a g e l 50
CHEMICAL DESCRIPTION
Solvent
Sol vent
O x i d i z i n g alkyd. % s o l i d s : 42
A c r y l i c polymer. % s o l i d s : 49
A c r y l i c polymer. % s o l i d s : 39
Hydrocarbon s o l v e n t
Hydrocarbon s o l v e n t
Cal c i um carbonate
Long-oil l i n s e e d a l k y d r e s i n
100% s o l i d s v e r s i o n o f Aroplaz 1271
Alkyd r e s i n
Wax emulsion
A1uminum s i 1i c a extender pigments
SOURCE
Arc0
Arc0
Rei chh
Reichh
Rei chh
Exxon
Exxon
ECC
Rei ch
Reich
Reich
CCA
Engel
Calcium carbonate, n a t u r a l ECC
C o l l o i d a l a t t a p u l g i t e t h i c k e n e r Engel
Aurasperse W-1021 Y I O Yellow i r o n o x i d e Harshaw
Aurasperse W-3041 R I O Red i r o n oxide Harshaw
Aurasperse W-4123 Harshaw
Aurasperse W-7012 LB Carbon b l a c k Harshaw
AZO-33 Zinc oxide Asarco
AZO-55 Z i nc o x i de. American process Asarco
228 Water-Based Paint Formulatiom
RAW MATERIAL CHEMICAL DESCRIPTION
B a r y t e s No. 1 Barium s u l f a t e extender pigment
Basic Lead S i l i c o Chromate
Bayhydur XP-7063 W a t e r - d i s p e r s i b l e i s o c y a n a t e
B a y f e r r o x 318M S y n t h e t i c i r o n o x i d e pigment
Beaverwhi t e 325 T a l c extender pigment
Beckosol 13-402 Water r e d u c i b l e a1kyd
B e e t l e 65/80/216-8 Urea-formaldehyde compound
Bentone AD/EW/LT/ R h e o l o g i c a l a d d i t i v e
SD-1/38
Benzof 1ex 9-88 P l a s t i c i z e r
BK5000 Pigment
BK5099 Pigment
B l a s t i t e #220 Aluminum o x i d e
Brown I r o n Oxide 444 Pigment
Bubble Breaker 776-P/ Defoamers
3295
Bubond 357 C a t i o n i c polymer
Bubreak 448/4400 Defoamer
Burgess No. 98/No. 128 Hydrous c l a y
Busan 11-M1 Barium metaborate m i c r o b i o c i d e
Busperse-39/203 D i s p e r s i n g agent
B u t r o l 23/35 C o r r o s i o n and s c a l e i n h i b i t o r
B u t y l Carbi t o 1 D i e t h y l e n e g l y c o l monobutyl e t h e r
B u t y l C a r b i t o l A c e t a t e D i e t h y l e n e g l y c o l monobutyl e t h e r
a c e t a t e
SOURCE
WC&D
Rheox
Bayer
M i l e s
Cyprus
Rei c h
AmCyan
Rheox
Vel s i c
P f iz e r
Harcros
SOHIO
Col umb
W i t c o
Buckman
Buckman
Burgess
Buckman
Buckman
Buckman
Union
Union
Trade Named Raw Materials 229
RAW MATERIAL CHEMICAL DESCRIPTION SOURCE
B u t y l Cel l o s o l v e Ethylene g l y c o l monobutyl ether UnCarb
Butyl O x i t o l Glycol ether She11
Byk 020/023/025 Defoamers Bykchem
acetate
0yk 155/156/301/306/ A d d i t i v e s
320/321/346
BykChem
Bykumen WS Wetti ng/di spersi ng agent BykChem
Cab-0-Si 1 L-SO/LM-130 Fumed s i 1icas
TS-61 O/TS-720
Calcium Hydrocem D r i e r c a t a l y s t f o r water systems
Calcium Hydro-Cure Catalyst f o r water systems
Camel Cal Extra f i n e ground limestone s l u r r y
Camel Carb Calcium carbonate extender
Camel F i l
CAO- 1
Carbi t o 1
Calci um carbonate
Antioxidant
Diethylene g l y c o l monoethyl ether
and e t h y l ene g l y c o l mixture
Carbopol 941 Thickening agent
Cargi 11 57-5766 WR High s o l i d s a l k y d
Cargi 11 72-7203 WR O i l f r e e polyester
Cargi 11 74-7450 WR Short soya a l k y d
Cargi 11 74-7474 WR chain-stopped a l k y d
C a r g i l l 7412 Non-oxi d i z i ng a1kyd
Cabot
Mooney
Mooney
Genst ar
Genstar
Genst ar
PMCSpec
UnCarb
BFGood
Cargi 11
Cargi 11
Cargi 11
Cargi 11
Cargi 11
230 Water-Based Paint Formulations
RAW MATERIAL CHEMICAL DESCRIPTION
Cargill 7464 Water reducible a1 kyd
Cel i te 281 /499 Di atomaceous si 1 i cas
Cellosize ER-52M Hydroxyethyl cellulose thickeners
ER-15,000/ER-30,000/
QP-44OO/QP-44OOH/QP-l5,OOO/
QP-15,OOOH
Chemcor AS-35-3 Wax emulsion
Chempol 10-0091 WR short oxidizing oil alkyd
Chlorez 700 Chlorinated paraffin resin
Chromi um Green Oxide 5-5310 Pigment
CL 27NA
Cobalt Chem-All 12%
Cobalt Hydrocure 12%/ Catalysts for water systems
I1
Cobalt Naphthenate-6% Drier
Colloid 107/111/111M/ Dispersants
226/35
Colloid 640/643/650/ Defoamer/Antifoams
653/675/677/679/
694/770
Composi ti on R/T Surfactants
Cosan 101/158/234 Preservat i ves
Cycat 4040 Acid catalyst
Cyclo Sol 63 Aromatic solvent
Cyme1 303/324/325/ Melamine-formaldehyde resins
327/350/385
SOURCE
Cargi 11
Manvi 1 1
UNCarb
CCA
Freeman
Dover
Mi nPi g
Dow
Mooney
Mooney
Interst
Rhone-
Rhone-
Cal gon
Cosan
AmCyan
She1 1
AmCyan
Trade Named Raw Materials 231
RAW MATERIAL
Dalpad A
Daxad 30-30
DC F l u i d 593
DC-14
DeeFo HG-12/PI-4/
806-1 15
Dehydran 1293
DER 331/660X80
D i cyandi ami de
D i sperbyk
Disperse-Ayd/W22/W28
DMEA
Dowanol DPM/DPnB/
EPh/ PM/ PnB/Pn P/PPH
Dow Corning 14/57
Dowicil 75
Dow XUS19000.01
Drewpl us L-475/
L-493/Y-281
D r i k a l it e
Durami t e
CHEMICAL DESCIPTION
Coal esci ng agent
Dispersant
Phenyl trimethicone
S i 1icone
Antifoam/defoamers
Defoamer
Epoxy r e s i n s
Dispersant
Dispersants
N e u t r a l i z i n g amine
Glycol ether products
S i 1icone a d d i t i v e s
A n t i m i c r o b i a l agent
Epoxy r e s i n
Foam c o n t r o l agents
Calcium carbonate extender pigment
Calcium carbonate extender pigment
E-845 Thickener
Eagle Zinc 417W Zinc oxide
Edaplan LA 402 Flow and l e v e l i n g agent
SOURCE
Dow
Grace
DowCorn
DowCorn
U l t r a
Henkel
Dow
AmCyan
BykChem
Daniel
UnCarb
DowChem
DowCorn
DowChem
DowChem
Drew
ECC
ECC
Rohm&
Eagle
King
232 Water-Based Paint Formulations
RAW MATERIAL
E k t a p r o EEP
E k t a s o l v e DB
E k t a s o l v e DB A c e t a t e
E k t a s o l v e DE
E k t a s o l v e EB
E k t a s o l v e EP
Emul s i o n E-2977
Emulsion E-3122
Emul s i on E-3275
€ p i -Cure 8290-Y-60
Epi -Cure 8292-Y-60
Epi -Cure 8536-MY-60
Epi -Cure 8537-WY-60
Epi -Rez 3515-W-60
Epi-Rez 3520-WY-55
Epi -Rez 3522-W-60
E p i -Rez 3540-WY-55
Epi -Rez 3551-WY-43
Epi-Rez 5522-WY-55
E p o d i l L
E p o d i l 759
E p o t u f 37-058
E p o t u f 37-143
E p o t u f 37-618
CHEMICAL DESCRIPTION
E t h e r e s t e r
Sol vent
S o l v e n t
Sol v e n t
Sol vent
2-propoxyethanol s o l v e n t
A c r y l i c emulsion
A c r y l ic d i s p e r s i on
Epoxy c u r i n g agent
Epoxy c u r i n g agent
Epoxy c u r i n g agent
Epoxy c u r i n g agent
Epoxy r e s i n
SOURCE
Eastman
Eastman
Eastman
Eastman
Eastman
Eastman
Rohm&
Rohm&
Rohm&
Shel 1
Shel 1
Shel 1
Shel 1
Shel 1
Epoxy r e s i n Shel
Epoxy r e s i n Shel
Epoxy r e s i n Shel
Epoxy r e s i n Shel
Epoxy r e s i n Shel
Hydrocarbon d i l u e n t f o r epoxy r e s i n s
R e a c t i v e d i 1uent
Epoxy r e s i n
Epoxy r e s i n
Epoxy r e s i n hardener
Rei ch
Rei ch
Rei ch
Trade Named Raw Materials 233
RAW MATERIAL
EpotUf 37-680
E p o t u f 38-501
Exxate 700
CHEMICAL DESCRIPTION
Epoxy r e s i n
Epoxy r e s i n
Oxo-acetate c o s o l v e n t
FC-430 F1u o r o s u r f a c t a n t
F1a t t i ng Agent TS-100
F l u o r a d FC-129 F1uorochemi c a l
Foamaster R/VF/VL/ Antifoam/defoamers
333
Foamex 825 A n t i foam
Foamki 11 639AA Foam c o n t r o l agent
F u n g i t r o l 234 Fungi c i de
Gold Bond R M i c r o c r y s t a l l i n e s i l i c a
H a l o f l e x 202 Polymer emu1s i on
Halox 8W-100 C a l c i um b a r i u m phospho-si 1ic a t e
Halox BW-191/CW-191/ W h i t e non-lead pigments
CW-49l/SW-lll/SW-1116/
szP-39 1
Halox X t a i n A
HEC QP-4400 H y d r o x y e t h y l c e l l u l o s e
Heucophos ZMP/ZPZ Z i n c y e l l o w s
Hexyl C a r b i t o 1 S o l v e n t
SOURCE
Rei c h
Rei ch
Exxon
3M
Degussa
3M
Henkel
TegoChe
C r u c i b
Cosan
Tamms
ICIRes
Halox
Hal ox
Hal ox
UnCarb
Heubach
UnCarb
234 Water-Based Paint Formulations
RAW MATERIAL
Hodag PX-218
H y d r i t e F l a t D
Iceberg
Igepal GO-630/
CTA-639
I m s i l A25
I n t e r c i d e T-0
I n t e r w e t #33
5-1365
5-31 03
Joncryl SCX-1520/
56/95/540/554
Jonwax 26
Kadox-515/911/915
Kathon LX
K-Cure 129W
Kelecin 1081
Kels o l 3931-WG4-45
K-F1 ex UD-320W/
XM-2304
K-F1 ex XM-2311
K-Flex XM-4310
CHEMICAL DESCRIPTION
Antifoam
Kaolin extender pigment
Anhydrous aluminum s i l i c a t e
Surfactants
M i c r o c r y s t a l l i n e s i l i c a
M i c r o b i o s t a t
Wetting agent
Strontium chromate
A c r y l i c polymers
Wax emulsion
Zinc oxide
Fungicide
Catalyst
Soybean o i l
O i l copolymer. % s o l i d s : 45
Poly01s
Pigment d i s p e r s i n g r e s i n
Polyester-urethane dispersion
SOURCE
Hodag
Georgia
Burgess
Rhone-
Unimin
Akzo
Davis
M i nPi g
Johnson
Johnson
N J Z i nc
Rohm&
King
Rei ch
Reich
King
King
King
Tra& Named Raw Materials 235
RAW MATERIAL
K-Flex XM-4316
K-Flex 188
Kodaflex DBP
KP-140
Kroma Red R0-7097
Kronos 2020
Kronos 2160
Kronos 2310
K-Sperse 152MS
L-203-D
Lampblack #E77
Lansford L243
Lodyne S107/S107B
LVT 400
Magnacat
Mai ncote HG-54
Mai ncote PR-71
Manganese Hydrocure
CHEMICAL DESCRIPTION
Polyester-urethane dispersion
Pol yo1
P l a s t i c i z e r
P1a s t i c i zer
I r o n oxide pigment
Rut i1e t i t a n i um d i o x i de
T i t a n i um d i o x i d e
Titanium d i o x i d e
Dispersant
Strontium chromate
Talc
D r i e r - c a t a l y s t
Acryl ic 1atex
A c r y l i c l a t e x
Catalyst
Manganese Hydrocure I 1 Catalyst
Mapico Red 297 I r o n oxide
Mapico Red 347A I r o n oxide
Mapico 567 I r o n oxide
Mapico 1075 I r o n oxide
SOURCE
King
King
Eastman
Eastman
P f izer
Kronos
Kronos
Kronos
King
Cookson
Hul s
S i 1ber
C i ba-
B a r r e t t
U l t r a
Rohm&
Rohm&
OMGroup
OMGroup
Col umb
Col umb
Col umb
Col umb
236 Water-Based Paint Formulations
RAW MATERIAL
McWhorter 73-7358
McWhorter 248-5409
Merbac 35
Methocel J-12-MS/856
Methyl Carbi t o 1
Methylon 75108
Mica
M i chem 392-25
M i chem Lube 110/182/
511/737/743/02925
M i c r o t a l c MP12-50
Microwhit e 25
Minex 4/10
Min-U-Si1 40
Moly-White 212
Monarch 1300
Mor-Lok 1035/1043
MPA- 1078
Nacor r
Nacorr 1552/1754
CHEMICAL DESCRIPTION SOURCE
Modi f ied p o lyo1e f in
A c r y l i c emulsion
McWhort
McWhort
B a c t e r i c i d e Cal gon
Hydroxypropyl m e t h y l c e l l u l o s e s Dow
Diethylene g l y c o l monomethyl e t h e r UnCarb
Occi den
325 mesh, water ground Engl i s h
KMG/
Uni m i n
Wax emulsion Michel
M i chelWax a d d i t i v e s
P fizer
GeoMarb
Low micron t a l c
Sodium potassium aluminum s i l i c a t e s Unimin
S i l i c a p a i n t f i l l e r
Corrosion i n h i b i t i v e pigment
F l u f f y carbon b l a c k
A n t i - s e t t l i n g agent
Corrosion i n h i b i t o r
Corrosion i n h i b i t o r s
Nacure X49-11O/XP-l81/Catalysts f o r polymeric c o a t i n g s
XP-188/155/25OO-X/
2547
Unim i n
Sherwi n
Cabot
Morton
Rheox
King
King
K i ng
Trade Named Raw Materials 237
RAW MATERIAL
Nalco 2300
Nal z i n SC-l/2
N a t r o s o l P l us/P1 us
330/P1 us 330PA
N a t r o s o l 250 HBR/
1on
250HR/250MHR/250MR/
250MXR
NeoCar L a t e x 2300
NeoCar L a t e x 6035
NeoCar L a t e x 6040
Neocryl XA-6085
N i c r o n 400 T a l c
Nopco NDW/NXZ
Nopcoci de N-96
No. 1 White
Novoperm Red F3RK-70
NuoCide 404-D/960
Nuocure C o b a l t 10%
Nuocure Manganese 6%
Nuosept 95/951/145/
6 3 5 1
Nuosperse 657
Nyad 1250
N y t a l 300/400
CHEMICAL DESCRIPTION SOURCE
A n t i foam Nal c o
C o r r o s i o n i n h i b i t i v e pigments Rheox
H y d r o x y e t h y l c e l l u l oses-modi f ied Aqua1 on
H y d r o x y e t h y l c e l l u l o s e s Aqua-
NeoCar polymer. 55% s o l i d s
E x t e r i o r polymer. 53.5% s o l i d s
For in t e r i o r semigloss appl ic a t i ons
A c r y l ic copolymer
Defoamers
M i 1dewci des
Calcium c a r b o n a t e
M i 1dewci de
P o l y u r e t h a n e c a t a l y s t
P o l y u r e t h a n e c a t a l y s t
P r e s e r v a t i v e s
D i s p e r s i n g agent
W o l l a s t o n i t e
T a l c s
UnCarb
UnCarb
UnCarb
IC I Res-
Luzenec
Henk e l
Henkel
ECC
Hoechs t
H u l s
Hul s
Hul s
Hul s
Hul s
Nyco
Vander
238 Water-Based Paint Formulations
RAW MATERIAL CHEMICAL DESCRIPTION
OK 412 F l a t t i n g agent
Omyacarb UF Natural calcium carbonate
Oncor M50 A n t i - c o r r o s i v e pigment
Optiwhi t e Anhydrous aluminum s i l i c a t e
Organofunctional S i lane A-187
Patcote 513/519/531/ Defoamers
047
Phos-Chek P/30 Flame r e t a r d a n t
Phosguard 5-0806/
5-0013/5-0015/5-0053
Pigment Disperser NL Dispersant
P1i01it e 7104 Styrene-butadiene copolymer
PMA-100 Fungicide
PM Acetate
Polygloss 90 C1ay
Polymekon SPP-W
POlyOX WSR-301 Water s o l u b l e r e s i n
Polyphase AF-1 B a c t e r i c i d e f u n g i c i d e
Poly-Tex 611-Q
Polywet ND-Z/ND-35 D i s p e r s a n t / s u r f a c t a n t s
Proglyde DMM Dipropylene g l y c o l dimethyl e t h e r
Propasol Solvent B I n d u s t r i a l s o l v e n t
Proxel GXL Chemical b i o c i d e
SOURCE
Degussa
Omya
NLChem
Burgess
OSISpec
P a t t e r
Monsant
M i nPi g
BASF
Goodyea
Dow
Arco
Huber
Mooney
UnCarb
Troy
I n t e r e z
Uni r o y
DowChem
UnCarb
I C 1
Trade Named Raw Materials 239
RAW MATERIAL CHEMICAL DESCRIPTION
9148 Defoamer
QR-708/OR-7088/ Rheology modifiers
QR-1374
R-2899 I r o n Oxide Red iron oxide
Raven 16/410/1020 Carbon blacks
Raybo 60 F1ash r u s t i n h i b i t o r
Red I r o n Oxide 5-3100 Pigment
Red I r o n Oxide 5-3106 Pigment
Red I r o n Oxide R-2899/R-4098/R-5098 Pigments
Red I r o n Oxide R0-4097 Pigment
Regal 330 Carbon black
Resi mene 747/797 Me1ami ne r e s i ns
Rhoplex AC-1024/ A c r y l i c emulsions
AC-3001/CL-lO4/CL-l05/
E-3188/MV-23/R-AC-507/WL-96
Ropaque OP-62 LO Opaque polymer
Ross & Rowe 551 Modi f ied 1eci t h i n
Rovace SF-091 V i n y l a c r y l ic copolymer
R u f f B u f f Coarse s i l i c a
SOURCE
Troy
Rohm&
P f izer
Col umb
Raybo
M i nPi g
M i nPi g
P f izer
Harcros
Cabot
Monsan
Rohm&
Rohm&
Ross&
Rohm&
Tammsco
Sancure 815/825
S a n t i c i z e r 160
Santolink EP-560
SF-69
Shi eldex
Short S t u f f
Waterborne urethane r e s i n Sanncor
P l a s t i c i z e r Monsanto
Cross1inker Monsanto
S i 1icone GE
Anti-corrosion pigment, nontoxic Davison
Polyethylene f i b e r s Mini F i b
240 Water-Based Paint Formulations
RAW MATERIAL CHEMICAL DESCRIPTION
S i c o r ZNP-S A n t i - c o r r o s i o n pigment
S i 1ane A-187
S i l c r o n G-601 F i n e p a r t i c l e s i l i c a g e l
S i 1wet L-77/7001/ S i l i c o n e w e t t i n g agents
L-7604/L-7605
Skane M-8 M i l d e w c i d e f o r p a i n t
S k i n o #2 A n t i s k i n n i ng agent
Snowf 1ake Calcium c a r b o n a t e
S o l v e n t 142HT
Sparmi t e B a r i um s u l f a t e
S p e c i a l B l a c k 4 Carbon b l a c k
Spensol L44/L51/L52/ Urethane p o l y o l s
L53/L54
Strodex MO-lOO/P-100/ S u r f a c t a n t s
PK-90/PK-95G
S u n b r i t e Green 264-8142/ Pigments
Sunbri t e Ye11ow 74/
S u n b r i t e Y e l l o w 272-0558/
S u n f a s t B l u e 248-3750
Super Seatone B u r n t Umber Pigment
S u r f a c t o l 365 D i s p e r s a n t
S u r f y n o l C T - l l l / S u r f a c t a n t s
CT-131/CT-151/DF-37/
DF-62
S u r f y n o l DF-58/ Defoamers
DF-70/DF-75
S u r f y n o l DF-llOD/ S u r f a c t a n t s
DF-11 OL/DF-21 O/GA/
TG/104/104DPM/104€/
104H/104PG-50/420/
485
SOURCE
BASF
OSISpec
SCM
UnCarb
Rohm&
OMGroup
ECC
She11
H a r c r o s
Degussa
Reich
D e x t e r
Sun
H i 1t o n
CasChem
A i r P r o d
A i r P r o d
A i r P r o d
Trade Named Raw Materials 241
RAW MATERIAL CHEMICAL DESCRIPTION
sws 211 A n t i foam
S y l o i d 234 S i 1ic a f 1a t t i ng agent
Syntex 3981 A c c e l e r a t o r
T a l c 399 Extender pigment
Tamol 165/681/731/ D i s p e r s a n t s
731A/050/960/983/
1124/SG-1
Tan 10A
T e r g i t o l NP-4/NP-10/ N o n i o n i c s u r f a c t a n t s
NP-40
Texanol Coal e s c i ng agent
T h a l o B l u e Aqueous d i s p e r s i on
T h i x a t r o l ST T h i x o t r o p e
T i n t - A y d WD-2744 P h t h a l o green d i s p e r s i o n
T i n u v i n 328 UV absorber
T i o n a RCL-9 T i t a n i um d i o x i d e
T i o x i de TR-92 T i t a n i um d i o x i d e
T i -Pure CR-800/ T i t a n i um d i o x i d e s
R-700/R-702/R-706/
R-900/R-901/R-902/
R-960
T i t a n o x 2020/2060/ T i t a n i um d i o x i d e s
2101/2160
T r i t o n GR-7M A n i o n i c s u r f a c t a n t
T r i t o n CF-10 W e t t i n g agent
T r i t o n CA/GR-SM/ N o n i o n i c s u r f a c t a n t s
N-57/N-lOl/X-100/
X-405
SOURCE
Wacker
Davi son
Rhone-
WC&D
Rohm&
Col umb
UnCarb
Eastman
Tenneco
Rheox
D a n i e l
C i ba-
SCM
T i o x i d e
duPont
Kronos
UnCarb
UnCarb
UnCarb
242 Water-Based Point Formulations
RAW MATERIAL CHEMICAL DESCRIPTION
Tronox CR-800/CR-813/ R u t i l e t i t a n i u m d i o x i d e s
CR-828
Troysan Polyphase Fungicides
AF-1/174/586
Troysol LAC Detergent/surfactant
TS 610
Ucar 515
Ucar F i 1mer I B T
Ucar Latex 100
Ucar Latex 105
Ucar Latex 144
Ucar Latex 146
Ucar Latex 161
Ucar Latex 163
Ucar Latex 169
Ucar Latex 353
Ucar Latex 367
Ucar Latex 379
Ucar Latex 3796
Ucar Latex 421
Ucar Latex 422
Ucar Latex 446
Ucar Latex 447
Ucar Latex 461
Ucar Latex 471
A c r y l i c l a t e x
High s o l i d s a c r y l i c b i n d e r
S e l f - c r o s s l i n k i n g a c r y l i c l a t e x
Styrene-acryl ic emu1s i on polymer
V i n y l a c r y l ic copolymer
A1 1- a c r y l ic b i nder
A c r y l ic polymer b i nder
V i n y l a c e t a t e copolymer
A c r y l ic 1atex polymer
A c r y l i c l a t e x polymer
V i n y l a c r y l ic polymer
S t y r e n e / a c r y l i c l a t e x - s o f t
S t y r e n e / a c r y l i c l a t e x - h a r d
SOURCE
Kerr-Mc
Troy
Troy
Cabot
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
Trade Named Raw Materials 243
RAW MATERIAL CHEMICAL DESCRIPTION
Ucar Latex 481 U l t r a - g l o s s l a t e x . Polymer: Hard
Ucar Latex 624 100% a c r y l i c l a t e x
Ucar Latex 625 A c r y l ic 1atex
Ucar l a t e x 626 A11- a c r y l ic b i nder
Ucar Latex 651 A c r y l i c l a t e x
Ucar Latex 2300
Ucar Latex 6030 F i ne p a r t i c l e s ze "booster" 1atex
Ucar Latex 6336 Hard, a l l - a c r y l c l a t e x
Ucar Latex 6390 A c r y l i c b i nder . "Booster" 1atex
Ucar Pol yphobe 102/103 Rheology modi f ie r s
Ucar Polyphobe 106HE/ High e f f i c i e n c y t h i c k e n e r s
107/114-
Ucar Polyphobe 9831
Ucar SCT100/SCT200/
146
Ucar V e h i c l e 435
Ucar V e h i c l e 441
Ucar V e h i c l e 443
Ucar V e h i c l e 455
Ucar V e h i c l e 462
Ucar XYHL
Ucar 376
Rheology modi f ie r
Thickeners
SOURCE
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
A c r y l i c polymer (45% s o l i d s ) UnCarb
A c r y l ic emu1s i on Uncarb
A c r y l i c l a t e x (41% s o l i d s ) UnCarb
S e l f -cross1 in k i ng a c r y l ic 1atex UnCarb
Thermosetting s t y r e n e a c r y l i c l a t e x UnCarb
P o l y v i n y l - b u t y r a l r e s i n UnCarb
UnCarb
244 Water-Based Paint Formulations
RAW MATERIAL CHEMICAL DESCRIPTION
V a r s o l No. 1 M i n e r a l s p i r i t s
Versa-F1 ow 102
Waterpoxy 701/702/1401 Epoxies
Wingdale White N a t u r a l ground c a l c i u m c a r b o n a t e
W i tcobond 234 P o l y u r e t h a n e d i s p e r s i o n
W o l l a s t o c o a t 10AS
W o l l a s t o k u p IOES
W/R Epoxy E s t e r Resin
W/R P o l y e s t e r 72-7203
SOURCE
Exxon
Shamroc
Henkel
GeorMar
W i t c o
Nyco
NyCQ
Rei ch
C a r g i 11
X-3356 C.P. Medium Medium chrome y e l l o w pigment C i ba-
XX-503/XX-503R Z i n c o x i d e s NJZinc
XAMA- 7 Rohm&
YD-2288
Ye1 k i ns-TS Soya l e c i t h i n
Y e l l o w I r o n Oxide YO-2087 Pigment
Y e l l o w I r o n Oxide 1075A Pigment
Zeeospheres 400
Zeeospheres 600
Z i n c Chromate Y539D
Z i n c Hydro-Nap
Z i n c Oxide 417-W
H a r c r o s
Ross&
H a r c r o s
Col umb
Zeel and
Zeel and
Heubach
Mooney
Eag1e
Trade Named Raw Materials 245
RAW MATERIAL CHEMICAL DESCRIPTION
Z i r c o 6% D r i e r
Z i r c o n i um Chem-All 12%
Z i r c o n i um Hydro-Cem Z i r c o n i um d r i e r , 12%
Zirconium Hydro-Cure 12% C a t a l y s t f o r water systems
Zopaque RCL-6 Titanium d i o x i d e . R u t i l e
Zopaque RCL-9 T i t a n i um d i o x i d e
1OES Wol 1astocoat
233 Basic Zinc Chromate
399 Lo-Micron T a l c Extender pigment
895-9901 Water-dispersed b l a c k pigment
SOURCE
I n t e r s t
Mooney
Mooney
Mooney
SCM
SCM
Nyco
Wayne
WC&D
Tenneco
Suppliers' Addresses 247
A i r Products and Chemicals
7201 Hami 1t o n Blvd.
Allentown, PA 18195
(215)-481-4911/(800)-345-3148
Akzo Chemical s, I n c .
300 S. Riverside Plaza
Chicago, I L 60175
(312)-906-7500/(800)-257-8292
Alcoa I n d u s t r i a l Chemicals
P.O. Box 67
Bauxite, AR 72011
(501)-776-4981/(800)-643-8771
American Cyanamid Co.
Chemicals Group
One Cyanamid Plaza
Wayne, NJ 07470
(201)-831-2000/(800)-443-0443
Angus Chemical Co.
1500 E. Lake Cook Rd.
B u f f a l o Grove, I L 60089
(708)-215-8600/(800)-362-2580
Aqua1on
P.O. Box 15417
2711 C e n t r e v i l l e Rd.
W i 1m i ngton, DE 19850
(302)-996-2000/(800)-345-8104
ARC0 Chemical Co.
3801 West Chester Pike
Newtown Square, PA 19073
(215)-359-2000
Asarco, I n c .
180 Maiden Lane
New York, NY 10038
(212)-510-2000
BASF Corp.
100 Cherry H i l l Rd.
Parsippany, NJ 07054
Buckman Laboratories I n t ' l I n c .
1256 N. McLean 8lvd.
Memphis, TN 38018
(201)-316-3000/(800)-526-1072
(901)-278-0330/(800)-BUCKMAN
Burgess Pigment Co.
P.O. Box 349
Sandersville, GA 31082
(912)-5552-2544/(800)-641-8999
Byk-Chemi e USA
524 S. Cherry S t .
Wall ingford, CT 06492
Cabot Corp.
R t . 36 West
Tuscola, I L 61953
(203)-265-2086
(217)-253-3370/(800)-222-6745
Calgon Corp.
P.O. Box 1346
Pitsburgh, PA 15230
C a r g i l l , I n c .
P.O. Box 5630
M i nneapol is , MN 55440
(612)-475-6478/(800)-535-1443
(412)-777-8000/(800)-4-CARBON
CasChem, I n c .
40 Avenue A.
Bayonne, NJ 07002
Chemical Corp. o f America
2 Carlton Ave.
E. Rutherford, NJ 07073
(201)-858-7900/(8OO)-CAS-CHEM
(201)-438-5600
C i ba-Gei gy Corp.
7 S k y l i n e D r .
Hawthorne, NY 10532
(914)-347-4700/(800)-431-1900
Columbian Chemicals Co.
1600 Parkwood C i r c l e
A t l a n t a , GA 30339
(404)-951-5700/(800)-235-4003
Cosan Chemical Corp.
400 14th S t .
C a r l s t a d t , N J 27072
(201)-460-9300
248 Water-Based Paint Formulations
C r u c i b l e Chemical Co., I n c .
P.O. Box 6786
G r e e n v i l l e , SC 29606
(803)-277-1284/(800)-845-8873
Cyprus I n d u s t r i a l M i n e r a l s
P.O. Box 3419
Englewood, CO 80155
(800)-325-0299
Daniel Products
400 Claremont Ave.
Jersey C i t y , NJ 07304
(201)-432-0800
Frank D. Davis Co.
7011 M u i r k i r k Rd.
Bel t s v i 1l e , MD 20705
(301)-776-2400/(800)-638-4444
Davi son Chemical D i v .
W.R. Grace & Co.
P.O. Box 2117
B a l t i m o r e , MD 21203
Degussa Corp.
65 Challenger Rd.
R i d g e f i e l d Park, N J 07305
(201)-641-6100
Dexter Chemical Corp.
845 Edgewater Rd.
Bronx, NY 10474
Dover Chemical Corp
W15 & D a v i s
P.O. Box 40
Dover, OH 44622
(800)-321-8805
Dow Chemical USA
2020 Dow Center
Midland, M I 48674
(800) -258-CHEM
Dow C o r n i n g Corp.
Box 0994
Midland, M I 48686
(5171-496-4000
Drew I n d u s t r i a l D i v .
Ashland Chemical I n c .
One Drew Plaza
Boonton, NJ 07005
(201)-263-7800/(800)-526-1015
DuPont Co.
1007 Market S t .
W i 1m i ngton , DE 19898
(800) -441 -751 5
Eagle-Picher I n d u s t r i e s , I n c .
P.O. Box 550
C & P o r t e r S t r e e t s
J o p l i n , MO 64802
(417)-623-8000
Eastman Chemical Co.
P.O. Box 431
K i n g s p o r t , TN 37662
(615)-229-4006/(8OO)-EASTMAN
ECC I n t e r n a t i o n a l
5775 Peachtree-Dunwoody Rd.
A t l a n t a , GA 30342
(404)-843-1551/(800)-843-3222
Engelhard Corp.
101 Wood Ave.
I s e l i n , N J 08830
(908)-205-5000
E n g l i s h Mica Co.
R i dgeway Center B1dg .
Stamford, CT 06905
(203)-324-9531
Exxon Chemical Americas
13501 Katy Frwy
Houston, TX 77079
(713)-870-6000/(800)-231-6633
Freeman I n d u s t r i e s , I n c .
100 M a r b l e d a l e Rd.
Tuckahoe, NY 10707
(914)-961-2100
Suppliers'Addresses 249
GE S i 1icones
260 Hudson River Rd.
Waterford, NY 12188
(518)-237-3330/(800)-255-8886
Genstar Stone Products Co.
Exec Plaza I V
11350 McCormick Rd.
Hunt Valley, MD 21031
(410)-527-4000
Georgia Marble Co.
1201 Roberts Blvd., 8ldg. 100
Kennesaw, GA 30144
(404)-421 -6500
B.F. Goodrich Co.
9911 Brecksvi 11e Rd.
Brecksvi 11e, OH 44141
(216)-447-5000/(800)-331~1144
Goodyear T i r e & Rubber Co.
1144 E . Market S t .
Akron, OH 44316
(216)-796-3010
W.R. Grace & Co.-Conn.
55 Hayden Ave.
Lexington, MA 02173
(617)-861 -6600
Harcros Chemical s I n c
5200 Speaker Rd.
Kansas C i t y , KS 66106
(913)-321-3131
Harshaw/Filtrol Partnership
30100 Chagrin Blvd.
Cleveland, OH 44124
Henkel Corp.
11501 Northlake D r .
C i n c i n n a t i , OH 45299
(513)-530-7300/(800)-543-7370
Heucotech, L t d .
99 Newbold Rd.
F a i r l e s s H i l l s , PA 19030
(215)-736-9533/(800)-HEUEACH
H i 1ton-Davi s Co.
2235 Langdon Farm Rd.
C i n c i n n a t i , OH 45237
(513)-841-4000/(800)-477-1022
Hoechst Celanese Corp.
5200 77 Center D r i v e
Charlotte, NC 28217
(704)-559-6000/(800)-365-2436
J.M. Huber Corp.
Clay Div.
One Huber Rd.
Macon, GA 31298
(912)-745-4751/(800)-637-8176
Huls America I n c .
80 Centennial Ave.
P i scataway, N J 08855
(908)-980-6800/(800)-631-5275
I C 1 Resins US
730 Main S t .
Wilmington, MA 01887
(508)-658-6600/(800)-225-0947
I n t e r s t a b Chemicals, I n c .
500 Jersey Ave.
P.O. Box 638
New Brunswick, NJ 08903
S.C. Johnson Polymer
1525 Howe S t .
Raci ne, W I 53403
(414)-631-4875/(800)-231-7868
Kerr-McGee Chemical Corp.
Kerr-McGee C t r .
P.O. Box 25861
Oklahoma C i t y , OK 73125
(405)-270-1313/(800)-654-3911
King I n d u s t r i e s , I n c .
Science Rd.
Norwalk, CT 06852
(203)-866-5551/(800)-431-7900
250 Water-Based Paint Formulations
KMG M i n e r a l s , I n c .
P.O. Box 729
1433 Grover Rd.
K i ngs Mountain, NC 28086
(704)-739-3616/(800)-443-MICA
Kronos, I n c .
P.O. Box 60087
3000 N . Sam Houston Pkwy
Houston, TX 77205
(713)-987-6300
M a n v i l l e F i l t r a t i o n 8, M i n e r a l s
P.O. Box 519
Lompoc, CA 93438
(303)-978-4900/(800)-6
McWhorter
400 East Cottage Place
C a r p e n t e r s v i l l e , I L 60
4-31 03
10
Michelman, I n c .
9089 S h e l l Road
C i n c i n n a t i , OH 45236
(5131-793-7766
M i c r o Powders, I n c .
580 White P l a i n s Rd.
Tarrytown, NY 10591
(914)-793-4058
M i l e s I n c .
Mobay Road
P i t t s b u r g h , PA 15205
(412)-777-2000/(800)-662-2927
M i n e r a l Pi gments Corp.
Davis C o l o r s
7011 M u i r k i r k Rd.
B e l t s v i l l e , MD 20705
Monsanto Chemi c a l Co.
800 N . Lindbergh B l v d .
S t . Loui s, MO 63167
(314)-694-1000/(800)-325-4330
Mooney Chemicals I n c .
2301 Scranton Rd.
Cleveland, OH 44113
Morton I n t e r n a t i o n a l
333 W. Wacker D r i v e .
Chicago, I L 60606
Nalco Chemical Co.
One N a l c o C t r .
N a p e r v i l l e , I L 60563
(312)-807-2000
(708)-305-1000
New Jersey Z i n c Co.
F o u r t h S t . 8 F r a n k l i n Ave.
Palmerton, PA 18071
NL Chemicals, I n c .
P.O. Box 700
Hightstown NJ 08520
Nyco M i n e r a l s , I n c . ,
P.O. Box 368
W i l l s b o r o , NY 12996
(5181-963-4262
O c c i d e n t a l Chemical Corp.
300 Berwyn Park
Berwyn, PA 19312
(215)-251-1000
OM Group I n c .
2301 Scranton Rd.
Cleveland, OH 44113
(216)-781-8383/(800)-321-9696
Omya I n c .
61 Main S t .
P r o c t o r , VT 05765
(802)-459-3311/(800)-451-4468
Paci f ic Anchor Chemical Corp.
1224 Mendon Rd.
Cumberland, R I 02864
(401)-333-4100/(800)-874-66668
P f i z e r , I n c .
235 E. 42 S t .
New York, NY 10017
(212)-573-7217
Suppliers'Addresses 251
PMC S p e c i a l t i e s Group
20525 Center Ridge Rd.
Rocky R i v e r , OH 44116
(216)-356-0700
Raybo Chemical Co.
P.O. Box 2155K
H u n t i n g t o n , WV 25722
R e i c h h o l d Chemicals, I n c .
P.O. Box 13582
Research T r i a n g l e Park, NC27709
(919)-990-7500/(800)-448-3482
Rheox, I n c .
P.O. Box 700
Hightstown, N J 08520
(609)-443-2500
Rhone-Poulenc I n c .
Prospect P l a i n s Rd.
Cranbury, NJ 08512
(609)-860-4000
Rohm & Haas Co.
Independence M a l l West
P h i l a d e l p h i a , PA 19105
(215)-592-3000
Sanncor I n d u s t r i e s , I n c .
300 Whitney S t .
P.O. Box 703
Leomi n s t e r , MA 01453
(508)-537-4748
SCM Chemical s
2701 Broening Hwy
B a l t i m o r e , MD 21222
(301)-288-8884/(800)-638-3234
Shamrock Technologies, I n c .
Foot o f P a c i f i c S t .
Newark, NJ 07114
S h e l l Chemical Co.
Two She1 1 Plaza
P . 0 . 8 0 ~ 1422
Houston, TX 77251
(201 )-242-2999
(EOO)-TEC-EPON
Sherwin W i 11iams Co.
Chemi c a l s D i v .
P.O. Box 6520
Cleveland, OH 44101
(216)-566-2344
S i l b e r l i n e Mfg. Co.
P.O. Box A
Lansford, PA 18232
(717) -668-6050
Sun Chemical Corp.
4526 C h i c k e r i n g Ave.
C i n c i n n a t i , OH 45242
(513)-68l-5950/(800)-543-2323
3M Corp.
3M Center
S t . Paul, MN 55144
(612) -733-1 110
Tammsco, I n c .
P . O . Box J
Tamms, I L 62988
Tenneco M i n e r a l s Co.
P.O. Box 281300
Lakewood, CO 80228
(303)-987-6200
Troy Corp.
72 Eagle Rock Ave.
East Hanover, N J 07936
(201)-884-4300
U l t r a A d d i t i v e s , I n c .
460 S t r a i g h t S t .
Paterson, NJ 07501
(201)-279-1306/(800)-524-0055
Unimin Corp.
258 E l m S t .
New Canaan, CT 06840
(203)-966-8880/(800)-243-9004
UCAR Emu1s i o n Systems
410 Gregson D r i v e
Cary, NC 27511
(919)-469-6700
252 Water-Based Paint Formulations
R.T. Vanderbilt Co.. I n c .
30 W i n f i e l d S t .
P . O . Box 5150
Norwalk, CT 06856
(203)-853-1400
Velsicol Chemical Corp.
5600 N . River Rd.
Rosemont, I L 60018
(708)-698-7000
Wacker S i l i c o n e s Corp.
3301 Sutton Rd.
Adrian, MI 49221
(517)-264-8500/(800)-248-0063
Whittaker, Clark & Daniels, I n c .
1000 Coolidge St.
South P l a i n f i e l d , NJ 07080
(908)-561-6100/(800-732-0562
Witco Corp.
520 Madison Ave.
New York, NY 10022
(212)-605-394l/(800)-238-9150

Water-based paint formulations Vol. 4

  • 1.
    WATER-BASED PA1NT FORMULATIONS Volume 4 by ErnestW. Flick NOYES PUBLICATIONS Inp IWesWood, New Jersey, U.S.A.
  • 2.
    Copyright 8 1997by Ernest W. Flick No patt of this book may be reproduced or utilized in any fonn or by any means, electronic or mechanical including photocopying, recording 01 by any informa- tion stonge and retrieval system, without permission in Writing from the Publisher. Library of Congress Catalog Card Number: 75-2939 Printed in the United States ISBN 0-8155-1415-8 Published in the United States of America by Noyes Publications 369 Fairview Avenue Westwood, New Jersey 07675 10 9 8 7 6 5 4 3 2 1 Library of Congress Cataloging-in-Publications Data (Revised for vol. 4) Flick, Ernest W. Water-based paint formulations. Vol. 4 published by Noyes Publications. Includes index. 1. Paint--Patents. II. Title. TP935.F62 1975 66T.63 75-2939 ISBN 0-8155-0571-X (v. 1) ISBN 0-8155-1345-3 (v. 3) ISBN 0-8155-1415-8 (v. 4)
  • 3.
  • 4.
    This collection of232up-to-date water-based trade and industrial formulations will be of value to technical and managerial personnel in paint manufacturing companies and firms which supply raw materials or services to these companies, and to those interested in less hazardous, environmentally safer formulations. The book will be useful to both those with extensive experience as well as those new to the field. This book includes new and different formulations than those included in the previously published Industrial Water- Based Paint Formulations and Water-Based Paint Formulations. The data consist of selections of manufacturers' suggested formulations made at no cost to, nor influence from, the makers or distributors of these materials. The information given is presented as supplied; the manufacturer should be contacted if there are any questions. Only the most recent data supplied us has been included. Any solvent contained is minimal. The table of contents is organized in such a way as to serve as a subject index. The formulations described are divided into sections which cover exterior, interior, and exterior and/or interior water-based paints, enamels, and coatings, as indicated below: I. Coatings and Topcoats 11. Coil Coatings 111. Enamels IV. Enamels-Baking V. Exterior Paints and Related Products VI. Interior Paints and Related Products VII. Lacquers VIII. Primers IX. Sealants and Related Compounds X. Stains XI. Miscellaneous Each formula has been placed in the chapter which is most applicable. The reader, if seeking a formula for a specific end use, should check each chapter which could possibly apply. vii
  • 5.
    ... viii Preface In additionto the above, there are two other sections which will be helpful to the reader: XI. A chemical trade name section where trade-named raw materials are listed with a chemical description and the supplier's name. The specifications which the raw materials meet are included if applicable. XIII. Main office addresses of the suppliers of trade-named raw materials and/or formulations. Included in the descriptive information for each formulations, where available, the following properties may be listed: viscosity, solids, content, % nonvolatiles, pigment volume concentration, density, pH, spatter, leveling, sag resistance, scrub stability, freeze-thaw stability, ease of application, gloss foaming, cratering, brightness, opacity, water spotting, adhesion to chalk, brush clean-up, reflectance, and sheen. Ernest W. Flick Notice To the best of our knowledge the information in this publications is accurate; however, the Publisher does not assume any responsibility or liability for the accuracy or completeness of, or consequence arising from, such information. These formulations do not purport to contain detailed manufacturing nor user instruction, and by its range and scope could not possibly do so. Mention of trade names or commercial products does not constitute endorsement or recommendation for use by the Author or Publisher. Water-based paint raw materials could be toxic, and therefore, due caution should always be exercised in the use of these hazardous materials. Final determination of the suitability of any information or product for use contemplated by any user, and the manner of that use, is the sole responsibility of the user. We strongly recommend that users seek and adhere to a manufacturer's or supplier's current instructions for handling each material they use. The Author and Publisher have used their best efforts to include only the most recent data available. The reader is cautioned to consult the supplier in case of questions regarding current availability.
  • 6.
    SECTION I: COATINGSAND TOPCOATS .................... 1 Clearcoat Modification ............................... 2 825/Rhoplex CL-104) ................................ 3 Ancamine 2410 High Solids Coating ........................ 4 2410/Ancamide 500 High Solids Coating . . . . . . . . . . . . . . . . . . 5 Cured with HMMM ................................. 6 Phenolic Clear Bake Coating .............................. 8 Clear Bake Coating ..................................... 9 Phenolic Clear Bake Coating .............................. 9 Clear Wood Coating-A & B & C K-Flex UD-320W Modified .... 10 Direct to Metal Acrylic Latex Coating Starting Point Formulation ...................................... 11 Low Gloss VinyVABS Topcoat ........................... 12 Clear Topcoat for Flexible Substrates ....................... 12 . . . . . . . . . . 13 Lower Adhesion ................................... 13 Polyphobe Rheology Modifiers Formula C Good Leveling . . . . . 14 ................................. 14 Acrylic EmulsiodUrea-Formaldehyde Wood Aliphatic Wood Coating Formulation (Sancure Exhibit 4 .Starting Formulation Ancamine Black Single Coat K-Flex XM-4316 PU Dispersion Clear Bake Coating ..................................... 7 Strippable Coating Sample Formulation A Unmodified Strippable Coating Sample Formulation B Strippable Coating Formulations Thickened with Ucar Formula D High Build Strippable Coating for Plastic Substrates ..................... 15 Strippable Coating Formulations .......................... 16 Topcoat for Prefinished Hardboard Siding .................... 17 Water-Borne Alkyd/Melamine Wood Clearcoat Modification . . . . . . 18 Waterborne Clear High Gloss Topcoat ...................... 20 White Gloss Maintenance Topcoat ......................... 21 White Gloss Topcoat . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22 Wood Topcoat Model Formulations ........................ 23 ix
  • 7.
    x Contents andSubject Index SECTION 11: COIL COATINGS ............................ 24 Chromate Coil-Coating Primer ........................... 25 Low-Sheen Coil-Coating Topcoat ......................... 26 Medium-Gloss Coil-Coating Topcoat ...................... 27 Strippable Coil Coating ................................. 28 SECTION LII: ENAMELS ................................. 29 Acrylic Emulsion Enamel-B&C K-Flex UD-320W Modified . . . . . 30 Synergistic Effects of Combining Nacorr with Anti- Corrosive Pigment in an Air Dry Water Reducible Alkyd Modified Acrylic Enamel ....................... 31 Ancamide 2353 Fast Drying White Gloss Enamel . . . . . . . . . . . . . . 32 Ancamide 2353 Low VOC White Gloss Enamel . . . . . . . . . . . . . . . 33 Cary Gloss White Enamel ............................... 34 Clear Enamel (For Maximum Solvent and Abrasion Resistance) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 Gloss Safety Red Enamel ............................... 37 Gloss Safety Yellow Enamel ............................. 38 Gloss White Enamel ................................... 39 Gloss White Enamel (Maximum Solvent and Abrasion Resistance) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41 Green Air Dry Enamel for Flexible Substrates . . . . . . . . . . . . . . . . . 42 High-Hiding Eggshell Enamel ............................ 43 MacGregor Gloss Black Enamel .......................... 44 Pinehurst Gloss Green Enamel ............................ 45 Self-Priming Interior Semi-Gloss Enamel . . . . . . . . . . . . . . . . . . . 46 Exterior Maintenance-Type Coating ........................ 46 Semigloss Enamel ..................................... 47 Southern Pines Gloss White Enamel ........................ 49 Spensol I54 Orange Enamel ............................. 50 Waterborne Black Enamel Based on Epotuf 37-143/37-680 (Formula No. 3019-28A) ............................ 51 Waterborne Blue Enamel Based on Epotuf 37-143/37-680 (Formula No.3019-316) ............................ 52 Waterborne Dark Blue Enamel Based on Epotuf 37-143/37-680 (Formula No.3019-31D) . . . . . . . . . . . . . . . . . 53 Waterborne Green Enamel Based on Epotuf 37-143/37-680 (Formula No. 3019-3lF) ............................. 54 Waterborne Orange Enamel Based on Epotuf 37-143/37-680 (Formula 3019-310 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55 Waterborne Red Enamel Based on Epotuf 37-143/37-680 (Formula No. 3019-31B) ............................ 56 Waterborne Red Orange Enamel Based on Epotuf 37-143/37-680 (Formula No. 3019-31E) . . . . . . . . . . . . . . . . . 57
  • 8.
    Contents and SubjectIndex xi Waterborne Yellow Epoxy Enamel Based on Epotuf 37-143/37-680 (Formula No.3019-31C) . . . . . . . . . . . . . . . . . 58 Whispering Pines Semigloss White Enamel . . . . . . . . . . . . . . . . . . . 59 Anquamine 401 1:l White Gloss Enamel .................... 60 Gloss Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61 Anquamine 401/Solid Resin Dispersion 2:l White SECTION IV: ENAMELS-BAKING ........................ 62 Clear Bake Coating .................................... 63 Phenolic Clear Bake Coating ............................. 63 Clear High Gloss. Baking Finish .......................... 64 Blue Metallic Urethane Enamel ........................... 64 Experimental Water-Reducible Polyester Gloss White Baking Enamel Using Halox SZP-391 . . . . . . . . . . . . . . . . . . . 65 Waterborne Acrylic Bake Enamel Water Reducible Polyester Baking Enamel Spensol L54 White Baking Enamel 2-Component Waterborne System ......................... 69 ......................... 66 . . . . . . . . . . . . . . . . . . . 67 ........................ 68 SECTION V: EXTERIOR PAINTS AND RELATED PRODUCTS . . . 70 Exterior Flat House Paint with ZnO ........................ 71 Exterior Gloss White . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73 Exterior House Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74 Exterior House Paint .Tint Base .......................... 75 Exterior Semigloss Formulation ........................... 77 Exterior Tint Base Formulation ........................... 78 Exterior Trim Formulation Modified Vinyl Acrylic Paint . . . . . . . . . 79 Exterior Trim Formulation ............................... 80 Exterior White Flat House Paint ........................... 82 Exterior White Trim house Paint .......................... 83 Good Quality White Exterior Flat Paint for Masonry . . . . . . . . . . . . 84 Good Quality White Exterior Flat Paint for Wood . . . . . . . . . . . . . . 85 Gregson Drive Gloss White .............................. 86 High Quality Exterior Semi Gloss Paint ..................... 87 High Sheen White House Paint ........................... 88 Low VOC Exterior House Paint ........................... 89 Quality Exterior Flat Formulation .......................... 90 Quality Exterior Flat Paint ............................... 91 Quality White Exterior Trim Paint ......................... 92 Quality White House Paint with ZnO ....................... 94 Urethane Fortified Porch & Deck Enamel .................... 95 Weather Barrier Formulation ............................. 96 White Exterior Flat House Paint with Zinc Oxide . . . . . . . . . . . . . . 97 Exterior Semigloss .................................... 76
  • 9.
    xii Contents andSubject Index White Roof Coating ................................... 99 SECI'ION VI: INTERIOR PAINTS AND RELATED PRODUCTS . 100 Clear High Gloss Varnish .............................. 101 Fast-Dry Sealer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101 Economy Flat Wall Paint .............................. 102 Good Quality Interior Flat with <50g/L VOC . . . . . . . . . . . . . . . . 104 High Quality Super Flat Interior Paint ..................... 105 Interior Clear Wood Finish (Rhoplex CL-l04/Sancure 815) . . . . . . 106 Interior Sanding Sealer (Rhoplex CL-105) . . . . . . . . . . . . . . . . . . 106 Interior Contractor Flat ................................ 107 Interior Good Quality Flat for Roller and Brush Application ..................................... 108 Interior Good Quality Flat .............................. 110 Interior Semigloss Formulation .......................... 111 Interior Vinyl Acrylic Eggshell for Roller and Brush Application ................................. 112 Interior Vinyl Acrylic Semigloss ......................... 114 Intumescent Interior White Fire-Retardant Paint . . . . . . . . . . . . . . 115 Low VOC Interior Flat ................................ 116 Solvent Free Interior Satin Paint ......................... 117 White Interior Eggshell ................................ 118 SECTION VII: LACQUERS .............................. 119 Green Lacquer ...................................... 120 DIY Waterborne Lacquer ........................... 121 White Lacquer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 122 Foam Control with Agitan Additives in a High Gloss SECI'ION VIII: PRIMERS ............................... 124 Acrylic Latex Tannin Block Primer Using Halox BW-100 . . . . . . 125 Alkyd Modified Latex Primer ........................... 126 Ancamide 2353 Curing Agent Anti-Corrosive Primer . . . . . . . . . . 127 Anquamine 401/Semi-solid Epoxy Dispersion Lead and Chromate Free Red Iron Oxide Primer 128 Anquamine 401/Solid Resin Dispersion Lead and Chromate Free Red Iron Oxide Primer . . . . . . . . . . . . . . . . . . 129 Corrosion Inhibitive Primer ............................. 130 Metal Wash Primer ................................... 130 Cost Effective 2K Water-Base Epoxy Primer Using Halox SW-111 ................................... 131 Dipping Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 132 Experimental General Purpose Tannin-Stain Resistant Water-Base Primer Using Halox Xtain A . . . . . . . . . . . . . . . . 133 . . . . . . . . . . . . . . .
  • 10.
    Contents and SubjectIndex xiii Experimental High Performance Tannin-Stain Resistant Water-Base Primer Using Halox Xtain A . . . . . . . . . . . . . . . . Experimental Waterbase Acrylic Red Iron Oxide Primer . . . . . . . . 135 Exterior House Paint Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . 138 Exterior House Paint Primer Based on Ucar Latex 163 . . . . . . . . . 139 General Purpose Latex Maintenance Primer . . . . . . . . . . . . . . . . . 140 General Purpose/Low Cost Water-Base Primer . . . . . . . . . . . . . . . 141 High Performance Bare Metal Primer ...................... 142 High Performance Galvanized Metal Primer . . . . . . . . . . . . . . . . . 143 High Performance 2K Water-Base Epoxy Primer 144 Halox SZP-391 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 145 High Solids Red Iron Oxide Epoxy Primer . . . . . . . . . . . . . . . . . . 147 House Paint Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 148 Lead and Chromate Free Primer .......................... 149 Lead and Chromate Free Red Iron Oxide Primer . . . . . . . . . . . . . . 150 Lead and Chromate Free Waterborne Epoxy Primer . . . . . . . . . . . 151 Lead Based Primer ................................... 152 Lead Silico Chromate Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153 Low Sheen Gray Primer ............................... 154 Non-Lead/Non-Chromate Primer ........................ 155 134 . . . . . . . . . . . . . High Performance 2K Water-Base Epoxy Primer Using Primer for Factory-Primer Hardboard Siding . . . . . . . . . . . . . . . . 156 Primer 20323D Based on Phosguard J-0853 and 10 ES Wollastocoat Henkel's Waterpoxy 1401:701 System . . . . . . . . 157 Primer 203236 Based on Phosguard J-0813 and 10 ES Wollastocoat Henkel's Waterpoxy 1401:701 System . . . . . . . . 158 Primer 20596F Based on Heucophos ZPZ and 10 ES Wollastocoat Henkel's Waterpoxy 1401:701 System . . . . . . . . 159 Primer 20596G Based on Heucophos ZMP and 10 ES Wollastocoat Henkel's Waterpoxy 1401:701 System . . . . . . . . 160 Primer 21102E Based on Molycoat 212 and 10 AS Wollastocoat Henkel's Waterpoxy 1401:701 System . . . . . . . . 161 Primer 21105H Based on Phosguard J-0815 and 10 ES Wollastocoat Henkel's Waterpoxy 1401:702 System . . . . . . . . 162 Primer 211051 Based on Nalzin 2 and 10 ES Wollastocoat Henkel's Waterpoxy 1401:702 System . . . . . . . . 163 Primer 21109C Based on Strontium Chromate and 10 ES Wollastocoat Henkel's Waterpoxy 1401:702 System . . . . . . . . 164 Rapid Dry Waterborne Epoxy Primer ...................... 165 Red Inhibitive Maintenance Primer ....................... 167 Red Iron Oxide Corrosion Resistant Epoxy Primer (Two Component System) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 168 Red Iron Oxide Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 169 Red Iron Oxide Water Reducible Alkyd Primer . . . . . . . . . . . . . . . 171
  • 11.
    xiv Contents andSubject Index Rust Inhibitive Chromate Primer ......................... 172 Solvent Resistant. Water-Reducible Epoxy Primer . . . . . . . . . . . . 173 lT-P-1975 Federal Specification Metal Primer . . . . . . . . . . . . . . 174 Universal Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 175 Universal Primer Non-Lifting and High Salt Spray Resistance . . . . 176 Water-Base Acrylic Universal Primer Using Halox Water-Base Acrylic Universal Primer Using Halox SZP-391 & Xtain A ............................... 178 Waterborne Black Iron Oxide Primer Based on Epotuf 37-143/37-680 (Formula No.3019-38A) . . . . . . . . . . 179 Waterborne Red Iron Oxide Primer Based on Epotuf 37-143/37-680 (Formula No.2954-76A) . . . . . . . . . . 180 Waterborne Red Oxide Epoxy Primer ...................... 181 Waterborne Yellow Iron Oxide Primer Based on Epotuf 37-143/37-680 (Formula No. 3019-39B) . . . . . . . . . . 182 Water Reducible Alkyd Yellow Iron Oxide Primer Using Halox SZP-391 ............................. 183 Water Reducible Alkyd Yellow Iron Oxide Primer Using Halox CW-491 .............................. 184 Water Reducible Epoxy-Ester Red Iron Oxide Primer . . . . . . . . . . 185 Water Reducible Epoxy-Ester Red Iron Oxide Primer Using Halox CW-491 .............................. 187 White. Corrosion Resistant Latex Primer . . . . . . . . . . . . . . . . . . . 188 White Inhibitive Maintenance Primer ...................... 189 SZP-391 & BW-100 .............................. 177 SECTION IX:SEALANTS AND RELATED COMPOUNDS . . . . . . 190 Ancamide 2353 Curing Agent Aluminum Mastic . . . . . . . . . . . . . . 191 Clear Sealant ....................................... 192 High-Quality Exterior Latex Caulk ....................... 193 Patching Compound (Brushing Grade) ..................... 194 Patching Compound (Trowel Grade) ....................... 195 Pigmented Caulk Formulation based on 2:l Vinyl AcrylidAcrylic Blend .............................. 196 Premium.Performance. Medium-Flexibility Caulk . . . . . . . . . . . . 197 Sealant Application ................................... 198 Translucent Caulk Formulation .......................... 199 ASTM C-920 Pigmented Caulk Formulation . . . . . . . . . . . . . . . . 200 Translucent Sealant ................................... 201 Vinyl Acrylic Sealant . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 202 Weather-Barrier Mastic ............................... 203 SECTION X: STAINS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 205 Brown Wiping Stain .................................. 206
  • 12.
    Contents and SubjectIndex xv Interior Wiping Stain (Emulsion E-2977) . . . . . . . . . . . . . . . . . . . 207 Light Redwood Wiping Stain ............................ 208 Stain Concentrate .................................... 209 Tannin Stain Blocking Formulation ....................... 210 Acrylic Tannin Stain-Blocking Primer ..................... 210 Water Reducible Redwood Solid Color Stain . . . . . . . . . . . . . . . . 211 Stain . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 207 SECI'ION XI: MISCELLANEOUS ......................... 212 Anquamine 401 Clear Coat Semi-Solid Epoxy Dispersion . . . . . . . 213 Anquamine 401 Clear Coat Solid Epoxy Dispersion . . . . . . . . . . . 214 Anquamine 401 Liquid Epoxy Clear Coat . . . . . . . . . . . . . . . . . . . 214 Aqueous Polyester-Urethane Pigment Dispersion . . . . . . . . . . . . . 215 Black Gloss Enamel .................................. 216 Clear Barriernie Coat for Vinyl ......................... 216 Clear Tint Base ..................................... 217 Clear Waterborne Cement Sealer ...................... 218 Waterborne Black Topcoat ............................. 218 Exterior/Interior Block Filler ............................ 219 High Solids Self Priming Alkyd .......................... 220 Masonry Block Fill . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 221 Masonry Blockfill .................................... 222 Water Reducible Alkyd ................................ 223 2-Component Waterborne System ........................ 224 FCA's for Waterborne Building Product Formulations SECTION XII: TRADE NAMED RAW M A T E W S . . . . . . . . . . . 225 SECTION XIII: SUPPLIERS ADDRESSES . . . . . . . . . . . . . . . . . . 246
  • 13.
    2 Water-Based PaintFormulations A c r y l i c Eaulsion/Urea-Formaldehyde Wood C l e a r c o a t M o d i f i c a t i o n K-Flex UD-320W i s an a l i p h a t i c , s a t u r a t e d , water s o l u b l e r e s i n m o d i f i e r . T h i s urethane d i o l m o d i f y i n g r e s i n i m p a r t s improved s t a i n r e s i s t a n c e t o t h e f o r c e d d r y (thermoset) wood c l e a r c o a t formul a t ion b e l ow. What makes t h i s f o r m u l a t i o n unique, i s t h e absence o f n e u t r a l - i z i n g amines. As a r e s u l t , a f r e e a c i d c a t a l y s t may be used (Nacure 155) and lower temperature c u r e s may be achieved. A p o t l i f e of 24-48 hours i s p o s s i b l e . WB Wood C l e a r c o a t Component: B e e t l e 65 Methanol S i l w e t t L-77 Rhopl ex AC-1024 Water Exxate 700 Chemcor AS-35-3 K-Flex UD-320W Nacure 155 Methanol M o d i f i c a t i o n : 0% 24.5 2.4 0 . 4 49.2 7.2 1 . 4 4.1 0.0 4.9 5.9 %K-Flex UD-320W -5% 10% 24.5 24.5 2.4 2 . 4 0 . 4 0 . 4 44.2 39.3 9 . 4 11.5 1.4 1 . 4 4 . 1 4.1 2.8 5.5 4.9 4.9 5.9 5.9 F o r m u l a t i on Procedure: 1. The components were added i n t h e o r d e r as presented, f o r easi e r in c o r p o r a t i on. 2. The Nacure 155 c a t a l y s t was p r e - d i l u t e d w i t h t h e methanol below i t i n t h e f o r m u l a t i o n b e f o r e i n c o r p o r a t i o n , w i t h a Nacure 155/Methanol r a t i o o f 45.5/54.5. S u b s t r a t e : B i r c h Faced Plywood S e a l e r : S e l f Sealed ( 2 Coats, 2 bakes) Sealer/Topcoat, WFT: 20-25u (0.8-1.0 m i l ) / C o a t Sealer/Topcoat Bake: 10 min./71C (160F) 4 Hour Spot T e s t S t a i n T e s t : 0% UD-320W 10% UD-320W Acrylic/UD-320W/B-65 50/0/50 40/10/50 C o f f e e Severe Haze L i g h t S t a i n M i l k Severe Haze No E f f e c t Mustard Water Lemon J u i c e No E f f e c t L i g h t S t a i n Severe Haze No E f f e c t S l i g h t Haze No E f f e c t No e f f e c t was seen i n t h e 4 hour s p o t t e s t i n any o f t h e f o r m u l a t i o n s w i t h ketchup, n a i l p o l i s h remover, i s o p r o p a n o l , l i q u i d c l e a n e r o r l i p s t i c k . 160F r e s u l t e d i n an H p e n c i l hardness and 100+ MEK double rubs. SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n WR-26 Drawdowns made o v e r Aluminum p a n e l s and baked 10 minutes a t
  • 14.
    Coatingsand Topcoats 3 Al i p h a t i c Wood Coatinn Formulation JSancure 825/Rho~lexCL-104) 61end : Rhoplex CL-104 (38% S o l i d s ) Water Add f o l l o w i n g w i t h good a g i t a t i o n : Dowanol DPM Hexyl C a r b i t o l Mix 10-15 minutes Sancure 825 (34% S o l i d s ) Surfactant Package (Premix t h e f o l l o w i n g ) : Surfynol 104H Surfynol DF-l1OL Mineral S p i r i t s Surfynol DF-70 DC-14 Add and mix 30 minutes Pounds 134.2 33.8 12.75 2.55 100.0 2.6 1 . 3 1.3 1.3 0.7 Adjust t o desired v i s c o s i t y using Acrysol RM825 (Rohm & Haas Co.) I f required, f l o w i s enhanced by a d d i t i o n o f very low l e v e l s o f Fluorad FC-129 (3M Corp.) as a 10% s o l u t i o n i n water. NOTE: Avoid excessive use o f fluorocarbons, as sharp surface tension drops can cause recoat problems and strong foaming tendencies. Always a d j u s t t o desired v i s c o s i t y range p r i o r t o evaluating f l o w / l e v e l and deaeration p r o p e r t i e s . Low v i s c o s i t y can y i e l d “Picture-Framing‘‘ and/or a “ F i sh-Eye“ e f f e c t . High v i s c o s i t y can y i e l d poor deaeration p r o p e r t i es. Surfynol a d d i t i v e s have been shown t o provide t h e f o l l o w i n g benef it s : *Color u n i f o r m i t y o f s t a i n s *Early s t a i n 1appi ng resistance *Consistent wetting, f l o w and l e v e l i n g on various woods *Foam c o n t r o l With no detrimental e f f e c t upon: *Topcoat r e c o a t a b i l i t y and i n t e r c o a t adhesion *Gloss r e t e n t i o n upon aging *Tannin bleed r e s i stance *Water s e n s i t i v i t y *Chemical resistance SOURCE: A i r Products & Chemicals, I n c . : Surfynol Surfactants: Formulation A (B.F. Goodrich)
  • 15.
    4 Water-Based PaintFormulations Ancamine 2410 H i g h S o l i d s C o a t i n g A S i d e : DER 331 TS 610 50% FC430 i n Xylene Disperse, t h e n reduce speed S t a i n l e s s s t e e l f l a k e BYK 320 Aromatic 100 B S i d e : Ancami ne 2410 E t h y l A l c o h o l D i s s o l v e , t h e n add: C a b o s i l TS 720 W o l l a s t o c o a t 10ES D i s p e r s e t o 6 n . s . u . Methyl E t h y l Ketone T y p i c a l P r o p e r t i e s : Non V o l a t i l e by Weight: 0.75 Non V o l a t i l e by Volume: 0 . 6 0 PVC: 0 . 1 6 CPVC: 0 . 3 4 PVC/CPVC: 0 . 4 8 P i gment Content: 0.30 NVV on V e h i c l e : 0 . 6 4 VOC g/1: 3 2 7 . 9 VOC l b s / g a l : 2 . 7 4 & 330.9 7 3.5 176 79 7 . 1 1 5 0 . 5 37.7 8.8 133.3 152.3 Wei ght/Gal l o n Comp A : Weight/Gallon Comp 0 : M i x i n q R a t i o : 1 : l Gals 34.1 0 . 4 0 . 4 3 . 2 1 1 0 . 9 1 5 . 5 5.8 0 . 5 5 . 5 22.7 1 2 . 0 6 9 . 6 5 Weight p e r G a l l o n : 1 0 . 8 5 I n i t i a l V i s c o s i t y : 580 cP Pot L i f e : 4 . 5 h r Dry t o Touch: 0.75 h r Dry Hard: 4 h r Ancamine 2410 Chemical Resistance: 7 Day Immersion R e s u l t s : Reagent : Acetone Cyclohexanone PM A c e t a t e E t h y l A c e t a t e Ethanol Isodecanol Aromatic 100 To1uene DMF THF EP R e s u l t : No E f f e c t No E f f e c t No E f f e c t No E f f e c t No E f f e c t No E f f e c t No E f f e c t No E f f e c t No E f f e c t No E f f e c t No E f f e c t Reagent: NMP C1o r o x Skydro1 50% c a u s t i c 10% c a u s t i c 6% HC1 : S u l f u r i c : A c e t i c A c i d D i e t h y l ami ne 50% phenol i n x y l e n R e s u l t : No E f f e c t No E f f e c t No E f f e c t No E f f e c t No E f f e c t No E f f e c t 81is t e r e d 81 is t e r e d B l i s t e r e d 0 1 i e D 0 4 SOURCE: A i r Products and Chemicals, I n c . : Ancamine 2410 C u r i n g Agent: E x h i b i t 3 F o r m u l a t i o n
  • 16.
    Coatings and Topcoats5 E x h i b i t 4 - S t a r t i n g Formul-ation Ancarni ne 241O/Ancami de 500 High. Sol i d s C o a t i n g A S i d e : DER 331 C a b o s i l TS-610 Lbs Gals 284.6 29.3 7.6 0.43 D i s p e r s e a t H i g h Speed Reduce Speed, t h e n add: A1 umi num L243 106 8.59 When u n i f o r m l y mixed, add: E p o d i l 759 SF 69 B S i d e : Ancami ne 2410 B e e t l e 216-8 Ancamide 500 E t h y l A l c o h o l M e t h y l E t h y l Ketone n B u t y l A l c o h o l E t h y l A l c o h o l T y p i c a l P r o p e r t i e s : Non V o l a t i l e by Weight: 0.72 Non V o l a t i l e by Volume: 0.64 PVC: 0.056 CPVC: 0.31 PVC/CPVC: 0.17 Pigment Content: 0.09 NVV on V e h i c l e : 0.7 VOC g / l : 290.53 VOC l b s / g a l : 2.43 86.3 11.64 0.3 0.04 77.67 8.00 22.7 2.60 81.8 10.34 29.1 4.44 73.9 11.01 81.7 12.10 9.8 1.49 Weight/Gallon Comp A : 9.68 W e i g h t / G a l l o n Comp 0: 7.53 M i x i n g R a t i o : 1:l Weight p e r G a l l o n : 8.61 I n i t i a l V i s c o s i t y : 270 CP Pot L i f e : 3 h r Dry t o Touch: 1.5 h r Dry Hard: 4 h r C o r r o s i o n Resi stance : E x h i b i t 4 i s a p r e l im i n a r y s t a r t i n g f o r m u l a t i o n combi n i ng Ancamine 2410 c u r i n g agent w i t h Ancamide 500 c u r i n g agent as t h e B s i d e . C o r r o s i o n r e s i s t a n c e i s v e r y good. C l e v e l a n d h u m i d i t y t e s t i n g showed no a t t a c k a f t e r 700 h o u r s . S a l t s p r a y r e s u l t s on g r i t b l a s t e d s t e e l showed no a t t a c k i n t h e f i e l d and minor a t t a c k a t t h e s c r i b e (8 r a t i n g ) a f t e r 700 h o u r s . SOURCE: A i r P r o d u c t s and Chemicals, I n c . : Ancamine 2410 C u r i n g Agent: E x h i b i t 4
  • 17.
    6 Water-Eased PaintFormulations B l a c k S i n g l e Coat K-Flex-XM-4316 P U - D ~ s p e r s l o nCured w i t h HMMM F o r m u l a t i o n WR-40 i s a h i g h performance h i g h g l o s s b l a c k f o r m u l a t i o n based on K-Flex XM-4316 p o l y e s t e r - u r e t h a n e d i s p e r s i o n c r o s s l i n k e d w i t h an amino r e s i n . The f o r m u l a t i o n o f f e r s a h i g h g l o s s c o a t ing Component: Pigment G r i n d Paste, P a r t 1 : K-F1 ex XM-2311 Water, d e i o n i z e d Dimethylethanolamine ( 1 ) Monarch 1300 K-Sperse 152 MS Dimethylethanolamine ( 2 ) Pigment Paste, P a r t 2 : K-Flex XM-2311 K-F1 ex XM-4316 Water, d e i o n i z e d Pigment Paste K-F1 ex XM-4316 Water d e i o n i zed Resimene 747 Nacure 2547 S i l w e t L7604/L7605 ( 1 : l ) 25% i n H20 Water as r e q u i r e d f o r v i s c o s i t y adjustment F o r m u l a t i o n C h a r a c t e r i s t i c s : Resi n/HMMM, r a t 10 : 75/25 N o n v o l a t i l e , c a l c u l a t e d , 'YO: 39.0 T h e o r e t i c a l VOC, g/L, ( l b / g a l l o n ) : 145, ( 1 .23) B r o o k f i e l d V i s c o s i t y , 25C, s p i n d l e #16, 60 rpm, c p . : Cure Schedule, temperature, t i m e : 150C, 15 m i n u t e s Dry F i l m Thickness, m i l , ( m i c r o n ) : 1 . 0 ( 2 5 ) Gloss, 60, 20, 90: 91, 81 pH: 7 . 8 - 8 . 3 F i l m P r o p e r t i e s : S u b s t r a t e , aluminum % W t 2 . 4 0 2.95 0.15 1 .oo 0.07 0 . 1 0 1.20 1 . 2 0 1 . 1 0 10.17 63.95 6 . 2 0 9 . 5 5 0 . 1 3 0.40 9 . 6 0 300-500 F o r m u l a t i o n Notes: Pigment G r i n d Paste P a r t 1 : B l e n d t h e K-Flex XM-2311 p o l y u r e t h a n e d i s p e r s a n t r e s i n w i t h water and d i m e t h y l e t h a n o l a m i n e ( 1 ) and add t h e carbon b l a c k , premix and add t h e b l e n d o f K-Sperse w i t h d i m e t h y l e t h a n o l a m i n e ( 2 ) , check t h e pH and add more d i m e t h y l e t h a - nolamine i f pH i s below 9.2, d i s p e r s e i n a s t e e l b a l l m i l l t o Hegman NS 8 r a t i n g . Pigment Paste P a r t 2 : A f t e r g r i n d i n g i n t h e s t e e l b a l l m i l l add t h e a d d i t i o n a l K-Flex XM-2311, XM-4316 and w a t e r t o t h e b a l l m i l l , r u n f o r an a d d i t i o n a l 30 m i n u t e s . The pigment c o n c e n t r a t e i s s t a b l e . A f t e r l o n g e r a g i n g a d d i t i o n o f s m a l l amounts o f amine f o r pH adjustment m i g h t be r e q u i r e d . Letdown Formula: L e t t h e pigment p a s t e down under a g i t a t i o n w i t h remainder o f K-Flex XM-4316, w a t e r , melamine c r o s s l i n k e r and c a t a l y s t . Add t h e s i l i c o n e s u r f a c t a n t and use t h e remainder o f t h e w a t e r f o r v i s c o s i t y a d j u s t m e n t s . F i n a l pH o f t h e f o r m u l a - t i o n s h o u l d be between 7.8 t o 8 . 3 . SOURCE: K i n g I n d u s t r i e s : P r e l i m i n a r y F o r m u l a t i o n WR-40
  • 18.
    Coatings and Topcoats7 Clear Bake Coating Materi a1 : E p i -Re2 3522-W-60 Resin ~ _ _ _Pounds Gal 1ons 637.50 69.29 Thoroughly pre-nix t h e f o l l o w i n g and add t o t h e above under g e n t l e a g i t a t i o n . Cyme1 324 B u t y l O x i t o l Glycol Ether 2-Propoxyethanol BYK-301 A n t i - c r a t e r i n g agent Syntex 3981 Accelerator 53.10 5.71 22.50 3.00 40.20 5.00 2.00 0.25 2.75 0.37 Blend thoroughly. Dissolve f o l l o w i n g by warming t o 150F. Add t o above under a g i t a t i o n before a l l o w i n g t o cool. O i cyandi ami de Dei oni zed water Typical Coati ng Properties : % N o n - v o l a t i l e - weight: 48.5 - volume: 43.2 V i s c o s i t y : 57 K.U. pH: 7.0 Pounds/Gallon: 9.05 V o l a t i l e Composition: Water Organics V o l a t i l e Organic Compounds (VOC): Pounds/Gallon: 1.46 Grams/Li t e r : 175 13.50 0.41 133.00 15.97 _ _ _ _ _ _Pounds Gallons 388.0 46.50 62.7 8.00 F i l m Properties:* Bake Schedule: Pencil Hardness Reverse Impact, i n . - l b s . 160 160 160 160 5 min. a t 450F 4H 30 min. a t 400F 5H 15 min. a t 400F 5H 30 min. a t 350F 4H * Films cast #42 Myra Bar (0.75 m f l a s h . SOURCE: She11 Chemical Co. : S t a r t E p i -Rez 3522-W-60 Resin 1 . ) on bonderite 1000; 10 min. ng Formulation No. 2500:
  • 19.
    8 Water-Based PaintFormulations Clear Bake Coatinq Materia1 : Pounds Epi -Rez 3551-WY-43 Resi n 756.0 Add under a g i t a t i o n : Ektapro EEP Beetle 80 Water Typical Coating Properties: Total Weight Solids, %: 47.5 Total Volume Solids, %: 41.8 Pounds/Gallon: 8.96 Epoxy/Urea, based on s o l i d s V o l a t i l e Organic Compounds Pounds/Gal l o n : 1 .85 Grams/Li t e r : 222 V i s c o s i t y , B r o o k f i e l d #5 Sp Dry F i l m Thickness: 1.0 m i l Substrate: Bonderite 1000 Typical F i l m Properties: 21.2 86.8 31.5 %: 80/20 VOC) : ndle, 20 rpm, cps: 1,400 Gal lons 84.00 2.68 9.54 3.78 Bake Schedule a t 350F, minutes: 20 Pencil Hardness: 3H Reverse Impact, i n . l b s . : 80 S t a r t i n g Formulation No. 2501: Epi-Rez 3551-WY-43 Resin Phenolic Clear Bake Coating Pounds GallonsMateri a1 : Water 115.5 13.87 Methylon 75108 162.5 16.75 B u t y l O x i t o l Glycol Ether 48.8 6.50 n-Butyl Alcohol 43.9 6.50 Syntex 3981 Accelerator 58.1 7.90 Typical Coating Properties: ~~ Epi-Rez 3540-WY-55 Resin 442.9 48.48 Premix and add slowly under a g i t a t i o n : Total Weight Solids, %: 46.6 Total Volume Solids, %: 31.0 Pounds/Gallon: 8.72 Epoxy/Phenolic: 60:40 C a t a l y s t , a c t i v e on r e s i n s o l i d s , %: 3.3 V o l a t i l e Organic Compounds (VOC): Pounds/Gallon: 2.68 Grams/Li t e r : 322 V i s c o s i t y , #4 Ford Cup, seconds: 40-60 pH: 6.4 Reduction f o r Conventional Spray A p p l i c a t i o n : None Dry F i l m Thickness: 0 . 4 m i l s Substrate: Bonderite 1000 Bake Schedule: 15 min. a t 450F Pencil Hardness: 9H Reverse Impact, i n . l b s . : >I60 MEK Resistance, double rubs: 100 Typical F i l m Properties: S t a r t i n g Formulation No. 2502: Epi-Rez 3540-WY-55 Resin SOURCE: Shell Chemical Co.: S t a r t i n g Formulations
  • 20.
    Coatingsand Topcoats 9 ClearBake Coating Materi a1 : Epi -Rez 3540-WY-55 Resin Water Premix and add: Beetle Urea Formaldehyde Resin n-Butyl Alcohol Syntex 3981 Accelerator Pounds 579.6 113.7 80.7 43.2 55.9 Gal l o n s 63.42 13.65 8.92 6.40 7.61 Typical Coating Properties: Total Weight Solids, %: 45.7 Total Volume Solids, %: 42.6 Pounds/Gallon: 8.73 Epoxy/Urea: 80/20 C a t a l y s t , % ( A c t i v e on r e s i n s o l i d s ) : 2 V o l a t i l e Organic Compounds (VOC): Pounds/Gal 1on: 2.19 Grams/Liter: 263 V i s c o s i t y , #4 Ford Cup, seconds: 60-80 pH: 7.1 S t a r t i n g Formulation No. 2506: Epi-Rez 3540-WY-55 Resin Phenolic Clear Bake Coating Materia1 : Part A: Epi -Rez 3551-WY-43 Resin Premix and add under a g i t a t i o n : Santol ink EP560 Ektapro EEP Add under a g i t a t i o n : Water _ _ _ _ _ _Pounds Gal 1ons 662.1 73.56 93.1 10.18 80.6 10.16 5 0 . 8 6.10 Typical Coati ng P r o p e r t i es : Total Weight Solids, %: 42.0 Total Volume Solids, %: 36.6 Pounds/Gallon: 8.87 Epoxy/Phenolic, based on s o l i d s , percent: 80/20 V o l a t i l e Organic Compounds (VOC): Pounds/Gal 1on: 2.90 Grams/Liter: 348 Viscosity, #4 Ford Cup, seconds: 70-80 Dry F i l m Thickness: 0 . 5 m i l Substrate: Bonderite 1000 Bake Schedule a t 350F. minutes: 20 Pencil Hardness: 5H Reverse Impact, i n . l b s . : s160 MEK Resistance, Double Rubs: 100 Typi c a l F i 1m Properties : S t a r t i n g Formulation No. 2505: €pi-Rez 3551-WY-43 Resin SOURCE: S h e l l Chemical Co. : S t a r t i n g Formulations
  • 21.
    10 Water-Based PaintFormulations C l e a r Wood CoatinQ-A & B 8 C _-K-F1 ex UD-320W Modi f ie d The f o l l o w i n g wood c o a t i n g f o r m u l a t i o n e v a l u a t e s K-Flex UD-320W a t 5 and 10% m o d i f i c a t i o n on s o l i d s . The system was c a t a l y z e d w i t h K-Cure 129W. Cure response was examined on c l e a n b a r e and 840 t r e a t e d Aluminum a t a r a p i d schedule o f 60 sec./82C. Hardness improvements were found a t a l l l e v e l s o f m o d i f i c a t i o n (See f i l m p r o p e r t i e s ) . The t r e a t e d s u b s t r a t e gave s o f t e r f i l m s i n i t i a l l y compared t o b a r e m e t a l , but improved p r o p e r t i e s were observed a f t e r 24 h o u r s a g i n g . K-Flex UD-320W m o d i f i c a t i o n i n c r e a s e d f i l m hardness b u t d i d n o t improve w a t e r r e s i s t a n c e p r o p e r t i e s Formul a t i on : Rhoplex AC-1024 B e e t l e 65 K-Flex UD-320W K-Cure 129W A c r y l i c / P o l y o l / U r e a % S o l i d s F i l m P r o p e r t i e s : FC-430 S u b s t r a t e : Aluminum (Clean Bare) Cure: 60 sec./82C F i l m Thickness: 0 . 7 + - 0 . 1 m i l DFT W* 66.7 33.3 0 . 0 0 . 1 3 1 . 7 SO/-/50 6 6 . 7 A : 50,’-/50 I n i t i a l 24 Hours 0 : 45/5/50 I n i t i a l 24 Hours C : 35/10/55 I n i t i a l 24 Hours Penci 1 KHN25 HB-F 4.19 F-H 11.20 HB-F 6 . 2 5 H-2H 14.20 HB-F 5.41 H-2H 15.50 W- Wt%C 61 .8 51.4 34.3 40.4 3 . 9 8 . 2 0 . 1 3 0.13 1 . 7 1.8 45/5/50 35/10/55 6 7 . 5 72.2 Crosshatch Adhesion MEK Rubs (%Loss) 200 0 200 0 200 0 200 0 180 0 200 0 SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n UDW-10 A & B & C
  • 22.
    Coatings and Topcoats11 I n g r e d i e n t s : Resin Phase: Water Maincote PR-71 Ammonia (28) D i r e c t t o Metal A c r y l i c Latex Coating S t a r t i n a P o i n t Formulation Lbs Gals 45.9 5.510204 2.05 0.273333 481.2 55.31034 Set aside f o r l a t e r a d d i t i o n , i n t o a separate vessel add: Water Phase: Water Bentone AD Tamol 165 Drewpl us L-493 B u t y l Cel l o s o l v e D i b u t y l Phthalate Ammonia (28) Premix: Chrom. Grn. Oxide 5-5310 A c t i r o x 215 Nyad 1250 Disperse t o 5 n.s.u. Then homogenization, add, whi E t h y l Alcohol 15% NaN02 i n Water 20% QR-708 i n Water 150 1.4 11.2 1 36.6 7.3 n 47.9 89.8 116.3 l e t down w i t h r e s i n phase e mixing, t h e f o l l o w i n g : 18 3.06 12.75 18.00720 0.064641 1.222707 0.133155 4 .a73501 0.8371 55 0.4 1.078828 3.368847 4.805785 4 f t e r 2.748091 0.337375 1 .514251 General Performance Benef t s : E x c e l l e n t adhesion t o s t e e l , galvanized s t e e l and aluminum S u i t a b l e f o r s i n g l e coat s e r v i c e Excel 1ent recoatabi 1it y w i t h s o l v e n t based f i n i s h e s High r e s i s t a n c e t o s a l t spray, 3000 hours from 2 d r y m i l s on Appl icab1e under margi nal c o n d i t i o n s (40F) c o l d r o l l e d s t e e l SOURCE: Nyco Minerals, I n c . : Suggested Formulation
  • 23.
    12 Water-Based PaintFormulations Low Gloss Vinvl/ABS Topcoat Materi a1 Spensol L53 D i sperse-Ayd Surfynol 104H Fl a t t ing Agent TS100 Lodyne S107B Lbs. Gals . 808.7 92.85 6.6 0.75 6.0 0.75 25.0 1.so 1.4 0.15 Disperse a t high speed f o r 15-20 minutes, then premix and add: M i cheml ube 737 Water Anal y s i s: Percent Sol i d s , Weight : 31 .8 Percent Solids, Volume: 28.4 V i s c o s i t y @ 25C, #2 Zahn, Secs.: 20-25 Gloss (60/20): 7/4 VOC (excluding water): Grams/Li t e r : 288 Pounds/Gal 1on : 2.4 pH: 8.0-8.5 Formulation 2124-54C 16.4 2.0 16.7 2.0 Clear Topcoat for F l e x i b l e Substrates Materia1 : Spensol L53 Surfynol 104H C o l l o i d 679 Ucar SCT 100 M i cheml ube 737 Water Lbs. Gals. 826.5 95.00 4 . 0 0.50 1.9 0.25 2.3 0.25 16.4 2.00 16.7 2.00 Add t h e above m a t e r i a l s i n order under good a g i t a t i o n . NOTE: An o p t i o n a l a z i r i d i n e c r o s s l i n k i n g agent can be added t o t h e above formula a t a l e v e l o f 7-10 lbs./100 gallons. Analysis: Percent Sol ids, Wei ght : 29.8 Percent Solids, Volume: 28.6 V i s c o s i t y @ 25C, #4 Ford, Secs.: 65+-5 Pounds/Gallon: 8.7 VOC (excluding water): Grams/Liter: 374 Pounds/Gallon: 3.1 PH: 8.5t-0.3 Formulation 2307-248 SOURCE: Reichhold Chemicals, I n c . : Spensol L: Formulations
  • 24.
    Coatings and Topcoats13 S t r i p p a b l e C o a t i n g Sample F o r m u l a t i o n A _____Unmodi f ied In n r e d i e n t s : Ucar Latex 447 Ucar F i l m e r IBT Foamaster VF Water C o a t i n g P r o p e r t i e s : AMP-95 V i s c o s i t y , cP: 1060 Stormer V i s c o s i t y , KU: 70 pH Value: 6.6 T o t a l S o l i d s , % by w e i g h t : 59.3 Pounds 797.3 2 . 1 47.5 2.1 40.9 S t r i p p a b l e C o a t i n q Sample F o r m u l a t i o n B -Lower- Adhesion I n q r e d i e n t s : Ucar Latex 447 AMP-95 Ucar F i l m e r IBT Foamaster VF Soya L e c i t h i n Water C o a t i n g P r o p e r t i e s : V i s c o s i t y , cP: 1820 Stormer V i s c o s i t y , KU: 83 pH Value: 6 . 7 T o t a l S o l i d s , % by w e i g h t : 60.3 S u b s t r a t e S t r i p p a b i 1i t y : S u b s t r a t e : Galvanized S t e e l A1 -Bonderi t e A1-A1 o d i ne Cold R o l l e d S t e e l My1a r G1ass P o l y s t y r e n e Gloss A1 kyd P o l y e s t e r X=peeled c l e a n and easi l y _ _ ~Pounds 777.0 2 . 1 46.7 2.1 20.0 41.1 G a l l o n s 88.54 0.27 6.01 0.27 4.91 G a l l o n s 86.33 0.27 5.91 0.27 2.29 4.93 Formula A X X X X X X X X X Formula B X X X X X X X X X SOURCE: Ucar Emulsion Systems: Ucar Latex 447: F o r m u l a t i o n s A & B
  • 25.
    14 Water-Based PaintFormulations S t r i p p a b l e Coatina Formulations Thickened w i t h Ucar Polyphobe Rheology M o d i f i e r s Formula C Good Leveling Pounds Gal lonsI n g r e d i e n t s : Ucar Latex 447 780.9 06.77 AMP-95 4.4 0.57 Ucar Filmer IBT 46.8 5.95 Foamaster VF 2.1 0.28 Water 40.6 4.89 Ucar Polyphobe 107 13.4 1.54 ~~ Coating Properties: V i s c o s i t y , cP: 2500 Stormer V i s c o s i t y , KU: 104 pH Value: 8.1 Total Solids, % by weight: 60.1 Formula D High B u i l d I n g r e d i e n t s : Ucar Latex 447 Ucar Filmer IBT Foamaster VF Water Ucar Polyphobe 102 Coating Properties: AMP-95 V i s c o s i t y , cP: 3200 Stormer Viscosity, KU: 84 pH Value: 8.9 Total Solids, % by weight: 58.8 Substrate S t r i p p a b i 1it y : Substrate: Galvanized Steel A1-Bonderi t e A1-Alodi ne Cold Rolled Steel Mylar G1ass Polystyrene Gloss Alkyd Polyester X=peeled clean and e a s i l y NT=not ~~Pounds Gal 1ons 702.7 06.97 4.8 0.62 46.9 5.94 2.1 0.27 40.6 4.07 11.6 1.33 Formula C Formula D X X X X NT NT X X X X X X NT NT X X NT NT t e s t e d SOURCE: Ucar Emulsion Systems: Ucar Latex 447: Formulations
  • 26.
    Coatingsand Topcoats 15 St r i p p a b l e C o a t i n q f o r P l a s t i c S u b s t r a t e s I n q r e d i e n t s : Premix #1 : Ucar V e h i c l e 441 Defoamer (1 ) Soya L e c i t h i n (2) Premix #2: T r i o c t y l Phosphate S t r i p p i n g A i d (3) Water Premix #3: T h i c k e n e r (4) Water Premix #4: T r i e t h y l a m i n e I s o p r o p a n o l , 91% Water Water Pounds 603.8 9.1 10.1 40.2 13.9 39.2 27.1 27.2 7.2 8.6 14.3 48.3 Gal l o n s Wt% 69.80 71.12 1 .31 1.07 1.16 1.19 5.22 4.74 1.47 1.64 4.71 4.62 3.10 3.19 3.26 3.20 1.18 0.85 1.27 1.01 1.72 1 .68 5.80 5.69 i e r s : ) Defoamer - P a t c o t e 513 ( P a t t e r s o n Chemical) o r e q u i v a l e n t . ) Soya L e c i t h i n - K e l e c i n 1081 (Spencer K e l l o g g ) o r e q u i v - a1e n t . e q u i v a l e n t . (3) S t r i p p i n g A i d - Strodex PK-90 ( D e x t e r Chemicals) o r (4) T h i c k e n e r - A c r y s o l ASE-60 (Rohm and Haas) o r e q u i v a l e n t . Procedure: Blend Premix #1 f i r s t , i n t h e o r d e r shown, and t h e n add t h e r e m a i n i n g Premixes i n numerical o r d e r . A l l o w f i v e t o 10 minutes o f a g i t a t i o n between a d d i t i o n s o f Premixes. The l a s t increment o f w a t e r , shown below Premix #4, can b e added i n stages t o a l l o w p r o p e r a g i t a t i o n . C o a t i n g P r o p e r t i e s : T o t a l S o l i d s , % by w t : 40.1 pH: 8.6 V i s c o s i t y , B r o o k f i e l d , cP: 2410 V i s c o s i t y , Stormer, KU: 84 Heat-Age S t a b i l i t y , 2 wk a t 12OF: Pass Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass SOURCE: Ucar Emulsion Systems: Ucar V e h i c l e 441: F o r m u l a t i o n Suggestion LP-1924
  • 27.
    16 Water-Based PaintFormulations S t r i p p a b l e C o a t i nq F o r m u l a t i o n s Inqr e dient-s : Ucar V e h i c l e 441 Thickener ( 1 ) (11% N . V ) B u t y l C a r b i t o 1 Sol v e n t Water C o a t i n g P r o p e r t i e s : Weight p e r G a l l o n , l b : 8 . 6 p H 8 . 0 T o t a l S o l i d s , % by w t : 43.8 Formul a t ion LP-3760 I n g r e d i entg: Ucar V e h i c l e 441 Thickener ( 1 ) (11% N.V.) B u t y l Carbi t o 1 S o l v e n t Soya L e c i t h i n W e t t i n g Agent ( 2 ) Water C o a t i n g P r o p e r t i e s : Weight p e r G a l l o n , l b : 8.6 p H : 8 . 0 T o t a l S o l i d s , % by w t : 44.4 F o r m u l a t i o n LP-3761 I n g r e d i e n t s : i c a r V e h i c l e 441 Thickener ( 1 ) (11% N.V.) B u t y l C a r b i t o l S o l v e n t Soya L e c i t h i n W e t t i n g Agent ( 2 ) Water C o a t i n g P r o p e r t i e s : Weight p e r G a l l o n , l b : 8 . 6 pH: 8 . 0 T o t a l S o l i d s , % by w t : 44.6 F o r m u l a t i o n LP-3762 I n g r e d i e n t s : Ucar V e h i c l e 441 Thickener ( 1 ) (11% N.V.) B u t y l C a r b i t o 1 S o l v e n t Soya L e c i t h i n W e t t i n g Agent ( 2 ) Water C o a t i n g P r o p e r t i e s : Weight p e r G a l l o n , l b : 8.6 pH: 8 . 0 T o t a l S o l i d s , % by w t : 45.0 F o r m u l a t i o n LP-3763 ~-Pounds 840.0 5 . 4 8 . 4 10.0 -~Gal 1ons 9 7 . 1 0.7 1 . o 1 . 2 Pounds Gal 1ons 830.0 9 5 . 9 5.4 0 . 7 8 . 4 1 . o 6 . 6 0 . 8 3.3 0 . 4 10.0 1 . 2 Pounds G a l l o n s 827.0 9 5 . 6 5.4 0 . 7 8 . 4 1 . o 10.0 1 . I 3 . 3 0 . 4 1 0 . 0 I . 2 Pounds Gal 1ons 820.0 94.8 5 . 2 0 . 6 8 . 2 1 .o 16.4 1 . 9 3.3 0 . 4 1 0 . 7 1 . 3 Suppl ie r s : ( 1 ) Thickener - A c r y s o l G-110 (Rohm and Haas) o r e q u i v a l e n t . ( 2 ) W e t t i n g Agent - I n t e r w e t #33 ( I n t e r s t a b ) o r e q u i v a l e n t . Note: I n c l u d e a s u i t a b l e p r e s e r v a t i v e i n each f o r m u l a s u g g e s t i o n . SOURCE: Ucar Emulsion Systems: Ucar V e h i c l e 441: F o r m u l a t i o n s
  • 28.
    Coatingsand Topcoats 17 Topcoatf o r Prefin ished Hardboard S i d i n g Inqredients: PiQment Or4 nd: Water T e r g i t o l Nonionic Surfactant Tamol 731 Foamaster VF T i -Pure R-960 Nytal 400 S i l c r o n G-601 Nuocide 960 Letdown : Ucar Vehicle 462 Cyme1 325 Arcosol ve PP Sol vent Cycat 4040 Foamaster VF CAO-1 Anti-Oxidant Tinuvin 328 UV Absorber NP-10 Pounds 134.8 4.7 9.3 1.o 174.4 46.5 46.5 4.5 Gal lons 16.2 0.6 1 .o 0.2 5.2 2.7 2.0 0.6 535.4 60.8 45.2 4.4 36.1 4.9 2.8 0.3 1.1 0.1 3.0 0.3 6.5 0.7 Paint Properties: Pigment Volume Concentration, %: 28 Crosslinker, phr: 15 Cosolvent, phr: 15 Volume Solids, %: 41 Weight per Gallon, l b : 10.6 SOURCE: Ucar Emulsion Systems: Ucar Vehicle 462: Formulation Suggestion
  • 29.
    18 Water-Based PaintFormulations Water-Borne A1 kvd/Mel ami ne Kood C l e a r c o a t M o d i f i c a t i o n K-Flex XM-2304 i s an e x p e r i m e n t a l p r i m a r y h y d r o x y l c o n t a i n i n g a l i p h a t i c , s a t u r a t e d u r e t h a n e r e s i n m o d i f i e r . T h i s water-borne alkyd/melamine wood c l e a r c o a t f o r m u l a t i o n demonstrates improved s t a i n r e s i s t a n c e and f l o w / l e v e l i n g u s i n g t h i s p r o d u c t . %K-Flex XM-2304 Component: 0% 5% 10% C a r g i l l 7412 Resimene 747 I s o p r o p a n o l Water K-Flex XM-2304 Nacure 155 K-F1 ex XM-2304: % S o l i d s ( C a l c u l a t e d ) W e t t i n g Alkyd/XM-Z304/HMMM 31 . 5 2 8 . 3 25.1 31 . 5 31.5 31.5 14.8 1 4 . 8 14.8 1 5 . 7 15.6 1 5 . 6 0 . 0 3 . 5 6 . 5 6 . 5 6.5 6 . 5 0% 5% 10% 66.6 6 6 . 5 66.4 5 0 / 0 / 5 0 45/5/50 40/10/50 Poor Good Best S u b s t r a t e : Sanded and Sealed B i r c h Faced Plywood S e a l e r : Commerci a1 V i n y l Sander/Sealer Topcoat, WFT: 20-25u ( 0 . 8 - 1 . 0 m i l ) Topcoat Bake: 10 min./71C (160F) 4 Hour Spot T e s t S t a i n Test Mustard Ketchup C o f f e e Homog. M i l k Lemon J u i c e L i q u i d C1eaner N a i l P o l i s h Remover 0% XM-2304 M i l d A t t a c k S t a i n Severe S t a i n Severe A t t a c k M i l d A t t a c k Severe A t t a c k Severe Atack 5% XM-2304 10% XM-2304 M i l d A t t a c k No E f f e c t No E f f e c t No E f f e c t M i l d S t a i n M i l d S t a i n M i l d A t t a c k M i l d A t t a c k M i l d A t t a c k No E f f e c t Severe A t t a c k / M i l d A t t a c k No E f f e c t No E f f e c t W h i l e a l l 3 f o r m u l a s were u n a f f e c t e d i n t h e 4 hour s p o t t e s t by b l e a c h and m i n e r a l o i l , t h e y a l l e x h i b i t e d a m i l d a t t a c k by Peps1 Cola; s t a i n i n g f r o m water; and a severe a t t a c k f r o m i s o p r o p a n o l . W i t h t h e above c u r e c o n d i t i o n a l l t h r e e f o r m u l a s gave an H-2H p e n c i l hardness and 100+ MEK d o u b l e r u b s a t 23 u ( 0 . 9 m i 1) on A1umi num. SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n WR-24
  • 30.
    Coatings and Topcoats19 Water-Borne Alkyd/Melamine Wood Clearcoat Modification K-Flex UD-320W i s an a l i p h a t i c , s a t u r a t e d , water s o l u b l e r e s i n m o d i f i e r . T h i s u r e t h a n e d i o l m o d i f y i n g r e s i n i m p a r t s s t a i n r e s i s t a n c e t o t h e f o r c e d d r y ( t h e r m o s e t ) alkyd/melamine wood c l e a r c o a t f o r m u l a t i o n below. What makes t h i s f o r m u l a t i o n unique i s t h e absence o f n e u t r a l - i z i n g amines. As a r e s u l t , a f r e e a c i d c a t a l y s t may be used (Nacure 155) and lower t e m p e r a t u r e c u r e s may be achieved. The b i n d e r r e s i n ( a l k y d ) i s water d i l u t a b l e w i t h t h e a d d i t i o n o f a c o s o l v e n t such as i s o p r o p a n o l . A p o t l i f e o f 8-10 hours i s p o s s i b l e . WB Wood C 1e a r c o a t -Modi f ic a t i o n Component: C a r g i l l 7412 Resimene 747 I s o p r o p a n o l Water K-F1 ex UD-320W Nacure 155 K-Flex UD-320W: % Sol i d s ( C a l c u l a t e d ) A1 kyd/K-F1 ex UD-32OW/HMMM % K-Flex UD-320W 0% 5% 10% 31 . 5 28.3 25.1 31 . 5 31.5 3 1 . 5 14.8 14.8 14.8 15.7 15.4 15.0 0 . 0 3 . 5 7 . 1 6.5 6.5 6 . 5 0% 5% 10% 6 6 . 6 66.5 66.4 50/0/50 45/5/50 40/10/50 S u b s t r a t e : Sanded and Sealed B i r c h Faced Plywood S e a l e r : Commerci a1 V i n y l Sander/Seal e r Topcoat, WFT: 20-25u ( 0 . 8 - 1 . 0 m i l ) Topcoat, Bake: 10 min./71C (160F) S t a i n T e s t Mustard Ketchup C o f f e e Homog. M i l k Lemon J u i c e Pepsi Cola N a i l P o l i s h Remover 4 Hour Spot Test 0% UD-320W 5% UD-320W M i l d A t t a c k M i l d A t t a c k Severe S t a i n Severe S t a i n S t a i n No E f f e c t Severe A t t a c k No E f f e c t M i l d A t t a c k Severe A t t a c k M i l d A t t a c k M i l d A t t a c k Severe A t t a c k No E f f e c t 10% UD-320W No E f f e c t No E f f e c t M i l d S t a i n No E f f e c t Severe A t t a c k No E f f e c t No E f f e c t W h i l e a l l 3 f o r m u l a s were u n a f f e c t e d i n t h e 4 hour s p o t t e s t by b l e a c h and m i n e r a l o i l , t h e y a l l e x h i b i t e d s t a i n i n g from water and a severe a t t a c k f r o m i s o p r o p a n o l and l i q u i d c l e a n e r W i t h t h e above c u r e c o n d i t i o n a l l t h r e e f o r m u l a s gave an H-2H p e n c i l hardness and 100+ MEK double r u b s a t 23u ( 0 . 9 m i l ) on A1umi num. SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n WR-25
  • 31.
    20 Water-Based PaintFormulations Waterborne Clear Hiqh Gloss Topcoat Edaplan LA-402 was used i n a Waterborne High Gloss Wood Topcoat t o improve w e t t i n g and l e v e l i n g . I n combination w i t h Agitan 315 foam c o n t r o l agent, superior f i l m p r o p e r t i e s are ach ieved . Materi a1 : & Rhoplex E-3188 (Rohm & Haas) 608.00 71 .77 Water 101.33 11.96 Adjust pH t o 8.5-9.0 Ammonia (28%) 5.27 0.62 Premix and add slowly: Water Dowanol PnB (DOW Chemical) Arcosolve DPM (Arco Chemical) Arcosolve DPt8 (Arco Chemical) Tributoxyethyl phosphate Add f o l l o w i n g w h i l e mixing: FCA (Foam Control Agent) Wetting Agent Michem 392-25 (Michelman) Adjust v i scosit y Acrysol RM-825 (Rohm & Haas) Water Properties: % N o n v o l a t i l e (by weight): 31.2 % N o n v o l a t i l e (by volume): 29.4 Weight per Gallon (pounds): 8.48 Theoretical VOC ( g r a m s / l i t e r ) : 106 V i s c o s i t y (cPs): 150+-10% 14.79 1.75 14.79 1.75 14.79 1.75 9.93 1.17 9.93 1.17 0.49 0.06 2.47 0.29 14.11 1.67 0.51 0.06 50.67 5.98 SOURCE: King I n d u s t r i e s : WR-31: A d d i t i v e s f o r Waterborne Wood Formulations
  • 32.
    Coatings and Topcoats21 White Gloss Maintenance Topcoat I n q r e d i e n t s : Pigment G r i nd: Methyl C a r b i t o l Solvent Water Bentone LT Ammonium Hydroxide, 28% Aqueous S o l u t i o n Tamol 681 T r i t o n Nonionic S u r f a c t a n t CF-10 Nuosept 95 DeeFo HG-12 Acrysol RM-2020 Acrysol SCT-275 Tronox CR-828 Letdown : Methyl C a r b i t o l Solvent )Premix Acrysol SCT-275 1 Ucar Vehicle 435 Ucar F i l m e r IBT Troysan Polyphase AF-1 DeeFo HG-12 Sodium N i t r i t e , 15% Aqueous S o l u t i o n Ammonium Hydroxide, 28% Aqueous S o l u t i o n Adjust t o minimum pH 8.7 Pounds 59.6 18.4 1.o 1.8 18.2 2.2 2.3 1.9 17.2 8.6 225.0 8.5 8 . 6 626.9 15.8 4.9 1.9 9.0 1.8 Pai n t P r o p e r t i es : Pigment Volume Concentration (PVC), %: 18.3 T o t a l Solids, %: pH Value, i n i t i a l : 8.7 V i s c o s i t y : Stormer, KU: 78 I C I , poise: 1.1 by volume: 36.1 Weight per Gallon, l b : 10.3 Freeze-Thaw S t a b i l i t y , 3 cycles: Pass Heat S t a b i l i t y , 2 weeks a t 140F: Pass F i l m Properties: Contrast Ratio, 6-mil wet drawdown: 0.958 Gloss, 60: 70 Gloss, 20: 25 Gal 1ons 7.00 2.21 0.06 0.25 2.00 0.25 0.25 0.25 2.00 1 .oo 6.59 1.oo 1.oo 72.06 2.00 0.50 0.25 1.08 0.25 SOURCE: Ucar Emulsion Systems: Ucar Vehicle 435: Formulation Suggestion M-2453
  • 33.
    22 Water-Based PaintFormulations White Gloss Topcoat ____M a t e r i a1 : A r o l o n 580-W-42 Tamol SG-1 T r i t o n CF-10 C o l l o i d 694 E t h y l e n e G l y c o l B u t y l Carbi t o 1 D o w i c i l 75 Water Mix a t low speed: T i t a n o x 2101 G r i n d under h i g h shear 15-20 m i n u t e s . Under low shear, add letdown. Water Col l o i d 694 A r o l o n 820-W-49 Propylene G l y c o l B u t y l Carbi t o 1 A c e t a t e C o b a l t Hydrocure I1 Hydroxyethyl C e l l u l o s e QP-300 (10% S o l n ) Ammonia *lo% QP-300 i n E t h y l e n e G l y c o l A n a l y s i s : Pigment Volume Concentration, Percent: 20.0 Pigment/Binder R a t i o : 0.94/1 Percent S o l i d s , Weight: 57.4 Percent S o l i d s , Volume: 44.0 V i s c o s i t y @ 25C, KU: 72-76 Pounds/Gallon: 11.08 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 144 Pounds/Gallon: 1.2 pH: 8.8-9.0 Lbs. Gals. 65.0 7.30 5.0 0.52 3.0 0.34 2.5 0.35 23.0 2.48 10.0 1.26 1 .o 0.08 18.0 2.16 300.0 8.57 20.0 2.40 2.5 0.35 598.0 67.95 18.0 2.08 8 . 0 0.98 0 . 4 0.05 5.0 0.53 1 .o 0.13 SOURCE: R e i c h h o l d Chrmicals, I n c . : A r o l o n 820: Formula 194-2
  • 34.
    Coatings and Topcoats23 Wood Topcoat Model Formulations Rohm and Haas: Wt% Rhoplex WL-96 (42%) 73.9 Patcote 519 0 . 2 B u t y l Carbi t o 1 ) 6.2 Dowanol PNB ) Premix 3.1 Michem Lube 110 (25% S o l i d s ) 2.9 Ammonia (14%) Adjust t o pH 8.0 0.1 Water 13.6 S.C. Johnson: Wt% Joncryl 554 90.9 Ektasolve EB 3.6 Jonwax 26 4.5 Water 1.o Goodyear : Wt% Ektasolve EP 8 . 5 S a n t i c i z e r 160 2.7 D i e t h y l ami ne 1.1 Drew L-475 0.2 Water 9 . 1 P l i o l i t e 7104 (44%) 58.5 W i tcobond 234 19.9 Sanncor : Wt% Water 16.1 Dowanol DPM 4.9 Rhoplex WL-96 (42%) 35.3 Sancure 815 42.3 Dehydran 1293 0.5 BYK 306 0.5 Acrysol RM-825 0.3 Ammonia ( 14%) Approx. 0.1 Evaluation i n Clear Topcoats: Surfynol 104 s u r f a c t a n t was evaluated i n waterborne c l e a r topcoats t o c o n f i r m i t s m u l t i p l e b e n e f i t s i n actual wood c o a t i n g formulas. Since t h e most s t r i n g e n t performance require- ments are r e l a t e d t o high-end wood coatings. Model topcoat formulations o f t h i s type were selected f o r study. Surfynol 104 s u r f a c t a n t was added a t 1% t o t h e model topcoat formulations. I n order t o evaluate a p p l i c a t i o n and f i l m property b e n e f i t s , Surfynol 104 s u r f a c t a n t ' s b e n e f i t s include: *Improved f 1ow and 1eve1 ing *Superior substrate w e t t i n g *Low foam, and o f t e n defoaming performance *Rapid d i spl acement o f a i r bubbles *Mi n imal r e s o l ubi 1izat ion in water SOURCE: A i r Products 8 Chemicals, I n c . : Surfynol Surfactants: Suggested Formulations
  • 35.
    Coil Coatings 25 ChromateCoi 1-Coati na Primer I n g r e d i e n t s : Pigment Grind: Deio n i zed Water Ethylene G1ycol N,N-Dimethylethanolamine Foamaster VF T e r g i t o l Nonionic S u r f a c t a n t NP-10 Polywet ND-2 L-203-D Strontium Chromate 233 Basic Zinc Chromate T i -Pure R-900 Letdown : N, N-Di methyl ethanol ami ne Ucar Vehicle 462 Carbi t o 1 Solvent Arcosolve PP Solvent Cyme1 303 Foamaster VF Deionized Water ~ _ _ _Pounds Gallons 46.0 5.54 3.8 0.41 0.6 0.09 0.3 0.03 3.8 0.45 15.3 1.63 25.6 0.83 25.6 0.81 204.5 5.96 5.9 0.79 629.5 71.85 16.1 1.88 16.1 2.15 35.5 3.55 1.8 0.22 31.7 3.81 Wei sht% 4.33 0.35 0.06 0.03 0.35 1.44 2.41 2.41 19.25 0.56 59.26 1.52 1.52 3.42 0.17 2.92 Procedure: order l i s t e d . Thoroughly mix l i q u i d components b e f o r e adding pigments. Add pigments s l o w l y and s t i r u n t i l uniform. Grind a t h i g h speed f o r 10 minutes o r u n t i l g r i n d reaches about 50C. For t h e letdown, add t h e i n g r e d i e n t s i n t h e order shown, making sure t h e mix i s uniform a f t e r each a d d i t i o n . For a l e s s c r i t i c a l procedure, premix f i l m i n g a i d s w i t h c r o s s l i n k e r and water. Mix p a i n t a t l e a s t 10 minutes a f t e r t h e f i n a l a d d i t i o n . P a i n t P r o p e r t i 8s: Charge t h e f i r s t s i x g r i n d components t o a Cowles mixer i n Pigment:Binder Ratio: 0 . 8 : l .O T o t a l N o n v o l a t i l e s , % by weight: 54.3 Resin:Me1ami ne: 89; 11 Organic i n E f f l u e n t , % by volume: 10 V i s c o s i t y , B r o o k f i e l d , cP: 300 pH Value: 9 SOURCE: Ucar Emulsion Systems: Ucar Veh Suggestion LP-3821 9 c l e 462: Formulation
  • 36.
    26 Water-Based PaintFormulations Low-Sheen Coil-Coatinq Topcoat I n q r e d ie n t s : Pigment G r i nd: Ethylene Glycol Polywet ND-2 T e r g i t o l Nonionic S u r f a c t a n t NP-10 Foamaster VF N, N-Di methyl ethanol ami ne Dei o n i zed Water S i l c r o n G-601 T i -Pure R-960 o r Zopaque RCL-6 Letdown : Foamaster VF Deionized Water N,N-Dimethylethanolamine Ucar V e h i c l e 462 Pigment G r i nd Arcosolve PP Solvent Cyme1 303 Procedure: _ _ _ ~Pounds Gallons 2.42 0.26 9.69 1.03 2.39 0.27 1.17 0.15 0.30 0.04 95.87 11.53 48.46 2.77 193.80 5.82 2.11 0.27 22.10 2.65 3.26 0.44 585.18 66.80 354.10 21.87 30.20 4.02 39.50 3.95 Weight% 0.23 0.93 0.23 0.11 0.03 9.25 4.68 18.70 0.20 2.13 0.32 56.47 34.16 2.91 3.81 Charge t h e f i r s t s i x g r i n d components t o a Cowles mixer tank i n t h e order l i s t e d . Mix a t low speed f o r 5 minutes. Slowly add t h e pigments and s t i r u n t i l uniform. Grind a t h i g h speed f o r 10 minutes o r u n t i l g r i n d reaches 50C. blend i n t o Ucar Vehicle 462 w i t h slow a g i t a t i o n . Reduce t h e pigment g r i n d w i t h t h e n e u t r a l i z e d l a t e x and s t i r a t low speed f o r 10 minutes. Add t h e melamine r e s i n and s o l v e n t . S t i r a t moderate speed f o r 10 minutes. P a i n t P r o p e r t i e s : For t h e letdown, combine t h e antifoam, water, and t h e amine; Pigment:Binder R a t i o : 0 . 8 : l .O Pigment Volume Concentration, %: 19.7 T o t a l N o n v o l a t i l e s , % by weight: 53.6 Organic i n E f f l u e n t , % by volume: 10.5 Resi n:Mel ami ne: 87: 13 SOURCE: Ucar Emulsion Systems: Ucar V e h i c l e 462: Formulation Suggestion LP-3794
  • 37.
    Coil Coatings 27 Medium-GlossCoil-Coating Topcoat I n g r e d i e n t s : Pigment Grind: Ethylene Glycol T e r g i t o l Nonionic S u r f a c t a n t NP- Foamaster VF Polywet ND-2 N,N-Dimethylethanolamine Deionized Water Ti-Pure R-960 o r Zopaque RCL-6 Letdown : Foamaster VF Deionized Water N,N-Dimethylethanol ami ne Ucar Vehicle 462 Pigment G r i nd Arcosolve PP Solvent Cyme1 303 Deionized Water Pounds 2.48 10 2.53 0.47 10.06 0.35 52.89 253.28 4.29 4.61 2.97 630.31 322.06 31.57 35.22 26.02 Gal 1ons 0.27 0.29 0.06 1.07 0.05 6.36 7.61 Wei qht% 0.23 0.24 0.04 0.95 0.03 5.00 23.96 0.55 0.41 0.55 0.44 0.40 0.28 71.96 59.64 15.69 30.45 4.20 2.99 3.52 3.33 3.13 2.46 Procedure: Charge t h e f i r s t s i x g r i n d components t o a Cowles mixer tank i n t h e order l i s t e d . Mix a t low speed f o r 5 minutes. Slowly add t h e t i t a n i u m d i o x i d e and s t i r u n t i l uniform. Grind a t h i g h speed f o r 10 minutes o r u n t i l g r i n d reaches 50C. For t h e letdown, combine t h e f i r s t increment o f water, t h e antifoam, and t h e amine; blend i n t o t h e Ucar Vehicle 462 w i t h slow a g i t a t i o n . Reduce t h e pigment g r i n d w i t h t h e n e u t r a l i z e d l a t e x and s t i r a t low speed f o r 10 minutes. Add t h e remaining water, melamine r e s i n , and s o l v e n t . S t i r a t moderate speed f o r 10 minutes. P a i n t P r o p e r t i e s : Pigment:Binder R a t i o : 0.8:l .O Pigment Volume Concentration (PVC): 18.9 T o t a l Nonvolatiles, % by weight: 53.1 Organic i n E f f l u e n t , % by volume: 10.5 Resin:Melami ne: 89: 11 pH Value: 9 SOURCE: Ucar Emulsion Systems: Ucar Vehicle 462: Formulation Suggestion LP-3793
  • 38.
    28 Water-Based PaintFormulations I n g r e d i e n t s : Pigment G r i nd: D i spersant (1 ) Soya L e c i t h i n (2) Ethylene Glycol Water Defoamer (3) Calcium Carbonate (4) Titanium D i o x i d e (5) Let Down: Ucar V e h i c l e 441 Dispersant ( 1 ) Soya L e c i t h i n Defoamer (3) Melamine ( 6 ) B u t y l C e l l o s o l v e Solvent Thickener (7) Blue T i n t Paste ( 8 ) S u o ~ lie r s : Pounds 3.3 3.1 4.7 74.3 0.7 263.0 25.6 630.2 3 . 1 4 . 9 1.6 5.6 14.4 6.3 2.6 Gallons 0.33 0.33 0.50 8.93 0.09 11.69 0.73 72.86 0.31 0.53 0.20 0.56 1.92 0.73 0.29 Wei qht% 0.32 0.30 0.45 7.12 0.07 25.21 2.46 60.38 0.30 0.47 0.15 0.54 1.38 0.60 0.25 Dispersant - Strodex PK-90 (Dexter Chemical) o r e q u i v a l e n t Dispersant - Ross and Rowe 551 (Ross and Rowe Chemicals) o r e q u i v a l e n t . Defoamer - Foamaster VF (Diamond Shamrock) o r e q u i v a l e n t . Calcium Carbonate - Atomite (Thompson, Weinman) o r equiv- a l e n t . Titanium Dioxide - Ti-Pure R-900 (duPont) o r e q u i v a l e n t . Me1ami ne - Cyme1 350 (American Cyanamid) o r e q u i v a l e n t . Thickener - Acrysol G-110, 22% (Rohm and Haas) o r equiv- a1e n t . Aqueous Dispersion - Thalo Blue (Tenneco) o r e q u i v a l e n t . Procedure: order l i s t e d . Mix a t low speed f o r one minute. Slowly add p i g - ments and s t i r u n t i l uniform. Grind a t h i g h speed u n t i l d e s i r e d g r i n d f ineness has been accompl ished. For t h e letdown, pre-blend Ucar V e h i c l e 441, Strodex PK-90, soya l e c i t h i n , and defoamer. With slow a g i t a t i o n , add t o t h e pigment g r i n d . S t i r a t low speed f o r 5 t o 10 minutes. Pre-blend B u t y l C e l l o s o l v e Solvent and melamine and add t o l e t down. S t i r f o r f i v e minutes. Add b l u e t i n t paste and t h i c k e n e r and s t i r f o r 5 t o 10 minutes. If done s l o w l y and c a r e f u l l l y , l e t down Charge t h e f i r s t f i v e components t o a Cowles mixer tank i n t h e components may be added s e q u e n t i a l l y . Coating P r o p e r t i e s : N o n v o l a t i l e s , %: 54 t o 55 pH: 8 . 0 Pigment/Binder R a t i o : 1 . O V i s c o s i t y a t 25C ( B r o o k f i e l d LVT, 60 r p m ) , cP: 200 SOURCE: Ucar Emulsion Systems: Ucar V e h i c l e 441: Formu Suggestion LP-3024 o 300 a t i on
  • 39.
    30 Water-Based PaintFormulations A c r y l ic Emu1s i o n Enamel -B&C K-F1 ex UD-320W M o d i f i e d K-F1 ex UD-320W modi f i c a t 1on o f t h i s w h i t e a c r y l ic/melami ne emulsion f o r g e n e r a l i n d u s t r i a l a p p l i c a t i o n s demonstrated s e v e r a l advantages in c l u d i ng: improved f l o w / l e v e l ing, h i g h e r g l o s s , improved g l o s s r e t e n t i o n on QUV exposure-higher s o l i d s ( l o w e r VOC) and lower c o s t p e r pound on a s o l i d s b a s i s . G r i n d Composition: J o n c r y l 540 S u r f y n o l 104 T i - P u r e R-960 Water ( G r i n d t o 6+ Hegman on t h e B a l l M i l l ) Letdown Composition: G r ind J o n c r y l 540 HMMM K-Flex UD-320W Nacorr 1552 Water Enamel C h a r a c t e r i s t i c s : AMP-95 V i s c o s i t y , cps (25C): 200-205 Pigment/Binder R a t i o : 0 . 7 6 : l . O pH: 8.70-8.75 Q 41.8 1. o 1 .o 4 8 . 6 7 . 6 Wt%-B Wt04-& 100.0 100.0 50.9 39.1 1 9 . 9 2 9 . 1 3 . 6 7.2 1 . 3 1 . 3 23.0 25.0 A p p l i c a t i o n and Cure: S u b s t r a t e : B o n d e r i t e 1000 ( i r o n phosphated CRS) Cure Schedule: 15'/300F (150C) DFT ( m i l s ) : 0.9+-0.01 ( 2 2 . 5 ~ ) F i l m P r o p e r t i e s : A c r y l ic/K-Flex/HMMM: Penci 1 Hardness Knoop Hardness (259) MEK R e s i s t a n c e (2X) Crosshatch Adhesion Impact R e s i s t a n c e : D i r e c t ( i n l b s ) : Reverse ( i n l b s ) : C1eve1 and H u m i d i t y (55C) 0 C 65/5/30 57/16/33 4H-5H 4H-5H 17.0 1 8 . 4 100 100 100% 100% 100-110 100-110 20- 30 20 -30 9/M 9/MD SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n UDW-12 B & C
  • 40.
    Enamels 31 S yn e r g i s t i c E f f e c t s o f Combinina Nacorr w i t h A n t i - C o r r o s i v e Pinment i n an A i r Dry Water R e d u c i b l e A1kyd M o d i f i e d A c r y l i c Enamel Improvements i n t h e c o r r o s i o n r e s i s t a n c e o f a w a t e r r e d u c i b l e a i r d r y a c r y l i c enamel a r e p o s s i b l e u s i n g Nacorr r u s t and c o r r - o s i o n i n h i b i t o r s , When used i n c o m b i n a t i o n w i t h a c a l c i u m s t r o n t - ium p h o s p h o s i l i c a t e c o r r o s i o n i n h i b i t i n g pigment (Halox SW-1111, a d e f in i t e improvement in c o r r o s i o n r e s i s t a n c e was o b t a i ned. S a l t spray t e s t i n g was c a r r i e d o u t o v e r i r o n phosphated p a n e l s ( B o n d e r i t e 1000). G r i n d : Aquamac 1090 Nacorr 2-Butoxyethanol N y t a l 400 Halox SW-111 Raven B l a c k 16 Hal ox C o n t r o l SW-111 3 . 7 9 3.79 2.79 2.79 11.61 9 . 2 9 2.38 0.71 0.71 ____ ---- ____ Letdown: (Add g r a d u a l l y w h i l e on m i l l a t low rpm): C o b a l t Hydrocure 0.06 0.06 Manganese Hydrocure 0.08 0.08 Water 15.85 15.85 Ammonium Hydroxide, 30% 0.28 0.27 Aquamac 640 (post-add 8 shake) 64.83 64.80 Hal ox C h a r a c t e r i s t i c s : C o n t r o l SW-111 P i gment/Bi nder R a t i o 0.4 0.4 T o t a l Resin S o l i d s , % by w e i g h t 32.0 32.0 Halox, % based on t o t a l p a i n t w e i g h t -- 2 . 4 F i l m P r o p e r t i e s : N o n - V o l a t i l e , % by w e i g h t 44.3 4 4 . 4 Nacorr, % based on t o t a l p a i n t w e i g h t -- __ S u b s t r a t e : B o n d e r i t e 1000 I r o n Phosphated CRS Cure: 7 days a t room temperature (22-23C) A p p l i c a t i o n : Spray F i l m Thickness: 20-25 m i c r o n s Hal ox F o r m u l a t i o n T e s t Procedure: C o n t r o l SW-111 Penci 1 Hardness Tukon Hardness, KHN25 2B-B 28-8 1.2 2 . 2 H a l o x t Nacorr 3 . 7 6 0.78 2.77 9 . 2 1 2.36 0 . 7 0 0 . 0 6 0 . 0 8 15.72 0.27 64.29 H a l o x t Nacorr 0.4 44.0 31.8 0 . 8 2 . 4 Halox+ Nacorr 1151 28-8 2 . 2 Crosshatch Adhesion, % removed 0 0 0 S a l t Spray, 100 h o u r s Light-med Very l i g h t No r u s t S a l t Spray, 310 h o u r s Very Very Medi u m r u s t r u s t dense r u s t dense r u s t r u s t The use o f N a c o r r s w i t h t h e a n t i - c o r r o s i v e pigment o f f e r e d t h e b e s t c o r r o s i o n r e s u l t s i n t h i s s t u d y . They had l i t t l e o r no d e l e t e r i o u s e f f e c t on o t h e r p a i n t p r o p e r t i e s . SOURCE: K i n g I n d u s t r i e s : Nacorr WR-14
  • 41.
    32 Water-Based PaintFormulations Ancamide 2353 Fast Drvina White Gloss Enamel Part A: Grind Base: DER 660x80 (Dow) Nuosperse 657 ( H u l s America) Beetle 216-8 (American Cyanamid) Dowanol PM (Dow) TiPure R-960 (DuPont) Let Down: High Flash Naphtha (Ashland) Methyl Propyl Ketone (Eastman) Part 8: Ancamide 2353 ( A i r Products) n-Butanol (Ashland) Properties : Part A V i s c o s i t y : 86KU Part B V i s c o s i t y : 64KU M i xed V i s c o s i t y : 80KU PVC: 15.2% Vo 1ume SOURCE S o l i d s : 62.2% -Lb 472.55 3.54 2.84 47.26 307.16 73.72 14.18 131.44 34.78 VOC, @ 80KU: 2.8 l b / g a l Mix Ratio: 4:l by Volume I n d u c t i o n Time: 0 Pot L i f e , h r : 3 Dry Times: Set t o Touch, min: 50 Dust Free, min: 75 Hard Dry: Overnight 60 Gloss: 104 Gal 51.47 0.42 0.34 6.20 9.44 10.03 2.10 14.86 5.14 A i r Products and Chemicals, I n c . : Ancamide 2353 Curing Agent: Table 12 Formulation
  • 42.
    Enamels 33 Ancamide 2353Low VOC White Gloss Enamel P a r t A: Grind Base: L i q u i d DGEBA Epoxy Nuosperse 657 (Huls America) Surfynol 740 ( A i r Products) Dowanol PM (Dow) TiPure R-960 (DuPont) Let Down: High Flash Naphtha (Ashland) Methyl Propyl Ketone (Eastman) Part 8 : Ancamide 2353 ( A i r Products) n-Butanol (Ashland) Propert ies : Part A V i s c o s i t y : 73 KU Part B V i s c o s i t y : 64 KU Mixed V i s c o s i t y : 70 KU PVC: 17% Volume S o l i d s : 70% 352.76 36.43 3.88 0.46 1.76 0.25 48.68 6.32 388.04 11.92 67.73 9.22 14.11 2.09 212.03 23.46 63.14 9.34 VOC, @ 70 KU: 2.2 l b / g a l Mix Ratio: 2:l by Volume I n d u c t i o n Time: 0 Pot L i f e , h r : 2 Dry Times: Set t o Touch, h r : 5 Dust Free, h r : 7 Hard Dry: Overnight 60 Gloss: 102 SOURCE: A i r Products and Chemicals, I n c . : Ancamide 2353 Curing Agent: Tab1e 11 Formulation
  • 43.
    34 Water-Based PaintFormulations Carv Gloss White Enamel I n a r e d i e n t s : Pigment Grind: B u t y l C e l l o s o l v e Solvent Water Tamol 731 T r i t o n Nonionic S u r f a c t a n t CF-10 Byk 023 T i -Pure R-900 Natrosol Plus 330 Water Nuosept 145 Letdown : Ucar Latex 481 Water B u t y l Carbi t o 1 Sol vent Solvent 142HT LE-410 Emulsion Surfynol 104E P a i n t P r o p e r t i e s : Pigment Volume Concentration, %: 17.8 Volume S o l i d s , %: 40.6 Weight S o l i d s , %: 51.9 Stormer, KU: 85 I C I , Poise: 2.0 pH Value: 9-9.6 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 0.1 Heat-Age S t a b i l i t y , 120F, weeks passed: 4 VOC, grams per l i t e r : 196 Pounds 39.0 20.0 9 . 6 2.4 2.5 240.0 1.1 5.0 1 . 4 620.0 19.6 12.8 32.8 15.0 2.0 Gal 1ons 5.20 2.40 1.05 0.27 0.35 7.02 0.10 0.60 0.16 71.84 2.35 1.60 5.00 1.82 0.24 T y p i c a l T i t a n i u m Dioxide Pigment Performance T i t a n i u m D i o i x d e Stormer I C 1 Gloss Values KU Poise 60 20 T i -Pure R-900 85 2.0 85 52 T i -Pure R-902 83 2.1 79 41 T i -Pure R-960 86 2.0 79 41 T i -Pure R-706 82 1.7 90 60 Tronox CR-828 Tiona RCL-535 Kronos 2310 T i o x i d e TR 90 T i o x i d e TR 93 T i o x i d e TR 80 86 2.0 87 59 83 1.7 87 59 84 1.8 84 53 83 86 85 1.7 88 54 1 . 8 86 57 2.0 90 68 SOURCE: Ucar Emulsion Systems: Ultra-Gloss Latexes: Formulation Suggestion E-2218C
  • 44.
    Enamek 35 C aw Gloss White Enamel I n g r e d i e n t s : Pigment Grind: B u t y l C e l l os01ve Solvent Water Tamol 731 T r i t o n Nonionic Surfactant CF-10 Byk 023 T i -Pure R-900 Water Nuosept 145 Ammonium Hydroxide, 28% Aqueous S o l u t i o n Letdown : Ucar Latex 481 B u t y l C a r b i t o l Solvent Sol vent 142HT LE-410 Emulsion Ucar Polyphobe 102 Rheo. Mod. Ucar Polyphobe 106HE Rheo. Mod. Water Surfynol 104E P a i n t Properties: Pigment Volume Concentration, %: 17.8 Volume Solids, %: 40.7 Weight Solids, %: 52.1 Stormer, KU: 86 ICI, Poise: 2.5 pH Value: 9-9.6 Freeze-Thaw S t a b i l i t y , cycles passed: 0-1 Heat-Age S t a b i l i t y , 120F, weeks passed: 4 VOC, grams per l i t e r : 196 F i 1m Properties : Gloss, 60: 88 Gloss, 20: 47 Flow and Leveling: Excellent Dry-to-Touch, hour: 1 Recoat, hours: 2-4 Water/Bl is t e r Resistance: Excel l e n t Pounds 39.0 20.0 9.6 2.4 2 . 5 240.0 5.8 1.4 2.0 620.0 12.8 32.8 15.0 5.0 2.7 10.0 2.0 Gal 1ons 5.20 2.40 1.05 0.27 0.35 7.02 0.70 0.16 0.27 71.84 1.60 5.00 1.82 0.57 0.31 1.20 0.24 SOURCE: Ucar Emulsion Systems: Ultra-Gloss Latexes: Formulation Suggestion E-221 6G
  • 45.
    36 Water-Based PaintFormulations C l e a r Enamel (For Maximum S o l v e n t and A b r a s i o n Resistance) _ _ _ _ _ _Pounds Gal l o n sM a t e r i a1.L P a r t A: Epi-Rez 5522-WY-55 Resin 490.6 54.82 Michem Lube 743 Mar and S l i p Agent 41 . O 5.00 C y c l o Sol 63 32.3 4.37 E k t a s o l v e EP, 2-Propoxyethanol 33.2 4.37 Water 53.6 6.44 P a r t 0 : Epi-Cure 8290-Y-60 C u r i n g Agent DeeFo P I - 4 Concentrate Defoamer Water Composite Blend: V i s c o s i t y P a r t A 58 K.U. P a r t B 68 K.U. P a r t s A and 0 85 K.U. 145.8 16.51 4.0 0.49 66.6 8.00 650.7 75.00 216.4 25.00 T y p i c a l C o a t i n g P r o p e r t i e s : T o t a l Weight S o l i d s , %: 41.8 T o t a l Volume S o l i d s , %: 37.6 V o l a t i l e Organic Compounds (VOC): Pounds/Gallon: 2.74 G r a m s / L i t e r : 329 I n d u c t i o n Time, minutes: 30 Resi n Composi ti on : Epoxy Resin, %: 75.0 C u r i n g Agent, %: 25.0 T o t a l , %: 100.0 SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1802: €pi-Rez 5522-WY-55 Resin/Epi-Cure 8290-Y-60 C u r i n g Agent
  • 46.
    Enamels 37 Gloss SafetyRed Enamel I n g r e d i e n t s : P i gment G r i nd : Ucar Latex 481 T r i t o n Nonionic S u r f a c t a n t CF-10 T o l u i d i n e Red 10-6C-41-L100 Aquatrend I 1 Red I r o n Oxide Disp. 878-1046 Colanyl Carmine Disp. 13-3148 (Azo Red) Foamaster 333 Natrosol Plus 330 Water Nuosept 145 Letdown : Ucar Latex 481 B u t y l C e l l o s o l v e Solvent B u t y l C a r b i t o l Solvent Solvent 140 LE-410 Emulsion Aquatrend I 1 Red I r o n Oxide Disp. 878-1046 Colanyl Carmine Disp. 13-3148 (Azo Red) Surfynol 104E P a i n t P r o p e r t i e s : Pigment Volume Concentration, %: 11 .O Volume S o l i d s , %: 39.5 Weight Solids, %: 43.4 Stormer, KU: 88 ICI, Poise: 1.5 pH Value: 8.5-9.5 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5 Heat-Age S t a b i l i t y , 12OF, weeks passed: 4 VOC, grams per l i t e r : 210 F i l m P r o p e r t i e s : Gloss, 60: 81 Gloss, 20: 40 Flow and Leveling: E x c e l l e n t Dry-to-Touch, hour: I Recoat, hours: 2-4 Water/Bl is t e r Resistance: Excel l e n t Pounds 173.4 10.0 110.0 9.4 7.8 15.0 1 .o 8.3 1.2 416.9 38.3 12.4 32.8 15.0 5.0 3.0 2.0 Gal l o n s 20.09 1.14 11.58 0.59 0.76 2.00 0.09 1.oo 0.13 48.31 5.10 1.55 5.00 1.82 0.31 0.29 0.24 SOURCE: Ucar Emulsion Systems: Ultra-Gloss Latexes: Formulation Suggestion E-2222C
  • 47.
    38 Water-Based PaintFormulations Gloss Safety Yellow Enamel I n p r e dient s : Pi ament G r i nd: Pounds BuTyl Cellosolve Solvent Water Tamol 731 T r i t o n Nonionic Surfactant CF-10 Foamaster 333 T i -Pure R-900 Natrosol Plus 330 Water Nuosept 145 B u t y l Cellosolve Solvent Letdown : Ucar Latex 481 Water Byk 026 B u t y l C a r b i t o l Solvent Sol vent 142HT LE-410 Emulsion Aquis Dalamar Yellow Disp. YW-811D Aquatrend I 1 Yellow I r o n Oxide Disp. 878-0012 Aquatrend I1 Lamp Black Disp. 878-9908 Surfynol 104E Paint Properties: Pigment Volume Concentration, %: 11.4 Volume Solids, %: 37.4 Weight Solids, %: 43.9 Stormer, KU: 89 ICI, Poise: 1.7 pH Value: 8.5-9.5 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5 Heat-Age S t a b i l i t y , 120F, weeks passed: 4 VOC, grams per l i t e r : 218 F i 1m P r o p e r t i es : Gloss, 60: 86 Gloss, 20: 46 F1ow and Level ing : Excel 1e n t Dry-to-Touch, hour: 1 Recoat, hours: 2-4 Water/Blister Resistance: E x c e l l e n t 12.8 10.0 5 . 0 10.0 15.0 66.3 2.8 5.0 1.2 24.8 572.9 24.0 2.0 12.8 32.8 15.0 76.2 12.1 0.1 2.0 Gallons 1.70 1.20 0.54 1.14 2.00 1.94 0.25 0.60 0.13 3.30 66.39 2.88 0.25 1.60 5.00 1.82 8.28 0.73 0.01 0.24 SOURCE: Ucar Emulsion Systems: Ultra-Gloss Latexes: Formulation Suggestion E-2225C
  • 48.
    Enameh 39 Gloss WhiteEnamel M a t e r ia1 : P a r t A: Epi -rez 3520-WY-55 Resin Michemlube 182 Mar and S l i p Agent Water P a r t 0: Epi-Cure 8537-WY-60 Curing Agent Ektasolve DB Acetate T r i e t h y l a m i n e Patcote 519 Defoamer Kronos 2020 o r Tronox CR-800 Pounds 411.6 27.8 13.7 160.0 8.2 3 . 7 4.0 250.0 Gal 1ons 45.03 3.33 1.64 17.70 1.oo 0.61 0.57 7.33 High Speed d i s p e r s e t o a t e x t u r e o f 10 P.C.S., then add: Epi-Cure 8537-WY-60 Curing Agent Water 42.4 4.69 150.0 18.10 Composi t e 81end : P a r t A P a r t B P a r t s A and B V i scosi t y 85 KU 453.1 50.00 110 KU 619.1 50.00 99 KU T y p i c a l Coating P r o p e r t i e s : T o t a l Weight S o l i d s , %: 55.8 T o t a l Volume S o l i d s , %: 42.3 PVC, %: 17.3 V o l a t i l e Organic Compounds (VOC): Pounds/Gal 1on : 1.61 Grams/Li t e r : 187 Resin Composition (based on s o l i d s ) : Epoxy Resin, %: 65.0 Curing Agent, %: 35.0 T o t a l , %: 100.0 Reduction f o r Conventional Spray (by volume): P a r t s A and B: 17 P a r t s Water: 1 Part SOURCE: S h e l l Chemical Co.: S t a r t i n g Formulation No. 1606: Epi-Rez 3520-WY-55 Resin/Epi-Cure 8537-WY-60 Curing Agent
  • 49.
    40 Water-Based PaintFormulations Gloss W h i t e~ . . ~Enamel M a tcr i_a 1-1 P a r t A : Epi -Rez 3520-WY-55 Resin Michemlube 182 Mar and S l i p Agent Water P a r t B : Epi-Cure 8536-MY-60 C u r i n g Agent Deefo P I - 4 Concentrate Defoamer R u t i l e T i t a n i u m D i o x i d e , Kronos 2020 o r Tronox CR-800 High speed d i s p e r s e t o a t e x t u r e o f 10 P . C . S Epi-Cure 8536-MY-60 C u r i n g Agent Water T y p i c a l C o a t i n g P r o p e r t i e s : T o t a l Weight S o l i d s , %: 5 1 . 5 T o t a l Volume S o l i d s , %: 3 7 . 6 PVC, % : 19.5 V o l a t i l e Organic Compounds (VOC): Pounds/Gal l o n s : 1 .89 Grams/Li t e r : 227 Resin Composition (based on s o l i d s ) : Epoxy Resin, %: 62.2 C u r i n g Agent, %: 37.8 ~~Pounds 329.4 8 8 . 6 27.8 160.0 4 . 0 250.0 G a l l o n s 36.04 3 . 3 3 10.63 19.28 0 . 4 9 7.33 t h e n add: 2 2 . 5 2.71 168.2 20.19 Reduction f o r Conventional Spray (by volume): None r e q u i r e d SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1805: Epi-Rez 3520-WY-55 Resin/Epi-Cure 8536-MY-60 C u r i n g Agent
  • 50.
    Enamels 41 G lo s s W h i t e Enamel (Maximum S o l v e n t and A b r a s i o n Resistance) M a t e r i a1 : P a r t A: €pi-Rez 5522-WY-55 Resin C y c l o Sol 63 E k t a s o l v e EP, 2-Propoxyethanol Water P a r t 8: Epi -Cure 8290-Y-60 C u r i n g Agent Deefo P I - 4 C o n c e n t r a t e Defoamer T i - P u r e R-960 o r Kronos 2160 Water H i g h speed d i s p e r s e t o a t e x t u r e o f 10 P . S . C Water G l a c i a l A c e t i c A c i d Composite Blend: V i s c o s i t y P a r t A 61 K . U . P a r t B 103 K . U . P a r t s A and B 83 K . U . T y p i c a l C o a t i n g P r o p e r t i e s : T o t a l Weight S o l i d s , Oh: 54.0 T o t a l Volume S o l i d s , %: 40.4 PVC, %: 1 9 . 2 V o l a t i l e Organic Compounds (VOC): Pounds/Gallon: 2 . 3 4 G r a m s / L i t e r : 280 I n d u c t i o n Time, m i n u t e s : 30 Resin Composition (based on s o l i d s ) : Epoxy Resin, %: 74.5 C u r i n g Agent, %: 2 5 . 5 ~ _ _ _Pounds Gal 1ons 442.2 49.41 2 2 . 2 3 . 0 0 22.7 3.00 9 3 . 8 11 .26 135.1 15.30 4.0 0.49 250.0 7 . 7 4 1 2 . 5 1 .so 6 6 . 1 7.93 3 . 2 0.37 580.9 66.67 470.9 33.33 Reduction f o r Conventional Spray (by volume): P a r t s A and B: 25 p a r t s Water: 1 p a r t SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1803: Epi-Rez 5522-WY-55 Resin/Epi-Cure 8290-Y-60 C u r i n g Agent
  • 51.
    42 Water-Based PaintFormulations Green A i r Dry Enamel f o r Flexible Substrates Materi a1 : Spensol L53 Amrnoni um Hydroxi de D i sperse-Ayd W28 C o l l o i d 679 Ucar SCT 100 Sunbrite Yellow 272-0558 Sunbri t e Green 264-8142 Titanox 2101 Mapico 1075 Lbs. 261.6 1.9 4.4 1.9 2.3 50.0 25.0 25.0 50.0 Gals. 30.00 0.25 0.50 0.25 0.25 4.69 1.43 0.75 1.48 Add the above i n order under good a g i t a t i o n , then pebble o r sandmill g r i n d t o 7 Hegman. Letdown: Spensol L53 526.7 60.40 Analysis: Pigment Volume Concentration, Percent: 24.7 Pigrnent/Binder Ratio: 0.6/l.O Percent Solids, Weight: 41.2 Percent Sol ids, Vol ume: 33.8 V i s c o s i t y @ 25C, #2 Zahn, Secs.: 50-60 Pounds/Gallon: 9.5 VOC (excluding water): Grams/Liter: 289 Pounds/Gallon: 2.4 pH: 8.5+-0.3 SOURCE: Reichhold Chemicals, I n c . : Spensol L: Formula 2316-62A
  • 52.
    Enamels 43 H iqh-HidinqEsashe11 Enamel PoundsI n s r e d ie n t s : Pigment Grind: Water 226.7 Cel l o s i ze Hydroxyethyl C e l l u l ose ER-4400 2.0 Nuosept 145 2 . 3 Tamol 731 9.2 T r i t o n Nonionic S u r f a c t a n t N-57 2.3 AMP-95 1.o Propylene Glycol 51.8 Col l o i d 643 1.9 Tronox CR-800 225.0 Optiwhi t e 100.0 Burgess No. 98 25.0 Letdown : Ucar F i l m e r I B T B u t y l Carbi t o 1 Solvent Acrysol SCT-275 Ucar Latex 379G Col l o i d 643 Pai n t P r o p e r t i e s PVC, %: 35.6 Volume Sol ids Weight Sol i d s Weight per Ga Stormer. KU: I C I . n o i s e : 1 %: 37.6 %: 53.4 l o n , l b : 04 . 4 11.9 11.9 17.2 418.2 2 . 8 1 . 0 9 G a l 1ons 27.21 0.18 0.25 1.oo 0.25 0.13 6.00 0.25 6.54 5.46 1.15 1.50 1.50 2.00 46.21 0.37 I . pH, i n i t i a l : 8.2 Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass F i 1m P r o p e r t i e s : Ref 1ectance, %: 91.9 Gloss, 60: 8 Sheen, 85: 22 Contrast R a t i o , 3-mil f i l m * : 0.968 Flow and l e v e l i n g , brushed: Good *Opacity increased w i t h t o n i n g . SOURCE: Ucar Emulsion Systems: Formulation Suggestion I-1998A
  • 53.
    44 Water-Based PaintFormulations MacGregor Gloss B1ack Enamel I n g r e d i e n t s : Pigment Grind: Ucar Latex 481 Byk 023 T r i t o n Nonionic Surfactant CF-10 Aurasperse Carbon B1ack W-7012 Water Nuosept 145 Ammoni urn Hydroxide, 28% Aqueous Sol u t i on Letdown : Ucar Latex 481 Dee Fo 102OF Butyl C e l l osolve Sol vent B u t y l C a r b i t o l Solvent Sol vent 142HT LE-410 Emu1s i on Water Ucar Polyphobe 102 Rheo. Mod. Ucar Polyphobe 106HE Rheo. Mod. Surfynol 104E Pounds 88.0 2.5 10.0 45.0 8.3 1 . 2 2 . 4 556.0 5.0 39.0 12.4 32.8 15.0 15.0 8.3 4.5 2 . 0 Gallons 10.20 0.35 1.14 4.69 1.oo 0.13 0.29 64.43 0.68 5.21 1.57 5.00 1.80 1.80 0.95 0.52 0.24 Paint Properties: Pigment Volume Concentration, %: 2.3 Volume Solids, %: 37.9 Weight Solids, %: 40.6 Stormer, KU: 90 I C I , Poise: 2.6 pH Value: 8.5-9 Freeze-Thaw S t a b i l i t y , cycles passed: 5 Heat-Age S t a b i l i t y , 120F, weeks passed: 4 VOC, grams per l i t e r : 204 F i l m Properties: Gloss, 60: 91 Gloss, 20: 65 Flow and Leveling: Excel l e n t Dry-to-Touch, hour: 1 Recoat, hours: 2 Water/Bl is t e r Resistance: Excel l e n t SOURCE: Ucar Emulsion Systems: Ultra-Gloss Latexes: Formulation Suggest ion E-2221 E
  • 54.
    Enamels 45 Pinehurst GlossGreen Enamel I n g r e d i e n t s : Pigment Grind: B u t y l Cellosolve Solvent Water Tamol 731 T r i t o n Nonionic Surfactant CF-10 Byk 023 Chromium Oxide Green W-6017 Aurasperse Carbon Black W-7012 Aurasperse Phthalo Green W-6013 Yellow I r o n Oxide 878-1812 Natrosol Plus 330 Water Nuosept 145 Letdown : Ucar Latex 481 Water B u t y l C a r b i t o l Solvent Solvent 142HT B u t y l Cellosolve Solvent Water LE-410 Emulsion Surfynol 104E Pounds 7.5 5.8 5.0 10.0 2.5 53.3 3.2 25.4 7.0 2.0 4.2 1.2 640.0 8.3 12.4 32.8 31 . 5 8 . 8 15.0 2.0 Gal 1ons 1.oo 0.70 0.54 1.14 0.31 3.08 0.34 2.54 0.42 0.18 0.59 0.13 74.16 1 .oo 1.55 5.00 4.20 1.06 1.82 0.24 P a i n t Properties: Pigment Volume Concentration, %: 4.6 Volume Solids, %: 37.1 Weight Solids, %: 42.0 Stormer, KU: 88 I C I , Poise: 2.3 pH Value: 8.5-9.5 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5 Heat-Age S t a b i l i t y , 120F, weeks passed: 4 VOC, grams per l i t e r : 221 F i l m Properties: Gloss, 60: 88 Gloss, 20: 64 Flow and Level ing: Excel 1ent Dry-to-Touch, hour: 1 Recoat. hours: 2-4 Water/Blister Resistance: E x c e l l e n t SOURCE: Ucar Emulsion Systems: Ultra-Gloss Latexes: Formulation Suggestion E-22429
  • 55.
    46 Water-Based PaintFormulations S e l f - P r i m i n a I n t e r i o r Semi-Gloss Enamel Pigment G r i n d : Water Busperse 203 I g e p a l CTA-639 Bubreak 448 Water* C e l l o s i z e QP 15,000* Atomi t e T i - P u r e R-900 Disperse 10-15 minutes on a high-speed m i l l Add t h e f o l l o w i n g w i t h slow a g i t a t i o n . L e t Down: Rhopl ex R-AC-507 E t h y l e n e g l y c o l Texanol Water *These i n g r e d i e n t s a r e premixed. Lbs. 100.0 14.0 3 . 0 3.0 25.0 2.0 73.0 200.0 550.0 40.0 25.0 32.0 E x t e r i o r Maintenance-Type C o a t i n g Pigment G r i n d : Water Tam01 -681 8ubreak 448 I g e p a l CTA-639 E-845 Ti-Pure R-900 Atomi t e Mica Kadox 911 Disperse 10-15 minutes on a high-speed m i 11. Add t h e f o l l o w i n g w i t h slow a g i t a t i o n . L e t Down: Rhopl ex MV-23 Texanol E t h y l e n e g l y c o l Water Lbs. 100.0 14.0 3.0 3.0 40.0 150.0 191.o 25.0 12.0 527.0 5.0 30.0 30.0 && 9 . 3 7 1 .31 0.28 0.28 2 . 3 4 0.19 6.84 18.74 51.55 3.75 2.34 3.01 Wt% 8.85 1.24 0.27 0.27 3.54 13.27 16.90 2.21 1.06 46.64 0.44 2.65 2.66 SOURCE: Buckman L a b o r a t o r i e s : B u t r o l 35: F o r m u l a t i o n Suggestions
  • 56.
    Enamels 47 Semigloss Enamel Inqredients: PiamentGrind: WaIer C e l l o s i z e Hydroxyethyl Cellulose ER-15,000 Nuosept 145 Tamol 731 T r i t o n Nonionic Surfactant N-57 Propylene G1ycol Byk 035 Tronox CR-800 Letdown : Thickener; premix* Ucar Latex 3796 Ucar Filmer IBT Byk 035 T r i t o n Anionic Surfactant GR-7M AMP-95 Pounds 268.2 2.0 2.4 9.2 2.1 1 .o 43.2 1.o 250.0 29.9 428.4 20.0 1.9 0.5 Gal 1ons 32.20 0.18 0.25 1 .oo 0.25 0.13 5.00 0.13 7.27 3.48 2.52 0.25 0.06 47.28 Pa *Premix consists o f 1 : l : l blend o f Propylene Glycol; Rohm and Haas' Acrysol SCT-275 thickener:water, respectively. n t Properties: PVC, %: 23.0 Volume Solids, %: 31.8 Weight Solids, %: 46.0 Weight per Gallon, l b : 10.60 Stormer, KU: 82 I C I , poise: 0 . 4 pH, i n i t i a l : 8.5 Freeze-thaw S t a b i l i t y , 3 cycles: Pass Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass F i 1m Properti es : Reflectance, %: 89.5 Gloss, 60: 59 Contrast Ratio, 3-mil f i l m : 0.967 Flow and Leveling: brushed: Very Good drawdown, NYPC Blade: 8 SOURCE: Ucar Emulsion Systems: Formulation Suggestion I-1989A
  • 57.
    48 Water-Eased PaintFormulations Semiq loss Enamel Ingredient s : Pigment Grind: Water Propylene Glycol Tamol 1124 Proxel GXL Col 1o i d 640 T i -Pure R-900 T r i t o n Nonionic Surfactant N-101 ASP-1 70 Water Letdown : Water C o l l o i d 640 NeoCar Latex 6040 Water Ucar Filmer IBT Ammonium Hydroxide, 28% Aqueous S o l u t i o n Ucar Polyphobe 102 Rheology M o d i f i e r Water Paint Properties: PVC, %: 24.9 Volume Solids, %: 30.5 Weight Solids, %: 44.5 Weight per Gallon, l b : 10.47 Stormer, KU: 88-93 I C I , poise: 1.1 pH Value: 8.75-9.25 Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass F i l m Properties: Gloss, 20: 20 Gloss, 60: 65 Contrast Ratio, 3-mil f i l m : 0.980 ASTM Scrub Cycles, w i t h shim: 1600 Block Resistance, 1 day: Exc Wet Adhesion, 4 hours: Exc Flow and Leveling: Exc S t a i n Removal : Exc Pounds 15.0 55.0 5.0 1. o 2.0 230.0 4.0 15.0 50.0 39.9 1 .o 425.0 100.0 30.0 4.0 20.0 50.0 Gal 1ons 1.80 6.35 0.51 0.11 0.26 6.90 0.46 0.70 6.00 4.79 0.13 47.39 12.00 3.79 0.52 2.30 6.00 Source: Ucar Emulsion Systems: NeoCar Polymers: Formulation Suggestion E-2481
  • 58.
    Enamels 49 Southern Pi n e s Gloss W h i t e Enamel I n g r e d i e n t s : Pigment G r i n d : Propylene G l y c o l Water Tamol 731 T r i t o n N o n i o n i c S u r f a c t a n t CF-10 Byk 023 T i -Pure R-900 Nuosept 145 Water Ammoni um Hydroxi de, 28% Aqueous Sol u t i on Letdown : Ucar L a t e x 481 B u t y l C a r b i t o l S o l v e n t Sol v e n t 142HT T r i t o n A n i o n i c S u r f a c t a n t GR-5M Byk 026 LE-410 Emu1s i on Ucar Polyphobe 102 Rheo. Mod. Water S u r f y n o l 104E Pai n t P r o p e r t i e s : Pigment Volume C o n c e n t r a t i o n , %: 1 7 . 6 Volume S o l i d s , %: 41.1 Weight S o l i d s , %: 53.1 Stormer, KU: 90 I C I , P o i s e : 1 . 9 pH Value: 8 . 5 - 9 . 5 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5 Heat-Age S t a b i l i t y , 12OF, weeks passed: 4 VOC, grams p e r l i t e r : 174 F i l m P r o p e r t i e s : Gloss, 60: 88 Gloss, 20: 52 F1ow and Level ing : Excel 1e n t Dry-to-Touch, h o u r : 2 Recoat, h o u r s : 4 Water/Bl is t e r Resistance: Excel 1e n t ___Pounds 40.0 2 0 . 0 9 . 6 2 . 4 2.5 240.0 1 . 4 1 1 . 1 2 . 0 620.0 1 2 . 8 2 0 . 0 1 . o 1 . o 1 5 . 0 20.0 1 1 . 9 2 . 0 G a l l o n s 4.62 2.40 1 . 0 5 0 . 2 7 0 . 3 5 7 . 0 2 0 . 1 6 1 . 3 3 0 . 2 4 71.84 1 . 6 2 3 . 0 5 0 . 1 2 0.14 1 . 8 2 2 . 3 0 1.43 0 . 2 4 SOURCE: Ucar Emulsion Systems: U l t r a - G l o s s Latexes: F o r m u l a t i o n Suggestion E-2251 C
  • 59.
    50 Water-Based PaintFormulations Spensol L54 Oranqe Enamel Materi a1 : Water Ammoni um Hydroxi de Bentone EW Lbs. Gals. 30.0 3.60 1.1 0.15 3.0 0.14 Premix the above three materials and Cowles grind 15-20 minutes to fully disperse Bentone EW. Then add the following materials under good agitation: Spensol L54 Surfynol GA Aerosol OT-75 Nalco 2300 Molybdate Orange Water Pebble or sand mill grind to 7 N . S . Letdown : _____Materi a1 : Spensol L54 Surfynol 104H 15% Solution FC430 in Water Ucar SCT-100 Analysis: Pigment Volume Concentration, Pigment/Binder Ratio: 0.5/1 .O Percent Solids, Weight: 39.1 Percent Solids, Volume: 30.0 Viscosity, #4 Ford, Secs.: 80- Pounds/Gallon: 9.7 VOC (excluding water): Grams/Li ter : 303 Pounds/Gallon: 2.5 Gloss (60): 50-60 pH: 8.5+-0.3 Percent: 9.0 .90 87.3 10.00 4.4 0.50 2.3 0.25 0.5 0.06 125.0 2.70 41.7 5.00 Lbs. 670.9 2.0 2.1 2.3 Gals. 76.85 0.25 0.25 0.25 SOURCE: Reichhold Chemicals, Inc.: Spensol L: Formula 2154-59A
  • 60.
    Enamels 51 Waterborne BlackEnamel Based on Eootuf 37-143/37-680 XForrula No. 3019-28A1 Component A: Arcosolv PTB 2-Butoxy Ethanol Dowanol PPH Add f o l l o w i n g i n order under a g i t a t i o n : Wollastokup 10 ES Raven 410 High speed disperse t o 5 N.S. Add f o l l o w i n g under a g i t a t i o n : Epotuf 37-680 & Gals 78.91 8.91 24.41 3.34 3.68 0.49 7.37 0.04 48.40 20.02 2.00 1.38 Epotuf 37-680 2-Butoxy Ethanol 432.06 48.77 9.54 1.27 Component 0: Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l uniform: Epotuf 37-1 43 91.85 10.32 Epotuf 37-058 7.95 1.07 2-Butoxy Ethanol 73.09 9.84 Tap Water 98.04 11.77 Wei ght/Gal l o n (Lbs. ) : 8.96 Percent S o l i d s (Wt.): 57.50 Percent S o l i d s ( V o l . ) : 37.30 PVC (%): 46.30 VOC ( Lbs. /Gal 1on) : 2.80 SOURCE: Reichhold Chemicals, I n c . : Formula 3019-28A
  • 61.
    52 Water-Based PaintFormulations Waterborne Blue Enamel Based On Epotuf 37-143/37-600 LFormula No. 3019-31Gl Component A : Epotuf 37-680 Arcosolv PTB 2-8utoxy Ethanol Oowanol PPH Add following in order under agitation: Wollastokup 10 ES Sunfast 81ue 248-3750 Tioxide TR92 High speed disperse to 5 N . S . Add following under agitation: j&S Gals 133.28 15.04 24.31 3.33 3.63 0.48 7.38 0 .84 64.54 34.37 22.02 Epotuf 37-600 368. 1 2.67 2.29 0.66 1.58 Component B: Mix following under high-speed agitation until uniform: EDotUf 37-143 88.91 Epotuf 37-058 2-Butoxy Ethanol Tap Water Weight/Gallon (Lbs.): 9.29 Percent Solids (Wt.) : 57.50 Percent Solids (Vol.): 37.30 PVC (%): 46.30 VOC (Lbs./Gallon): 2.83 9.99 7.62 1.03 91 .15 12.14 82.89 9.95 SOURCE: Reichhold Chemicals, Inc.: Formula No. 3019-31G
  • 62.
    Enamels 53 Waterborne DarkBlue Enamel Based on Epotuf 37-143/37-600 (Formula No. 3019-31Dl Component A: Arcosolv PTB 2-Butoxy Ethanol Dowanol PPH Add f o l l o w i n g i n order under a g i t a t i o n : Wollastokup 10 ES Sunfast Blue 248-3750 High speed disperse t o 5 N.S. Add f o l l o w i n g under a g i t a t i o n : Epotuf 37-680 !& Gals 134.16 15.14 24.47 3.35 3.65 0.49 7.43 0.84 64.97 34.60 Epotuf 37-680 370.85 Component 0 : Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l uniform: Epotuf 37-1 43 Epotuf 37-050 2-Butoxy Ethanol Tap Water 89.50 7.67 91.75 83.44 Weight/Gallon ( L b s . ) : 9.12 Percent S o l i d s (Wt.): 57.50 Percent S o l i d s ( V o l . ) : 37.30 PVC (%): 46.30 VOC (Lbs/Gallon): 2.83 SOURCE: Reichhold Chemicals, I n c . : Formula No. 3019-31D 2.68 2.31 41 .86 10.06 1.04 12.22 10.02
  • 63.
    54 Water-Based PaintFormulations Waterborne Green Enamel XFormula No. 3019-31F) Based on E D O t U f 37-143/37-680 Component A: Arcosolv PTB 2-Butoxy Ethanol Dowanol PPH Add f o l l o w i n g i n order under a g i t a t i o n : Epotuf 37-680 Wollastokup 10 ES S u n b r i t e Y e l l o w 75 Sunfast Blue 248-3750 T i o x i d e TR92 High speed disperse t o 5 N.S. Add f o l l o w i n g under a g i t a t i o n : Epotuf 37-680 2-Butoxy Ethanol ~ Lbs 165.99 23.12 3.47 8.05 78.51 23.71 9.68 9.21 295.72 29.74 Component B: Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l uniform: Epotuf 37-058 6.97 Tap Water 123.78 Epotuf 37-143 82.10 2-Butoxy Ethanol 59.85 Wei ght/Gal 1on (Lbs .) : 9.20 Percent Sol i d s (Wt .) : 57.50 Percent S o l i d s ( V o l . ) : 37.30 PVC (%): 46.30 VOC (Lbs./Gallon): 2.80 SOURCE: Reichhold Chemicals, I n c . : Formula No. 3019-31F 18.73 3.17 0.46 0.91 3.24 2.22 0.65 0.28 33.38 3.96 9.22 0.94 7.97 14.86
  • 64.
    Enamels 55 Waterborne OranqeEnamel Based on E p o t u f 37-143/37-600 (Formula 3019-3111 Component A: A r c o s o l v PTB 2-Butoxy Ethanol Dowanol PPH Add f o l l o w i n g i n o r d e r under a g i t a t i o n : Wollastokup 10 ES Sunbri t e Ye1 low 74 Novoperm Red F3RK-70 High speed d i s p e r s e t o 5 N . S . Add f o l l o w i n g under a g i t a t i o n : Epotuf 37-680 EpOtuf 37-680 2-Butoxy Ethanol Lbs 179.20 20.23 22.73 3.11 3.41 0.45 8.36 0.95 78 * 45 26.52 8.20 282.39 30.04 Component B: M i x f o l l o w i n g under high-speed a g i t a t i o n u n t i l u n i f o r m : EpOtuf 37-143 82.02 Epotuf 37-058 7.80 2-Butoxy Ethanol 60.60 Tap Water 122.11 Wei ght/Gal 1on ( Lbs . ) : 9 . 1 2 Percent S o l i d s ( W t . ) : 57.50 Percent S o l i d s ( V o l . ) : 37.30 PVC (%): 46.30 VOC ( L b s . / G a l l o n ) : 2.80 SOURCE: Reichhold Chemicals, I n c . : Formula No. 3019-311 3.24 2.49 0 . 7 6 31.87 4 . 0 0 9 . 2 2 1.oo 8.07 14.66
  • 65.
    56 Water-Based PaintFormulations Waterborne Red Enamel Based on Epotuf 37-143/37-6%0 (Formula No. 3019-3181 Component A : Arcosolv PTB 2-Butoxy Ethanol Dowanol PPH Add f o l l o w i n g i n order under a g i t a t i o n : Wollastokup 10 ES Novoperm Red F3RK-70 High speed disperse t o 5 N . S . Add f o l l o w i n g under a g i t a t i o n : 2-Butoxy Ethanol Tap Water Epotuf 37-680 Epotuf 37-680 !& 97.48 11.oo 25.04 3.43 3.73 0.50 9.29 1 .06 60.09 2.48 20.69 1.92 377.11 18.73 12.91 Component 8 : Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l uniform: Epotuf 37-1 43 80.34 Epotuf 37-058 7.88 2-Butoxy Ethanol 65.27 Tap Water 118.45 Wei ght/Gal 1on ( Lbs .) : 8.97 Percent Sol i d s (Wt .) : 57.50 Percent S o l i d s ( V o l . ) : 37.30 PVC (%): 46.30 VOC (Lbs./Gallon): 2.84 SOURCE: Reichhold Chemicals, I n c . : Formula No. 3019-318 42.56 2.49 1.55 9.03 1.06 14.22 8.69
  • 66.
    Enamels 57 Waterborne RedOrange Enamel Based on EDOtUf 37-143/37-600 I f o r m u l a No. 3019-31El Component A: Arcosolv PTB 2-Butoxy Ethanol Dowanol PPH Add f o l l o w i n g i n o r d e r under a g i t a t i o n : Epotuf 37-680 Wol l a s t o k u p 10 ES S u n b r i t e Yellow 74 Novoperm Red F3RK-70 T i o x i d e TR 92 High speed d i s p e r s e t o 5 N.S. Add f o l l o w i n g under a g i t a t i o n : Epotuf 37-680 2-Butoxy Ethanol Arcosolv PTB Lbs Gals 157.10 17.73 23.40 3.21 3.49 0.46 8.57 0.97 73.31 19.47 8.20 7.56 307.00 25.51 5.40 Component 8: Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l uniform: Epotuf 37-143 84.28 Epotuf 37-058 7.36 2-Butoxy Ethanol 57.28 Tap Water 124.03 Weight/Gallon ( L b s . ) : 9.12 Percent S o l i d s (Wt.): 57.50 Percent S o l i d s ( V o l . ) : 37.30 PVC (%I: 46.30 VOC ( L b s . / G a l l o n ) : 2.80 SOURCE: Reichhold Chemicals, I n c . : Formula No. 3019-31E 3.03 1.83 0.76 0.23 34.65 3.40 0.75 9.47 1.00 7.63 14.89
  • 67.
    58 Water-Based PaintFormulations Waterborne Y e l l o w EDOXY Enamel Based on EDOtuf 37-143/37-680 (Formula No. 3019-31Cl Component A: Arcosolv PT8 2-Butoxy Ethanol Dowanol PPH Add f o l l o w i n g i n o r d e r under a g i t a t i o n : Wollastokup 10 ES S u n b r i t e Yellow 74 T i o x i d e TR-92 High speed d i s p e r s e t o 5 N.S. Add f o l l o w i n g under a g i t a t i o n : Epotuf 37-680 Epotuf 37-680 2-8utoxy Ethanol Lbs Gal 198.55 22.41 22.56 3.09 3.36 0.45 8.21 0.93 83.03 32.49 12.63 3.43 3.05 0.38 263.53 29.74 26.43 3.52 Component 8 : Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l uniform: Epotuf 37-143 80.25 9.02 Epotuf 37-058 6.91 0.93 2-Butoxy Ethanol 65.03 8.66 Tap Water 119.86 14.39 Wei g h t / G a l l on (Lbs. ) : 9.23 Percent S o l i d s (Wt.): 57.50 Percent S o l i d s ( V o l . ) : 37.30 PVC (%): 46.30 VOC (Lbs./Gallon): 2.40 SOURCE: Reichhold Chemicals, I n c . : Formula 3019-31C
  • 68.
    EnameLF 59 Whisoering PinesSemigloss White Enamel Inqredients: Pigment Grind: Propylene Glycol Water 6yk 023 Tamol 731 T i -Pure R-902 Path 9 Nuosept 145 Water Ammoni um Hydroxi de, Pounds 30.0 53.3 2.5 10.0 230.0 40.0 1.5 16.7 28% Aqueous Sol u t i on 2.0 Letdown : Ucar Latex 461 Ucar Filmer I6T Sol vent 142HT LE-410 Emulsion Ucar Polyphobe 102 Rheo. Mod Water Surfynol 104E 556.0 12.4 31.5 15.0 16.9 19.7 2.0 Gal 1ons 3.47 6.40 0.35 1.09 6.92 1.98 0.17 2.00 0.94 64.66 1.57 4.80 1.BO 1.94 2.37 0.24 P a i n t Properties: Pigment Volume Concentration, %: 23.3 Volume Solids, %: 39.2 Weight Solids, %: 51.5 Stormer, KU: 93 I C I , Poise: 2.1 pH Value: 8.5-9.5 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5 Heat-Age S t a b i l i t y , 120F. weeks passed: 4 VOC, grams per l i t e r : 181 F i l m Properties: Gloss, 60: 54 Gloss, 20: 14 Flow and Leveling: Excellent Dry-to-Touch, hour: 2 Recoat, hours: 4 Water/61 is t e r Resistance: Excel l e n t SOURCE: Ucar Emulsion Systems: Ultra-Gloss Latexes: Formulation Suggestion E-2245C
  • 69.
    60 Water-Based PaintFormulations Anquamine 401 1 : l White Gloss Enamel P a r t A: j& Gals Epi -Rez 3520-WY-55 Epoxy Resin (She11) 363.24 39.20 DER 331 Epoxy Resin (Dow) 40.36 4.17 Water S u r f y n o l DF-11OD ( A i r P r o d u c t s ) 52.32 6 . 2 7 3.00 0.36 P a r t B: Anquami ne 401 C u r i n g Agent ( A i r P r o d u c t s ) 90.46 9.90 Dowanol PM S o l v e n t (Dow) 40.87 5 . 3 7 Benzyl A l c o h o l 29.97 3.44 S u r f y n o l DF-l10D ( A i r P r o d u c t s ) 3.00 0 . 3 6 T i P u r e 960 (DuPont) 272.48 8.16 G l a c i a l A c e t i c A c i d ( A i r P r o d u c t s ) 5.31 0 . 6 1 Water 185.01 22.16 T y p i c a l P r o p e r t i e s : W t S o l i d s ( % ) : 65.84 Resin S t o i c h i o m e t r y : 1.3:1 Volume S o l i d s (36): 40.95 VOC ( l b / g a l ) : 1.53 PVC ( % ) : 1 9 . 9 4 VOC ( g / l ) : 184 White G1oss Enamel P r o p e r ties : Pot L i f e , h r : >4 Gloss, 60 spec, 1 day: >90 Gloss, 60 spec, 4 week: >90 M i x R a t i o : 1 : l Mixed V i s c o s i t y , cP: 290 Tack F r e e Time, h r : 1 Hard Dry Time, h r : 6-8 P e n c i l Hardness, o v e r n i g h t : HB P e n c i l Hardness, 7 days: H Cross Hatch Adhesion: 5 1/8" Mandrel Bend: Pass D i r e c t Impact Resistance, i n - l b s : 60 Reverse Impact Resistance, i n - l b s : 20 VOC, l b / g a l : 1 . 6 Volume S o l i d s , %: 41 PVC, Yo: 19.9 SOURCE: A i r P r o d u c t s and Chemicals, I n c . : Aquamine 401 C u r i n g Agent: F o r m u l a t i o n 1
  • 70.
    Enamels 61 Anquamixe-401/Sol id R e s i n D i s p e r s i o n 2 :1 W h i t e -Gloss Enamel P a r t A: Lbs G-a 1s Epi -Rez 3520-WY-55 Epoxy Res1n (She1 1) 5 5 7 . 4 6 1 . 2 6 Water 4 5 . 1 5 . 4 1 P a r t B: Anquamine 401 C u r i n g Agent ( A i r Products) 7 2 . 5 7 . 9 3 Dowanol PM S o l v e n t (00,) Dowanol EPh S o l v e n t (Dow) Defoamer T i Pure R960 (DuPont) G1a c i a1 A c e t i c A c i d ( A i r Products) Water 2 6 . 0 3 . 4 2 1 7 . 0 1 . 8 5 4 . 0 0 . 5 0 2 2 7 . 7 6 . 8 2 2 . 0 0 . 2 3 1 0 5 . 0 1 2 . 5 8 T y p i c a l P r o p e r t i e s : W t S o l i d s ( % ) : 7 4 . 2 6 Resin S t o i c h i o m e t r y : 1 . 5 8 : l Volume Sol i d s (%) : 4 3 . 0 3 VOC ( l b / g a l ) : 1 . 2 6 PVC ( % I : 1 5 . 8 5 VOC ( g / l ) : 151 White Gloss Enamel P r o p e r t i e s : Pot L i f e , h r : >6 Gloss, 60 spec, 1 day: >90 Gloss, 60 spec, 4 w k : > 9 0 M i x R a t i o : 2 : l Mixed V i s c o s i t y , cP: 360 Tack Free Time, h r : 1 Hard D r y Time, h r : 6-8 P e n c i l Hardness, o v e r n i g h t : HB P e n c i l Hardness, 7 days: H Cross Hatch Adhesion: 5 1/8" Mandrel Bend: Pass D i r e c t Impact Resistance, in-1 b s . : 60 Reverse Impact Resistance, i n - l b s . : 20 Taber Abrasion, mg loss/lOOO c y c l e s : 9 0 VOC, l b / g a l : 1 . 8 Volume Sol i d s , '%: 4 3 PVC, %: 1 6 . 5 SOURCE: A i r P r o d u c t s and Chemicals, I n c . : Anquamine 401 C u r i n g Agent : Formul a t i on 2
  • 71.
    Enamels-Baking 63 Clear BakeCoatins Pounds Gal l o n sMateri a1 : _ _ _ ~ Epi -Rez 3551-WY-43 Resi n 617.04 68.56 Ektapro EEP 16.14 2.04 B e e t l e 80 188.87 20.87 Water 71 .OS 8.53 Typical Coating P r o p e r t i es : Add under a g i t a t i o n : T o t a l Weight Solids, %: 51.8 T o t a l Volume S o l i d s , %: 47.4 Pounds/Gallon: 8.93 Epoxy/Urea, based on s o l i d s , %: 60/40 V o l a t i l e Organic Compounds (VOC): Pounds/Gallon: 1.47 Grams/Li t e r : 176 V i s c o s i t y , #4 Ford Cup, seconds: 60-70 Dry F i l m Thickness: 0.7 m i l Substrate: Bonderite 1000 Bake Schedule a t 350F, minutes: 20 Pencil Hardness: 6H Reverse Impact, i n . l b s . : 160 M€K Double Rubs: 100 Typical F i l m Properties: S t a r t i n g Formulation No. 2503: Epi-Rez 3551-WY-43 Resin Phenol ic Clear Bake Coating Pounds Gal l o n sMateri a1 : Epi -Rez 3540-WY-55 Resin 439.6 48.07 _ _ _ ~ Methyl I s o b u t y l Ketone 98.8 14.81 Dei oni zed Water 98.8 11.85 S i l w e t L-7604 S u r f a c t a n t 2.4 0.28 Santol i n k EP-560 193.3 21.15 Dimethylethanolamine 19.1 2.54 Syntex 3981 Accelerator 9.1 1.30 T y p i c a l Coating P r o p e r t i e s : T o t a l Weight S o l i d s , %: 46.8 T o t a l Volume S o l i d s , %: 42.7 Pounds per Gallon: 8.61 Epoxy/Phenol ic, sol i d s : 60/40 Percent C a t a l y s t , Active, on Resins S o l i d s : 0.5 V o l a t i l e Organic Compounds (VOC): Pounds/Gallon: 2.90 Grams/Li t e r : 348 V i s c o s i t y , B r o o k f i e l d , #5 Spindle a t 50 RPM, cps: 1,200 Dry F i l m Thickness: 0.5 m i l s Substrate: Bonderite 1000 Bake Schedule: 10 minutes a t 400F Pencil Hardness: 6H Reverse Impact, i n . l b s . : 160 MEK Resistance, double rubs: 100 Typical F i l m Properties: S t a r t i n g Formulation No. 2504: Epi-Rez 3540-WY-55 Resin SOURCE: S h e l l Chemical Co.: S t a r t i n g Formulations
  • 72.
    64 Water-Based PaintFormulations Clear H i q h Gloss, Bakina F i n i s h Materi a1 : Lbs. Cymel 303 premi x--combi ne in t h e f o l l o w i n g o r d e r : Cymel 303 57.6 Isopropanol 4.5 Nacure 2500-X 4 . 5 T r i e t h y l a m i n e 0.6 Water 28.8 Add i n f o l l o w i n g order w i t h a g i t a t i o n : Spensol L51 768.1 Cymel 303 Premix 96.0 Aerosol OTS 5 . 4 Lodyne S107B 5.4 Byk 301 3.1 Cure f o r 2 hours a t 250F o r 30 minutes a t 300F. A n a l y s i s : R a t i o o f Spensol L51 t o Cymel 303: 80:20 Percent S o l i d s , Weight: 33.8 Percent S o l i d s , Volume: 30.1 VOC ( e x c l u d i n g water): Grams/Li t e r : 189 Pounds/Gallon: 1.6 Formulation 2061-40D B l u e Metal 1ic Urethane Enamel M a t e r i a l : Lbs. Component A--add i n f o l l o w i n g order w i t h a g i t a t i o n : Spensol L51 707.9 Premix t h e f o l l o w i n g two m a t e r i a l s , then add: A1umi num Paste #E2255 30.0 Water 31 .2 Add : Aurasperse W4123 92.0 Surfynol 104H 4.0 Lodyne 51076 1.5 Component B: XAMA-7 7.4 NOTE: Add t h e above Component B t o Component A p r i o r t o A n a l y s i s : t i o n and mix w e l l f o r 5 t o 10 minutes. Percent Sol i d s , Weight : 31 .8 Percent S o l i d s , Volume: 28.4 V i s c o s i t y @ 25C, #2 Zahn, Secs.: 25-30 VOC ( e x c l u d i n g w a t e r ) : Grams/Liter: 408 pH: 8.0-8.5 Pounds/Gallon: 3 . 4 Formulation 2099-19 Gals. 5.76 0.68 0.55 0.10 3.46 87.88 10.55 0.63 0.56 0.38 Gals. 81 .oo 2.34 3.75 11.50 0.50 0.16 0.75 appl ica- SOURCE: Reichhold Chemicals, I n c . : Spensol L: Formulations
  • 73.
    Enamels-Baking 65 E xp e r i r e n t a l Water-Reducible Polyester Gloss White Baking Enamel Usina Halox SZP-391 Grind: W/R Polyester 72-7203 DMEA Cyme1 303 Lbs./lOO Gals. Gms/Liter 170.0 204.0 10.0 12.0 50.0 60.0 Premix t h e next two raw m a t e r i a l s before adding. n-Butyl Alcohol Dow Corning 14 R-902 Ti02 Halox SZP-391 Deionized Water High Speed Disperse t o 7 Hegman g r i n d . Letdown : W/R Polyester 72-7203 DMEA n-Octyl Alcohol Troysol LAC n-Butyl Alcohol Deionized Water Mix u n t i l uniform - Do not aerate! Hold f o l l o w i n g f o r v i s c o s i t y adjustment. 8.0 9.6 0.8 I . o 225.0 275.0 15.0 18.0 50.0 60.0 100.0 120.0 15.0 18.0 1.o 1.8 1.5 1.8 10.0 12.0 325.0 390.0 Deionized Water 55.0 66.0 Formula Constants: % P i gment/Wt .: 23.16 % Pigment/Vol .: 7.25 % Solids/Wt.: 48.24 Formula P r o p e r t i e s : Density 1bs. /gal .: 10.36 Density g/L: 1,249 Visc. #2 Zahn (sec. % S o l i d s / V o l . : 33.12 pH @ R.T.: 8.5-9.0 % PVC: 21.85 VOC, l b s . / g a l . : 2.03 VOC, g/L: 304.5 SOURCE: Halox Pigments: Suggested Formulation PEG39 : 50-60
  • 74.
    66 Water-Based PaintFormulations Waterborne A c r y l i c Bake Enamel The WR-17 study was conducted t o demonstrate t h e improved corrosion resistance afforded a waterborne system by choosing a more hydrophobic c a t a l y s t , Nacure 155 (DNNDSA), over a more h y d r o p h i l i c c a t a l y s t , K-Cure 1040 (p-TSA). Free a c i d c a t a l y s t , r a t h e r than t h e blocked versions, were used i n t h i s study, since t h e formula already contained a n e u t r a l i z i n g amine. A summary o f the formulation, i t s physical p r o p e r t i e s and t e s t r e s u l t s are l i s t e d below. G r i nd Composition : Titanox 2020 Acrysol WS-68 2-Butoxyethanol n-Butanol DMEA 0.1. Water (Pebble M i l l Grind t o 7 t on Hegman) Letdown Composi t ion : Acrysol WS-68 n-Butanol Hexamethoxymethylmelamine 2-Butoxyethanol *DMEA (10% i n water) * O . I . Water *Used t o a d j u s t pH and v i s c o s i t y C h a r a c t e r i s t i c s : P i gment/Bi nder : 40/60 Acryl ic/Mel ami ne: 80/20 Total S o l i d s , %: 37.7 Total Resin Solids, %: 22.6 Wt./gal. C 25C ( l b / g a l ) : 9.65 V.O.C. (Measured) l b . / g a l . : 1.84 A p p l i c a t i o n and Cure: Substrate: Bonderite 1000 ( i r o n phosphated CRS) Cure Schedule: 15' a t 149C (300F) F i 1m Thickness : 0.7-0.8 m i 1 Wt% 15.07 3.97 0.67 0.63 0.90 4.69 43.63 0.54 4.51 3.90 2.20 20.10 F i l m Properties: Control K-Cure 1040 Nacure 155 p-TSA DNNDSA Pencil Hardness H-2H Tukon Hardness, KNH25 13.2 MEK Rubs (2X) 24 Impact Resistance, ( i n - l b s . ) Reverse 90-100 O i r e c t 40-50 Crosshatch Adhesion, % Loss 100 S a l t Spray, 150 h r s . (ASTM 8117) mm Creep/Blister: 6-7mm/10 6 H-2H H-2H 13.2 13.0 42 50 20-1 30 90-1 00 30-40 30-40 100 100 7mm/lO 3-4mm/ 0 SOURCE: King I n d u s t r i e s : Formulation WR-17
  • 75.
    Enamels-Baking 67 Water ReducibleP o l v e s t e r Baking Enamel I n t h i s s t u d y Nacorr c o r r o s i o n i n h i b i t o r s were i n c o r p o r a t e d i n t o a pigmented waterborne p o l y e s t e r system c r o s s l i n k e d w i t h a h i g h -NH t y p e melamine r e s i n . The Nacorrs were added a t a l e v e l o f 3%, based on t h e t o t a l f o r m u l a w e i g h t . S i n c e t h e Nacorrs a l s o f u n c t i o n as d i s p e r s i n g agents, t h e r e i s a d e f i n i t e advantage i n in c o r p o r a t i ng them in t o t h e d i s p e r s i ng stage. G r i n d (Pebble M i l l ) : T i -Pure R-960 Cargi 11 72-7203 2-Butoxyethanol Nacorr Water DMEA Letdown : Cargi 11 72-7203 DMEA Cyme1 327 S i l w e t 7605 (10% i n 2-butoxyethanol) Water C o n t r o l Nacorr 24.00 24.00 18.00 17.81 4.00 2.50 ---- 3.00 1.31 0.69 6.00 6.19 1.oo 1 .69 6.67 6.67 1.oo 1.oo 37.33 37.14 ---- ---- C h a r a c t e r i s t i c s : C o n t r o l Nacorr Pol yester/Mel ami ne R a t i o 75/25 75/25 Pigment, % 24 24 T o t a l Resin S o l i d s , % by weight 24 24 A d d i t i v e l e v e l , % based on t o t a l weight o f p a i n t -- 3.0 F i l m P r o p e r t i e s : Pigment/Bi nder R a t i o 1/ I 1/ I S u b s t r a t e : B o n d e r i t e 1000 I r o n Phosphated CRS Cure: 10 minutes/300F (149C) F i l m Thickness: 16-21 microns P e n c i l Hardness Tukon Hardness KHN25 C o n t r o l N-1151 N-1351 2H-3H 2H-3H H-2H 16.6 17.7 11 .o MEK Rubs (2X) 65 Impact ( i nch 1bs. ) , Reverse 5-10 D i r e c t 70-80 Gloss, 60 9 1 . 4 S a l t Spray, 408 h r s . 13/D3 F i l m P r o p e r t i e s : S u b s t r a t e : B o n d e r i t e 1000 I r o n Phosphated Cure: 10 minutes/250F (121C) F i l m Thickness: 16-21 microns C o n t r o l Penci 1 Hardness H-2H Tukon Hardness KHN25 11.1 MEK Rubs (2x1 12 Impact ( inch 1bs. ) , Reverse (5 D i r e c t 60-70 Gloss, 60 93.3 S a l t Spray, 408 h r s . 13/MD4 SOURCE: K i n g I n d u s t r i e s : Nacorr WR-18 64 5-10 60-70 90.6 2/10 CRS N-1151 H-2H 12.2 13 <5 60-70 94.7 2/10 24 5-10 60-70 92.2 2/F8 N-1351 HB-F 6 . 7 12 5-10 50-60 93.3 3F/2
  • 76.
    68 Water-Based PaintFormulations Spensol L54 White Bakina Enamel ____Materi a1 : Speneol L54 Water Ammonium Hydroxide Surfynol GA Aerosol OT-75 Foamki 11 639AA Titanox 2101 Lbs. 87.3 75.0 1.9 4.4 2.3 1.1 200.0 Pebble o r sandmill g r i n d the above m a t e r i a l s t o 7+ N . S . Letdown : Spensol L54 536.9 Gals. 10.00 9.00 0.25 0.50 0.25 0.15 5.85 61.50 Premix t h e next f o u r materials, then add under good a g i t a t i o n . Cyme1 385 DMEA Isopropanol Water Add t h e f o l l o w i n g under good a g i t a t i o n : Surfynol 104H Versa-Flow 102 Bake schedule: 10 minutes a t 300F (150C). Analysis: Pigment Volume Concentration, Percent: 18 Pigment/Binder Ratio: 0.8/1 .O Percent Solids, Weight: 44.7 Percent Solids, Volume: 32.6 V i s c o s i t y @ 25C, #4 Ford, Secs. : 30 Pounds/Gal l o n : 10.3 VOC ( e x c l udi ng water) : Grams/Liter: 240 Pounds/Gal 1on : 2 Gloss (60): 60-70 pH: 8.3+-0.3 62.1 5.75 1.8 0.25 6.8 1.oo 41.7 5.00 2 . 0 0.25 2.0 0.25 SOURCE: Reichhold Chemicals, I n c . : Spensol L: Formula 2154-598
  • 77.
    Enamels-Baking 69 ?-Component WaterborneSysteE Formulation WR-41 demonstrates t h e improved performance o f a 2-component waterborne system when m o d i f i e d w i t h K-Flex XM-4316, a p o l y e s t e r - u r e t h a n e d i s p e r s i o n . A t b o t h NCO/OH r a t i o s , improve- ments were made i n gloss, M E K r e s i s t a n c e , and f l e x i b i l i t y . NCO/OH R a t i o : 1 . 1 A c r y l i c / P U - D i s p e r s i o n : 80/20 Component A: Emulsion E-3275 K-F1 ex XM-4316 Sodium N i t r i t e (5% aq) Proglyde DMM Edaplan LA 402 S i l w e t 7001 (5% aq) S i l w e t 7605 (25% aq) S i l w e t 7604 (25% aq) Dimethylethanolamine Component 0: Bayhydur XP-7063 Formulation C h a r a c t e r i s t i c s : N o n v o l a t i l e , t h e o r e t i c a l , %: 46.3 T h e o r e t i c a l VOC, g/L, ( l b / g a l l o n ) : 60, ( 0 . 5 ) Formulation Propert Gloss 60, %: 95 20, %: 69 Koenig Hardness Pencil Hardness: es, A i r - D r y 20-25C, 2 weeks: s e c ) : 69 H-2H Knoop Hardness: 2 . 4 MEK Double Rubs: 80 Impact, D i r e c t , i n c h . l b . : >160 Impact, Reverse, i n c h . l b . : >160 W t % 71 .38 17.40 0 . 0 0 0 . 8 9 0.07 0 . 0 0 0.25 0.25 0.73 9.03 Formulation P r o p e r t i e s , Bake 8OC 20 min. Post-cure 20-25C, 2 weeks : Substrate: Bonderite 1000 c o l d r o l l e d s t e e l F i l m thickness, micron (mi 1 .) : 32+-2 (1.3+-0.1) NCO/OH R a t i o : 1 . 1 Knoop Hardness: 3.7 Gloss 60, %: 96 MEK Double Rubs: 120 Koenig Hardness ( s e c ) : 89 Impact, Reverse, i n c h x l b . : 160 Pencil Hardness: 2H 20, %: 66 Impact, Forward, i n c h x l b . : ,160 Formulation Preparation: a g i t a t i o n f o r approx. 5 minutes. SOURCE: King I n d u s t r i e s : P r e l i m i n a r y Formulation WR-41 Add component B t o component A under low shear mechanical
  • 78.
    Exterior Paints andRelated Products 71 E x t e r i o r F l a t House P a i n t w i t h ZnO I n q r e d i e n t s : Pi gment G r ind : Water Ucar Pol yphobe 9831 Rheology Modi f ie r Ammonium Hydroxide, 28% Aqueous S o l u t i o n P r o x e l GXL C o l l o i d 226/35 C o l l o i d 640 T r i t o n N o n i o n i c S u r f a c t a n t X-100 Propylene G1y c o l Potassium T r i p o l y p h o s p h a t e (KTPP) T i -Pure R-706 417-W Z i n c Oxide Minex 4 N y t a l 300 ___.Pounds 236.2 9 . 5 1 . 8 2.0 8 . 5 1 . 9 3 . 3 25.9 1 . 5 225.0 2 5 . 0 1 2 5 . 9 5 0 . 0 Letdown : Ucar L a t e x 625 426.4 B u t y l C a r b i t o l S o l v e n t 1 0 . 7 C o l l o i d 640 1 . 9 Skane M-8 2 . 2 Ammonium Hydroxide, 28% Aqueous S o l u t i o n 0 . 9 P a i n t P r o p e r t i e s : Pigment Volume C o n c e n t r a t i o n , %: 40.0 Volume S o l i d s , %: 38.0 Weight S o l i d s , %: 5 5 . 6 Weight p e r G a l l o n , l b : 11.59 Stormer, KU: 95 I C I , P o i s e : 1 . 1 pH Value: 8 . 9 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Age S t a b i l i t y , 120F, weeks passed: 2 F i 1m P r o p e r t ies : C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.969 R e f l e c t a n c e , %: 9 1 . 9 Sheen, 8 5 : 8 Wet Adhesion, g l o s s a l k y d : E x c e l l e n t Flow and L e v e l i n g : Good Sag R e s i s t a n c e , m i l s : >12 Gal l o n s 28.30 1 . 1 0 0 . 2 0 0.20 0 . 8 0 0.30 0 . 4 0 3.00 0 . 1 0 6 . 6 0 0 . 6 0 5 . 8 0 2 . 1 0 48.40 1 . 4 0 0.30 0.30 0.10 SOURCE: Ucar Emulsion Systems: Ucar Polyphobe 9831 Rheology M o d i f i e r : F o r m u l a t i o n Suggestion E-2483
  • 79.
    72 Water-Based PaintFormulations E x t e r i o r F l a t House P a i n t w i t h ZnO I n q r e d i e n t s : Pigment Grind: Water Ucar Polyphobe 102 Rheo. Mod. Ammonium Hydroxide, 28% Aqueous S o l u t i o n Proxel GXL Col 1o i d 226/35 C o l l o i d 640 T r i t o n Nonionic S u r f a c t a n t X-100 Propylene G1y c o l Potassium Tripolyphosphate (KTPP) T i -Pure R-706 417-W Zinc Oxide Minex 4 N y t a l 300 Pounds 227.2 18.5 1.8 2 . 0 8.5 1.9 3.3 25.9 1.5 225.0 25.0 125.9 50.0 Letdown : Ucar Latex 625 426.4 Ucar F i l m e r I B T 10.7 C o l l o i d 640 1.9 Skane ME 2.2 Ammonium Hydroxide, 28% Aqueous S o l u t i o n 0.9 Pai n t Propert ies : P i gment Vol ume Concentration, %: 40.0 Volume Solids, %: 38.0 Weight S o l i d s , %: 55.6 V i s c o s i t y , equi 1ib r a t e d : Stormer, KU: 98 I C I , Poise: 1.5 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Aged S t a b i l i t y , 120F, weeks passed: 2 F i l m P r o p e r t i e s : Contrast R a t i 0, 6 - m i 1 wet drawdown : 0.968 Reflectance, %: 91.9 Sheen, 85: 7 Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass Wet Adhesion, g l o s s alkyd: E x c e l l e n t Gal l o n s 27.30 2.10 0.20 0.20 0.80 0.30 0.40 3.00 0.10 6.60 0.60 5.80 2.10 48.40 1.40 0.30 0.30 0.10 SOURCE: Ucar Emulsion Systems: Ucar Latex 625: Formulation Suggestion E-2463
  • 80.
    Exterior Paints andRelated Products 73 E x t e r i o r Gloss White I n q r e d i e n t s : Pigment Grind: Water Ammonium Hydroxide, 28% Aqueous S o l u t i o n Sol vent 142HT Tamol 165 Potassium Tripolyphosphate (KTPP) T r i t o n Nonionic S u r f a c t a n t CF-10 Proxel GXL Byk 023 T i -Pure R-706 Letdown : Ucar Latex 481 Solvent 142HT Byk 025 B u t y l C a r b i t o l Solvent Water Ammonium Hydroxide, 28% Aqueous S o l u t i o n Ucar Polyphobe 9831 Rheology Modi f ie r P a i n t P r o p e r t i e s : Pigment Volume Concentration, %: 19.8 Volume S o l i d s , %: 33.9 Weight S o l i d s , %: 45.8 Weight per Gallon, l b : 10.28 Stormer, KU: 95 I C I , Poise: 1.8 pH Value: 9-9.5 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 0-1 Heat Age S t a b i l i t y , 120F, weeks passed: 4 V o l a t i l e Organic Content, g/L: 120 F i l m P r o p e r t i e s : Gloss, 60: 77 Gloss, 20: 34 F1ow and Level ing : Excel 1e n t Dry-to-Touch, hours: 2 Recoat, hours: 4-6 Water/Bl is t e r Resi stance: Good Pounds 112.0 1.o 10.0 13.7 0.5 3.0 2.0 2.5 225.0 519.0 10.0 2.0 26.0 8 5 . 6 1.o 14.8 G a l l o n s 13.40 0.10 1.50 1.50 0.03 0.40 0.20 0.30 6.80 58.60 1.50 0.30 3.30 10.10 0.10 1.70 SOURCE: Ucar Emulsion Systems: Ucar Polyphobe 9831 Rheology Modi f ie r : Formulation Suggestion E-2482
  • 81.
    74 Water-Based PaintFormulations E x t e r i o r House P a i n t Materi a1 : Grind: Water Nuosept 95 (Nuodex) Tamol 731 (Rohm and Haas) Igepal CO-630 (GAF) Ti-Pure R-902 (DuPont) Beaverwhite 325 Talc (Cyprus) 325 W.G. Mica (Unimin) FCA (Foam Control Agent) Premix and add: Ethylene Glycol Texanol (Eastman) Natrosol Plus 330 PA (Aqualon) Letdown : Water 248-5809 (McWhorter) FCA (Foam Control Agent) Water Properties: Pigment Volume Content, %: 31.2 % N o n v o l a t i l e (by weight): 54.6 % N o n v o l a t i l e (by volume): 39.3 VOC. g / l : 126 Stormer Viscosity. K.U.: 90+-5 I C 1 V i s c o s i t y , Poise: 1+-0.1 Gloss a t 60, %: 0-5 Recommended Products: Agitan 260, 315 o r 731 -Lbs 101.6 12.20 1.5 0.16 7.5 0.82 3.4 0.38 213.3 6.23 111.7 1.07 25.4 4.99 4.5 0.20 23.6 2.54 5.9 0.74 4.0 0.36 125.0 15.01 437.8 48.03 3.0 0.39 50.0 6.10 SOURCE: King I n d u s t r i e s : Formulation WR-39: FCA's f o r Trade Sales P a i n t
  • 82.
    Exterior Paints andRelated Products 75 E x t e r i o r House P a i n t - T i n t Base Inaredients: Pigment Grind: Water Ucar Polyphobe 102 Rheo. Mod. Ammoni um Hydroxide, 28% Aqueous Sol u t i on Proxel GXL Tamol 1124 C o l l o i d 640 T r i t o n Nonionic Surfactant N-101 Propylene Glycol Tronox CR-828 Minex 4 H y d r i t e F l a t D Pounds 209.6 19.6 1.8 2.0 5 . 0 1.9 3.2 25.9 150.0 125.0 75.0 Gal 1ons 25.20 2.10 0.20 0.20 0.50 0.30 0.40 3.00 4.40 5.80 3.50 Letdown : Ucar Latex 625 455.9 51.80 Ucar Filmer IBT 11.4 1.40 C o l l o i d 640 1.9 0.30 Troysan Polyphase AF-1 7.3 0.80 Ammonium Hydroxide, 28% Aqueous S o l u t i o n 0.9 0.10 P a i n t Properties: Pigment Volume Concentration, %: 35.8 Volume Solids, %: 38.0 Weight Solids, %: 53.2 V i s c o s i t y , e q u i l i b r a t e d : Stormer, KU: 91 I C I , poise: 1.4 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Aged S t a b i l i t y , 120F, weeks passed: 2 F i l m Properties: Contrast Ratio, 6-mil wet drawdown: 0.956 Reflectance, %: 90.1 Sheen, 85: 7 Color Acceptance: E x c e l l e n t Color F l o a t : Good Wet Adhesion, 4-hr: E x c e l l e n t Flow and Leveling, ASTM D-4062: 8 F i l m B u i l d , s q . f t . / g a l . : 411 Low Temperature Coalescence: sealed: 10 unsealed: 10 SOURCE: Ucar Emulsion Systems: Ucar Latex 625: Formulation Suggestion E-2460
  • 83.
    76 Water-Based PaintFormulations E x t e r i o r Senialoss ~ _ _ _Pounds Gal 1onsI n q r e d ie n t s : Pigment Grind: Water Nuosept 95 Propylene G1ycol Tamol 1124 Ammonium Hydroxide (28% Aqueous S o l u t i o n ) T r i t o n Nonionic S u r f a c t a n t N-57 C o l l o i d 653 T i -Pure R-700 Letdown : Water Ucar Pol yphobe 102 Rheology Modi f ie r Ucar Latex 2300 Ucar F i l m e r IBT Col l o i d 653 Troysan Polyphase AF-1 T r i t o n Anionic S u r f a c t a n t GR-7M P a i n t P r o p e r t i e s : Pigment Volume Concentration, %: 22.0 Volume Solids, %: 32.6 Weight S o l i d s , %: 47.2 Weight per Gallon, l b : 10.43 Stormer, KU: 99 I C I , Poise: 1 .26 pH Value: 8.0 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 7 F i l m P r o p e r t i e s : Gloss, 60: 78.3 Gloss, 20: 39.6 Contrast R a t i o , 6-mil wet drawdown: 0.964 Reflectance, %: 91.8 Scrub Resistance, c y c l e s passed: 161 150.0 18.96 2.3 0.25 60.5 7.00 7.4 0.75 2.0 0.25 2.1 0.25 1.9 0.25 250.0 7.16 91.5 10.99 13.1 1 .so 447.7 50.88 11.2 1.41 2.8 0.37 7.3 0.75 1.1 0.13 SOURCE: Ucar Emulsion Systems: Formulation Suggestion E-2263
  • 84.
    Exterior Paints andRelated Products 77 E x t e r i o r Semisloss Formulation I n q r e d i e n t s : P igment G r ind: Water Ucar Polyphobe 102 Rheology M o d i f i e r Ammonium Hydroxide, 28% Aqueous S o l u t i o n Propylene Glycol Troysan 586 Tamol 1124 C o l l o i d 643 T r i t o n Nonionic Surfactant N-57 Tronox CR-828 Polygloss 90 Pounds 190.0 17.4 1.8 60.5 1.8 5.3 1.8 2.1 250.0 25.0 Letdown: Water 1 5.5 Ucar Polyphobe 102 Rheology M o d i f i e r ) Premix 4.4 NeoCar Latex 2300 474.4 C o l l o i d 643 1.8 Ucar Filmer I B T 15.8 Troysan Polyphase AF-1 7.4 T r i t o n Anionic Surfactant GR-7M 1 . 1 Ammonium Hydroxide, 28% Aqueous S o l u t i o n 1.8 Gal 1ons 22.80 2.00 0.23 6.99 0.19 0.54 0.23 0.25 7.50 1.15 0.66 0.51 53.61 0.23 1.99 0.74 0.13 0.23 Note: If wet adhesion i s desired, blending w i t h an a c r y l i c r e s i n , such as Ucar Latex 625, i s recommended. Pai n t P r o p e r t ies : PVC, %: 23.6 Volume Solids, %: 38.7 Weight Solids, %: 52.6 Weight per Gallon, l b : 10.68 Stormer, KU: 99 I C I , poise: 1.5 pH Value: 8.7 Freeze-Thaw S t a b i l i t y , 3 cycles: Pass Heat-Aged S t a b i l i t y , 4 weeks a t 140F: pass Fi 1m Properties : Reflectance, %: 92.3 Gloss, 20: 19 Gloss, 60: 59.5 Flow and Leveling: Exc Color Acceptance: Exc SOURCE: Ucar Emulsion Systems: NeoCar Polymers: Formulation Suggest ion E-2264
  • 85.
    78 Water-Based PaintFormulations E x t e r i o r T i n t Base Formulation Inqredient s : Pigment Grind: Water Ucar Polyphobe 102 Rheology Modi f ie r Ammonium Hydroxide, 28% Aqueous S o l u t i o n Troysan 586 Tamol 1124 C o l l o i d 640 T r i t o n Nonionic S u r f a c t a n t N-101 Propylene G1ycol Tronox CR-828 Minex 4 H y d r i t e F l a t D Pounds 197.4 15.2 1.8 2.0 5.0 1.9 3.2 25.9 150.0 125.0 75.0 Letdown : Water 3.8 Ucar Latex 625 319.2 Ucar Latex 461 145.5 Ucar F i l m e r IBT 11.4 C o l l o i d 640 1.9 Troysan Polyphase AF-1 7 . 3 Ammonium Hydroxide, 28% Aqueous S o l u t i o n 0.9 Pai n t Propert ies : Pi gment Vol ume Concentrat ion, %: 35.8 Volume S o l i d s , %: 38.0 Weight per Gallon, l b : 10.9 Stormer, KU: 83 I C I , Poise: 0.95 pH Value: 9.6 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Age S t a b i l i t y , 12OF, weeks passed: 2 R a t i o o f Ucar Latexes 625:461: 70:30 F i lrn P r o p e r t i e s : Sheen. 85: 9 . 2 Gal l o n s 23.7 1.7 0 . 3 0.2 0.5 0.3 0.4 3.0 4.4 5.8 3.5 0.5 36.3 16.9 1.4 0.3 0.8 0.1 Contrast Ratio, 6-mil wet drawdown: 0.952 Dry Adhesion ( u n t r e a t e d aluminum, galvanized s t e e l , a1kyd Wet Adhesion ( u n t r e a t e d aluminum, galvanized s t e e l , a l k y d B1is t e r i ng ( u n t r e a t e d a1umi num, g a l vani zed s t e e l , a1kyd and l a t e x c h a l k ) : Exc and l a t e x chalk, g l o s s a l k y d ) : Exc and l a t e x c h a l k ) : Exc SOURCE: Ucar Emulsion Systems: Ucar Latex 461: Formulation E-2474
  • 86.
    Exterior Paints andRelated Products 79 E x t e r i o r T r i m F o r m u l a t i o n Modi f ied V i nvl A c r v l ic P a i n t I n q r e d i e n t s : P i ament G r i nd: WaTer Ucar Polyphobe 102 Rheology Modi f ie r Ammonium Hydroxide, 28% Aqueous S o l u t i o n Propylene G l y c o l Nuosept 95 Tamol 1124 C o l l o i d 643 T r i t o n N o n i o n i c S u r f a c t a n t N-57 Tronox CR-828 P o l y g l o s s 90 Letdown : Water Ucar Polyphobe 114 Rheology Modi f ie r B u t y l C a r b i t o l S o l v e n t Ucar F i l m e r I 8 T Ucar Latex 3796 Ucar Latex 633G C o l l o i d 643 Troysan Polyphase AF-1 Byk 346 Ammonium Hydroxide, 28% Aqueous S o l u t i o n Pai n t P r o p e r t ias : Pigment Volume C o n c e n t r a t i o n , %: 24.2 Volume S o l i d s , %: 35.0 Weight p e r G a l l o n , l b : 10.7 Stormer, KU: 96 I C I , P o i s e : 1.2 pH Value: 7.6 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Age S t a b i l i t y , 120F, weeks passed: 2 R a t i o o f Ucar Latexes 379G:6336: 70:30 F i l m P r o p e r t i e s : Gloss, 60: 46 Gloss, 20: 10 C o n t r a s t R a t i o , 6-mil wet drawdown: 0.967 Reflectance, %: 91.8 B l o c k Resistance: 8 Pounds 98.5 19.3 1.8 59.6 2.3 7.3 1 . 9 2 . 1 246.3 24.6 78.0 6 . 5 20.5 10.2 316.1 162.0 2 . 8 7.2 1 . 1 1 . 8 Gal 1ons 11.8 2.2 0.3 6 . 9 0.2 0.7 0 . 3 0.2 7.2 1 . 1 9 . 4 0 . 7 2.6 1 . 3 34.9 18.4 0.4 0.7 0 . 1 0 . 3 Dry Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a1kyd Wet Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a l k y d B l i s t e r i n g ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a l k y d and l a t e x c h a l k ) : Exc and l a t e x c h a l k , g l o s s a l k y d ) ; Exc and l a t e x c h a l k ) : Exc SOURCE: Ucar Emulsion Systems: Ucar L a t e x 0336: F o r m u l a t i o n E-2471
  • 87.
    80 Water-Based PaintFormulations E x t e r i o r T r i m Formulation I n g r e d i e n t s : Pigment Grind: Water Ucar Pol yphobe 102 Rheology Modi f ie r Ammonium Hydroxide, 28% Aqueous S o l u t i o n Propylene Glycol Troysan 586 Tamol 1124 C o l l o i d 643 T r i t o n Nonionic S u r f a c t a n t N-57 Tronox CR-828 Polygloss 90 Letdown : Water NeoCar Latex 2300 Ucar Latex 6336 C o l l o i d 643 Ucar Filmer IBT Troysan Polyphase AF-1 T r i t o n A n i o n i c S u r f a c t a n t GR-7M Ammonium Hydroxide, 28% Aqueous S o l u t i o n P a i n t P r o p e r t i e s : Pigment Volume Concentration, %: 24.0 Volume S o l i d s , %: 35.5 Weight per Gallon, l b : 1 0 . 7 Stormer, KU: 93 I C I , Poise: 1 . 4 pH Value: 8.9 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Age S t a b i l i t y , 12OF, weeks passed: 2 Pounds 190.6 21.8 1 . 8 60.5 1 . 8 5.3 1 . 8 2 . 1 250.0 25.0 7.2 365.4 107.8 1.8 15.8 7 . 4 1 . 1 1 . 8 Gal 1ons 22.9 2.5 0.3 7 . 0 0.2 0.5 0.3 0.2 7 . 3 1.1 0.9 41.3 12.3 0.3 2.0 0.8 0 . 1 0.3 F i l m P r o p e r t i e s : Gloss, 60: 77 Gloss, 20: 28 Contrast R a t i o , 6-mil wet drawdown: 0.977 Reflectance, %: 92.2 Block Resistance, 1-week d r y , RT: 8 Dry Adhesion ( u n t r e a t e d aluminum, galvanized s t e e l , Wet Adhesion ( u n t r e a t e d aluminum, galvanized s t e e l , 61 is t e r i ng ( u n t r e a t e d a1umi num, galvanized s t e e l , a1kyd a l k y d c h a l k ) : Exc a l k y d chalk, g l o s s a l k y d ) : Good c h a l k ) : Good SOURCE: Ucar Emulsion Systems: Ucar Latex 6336: Formulation E-2472
  • 88.
    Exterior Paints andRelated Products 81 E x t e r i o r T r i m F o r m u l a t i o n I n a r e d i e n t s : Pigment G r i n d : Water Ucar Polyphobe 102 Rheology M o d i f i e r Ammoni um Hydroxi de, 28% Aqueous Sol u t i on Propylene G1y c o l Nuosept 95 Tamol 1124 C o l l o i d 643 T r i t o n N o n i o n i c S u r f a c t a n t N-57 Tronox CR-828 P o l y g l o s s 90 Pounds 98.5 1 9 . 3 1 . 8 5 9 . 6 2 . 3 7 . 3 1 . 9 2 . 1 2 4 6 . 3 2 4 . 6 Letdown : Water B u t y l C a r b i t o l S o l v e n t Ucar F i l m e r I 8 T Ucar L a t e x 626 Ucar L a t e x 471 C o l l o i d 643 Troysan Polyphase AF-1 Byk 346 Ammonium Hydroxide, 28% 47.2 2 0 . 5 1 0 . 2 372.5 129.4 2 . 8 7 . 2 1 . 1 Aqueous Sol u t i on 1 . 8 P a i n t P r o p e r t i e s : Pigment Volume C o n c e n t r a t i o n , %: 2 4 . 2 Volume S o l i d s , %: 35.0 Weight p e r G a l l o n , l b : 10.5 Stormer, KU: 89 I C I , P o i s e : 1 . 5 p H Value: 8 . 8 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Age S t a b i l i t y , 120F, weeks passed: 2 R a t i o o f Ucar Latexes 626:Ucar 471: 70:30 F i 1m P r o p e r t ies : Gloss, 60: 53 Gloss, 20: 15 C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.97 R e f l e c t a n c e , %: 92.2 B l o c k R e s i s t a n c e : 9 G a l l o n s 11 . 8 2 . 2 0.3 6 . 9 0 . 2 0.7 0 . 3 0 . 3 7 . 2 1 . 1 5.7 2.6 1 . 3 42.8 1 4 . 9 0.4 0 . 8 0 . 1 0 . 3 Dry Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a l k y d B l i s t e r i n g ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , and l a t e x c h a l k ) : Exc l a t e x c h a l k ) : Exc l a t e x c h a l k , g l o s s a l k y d ) : Exc Wet Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e SOURCE: Ucar Emulsion Systems: Ucar L a t e x 471: Formu E-2475 a l k y d and , a l k y d and a t i o n
  • 89.
    82 Water-Based PaintFormulations E x t e r i o r White F l a t House P a i n t I n q r e d ients: P igment G r ind: Water Ucar Polyphobe 102 Rheo. Mod. Ammonium Hydroxide, 28% Aqueous S o l u t i o n Proxel GXL Tamol 1124 Col l o i d 640 T r i t o n Nonionic Surfactant N-101 Propylene G1ycol T i -Pure R-706 Minex 4 Nytal 300 Pounds 234.5 19.6 1.8 2.0 5.0 1.9 2.1 25.9 225.0 135.4 75.0 Letdown : Ucar Latex 625 408.6 Ucar Filmer IBT 10.2 C o l l o i d 640 1.9 Troysan Polyphase AF-1 7.3 Ammonium Hydroxide, 28% Aqueous S o l u t i o n 1.8 Paint Properties: Pigment Volume Concentration, %: 42.5 Volume Solids, %: 38.0 Weight Solids, %: 5 5 . 7 V i s c o s i t y , equi 1ibrated: Stormer, KU: 90 I C I , Poise: 1 . 3 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Aged S t a b i l i t y , 120F, weeks passed: 2 F i l m Properties: Contrast Ratio, 6-mil wet drawdown: 0.965 Reflectance, %: 91.9 Wet Adhesion, gloss alkyd: E x c e l l e n t Chalk Adhesion, ASTM #5: G o o d Gal 1ons 28.20 2.30 0.20 0.20 0.50 0.30 0.30 3.00 6.60 6.20 3.20 46.40 1.30 0.30 0.80 0.20 SOURCE: Ucar Emulsion Systems: Ucar Latex 625: Formulation Suggestion E-2459
  • 90.
    Exrenor Paints andRelated Products 83 E x t e r i o r White T r i m House P a i n t I n q r e d i e n t s : P i Qment G r i nd: Water Ucar Polyphobe 102 Rheo. Mod. Ammonium Hydroxide, 28% Aqueous Troy 586 Tamol 1124 C o l l o i d 640 T r i t o n N o n i o n i c S u r f a c t a n t N-57 Propylene G1y c o l T i -Pure R-902 P o l y g l o s s 90 Letdown : Ucar Latex 625 Ucar F i l m e r IBT Pounds 208.1 19.6 S o l u t i o n 1 . 8 2.0 7.4 1 . 9 2.1 60.5 237.5 50.0 Gal 1ons 24.90 2.30 0.20 0.20 0.70 0.30 0.20 7 . 0 0 7.10 2.30 459.3 52.20 11.5 1 .50 C o l l o i d 640 2.8 0.40 Troysan Polyphase AF-1 7.3 0.80 Ammonium Hydroxide, 28% Aqueous S o l u t i o n 0.9 0.10 Byk 346 1 . 1 0.10 P a i n t P r o p e r t i e s : Pigment Volume C o n c e n t r a t i o n , %: 27.0 Volume S o l i d s , %: 34.0 Weight S o l i d s , %: 48.6 V i s c o s i t y , e q u i l i b r a t e d : Stormer, KU: 91 I C I , Poise: 1 . 3 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Aged S t a b i l i t y , 120F, weeks passed: 2 F i l m P r o p e r t i e s : C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.968 R e f l e c t a n c e , %: 9 3 . 4 Gloss, 60: 40 Wet Adhesion, g l o s s a l k y d , 4-hr: E x c e l l e n t Adhesion, 1 week, ASTM D3359 ( w e t ) : a l k y d : 4A aluminum: 5A Chalk Adhesion, ASTM #5: Good B l i s t e r i n g , 24 h r s . : aluminum: 10 a l k y d c h a l k (ASTM #5): 8F Flow and L e v e l i n g , brushed: 7 SOURCE: Ucar Emulsion Systems: Ucar L a t e x 025: F o r m u l a t i o n Suggestion E-2402
  • 91.
    84 Water-Based PaintFormulations Good Q u a l i t y White E x t e r i o r F l a t P a i n t for Masonry I n a r e d i e n t s : P i gment G r i nd : Water C e l l o s i z e Hydroxyethyl C e l l u l o s e QP-15,000 Potassium T r i p o l y p h o s p h a t e (KTPP) Nuosept 95 C o l l o i d 643 T r i t o n N o n i o n i c S u r f a c t a n t N-101 Tamol 850 Ti-Pure R-902 Eagle 417W Snowf 1ake Minex 4 AMP-95 Pounds 199.9 2.5 2.0 1.5 2.0 3.0 1 .o 7.0 220.0 25.0 100.0 131.7 G a l l o n s 24.00 0.22 0.09 0.16 0.26 0.34 0.13 0.71 6.60 0.53 4.44 6.07 Disperse a t h i g h speed f o r 15 minutes. Do n o t exceed 120F. D i s p e r s i o n s h o u l d be 3-4 on Hegman. Letdown : Water 1 127.1 15.26 Propylene G1y c o l ) Premi x 40.0 4.62 C e l l o s i z e Hydroxyethyl C e l l u l o s e ) QP-15,000 ) 2.3 0.20 C o l l o i d 643 2.0 0.26 NeoCar Latex 2300 305.0 34.47 Ucar F i l m e r IBT 13.0 1.64 P a i n t P r o p e r t i e s : PVC, %: 50.0 Volume S o l i d s , %: 35.3 Weight S o l i d s , %: 54.6 Weight p e r G a l l o n , l b : 11.98 Stormer, KU: 88-93 I C I , p o i s e : 0.8-1.0 pH Value: 8.0-8.5 Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass F i l m P r o p e r t i e s : R e f l e c t a n c e , %: 89.4 Gloss, 60: 2 Sheen, 85: 3 C o n t r a s t R a t i o , 3-mil f i l m : 0.970 ASTM Scrub Cycles, w i t h shim F a i l u r e : >3000 SOURCE: Ucar Emulsion Systems: NeoCar Polymers: F o r m u l a t i o n Suggest ion E-2252
  • 92.
    Exterior Paints andRelated Products 85 Good Q u a l i t y White E x t e r i o r F l a t P a i n t f o r Wood I n g r e d i e n t s : Pigment G r i nd: Water C e l l o s i z e Hydroxyethyl C e l l u l o s e QP- Potassium Tripolyphosphate (KTPP) Nuosept 95 C o l l o i d 643 T r i t o n Nonionic Surfactant N-101 Tamol 850 T i -Pure R-902 Eagle 417W Snowf 1ake Minex 4 AMP-95 Pounds 195.8 15,000 2.5 2.0 1.5 2.0 3.0 1.o 7.0 245.0 50.0 70.0 85.0 Gallons 23.50 0.22 0.09 0.16 0.26 0.34 0.13 0.71 7.35 1.07 3.11 3.92 Disperse a t h i g h speed f o r 15 minutes. Do not exceed 120F. Dispersion should be 3-4 on Hegman. Letdown : Water ) 51 .5 6.17 Propylene G1ycol 1 40.0 4.62 C e l l o s i z e Hydroxethyl C e l l u l o s e ) Premix QP-15,OOO 1 2.0 0.17 C o l l o i d 643 2.0 0.26 NeoCar Latex 2300 405.0 45.77 Ucar Filmer I B T 17.0 2.15 Note: I f wet adhesion i s desired, blending w i t h an a c r y l i c r e s i n , such as Ucar Latex 625, i s recommended. P a i n t Properties: PVC, %: 39.8 Volume Solids, %: 38.8 Weight Solids, %: 56.6 Weight per Gallon, l b : 11.82 Stormer, KU: 88-93 I C I , poise: 0.8-1 .O pH value: 8.0-8.5 Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass Reflectance, %: 90.8 Gloss, 60: 3 Sheen, 85: 6 Contrast Ratio, 3-mil f i l m : 0.976 ASTM Scrub Cycles, w i t h shim F a i l u r e : >3000 F i 1m Properties : SOURCE: Ucar Emulsion Systems: NeoCar Polymers: Formulation Suggestion E-2253
  • 93.
    86 Water-Based PaintFormulations Ingrediernrs; Pigment G r i nd: Water Ucar Polyphobe Ammoni um Hydrox Solv e n t 142HT Tamol 165 P o t a s s i um T r i po T r i t o n N o n i o n i c Proxel GXL Byk 023 Ti-Pure R-706 Greqson D r i v e Gloss White Pounds 112.0 02 Rheo. Mod. 10.0 de, 28% Aqueous S o l u t i o n 1 .o 1 0 . 0 1 3 . 7 yphosphate (KTPP) 0 . 5 S u r f a c t a n t CF-10 3 . 0 2 . 0 2.5 2 2 5 . 0 Letdown : Ucar L a t e x 481 519.0 Sol v e n t 142HT 10.0 Byk 025 2 . 0 B u t y l C a r b i t o l S o l v e n t 26.0 Water 76.4 Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 1.o Ucar Polyphobe 106HE Rheo. Mod. 14.0 P a i n t P r o p e r t i e s : Pigment Volume C o n c e n r t a t i o n , %: 1 9 . 8 Volume S o l i d s , %: 33.9 Weight S o l i d s , %: 45.8 Stormer, KU: 87 I C I , P o i s e : 1 . 0 pH Value: 9-9.5 Freeze-Thaw Stab Heat-Age S t a b i l i VOC, grams p e r 1 F i l m P r o p e r t i e s : Gloss, 60: 90 G l o s s . 20: 70 l i t y , c y c l e s passed: 0-1 y. 12OF, weeks passed: 4 t e r : 120 Gal l o n s 13.40 1.20 0.10 1 . 5 0 1.50 0 . 0 3 0 . 4 0 0 . 2 0 0 . 3 0 6.80 ____ 58.60 1.50 0.30 3.30 9.17 0.10 1 .60 F1ow and Level ing : Excel 1e n t Dry-to-Touch, h o u r s : 2 Recoat, h o u r s : 4-6 W a t e r / B l i s t e r R e s i s t a n c e : Good SOURCE: Ucar Emulsion Systems: U l t r a - G l o s s Latexes: F o r m u l a t i o n Suggestion E-2256
  • 94.
    Exterior Points andRelated Products 87 H i g h Q u a l i t y E x t e r i o r Semi Gloss P a i n t M a t e r ia1 : Grind: Water Natrosol Plus (Aqualon) Acrysol RM 1020 (Rohm and Haas) Acrysol RM 825 (Rohm and Haas) Pigment Disperser NL (BASF) TKPP (10% i n water) Proxel GXL ( I C 1 B i o c i d e s ) FCA (Foam Control Agent) Kronos 2310 (Kronos) Letdown : Propylene g l y c o l Dowanol DPnB (Dow) Mineral S p i r it s Acronal DS 6183 (BASF) FCA (Foam Control Agent) Water Propert i es : Pigment Volume Content, %: 25.5 % N o n v o l a t i l e (by weight): 45.2 % N o n v o l a t i l e (by volume): 32.1 VOC, g / l : 107.0 Stormer V i s c o s i t y , K . U . : 105t-5 I C 1 V i s c o s i t y , Poise: 1.5+-2 Gloss a t 60, %: 67.0 Weight p e r Gallon, l b s / g a l l o n : % foam on manufacturing: Recommended Product: A l t e r n a t i v e Products: SOURCE: King I n d u s t r i e s : Formulat Agitan 731: High performance w A g i t a n 260 o r A g i t a n 315 62.50 5.99 0.52 0.05 31.32 3.00 7.31 0.70 1.04 0.10 3.13 0.30 2.09 0.20 3.13 0.30 261 .02 25.02 41.76 4.00 10.44 1.oo 10.44 1.oo 417.63 40.00 3.13 0.30 188.46 18.04 Agitan 731 10.6 0.66 t h excel l e n t p e r s i stency on WR-39-2
  • 95.
    88 Water-Based PaintFormulations High Sheen White House P a i n t I n q r e d i e n t s : Pounds Pigment Grind: Water 203.9 Ucar Polyphobe 102 Rheo. Mod. 15.2 Ammoni um Hydroxi de, 28% Aqueous Sol u t i on 1.8 Troy 586 2.0 Tamol 1124 4.9 C o l l o i d 643 1 . 9 T r i t o n Nonionic S u r f a c t a n t N-101 2.1 Propylene Glycol 34.6 Kronos 2310 225.0 Minex 10 71 .O Burgess No. 98 75.0 Letdown : Ucar Latex 625 Ucar F i lmer IBT Col l o i d 643 Troysan Polyphase AF-1 Byk 346 Ammmonium Hydroxide, 28% Aqueous S o l u t P a i n t P r o p e r t i e s : Pigment Volume Concentration, %: 35 Volume S o l i d s , %: 38.1 Weight S o l i d s , %: 54.0 V i s c o s i t y , equi 1ib r a t e d : Stormer, KU: 88 I C I , Poise: 1.O 461.9 11.5 1.9 7.3 1.1 on 0.9 2 Gallons 24.48 1.75 0.25 0.20 0.48 0.25 0.25 4.00 6.75 3.27 3.42 52.19 1.45 0.25 0.75 0.13 0.13 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Aged S t a b i l i t y , 120F, weeks passed: 2 F i l m P r o p e r t i e s : Contrast Ratio, 6-mil wet drwadown: 0.984 Reflectance, %: 92.2 Sheen, 85: 64.0 Wet Adhesion, g l o s s alkyd: E x c e l l e n t Chalk Adhesion, ASTM #5: Good SOURCE: Ucar Emulsion Systems: Ucar Latex 625: Formulation Suggestion E-2461
  • 96.
    Exterior Paints andRelated Products 89 Low VOC E x t e r i o r House P a i n t M a t e r i a1 : G r i n d : N a t r o s o l 250 MHR 2.5% (Aqualon) Water Tamol 731 (Rohm and Haas) KTPP T r i t o n CF-10 (Rohm and Haas) Kathon LX 1.5% (Rohm and Haas) FCA (Foam C o n t r o l Agent) T i -Pure R-902 ( DuPont ) Eagle Z i n c 417W (Eagle) Minex 4 (Indusmin) A t t a g e l 50 (Englehard) Letdown : Emulsion E-3122 (Rohm and Haas) FCA (Foam C o n t r o l Agent) A c r y s o l RM-2020 (Rohm and Haas) N a t r o s o l 250 MHR 2.5% (Aqualon) Skane M-8 (Rohm and Haas) Water Lbs 127.0 85.0 16.0 1 .o 1.o 1.7 2.0 250.0 25.0 144.0 5.0 301 .O 2.0 15.0 29.0 2.0 149.0 %Wt 1 5 . 2 10.2 1.8 0.1 0.1 0 . 2 0.3 7.5 0 . 5 6 . 6 0 . 2 34.0 0.3 0.2 1.7 3 . 5 17.9 P r o p e r t i e s : Pigment Volume Content, %: 43.5 % N o n v o l a t i l e (by w e i g h t ) : 52.4 % N o n v o l a t i l e (by volume): 34.3 Stormer V i s c o s i t y , K.U.: 9 2 t - 5 I C 1 V i s c o s i t y , Poise: 1.3+-2 Recommended Product: A g i t a n 731: S u p e r i o r performance i n b o t h a p p l i c a t i o n and p r o d u c t i o n o f p a i n t . F i n e t u n i n g w i l l o p t i m i z e performance and may p r o v i d e a c o s t advantage. A g i t a n 315: E x c e l l e n t foam c o n t r o l i n a l l aspects o f p a i n t manufacture and a p p l i c a t i o n . Lower c o s t a l t e r - n a t i v e t o 731. A l t e r n a t i v e Product: A g i t a n 260 SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n WR-39-4
  • 97.
    90 Water-Based PaintFormulations Q u a l i t y E x t e r i o r F l a t Formulation I n g r e d i e n t s : Pigment G r i nd: Water C e l l o s i z e Hydroxyethyl C e l l u l o s e QP-15,000 Potassium Tripolyphosphate (KTPP) Drewplus L-475 T r i t o n Nonionic Surfactant N-101 Tamol 850 AMP-95 T i -Pure R-902 Eagle 417W I m s i l A25 C e l i t e 499 Water Letdown : Water 1 Natrosol Plus 330 ) premix Propylene Glycol Drewplus L-475 Ucar Latex 6390 NeoCar Latex 2300 Ucar Filmer I8T P a i n t Properties: Pigment Volume Concentration, %: 48.7 Volume Solids, %: 30.0 Weight per Gallon, l b : 11.5 Stormer, KU: 83-88 I C I , Poise: 0.9 pH Value: 8.9 Low Temperature Coalescence: Pass F i l m Properties: Gloss, 60: 2 Sheen, 85: 2 Contrast Ratio, 6-mil wet drawdown: 0.990 Reflectance, %: 88.4 Scrub Resistance, cycles passed: >1500 Dry Adhesion, crosshatch tape p u l l : Pass Wet Adhesion, c y c l e s passed: >2000 50-mil Mudcracking: Pass Pounds 183.3 2.5 2.0 2.0 4.0 7.0 1.5 220.0 50.0 130.0 20.0 16.7 188.2 4 . 0 30.0 2.0 65.0 208.0 14.0 Gal 1ons 22.0 0 . 2 0.1 0.3 0.5 0.7 0.2 6.6 1.1 5.9 1 .o 2.0 22.6 0.4 3.5 0.3 7.4 23.5 1.7 SOURCE: Ucar Emulsion Systems: Ucar Latex 8390: Formulation E-2477
  • 98.
    Exterior Paints andRelated Products 91 Qual i ty Exterior Flat Paint Inaredients; Pigment Grind: Water Cellosize Hydroxyethyl Cellulose ER-30,000 Nuosept 145 Tamol 960 Potassium Tripolyphosphate (KTPP) Triton Nonionic Surfactant N-101 Propylene G1 ycol Colloid 640 Ti -Pure R-900 Eagle 417W Mica 325WG ~ ~ p - 9 5 IT-325 Letdown: Ucar Latex 379G Ucar Filmer IBT Skane M-8 Colloid 640 Paint Properti8s: PVC, %: 40.1 Volume Solids, %: 39.3 Weight Solids, %: 57.7 Weight per Gallon, lb: 11.9 Stormer, KU: 100 ICI, poise: 0.9 pH, initial: 8.9 Freeze-thaw Stability, 3 cycles: Pass Heat-Aged Stability, 2 weeks at 120F: Pass Film Properties: Ref1 ectance, %: 90.5 Sheen, 85: 5.1 Contrast Ratio, 3-mil film: 0.966 Pounds 252.1 4.0 2.3 10.5 2.0 2.2 1 .o 34.5 1.9 225.0 25.0 25.0 175.0 408.3 17.8 2.2 1.9 Gal 1 ons 30.27 0.36 0.25 1 .oo 0.10 0.25 0.13 4.00 0.25 6.54 0.54 1.07 7.37 45.12 2.25 0.25 0.25 SOURCE: Ucar Emulsion Systems: Formulation Suggestion E-19928
  • 99.
    92 Water-Based PaintFormulations Q u a l i t y White E x t e r i o r Trim P a i n t I n a r e d i e n t s : Pigment Grind: Water Ucar Polyphobe 9831 Rheology Modi f ie r Ammonium Hydroxide, 28% Aqueous S o l u t i o n Propylene Glycol Nuosept 95 Tamol 1124 Col l o i d 643 T r i t o n Nonionic S u r f a c t a n t N-57 Tronox CR-828 Polygloss 90 Pounds 98.5 5.0 1.8 59.6 2.3 7.3 1.9 2.1 246.3 24.6 Letdown : Water Ucar Polyphobe 9831 Rheology M o d i f i e r ) Water ) Premix B u t y l C a r b i t o l Solvent Ucar Latex 626 Col l o i d 643 Troysan Polyphase AF-1 T r i t o n A n i o n i c S u r f a c t a n t GR-7M Ammonium Hydroxide, 28% Aqueous S o l u t i o n 16.7 5.8 44.7 30.7 496.7 2.8 7.2 1.1 0 . 9 Gallons 11.79 0.60 0.20 6.90 0.30 0.69 0.30 0.30 7.39 1.18 1.99 0.69 5.38 3.04 57.08 0.39 0.79 0.10 0.10 P a i n t P r o p e r t i e s : Pigment Volume Concentration, %: 24.2 Volume S o l i d s , %: 35.0 Weight S o l i d s , %: 49.7 Weight per Gallon, l b : 10.56 Stormer, KU: 95 I C I , Poise: 1.4 pH Value: 8.9 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Age S t a b i l i t y , 12OF. weeks passed: 2 F i l m P r o p e r t i e s : Gloss, 60: 71 Gloss, 20: 26 Color Acceptance: E x c e l l e n t Flow and Leveling: E x c e l l e n t Wet Adhesion, 24-hr d r y : E x c e l l e n t SOURCE: Ucar Emulsion Systems: Ucar Polyphobe Q83l Rheology M o d i f i e r : Formulation Suggestion E-2484
  • 100.
    I n gr e d i e n t s : Pigment Grind: Water Ucar Polyphobe Ammoni um Hydrox Propylene G1yco Nuosept 95 Tamol 1124 Col l o id 643 T r i t o n Nonionic Tronox CR-828 Polygloss 90 Letdown : Water Exterior Paints and Related Products 93 Q u a l i t y White E x t e r i o r Trim P a i n t 02 Rheology Modi f ie r de, 28% Aqueous Solut S u r f a c t a n t N-57 on Ucar Polyphobe 102 Rheology Modi f ie r ) Premi x Water 1 B u t y l Carbi t o 1 Sol vent Ucar Filmer IBT Ucar Latex 626 C o l l o i d 643 Troysan Polyphase AF-1 T r i t o n Anionic S u r f a c t a n t GR-7M Ammonium Hydroxide, 28% Aqueous S o l u t i o n P a i n t Properties: Pigment Volume Concentration, %: 24.2 Volume Solids, %: 35.0 Weight Solids, %: 49.7 Weight per Gallon, l b : 10.56 Stormer, KU: 90-95 I C I , Poise: 1.4 pH Value: 8.9 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Age S t a b i l i t y , 12OF, weeks passed: 2 F i l m P r o p e r t i e s : Gloss, 60: 62 Gloss, 20: 15 Color Acceptance: E x c e l l e n t Flow and Leveling: Excel l e n t Wet Adhesion, 24-hr d r y : E x c e l l e n t Pounds Gal 1ons 98.5 11.79 10.7 1.28 1.8 0.20 59.6 6.90 2.3 0.30 7.3 0.69 1.9 0.30 2.1 0.30 246.3 7.39 24.6 1.18 8 . 2 0.98 8.6 1.02 44.7 5.38 20.5 2.56 10.2 1.28 496.7 57.08 2.8 0.39 7.2 0.79 1.1 0.10 0.9 0.10 SOURCE: Ucar Emulsion Systems: Formulation Suggestion E-2458
  • 101.
    94 Water-Based PaintFormulations Q u a l i t y White House P a i n t w i t h ZnO I n q r e d ients: Pigment G r i nd: Water C e l l o s i z e Hydroxyethyl C e l l u l o s e ER-30,000 Nuosept 95 Propylene Glycol Col l o i d 226/35 Potassium Tripolyphosphate (KTPP) T r i t o n Nonionic Surfactant N-101 Col l o i d 653 T i -Pure R-902 XX503R Nytal 300 Minex 4 Pounds 295.6 4.0 2.3 25.9 10.3 1 .o 2.2 1.9 225.0 25.0 100.0 96.4 Letdown : Ucar Latex 624 364.2 Ucar Filmer I8T 9.1 Skane M8 2.2 C o l l o i d 653 2.8 Ammoni um Hydroxi de, 28% Aqueous Sol u t ion 2.0 Paint Properties: Pigment Volume Concentration, %: 45.0 Volume Solids, %: 35.4 V i s c o s i t y , equi 1ibrated: Stormer, KU: 82 I C I , poise: 0.85 Weight per Gallon, l b : 11.70 Freeze-thaw S t a b i l i t y , 3 cycles: Pass Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass F i 1m Propert ies : Contrast Ratio, 6-mil wet drawdown: 0.951 Reflectance, %: 91 . 1 Sheen, 85: 4.0 Flow and Leveling, brushed: Good Wet Adhesion: E x c e l l e n t Gal l o n s 35.49 0.36 0.25 3.00 1 .oo 0.05 0.25 0.25 6.75 0.54 4.21 4.44 41.39 1 .I5 0.25 0.37 0.25 SOURCE: Ucar Emulsion Systems: Ucar Latex 624: Formulation Suggestion E-2426
  • 102.
    Exterior Paints andRelated Products 95 Urethane F o r t i f i e d Porch & Deck Enamel M a t e r i a1 : A r o l o n 840-W-39 Water C o l l o i d 679 Cel l o s i ze QP4400 Ammonium Hydroxide D i sperse-Ayd W28 Kroma Red RO 7097 T i t a n o x 2101 Durami t e Lbs. 130.5 5 0 . 0 1 . 9 1 . o 1 . 9 4 . 4 5 0 . 0 5 . 0 1 5 0 . 0 Gals . 15.00 6 . 0 0 0 . 2 5 0.09 0.25 0 . 5 0 1.23 0 . 1 5 6 . 6 1 Add t h e above i n o r d e r under good a g i t a t i o n , t h e n pebble o r sand m i l l g r i n d t o 7 Hegman. Letdown : A r o l o n 840-W-39 Spensol L51 Ucar SCTI 00 u s I Gals_ 304.5 35.00 304.1 34.75 2 . 3 0 . 2 5 A n a l y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 22.0 Pigment/Binder R a t i o : 0 . 8 / 1 . O Percent S o l i d s , Weight: 46.9 Percent S o l i d s , Volume: 36.4 V i s c o s i t y (a 25C, KU: 85-95 Pounds/Gal l o n : I O . 1 VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 150 Pounds/Gallon: 1 . 3 pH: 8 . 5 + - 0 . 3 SOURCE: R e i c h h o l d Chemicals, I n c . : Spensol L: Formula 2262-80
  • 103.
    96 Water-Based PaintFormulations Weather B a r r i e r Formulat- I l r p d E n t s : Pigment G r i n d : Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-52M D i s p e r s a n t ( 1 ) P o t a s s i um T r i p o l y p h o s p h a t e (KTPP) E t h y l e n e G l y c o l W e t t i n g Agent ( 2 ) A n t i f o a m ( 3 ) T i t a n i u m D i o x i d e ( 4 ) C a l c i um Carbonate ( 5 ) Z i n c Oxide ( 6 ) M i l d e w c i d e ( 7 ) Pounds 143.3 4.0 8 . 0 2.0 20.0 1 . 2 1 . 5 1 0 3 . 0 385.0 40.6 5 . 0 Letdown : Ucar L a t e x 123 496.6 Ucar F i lmer IBT 6 . 0 A n t i f o a m ( 3 ) 2.0 Ammonium Hydroxide, 28% Aqueous S o l u t i o n 2 . 5 Gal l o n s 17.3 0 . 3 0 . 8 2.2 0 . 2 0.2 3 . 2 1 7 . 1 0.9 0 . 5 --- 5 5 . 9 0 . 8 0 . 3 0 . 3 S,uppli ( 1 ) e r s : D i s p e r s a n t - C o l l o i d 226/35 (Rhone-Poulenc) o r e q u i v a l e n t . W e t t i n g Agent - S u r f y n o l 104 ( A i r P r o d u c t s ) o r e q u i v a l e n t . A n t i f o a m - C o l l o i d 643 (Rhone-Poulenc) o r e q u i v a l e n t . T i t a n i u m D i o x i d e - T i - P u r e R-960 (DuPont) or e q u i v a l e n t . Calcium Carbonate - A t o m i t e (ECC) o r e q u i v a l e n t . ( 6 ) Z i n c Oxide - Kadox 915 (Cookson) o r e q u i v a l e n t . ( 7 ) M i l d e w c i d e - Nopcocide N-96 (Henkel) o r e q u i v a l e n t . P a i n t P r o p e r t i e s : Pigment Volume C o n c e n t r a t i o n (PVC), %: 40 T o t a l S o l i d s , %: by Volume: 53.8 by Weight: 6 8 . 5 Stormer V i s c o s i t y , KU: 110 F i 1m P r o p e r t i es* : T e n s i l e : S t r a i n Rate, i n / m i n : 2.0 S t r e s s , p s i : 108 E l o n g a t i o n , %: 1070 S t r a i n Rate, i n / m i n : 2 . 0 S t r e s s , p s i : 52 E l o n g a t i o n , %: 1650 Water Transmission a t 24 Hours, mg: 90 180 Bend a t -2OC: No C r a c k i n g T e n s i l e a f t e r 24-hour Water immersion: Water Pondi ng: Low Temperature F l e x i b i l i t y : * D r i e d and C o n d i t i o n e d 7 Days a t 72F (22C) and 50% RH SOURCE: Ucar Emulsion Systems: Ucar L a t e x 123: F o r m u l a t i o n WB-120
  • 104.
    Exterior Paints andRelated Products 97 White E x t e r i o r F l a t House P a i n t w i t h Z i n c Oxide Pounds GallonsI n q r e d ients: _ _ _ ~ Pigment Grind: Water 249.1 29.90 C e l l o s i z e Hydroxyethyl C e l l u l o s e ER-30,000 4.0 0.40 Nuosept 95 2.3 0.25 Propylene G1ycol 25.9 2.98 Tamol 850 4.0 0.40 T r i t o n Nonionic Surfactant N-101 2.1 0.24 C o l l o i d 640 1.9 0.25 T i -Pure R-706 200.0 5.90 Minspar 4 100.0 4.63 Nytal 300 75.0 3.16 Letdown : Water 75.0 9.00 Ucar Latex 353 251 .O 27.50 Ucar Latex 6390 88.7 10.08 Ucar Filmer IBT 23.8 3.01 Col l o i d 640 3.8 0.51 Ammonium Hydroxide, 28% Aqueous S o l u t i o n 3.0 0.40 Potassium Tripolyphosphate (KTPP) 2.0 0.20 Eagle 417W 50.0 1.11 P a i n t Properties: PVC, %: 41 .1 Volume Solids, %: 36.0 Weight Solids, %: 59.6 Weight per Gallon, l b : 11.61 Stormer, KU: 93 I C I , poise: 0.9 pH, i n i t i a l : 9.4 Freeze-thaw S t a b i l i t y , 5 cycles: Pass Heat-Aged S t a b i l i t y : 1 week a t 140F: Pass 2 weeks a t 120F: Pass R o l l e r S t a b i l i t y , 1 week*: Pass F i 1m Properti es : Reflectance, %: 88.2 Contrast Ratio, 3-mil f i l m : 0.951 Wet Adhesion, 24-hr., cycles: >2000 Chalk Adhesion: Dry: Exc Wet: Exc Acceptance: Exc Development : Exc F l o a t : Exc Color*: *Tinted w i t h 2% by weight phthalo b l u e (Huls 888-7124) SOURCE: Ucar Emulsion Systems: Ucar Latex 353: Formulation Suggestion E-1519
  • 105.
    98 Water-Bared PaintFormulations White E x t e r i o r F l a t House P a i n t w i t h Zinc Oxide I n g r e d i e n t s : P igrnent O r ind: Cel l o s i ze Hydroxyethyl C e l l u l o s e QP-4400 Water Propylene Glycol Tamol 960 Potassi urn Tripolyphosphate (KTPP) T r i t o n Nonionic S u r f a c t a n t CF-10 Col l o i d 643 T i -Pure R-902 Eagle 417W Minex 4 Optiwhi t e A t t a g e l 50 AMP-95 Pounds 123.1 98.1 59.0 7.1 1.5 2.5 1.o 1.o 225.0 25.0 145.0 50.0 5.0 Letdown : NeoCar Latex 6035 378.0 Ucar F i l m e r IBT 20.0 Skane M-8 1 .o C o l l o i d 643 1 . 5 Ammonium Hydroxide, 28% Aqueous S o l u t i o n 2.0 Cel l o s i z e Hydroxyethyl C e l l u l o s e QP-4400 43.0 Pai n t Propert ies : PVC, %: 45.0 Volume S o l i d s , %: 37.0 Weight S o l i d s , %: 54.7 Weight per Gallon, l b : 11.7 Stormer, KU: 97 ICI, poise: 0.8-1.0 pH Value: 8.5-9.0 Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass F i l m P r o p e r t i e s : Reflectance, %: 89.7 Gloss, 60: 3 Sheen, 85: 4 Contrast Ratio, 3-mil f i l m : 0.969 ASTM Scrub Cycles, w i t h shim F a i l u r e : >lo00 Chalk Adhesion: Exc Gal 1ons 14.78 11.78 6.86 0.72 0.15 0.28 0.14 0.13 6.76 0.54 6.68 2.73 0.25 41.77 2.53 0.12 0.21 0.24 5.16 SOURCE: Ucar Emulsion Systems: NeoCar Polymers: Formulation Suggestion E-2272
  • 106.
    Exterior Paints andRelated Products 99 White R o o f C o a t i n g M a t e r i a1 : Water Ammonia (28%) Potassium T r i p o l y p h o s p h a t e AZO-33 Z i n c Oxide Durami t e T i t a n o x 2160 Bubble Breaker 3295 Bubble Breaker 776-P Methocel 312MS Texanol Disperse under h i g h shear f o r 10-15 minutes. Add letdown: A r o l o n 820-W-49 A n a l y s i s : PMA-100 Pigment Volume C o n c e n t r a t i o n , Percent: 47.5 Pigment/Binder R a t i o : 2.26/1 Percent S o l i d s , Weight: 63.18 Percent S o l i d s , Volume: 47.33 V i s c o s i t y @ 25C, KU: 80-90 Gloss: F l a t Pounds/Gallon: 11.91 VOC ( e x c l u d i n g w a t e r ) : Grams/Liter: 64.0 Pounds/Gallon: 0.53 pH: 8.8-9.2 Lbs. Gals. 172.60 20.72 1 .80 0 . 0 9 0.90 0.12 1.92 0.09 22.83 0.49 466.65 20.74 24.31 0.73 3.30 0.44 3.30 0.44 4.14 0.36 17.93 2.27 470.89 53.51 SOURCE: R e i c h h o l d Chemicals, I n c . : A r o l o n 820: Formula 2185-40A
  • 107.
    Interior Paints andRelated Products 101 Clear High Gloss Varnish M a t e r i a l : Spensol L51 Ammonium Hydroxide Surfynol 104H Byk 321 C o l l o i d 679 Arolon 840-W-39 M icheml ube 02925 Lodyne S107B Lbs. Gals. 651.9 74.50 1.9 0.25 4.0 0.50 1.9 0.25 I .9 0.25 167.5 19.25 31 .1 3.75 1.o 0.10 Add t h e above m a t e r i a l s i n order under good a g i t a t i o n , then add t h e f o l l o w i n g c u r i n g agent j u s t p r i o r t o use and m i x w e l l f o r a t l e a s t 10 minutes. XAMA- 7 11.4 1.15 Analysis: Percent Sol i d s , Weight : 30.9 Percent Solids, Volume: 28.0 V i s c o s i t y @ 25C #2 Zahn, Secs.: 20 Gloss (60): 100+ Pounds/Gallon: 8.7 VOC (excluding water): Grams/Liter: 290 pH: 8.5+-0.3 Pounds/Gallon: 2 . 4 Formulation 2307-22A Fast-Dry Sealer Materi a1 : Spensol L51 Premix and add: Water Ammoni um Hydroxi de Add i n f o l l o w i n g order w i t h a g i t a t i o n : Arolon 840-W-39 Surfynol 104H Lodyne SI07 Analysis: R a t i o of Spensol L51 t o Arolon 840: 75:25 Percent Solids, Weight: 32.1 Percent Solids, Volume: 29.5 V i s c o s i t y @ 25C, #2 Zahn, Secs.: 23t-4 Pounds/Gallon: 8.73 VOC (excluding water): Grams/Liter: 286 pH: Bt-0.5 Pounds/Gallon: 2.4 Forrnul a t i o n 2061-91A Lbs. Gal s . 687.2 78.63 1.4 0.17 0.4 0.06 176.2 20.25 5.2 0.66 2 . 2 0.23 S0URCE:Reichhold Chemicals, I n c . : Spensol L51: Formulations
  • 108.
    102 Water-Based PaintFormulations Economv F l a t W a l l P a i n t I n q r e d i e n t s : P i gment G r i nd : Water C e l l o s i z e Hydroxyethyl C e l l u l o s e ER-30,000 Nuosept 95 Tamol 731 T r i t o n N o n i o n i c S u r f a c t a n t N-101 T e r g i t o l N o n i o n i c S u r f a c t a n t NP-40 Propylene G1y c o l Drewplus L-475 Tronox CR-813 ASP NC2 No. 1 White C e l i t e 281 Letdown: Water Ucar Latex 353 Ucar F i l m e r IBT Drewpl us L-475 P a i n t P r o p e r t i e s : PVC, %: 70.0 Volume S o l i d s , %: 29.8 Weight S o l i d s , %: 50.2 Weight p e r G a l l o n , l b : 11.32 Stormer, KU: 9 4 I C I , p o i s e : 0.9 pH, i n i t i a l : 8 . 3 Freeze-thaw S t a b i l i t y , 5 c y c l e s : Pass Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass AMP-95 Pounds 484.5 6.0 2.3 4.6 2.2 2.2 1 .o 13.0 1.o 75.0 200.0 150.0 25.0 Gal l o n s 58.16 0.55 0.25 0.50 0.25 0.25 0.13 I .50 0.13 2.34 9.30 6.65 1.30 30.2 3.63 125.4 13.78 8.1 1.03 1 . 9 0.25 F i l m P r o p e r t i e s : R e f l e c t a n c e , %: 91.2 Sheen, 85: 1 . 1 C o n t r a s t R a t i o , 3-mil f i l m : 0.959 ASTM Scrub Cycles, w i t h shim f a i l u r e , 10%: 102 C o l o r * : Acceptance: Exc Development: Exc * T i n t e d w i t h 2% b y w e i g h t p h t h a l o b l u e ( H u l s 888-7214) o r r e d i r o n o x i d e ( H u l s 888-1045). SOURCE: Ucar Emulsion Systems: Ucar L a t e x 353: F o r m u l a t i o n Suggestion 1-2469
  • 109.
    Interior Paints andRelated Products 103 Economy F l a t Wall P a i n t I n g r e d i e n t s : Pigment G r i n d : Water Cel l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-30,000 Nuosept 95 Tamol 731 T r i t o n N o n i o n i c S u r f a c t a n t N-101 T e r g i t o l N o n i o n i c S u r f a c t a n t NP-40 AMP-95 Propylene G l y c o l Drewplus L-475 Tronox CR-813 ASP NC2 No. 1 White C e l i t e 281 Letdown: Water Ucar Latex 353 Ucar F i l m e r IBT Orewplus L-475 P a i n t P r o p e r t i e s : PVC, %: 70.0 Volume S o l i d s , %: 29.8 Weight S o l i d s , %: 50.2 Weight p e r G a l l o n , l b : 11.32 Stormer, KU: 94 I C I . o o i s e : 0 . 9 Pounds 484.5 6.0 2.3 4.6 2.2 2 . 2 1 .o 13.0 1 .o 75.0 200.0 150.0 25.0 30.2 125.4 8 . 1 1.9 Gal l o n s 58.16 0 . 5 5 0.25 0.50 0.25 0.25 0.13 1.50 0.13 2.34 9.30 6.65 1.30 3.63 13.78 1.03 0.25 . . pH, i n i t i a l : 8 . 3 Freeze-thaw S t a b i l i t y , 5 c y c l e s : Pass Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass F i 1m P r o p e r t ies : R e f l e c t a n c e , %: 91.2 Sheen, 85: 1 . 1 C o n t r a s t R a t i o , 3-mil f i l m : 0.959 ASTM Scrub Cycles, w i t h shim f a i l u r e , 10%: 102 C o l o r * : Acceptance: Exc Development : Exc * T i n t e d w i t h 2% b y weight p h t h a l o b l u e ( H u l s 888-7214) o r r e d i r o n o x i d e ( H u l s 888-1045). SOURCE: Ucar Emulsion Systems: Ucar Latex 353: F o r m u l a t i o n Suggestion 1-2460
  • 110.
    104 Water-Based PaintFormulations Good Q u a l i t y I n t e r i o r F l a t w i t h <50g/L VOC I n q r e d ie n t s : P i gment G r i nd : Water Propylene Glycol Proxel GXL Col l o i d 226/35 T r i t o n Nonionic S u r f a c t a n t N-101 Drewplus L-475 Ucar Polyphobe 102 Rheology M o d i f i e r Sodium Hydroxide (50% S o l u t i o n ) T i -Pure R-902 Snowf 1ake Minex 4 Letdown : Ucar Latex 3796 Ucar F i l m e r IBT Drewplus L-475 Ucar Polyphobe 102 Rheology M o d i f i e r Water Pounds 358.0 10.0 0.5 6.0 2.2 4.0 15.0 2.5 200.0 175.0 175.0 200.0 3.0 4.0 17.3 50.0 Gal 1ons 43.00 1.16 0.05 0.59 0.25 0.52 1.72 0.19 6.00 7.75 8.05 22.10 0.38 0.52 1.98 6.01 P a i n t P r o p e r t i e s : PVC, %: 63.1 Volume Solids, %: 34.5 Weight S o l i d s , %: 55.1 Weight per Gallon, l b : 12.18 Stormer, KU: 87 I C I , p o i s e : 2.1 pH, i n i t i a l : 9.2 Freeze-Thaw Stabi 1it y , 1 c y c l e : Pass Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass V o l a t i l e Organic Content, g/L: 45.6 F i 1m Properties : Ref 1ectance, %: 90.0 Sheen, 85: 2 Contrast Ratio, 3-mil f i l m : * 0.961 ASTM Scrub Cycles, w i t h shim F a i l u r e : 330 C o l o r : * Acceptance: Excel l e n t Development: E x c e l l e n t Low Temperature Coalescence I O - m i l drawdown a t 40F: Pass Mudcracki ng, 30-mi 1 on sheetrock: Pass * T i n t e d w i t h 2% by weight p h t h a l o b l u e (Huls 888-7214) o r r e d i r o n o x i d e (Huls 888-1045). SOURCE: Ucar Emulsion Systems: Formulation Suggestion I-2230A
  • 111.
    Interior Paints andRelated Products 105 Hiah-Quality Super F l a t I n t e r i o r P a i n t I n g r e d i e n t s : P i Qment Grind: Water Propylene G1y c o l Proxel GXL Col 1o i d 226/35 T r i t o n Nonionic S u r f a c t a n t N-10 C o l l o i d 640 Ucar Polyphobe 102 Rheology Mod T i -Pure R-902 Snowf 1ake 960 Minex 4 Letdown : Ucar Latex 3796 Ucar Filmer IBT C o l l o i d 640 AMP-95 f i e r Ucar Pol yphobe 102 Rheology Modi f ie r Water Pounds 150.0 25.9 0.5 8.0 2.2 3.5 15.0 5.0 250.0 125.0 125.0 Gal l o n s 18.02 3.00 0.05 0.78 0.25 0.47 1.72 0.63 7.51 5.54 5.76 419.8 46.64 16.8 2.11 3.5 0.50 7.5 0.86 51.3 6.16 Pai n t P r o p e r t i es : PVC, %: 43.3 Volume S o l i d s , %: 43.4 Weight S o l i d s , %: 61.0 Weight per Gallon, l b : 12.09 Stormer. KU: 90 I C I , poise: 2.0 pH, i n i t i a l : 9.2 Freeze-Thaw S t a b i l i t y , 3 cycles: Pass Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass F i 1m Properties : Reflectance, %: 92.5 Sheen, 85: 7 Contrast Ratio, 3-mil f i l m * : 0.962 ASTM Scrub Cycles, w i t h shim F a i l u r e : >2000 Color*: Acceptance: Excel 1ent Development : Excel 1ent *Tinted w i t h 2% by weight phthalo b l u e (Huls 888-7214) or red i r o n oxide (Huls 888-1045). SOURCE: Ucar Emulsion Systems: Formulation Suggestion I-2227A
  • 112.
    106 Water-Based PaintFormulations I n t e r i o r Clear Wood F i n i s h (RhoDlex CL-l04/Sancure 8151 B1end : Rhopl ex CL-104 (38.5%) Sancure 815 (35.0%) Surfynol DF-62 Surfynol 104PG-50 Mix above f o r 10 minutes before adding t h e f o l l o w i n g : Hexyl Carbi to1 Propylene Glycol Acrysol RM-1020 Water Michem 39235 Aqueous Ammonia ( 14%) Formulation B (Rohm and Haas) I n t e r i o r Sandina Sealer (RhoDlex CL-1051 E lend : Rhopl ex CL-105 (37.0%) Surfynol DF-62 Water Aqueous Ammonia (14%) Mix above f o r 10 minutes before adding t h e f o l l o w i n g : Propasol B Hexyl Carbi to1 Acrysol RM-2020 Water Aqueous Ammonia (7%) Surfynol 104DPM Formulation C (Rohm & Haas) Pounds 540.0 148.5 1.4 3.0 20.8 30.0 18.0 66.0 22.3 2.5 Pounds 709.3 1.3 32.9 8.0 45.2 22.3 4.1 30.8 2.6 3.0 Surfynol a d d i t i v e s have been shown t o provide t h e f o l l o w i n g benef it s : *Color u n i f o r m i t y o f s t a i n s *Early s t a i n 1appi ng resistance *Consistent wetting, f l o w and l e v e l i n g on various woods *Foam c o n t r o l *Topcoat r e c o a t a b i l i t y and i n t e r c o a t adhesion *Gloss r e t e n t i o n upon aging *Tannin bleed r e s i stance *Water s e n s i t i v i t y *Chemical resistance Formulas With no detrimental e f f e c t upon: SOURCE: A i r Products 8, Chemicals, Inc.: Surfynol Surfactants:
  • 113.
    Interior Paints andRelated Products 107 I n t e r i o r Contractor F l a t I n g r e d i e n t s : Pigment Grind Water Propylene G1ycol Tamol 1124 T r i t o n Nonionic Surfactant X-405 C o l l o i d 643 AMP-95 T i -Pure R-901 Optiwhite Duramit e C e l i t e 281 Letdown : Ucar Latex 379G Ucar Filmer I B T C o l l o i d 643 Water Ucar Polyphobe 10 Water Paint Properties: PVC, %: 71.4 Volume Sol i d s , Wei ght Sol ids, Weight per Gal pti, i n i t i a l : 8 Pounds 184.0 26.0 10.0 2.0 1.5 2.0 100.0 150.0 190.0 20.0 148.0 8.0 2.5 50.0 Rheology Modi f ie r 21 .o-. 217.5 %: 40.3 %: 29.4 on, l b : 11.3 5-9.0 Gal 1ons 22.09 3.02 1.01 0.23 0.21 0.25 3.33 8.20 8.41 1.04 16.35 1.01 0.34 6.00 2.41 26.11 Ucar Polyphobe 107: NVM lb/100 g a l : 5.3 Stormer, KU: 90/98 I C I , poise: 0.7 Scrub Cycles: 140 SOURCE: Ucar Emulsion Systems: Formulation Suggestion I-2231A
  • 114.
    108 Water-Based PaintFormulations I n t e r i o r Good Quality F l a t f o r R o l l e r and Brush A p p l i c a t i o n I n Q r e d ients: Pigment Grind: Water Propylene G1ycol Tamol 1124 T r i t o n Nonionic Surfactant X-405 Col l o i d 643 AMP-95 T i -Pure R-901 Opt iwhi t e Durami t e Letdown : Ucar Latex 379 Ucar Filmer IBT C o l l o i d 643 Water Ucar Polyphobe 103 Rheology M o d i f i e r Water Paint Properties: Pigment Volume Concentration, %: 58.0 Volume Solids, %: 34.4 Weight Solids, %: 51.9 Weight per Gallon, l b : 11.3 pH, i n i t i a l : 8.5-9.0 Thickener Comparison: Ucar Polyphobe 103: NVM lb/100 g a l : 5 . 7 Stormer, KU: 91/98 I C I , P: 1.5 Scrub Cycles: 1102 Flow/Leveling: Excellent 50-mi 1 Mudcrack: Pass R o l l er/Spatter : M i n i mal NVM lb/110 g a l : 7.0 Stormer, KU: 86/96 I C I , P: 1.8 Scrub Cycles: 1200 Flow/Leveling: Excel l e n t 50-mi 1 Mudcrack: Pass R o l l er/Spatter : M i n i mal Ucar Polyphobe 102/104 blend: NVM lb/100 g a l : 3.7/2.3 Stormer. KU: 95/101 Ucar Polyphobe 102: ~I ~ ~I ~ I C I , P: 1.4 Scrub Cycles: 1200 Pounds 184.0 26.0 9.0 2.0 1.5 2.0 100.0 150.0 190.0 254.0 16.0 2.5 50.0 22.8 119.2 Flow/Leveling: Good 50-mi 1 Mudcrack: Pass R o l l er/Spatter : M i n i mal SOURCE: Ucar Emulsion Systems: Formulation Suggestion Gal 1ons 22.09 3.02 0.91 0.23 0.21 0.25 3.33 8.20 8.41 28.07 2.03 0.34 6.00 2.62 14.31 1-2232
  • 115.
    Interior Paints andRelated Products 109 I n t e r i o r Good Q u a l i t y F l a t f o r R o l l e r and Brush A p p l i c a t i o n I n g r e d i e n t s : Pigment Grind: Water Propylene Glycol Tamol 1124 T r i t o n Nonionic Surfactant X-405 C o l l o i d 643 Ti-Pure R-901 Opt iwhi t e Durami t e Letdown : Ucar Latex 379 Ucar F i l m e r I B T C o l l o i d 643 Water Ucar Polyphobe 9831 Rheology M o d i f i e r Water AMP-95 Pounds 184.0 26.0 9.0 2.0 1.5 2.0 100.0 150.0 190.0 254.0 16.0 2 . 5 60.3 12.5 119.2 Gal 1ons 22.09 3.02 0.91 0.23 0.21 0.25 3.33 8.20 8.41 20.07 2.03 0.34 7.20 1.40 14.31 P a i n t P r o p e r t i e s : Pigment Volume Concentration, %: 58.0 Volume S o l i d s , %: 34.4 Weight S o l i d s , %: 51.9 Weight per Gallon, l b : 11.3 Stormer, KU: 95 I C I , Poise: 1.6 pH Value: 8.5-9.0 V o l a t i l e Organic Content, g/L: 139 Sheen, 85: 1.8 Flow and Leveling: Good Sag Resistance, m i l s : 7 F i l m P r o p e r t i e s : SOURCE: Ucar Emulsion Systems: Ucar Polyphobe 9831 Rheology M o d i f i e r : Formulation Suggestion 1-2240
  • 116.
    110 Water-Based FaintFormulations I n t e r i o r Good Q u a l i t y F l a t I n g r e d i e n t s : Pi gment G r i nd : Water Propylene G1ycol Proxel GXL Tamol 1124 T r i t o n Nonionic Surfactant X-405 C o l l o i d 643 T i -Pure R-901 O p t i whi t e Ourami t e Letdown : Ucar Latex 3796 Ucar Filmer IBT Col l o i d 643 Water Ucar Polyphobe 103 Rheology Modi f ier Water Paint Properties: PVC, %: 58.0 Volume Solids, %: 34.4 Weight Solids, %: 51.9 Weight per Gallon, l b : 11.3 pH, i n i t i a l : 8.5-9.0 AMP-95 Thickener Comparison: Ucar NVM, lb/100 gal Stormer, KU I C I , p o i s e Scrub Cycles Flow/Level ing 50-mi 1 Mudcracki ng Pounds 184.0 26.0 0.5 9.0 2.0 1.5 2.0 100.0 150.0 190.0 254.0 16.0 2.5 50.0 22.8 119.2 Polyphobe Ucar 02 7.0 Gal 1ons 22.09 3.02 0.05 0.91 0.23 0.21 0.25 3.33 8.20 8.41 28.07 2.03 0.34 6.00 2.62 14.31 Polyphobe 03 5.7 86/96 1.8 1200 Exc Pass 91/98 1.5 1102 Exc Pass SOURCE: Ucar Emulsion Systems: Formulation Suggestion I-2232A
  • 117.
    Interior Paints andRelated Products 111 I n t e r i o r Semigloss Formulation I n g r e d i e n t s : Pigment G r i nd: Water Ucar Polyphobe 102 Rheology M o d i f i e r Ammoni um Hydroxi de, 28% Aqueous Sol u t i on Propylene G1ycol Proxel GXL Tamol 1124 Col l o i d 643 T r i t o n Nonionic Surfactant N-57 Tronox CR-828 Burgess No. 98 Letdown : Water Ucar Polyphobe 102 Rheology M o d i f i e r B u t y l C a r b i t o l Solvent Ucar Filmer IBT Ucar Latex 379G Ucar Latex 6030 C o l l o i d 643 Byk 346 Ammoni um Hydroxide, 28% Aqueous Sol u t i on Pounds 125.0 19.6 1.8 43.2 2.3 7.3 1.9 2.1 250.0 19.7 24.8 2.2 23.8 11.9 346.8 184.0 2.8 1.1 1.8 Gal 1ons 15.0 2.3 0.3 5.0 0.2 0.7 0.3 0.2 7.3 0.9 3.0 0.3 3.0 1.5 38.3 20.9 0.4 0.1 0 . 3 P a i n t Properties: Pigment Volume Concentration, %: 22.5 Volume Solids, 96: 36.4 Weight per Gallon, l b : 10.7 Stormer, KU: 83 I C I , Poise: 1.9 pH Value: 8.7 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Age S t a b i l i t y , 120F. weeks passed: 2 R a t i o o f Ucar Latexes 379:6030: 70:30 F i l m Properties: Gloss, 60: 64 Gloss, 20: 18 Contrast Ratio, 6-mil wet drawdown: 0.972 Reflectance, %: 91.9 Block Resistance: 9 Flow and Leveling: Good Low Temperature Coalescence: 10 Washability, s t a i n removal*: 10 (crayon, f e l t pen, l i p s t i c k , p e n c i l ) % gloss retained: 92 *Washed w i t h Fantastik; lO=complete s t a i n removal Wet Adhesion, gloss alkyd: Exc SOURCE : Ucar Emulsion Systems: 1-2473 Ucar Latex 0030: Formulation
  • 118.
    112 Water-Based Pain?Formidations _ _ _ ~I n t e r i o r V i n y l A c r y l i c Eggshell f o r R o l l e r and Brush A p p l i c a t i o n I n q r e d ie n t s : Pigment Grind: Water Propylene G1ycol Tamol 1124 T r i t o n Nonionic S u r f a c t a n t X-100 C o l l o i d 643 Proxel GXL T i -Pure R-900 Omyacarb UF AMP-95 ASP-1 70 Letdown : Ucar Latex 379 Ucar F i l m e r IBT Col l o i d 643 Ucar Polyphobe 9831 Rheology M o d i f i e r Water P a i n t P r o p e r t i e s : AMP-95 Pigment Volume Concentration, %: 36.4 Volume S o l i d s , %: 37.4 Weight S o l i d s , %: 54.4 Weight per Gallon, l b : 11.3 Stormer, KU: 95 I C I , Poise: 1 . 2 pH Value: 8.5-9.0 V o l a t i l e Organic Content, g/L: 121 F i l m P r o p e r t i e s : Gloss, 60: 35 Flow and Leveling: Good Sag Resistance, m i l s : 12 Pounds 100.0 26.0 8.0 2.0 1.5 1.5 2.0 230.0 100.0 50.0 420.0 12.0 2.5 2.0 11.o 168.0 Gallons 12.00 3.02 0.81 0.23 0.21 0.15 0.25 6.91 4.42 2.33 46.41 1.52 0.34 0.25 1.27 20.07 SOURCE: Ucar Emulsion Systems: Ucar Polyphobe 9831 Rheology Modi f ie r : Formulation Suggestion 1-2241
  • 119.
    I n te r i o r V i n y l A c r y l ic Eqashel1 f o r R o l l e r and Brush A p p l i c a t i o n Ingredients: Pigment G r i nd : Water Propyl ene G1ycol Tamol 1124 T r i t o n Nonionic Surfactant C o l l o i d 643 Proxel GXL T i -Pure R-900 Omyacarb UF AMP-95 ASP- 170 x-1 00 Pounds 100.0 26.0 8.0 2.0 1.5 1.5 2.0 230.0 100.0 50.0 Letdown : Ucar Latex 379 420.0 Ucar Filmer IBT 12.0 C o l l o i d 643 2.5 AMP-95 2.0 Ucar Polyphobe 102 Rheology Modi f ie r 30.0 Water 149.0 Paint Properties: Pigment Volume Concentration, %: 36.4 Volume Solids, %: 37.4 Weight Solids, %: 54.4 Weight per Gallon, l b : 11.3 pH, i n i t i a l : 8.5-9.0 Thickener Comparison: Ucar Polyphobe 114: NVM lb/100 g a l : 5.0 Stormer, KU: 93 I C I , P: 0.5 Flow/Leveling: Poor Sag Resistance: 24+ Ucar Polyphobe 102: NVM l b / l 0 0 g a l : 7.5 Stormer, KU: 92 I C I , P: 1.8 Flow/Level ing: Excellent Sag Resistance: 12 Ucar Polyphobe 102/114 blend ( 4 : l ) : NVM lb/100 aal : 4.0 l b o f Ucar Poly. 102 Storme;, KUT 97 I C I , P: 1.6 F1ow/Level ing : Very Good Sag Resistance: 14 Gallons 12.00 3.02 0.81 0.23 0.21 0.15 0.25 6.91 4.42 2.33 46.41 1.52 0.34 0.25 3.45 17.89 Interior Paints and Related Products 113 SOURCE: Ucar Emulsion Systems: Formulation Suggestion 1-2237
  • 120.
    114 Water-Based PaintFormulations I n t e r i o r V i n y l A c r y l i c Semigloss I naredients : Pigment Grind: Water Polywet ND-35 T i -Pure R-902 Drewpl us L-475 Letdown : Ucar Latex 367 Water Ucar F i l m e r I B T Nuosept 95 T r i t o n Nonionic S u r f a c t a n t GR-5M Drewpl us L-475 Water ( a d j u s t according t o Polyphobe Ucar Polyphobe 114 Rheology M o d i f i e r AMP-95 Pounds 104.9 4.0 205.0 2.0 423.0 33.3 23.8 2.0 1.o 5.0 4.0 l e v e l ) 214.5 26.5 Gal l o n s 12.59 0.39 6.16 0.28 47.00 4.00 3.01 0.21 0.12 0.64 0.56 25.75 3.05 P a i n t P r o p e r t i e s : Pigment Volume Concentration, %: 20.4 Volume S o l i d s , 96: 40.3 Weight Solids, %: 54.2 Weight per Gallon, l b : 10.5 Thickener Compari son : Ucar Polyphobe 114: NVM lb/100 g a l : 6.6 B r o o k f i e l d , 0.3, P: 680 I C I , P: 0.5 60 Gloss: 79 Ucar Polyphobe 102: NVM lb/100 g a l : 10.7 Brookfield,-0.3, P: 186 ICI, P: 2.2 60 Gloss: 74 Ucar Polyphobe 103: NVM lb/100 gal : 8.2 B r o o k f i e l d , 0.3, P: 336 I C I , P: 1.5 60 Gloss: 69 Ucar Polyphobe 107; NVM lb/100 g a l : 5.1 B r o o k f i e l d , 0.3, P: 226 I C I , P: 0.7 60 Gloss: 67 NVM lb/100 g a l : 5.6 B r o o k f i e l d , 0.3, P: 2,086 I C I , P: 0.7 60 Gloss: 70 Ucar Polyphobe 106HE: SOURCE: Ucar Emulsion Systems: Formulation Suggestion 1-2239
  • 121.
    Interior Paints andRelated Products 115 Intumescent I n t e r i o r White F ire-Retardant Paint I ngredients : Pigment Grind: Water Potassium Tripolyphosphate (KTPP) Surfactol 365 Ucar Latex 367 C o l l o i d 677 Phos-Chek PI30 Aero Melamine (powdered grade) D i pentaerythri t o 1 (powdered grade) Nuosept 6351 T i -Pure R-900 Chlorez 700 Pounds 290.0 3.0 4.0 75.0 3.0 260.0 80.0 75.0 1 .o 60.0 40.0 Gal 1ons 34.8 0.3 0.4 8.2 0.3 17.3 6.8 6.4 0.1 1 .8 2.9 Letdown : C e l l o s i z e Hydroxyethyl Cellulose QP-15,OOOH (1.5% aqueous s o l u t i o n ) 45.0 5.2 Ucar Latex 367 145.0 16.0 C o l l o i d 677 1.o 0.1 Procedure: t h e order l i s t e d . Completely disperse each ingredient before adding t h e next. When t h e pigment g r i n d s l u r r y i s complete, a g i t a t e f o r an a d d i t i o n a l f i v e minutes; t r a n s f e r t o a pebble m i l l and g r i n d t o Hegman 3. Under a g i t a t i o n , prepare t h e f i n a l letdown i n t h e order l i s t e d . Under a g i t a t i o n , add t h e pigment g r i n d slowly t o t h e letdown. Note: Protect thickener s o l u t i o n s w i t h preservative during processing and storage. Paint Properties: Under a g i t a t i o n , add a l l ingredients o f t h e pigment g r i n d i n Pigment Volume Concentration, %: 74 Total Solids, % by weight: 60 Weight per Gallon, l b : 10.8 Stormer. KU: 75-80 Contrast Ratio: 0.87 SOURCE: Ucar Emulsion Systems: Ucar Latex 367: Formulation Suggestion 1-1338
  • 122.
    116 Water-Based PaintFormulations Low VOC I n t e r i o r F l a t _ _ _ _ _ _ _Pounds GallonsI n q r e d ie n t s : Pigment Grind: Water Kathon LX Tamol 1124 T r i t o n Nonionic S u r f a c t a n t N-101 Drewpl us L-475 Ucar Polyphobe 102 Rheology M o d i f i e r Sodi um Hydroxide Ti-Pure R-902 Duramit e Iceberg Water Letdown : Ucar Latex 379 Water Drewplus L-475 Ucar F i l m e r IBT Ucar Polyphobe 102 Rheology M o d i f i e r P a i n t P r o p e r t i e s : Pigment Volume Concentration, %: 64.9 Volume S o l i d s , %: 32.3 Weight S o l i d s , %: 53.1 Weight per Gallon, l b : 12.1 Stormer, KU: 92 VOC, grams per l i t e r : 26.09 F i l m P r o p e r t i e s : Gloss, 60: 2 Sheen, 85: 3 Contrast R a t i o , 6-mil wet drawdown: 0.977 Reflectance, %: 91 .8 Scrub Resistance, c y c l e s passed: 161 333.3 40.00 1.7 0.20 5.1 0.52 2.0 0.23 2.0 0.26 15.0 1.73 3.0 0.15 190.0 5.70 185.0 8.21 155.0 7.07 50.0 6.00 200.7 22.18 39.4 4.73 2 . 5 0.33 7.7 0.96 15.0 1.73 SOURCE: Ucar Emulsion Systems: Formulation Suggestion 1-2238
  • 123.
    Interior Paints andRelated Products 117 -S o l v e n t Free I n t e r i o r S a t i n P a i n t M a t e r i a l : G r i n d : Water KTPP (100%) Tamol 731 (Rohm and Haas) T r i t o n CF-10 (Rohm and Haas) Kathon LX 1.5% (Rohm and Haas) FCA (Foam C o n t r o l Agent) Ti-Pure R-900 (DuPont) N y t a l 300 ( R . T . V a n d e r b i l t ) C a l c i um Carbonate Letdown : Rovace SF-091 (Rohm and Haas) Rovaque OP-62 L O (Rohm and Haas) FCA (Foam C o n t r o l Agent) A c r y s o l RM-2020 (Rohm and Haas) A c r y s o l TT-935 (Rohm and Haas) Sodium Carbonate Water P r o p e r t i e s : Pigment Volume Content, %: 37.0 % N o n v o l a t i l e (by volume): 34.0 Stormer V i s c o s i t y , K.U.: 95+-5 I C 1 V i s c o s i t y . Poise: 1.1+-2 Gloss a t 60,-%: 13.0 Recommended P r o d u c t : A g i t a n 315: E f f i c i e n t . F i n e A l t e r n a t i v e Products: A g i t a n 260: E f f i c i e n t , c o s t A g i t a n 731: E f f i c i e n t , z e r o SOURCE: K i n g I n d u s t r i e s : Formu !& 260.0 1.5 7.0 2.5 1 . 7 1.o 170.0 40.0 70.0 372.2 45.0 2.0 15.0 12.5 24.0 57.5 %wt 31.20 0.07 0 . 7 6 0.28 0.20 0.13 5.10 1.68 3.11 41.50 5.22 0.26 1.65 1.42 2.52 6.90 t u n i ng w i 11 p r o v i d e c o s t b e n e f i t s . e f f e c t i v e . voc . a t i o n WR-39-3
  • 124.
    118 Water-Based PaintFormulations White I n t e r i o r Eqsshell I n q r e d i e n t s : ~~Pounds Gal l o n s Pigment Grind: Water 226.7 27.21 Ucar Polyphobe 9831 Rheology M o d i f i e r 8.5 0.97 Nuosept 145 2.3 0.25 Tamol 731A T r i t o n Nonionic Surfactant N-57 AMP-95 Propylene Glycol Col l o i d 640 Tronox CR-800 Opt iwh it e Burgess No. 98 Letdown : AMP-95 Ucar Filmer IBT Water Ucar Latex 353 Col l o i d 640 P a i n t Properties: PVC, %: 35.8 Volume Solids, %: 38.2 Weight Solids, %: 52.4 Weight per Gallon, l b : 11.04 Stormer, KU: 95 I C I , poise: 1.4 pH, i n i t i a l : 9.0 Freeze-thaw S t a b i l i t y , 5 cyc Heat-Aged S t a b i l i t y , 2 weeks F l m Properties: Reflectance, %: 91.4 Gloss, 60: 6.3 Sheen, 85: 22.6 Contrast Ratio, 3-mil f i l m : .969 Color*: Acceptance : Exc Development: Exc *Tinted w i t h 2% by weight phthalo i r o n oxide (Huls 888-1045). 11.5 1.25 2.3 0.25 2.0 0.26 51.8 6.00 1.9 0.25 225.0 6.54 100.0 5.46 25.0 1.15 2.0 0.27 22.5 2.85 78.7 9.45 341 .O 37.47 2.8 0.37 es: Pass a t 120F: Pass SOURCE: Ucar Emulsion Systems: Formu b l u e (Huls 888-7124) o r red a t i o n Suggestion 1-1520
  • 125.
    120 Water-Based PaintFormulations Green Lacquer I n s r e d i e n t s : P i ament G r i nd : Water Ethylene Glycol Dispersant ( 1) T e r g i t o l Surfactant NP-10 Antifoam (2) Phthalo Green (3) Medium Chrome Yellow ( 4 ) Let Down: Ucar Vehicle 443 B u t y l C a r b i t o l Solvent T r i butoxyethyl Phosphate Phthalo Green (3) Deionized Water Pounds 45.00 0.65 6.26 0.62 1.oo 50.00 33.04 Gal l o n s 5.40 0.07 0.68 0.07 0.13 4.95 0.67 666.11 75.19 13.26 1.67 13.26 1.58 51.50 5.10 26.55 3.19 Suppl i e r s : ( 1 ) Dispersant - C o l l o i d 107 ( C o l l o i d s ) o r e q u i v a l e n t . ( 2 ) Antifoam - C o l l o i d 675 ( C o l l o i d s ) o r e q u i v a l e n t . (3) Phthalo Green - T i nt-Ayd WD-2744 D i spersi on (Daniel ( 4 ) Medium Chrome Yellow - X-3356 C.P. Medium Y (Ciba-Geigy) Products) o r e q u i v a l e n t . o r e q u i v a l e n t . Lacquer P r o p e r t i as : by Weight: 37 by Volume: 31 Pi gment/Bi nder Ratio : 0.25/ 1 Solids, %: pH: 8.5 V i s c o s i t y , No. 4 Ford Cup, sec: 25 SOURCE: Ucar Emulsion Systems: Ucar Vehicle 443: Formulation Suggestion LP-3812
  • 126.
    Lacquers 121 Foam Controlw i t h Agitan A d d i t i v e s i n a Hiah Gloss DIY Waterborne Lacquer The choice o f coalescing agents can s i g n i f i c a n t l y i n f l u e n c e t h e generation o f foam i n a waterborne formulation as w e l l as a f f e c t t h e performance o f t h e foam c o n t r o l agent (FCA). Component: Rhoplex CL-104 (Rohm and Haas) DC-14 (Dow Corning A d d i t i v e s ) FCA (Foam Control Agent) Michem 39235 (Michelman) Adjust pH t o 7-8 Aqueous Ammonia 28% Propylene Glycol Coalescent Water Adjust t o v i s c o s i t y Water j& %Wt 642.8 76.83 24.7 2.95 1.3 0.16 21 . e 2.61 3 24.7 37.6 29.2 51.5 0.36 2.95 4.49 3.49 6.16 Properties: % N o n v o l a t i l e (by weight): 30.7 % N o n v o l a t i l e (by volume): 29.1 V i s c o s i t y #2 Zahn, 25C (seconds): 20-26 Theoretical VOC (pounds/gallon): 2.07 Theoretical VOC (grams/l it e r ) : 249 This study has demonstrated t h a t d i f f e r e n t coalescents can pH, 25C: 7.5-8.0 s i g n i f i c a n t l y a f f e c t foam generation and hence t h e performance o f t h e foam c o n t r o l agent. However, Agitan 295 performed e q u a l l y w e l l i n both systems, regardless o f t h e coalescing agent used. For optimum foam prevention and f i l m p r o p e r t i e s , Agitan 305 i s recommended w i t h t h e Texanol, w h i l e Agitan 731 i s recommended f o r t h e DPnB. SOURCE: King I n d u s t r i e s : WR-32: FCA's f o r Waterborne Wood Formulations
  • 127.
    122 Water-Based PaintFormulations White Lacauer I n a r e d i e n t s : Pigment G r i nd : Ucar Vehicle 443 D i spersant (1 ) S u r f a c t a n t ( 2 ) T e r g i t o l S u r f a c t a n t NP-10 Antifoam ( 3 ) Titanium Dioxide (4) Pebble M i l l o v e r n i g h t . Let Down: Ucar Vehicle 443 Antifoam ( 3 ) Proposol Solvent B T r i butoxyethyl Phosphate Mar-Resi s t a n t A i d (5) Ammonium Benzoate, 10% Aqueous S o l u t i o n Dei oni zed Water Pounds 149.9 5.9 2.1 2.1 0.9 187.4 421.3 0.9 40.9 20.4 0.9 10.0 150.8 Gal l o n s 17.2 0.7 0.3 0 . 2 0.1 5.5 48.2 0.1 5.6 2 . 4 0.1 1.1 18.1 Suppliers: ( 1 ) Dispersant - Disperbyk (Byk-Mallinckrodt) o r e q u i v a l e n t . (2) S u r f a c t a n t - Surfynol 104 ( A i r Products) o r equivalent. ( 3 ) Antifoam - Hodag PX-218 (Hodag) o r e q u i v a l e n t . ( 4 ) Titanium Dioxide - Zopaque RCL-9 (SCM) o r e q u i v a l e n t . (5) Mar-Resistant A i d - Byk 301 ( B y k - M a l l l i n c k r o d t ) o r e q u i v a l e n t . Lacquer P r o p e r t i e s : Pigment/Binder Ratio: 0.8/1 T o t a l S o l i d s , %: 42.4 pH: 8 . 6 V i s c o s i t y , No. 4 Ford Cup, sec: I n i t i a l : 20 A f t e r 10 days a t 140F: 20 SOURCE: Ucar Emulsion Systems: Ucar Vehicle 443: Formulation Suggestion LP-3846
  • 128.
    Lacquers 123 White Lacquer In a r e d ients: P igment G r i nd: Ethylene Glycol Dispersant (1 ) T e r g i t o l S u r f a c t a n t NP-10 Antifoam (2) Ammonium Hydroxide, 28% Aqueous Deionized Water T i t a n i um Dioxide (3) Pounds 3.16 6.31 1.59 0.23 S o l u t i o n 0.44 28.20 156.52 Gal 1ons 0.34 0.70 0.18 0.03 0.05 3.39 4.59 Grind f o r 15 minutes a t h i g h speed i n a high-shear mixer. Let Down: Ucar Vehicle 443 T r i butoxyethyl Phosphate Filmer (4) B u t y l C a r b i t o l Solvent Ammonium Benzoate Deionized Water 546.84 62.00 4.60 0.55 11.19 1.42 11.20 1.41 0.74 0.07 210.25 25.29 Suppl iers: (1) Dispersant - Disperbyk (Byk-Mgllinckrodt) o r equivalent (2) Antifoam - C o l l o i d 675 ( C o l l o i d s ) o r e q u i v a l e n t . (3) Titanium Dioxide - Titanox 2060 (NL I n d u s t r i e s ) o r ( 4 ) Filmer - Texanol (Eastman) or e q u i v a l e n t . e q u i v a l e n t . Lacquer P r o p e r t i e s : Pigment/Binder Ratio: 0.67/1 S o l i d s , %: by Weight: 38.5 by Volume: 28.1 pH: 8 . 5 V i s c o s i t y . No. 4 Ford Cup, sec: 35 SOURCE: Ucar Emulsion Systems: Ucar Vehicle 443: Formulation Suggestion LP-3813
  • 129.
    Primers 125 fi Halox BW-100 Grind: Water PropyleneG1ycol Dowicil 75 C o l l o i d 111 St rodex PK-95G Surfynol 104E Drewplus L-475 Texanol Polyphobe 102 Aqua Ammonia (28%) Lbs./100 Gals. Gms/Liter 250.0 300.0 15.0 18.0 1.o 1.2 5.0 6.0 3.5 4.2 4.0 4.8 2.0 2.4 10.0 12.0 16.0 19.2 4.0 4.8 Add t h e f o l l o w i n g a t high speed and disperse t o 4+ Hegman g r i n d . T i -Pure R-902 Halox BW-100 Beaverwhi t e 325 Snowf 1ake Letdown : CL 27NA Drewpl us L-475 175.0 210.0 100.0 120.0 50.0 60.0 185.0 222.0 340.0 408.0 2.0 2.4 Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l uniform. Premix t h e f o l l o w i n g 2 raw m a t e r i a l s and add under good a g i t a t i o n DO NOT AERATE! Water Pol yphobe 106E Mix u n t i l uniform. Formula Constants: % P i gment/Wt .: 42.91 % P i gment/Vol .: 20.07 % Solids/Wt.: 57.79 % Solids/Vol.: 39.51 % PVC: 50.79 VOC, l b s . / g a l . : 1.01 VOC. g/L: 120.97 25.0 30.0 2.0 2.4 Formula Properti 8s: Density l b s . / g a l . : 11.90 Density g/L: 1,427.4 KU Visc. I3 R.T.: 85-90 pH I3 R.T.: 8.5-9.0 SOURCE: Halox Pigments: SugQested Formulation DOW/BW-100
  • 130.
    126 Water-Based PaintFormulations A l k v d M o d i f i e d Latex Primer I n g r e d i e n t : Pigment G r i n d : Water Busperse 39/Dispersant Bubreak 448/Defoamer (Premix n e x t 2 items) Water QP-15000 Cellosize/Hydroxyethyl I g e p a l CTA 639/Surfactant Aroplaz 1271/Long O i 1 A1kyd B u t r o l 23/Modified Barium Meta- b o r a t e Ti-Pure R-SOO/Titanium Dioxide- R u t i l e M i ca-325 Atomi t e / C a l c i um Carbonate N y t a l 300/Talc-Magnesium S i l i c a t e L e t Down: Rhoplex MV-23/Acrylic Emulsion Texanol/Ester Alcohol Ethylene G l y c o l Water Pai n t P r o p e r t ies : T o t a l V e h i c l e 60.27 Pigment 39.73 V o l a t i l e 42.67 Organic Solvent 7.59 Non-Volati l e 57.33 Non-Volati 1e V e h i c l e 17.60 Density (lb/U.S. gal): 11.99 S p e c i f i c G r a v i t y : 1.44 P.V.C.: 43.42% P/B R a t i o : 2.258 Spread @ 1 M i l : 624 F2 Coating VOC: 220 G/L M a t e r i a l VOC: 109 G/L C e l l u l o s e -Lb 100.10 8.01 3.00 25.02 1 .oo 6.01 42.04 100.10 200.19 25.02 75.07 75.07 483.46 5.00 30.03 20.02 w 83.10 16.90 61.07 10.58 38.93 22.02 Gal 12.02 0.74 0.44 3.00 0.09 0.68 5.01 3.25 6.01 1.06 3.32 3.17 54.94 0.63 3.23 2.40 Wt% 8.35 0.67 0.25 2.09 0.08 0.50 3.51 8.35 16.69 2.09 6.26 6.26 40.32 0.42 2.50 1.67 SOURCE: Buckman L a b o r a t o r i e s : Formulat on Sugges ion: KR-01
  • 131.
    Primers 127 Ancamide 2353Curina Aaent Anti-Corrosive Primer Preliminary Formulation P a r t A: L i q u i d DGEBA Epoxy MPA-1078 (Rheox) Mix w e l l , then add a t h i g h speed: T i Pure R-900 ( DuPont) 10 Wollastekup AS (Nyco) Disperse t o 5 Hegman and 125F. Reduce speed and add: !&J 233.7 4.0 25.0 370.0 Xylene (Ashland) 45.0 Part B: Ancamide 2353 ( A i r Products) MPA-1078 (Rheox) Beetle 216-8 (Cyanamid) 125.54 4.0 15.0 Mix w e l l a t high speed, then add: Red I r o n Oxide 5-3100 (Mineral Pigments) 60.0 Beaverwhite 325 (Cyprus) 96.7 Phospl us 5-0866 (Mi neral Pigments) 141.4 Disperse t o 5 Hegman and 125F. Reduce speed and add: Diacetone Alcohol (Union Carbide) Super High F1ash Naphtha (Ash1and) 31.3 106.8 Gal 24.093 0.541 0.751 15.289 6.207 15.212 0.541 1.724 1.441 4.204 5.065 3.997 14.691 Properties: Volume Sol i d s : 71.8% VOC: <2.1 l b / g a l PVC: 39.7% Mixing Ratio: 1:l by Volume CPVC: 54.6% Pot L i f e , h r : 3 PVC/CVPC : 0.725 Dry t o Touch, h r : 1 Weight/gallon. Part A: 14.45 Dry Through, h r : 6 Weight/gallon, Part B: 12.45 Weight/gal lon: 13.45 SOURCE: A i r Products and Chemicals, I n c . : Ancamide 2353 Curing Agent: Table 9 Formulation
  • 132.
    I28 Water-Based PaintFormulations Anquami ne 401/Semi -sol i d Epox D i s p e r s i on ___Lead and Chromate F r e e Red IronYOxide P r i m e r P a r t A* Dow XUS19000.01 Epoxy Resin Benzyl A l c o h o l Water P a r t B: Anquamine 401 C u r i n g Agent Water G l a c i a l A c e t i c A c i d ( A i r P r Red I r o n Oxide** LVT 400 T a l c ( B a r r e t t ) W a l l a s t o k u p I O E S (Nyco) Zeospheres 400 (3M) Halox SZP 391 Dowanol PM S o l v e n t (Dow) Dowanol PnP S o l v e n t (Dow) & @& 223.79 23.11 1 1 . 1 7 1.28 213.66 25.60 ( A i r P r o d u c t s ) 111.95 80.05 o d u c t s ) 2 . 1 0 62.98 125.94 139.95 62.98 76.96 32.18 33.59 1 2 . 2 5 9 . 5 9 0 . 2 4 I . 5 7 5.29 5 . 7 8 3.43 3.07 4.23 4.55 * A l t e r n a t e l y use Epi-Rez 3515-W-60 a t same l o a d i n g * * A l t e r n a t i v e l y use T i 0 2 f o r o f f - w h i t e p r i m e r T y p i c a l P r o p e r t i e s : W t S o l i d s ( % ) : 6 5 . 9 6 Volume S o l i d s (%): 51.17 PVC ( % ) : 37.4 Resin S t o i c h i o m e t r y : 1 . 6 : 1 VOC ( l b / g a l ) : 1 . 2 1 VOC ( g / l ) : 145 A n t i c o r r o s i v e Primer P r o p e r t i e s : Pot L i f e , h r : 4 M i x R a t i o : 1 : l Tack Free Time, h r : 1 . 0 Hard D r y Time, h r : 6 VOC, l b / g a l : 1 . 2 Volume S o l i d s , %: 51 PVC, %: 37 Cross Hatch Adhesion: 5 1/4" Mandrel Bend: Fai 1 D i r e c t Impact Resi stance, in-1 bs: 20 D i r e c t Impact Resi stance, in-1 bs: (5 SOURCE: A i r P r o d u c t s and Chemicals, I n c . : Anquamine 401 C u r i n g Agent: F o r m u l a t i o n 3
  • 133.
    Primers 129 Anquami ne401/Soli d Resi n D ispersi on Lead and Chromate Free Red I r o n Oxide Primer Part A: Epi-Rez 3520-WY-55 Epoxy Resin ( S h e l l ) Benzyl Alcohol Surfynol DF-58 Defoamer ( A i r Products) Water Red I r o n Oxide Barium S u l f a t e lOES Wollastokup (Nyco) Halox SW-1116 Zeosphere 4007 (3M) Water Ground Mica !=& 342.6 8.9 4.0 61.6 73.0 72.8 109.4 100.0 73.0 10.3 High speed disperse t o a t e x t u r e of N.S., then add: Epi -Rez 3520-WY-55 Epoxy Resi n (She11) 129.3 Water 22.1 Part 8 : Anquamine 401 Curing Agent ( A i r Products) 60.7 Water 111.8 Typical Properties: W t S o l i d s (%I: 63.1 Volume S o l i d s (%): 47.3 PVC (%): 35.1 Resin Stoichiometry (on equivalents): 1.6:1 VOC ( l b / g a l ) : 1.02 voc ( g / l ) : 122.5 Pot L i f e , h r : 4 Mix Ratio: 4 : l Tack Free Time, h r : 0.5 Hard Dry Time, h r : 6 VOC, l b / g a l : 1 . 0 Volume S o l i d s , %: 47 PVC, %: 35 Cross Hatch Adhesion: 4 Pencil Hardness, overnight: HB Pencil Hardness, 7 days: H 1/4” Mandrel Bend: F a i l D i r e c t Impact Resistance, i n - l b s : 35 Reverse Impact Resistance, i n - l b s : t5 A n t i c o r r o s i v e Primer Properties: SOURCE: A i r Products and Chemicals, I n c . : Anquamine 401 Agent: Formulation 4 37.65 1.03 0.48 7.39 1.79 1.99 4.52 4.20 3.65 0.44 14.21 2.65 6.58 13.42 Curing
  • 134.
    130 Water-Based PaintFormulations Corrosion Inhibitive Primer Material: j& Add to mixer with agitation: Water 98.6 Bubreak 448--Defoamer 2.0 Busperse 39--Dispersant 5 . 0 Igepal CTA-639 2.0 Premix and add the following: Natrosol 250HR 2.0 Water 6.0 Stir in the following pigments: Atomite 135.0 Ti-Pure R-900 100.0 Busan 11-M1 50.0 High speed disperse to minimum 5.0 NS grind Let down with the following materials: Aquamac 700 570.0 Texanol 69.0 Butrol 35--Flash rust inhibitor 7.0 Parameters: Properties: Weight Solids: 52.9% Viscosity: 80-85 KU Volume Solids: 40.5% DH: 8.4-8.6 Gals 11.83 0.30 0.46 0.23 0.40 0.72 5.97 3.08 1.82 65.82 8.75 0.63 Pigment Weight: 27.4% Gloss (a 60: 18-22 PVC: 27.9% P/B Ratio: 1.08 VOC Level: 174 g/L Metal Wash Primer With today‘s concern over coatings containing chromate pig- ments, there is a need for a chromate-free metal wash primer. Buckman Laboratories has developed a metal wash primer made with Busan 1 1 4 1 , which is a non-lead, non-chromate anticorrosive pigment. This formula is based on the military specification coating MIL-P-15328C entitled “Primer (Wash) Pretreatment Blue.” This specification is the same a s the U . S . Navy Formula 117-8 for metals. The Busan 11-M1 based primer has performed well in tests versus the traditional zinc chromate primer. The formula is as follows: Resin Component (80 gal lonsl: Lbs/100 Gals Polyvinyl-Butyral Resin (Ucar XYHL) 56 Busan ll-Ml 50 Ti-Pure R-900, Titanium Dioxide 50 Copper-Phthalocyanine Blue 17 Butyl Alcohol, Normal 125 Isopropyl Alcohol 341 Water 15 Acid Component (20 aallons): Phosphoric Acid, 85% 28 Water 25 Isopropyl Alcohol 99 Package separately: The mixed container must be used within SOURCE: Buckman Laboratories: Suggested Formulations 8 hours after mixing.
  • 135.
    Primers 131 Cost Ef f e c t i v e 2K Water-Base Epoxv Primer Usina Halox SW-111 Component A: Lbs./100 G a l s . Grams/Li t e r Add t h e f o l l o w i n g i n o r d e r l i s t e d : €pi-Rez 5522-WY-55 450.0 540.0 D i acetone A l c o h o l 7.0 8.4 Water 100.0 120.0 Nopco NDW 2.0 2 . 4 Mix f o r 5 minutes and add t h e f o l l o w i n g w h i l e m i x i n g a t h i g h speed : R . I . O . R-4098 Halox SW-111 Wol 1astokup 1OES Sparmi t e 100.0 50.0 150.0 100.0 120.0 60.0 180.0 120.0 High speed d i s p e r s e t o 5+ Hegman g r i n d . Then add t h e f o l l o w i n g s l o w l y w h i l e m i x i n g . Do n o t a e r a t e ! Epi r e z 5522-WY-55 Water Component B: Mix a t l o w speed: € p i -Cure 8290-Y-60 Nacorr 1754 30.0 36.0 25.0 30.0 Lbs. / l o 0 Gals. Grams/L ite r 60.0 72.0 3 . 0 3.6 A d d t h e f o l l o w i n g raw m a t e r i a l s i n o r d e r l i s t e d w h i l e m i x i n g a t h i g h speed: Zeeospheres 400 325 Mesh W.G. Mica 100.0 10.0 120.0 12.0 High speed d i s p e r s e t o 4+ Hegman g r i n d . Then add t h e f o l l o w i n g s l o w l y w h i l e m i x i n g . Do n o t a e r a t e ! Water M i x r a t i o : * Component A - Component B - *TO o b t a i n optimum r e s u p r i o r t o a p p l i c a t i o n . Formula Constants: % P i gment/Wt. : 41.65 % Pigment/Vol.: 18.78 % S o l i d s / W t . : 65.81 % Sol i d s / V o l . : 49.66 % PVC: 37.81 P/B R a t i o : 1.72 VOC, l b s . / g a l . : 1.25 voc, g/L: 150.00 40.0 48.0 80% by volume. 20% by volume. t s , a l l o w 20-30 minutes i n d u c t i o n t me Formula P r o p e r t i e s : D e n s i t y l b s . / g a l . : 12.25 D e n s i t y g/L: 1,470.0 Set-to-touch: 30 minutes Dry Hard: Overnight SOURCE: Halox Pigments: Suggested F o r m u l a t i o n
  • 136.
    I32 Water-Based PaintFormulations D ippi na Primer I n g r e d i e n t s : P i oment Grind: Oeioni zed Water Ammoni um Hydroxi de, 28% Aqueous Sol u t i on Dispersant ( 1) T e r g i t o l Surfactant NP-10 Antifoam (2) T i t a n i um Dioxide (3) Barytes (4) Strontium Chromate ( 5 ) Let Down: Ucar Vehicle 443 Antifoam ( 2 ) B u t y l Cellosolve Solvent B u t y l C a r b i t o l Solvent Hexamethoxymethylmelamine (6) Ammonium Benzoate, 10% Aqueous S o l u t i o n Ammonium Hydroxide, 28% Aqueous S o l u t i o n Oeioni zed Water Suppliers: Pounds 41.6 0.2 1.6 3.2 0 . 7 50.0 53.1 57.7 500.0 0.8 51.5 20.6 54.7 8.5 6.5 127.1 Gal l o n s 5.00 0.02 0.22 0.36 0.09 1.so 1.45 1.87 57.52 0.11 6.86 2.60 5.47 0.93 0.74 15.26 o r equi valent . (Oavis/MPC) o r equivalent. Cyme1 303 (American Cyanamid) (1) Dispersant - Bykumen WS (Byk-Mallinckrodt) o r equivalent. ( 2 ) Antifoam - Hodag PX-218 (Hodag) o r equivalent. (3) Titanium Dioxide - Ti-Pure R-960 (Du Pont) o r equivalent. (4) Barytes - Sparmite ( P f i z e r ) (5) Strontium Chromate - 5-1365 (6) Hexamethoxymethylmelamine - o r equivalent. Primer Properties: Solids, % by w t : 37.4 pH: 9.5 V i s c o s i t y , B r o o k f i e l d , cP: 800 Add Water t o 18 sec (#3 Zahn Cup) f o r dipping. Primer Performance:* Bake Cycle, min: S a l t Spray: Flash Time: 10 Hours Exposed: 565 Bake a t 200F: 2.5 Rusting Rating: 9 F i n a l Bake a t 300F: 10 B l i s t e r Rating: 9M Pencil Hardness: 2H Creepage, i n : 1/8 Gloss, 60: 30 Impact Resistance, i n - l b : D i r e c t : 45 Reverse: 5 *Substrate - Bonderite 1000 SOURCE: Ucar Emulsion Systems: Ucar Vehicle 443: Formulation Suggestion C-2030
  • 137.
    Primers 133 Experimental GeneralPurpose Tannin-Stain Resistant Water-Base Primer Usina Halox X t a i n A Grind: Water Natrosol 250 MR Aqua Ammonia (28%) Ethylene G1ycol Tamol 681 T r i t o n CF-10 Foamaster VL Halox X t a i n A Snowf 1ake R-902 Lbs. / l o 0 Gals. Gms/Li t e r 100.00 120.00 0.75 0.90 1.oo 1.20 30.00 36.00 15.00 18.00 3.00 3.60 2.00 2.40 150.00 180.00 15.00 18.00 220.00 264.00 High speed disperse t o 4+ NS g r i n d . Water 25.00 30.00 Letdown : Mor-Lok 1035 Skane M-8 Aqua Ammonia (28%) Texanol Foamaster VL 467.00 560.40 2.00 2.40 1 .oo 1.20 5.00 6.00 1.oo 1.20 Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l uniform. QR-708 Water Add t h e f o l l o w i n g w h i l e mixing and mix u n t i l uniform 5.50 79.00 Properties: l b s . / g a l . : 1 Formula Constants: % P i gment/Wt .: 34.36 % Pigment/Vol .: 15.03 % Solids/Wt.: 55.81 % S o l i d s / V o l . : 40.73 % PVC: 36.89 VOC, l b s . / g a l . : 1.10 VOC, gms./l.: 132.04 Formula Density Density PH @ R. KU Visc SOURCE: Halox Pigments: Suggested Formu .23 gms./i.: 1,346.7 .: 9.0-9.5 @ R . T . : 95-100 a t i o n MOR-1035-A 6.60 94.80
  • 138.
    134 Water-Based PaintFormulations ExDerirenta1 Hiph Performance Tanni n-Stai n Resistant Water-Base Primer Usina Halox X t a i n A Grind: Lbs./100 Gals. Gms/Liter Water 125.00 150.00 Natrosol 250 MR Aqua Ammonia (28%) E t h y l ene G1ycol Tamol 681 T r i t o n CF-10 Foamaster VL Halox X t a i n A Snowf 1ake High speed disperse t o 4+ NS g r i n d Water Letdown : Mor-Lok 1043 Skane M-8 Aqua Ammonia (28%) Texanol Foamaster VL R-902 0.75 1.00 30.00 18.00 3.00 2.00 150.00 5.00 277.00 25.00 434.00 2.00 1 .oo 4.75 1 .oo 0.90 1.20 36.00 21 - 6 0 3.60 2.40 180.00 6.00 332.40 30.00 520.80 2.40 1.20 5.70 1.20 Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l uniform. Add t h e f o l l o w i n g w h i l e mixing and mix u n t i l uniform. QR-708 Water Formula Constants: % P i gment/Wt .: 37.60 % P i gment/Vol .: 17.11 % Solids/Wt.: 57.21 % S o l i d s / V o l . : 41.18 % PVC: 41.55 VOC, l b s . / g a l . : 1.13 VOC, gms./l.: 134.92 5.50 6.60 66.00 79.20 Formula P r o p e r t i e s : Density 1bs. / g a l . : 11.51 Density gms. /l.: 1,381.2 KU Visc. @ R.T.: 90-95 pH @ R.T.: 9.0-9.5 SOURCE: Halox Pigments: Suggested Formulation MOR-1043-A
  • 139.
    Primers 135 Experimental WaterbaseA c r y l i c Red I r o n Oxide Primer G r i n d : Water Methyl Carbi t o 1 Tamol 165 T r i t o n CF-10 Drew L-493 Snowf 1ake AMP-95 R . I . O . R0-4097 Lbs./100 Gals. Gms/Liter 63.0 75.6 52.0 62.4 10.0 12.0 3.0 3 . 6 3.0 3 . 6 1.o 1 . 2 50.0 60.0 250.0 300.0 0 40.0Halox SZP-391 33. High speed d i s p e r s e t o 4+ NS g r i n d . Water 25. Letdown : Mai n c o t e HG-54 Texanol D i b u t y l P h t h a l a t e Drew L-493 Aqua Ammonia (28%) Raybo 60 510. 4. 12 3 1 5 Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l un A c r y s o l RM-1020 Water M i x u n t i l u n i f o r m . Formula Constants: % Pigment/Wt.: 31.58 % Pigment/Vol.: 13.81 % S o l i d s / W t . : 52.35 % S o l i d s / V o l . : 38.97 ?6 PVC: 35.41 VOC, l b s . / g a l . : 1.72 VOC. g/L: 206.40 0 30.0 0 612.0 0 9 5 5 0 form. 10.0 26.0 Formula P r o p e r t i e s : D e n s i t y l b s . / g a l . : 10.63 D e n s i t y g/L: 1,275.9 KU V i s c . B R.T.: 90-95 pH @ R.T.: 8.0-9.0 4.8 15.5 4.2 1.8 6.0 12.0 31.2 SOURCE: Halox Pigments: Suggested F o r m u l a t i o n HG54-391
  • 140.
    136 Water-Based PaintFormulations Experimental Waterbase A c r y l i c G r i n d : Water Methyl Carbi t o 1 Tamol 165 T r i t o n CF-10 Drew L-493 Red I r o n Oxide S n o w f 1ake Halox BW-191 L e t Down: Mai n c o t e HG54 Texanol O i b u t y l P h t h a l a t e Drew L-493 Ammoni um Hydroxi de Sodium N i t r i t e Water Ucar Thickener SCT 28% 200 Red Iron Oxide P r i m e r ~ _ _Pounds _____G a l l o n s 63.00 7.56 52.00 6.11 12.30 1 .26 3.00 0.34 1 .oo 0 . 1 4 57.40 1.34 192.60 8 . 5 6 100.00 4.21 510.00 60.00 4.00 0 . 5 0 12.90 1.48 3 . 6 0 0.50 1 . 7 0 0.24 8 . 4 0 1 . 0 1 49.00 5.90 7.50 0 . 8 5 D e n s i t y l b s / g a l : 10.78 % W t . S o l i d s : 5 3 . 5 % V o l . S o l i d s : 40.0 % PVC: 3 5 . 0 V i s c o s i t y : 90-95 KU @ 77F SOURCE: Halox Pigments: Suggested F o r m u l a t i o n
  • 141.
    Primers 137 ExDerimental WaterbaseA c r y l i c Red I r o n Oxide P r i m e r G r i n d : Water Methyl C a r b i t o l Tamol 165 T r i t o n CF-10 Drew L-493 Snowflake AMP-95 R. I.0 . R0-4097 Halox CW-491 Lb.s Jl_O 0. G31-s .. Gms/ L1 t_er 6 3 . 0 75.6 5 2 . 0 6 2 . 4 10.0 1 2 . 0 3 . 0 3.6 3 . 0 3 . 6 1 . o 1 . 2 5 0 . 0 6 0 . 0 225.0 270.0 6 6 . 0 7 9 . 2 H i g h speed d i s p e r s e t o 4+ NS g r i n d Water 2 5 . 0 30 t 0 Letdown : Mai n c o t e HG-54 Texanol D i b u t y l P h t h a l a t e Drew L-493 Aqua Ammonia (28%) Raybo 60 .310.0 6 1 2 . 0 4 . 0 4 . 0 12 9 1 5 . 5 3 . 5 4 . 2 1 . 5 1 . 8 5 . 0 6.0 Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l un7form. A c r y s o l RM-1020 Water Mix a n t i i u n i f o r m Formula Constants: % Pigment/Wt.: 31 .99 % Pigment/Vol . : 13.93 % S o l i d s / W t . : 52.62 % S o l i d s / V o l . : 39.05 % PVC: 35.66 VOC, l b s . / g a l : 1 . 7 0 VOC, g/L: 204.00 1 0 . 0 12.0 26.0 31 . 2 Formula P r o p e r t i e s : D e n s i t y l b s . / g a l . : 10.71 D e n s i t y g/L: 1,285.1 KU V i s c . @ R.T.: 95-100 pH @ R . T . : 8 . 0 - 9 . 0 SOURCE: Halox Pigments: Suggested F o r m u l a t i o n HG54-491
  • 142.
    138 Water-Based PaintFormulations E x t e r i o r House P a i n t Primer Iflared> entss: Pigment G r i n d : Water Ucar Polyphobe 102 Rheo. Mod. Ammonium Hydroxide, 28% Aqueous S o l u t i o n Nuosept 95 Col l o i d 226/35 Propylene Glycol C o l l o i d 640 T r i t o n Nonionic S u r f a c t a n t N-101 Kronos 2310 Halox BW-100 Nicron 400 Letdown : Water ) Ucar Polyphobe 102 )Premix Ucar Latex 625 C o l l o i d 640 B u t y l Carbi t o 1 Sol vent NuoCide 404-D T r i t o n Nonionic S u r f a c t a n t CA Ammonium Hydroxide, 28% Aqueous S o l u t i o n P a i n t P r o p e r t i e s : Pigment Volume Concentration, %: 32.0 Volume S o l i d s , %: 40.0 Weight S o l i d s , %: 54.5 V i s c o s i t y , e q u i l i b r a t e d : Stormer, KU: 90 I C I , Poise: 1.45 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Aged S t a b i l i t y , 120F, weeks passed: 2 F i l m P r o p e r t i e s : Contrast R a t i o , 6-mil wet drawdown: 0.96 Ref1ectance, %: 88.3 Sheen, 85: 19.9 Tannin S t a i n Resistance: Cedar and Redwood: Very Good Pounds 150.4 8.7 1.9 2 . 3 10.2 25.9 1 . 9 2.1 125.0 100.0 113.5 8.3 8 . 7 508.6 1 . 9 12.7 10.3 2.1 1 . 9 Gal l o n s 18.05 1.oo 0.25 0.25 1.oo 3.00 0.25 0.25 3.65 4.37 4.78 1 .oo 1 .oo 57.80 0.25 1.60 1 .oo 0.25 0.25 SOURCE: U c a r Emulsion Systems: U c a r Latex 625: Formulation Suggestion E-2456
  • 143.
    Primers 139 E xt e r i o r House P a i n t Primer Based On Ucar Latex 163 I nqredie n t s : Pigment Grind: Water C e l l o s i z e Hydroxyethyl C e l l u l o s e Nuosept 95 Col 1o i d 226/35 C o l l o i d 640 T r i t o n Nonionic S u r f a c t a n t N-101 Propylene Glycol Tronox CR-828 Nicron 400 Talc Halox EW-100 ~~Pounds Gal l o n s 244.7 29.37 ER-30,000 3.5 0.32 2 . 3 0.25 10.5 I .oo 1 . 9 0.25 2.1 0.25 25.9 3.00 125.0 3.65 113.5 4.76 100.0 4.37 Letdown : Ucar Latex 163 437.5 49.16 Ucar F i l m e r IET 12.7 1.60 C o l l o i d 640 1.9 0.25 NuoCi de 404-D 10.3 1 .oo T r i t o n Nonionic S u r f a c t a n t CA 2 . 1 0.25 Ammonium Hydroxide, 28% Aqueous S o l u t i o n 3.8 0.50 P a i n t P r o p e r t i e s : Pigment Volume Concentration, %: 32.0 Volume S o l i d s , %: 40.0 Weight S o l i d s , %: 54.0 Weight per Gallon, l b : 11.0 Stormer, KU: 86 I C I . poise: 1 .O pH, i n i t i a l : 8 . 5 Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks a t 120F: Pass F i l m P r o p e r t i e s : Reflectance, %: 88.3 Sheen, 85: 11.6 Contrast R a t i o , 6-mil bar: 0.96 Tannin S t a i n Resistance cedar and redwood: Very Good SOURCE: Ucar Emulsion Systems: Formulation Suggestion E-2457
  • 144.
    140 Water-Based PaintFormulations General Purpose Latex Maintenance Primer -Ingredients: Pigment Grind: Water Busperse 39/Dispersant Bubreak 448/Defoamer !& 105.91 8.47 3.18 (Premix next 2 items) Water 26.48 QP-15000 Cellosize/Hydroxyethyl Cellul ose 1.06 Igepal CTA 639/Surfactant 6.35 Aroplaz 1271/Long Oi 1 A1 kyd 40.47 Butrol 23/Modified Barium MetaboratelO5.91 Ti -Pure R-SOO/Titanium Dioxide- Rutile 211.83 Mi ca-325/Potassium A1 uminum Si 1 i cate 26.48 Atomite/Calcium Carbonate 17.71 Nytal 3OO/Talc-Magnesium Silicate 17.71 Let Down: Rhoplex MV23/Acrylic Emulsion 511.57 Texanol/Ester Alcohol 5.30 Ethylene Glycol 31 .77 Water 21 .18 Paint Properties: %wt .__%VOl Total Vehicle 66.65 87.45 Pigment 33.35 12.55 Volatile 47.08 64.15 Organic Solvent 8.08 10.71 Non-Volatile 52.92 35.85 Non-Volatile Vehicle 19.56 23.20 Density (lb/U.S. gal): 11.41 Specific Gravity: 1 .37 P.V.C.: 35.00% P/B Ratio: 1.705 Spread I3 1 M i l : 575 F2 Coating VOC: 237 G/L Material VOC: 1 1 1 G/L Gal 12.71 0.79 0.47 3.18 0.09 0.72 4.82 3.44 6.36 1.13 0.78 0.75 58.13 0.67 3.41 2.54 Wt% 9.28 0.74 0.28 2.32 0.09 0.56 3.55 9.28 18.56 2 . 3 2 1.55 1.55 44.82 0.46 2.78 1 .86 SOURCE: Buckman Laboratories: Formulation Suggestion: KR-02
  • 145.
    Primers 141 General PurposeJL0.wC o s t Water-Base Primer G r i n d : Water B u t y l C e l l o s o l v e Tamol 165 T r o y s o l LAC Drew L-493 AMP-95 Lbs./100 G a l s . G m s i l i t e r 150.0 180.0 2 9 . 0 3 4 . 8 1 5 . 0 1 8 . 0 3 . 0 3 . 6 3 . 0 3 . 6 1 . o 1.2 Add t h e f o l l o w i n g a t h i g h speed and d i s p e r s e t o 5 Hegman g r i n d . Y . I . O . YO-2087 Halox CW-491 N y t a l 400 Letdown : Water Mai n c o t e PR-71 D i b u t y l P h t h a l a t e Aqua Ammonia (28%) Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t add t h e f o l l o w i n g i n o r d e r l i s t e d : Ethanol 95% Raybo 60 Add s l o w l y w h i l e m i x i n g a t h i g h speed. Do n o t QR-700 A c r y s o l RM-1020 Mix u n t i l u n i f o r m . 5 0 . 0 60.0 100.0 1 2 0 . 0 2 5 0 . 0 300.0 9 3 . 0 111 . 6 380.0 456.0 5 . 7 6 . 8 3 . 0 3 . 6 1 u n i f o r m . Then 14.5 1 7 . 4 5 . 0 6 . 0 a e r a t e ! 5 . 0 6 . 0 2 . 0 2 . 4 Formula C o n s t a n t s : % P i gment/Wt . : 36.05 % P i g m e n t / V o l . : 16.29 % S o l i d s / W t . : 54.20 % S o l i d s / V o l . : 31 .35 % PVC: 42.63 VOC, l b s . / g a l . : 1 . 5 4 VOC, g/L: 184.68 Formula P r o p e r t i e s : D e n s i t y 1b s . / g a l . : 11 .09 D e n s i t y g/L: 1 , 3 3 1 . 0 KU V i s c . @ R . T . : 90-95 p H @ R . T . : 9 . 0 - 9 . 5 SOURCE: Halox Pigments: Suggested F o r m u l a t i o n PR-71/491A
  • 146.
    142 Water-Based PaintFormulations H i q h Performance Bare M e t a l Primer G r i nd : Water B u t y l C e l l o s o l v e Tamol 165 T r o y s o l LAC Drew L-493 AMP-95 Lbs./100 Gals. Gms/Liter 92.0 110.0 35.0 42.0 10.0 1 2 . 0 2.0 2 . 4 3 . 0 3 . 6 1.o 1.2 Add t h e f o l l o w i n g a t h i g h speed and d i s p e r s e t o 5 Hegman g r i n d . Y . I . O . YO-209 Halox SZP-391 N y t a l 400 Letdown : Water Mai n c o t e PR-7 D i b u t y l Phtha Aqua Ammonia a t e 28%) 50.0 60.0 50.0 60.0 125.0 150.0 112.0 134.5 470.0 564.0 7.0 8 . 4 3.0 3 . 6 Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l u n i f o r m . Then add t h e f o l l o w i n g i n o r d e r l i s t e d . Ethanol 95% Raybo 60 18.0 2 1 . 6 5.0 6 . 0 Add s l o w l y w h i l e m i x i n g a t h i g h speed. Do n o t a e r a t e ! QR-708 A c r y s o l RM-1020 Mix u n t i l u n i f o r m . Formula Constants: % P i gment/Wt. : 22.51 % P i gment/Vol .: 8.76 % S o l i d s / W t . : 47.26 % Sol ids/Vol . : 35.78 % PVC: 24.48 VOC, l b s . / g a l . : 1.85 VOC, g/L: 222.13 12.0 14.4 5 . 0 6.0 Formula P r o p e r t i e s : D e n s i t y Lbs ./ g a l . : 10.00 D e n s i t y g/L: 1,199.7 KU ViSc. @ R.T.: 90-95 PH @ R.T.: 9.0-9.5 SOURCE: Halox Pigments: Suggested F o r m u l a t i o n PR-71/391BM
  • 147.
    Primers 143 Hitah PerformanceGalvanized Metal Primer Grind: Water Butyl Cellosolve Tamol 165 Troysol LAC AMP-95 Drew L-493 Lbs./100 Gals. Gms/Liter 92.0 110.0 35.0 42.0 1 0 . 0 1 2 . 0 2 . 0 2 . 4 3 . 0 3 . 6 1.o 1 . 2 Add the following at high speed and disperse to 5 Hegman grind. Y.I.O. YO-2087 Halox SZP-391 Shieldex Nytal 400 Letdown : Water Mai ncote PR-71 Dibutyl Phthalate Aqua Ammonia (28%) 50.0 60.0 50.0 6 0 . 0 25.0 30.0 100.0 120.0 106.5 128.0 470.0 564.0 7 . 0 8 . 4 3 . 0 3 . 6 Add grind portion under agitation and mix until uniform. Then add the following in order listed: Ethanol 95% Raybo 60 18.0 21 . 6 5.0 6 . 0 Add slowly while mixing at high speed. Do not aerate! OR-708 Acrysol RM-1020 Mix until uniform. Formula Constants: % P i gment/Wt .: 22.63 % Pigment/Vol . : 9 . 3 7 % Solids/Wt.: 47.50 % Solids/Vol.: 36.59 % PVC: 25.75 VOC, lbs./gal.: 1 . 8 3 VOC, g/L: 219.19 1 2 . 0 1 4 . 4 5 . 0 6 . 0 Formula Properties: Density lbs./gal.: 9 . 9 5 Density g/L: 1 , 1 9 3 . 2 KU Visc. @ R.T.: 90-95 pH @ R.T.: 9.0-9.5 SOURCE: Halox Pigments: Suggested Formulation PR-71/391GM
  • 148.
    144 Water-Based PaintFormulations H i g h Performance 2 K Water-Base Epoxy P r i m e r Component A : Add t h e f o l l o w i n g i n o r d e r l i s t e d O i a c e t o n e A l c o h o l Water Nopco NDW M i x f o r 5 m i n u t e s and add t h e f o l speed. Eai-Rez 5522-WY-55 R . I . O . R-4098 H a l o x SZP-391 Wol 1a s t o k u p 1 OES Sparmi t e Lbs. / l o 0 G a l s . Gms(L1 t e r 450.0 540.0 7.0 8 . 4 1 0 0 . 0 1 2 0 . 0 2 . 0 2 . 4 o w i n g w h i l e m i x i n g a t h i g h 1 0 0 . 0 120.0 5 0 . 0 6 0 . 0 1 5 0 . 0 180.0 1 0 0 . 0 1 2 0 . 0 H i g h speed d i s p e r s e t o 5+ Hegman g r i n d . Then add t h e f o l l o w i n g s l o w l y w h i l e m i x i n g . DO NOT AERATE' Epi-Rez 5522-WY-55 Water Component 8 : M i x a t l o w speed: Epi -Cure 8290-Y-60 N a c o r r 1754 3 0 . 0 3 6 . 0 2 5 . 0 30.0 Lbs. / l o 0 Gal s . Gms/Li t e r 6 0 . 0 7 2 . 0 3 . 0 3 . 6 Add t h e f o l l o w i n g raw m a t e r i a l s i n o r d e r l i s t e d w h i l e m i x i n g a t h i g h speed: Zeeospheres 400 1 0 0 . 0 120.0 325 Mesh W.G. M i c a 1 0 . 0 1 2 . 0 H i g h speed d i s p e r s e t o a 4 t Hegman g r i n d . Then add t h e f o l l o w i n g s l o w l y w h i l e m i x i n g . DO NOT AERATE! Water 4 0 . 0 48.0 M i x R a t i o : * Component A : 80% b y volume. Component 8 : 20% b y volume. *To o b t a i n optimum r e s u l t s , a l l o w 20-30 m i n u t e s i n d u c t i o n t i m e p r i o r t o a p p l i c a t i o n . Formula C o n s t a n t s : % Pigment/Wt. : 41.63 % P i g m e n t / V o l . : 1 8 . 7 0 % S o l i d s / W t . : 6 5 . 7 7 % Sol id s / V o l . : 49.5% % PVC: 3 7 . 7 1 P / B R a t i o : 1 . 7 2 VOC, l b s . / g a l . : 1.32 VOC, g / L : 1 5 8 . 4 0 Formul a P r o p e r t i es : D e n s i t y l b s . / g a l . : 1 2 . 2 5 D e n s i t y g / L : 1 , 4 7 0 . 0 S e t - t o - t o u c h : 30 m i n u t e s D r y H a r d : O v e r n i g h t SOURCE: H a l o x Pigments: Suggested F o r m u l a t i o n Epi-Rez/BBl
  • 149.
    Primers 145 Hiah Performance2K Water-Base EDOXV Primer Using Halox SZP-391 Component A: Lbs./lOO Gals. Grams/Li t e r Add t h e f o l l o w i n g i n o r d e r l i s t e d : Waterpoxy 1401 E k t a s o l v e EP 375.0 450.0 30.0 36.0 M i x f o r 5 minutes and add t h e f o l l o w i n g w h i l e m i x i n g a t h i g h speed. R . I . O . R-4098 Halox SZP-391 Wollastokup 10ES N y t a l 400 100.0 75.0 100.0 150.0 120.0 90.0 120.0 180.0 High speed d i s p e r s e t o 5+ Hegman g r i n d . Then add t h e f o l l o w i n g s l o w l y w h i l e m i x i n g . Do n o t a e a r a t e ! Deionized water 240.0 288 * 0 Component 0 : Mix a t low speed. Waterpoxy 701 E k t a s o l v e EP Lbs./100 Gals. Grams/Li t e r 80.0 5.0 96.0 6.0 Mix r a t i o : * Component A - 90% b y volume. Component B - 10% b y volume. *To o b t a i n optimum r e s u l t s , a l l o w 20-30 minutes i n d u c t i o n t i m e p r i o r t o a p p l i c a t i o n . Formula Constants: % P i gment/Wt .: 36.75 % Pigment/Vol. : 15.80 % S o l i d s / W t . : 60.10 % Sol ids/Vol .: 43.96 % PVC: 35.93 P/B R a t i o : 1.57 VOC, l b s . / g a l . : 1.57 voc, g/L: 188.40 Formula P r o p e r t i e s : D e n s i t y 1bs. / g a l . : 11 .56 D e n s i t y g/L: 1,387.2 Set-to-touch: 30 minutes Dry Hard: Overnight SOURCE: Halox Pigments: Suggested F o r m u l a t i o n
  • 150.
    146 Water-Based PaintFormulations H i g h Performance 2K Water-Base Epoxy P r i m e r Usinq H a l o x SZP-391 Component A: Lbs./100 Gals. Grams/Li t e r A d d t h e f o l l o w i n g i n o r d e r l i s t e d : Epi-Rez 5522-WY-55 450.0 540.0 D i acetone A l c o h o l 7.0 8.4 Water 100.0 120.0 Nopco NDW 2.0 2.4 Mix f o r 5 m i n u t e s and add t h e f o l l o w i n g w h i l e m i x i n g a t h i g h speed : R . 1 . O . R-4098 Halox SZP-391 W o l l a s t o k u p lOES Sparmi t e 100.0 50.0 150.0 100.0 120.0 60.0 180.0 120.0 H i g h speed d i s p e r s e t o 5+ Hegman g r i n d . Then add t h e f o l l o w i n g s l o w l y w h i l e m i x i n g . Do n o t a e r a t e ! E p i -Rez 5522-WY-55 Water Component 8 : Mix a t l o w speed: € p i -Cure 8290-Y-60 30.0 36.0 25.0 30.0 Lbs./100 Gals. Grams/Li t e r 60.0 72.0 3.6Nacorr 1754 3 . 0 Add t h e f o l l o w i n g raw m a t e r i a l s i n o r d e r l i s t e d w h i l e mix h i g h speed: Zeeospheres 400 100.0 325 Mesh W.G. Mica 10.0 ng a t 20.0 12.0 H i g h speed d i s p e r s e t o 4+ Hegman g r i n d . Then add t h e f o l l o w i n g s l o w l y w h i l e m i x i n g . Do n o t a e r a t e ! Water 40.0 48.0 M i x R a t i o : * Component A - 80% b y volume. Component B - 20% b y volume. *To o b t a i n optimum r e s u l t s , a l l o w 20-30 m i n u t e s i n d u c t i o n t i m e p r i o r t o a p p l i c a t i o n . Formula C o n s t a n t s : Formula P r o p e r t i e s : 96 P i gment/Wt. : 41.63 D e n s i t y l b s . / g a l : 12.25 % Pigment/Vol . : 18.70 D e n s i t y g/L: 1,470.0 % S o l i d s / W t . : 65.77 S e t - t o - t o u c h : 30 m i n u t e s % Sol i d s / V o l . 49.58 Dry Hard: Over night % PVC: 37.71 P/B R a t i o : 1.72 VOC, l b s . / g a l . : 1.32 voc, g/L: 158.40 SOURCE: Halox Pigments: Suggested F o r m u l a t i o n
  • 151.
    Primers 147 H iq h S o l i d s Red I r o n Oxide EDOXY Primer M a t e r i a1 : P a r t A: Epon Resin 874-CX-90 B e e t l e 216-8 S h e l l Xylene S h e l l MIBK PGME A c e t a t e Z i n c Phosphate 5-0852 10 ES Wollastokup Sparmi t e M i croMi ca C-3000 Copperas R-5098 High Speed Disperse t o a T e x t u r e o f 5-6 N.S Bentone SD-2 P a r t B: Epi-Cure C u r i n g Agent 3140 S h e l l Xylene She11 n-Butanol Composite Blend: P a r t A P a r t B P a r t s A and B: V i s c o s i t y : 85 K.U. T y p i c a l C o a t i n g P r o p e r t i e s : T o t a l weight s o l i d s , p e r c e n t : 81.2 T o t a l v o l ume s o l i d s , p e r c e n t : 65.4 PVC, p e r c e n t : 35.0 I n d u c t i o n t i m e , minutes: 30 V o l a t i l e Organic Compounds (VOC): Pounds p e r g a l l o n : 2.43 Grams p e r l i t e r : 292 F i 1m ProDert ies : Pounds 263.0 12.0 75.5 60.4 15.1 176.5 176.5 233.5 38.8 38.7 9 . 3 132.0 42.9 18.4 1099.3 193.3 Gal l o n s 28.85 1.41 10.49 9.10 1 . 8 6 6 . 7 4 7.29 6.35 1.36 0.90 0 . 6 5 16.32 5.95 2.73 75.00 25.00 (Drawdown on CRS. Cured f o r 7 days a t 77F, 55% R.H.) Pigment: b i n d e r r a t i o : 1.72 C u r i n g agent p h r , on s o l i d s : 56 Pot l i f e ( h r s ; f r o m 85-130 KU): 6 Pounds/gallon: 12.92 Dry f i l m t h i c k n e s s : 1.5 m i l s S e t - t o - t o u c h d r y , h r s . : 1 . 0 C o t t o n - f r e e d r y , h r s . : 7.5 Through-dry, h r s . : 1 8 . 0 P e n c i l hardness: H Impact r e s i s t a n c e , (Di r ./Rev. ) : 52/4 F l e x i b i l i t y : Pass 1/4" Adhesion: SA S a l t spray t e s t i n g (500 h r s ) : 2F-2M Water r e s i s t a n c e (500 h r s a t 160F): 4M SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1819: Epon Resin 874-CX-Q0/Epi -Cure C u r i n g Agent 3140
  • 152.
    148 Water-Based PaintFormulations House P a i n t Primer I n g r e d i e n t s : Pigment Grind: Water C e l l o s i z e Hydroxyethyl C e l l u l o s e ER-30,000 Nuosept 95 Propylene Glycol Col 1o i d 226/35 T r i t o n Nonionic S u r f a c t a n t N-101 C o l l o i d 650 T i -Pure R-902 325 Mesh White Waterground Mica N y t a l 300 Letdown : Ucar Latex 624 Ucar F i l m e r IBT NuoCide 404D C o l l o i d 650 Ammonium Hydroxide, 28% Aqueous S o l u t i o n Pai n t Propert ies : Pigment Volume Concentration, %: 30.0 Volume Solids, %: 32.6 V i s c o s i t y , equi 1ibrated: Stormer, KU: 80 I C I , poise: 0.7 Weight per Gallon, l b : 10.54 Pounds 283.8 3.5 2.3 25.9 6.4 2.2 1 . 9 150.0 25.0 100.0 426.7 10.7 10.3 2.0 2.0 Gal 1ons 34.07 0.32 0.25 3.00 0.62 0.25 0.25 4.50 1.07 4.21 48.49 1.35 1 .oo 0.37 0.25 Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass F i l m P r o p e r t i e s : Contrast R a t i o , 6-mil wet drawdown: 0.948 R e f 1ectance, %: 88.7 Sheen, 85: 7.0 Flow and Leveling, brushed: Good Wet Adhesion: E x c e l l e n t Chalk Adhesion: E x c e l l e n t SOURCE: Ucar Emulsion Systems: Ucar Latex 824: Formulation Suggestion E-2425
  • 153.
    Primers 149 Lead M at e r i a l : P a r t A: Epi -Rez 5522-WY-55 Res D i acetone Alcohol Col 1o i d 640 Defoamer Water R0-4097 Kroma Red Sparmi t e l O E S Wollastokup Halox SW-111 and Chromate Free Primer n High speed disperse t o a t e x t u r e o f 6-7 N . S . Epi -Rez 5522-WY-55 Resin 15% Sodium N i t r i t e S o l u t i o n (Water) Water P a r t B: Epi-Cure 8290-Y-60 Curing Agent Water Zeeosphere 400 Water Ground Mica, 325 mesh High speed d i s p e r s e t o a t e x t u r e o f 4-5 N.S. Composite Blend: V i s c o s i t y P a r t A 114 K.U. P a r t B 101 K.U. P a r t s A and B 106 K.U. & 330.0 7.0 3 . 5 80.0 100.0 23.1 150.0 100.0 147.0 8.0 8 . 7 60.0 11.0 100.0 10.0 957.3 234.7 Gals 37.21 0.89 0.41 9.60 2.45 0.63 6.19 4.20 16.43 0.95 1 .04 6.80 1 .32 5.00 0.43 80.00 20.00 SOURCE: Shell Resins: S t a r t i n g Formulation No. 1818
  • 154.
    I50 Water-Based PaintFormulations Lead and Chromate Free Red I r o n Oxide Primer M a t e r i a l : P a r t A: Epi -Rez 5522-WY-55 Resin Oiacetone Alcohol Col 1o i d 640 Defoamer Water R0-4097 Kroma Red Sparmi t e 1OES Wol 1astokup Halox SW-111 High speed disperse t o a t e x t u r e o f 5-6 P.C.S Epi -Rez 5522-WY-55 Resin Water P a r t 8 : Epi-Cure 8290-Y-60 Curing Agent Water Zeeosphere Type 400 Water Ground Mica, 325 mesh High speed disperse t o a t e x t u r e o f 4-5 P.C.S Water Composite B P a r t A P a r t B Parts A and SOURCE: She end : 8 V i s c o s i t y 82 K.U. 101 K.U. 85 K.U. !=,& 330.0 7.0 3.5 80.0 100.0 100.0 150.0 50.0 147.0 16.6 60.0 11.0 100.0 10.0 53 984 234 1 Resins: S t a r t i n g Formulation No. 180 Gals 37.21 0.89 0.41 9.60 2.45 2.73 6.19 2.10 16.43 1.99 6.80 1.32 5.00 0.43 6.45 80.00 20.00
  • 155.
    Primers 151 Lead andChromate Free Waterborne EPOXY Primer Materi a1 : Part A: Epi -Rez 5522-WY-55 Resin D i acetone A1coho1 C o l l o i d 640 Defoamer Water R0-4097 Kroma Red, Red I r o n Oxide Sparmite Barium S u l f a t e lOES Wollastokup Halox SW-111 Zeeosphere 400 Water Groumd Mica, 325 Mesh High speed disperse t o t e x t u r e o f 5-6 N.S. € p i-Rez 5522-WY-55 Resin 15% Aqueous Sodium N i t r i t e S o l u t i o n Water P a r t 9: Epi-Cure 8292-Y-60 Curing Agent Water Composit e 81end : V i scosi t y P a r t A 122 K.U. Part B (#4 Ford cup, P a r t s A and B 68 K . U . Typical Coating Properties: 15.1 Seconds) T o t a l Weight S o l i d s , %: 62.1 T o t a l Volume S o l i d s , %: 46.3 P.V.C., %: 34.9 I n d u c t i o n Time, minutes: 30 V o l a t i l e Organic Compounds (VOC): Pounds/Gallon: 1.23 Grams/Liter: 148 Resin Composition (on s o l i d s ) : Epoxy Resin, %: 07.6 Curing Agent, %: 12.4 Pounds 330.0 7.0 3.5 60.0 71.1 71.1 106.7 100.0 71 .1 7.5 147.0 8.0 6.3 60.0 11c.o 989.3 170.0 Gal 1ons 37.21 0 . 8 9 0.41 7.20 1.74 1.94 4.40 4.20 3.55 0.32 16.43 0.95 0.76 6.80 13.20 80.00 20.00 SOURCE: S h e l l Chemical Co.: S t a r t i n g Formulation No. 1818: Epi-Rez 5522-WY-55 Resin/Epi-Cure 8292-Y-60 Curing Agent
  • 156.
    152 Water-Based PaintFormulations Lead Based .Primer Mater1 a1 : P a r t A : 2-Propoxyethanol T r i t o n X-100 S u r f a c t a n t Tamol 731 S u r f a c t a n t 9-148 Defoamer Bentone LT, 3% i n w a t e r Blend w e l l and add: Red I r o n Oxide B a s i c Lead S i l i c o Chromate C e l l t e 499 Diatomaceous E a r t h Maonesi um S i 1 1 c a t e Pounds 11.6 3 . 5 3.5 4.0 75.0 1 0 0 . 0 100.0 25.0 25.0 Gal 1ons 1.50 0 . 3 9 0.38 0.48 8.95 2 . 3 4 2.93 1.30 1 .05-I n c r e a s e d i s p e r s e r speed t o 3,000 RPM. Achieve g r i n d f i n e n e s s o f 6-7 PCS. Add under reduced a g i t a t i o n : Epi -Rez 3520-WY-55 Resin 260.0 30.00 Tap Water 297.0 35.68 P a r t B: Epi-Cure 8536-MY-60 C u r i n g Agent Composite B1end : P a r t A P a r t 8 124.5 1 5 . 0 0 904.6 85.00 124.5 15.00 T y p i c a l C o a t i n g P r o p e r t i e s : V i s c o s i t y : P a r t A : 65 KU P a r t 8: 90 KU P a r t s A and 8: 94 KU Wei g h t / G a l l l o n : I O . 29 A p p l i c a t i o n : Brush: As i s Spray: Reduce 10 p a r t s p a i n t t o 1 p a r t water t o a v i s c o s i t y o f 80 Krebs U n i t s P . V . C . , %: 25.2 V e h i c l e N o n - V o l a t i l e , %: 2 8 . 4 T o t a l Volume S o l i d s , %: 30.2 T o t a l Weight S o l i d s , %: 46.4 Resin Composition: Epoxy Resin, %: 67 V o l a t i 1e Composition: Pounds Gal 1ons Water 465.0 55.81 C u r i n g Agent, %: 33 O r g a n i c 85.2 11.20 Dry C h a r a c t e r i s t i c s (Room Temperature C u r e ) : Set t o t o u c h : 30-60 minutes Dry t o handle: 60 minutes Dry h a r d : 4 h o u r s Dry t o r e c o a t : 20 h o u r s SOURCE: S h e l l Chemical Co. : S t a r t i n g F o r m u l a t i o n No. 1809: Epi-Rez 3520-WY-55 Resin/Epi-Cure 8536-MY-60 C u r i n g Agent
  • 157.
    Primers 153 Lead SilicoChromate Primer M a t e r i a l : P a r t A: Epi -Rez 5522-WY-55 Resin D i acetone A1coho1 T r i t o n X-100 S u r f a c t a n t Water C o l l o i d 640 Defoamer RO-4097 Kroma Red, Red I r o n Zeeospheres Type 400 B a s i c Lead S i l i c o Chromate Oxide Pebble m i l l a p p r o x i m a t e l y 18 hours E p i -Rez 5522-WY-55 Resin Water P a r t 8: Epi -Cure 8290-Y-60 C u r i n g Agent Water Zeeospheres Type 400 High speed d i s p e r s e t o a t e x t u r e o f 6 PC Pounds 200.0 6 . 6 5.0 84.8 3.5 104.4 194.6 83.5 266.8 10.2 45.3 35.0 150.0 Water 26.4 Composi t e 81end : V i s c o s i t y P a r t A 87 K . U . P a r t B 140 K.U. P a r t s A and B 90 K.U. T y p i c a l C o a t i n g P r o p e r t i e s : T o t a l Weight S o l i d s , %: 67.1 T o t a l Volume Sol i d s , %: 5 1 . 4 P.V.C., %: 43.1 V o l a t i l e Organic Compounds (VOC): Pounds/Gal 1on : 1 .01 Grams/Liter: 121 I n d u c t i o n Time, minutes: 30 Resin Composition (based on s o l i d s ) : Epoxy Resin, %: 90.0 C u r i n g Agent, %: 1 0 . 0 T o t a l , %: 100.0 Reduction f o r Conventional Spray (by volume): P a r t s A and B: 20 p a r t s Water: 1 p a r t 959.4 256.7 Gal 1ons 22.35 0.84 0.56 10.18 0.41 2.45 9.73 2.45 29.81 1.22 5.13 4.20 7.50 3.17 80.00 20.00 SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1813: €pi-Rez 5522-WY-55 Resin/Epi-Cure 8290-Y-60 C u r i n g Agent
  • 158.
    154 Water-Based PaintFormulations Low Sheen Gray Primer Materi a1 : P a r t A: Epi -Rez 5522-WY-55 Resin Water P a r t 8: Epi -Cure 8290-Y-60 Curing Agent Kronos 2020 SP Black 4 Powder Patcote 847 Def P a r t A Part B Parts A Typical Tota Tota PVC , Vola Water High Speed D Water Composite Blend and B Coati nQ amer sperse t o 7-8 N.S. Texture. V i scosi t y 48 K . U . 76 K.U. 62 K.U. Prooerties : Weigh: Sol;ds, %: 51.1 Weight Solids, %: 39.5 %: 14.2 i l e Organic Compounds (VOC): Pounds/Gallon: 1 .51 Grams/Liter: 181 I n d u c t i o n Time, minutes: 30 Pounds 522.1 69.4 82.1 191 .o 0.3 2.0 25.0 126.2 592.5 426.6 Gal 1ons 58.34 8.33 9.30 5.58 0.02 0.28 3.00 15.15 66.67 33.33 Resin Composition (based on s o l i d s ) : Epoxy Resin, %: 85.0 Curing Agent, %: 15.0 Reduction f o r Conventional Spray (by volume): ( V i s c o s i t y = 55 K.U.) P a r t s A and B : 11 p a r t s Water: 1 p a r t SOURCE: S h e l l Chemical Co.: S t a r t i n g Formulation No. 1812: €pi-Rez 5522-WY-55 Resin/Epi-Cure 8290-Y-60
  • 159.
    Primers 155 M at e r i a l : Water I g e p a l CO-630 Tamol 731 Foamaster VL S u r f y n o l 104H D i e t h y l e n e G l y c o l T i t a n o x 2101 Raven 1020 Halox BW-191 QP-4400 #on-Lead/Non-Chromate Primer Monomethyl E t h e r Lbs. 83.89 2.54 0.87 10.70 1.10 1.66 35.32 58.50 0.65 148.69 High speed Cowles 15-20 minutes t o a 3-4 Hegman g r i n d . Add letdown: A r o l o n 820-W-49 540.36 Premix: Dalpad A Water Premix: Aroplaz 1271 C o b a l t Hydrocure I 1 C a l c i um Hydrocem Z i r c o n i um Hydrocem Then add: S u r f y n o l 104H Skane M-8 Premi x : OR-708 Water 13.24 58.26 37.99 3.79 3.79 1.88 3.31 2.20 0.17 2.26 Gals. 10.06 0.29 0.07 1.23 0.14 0.21 4.14 1.75 0.03 6.27 61.40 1.43 6 . 9 9 4.54 0.49 0.46 0.22 0.17 0.15 0.02 0 . 2 6 A n a l y s i s : Pigment Volume Concentration, Percent: 18.85 Pigment/Binder R a t i o : 0.69/1 Percent Sol i d s , Weight : 50.54 Percent S o l i d s , Volume: 34.52 V i s c o s i t y C 25C, KU: 85-89 Gloss (60): F l a t Pounds/Gallon: 10.08 VOC ( e x c l u d i n g w a t e r ) : pH: 8.7-9.2 Grams/Liter: 70.8 Pounds/Gallon: 0.6 SOURCE: Reichhold Chemicals, I n c . : A r o l o n 820: Formula 2025-80-1
  • 160.
    156 Water-Based PaintFormulations Primer f o r Factory-Pri med Hardboard S i d i ng I n g r e d i e n t s : Pigment Grind: Water T e r g i t o l Nonionic Surfactant NP-10 Tamol 731 Foamaster VF T i -Pure R-960 ASP 400 Letdown : Ucar Vehicle 462 Ucar A c r y l i c 515 Cyme1 325 Foamaster VF Nuocide 960 Arcosolve PP Solvent Propylene Glycol Pounds 164.3 6.0 17.6 2.6 96.5 289.4 325.0 118.2 31.3 0.9 5 . 1 31 . 3 35.3 Gallons 19.8 0.6 1.9 0 . 3 2.9 13.5 37.0 13.0 3.0 0.1 0.6 3.0 4.3 P a i n t P r o p e r t i e s : Pigment Volume Concentration, %: 42 C r o s s l i n k e r , p h r : 12 Cosolvent, phr: 15 Volume Solids, %: 40 Weight per Gallon, l b : 11.2 SOURCE: Ucar Emulsion Systems: Ucar Vehicle 462: Suggested Formu1a t ion
  • 161.
    Primers 157 Primer 20323DBased on Phosguard J - O m and 10 ES W o l l a s t o c o a t Henkel ‘ s Waterpoxy 1401:701 _Sysrem Component A: Waterpoxy 1401 Ektasolve EP 10 ES Wol l a s t o c o a t Red I r o n Oxide 5-3106 Phosguard 5-0853 Disperse t o 5 n . s . u . , reduce speed and add: Methyl Amyl Ketone Water Component 8 : Waterpoxy 701 Ektasolve EP Formulation Constants: & 452.05 10.44 255.50 137.40 147.89 55.00 74.60 100.00 10.40 Non V o l a t i l e by Weight: 0.70 VOC g r m s / l i t r e : Non V o l a t i l e by Volume: 0.53 VOC l b s . / g a l . : PVC : 0.36 Weight/Gallon Comp A : CPVC : 0.46 Weight/Gallon Comp 0 : PVC/CPVC : 0.79 M i x i n g R a t i o : Pigment Content: 0.44 Weight per Gallon: NVV by W t . o f Vehicle: 0.47 SOURCE: Nyco Minerals, I n c . : Primer 20323D Gals 49.95 1 .38 10.56 3.30 5.22 8.09 8.96 11.17 1.37 236.82 1.98 12.96 8.80 6.97 12.43
  • 162.
    1.58 Water-Based PaintFormulations Primer 203236 Based on Phosguard 5-0813 and 10 ES W o l l a s t o c o a t Henkel ‘sWaterpoxy 1401:701 System Component A : Waterpoxy 1401 E k t a s o l v e EP 10 ES W o l l a s t o c o a t Red I r o n Oxide 5-3106 Phosguard 5-0813 Disperse t o 5 n . s . u . , reduce speed and add: Methyl Amyl Ketone Water Component B: Waterpoxy 701 E k t a s o l v e EP F o r m u l a t i o n Constants Lbs 452.05 10.44 255.50 137.40 130.49 55.00 74.60 100.00 10.40 PVC : 0.36 Wei ght/Gai CPVC : 0.46 Weight/Gal PVC/CPVC : 0.79 M i x i n g Rat Pigment Content; 0.43 Weight p e r NVV by W t . o f V e h i c l e : 0 . 4 7 Non V o l a t i l e by Weight: 0.70 VOC g r m s / l i t r e : Non V o l a t i l e by Volume: 0.53 VOC l b s . / g 1 . : on Comp A: 12.76 on Comp 9: 8.80 0: 6.97 G a l l o n : 12.26 Gals 49.95 1 . 3 8 10.56 3.30 5.22 8.09 8.96 11.17 1.37 236.82 1.98 SOURCE: Nyco M i n e r a l s , I n c . : Primer 203230
  • 163.
    Primers 159 Primer 20596FBased on Heucophos ZPZ ~~and 10 ES Wollasto- _ _ ~ _Henkel's -Waterpoxy 1401:701 System Component A: Waterpoxy 1401 Ektasolve EP 10 ES Wol 1 astocoat Red Iron Oxide 5-3106 Heucophos ZPZ Disperse to 5 n.s.u., reduce speed and add: Methyl Amyl Ketone Water Component 0 : Waterpoxy 701 Ektasolve EP Formulati on Constants Lbs &lls 452.05 49.95 1 0 . 4 4 1 . 3 8 255.50 1 0 . 5 6 137.40 3 . 3 0 152.48 5 . 2 2 5 5 . 0 0 8 . 0 9 74.60 8 . 9 6 100.00 1 1 . 1 7 10.40 1 . 3 7 Non Volatile by Weight: 0 . 7 0 VOC grms/litre: 236.82 Non Volatile by Volume: 0 . 5 3 VOC 1bs./gal . : 1 . 9 8 PVC: 0 . 3 6 Weight/Gallon Comp A : 13.01 cpvc: 0 . 5 5 Weight/Gallon Comp 6 : 8 . 8 0 PVC/CPVC : 0.67 Mixing Ratio: 6 . 9 7 Pigment Content: 0 . 4 4 Weight per Gallon: 12.48 NVV by Wt. o f Vehicle: 0 . 4 7 SOURCE: Nyco Minerals, Inc.: Primer 20596F
  • 164.
    I60 Water-Based PaintFormulations Primer 205966 Based On HeucoDhos ZMP and 10 ES Wollastocoat Henkel's Waterpoxy 1401:701 System Component A: Waterpoxy 1401 Ektasolve EP 10 ES Wollastocoat Red I r o n Oxide 5-3106 Heucophos ZMP Disperse t o 5 n.s.u., reduce speed and add: Methyl Amyl Ketone Water Component B: Waterpoxy 701 Ektasolve EP Formulation Constants & Gals 452.05 49.95 10.44 1 .38 255.50 10.56 137.40 3.30 152.48 5.22 55.00 8.09 74.60 8.96 100.00 11.17 10.40 1.37 Non V o l a t i l e by Weight: 0.70 VOC g r m s / l i t r e : 236.82 PVC : 0.36 Weight/Gallon Comp A: 13.01 CPVC: 0.53 Weight/Gallon Comp 8 : 8.80 PVC/CPVC : 0.68 M i x i n g R a t i o : 6.97 Pigment Content : 0.44 Weight per Gallon: 12.48 NVV by W t . o f Vehicle: 0.47 SOURCE: Nyco Minerals, I n c . : Primer 205966 Non V o l a t i l e by Volume: 0.53 VOC l b s . / g a l . : 1.98
  • 165.
    Primers 161 Primer 21102EBased on Molycoat 212 and 10 AS W o l l a s t o c o a t H e n k e l ' s Waterpoxy 1401:701 System Component A: Waterpoxy 1401 E k t a s o l v e EP 10 AS W o l l a s t o c o a t Red I r o n Oxide 5-3106 M o l y w h i t e 212 Disperse t o 5 n . s . u . , reduce speed and add: Methyl Amyl Ketone Water Component 9: Waterpoxy 701 E k t a s o l v e EP & 452.05 10.44 255.50 137.40 130.39 55.00 74.60 100.00 10.40 F o r m u l a t i o n Constants Non V o l a t i l e b y Weight: 0.70 VOC g r m s / l i t r e : Non V o l a t i l e bv Volume: 0.53 VOC l b s . / a a l . 3: &3& 49.95 1.38 10.56 3.30 5.22 8.09 8 . 9 6 11.17 1.37 236.82 1.98 PVC : 0.36 Weight/Gailon Comp A: 12.76 CPVC: 0.55 Weight/Gallon Comp 8: 8.80 PVC/CPVC : 0.66 M i x i n g R a t i o : 6.97 Pigment Content: 0.43 Weight p e r G a l l o n : 12.26 NVV b y W t . of V e h i c l e : 0.47 SOURCE: Nyco M i n e r a l s , I n c . : Primer 21102E
  • 166.
    162 Water-Based PaintFormulations Primer 21105H Based on Phosauard 5-0815 and 10 ES W o l l a s t o c o a t Henkel's Waterpoxy 1401:702 System Component A: Waterpoxy 1401 Ektasolve EP 10 ES Wol l a s t o c o a t Red Iron Oxide 5-3106 Phosguard 5-081 5 Disperse t o 5 n.s.u., reduce speed and add: Methyl Amyl Ketone Water Component 0: Waterpoxy 702 Ektasolve EP Formulation Constants !& Gals 452.05 49.95 10.44 1.38 255.50 10.56 137.40 3.30 139.19 5.22 55.00 8.09 74.60 8.96 45.28 5.27 23.41 3.08 Non V o l a t i l e by Weight: 0.69 VOC g r m s / l i t r e : 237.36 Non V o l a t i l e by Volume: 0.51 VOC l b s . / g a l . : 1 . 9 8 PVC: 0.39 Weight/Gallon Comp A: 12.86 CPVC : 0 . 5 0 Weight/Gallon Comp B: 8.23 PVC/CPVC : 0.79 M i x i n g R a t i o : 10.47 Pigment Content : 0.45 Weight per Gallon: 12.45 NVV by W t . o f Vehicle: 0.44 SOURCE: Nyco Minerals, I n c . : P r i m e r 21105H
  • 167.
    Primers 163 Primer 211051Based On N a l z i n 2 and 10 ES Wollastocoat Henkel 's Waterpoxy 1401 :702 System Component A: Waterpoxy 1401 Ektasolve EP 10 ES Wol l a s t o c o a t Red I r o n Oxide 5-3106 N a l z i n 2 Disperse t o 5 n.s.u., reduce speed and add: Methyl Amyl Ketone Water Component 8 : Waterpoxy 702 Ektasolve EP Formulation Constants & 452.05 10.44 255.50 137.40 172.32 55.00 74.60 45.28 23.41 Non V o l a t i l e by Weight: 0.70 VOC g r m s / l i t r e : Non V o l a t i l e by Volume: 0.51 VOC l b s . / g a l . : PVC: 0.39 Weight/Gallon Comp A: CPVC: 0.54 Weight/Gallon Comp 8: PVC/CPVC : 0.73 Mixing Ratio: Pigment Content : 0.46 Weight per Gallon: NVV by W t . o f Vehicle: 0.43 SOURCE: Nyco Minerals, I n c . : Primer 211051 Gals 49.95 1.38 10.56 3.30 5.22 8.09 8.96 5.27 3.08 237.36 1.98 13.23 8.23 10.47 12.80
  • 168.
    164 Water-Based PaintFormulations Primer 21109C Based on S t r o n t i u m Chromate and 10 ES Wollastocoat Henkel's Waterpoxy 1401:702 System Component A: Waterpoxy 1401 Ektasolve EP 10 ES Wollastocoat Red I r o n Oxide 5-3106 S t r o n t i u m Chromate Disperse t o 5 n . s . u . , reduce speed and add: Methyl Amyl Ketone Water Component B : Waterpoxy 702 Ektasolve EP Formulation Constants * L 453.17 10.47 256.20 137.75 166.40 55.10 74.79 68.04 35.18 Non V o l a t i l e bv Weiaht: 0.69 VOC a r m s / l i t r e : CPVC : 0.54 Wei ght/Gal 1on PVC/CPVC : 0 . 7 0 M i x i n g R a t i o : Pigment Content: 0.45 Weight per Ga NVV by W t . o f Vehicle: 0.44 50.07 1.38 10.59 3.31 5.27 8.10 8.98 7.91 4.64 250.17 2.09Non V o l a t i l e b; V o l h e : 0.51 VOC i b s . / g a l . : PVC : 0.38 Weight/Gallon Comp A: 13.16 Comp B: 8.23 6.99 l o n : 12.54 SOURCE: Nyco Minerals, I n c . : Primer 21109C
  • 169.
    Primers 165 Rapid DryWaterborne Epoxy Primer M a t e r i a l : P a r t A: E p i -Rez 5522-WY-55 Resin D i acetone A1coho1 C o l l o i d 640 Defoamer Water R0-4097 Kroma Red, Red I r o n Oxide lOES Wollastokup Halox SW-111 High Speed Disperse t o a Texture o f 5-6 N.S Epi -Rez 5522-W-55 Resin E p i -Rez 3540-WY-55 Resin 15% Aqueous s o l u t i o n o f sodium n i t r i t e Water P a r t B: Epi-Cure 8290-Y-60 Curing Agent Water Zeeosphere 400 t y p e Water Ground Mica, 325 Mesh High Speed Disperse t o a t e x t u r e o f 4-5 N.S Water G l a c i a l A c e t i c A c i d Composite Blend: V i s c o s i t y P a r t A 64 K.U. P a r t 0 70 K.U. P a r t s A and B 62 K.U. T y p i c a l Coating P r o p e r t i e s : T o t a l Weight S o l i d s , %: 59.1 T o t a l Volume S o l i d s , %: 43.8 P.V.C., %: 36.2 I n d u c t i o n Time, minutes: 30 V o l a t i l e Organic Compounds (VOC): Pounds/Gallon: 1.19 Grams/Liter: 142.8 Res4 n ComDosi tion : Epoxy Resin, %: 89.6 C u r i n g Agent, %: 10.4 Reduction t o Spray V i s c o s i t y : None r e q u i r e d Pounds 258.7 5.4 2.7 59.4 77.6 116.6 116.6 114.3 74.1 6.2 79.7 46.7 8.6 77.0 7.7 78.5 0.4 911.4 219.7 Gal 1ons 28.92 0.69 0.32 7.13 1.90 4.81 4.90 12.77 8.24 0.74 9.58 5.29 1.03 3.89 0.33 9.42 0.04 80.00 20 * 00 SOURCE: S h e l l Chemical Co.: S t a r t i n g Formulation No. 1814: Epi-Rez 5522-WY-55 Resin/Epi-Rez 3540-WY-55 Resin/ Epi-Cure 8290-Y-60 Curing Agent
  • 170.
    166 Water-Based PaintFormulations Rapid D r y Waterborne Epoxy Primer M a t e r i a l P a r t A: Epi-Rez 5522-WY-55 Waterborne Resin Epi-Rez 3540-WY-55 Waterborne Resin C o l l o i d 640 Water Bentone LT High Speed Mix f o r 15 minutes Water D i acetone Alcohol R0-4097 Kroma Red, Red I r o n Oxide Halox SW-111 Sparmi t e 325 Mesh Wet Ground Mica 399 Lo-Mi c r o n High Speed Disperse t o a t e x t u r e of 5-6 N.S. Pounds Gal 1ons 205.0 22.78 _ _ _ ~ 61.9 6.88 5.0 0.60 140.0 16.81 3.0 0.20 30.0 3.60 7.8 1 .oo 65.5 1.60 93.8 3.94 46.7 1.28 46.9 2.00 85.0 3.78 Epi-Rez 5522-WY-55 Resin 18.8 2.09 15% Aqueous s o l u t i o n o f potassium n i t r i t e 8.0 0.95 Water 104.0 12.49 M a t e r i a l P a r t 8: Epi -Cure 8292-Y-60 Curing Agent Ektasolve EP Water 27.0 3.08 37.9 5.00 99.3 11.92 Composite Blend: V i s c o s i t y P a r t A 102 K.U. 921.4 80.00 P a r t 8 10.5 secs (Ford #4) 164.2 20.00 P a r t s A and 8 68 K.U. T y p i c a l Coating P r o p e r t i e s : Resin/Curing Agent R a t i o ( s o l i d s b a s i s ) : Epoxy Resin: 88.1 Curing Agent: 11.9 T o t a l weight s o l i d s , %: 47.6 T o t a l volume s o l i d s , %: 33.2 P.V.C., %: 40.8 I n d u c t i o n time, minutes: 30 V o l a t i l e Organic Compounds (VOC): Pounds/gal 1on : 1.95 G r a m s / l i t e r : 234 SOURCE: S h e l l Chemical Co.: S t a r t i n g Formulation No. 1821: Epi-Rez 5522-WY-55 Waterborne Resin/Epi-Rez 3540-WY-55 Waterborne Resin/Epi-Cure 8292-Y-60 Curing Agent
  • 171.
    Primers 167 Red In h i b i t i v e Maintenance Primer I n a r e d i ents: Pigment Grind: Water Bentone LT Methyl C a r b i t o l Solvent Tamol 681 Nuosept 95 DeeFo HG-12 T r i t o n Nonionic S u r f a c t a n t CF-10 Ammonium Hydroxide, 28% Aqueous S o l u t i o n Acrysol RM-2020 Heucophos ZBZ Atomite Letdown : Methyl C a r b i t o l Solvent Acrysol SCT-275 Ucar Vehicle 435 Ucar F i l m e r I B T Troysan Polyphase AF-1 Foamex 825 Sodium N i t r i t e , 15% Aqueous S o l u t i o n Ammonium Hydroxide, 28% Aqueous S o l u t i o n 5-3103 Adjust t o minimum pH 8.7 Pounds 151.5 1.o 25.5 18.2 2.3 2.1 2 . 2 1.8 17.2 50.0 75.0 145.8 8 . 5 8.6 505.1 11.4 4.9 2.1 9.0 1.8 Gallons 18.19 0.06 3.00 2.00 0.25 0.25 0.25 0.25 2.00 1.20 2.51 6.46 1.oo 1.oo 58.06 1.44 0.50 0.25 1.08 0.25 P a i n t Properties: Pigment Volume Concentration (PVC), %: 30.0 T o t a l Solids, %: by volume: 34.0 pH Value, i n i t i a l : 8.7 V i s c o s i t y : Stormer. KU: 80 I C I , poise: 0.7 Weight per Gallon, l b : 10.4 Freeze-Thaw S t a b i l i t y , 3 cycles: Pass Heat S t a b i l i t y , 2 weeks a t 140F: Pass SOURCE: Ucar Emulsion Systems: Ucar Vehicle 435: Formulation SugQestion M-2452
  • 172.
    168 Water-Based PaintFormulations Red I r o n Oxide C o r r o s i o n R e s i s t a n t EPOXY Primer (Two Component System) Ingredients: -Lb (Prepare P a r t # l & P a r t #2 s e p a r a t e l y ) P a r t #l E p o t u f 37-618/Epoxy Resin Hardener 147.91 X y l o l / X y l e n e 95.36 Ye1 k i ns-TS/Soya L e c i t h i n 3.89 B u t r o l 2 3 / M o d i f i e d Barium Meta- b o r a t e 194.62 Red I r o n Oxide 194.62 N y t a l 300/Talc-Magnesium S i l i c a t e 18.49 P a r t #2: E p o t u f 38-501/Epoxy Resin Methyl I s o b u t y l Ketone X y l o l /Xylene 272.91 70.06 105.10 M i x two components i n 1 : l r a t i o and w a i t f o r p a i n t a p p l i c a t i o n . Pigment Vol a t i 1e Organi c Solvent Non-Vol a t i1e N o n - V o l a t i l e Veh D e n s i t y (lb/U.S. S p e c i f i c G r a v i t y P.V.C.: 47.19% P/B R a t i o : 1.323 P a i n t P r o p e r t i es : %Wt %vel T o t a l V e h i c l e 63.03 87.92 36.97 12.08 35.09 74.41 35.09 74.41 64.91 25.59 c l e 27.94 13.52 g a l ) : 11.03 1.32 18.96 13.41 13.19 8.65 0.46 0.35 6.32 17.65 4.98 17.65 0.78 1.68 30.29 24.74 10.49 6.35 14.54 9.53 30 minutes b e f o r e Spread @ 1 M i l : 411 F2 C o a t i n g VOC: 464 G/L M a t e r i a l VOC: 464 G/L SOURCE: Buckman L a b o r a t o r i e s : F o r m u l a t i o n Suggestion: KQ-23
  • 173.
    Primers 169 Red Ir o n Oxide Primer M a t e r i a l : P a r t A: 2-Propoxyethanol T r i t o n X-100 S u r f a c t a n t Tamol 731 S u r f a c t a n t 91 48 Defoamer Bentone LT, 3% i n water Blend w e l l and add: Red I r o n Oxide C e l i t e 499 Diatomaceous E a r t h Magnesi um S i 1ic a t e Pounds G a l l o n s 11.6 1.50 3.5 0.39 3 . 5 0.38 4.0 0.48 75.0 8.95 ~ _ _ _ 100.0 2.34 25.0 I .30 100.0 4.22 D i s p e r s e t o a g r i n d f i n e n e s s o f 6-7 P.C.S., t h e n add under a g i t a t i o n : Epi -Rez 3520-WY-55 Resin Tap Water P a r t B: Epi -Cure 8536-MY-60 C u r i ng Agent Composite 81end : P a r t A P a r t 8 276.0 30.00 295.0 35.44 124.5 15.00 893.6 85.00 124.5 15.00 T y p i c a l C o a t i n g P r o p e r t i e s : V i s c o s i t y : P a r t A: 68 Krebs U n i t s P a r t B: 90 Krebs U n i t s P a r t s A and B: 98 Krebs u n i t s Pounds/Gal l o n : 10.18 A p p l i c a t i o n : Brush: as i s Spray: Reduce 10 p a r t s p a i n t t o 1 p a r t water t o a v i s c o s i t y o f 83 Krebs U n i t s P.V.C., %: 25.2 V e h i c l e N o n - V o l a t i l e , %: 29.2 T o t a l Volume S o l i d s , %: 31.3 T o t a l Weight S o l i d s , %: 45.3 Resin Composition: Epoxy Resin, %: 67 Vol a t i 1e Composi t i on Pounds G a l l o n s Water 467.0 56.14 C u r i n g Agent, %: 33 Organics 85.2 11.20 V o l a t i l e Organic Compounds (VOC): Pounds/Gallon: 2.05 G r a m s / L i t e r : 246 SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1806: Epi-Rez 3520-WY-55 Resin/Epi-Cure 8536-MY-60 C u r i n g Agent
  • 174.
    170 Water-Based PaintFormulations Red Iron Oxide Primer I n g r e d i e n t s : -Lb P iOment O r ind: Water 117.69 Busperse 39/Dispersant 5.65 Bubreak 448/Defoamer 2.82 Zinc S u l fate-Heptahydrate 1.88 I g e p a l CTA 639/Surfactant 2.82 (Mix 10 minutes and add) B u t r o l 23/Modi f ied B a r i um Meta- b o r a t e 47.08 Red I r o n Oxide 94.15 N y t a l 300/Talc-Magnesi um S i 1ic a t e 94.15 Let Down: (Premix a l l t h e f o l l o w i n g i n g r e d i e n t s and t h Beckosol 13-402/Water Reducible A1 kyd 282.46 B u t y l C e l l o s o l v e 84.74 Ammonium Hydroxide-28% 22.60 Water 233.50 Act iv-8/Dri e r 0.94 Z i r c o n i urn 6%/Dri e r 5.65 Cobalt Naphthenate-G%/Drier 1.88 A n t i s k i n n i n g Agent 1.88 P a i n t P r o p e r t i e s : %vel T o t a l V e h i c l e 76.27 91.98 Pigment 23.73 8.02 V o l a t i l e 54.56 68.54 Organic Solvent 19.43 26.38 Non-Volati l e 45.44 31.46 N o n - V o l a t i l e V e h i c l e 21.72 23.44 Density (lb/U.S. g a l ) : 10.00 Speci f ic G r a v i t y : 1 .20 P.V.C.: 25.50% P/B R a t i o : 1.093 Spread @ 1 M i l : 505 F2 Coating VOC: 403 G/L M a t e r i a l VOC: 233 G/L en __Ga1 14.13 0.53 0.42 0.11 0.32 1.53 2.41 3.97 add t o 32.84 11.28 3.01 28.03 0.12 0.26 0.79 0.25 Wt% 11.77 0.56 0.28 0.19 0.28 4.71 9.42 9.42 t h e g r i n d ) 28.25 0.47 2.26 23.35 0.09 0.19 0.56 0.19 SOURCE: Buckman Laboratories: Formulation Suggestion: KP-10
  • 175.
    Primers 171 Red Ir o n Oxide Water R e d u c i b l e A l k v d Primer I n q r e d i e n t s : -Lb Pigment G r i n d : Water 154.98 1 Busperse 39/Dispersant 5.81 Bubreak 448/Oefoamer 2.91 I g e p a l CTA 6 3 9 / S u r f a c t a n t 2.91 Zinc S u l f a t e - H e p t a h y d r a t e 1.94 B u t r o l 2 3 / M o d i f i e d Barium Meta- b o r a t e 48.43 Red I r o n Oxide 98.86 N y t a l 300/Talc-Magnesium S i l i c a t e 193.72 Gal 18.60 0.54 0.43 0.33 0.12 1.57 2.48 8.17 Wt% 14.64 0.55 0.27 0.27 0.18 4.57 9.15 18.30 L e t Down: (Premix a l l t h e f o l l o w i n g i n g r e d i e n t s and t h e n add t o t h e g r i n d . ) C a r g i l l 7464/Water R e d u c i b l e A l k y d 248.93 28.78 23.51 Secondary B u t y l A l c o h o l 86.21 12.81 8.14 Ammonium Hydroxide-28% 9.69 1.29 0.91 Water 200.50 24.07 18.94 C o b a l t Naphthenate-6%/Orier 1.94 0.26 0.18 Z i r c o n i um 6%/Dri e r 3.87 0.54 0.37 Pai n t P r o p e r t i as: T o t a l V e h i c l e 67. ao 87.66 Pigment 32.20 12.34 V o l a t i 1e 49.71 67.42 Organic S o l v e n t 16.14 24.74 Non-Vol a t i 1e 50.29 32.58 N o n - V o l a t i l e V e h i c l e 18.08 20.24 D e n s i t y (lb/U.S. g a l ) : 10.59 S p e c i f i c G r a v i t y : 1.27 P.V.C.: 37.88% P/B R a t i o : 1.781 Spread I3 1 M i l : 523 F2 C o a t i n g VOC: 357 G/L M a t e r i a l VOC: 205 G/L SOURCE: Buckman L a b o r a t o r i e s : F o r m u l a t i o n Suggestion: KP-09
  • 176.
    I72 Water-Based PaintFormulations Rust Inhibitive Chromate Primer Material: Water Tamol 731 Triton CF-10 Nopco NDW Ethylene Glycol Dowicil 75 Kelecin 1081 Mix at low speed: Titanox 2101 Zinc Chromate Y539D Oncor M50 Mica 325 Snowf1 ake Lampblack #877 QP-4400 Lbs. Gals . 136.0 16.33 16.0 1.85 3.0 0.34 2.0 0.27 26.0 2.80 0.5 0.02 2.0 0.24 200.0 6.01 15.0 0.52 30.0 0.88 33.0 1.41 100.0 4.43 4.0 0.37 1.2 0:1 1 Grind under high shear 15-20 minutes. NOTE: Do not allow temperature to exceed llOF during grind. Under low speed add letdown: Nopco NDW 1.5 0.20 Arolon 820-W-49 500.0 57.08 Ammoni a 7.0 0.84 Diethylene Glycol Monobutyl Ether 6.0 0.76 Diethylene Glycol Monobutyl Ether Acetate 6.0 0.73 Preblend : Aroplaz 1271 or 1272 Triton CF-10 Water 25.7 3.08 1.3 0.15 4.0 0.48 Analysis: Pigment/Binder Ratio: 1.37/1 Pounds/Gallon: 11.33 Percent Nonvolatile, Weight: 58.5 Percent Nonvolatile, Volume: 43.4 Pigment Volume Concentration, Percent: 31 .O pH: 8.8 Viscosity @ 25C, KU: 75-78 60/20 Gloss: Flat Grind Hegman: 4-5 VOC (excluding water): Grams/Liter: 1 1 3.0 Pounds/Gallon: 0.94 SOURCE: Reichhold Chemicals, Inc.: Arolon 820: Formula 5-3
  • 177.
    Primers 173 S ol v e n t R e s i s t a n t , Water-Reducible EPOXV Primer M a t e r i a l :. P a r t A: Epi -Rez 5522-W-55 Resin D i acetone A1coho1 T r i t o n X-100 S u r f a c t a n t Water C o l l o i d 640 Defoamer R0-4097 Kroma Red, Red I r o n Oxide Zeeospheres Type 600 Pebble m i l l a p p r o x i m a t e l y 18 hours Epi -Rez 5522-WY-55 Resin Water P a r t 6: Epi-Cure 8290-Y-60 C u r i n g Agent Water Composite Blend: V i s c o s i t y P a r t A 64 K.U. P a r t 0 58 K.U. P a r t s A t B 85 K.U. Pounds 200.0 6 . 6 5.0 84.8 3 . 5 104.4 307.1 187.2 39.5 118.3 55.0 938.1 173.3 Gal 1ons 22.35 0.84 0 . 5 6 10.18 0.41 2 . 4 5 17.55 20.92 4.74 13.40 6.60 80.00 20.00 T y p i c a l C o a t i n g P r o p e r t i e s : T o t a l Weight S o l i d s , %: 6 2 . 6 T o t a l Volume S o l i d s , %: 49.2 P.V.C., %: 40.7 V o l a t i l e Organic Compounds (VOC): Pounds/Gal 1on : 1 .37 Grams/Li t e r : 164 I n d u c t i o n Time, minutes: 30 Resin Composition (based on s o l i d s ) : Epoxy Resin, %: 75.0 C u r i n g Agent, %: 25.0 T o t a l , %: 100.0 Reduction f o r Conventional Spray (by volume): P a r t s A and 6 : 36 p a r t s Water: 1 p a r t SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1808: Epi-Rez 5522-W-55 Resin/Epi-Cure 8290-Y-60 C u r i n g Agent
  • 178.
    174 Water-Based PaintFormulations TT-P-1975 Federal S D e c i f i c a t i o n Metal Primer I n q r e d i e n t s : Pigment Grind: Water C e l l o s i ze Hydroxyethyl C e l l u l ose ER-15M Dispersant ( 1 ) Nonionic Surfactant (2) Ethylene Glycol B u f f e r (3) Antifoam (4) Preservative ( 5 ) Titanium Dioxide (6) I n h i b i t i v e Pigment (7) Mica (8) Calcium Carbonate (9) Pounds 266.4 1.o 15.2 2.7 26.8 2.0 2.4 2.7 133.9 89.2 35.7 46.5 Gal l o n s 32.0 0.1 1.7 0.3 2.9 0.3 0.3 0.3 3.9 2.7 1.5 2.1 Let Down: B u t y l C a r b i t o l Solvent--Premix w i t h : 7.2 0.9 Ucar Thickener SCT-275 8.2 1 .o Ucar Latex 163 423.6 47.6 Antifoam (4) 4.8 0.6 Mildewcide (IO) 5.8 0.6 Ammonium Hydroxide, 28% Aqueous S o l u t i o n 9.0 1.2 Suppl ie r s : (1) Dispersant - C o l l o i d l l l M ( C o l l o i d s ) o r equivalent. (2) Nonionic Surfactant - T r i t o n CF-10 (Rohm and Haas) o r (3) B u f f e r - AMP 95 (Angus) o r equivalent. (4) Antifoam - C o l l o i d 770 ( C o l l o i d s ) o r equivalent. (5) Preservative - Nuosept 95 (Huls) o r equivalent. (6) Titanium Dioxide - Ti-Pure R-900 (DuPont) o r equivalent. (7) I n h i b i t i v e Pigment - N a l z i n 2 (NL Chemicals) o r equivalent (8) Mica - 325 WG Mica (KMG Minerals) o r e q u i v a l e n t . (9) Calcium Carbonate - Snowflake (Thompson, Weinman) o r equivalent. equi Val ent . (IO) Mildewcide - Polyphase AF-1 (Troy) o r equivalent Paint Properties: Pigment Volume Concentration (PVC), %: 27.9 T o t a l Solids, % by Volume: 36.5 SOURCE: Ucar Emulsion Systems: Ucar Latex 163: Formulat Suggestion LP-2085 on
  • 179.
    Rimers 175 Universal Primer In q r e d i e n t s : P i gment Grind: Water Methyl C a r b i t o l Solvent Ammonium Hydroxide, 28% Aqueous S o l u t i o n Tamol 165 Surfynol CT-111 Drewplus L-475 Aerosi 1 R-972 T i -Pure R-900 M i c r o t a l c MP 12-50 Busan 11-MI Water Letdown : B u t y l C a r b i t o l Solvent Ucar Latex 461 Ucar F i l m e r I B T ) Premix S a n t i c i z e r 160 ) Sodium N i t r i t e ) Premix Water 1 Water Ammoni um Hydroxide, 28% Aqueous Sol u t i on Ucar Polyphobe 102 Rheology M o d i f i e r Pai n t P r o p e r t i es : Arcosolv PNB 1 Pigment Volume Concentration, %: 22.4 Volume Solids, %: 38.0 Weight S o l i d s , %: 49.5 Weight per Gallon, l b : 10.2 Stormer, KU: 85 I C I , Poise: 0.9 pH value: 8.5-9.5 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5 Heat-Age S t a b i l i t y , 120F, weeks passed: 4 VOC, grams per l i t e r : 225 Pounds 51 . 5 50.4 2.0 8.1 4.0 2.0 3.0 121.o 61 .7 50.0 60.8 21.2 521.2 10.1 10.1 2.3 2.4 20.2 10.7 1.5 5.5 Gallons 6.18 5.93 0.26 0.92 0.48 0.27 0.19 3.57 2.74 2.08 7.30 2.66 59.91 1.37 1.27 0.24 0.14 2.42 1.28 0.20 0.59 F i l m P r o p e r t i e s : Sheen, 85: 5 max Prohesion Corrosion Weathering Cycle, hours passed: 800 Cleveland Humidity, hours passed: 800 Tanning/Stai n i ng Resistance: Good Tape Adhesion (ASTM 0-33): E x c e l l e n t S a l t Fog, hours: 48 max SOURCE: Ucar Emulsion Systems: Formulation Suggestion E-18138
  • 180.
    176 Water-Based PaintFormulations Universal Primer Non-Li f t ing and H i g h S a l t Spray Resistance I n s r e d i e n t s : Aroplaz 3859-2-80 Calcium Chem-All 8% Premix: Red I r o n Oxide 5-3106 Phosguard 5-0806 10 AS Wollastocoat 399 Talc Methyl I s o b u t y l Ketone Disperse t o 135F and 5 n.s.u. MPA-1078 To1uene VM & P Naphtha Aroplaz 3859-2-80 Cobalt Chem-A1 1 12% Z i r c o n i um Chem-All 12% nButyl Alcohol Skino #2 PM Acetate & Gals 245.30 27.72 6.00 0.81 9.00 1.13 100.00 2.40 138.60 5.20 121.oo 5.00 103.50 4.60 133.30 19.99 13.50 1.86 68.80 11.24 123.20 13.92 1 .25 0.15 3.75 0.47 25.80 3.82 3.00 0.39 16.53 2.16 Formulation Constants Non V o l a t i l e by Weight: 0.69 VOC g r a m s / l i t r e : 410.71 Non V o l a t i l e by Volume: 0.48 VOC l b s . / g a l . : 3.43 PVC : 0.35 Weight per Gallon: 11.03 CPVC: 0.45 P i gment Content: 0.42 PVC/CPVC : 0.79 1. Can be re-coated w i t h powerful s o l v e n t - c o n t a i n i n g topcoats. 2. Very h i g h s a l t spray r e s i s t a n c e - 3000 hours a t 3 m i l s . 3. Fast d r y i n g i n t h i n f i l m s . 4. Must be f u l l y cured before t o p coated. 5. Ready t o spray w i t h o u t d i l u t i o n . 6. Touch d r y i n approximately 8 minutes. SOURCE: Nyco Minerals, Inc.: Suggested Formulation N o n - l i f t i n g epoxies, urethanes, and alkyds.
  • 181.
    Primers 177 Water-Base AcrylicUniversal Primer Using Halox SZP-391 & EJW-100 Grind: Lbs./100 Gals. Gms/Liter Add t h e f o l l o w i n g i n order l i s t e d w h i l e mixing a t low speed: Water 125.0 150.0 Nopco NDW 1.5 1.8 Natrosol 250MBR 1 .o 1.2 Aqua Ammonia 28% 1 .o 1.2 Mix f o r 5 minutes then add t h e f o l l o w i n g raw material i n order l i s t e d : Ethylene G1ycol Tamol 681 T r i t o n CF-10 T i -Pure R-902 Zinc Oxide Halox SZP-391 Halox BW-100 Snowf 1ake High speed disperse t o 5+ Hegman g r i n d Letdown : Rhopl ex MV-23 Texanol Skane M-8 Nopco NDW 30.0 36.0 18.5 27.8 3.0 3.6 150.0 180.0 10.0 12.0 50.0 60.0 50.0 60.0 130.0 156.0 490.0 588.0 8.0 9.6 2.0 2.4 1 .o 1.2 Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l uniform. Then slowly add t h e f o l l o w i n g raw material w h i l e mixing a t high speed. Do not aerate! OR-708 Thickener 5.5 6.6 Mix u n t i l uniform and add t h e following: Water 58.0 70.0 Mix u n t i l uniform. Formula Constants: % Pigment/Wt. : 34.55 % Pigment/Vol.: 14.76 % Solids/Wt.: 54.55 96 Sol ids/Vol .: 38.71 46 PVC: 38.14 VOC. l b s . / g a l . : 1.14 VOC, g/L: 136.82 Formula Properties: Density 1bs. /gal. : 1 1 .35 Density g/L: 1 ,367.4 KU Visc. @ R.T.: 90-95 pH @ R.T.: 9.0-9.5 SOURCE: Halox Pigments: Suggested Formulation MV-23/391-100
  • 182.
    178 Water-Based PaintFormulations Water-Base A c r y l i c U n i v e r s a l Primer Using Halox SZP-391 (L X t a i n A Q r i nd: Lbs./100 Gals Gms/Liter Add t h e f o l l o w i n g i n order l i s t e d w h i l e mixing a t low speed. Water Nopco NDW Natrosol 250MBR Aqua Ammonia 28% 125.0 150.0 1.5 1.8 1.o 1.2 1.o 1.2 Mix f o r 5 minutes then add t h e f o l l o w i n g raw m a t e r i a l i n order l i s t e d : Ethylene G1ycol Tamol 681 T r i t o n CF-10 T i -Pure R-902 Zinc Oxide Halox SZP-391 Halox X t a i n A Snowf 1ake High speed disperse t o 5+ Hegman g r i n d Letdown : Rhoplex MV-23 Texanol Skane M-8 Nopco NDW 30.0 36.0 18.5 27.8 3.0 3 . 6 150.0 180.0 10.0 12.0 50.0 60.0 5.0 6.0 175.0 210.0 490.0 588.0 8.0 9 . 6 2.0 2.4 1.o 1.2 Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l uniform. Then s l o w l y add t h e f o l l o w i n g raw m a t e r i a l w h i l e m i x i n g a t h i g h speed. Do n o t a e r a t e ! QR-708 Thickener 5.5 6.6 Mix u n t i l u n i f o r m and add t h e f o l l o w i n g : Water 58.0 70.0 Mix u n t i l uniform. Formula Constants: % P i gment/Wt .: 34.56 % Pigment/Vol .: 14.81 % Solids/Wt.: 54.57 % Solids/Vol .: 38.76 % PVC: 38.20 VOC, l b s . / g a l . : 1.14 VOC, g/L: 136.69 Formula P r o p e r t i e s : Density l b s . / g a l . : 11.35 Density g/L: 1,367.4 KU V i s c . @ R.T.: 90-95 pH @ R.T.: 9.0-9.5 SOURCE: Halox Pigments: Formulation MV-23/3BlXA
  • 183.
    Primers 179 Waterborne BlackIron Oxide Primer Based on EDotuf 37-143/37-680 (Formula No. 3019-38A) Component A: Arcosolv PTB Dowanol PPH Add f o l l o w i n g i n order under a g i t a t i o n : Epotuf 37-680 BK-5099 Wollastokup 10 ES High speed disperse t o 5 N.S. Add f o l l o w i n g under a g i t a t i o n : Epotuf 37-680 Arcosolv PTB Tap Water Lbs 183.82 38.54 10.79 85.85 285.60 214.59 25.73 92.72 Component 8 : Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i 1 uniform: Epotuf 37-143 77.43 Mineral S p i r i t s 24.71 Aromatic 150 24.71 Tap Water 33.32 Weight/Gallon (Lbs.): 10.98 Percent S o l i d s (Wt.): 55.56 Percent S o l i d s ( V o l . ) : 38.67 PVC (%I: 35.88 VOC (Lbs./Gallon): 2.50 SOURCE: Reichhold Chemicals, I n c . : Formula No. 3019-38A Gals 20.75 5.28 1.23 2.07 11 .80 24.22 3.52 11.13 8.80 3.85 3.35 4.00
  • 184.
    180 Water-Based PaintFormulations Waterborne Red I r o n Oxide Primer Based on EDotuf 37-143/37-680 I f o r m u l a No. 2954-76A) Component A: Arcosolv PTB Dowanol PPH Add f o l l o w i n g i n order under a g i t a t i o n : R5098 Red I r o n Oxide Wollastokup 10 ES High speed disperse t o 5 N.S. Add f o l l o w i n g under a g i t a t i o n : Epotuf 37-680 Epotuf 37-680 Arcosolv PTB Tap Water Lbs 172.36 34.47 10.34 87.04 290.42 209.42 24.99 112.88 Component 0 : Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l uniform: Epotuf 37-143 72.91 Mineral S p i r i t s 24.13 Aromatic 150 24.13 Tap Water 39.07 Weight/Gallon (Lbs.): 11.02 Percent Sol i d s (Wt. ) : 54.89 Percent S o l i d s ( V o l . ) : 37.68 PVC (%I: 37.25 VOC (Lbs./Gallon): 2.46 SOURCE: Reichhold Chemicals, I n c . : Formula No. 2954-76A Gals 19.45 4.72 1.18 2.03 12.00 23.64 3.42 13.55 8.28 3.76 3.28 4.69
  • 185.
    Primers 181 Waterborne RedOxide Epoxy Primer Materi a1 : P a r t A: Epi -Rez 5522-WY-55 Resin D i acetone A1coho1 Col 1o i d 640 Defoamer Water R0-4097 Kroma Red, Red I r o n Oxide Sparmite Barium S u l f a t e 1OES Wollastokup Halox SW-111 Zeeosphere 400 Water Ground Mica, 325 Mesh High Speed Disperse t o a T e x t u r e o f 5-6 N.S € p i -Rez 5522-WY-55 Resin Water P a r t 8 : €pi-Cure 8290-Y-60 Curing Agent Water Composi t e 61end: V i s c o s i t y P a r t A P a r t B P a r t s A and B 70 K.U. T y p i c a l Coating P r o p e r t i e s : T o t a l Weight S o l i d s , %: 62.0 T o t a l Volume S o l i d s , %: 46.2 P . V . C . , %: 35.0 I n d u c t i o n Time, minutes: 30 V o l a t i l e Organic Compounds (VOC): Pounds/Gallon: 1.23 Grams/Li t e r : 148 Resin Composi t i on : Epoxy Resin, %: 87.6 Curing Agent, %: 12.4 T o t a l , %: 100.0 Pounds 330.0 7.0 3.5 60.0 71.1 71 . I 106.7 100.0 71 . 1 7.5 147.0 14.2 60.0 110.0 989.2 170.0 Gal l o n s 37.21 0 . 8 9 0.41 7.20 1.74 1 . 9 4 4.40 4.20 3.55 0.32 16.43 1 .71 6.80 13.20 80.00 20.00 Source: S h e l l Chemical Co.: S t a r t i n g Formulation No. 1810: Epi-Rez 5522-WY-55 Resin/Epi-Cure 8290-Y-60 Curing Agent
  • 186.
    182 Water-Based PaintFormulations Waterborne Y e l l o w I r o n Oxide Primer Based on EDotuf 37-143/37-680 (Formula No. 3019-396) Component A: A r c o s o l v PTB Dowanol PPH Add f o l l o w i n g i n order under a g i t a t i o n : Epotuf 37-680 YD-2288 Wollastokup 10 ES High speed disperse t o 5 N.S. Add f o l l o w i n g under a g i t a t i o n : Epotuf 37-680 A r c o s o l v PTB Tap Water & 183.41 38.45 10.77 69.43 284.95 214.11 25.88 93.71 Component 8 : Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l uniform: Epotuf 37-143 77.25 Mineral S p i r it s 24.55 Aromatic 150 24.55 Tap Water 33.90 Weight/Gallon ( L b s . ) : 10.81 Percent Sol i d s (Wt. ) : 54.80 Percent S o l i d s ( V o l . ) : 38.50 PVC (%): 35.89 VOC ( Lbs./Gal 1on) : 2.50 SOURCE: Reichhold Chemicals. I n c . : Formula No. 3019-398 Gals 20.70 5.72 1.22 2.07 11.77 24.17 3.55 11.25 8.78 3.82 3.33 4.07
  • 187.
    Primers 183 Water ReducibleAlkyd Yellow I r o n Oxide Primer Using Halox SZP-391 Grind: Chempol 10-0091 Butyl Cel losolve DMEA Aqua Ammonia (28%) Y.I.O. YO-2087 Halox SZP-391 Beaverwhit e 325 Snowf1ake Bentone SD-1 Disperse a t high speed t o 4+ NS grind. Letdown : Chempol 10-0091 DMEA Aqua Ammonia (28%) Cobalt Hydro-Cure 5% Cal c i um Hydro-Cure 5% Zirconium Hydro-Cure 12% Active 8 Byk 301 n-Butanol Add slowly while mixing. Water Lbs./100 Gals. Gms/Liter 200.0 240.0 55.0 66.0 4 . 0 4 . 8 4 . 0 4 . 8 75.0 90.0 33.0 40.0 75.0 90.0 75.0 90.0 1 .o 1.2 50.0 4 . 0 4 . 0 2 . 0 3 . 5 2 . 0 1.o 1 .o 25.0 60.0 4 . 8 4 . 8 2 . 4 4 . 2 2 . 4 1 . 2 1 . 2 30.0 400.0 480.0 Formula Constants: % P i gment/Wt .: 25.67 % Pigment/Vol .: 10.24 % Solids/Wt.: 44.75 % S o l i ds/Vol .: 31.35 % PVC: 32.65 VOC, lbs./gal.: 2.93 VOC, g/L: 351.68 Formula Properties: Density lbs./gal.: 10.15 Density g/L: 1,217.8 KU V i sc. @ R.T. : 80-85 pH @ R.T.: 9.0-9.5 SOURCE: Halox Pigments: Suggested Formulation WRA-301
  • 188.
    184 Water-Based PaintFormulations Water R e d u c i b l e A l k y d Y e l l o w I r o n Oxide Primer U s i n s Halox CW-491 G r i n d : Chempol 10-0091 B u t y l C e l l o s o l v e DMEA Aqua Ammonia (28%) Halox CW-491 Y.I.O. YO-2087 Beaverwhi t e 325 Snowf 1ake Bentone SD-1 D i s p e r s e a t h i g h speed t o 4+ NS g r i n d . Letdown : Chempol 10-0091 DMEA Aqua Ammonia (28%) C o b a l t Hydro-cure 5% Calcium Hydro-cure 5% Z i r c o n i u m Hydro-cure 12% A c t i v e 8 Byk 301 n-Butanol Add s l o w l y w h i l e m i x i n g . Water M i x u n t i l u n i f o r m . Formula Constants: % Pigment/Wt.: 25.67 % P i gment/Vol .: 10.24 % S o l i d s / W t . : 44.75 % Sol i d s / V o l .: 31 .35 % PVC: 32.65 VOC, l b s . / g a l . : 2.93 VOC, g/L: 351.68 Lbs./lOO Gals. Gms/Liter 200.0 240.0 55.0 66.0 4.0 4.8 4.0 4.8 75.0 90.0 33.0 40.0 75.0 90.0 75.0 90.0 1.0 1.2 50.0 4.0 4.0 2.0 3.5 2.0 1 .o 1.o 25.0 60.0 4.8 4.8 2.4 4.2 2 . 4 1 . 2 1.2 30.0 400.0 480.0 Formula P r o p e r t i e s : D e n s i t y l b s . / g a l . : 10.15 D e n s i t y g/L: 1,217.8 KU V i s c . @ R.T.: 80-85 pH C R.T.: 9.0-9.5 SOURCE: Halox Pigments: Suggested F o r m u l a t i o n WRA-491
  • 189.
    Primers I85 Water ReducibleEDoxv-Ester Red I r o n Oxide Primer Grind: W/R Epoxy Ester Resin B u t y l C e l l os01ve Aqua Ammonia (28%) Red I r o n Oxide Halox SZP-391 Talc AMP-95 Lbs/100 Gals. Gms/Liter 340.0 408.0 25.0 30.0 3.0 3 . 6 3.0 3.6 100.0 120.0 42.0 50.4 791 .O 229.2 High speed d i s p e r s e t o 4+ NS G r i n d Letdown : W/R Epoxy Ester Resin B u t y l Cel l o s o l ve Aqua Ammonia (28%) Cobalt Hydrocure (13%) Manganese Hydrocure (12%) A c t i v 8 N-Butanol Byk 301 Add s l o w l y w h i l e mixing and mix u n t i l uniform. 125.0 25.0 3.0 2.5 2.5 1.o 25.0 2.0 150.0 30.0 3 . 6 3.0 3.0 1.2 30.0 2.4 Water 175.0 210.0 Formula Constants: % P i gment/Wt. : 31 .24 % Pigment/Vol.: 12.15 % Solids/Wt.: 52.28 % S o l i d s / V o l . : 34.70 % PVC: 34.70 VOC, l b s . / g a l . : 4.13 voc, g/L: 494.87 Formula P r o p e r t i e s : Density l b s . / g a l . : 10.65 Oensity g / l . : 1,278.4 KU Visc. @ R.T.: 80-85 pH @ R.T.: 9.0-9.5 SOURCE: Halox Pigments: Suggested Formulation WREE39lH
  • 190.
    186 Water-Based PaintFormulations Water Reducible Eooxv-Ester Red I r o n Oxide Primer Grind: W/R Epoxy Ester Resin Butyl Cellosolve Aqua Ammonia (28%) Red I r o n Oxide Halox CW-191 Talc AMP-95 Lbs./100 Gals. Gms/Liter 340.0 408.0 25.0 30.0 3.0 3.6 3.0 3.6 100.0 120.0 42.0 50.0 190.0 228.0 High speed disperse t o 4+ NS grind. Letdown : W/R Epoxy Ester Resin Butyl Cellosolve Aqua Ammonia (28%) Cobalt Hydrocure (12%) Manganese Hydrocure (12%) A c t i v e 8 N-Butanol BYK 301 Add slowly w h i l e mixing and mix u n t i l uniform. 125.0 150.0 25.0 30.0 3.0 3.6 2.5 3.0 2.5 3.0 1.o 1.2 25.0 30.0 2.0 2.4 Water 175.0 210.0 Formula Constants: % P i gment/Wt .: 31 ,55 % P i gment/Vol .: 12.35 % Sol ids/Wt. : 52.54 % Solids/Vol.: 34.90 % PVC: 35.39 VOC, l b s . / g a l . : 4.12 VOC, g/L: 493.60 Formul a Properti 8s : Density l b s . / g a l . : 10.64 Density g/L: 1,276.4 KU Visc. @ R.T.: 80-85 pH @ R.T.: 9.0-9.5 SOURCE: Halox Pigments: Suggested Formulation WREE491
  • 191.
    Primers 187 Water ReducibleEpoxy-Ester Red Iron Oxide Primer Using Halox CW-491 Grind: W/R Epoxy Ester Resin B u t y l C e l l o s o l v e Aqua Ammonia (28%) Red I r o n Oxide Halox CW-491 Talc AMP-95 Lbs. / l o 0 Gals. Gms/Li t e r 340.0 408.0 25.0 30.0 3.0 3.6 3.0 3.6 100.0 120.0 42.0 50.0 190.0 228.0 High speed disperse t o 4+ NS g r i n d . Letdown : W/R Epoxy Ester Resin B u t y l C e l l o s o l v e Aqua Ammonia (28%) Cobalt Hydrocure (12%) Manganese Hydrocure (12%) A c t i v e 8 N- Butano1 Byk 301 Add slowly w h i l e mixing and mix u n t i l uniform. 125.0 25.0 3.0 2.5 2.5 1.o 25.0 2.0 150.0 30.0 3.6 3.0 3.0 1.2 30.0 2.4 Water 175.0 210.0 Formula Constants: % P i gment/Wt .: 31 .55 % P i gment/Vol .: 12.35 % Solids/Wt.: 52.54 % S o l i d s / V o l . : 34.90 % PVC: 35.39 VOC, l b s . / g a l . : 4.12 VOC, g/L: 493.60 Formula P r o p e r t i e s : Density l b s . / g a l . : 10.64 Density g/L: 1,276.4 KU Visc. @ R . T . : 80-85 pH @ R.T.: 9.0-9.5 SOURCE: Halox Pigments: Suggested Formulation WREE491
  • 192.
    188 Water-Based PaintFormulations White. Corrosion Resistant Latex Primer Innredient s : Pigment G r i nd: Water Busperse 39/Dispersant Bubreak 448/Defoamer Igepal CTA 639/Surfactant C e l l o s i z e QP-l500O/Hydroxyethyl Water B u t r o l 23/Modified Barium Meta- T i -Pure R-SOO/Titanium Dioxide- Atomite/Calcium Carbonate Mica-325 Mesh/Water Ground Let Down: Rhoplex MV-23/Acryl i c Emu1sion Texanol/Ester Alcohol Ethylene Glycol Water Pai n t Propert ies : Total Vehicle 63.19 Pigment 36.81 V o l a t i l e 44.32 Organic Solvent 4.23 Non-Volatile 55.68 Non-Volatile Vehicle 18.87 Density (lb/U.S g a l ) : 11.61 S p e c i f i c G r a v i t y : 1.39 P.V.C.: 40.65% P/B Ratio: 1.951 Spread @ 1 M i l : 617 F2 Coating VOC: 134 G/L M a t e r i a l VOC: 59 G/L C e l l u lose borate R u t i l e !& Gal 100.12 12.02 10.01 0.93 3.00 0.44 3.00 0.34 2.00 0.17 25.03 3.00 100.12 3.25 150.19 4.51 150.19 6.65 25.03 1.07 500.62 56.89 7.01 0.89 30.04 3.23 55.07 6.61 %vel 84.36 15.64 61 .52 5.63 38.48 22.84 a 8.62 0.86 0.26 0.26 0.17 2.16 8.62 12.93 12.93 2.16 43.10 0.60 2.59 4.74 SOURCE: Buckman Laboratories: Formulation Suggestion: KP-08
  • 193.
    Primers 189 White In h i b i t i v e Maintenance Primer I n a r e d i e n t s : Pigment G r i n d : Water Eentone LT Methyl C a r b i t o l S o l v e n t Tamol 681 Nuosept 95 DeeFo HG-12 T r i t o n N o n i o n i c S u r f a c t a n t CF-10 Ammonium Hydroxide, 28% Aqueous S o l u t i o n A c r y s o l RM-2020 Tronox CR-828 Heucophos ZBZ Atomi t e Letdown : Methyl C a r b i t o l S o l v e n t A c r y s o l SCT-275 Ucar V e h i c l e 435 Ucar F i l m e r IET Troysan Polyphase AF-1 Foamex 825 Sodium N i t r i t e , 15% Aqueous S o l u t i o n Ammonium Hydroxide, 28% Aqueous S o l u t i o n Pounds 151.5 1 . o 25.5 18.2 2 . 3 2.1 2 . 2 1.8 17.2 100.0 50.0 125.7 8 . 5 8 . 6 505.1 1 1 . 4 4.9 2 . 1 9 . 0 1.8 loris 8.19 0 . 0 6 3.00 2.00 0.25 0.25 0.25 0.25 2.00 2.93 1.67 5.57 1.oo 1 .oo 58.06 1 . 4 4 0.50 0.25 1.08 0.25 A d j u s t t o minimum p H 8 . 7 Pai n t P r o p e r t i es : Pigment Volume C o n c e n t r a t i o n (PVC) , %: 30.0 T o t a l S o l i d s , %: by volume: 34.0 pH Value, i n i t i a l : 8 . 7 V i s c o s i t y : Stormer, KU: 80 I C I , p o i s e : 0.8 Weight p e r G a l l o n , l b : 10.5 Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks a t 140F: Pass SOURCE: Ucar Emulsion Systems: Ucar V e h i c l e 435: F o r m u l a t i o n Suggestion M-2451
  • 194.
    Sealants and RelatedCompounds 191 Ancamide 2353 Curina Aaent Aluminum Mastic P r e l im inary Formulation Part A: L i q u i d DGEBA Epoxy MPA-1078 (Rheox) 10 Wollastekup AS (Nyco) Disperse t o 6 Hegman and 130F: Epodil L ( A i r Products) High Flash Naphtha Beetle 216-8 (Cyanamid) Lansford L243 ( S i 1b e r l i n e ) Diacetone Alcohol (Union Carbide) Cabosil TS 720 (Cabot) Part 8 : Ancamide 2553 ( A i r Products) -Lb Gal 307 31.7 8 1.0 250 10.3 35 4.0 120 16.5 25 2.8 125 10.2 24 3.0 10 0.4 169 20 Properties: Volume S o l i d s : 71 .9% VOC: t2.5 l b gal PVC: 20.0% Mixing Ratio 4:l by Volume CPVC: 47.1% Pot L i f e , h r 5 PVC/CPVC: 0.426 Dry t o Touch, h r : 3 Weight/gallon, Part A: 11.29 Dry Through, h r : 7 Weight/gallon, Part B: 8.45 Wei ght/gal lon: 10.73 SOURCE: A i r Products and Chemicals, I n c . : Ancamide 2353 Curing Agent: Table 10 Formula
  • 195.
    192 Water-Based PaintFormulations Clear Sealant Inaredients : Ucar Latex 100 T e r g i t o l Nonionic Surfactant NP-4 Nopco NXZ Proxel GXL Ucar Filmer I B T Cosan 158 Propylene Glycol Ucar Thickener 146 Ammonium Hydroxide, 28% Aqueous S o l u t i o n Acrysol SCT-275 Weight% 95.15 0.16 0.36 0.24 0.85 0.42 0.85 0.48 0.64 0.85 M i x i ng Procedure: A high-shear, low-speed vacuum mixer o f t h e double-bladed planetary type o r t h e double-bladed sigma type i s recommended. Charge t h e l a t e x t o t h e mixer. Add t h e remaining i n g r e d i e n t s slowly i n t h e order l i s t e d t o t h e mixer w i t h a g i t a t i o n . The mix w i l l thicken when t h e NH40H i s added. S t i r f o r f i v e minutes and then add associative thickener. Mixing time should be >30 m i nutes. Sealant Properties: Nonvolati les, % by weight: 61.9 pH Value: 8.8 Viscosity, Brookfield, P: 24,000 Semco Gunnability, g/sec: 28 ASTM C731: Pass Tooling Time, min: >5 Boeing Slump, i n : 0 . 0 Elongation a t Break, %: 1000 Tensile Strength, max, p s i : 230 Time f o r 180-mil Bead t o D r y Clear, days: 7 Shore "A" Hardness, 7 days a t 50% R.H.: 48 SOURCE: Ucar Emulsion Systems: Ucar Latex 100: Formulation Suggestion CC-1010
  • 196.
    Sealants and RelatedCompounds 193 High-Qual it y E x t e r i o r Latex Caulk I n g r e d i e n t s : C o l l o i d 677 Propyl ene G1yco T e r g i t o l Nonion Composi t ion T Potassium T r i p o Tamol 983 T i -Pure R-900 Ucar Latex 100 S a n t i c i z e r 160 Organofuntional Camel Carb Snowf1ake Camel Cal Mineral Spi r its Nuosept 95 Skane M8 Acrysol SCT-275 c Surfactant NP-40 yphosphate (KTPP) Silane A-187 Ammoni um Hydroxi de, 14% Aqueous Sol u t i on Caulk Properties: T o t a l Solids, %: bv weiaht: 84.7 Pounds 1.8 13.6 5.5 3.0 0.5 0.9 12.7 418.0 0.5 109.0 0.6 521.6 172.7 58.2 22.7 1 . 8 2.3 5.5 Gallons 0.3 1.6 0.6 0.1 0.0 0.1 0.4 46.9 0.1 11.8 0.1 23.0 7 . 7 2.6 3.5 0.2 0.3 0 . 7 Wt% 0.13 1.01 0.40 0.22 0.04 0.07 0.94 30.94 0.03 8.07 0.05 38.63 12.78 4.31 1.68 0.13 0.17 0.40 -by volume: 74.4 Weight per Gallon, t h e o r e t i c a l , l b : 13.5 V i s c o s i t y , B r o o k f i e l d , P: I n it i a1 : 2800 A f t e r 5 freeze-thaw cycles: 2150 Pigment Volume Concentration, %: 45 Boeing Slump: None O F Bend: Pass Shore "A" Hardness, 72F a t 50% R.H. : 1-day: 10 3-day: 33 7-day: 50 i n i t i a l : 9.5 a f t e r 5 freeze-thaw cycles: 9.0 Stress-Strain Properties: 32F -OF t e n s i l e strength, max, p s i 54 67 330 elongation a t break, % 230 155 87 Semco Gunnability, g/sec: Adhesion P r o p e r t i es : 180 Peel Adhesion*, p l i Substrate Drv 24-hr. Water Soak G1ass 20.7 (COH) 15.1 (COH) A1umi num 21.9 (COH) 13.2 (COH) Concrete 20.5 (COH) 12.7 (AO/COH) Hypalon Sheet 13.8 (COH) 12.9 (COH) * COH=cohesive f a i 1ure A 0 =adhesive f a i 1ure SOURCE: Ucar Emulsion Systems: Ucar Latex 100: Formulation Suggestion CP-1001
  • 197.
    194 Water-Based PaintFormulatiom Patchina C o l w u n d (Brushina Grader I n q r e d i e n t s : Pi gment G r i nd : Ucar Latex 163 Wetting Agent (1) S l u r r y o f : Water Ammonium Hydroxide, 28% Aqueous S o l u t i o n Antifoam (2) Dispersant (3) Preservative ( 4 ) Calcium Carbonate (5) Mica ( 6 ) Titanium Dioxide ( 7 ) M i 1dewci de (9) Let Down: Coarse S i l i c a (10) Mineral Spi r it s Ammonium Hydroxide, 28% Aqueous S o l u t i o n Ethylene Glycol Suppl ie r s : *Post Added Pounds 667.5 1.7 8.3 1 . 5 3.9 3.1 0 . 8 90.0 25.8 65.6 4.5 286.7* 3.4 3.4 17.6 Gallons 75.0 0.2 1.o 0.2 0.5 0.3 0.1 4.0 1.1 2.1 0.3 12.2 0.6 0.5 1.9 Wetting Agent - Surfynol 104 ( A i r Products) o r equivalent. Antifoam - C o l l o i d 770 ( C o l l o i d s ) o r equivalent. Dispersant - C o l l o i d 226/35 ( C o l l o i d s ) o r equivalent. Preservative - Cosan 101 (Cosan) o r equivalent. Calcium Carbonate - Duramite (Thompson, Weinman) or equivalent. Mica - 325 WG Mica (KMG Minerals) o r equivalent. Titanium Dioxide - Ti-Pure R-901 (DuPont) o r equivalent. S i l i c a - C e l i t e 281 (Johns-Manville) o r equivalent. Mildewcide - Nopcocide N-96 (Diamond Shamrock) o r equivalent. Coarse S i l i c a - Ruff B u f f (Tammsco) o r equivalent. Patching Compound P r o p e r t i8s: Pigment Volume Concentration (PVC) , %: 31 .7 Total Solids, %: by Volume: 60.4 by Weight: 71.6 SOURCE: Ucar Emulsion Systems: Ucar Latex 163: Formulation Suggestion V-2084
  • 198.
    Sealants andRelated Compounds195 Patchins Compound (Trowel Gradel I n a r e d i e n t s : Pigment Grind: Ucar Latex 163 Wetting Agent (1) S l u r r y o f : Water Ammonium Hydroxide, 28% Aqueous S o l u t i o n T e r g i t o l Nonionic Surfactant NP-40 Antifoam (2) Dispersant (3) Preservative ( 4 ) Calcium Carbonate (5) Mica (6) Titanium Diox S i l i c a (8) Mildewcide (9 Let Down: Coarse S i 1i c a Pounds 685.3 8.6 1.7 1 .l 1.7 3.5 0.8 219.3 ----- Gallons 77.0 1 .o 0.2 0.1 0.2 0.3 0.1 9.7 ---- 25.8 1.1 64.4 2.1 64.6 3.4 5.1 0.3 34.5 1.6 3.4 0.5Mineral S p i r i ~ Ammonitim Hvdrnxida. 3R% A a t i e n u s S n l u t i n n 3 . 4 0 . 5........-.. . -... ..,-. -...--, --.- . .------ -- . - - .-.. - . . Ethylene Glycol 17.2 1.9 Suppliers: ( 1 ) Wetting Agent - Surfynol 104 ( A i r Products) o r equivalent (2) Antifoam - C o l l o i d 770 ( C o l l o i d s ) o r equivalent. (3) Dispersant - C o l l o i d 226/35 ( C o l l o i d s ) o r equivalent. (4) Preservative - Cosan 101 (Cosan) o r equivalent. (5) Calcium Carbonate - Duramite (Thompson, Weinman) o r (6) Mica - 325 WG Mica (KMG Minerals) o r equivalent. (7) Titanium Dioxide - Ti-Pure R-901 (DuPont) o r equivalent. (8) S i l i c a - C e l i t e 281 (Johns-Manville) o r equivalent. (9) Mildewcide - Nopcocide N-96 (Diamond Shamrock) o r (10) Coarse S i l i c a - Ruff B u f f (Tammsco) o r equivalent. equivalent. equivalent. Patching Compound Properties: Pigment Volume Concentration (PVC), %: 29.7 Total Solids, %: by Volume: 59.9 by Weight: 70.7 SOURCE: Ucar Emulsion Systems: Ucar Latex 163: Formulation Suggestion V-2083
  • 199.
    1% Water-Based PaintFormulations PiQlented Caulk Formulation based on 2:l V i n y l A c r v l i c / A c r v l i c Blend I n a r e d i ents: Ucar Latex 161 Ucar Latex 163 T r i t o n Nonionic Surfactant X-405 Nopco NXZ Propylene G1ycol Ammonium Hydroxide, 14% Aqueous S o l u t i o n Cosan 234 Acrysol SCT-200 S a n t i c i z e r 160 S i l a n e A-187 Mineral Spi r it s Pounds 269.5 127.7 5.0 1.6 12.5 0.4 6.0 0.5 99.8 0.6 20.8 Blend 10 minutes, then add t h e f o l l o w i n g : Tamol 850 1.2 Composit ion T 3.3 T i -Pure CR-800 14.0 W i ngdal e White 576.2 Potassium Tripolyphosphate (KTPP) 0.5 Microwhite 25 254.0 Ammonium Hydroxide, 28% Aqueous S o l u t i o n 0.8 Gallons 30.12 14.40 0.60 0.20 1.50 0.05 0.70 0.06 10.70 0.07 3.20 0.15 0.40 0.81 25.50 0.02 11.40 0.12 Disperse a t h i g h speed u n t i l uniform i n consistency ( t y p i c a l l y Typical Properties: T o t a l Solids, %: 10-30 minutes) . by weight: 83.9 by volume: 73.6 Pigment :B i nder Ratio: 3.2:1 P l a s t i c i z e r on Latex S o l i d s , 96: 44.9 SOURCE: Ucar Emulsion Systems: Ucar Latex 161: Formulation JDD-995
  • 200.
    Sealants and RelatedCompoundF 197 Premi um-Performance. Medium-F1 e x i b i 1it y Caul k Inaredients: Ucar Latex 163 Surfactant (1) Surfactant (2) P l a s t i c i z e r (3) Tooling Agent (4) Ethylene Glycol Water Cal c i um Carbonate (5) T i t a n i um Dioxide (6) Ammonium Hydroxide, 28% Sol u t ion Pounds 485.0 6 . 5 8 . 5 93.5 19.0 12.5 32.5 583.0 10.0 0 . 5 Aqueous Gallons 54.5 0.7 0.4 10.1 2.9 1.4 3.9 25.8 0.3 --- K% 38.8 0.5 0 . 7 7.5 1.5 1.o 2.6 46.6 0.8 --- Suppl iers : (1) Surfactant - T r i t o n X-405 (Rohm and Haas) o r equivalent. (2) Surfactant - Composition R (Merck) o r equivalent. (3) P l a s t i c i z e r - S a n t i c i z e r 160 (Monsanto) o r equivalent. (4) Tooling Agent - Varsol No. 1 (Exxon) o r equivalent. (5) Calcium Carbonate - Atomite (Thompson, Weinman) o r (6) Titanium Dioxide - Ti-Pure R-901 (DuPont) o r equivalent. equivalent. Seal ant Properties : Total Solids, % by w t : 79.0 Weight per Gallon ( t h e o r e t i c a l ) , l b : 12.5 F i l l e r / L a t e x Solids Ratio: 2.1/1.0 P l a s t i c i z e r (on t o t a l binder s o l i d s ) , % by w t : 26.0 Shore "A" Hardness ( 4 wks a t 73F, 50% RH): 27 Tensile Strength ( 2 w k s a t 73F, 50% RH), p s i : 13 Elongation ( 2 wks a t 73F, 50% RH), %: 460 180 Peel Adhesion (per i n ) : Pinewood: 9 (adhesive) Aluminum: 11 (cohesive) Glass: 12 (cohesive) Extrusion: Good g u n n a b i l i t y ASTM Shrinkage (28 days a t 73F, 50% RH) Slump a t Room Temperature: None Recovery (25% Extension RT f o r 1/2 h r ) , SOURCE: Ucar Emulsion Systems: Ucar Latex Suggestion K-2080 %: <25 %: >80 63: Formulation
  • 201.
    198 Water-Based PaintFormulations Sealant A ~ p l i c a t i o n Inqredients: Ucar Latex 163 Surfactant (1) P l a s t i c i z e r (2 Tool ing Agent Water Ethvlene Glvco 3) Calcium carbonate ( 4 ) Extender (5) Surfactant (6) Titanium Dioxide ( 7 ) Weiqht% 33.00 0.70 9.00 2.00 1.50 1 .oo 48.00 3.00 1.oo 0.80 Suppl ie r s : ( 1 ) Surfactant - T r i t o n X-405 (Rohm and Haas) o r equivalent. (2) P l a s t i c i z e r - Benzoflex 9-88 ( V e l s i c o l ) or equivalent. (3) Tooling Agent - Varsol No. 1 (Exxon) o r equivalent. (4) Calcium Carbonate - Atomite (Thompson, Weinman) o r (5) Extender - Barytes No. 1 (Williams) o r equivalent. (6) Surfactant - Composition T (Merck) o r equivalent. ( 7 ) Titanium Dioxide - Ti-Pure R-901 (OuPont) o r equivalent. equivalent. Sealant Properties: Nonvolatiles, %: 83.3 F i l l e r / L a t e x Solids Ratio: 2.6/1.0 P l a s t i c i z e r t o Latex Solids, %: 31.2 Weight per Gallon, l b : 12.5 24-hr Extrusion Rate, g/sec: 3 Shore "A" Hardness, 1 month: 22 Tensile Strength, p s i : 8 Elongation, %: 158 Accelerated Weathering, XW, Wooden Channel, 1000 h r : Very good SOURCE: Ucar Emulsion Systems: Ucar Latex 163: Formulation Suggestion K-2079
  • 202.
    Sealants and RelatedCompouna!s 199 Translucent Caulk Formulation Inaredients: Lb/100 Gal Gallons Ucar Latex 105 758.16 89.09 Antifoam (1) 0.59 0.08 Ucar Filmer IBT 6.18 0.87 Ammonium Hydroxide, 28% Aqueous S o l u t i o n 5.88 0.78 Ethylene Glycol 9.81 1.06 Nonionic Surfactant ( 2 ) 1.96 0.26 Dispersant (3) 1.96 0.22 S i l i c a (4) 24.52 1.34 P l a s t i c i z e r (5) 53.94 5.83 Union Carbide Organofunctional Silane A-187 3.92 0.44 Preservative (6) 2.94 0.39 T e r g i t o l Nonionic Surfactant NP-10 2.94 0.35 Suppl ie r s : (1) Antifoam-Nopco NXZ (Henkel) o r equivalent. (2) Nonionic Surfactant - Surfynol 104E ( A i r Products) o r (3) Dispersant - Disperse-Ayd W-22 (Daniel) o r equivalent. (4) S i l i c a - Cab-0-Si1 L-90 (Cabot) o r equivalent. ( 5 ) P l a s t i c i z e r - S a n t i c i z e r 160 (Monsanto) o r equivalent. (6) Preservative - Nuosept 95 (Huls) o r equivalent. equi Val ent . Typical P r o p e r t i 8s: pH Value: 7.2 T o t a l Solids, %: by Weight: 60.2 by Volume: 55.1 B r o o k f i e l d V i s c o s i t y , P: 31,000 Typical Performance Properties: Boei ng S1ump: Passed Semco Gunnability, g/sec: 32 A f t e r 5 Freeze-Thaw Cycles: 11 A f t e r 14-day Heat Aging: 34 7-day d r y : 30 14-day d r y : 30 Shore A: ASTM C679 Tack: Passed ASTM C794 180 Peel Adhesion, p l i : Dry Glass: 33.8 Dry Aluminum: 31.3 Wet Glass (7-day immersion): 15.0 Wet Aluminum: 14.0 ASTM C793: Passed SOURCE: Ucar Emulsion Systems: Ucar Latex Suggestion CT-2002 05: Formu a t i o n
  • 203.
    200 Water-Based PaintFormulations Translucent Caulk Formulation Ingredients: Ucar Latex 169 Nopco NXZ Ammonium Hydroxide, 28% Aqueous Ethylene G1ycol Surfynol 104E Daniels WO-22 Cab-0-Si 1 L-90 Santicizer 160 Organof u n c t i onal S i 1ane A-1 87 Nuosept 95 T e r g i t o l Nonionic Surfactant NP- Pounds 758.5 0.6 Sol u t i on 6.3 14.4 2.1 2.1 26.4 58.2 4.2 3.2 ,lo 3.2 Typical Properti8s: Total Solids, % by weight: 63.5 pH: 7.2 Viscosity, Poise: 31,000 Tensile, p s i , maximum: 64 Elongation a t break, %: 990 Water Absorption, %, 7 days: 31.6 Formulation CT-2012 ASTM C-920 Pigmented Caulk Formulation Ingredients: Santicizer 160 Potassi um Tripolyphosphate (KTPP) T r i t o n Nonionic Surfactant X-405 Oaxad 30-30 Pounds 106.1 1.8 13.5 Proxel GXL Cosan 101 Ucar Latex 169 Snowf 1ake T i -Pure R-902 Mineral S p i r i t s Organofunctional S Ammoni um Hydroxide Methocel 856 Propylene G1ycol Acrysol ASE-60 1.8 1 .o 1.5 481.1 532.7 12.9 25.1 lane A-187 1.2 28% Aqueous Solution 1.3 2.1 14.6 9.3 Gal 1ons 87.90 0.09 0.84 1.56 0.28 0.24 1.44 6.28 0.47 0.42 0.38 Gallons 11.46 0.08 1.53 0.19 0.13 0.19 55.48 23.65 0.39 3.97 0.14 0.17 0.18 1.68 1.06 Typical Properti 8s Total Solids, %: Tensile, psi, maximum: 90 Pigment:Binder: 1.8:l Shore A Hardness: 30 SOURCE: Ucar Emulsion Systems: Ucar Latex 169: Suggested by weight: 79.5 Elongation a t Break, %: 270 by volume: 70.7 Water Absorption, %, 7 days: 11.3 Formu1a tiono
  • 204.
    Sealants and RelatedCompounds 201 Trans1ucent Seal ant Inqredi ents: Ucar Latex 100 Nopco NXZ Ucar Filmer IBT Ammoni um Hydroxi de, 14% Aqueous Propyl ene G1ycol Surfynol 104 D i sperse-ayd W-22 Cab-0-Si1 LM-130 Organofunctional Silane A-187 So1u t i on Pounds 815.50 0.68 7.13 13.53 11.32 2.22 2.29 28.04 3.36 42 28 Nuisept 95 3. T e r g i t o l Nonionic Surfactant NP-10 3 Caulk Properties: Total Solids, % by weight: 61.2 pH Value: 9.4 Weight per Gallon, t h e o r e t i c a l , l b : Viscosity, Brookfield, P: 27,800 Boeing Slump: None Semco Gunnability, g/sec: i n i t i a l : 24 a f t e r 5 freeze-thaw cycles: 24 glass: >50 a1umi num: >50 Hunter Lab Color: L: +93.24 a: -0.59 180 Peel Adhesion, Dry, p l i : b: -0.78 3.5 Gallons 92.67 0.09 1.oo 1.71 1.31 0.30 0.26 1.53 0.39 0.36 0.39 Wei qht% 91.47 0.08 0.80 1.52 1.27 0.25 0.25 3.16 0.40 0.40 0.40 Y I E : -0.93 ASTM C732 Weathering-500 Hours: no cracking no d i s c o l o r a t i o n no adhesion loss SOURCE: Ucar Emulsion Systems: Ucar Latex 100: Formulation Suggestion CT-2008
  • 205.
    202 Water-Bared PaintFormulatwns V i n y l Acrvl ic Seala n t Ingredients :. Ucar Latex 161 Kathon LX (1.5%) ( 1 ) Tamol 850 Ethylene Glycol S a n t i c i z e r 160 Mineral S p i r i t s Natrosol 250 MXR Potassi um Tripolyphosphate (KTPP) Camel F i l T i -Pure R-902 T r i t o n Nonionic S u r f a c t a n t X-405 Ammonium Hydroxide, 28% Aqueous S o l u t i o n T y p i c a l P r o p e r t i e s : T o t a l S o l i d s , %: by weight: 82.2 by volume: 78.2 Pigment Volume Concentration (PVC): 46.9 Pigment:Binder R a t i o : 3:l P l a s t i c i z e r on Latex S o l i d s , %: 40.0 Elongation a t Break, %: 722.0 Boeing Slump: Pass ASTM C-731: Pass ASTM C-732 Weathering: No bond l o s s ASTM C-734 OF Bend: Pass ASTM C-736 Extension-Recovery: Pass Water Absorption, 7 days, %: 41.9 Pounds 450.0 1.3 1.3 12.4 99.0 20.0 3.0 1 .o 729.4 15.0 9.1 0.5 Gal 1ons 50.34 0.15 0.14 1.34 10.69 3.07 0.05 32.42 0.45 1 .oo 0.07 0.28 SOURCE: Ucar Emulsion Systems: Ucar Latex 161 : Formulation CM-294
  • 206.
    Sealants and RelatedCompowrds 203 Weather-Barrier Mastic I n a r e d i ents: P igment G r ind: Water C e l l o s i z e Hydroxyethyl C e l l u l o s e D i spersant ( 1) Potassium Tripolyphosphate E t h y l ene G1ycol Antifoam (2) Titanium Dioxide (3) Calcium Carbonate (4) Zinc Oxide (5) M i ldewcide (6) Let Down: Ucar Latex 163 Ucar F i l m e r I B T Antifoam (2) Pounds 150.0 QP-4400H 4.0 4.0 1.o 20.0 1.5 62.0 407.0 40.0 5.0 Gallons 18.0 0.3 0.4 2.2 0.2 1.9 18.1 0.9 0.5 --- 502.0 56.4 6.0 0.8 2.0 0.3 Suppl ie r s : (1) Dispersant - C o l l o i d 226/35 ( C o l l o i d s ) o r equivalent. (2) Antifoam - Nopco NXZ (Diamond Shamrock) o r equivalent. (3) Titanium Dioxide - "Ti-Pure" R-960 (DuPont) o r equivalent (4) Calcium Carbonate - "Atomite" (Thompson, Weinman) o r (5) Zinc Oxide - AZO-55 (ASARCO) o r equivalent. (6) Mildewcide - Nopcocide N-96 (Diamond Shamrock) o r equiv- equi Val ent . a1e n t . Mastic P r o p e r t i e s : Pigment Volume Concentration (PVC), %: 40.0 T o t a l Solids, %: by Volume: 53.0 by Weight: 67.3 F i l m Properties*: Tensi 1e Propert ies : S t r a i n Rate, %: 20 100 200 Stress, p s i : 120 120 200 Elongation, %: 420 300 260 200S t r a i n Rate, in/min: --- --- 70Stress, p s i : --- --- 800Elongation, %: --- --- T e n s i l e P r o p e r t i e s a f t e r 7 days water immersion: Water Ponding: Water Transmission a t 24 h r : 210 mg water Low-Temperature F l e x i b i l i t y : 180 Bend a t -4F: No c r a c k i n g Water Vapor Transmission Rate f o r 336 h r , perms: 5.7 Adhesion t o Urethane Foam, 180 Peel, l b / i n : Dry: 7.8 (Foam Cohesion F a i l u r e ) Wet-7 days immersion i n water: 2.2 (Foam Cohesion F a i l u r e ) *Dried and conditioned 7 days a t 72F and 50% RH SOURCE: Ucar Emulsion Systems: Ucar Latex 183: Formulation Suggestion WB-2081
  • 207.
    204 Water-Based PaintFormulations Weather-Barrier Mastic The f o l l o w i n g formulation has undergone extensive e x t e r i o r exposure and provides improved resistance t o d i r t and d a r l y chal k i ng : Inqredients: Piament O r ind : Wa:er Dispersant ( 1) Potassi um Tripolyphosphate Wetting Agent (2) Ethylene Glycol Antifoam (3) Titanium Dioxide (4) Calcium Carbonate (5) Zinc Oxide (6) M i 1dewci de (7) Water Cel l o s i ze Hydroxyethyl Cellulose QP-15000 Let Down: Ucar Latex 163 Ucar Filmer I 8 1 Antifoam (3) Water Pounds 95.8 8.9 1.o 1.2 19.3 1.5 112.5 420.3 44.3 2.5 33.3 3.9 496.9 5.8 1.9 2.5 Gal 1ons 11.5 0.9 0.2 2.1 0.2 3.5 18.7 I.o 0.3 4.0 0.3 --- 55.8 0 . 8 0.3 0.3 Suppl iers : (1) Dispersant - C o l l o i d 226/35 (Collods) o r equivalent. (2) Wetting Agent - Surfynol 104 ( A i r Products) o r equivalent. (3) Antifoam - C o l l o i d 643 ( C o l l o i d s ) or equivalent. ( 4 ) Titanium Dioxide - Ti-Pure R-960 (DuPont) o r equivalent. (5) Calcium Carbonate - Atomite (Thompson, Weinman) o r equiv- (6) Zinc Oxide - XX-503 (NJ Zinc) o r equivalent. (7) Mildewcide - Skane M-8 (Rohm and Haas) o r equivalent. a l e n t . Mastic Properti8s : Pigment Volume Concentration (PVC) %: 43.0 Total Solids, % by Volume: 55.0 SOURCE: Ucar Emulsion Systems: Ucar Latex 183: Formulation Suggestion WB-2002
  • 208.
    206 Water-Based PaintFormulations Brown Wiping Stain Materi a1 : Kelsol 3931-WG4-45 2-Butoxy Ethanol Patcote 531 Red Iron Oxide R-4098 Yellow Iron Oxide 1075A Brown Iron Oxide 444 Syloid 234 Lbs. 261.00 18.00 7.50 7.30 4.50 14.90 25.00 Grind to a 5+ Hegman grind Kel sol 3931-WG4-45 402.00 Premix the following, then add under agitation. 2-Butoxy Ethanol Acti v-8 Cobalt Hydrocure I 1 Manganese Hydrocure I1 Pregel the following, then add under agitation: 4.00 2.40 3.80 6.00 Ammoni um Hydroxide Carbopol 941 Water Pol OX WSR-301 2.20 1.10 1.10 100.00 Analysis: Figment Volume Concentration, Percent: 2.17 Pigment/Binder Concentration, Percent: 0.164 Percent Sol ids, Weight : 42.55 Percent Solids, Volume: 39.29 Pounds/Gallon: 8.59 VOC (excludi ng water) : Grams/Liter: 229 Pounds/Gallon: 1.91 pH: 8.2-8.6 Gals. 31.45 2.39 1.09 0.17 0.13 0.38 1.50 48.43 0.53 0.30 0.50 0.71 0.29 0.11 0.11 12.00 SOURCE: Reichhold Chemicals, Inc.: Kelsol 3931: Formula 2581-81-A
  • 209.
    Stains 207 I nt e r i o r Wiping S t a i n I E n u l s i o n E-2977) Blend: Water Aurasperse W-1021 Y I O Aurasperse W-3041 R I O Aurasperse W-7012 LB Emu1s i on E-2977 Surfynol DF-37* Propylene Glycol Ammoni um Hydroxide (28%) Acrysol ASE-601:1 Water/premi x Water Surfynol 104DPM *Surfynol DF-58, 70 and 75 Formulation E (Rohm & Haas) Pounds 150.0 22.5 7.6 3.3 372.0 1.3 39.0 6.3 64.0 64.0 133.8 4.4 defoamers are v i a b l e a l t e r n a t i v e s . S t a i n 81end : Joncryl 95 Ektasolve DB Surfynol DF-37 Super Seatone Burnt Umber Nuosept 95 Mix a t 1000 rpm f o r 10-15 minutes. Premix t h e f o l l o w i n g and add w i t h a g i t a t i o n : Letdown : Water Propylene Glycol Natrosol 250 HBR Ammonia Surfynol 104DPM Formulation F (S.C.Johnson) Pounds 293.19 9.00 1.32 100.00 1.50 441 .32 30.24 3.00 1 .oo 8 . 8 0 Surfynol a d d i t i v e s have been shown t o provide t h e f o l l o w i n g benef it s : *Color u n i f o r m i t y o f s t a i n s *Early s t a i n lapping resistance *Consistent wetting, f l o w and l e v e l i n g on various woods *Foam c o n t r o l *Topcoat r e c o a t a b i l i t y and i n t e r c o a t adhesion *G1oss r e t e n t i on upon aging *Tannin bleed resistance *Water s e n s i t i v i t y *Chemical resistance With no detrimantal e f f e c t upon: SOURCE: A i r Products & Chemicals, I n c . : Surfynol Surfactants: Suggested Formulations
  • 210.
    208 Water-Based PaintFormulations M a t e r i a1 : Spensol L54 Water D i sperse-Ayd W22 Foamki 11 639AA Mapico 297 BK 5000 L i a h t Redwood Wipina S t a i n Pebble m i l l g r i n d 16-24 h r s . Then add i n f o l l o w i n g order w i t h a g i t a t i o n : Letdown : 3% Bentone LT Pregel* Spensol L54 Arolon 820-W-49 Lodyne S107 QR708B Ammoni um Hydroxi de *3% Bentone LT Pregel: Water (deionized p r e f e r r e d ) Bentone LT High speed d i sperser 15-20 m i nutes. Analysis: Ratio o f Spensol L54 t o Arolon 820: 50:50 Pigment Volume Concentration, Percent: 2.6 Pigment/Binder Ratio: 0.15/1 .0 Percent Solids, Weight: 26.5 Percent Solids, Volume: 24.3 Percent Vehicle Sol i d s . Weight : 20.8 Percent Vehicle Solids, Volume: 19.6 Pounds/Gallon: 8.44 VOC (excluding water): Grams/Li t e r : 72 Pounds/Gallon: 0.60 pH: 8.Ot-0.5 Lbs. Gals. 51.9 5.94 51.8 6.22 0.5 0.06 0 . 8 0.10 24.5 0.60 1.7 0.04 288.0 34.12 254.2 29.12 187.4 21.29 1.7 0.18 17.5 2.10 1.7 0.23 818.9 98.31 25.4 1.69 SOURCE: Reichhold Chemicals, I n c . : Spensol L: Formulation 2099-81 D
  • 211.
    Stains 209 S ta i n Concentrate Component A: Materia1 : Kels o l 3931-WG4-45 2-Butoxy Ethanol Water Ammoni um Hydroxide Patcote 531 Mapico 567 Mapico 1075 Atomi t e S y l o i d 234 Pebble o r sand m i l l t o 6+ Hegman g r i n d . Letdown : Kels o l 3931-WG4-45 Cobalt Hydrocure I 1 Manganese Hydrocure I1 Activ-8 2-Butoxy Ethanol Premix t h e next t h r e e m a t e r i a l s before adding: Polyphase AF-1 2-Butoxy Ethanol Aerosol OT-75 M i cheml ube 511 Water Lbs. 207.5 7.5 34.7 1.9 1.8 50.0 25.0 50.0 10.0 166.0 1.9 2.1 0.2 3.8 9 . 8 3.8 2.3 32.0 37.5 Gal s. 25.00 1.oo 4.17 0.25 0.25 1.16 0.74 2.22 0.60 20.00 0.25 0.25 0.03 0.50 1.oo 0.50 0.25 4.00 4.50 Add t h e f o l l o w i n g amount o f water j u s t p r i o r t o use and mix w e l l . Component 0: Water Analysis: Pigment Volume Concentration, Percent Pigment/Binder R a t i o Percent Sol ids, Weight Percent Solids, Volume V i s c o s i t y @ 25C. #4 Ford, Secs. Pounds/Gal 1on VOC (excl udi ng water) : Grams/Li t e r Pounds/Gal 1on : 277.6 33.33 Comp. A 18 2.8/1 .O 49.0 39.3 110 9.72 169 1.4 Comp. A+B 18 0.0/1 .O 34.45 26.2 19 9.26 169 1.4 NOTE: T h i s type o f formulation might be b e n e f i c i a l t o p a i n t manufacturers who s e l l d i r e c t l y t o b u i l d i n g o r p a i n t i n g c o n t r a c t o r s . These s t a i n concentrates can be mixed w i t h water a t t h e j o b s i t e . SOURCE: Reichhold Chemicals, Inc.: Kelsol 3931: Formula 2210-44
  • 212.
    210 Water-Based PaintFormulations Tannin S t a i n Blockina Formulation Pigment Grind: Water Bubond 357 Busperse 39 Bubreak 4400 Igepal CTA 639 Water Cel l o s i ze QP-15000 TiPure R-900 Nytal 300 Let Down: Ucar 376 Texanol Ethylene Glycol C e l l o s i ze QP-15000 Water T i n t t o desired c o l o r % by Weisht 9.2 1 . 0 0 . 6 0.3 0.3 2.3 0 . 2 18.3 9.9 39.2 2.0 2.7 0.2 13.8 A c r y l i c Tannin Stain-Blockinq Primer Materi a1 : Water Busperse 39 T r i t o n X-100 Bubreak 448 Premix f o l l o w i n g , then add t o above: Water C e l l o s i ze QP-15000 S i f t i n f o l l o w i n g pigments: T i -Pure R-900 Nytal 300 Busan 11-M1 High speed disperse t o Hegman 5.0. Reduce speed as shown below: Rhopl ex MV-23 Acryl ic Emu1s i o n Water Texanol Ethylene G1ycol % bv Weisaht 8.6 0.6 0.3 0.2 2.2 0.2 17.4 6.6 2.5 and l e t down 48.1 8.8 2.0 2.5 SOURCE: Buckman Laboratories, I n c . : Suggested Paint Formulations
  • 213.
    Stains 211 Water ReducibleRedwood S o l i d Color S t a i n I n c o r p o r a t i o n o f Agitan 701 i n t o a water r e d u c i b l e wood s t a i n g r i n d y i e l d s improved g r i n d v i s c o s i t y as w e l l as foam c o n t r o l i n t h e letdown. A d d i t i o n o f t h i s s i l i c o n e type FCA has no e f f e c t on r e c o a t a b i l i t y o f t h e topcoat. Grind: McWhorter 73-7358 Red I r o n Oxide Aerosil R972 (Degussa) FCA (Foam Control Agent) & %Wt 70 8.13 50 5.80 2.5 0.29 2.5 0.29 High speed 15 Minutes t o 6 Hegman Data on Imoroved V i s c o s i t v and Foam Control w i t h Aoitan: Test No Agitan Grind V i s c o s i t y , 25C, Poise 69 Grind Weight per Gallon (pounds) 10.06 Letdown : Add w h i l e mixing: McWhorter 73-7358 OK 412 (Degussa Corp.) B u t y l C e l l os01ve Premix and add: Manganese Hydro Cure I 1 (Mooney) Butyl Cellosolve Polyphase AF-1 (Troy Chemical ) Add f o l l o w i n g w h i l e mixing: Aqueous Ammonia 28% Deionized Water Aquabead 519 (Micro Powders) Properties: % N o n v o l a t i l e (by weight): 29.54 (by volume): 25.41 Pigment t o Binder Ratio: 0.44 Pigment Volume Concentration: 11.92 Weight per Gallon (pounds): 8.61 Theoretical VOC (pounds/gallon): 2.84 Water-Cosolvent Weight Ratio: 80.68:19.32 pH, 25C: 8.8 V i s c o s i t y , #2 Zahn Cup, 25C (seconds): 33 ( g r a m s / l i t e r ) : 341 - Agitan 701 58.5 11.11 & 90.0 10.45 25.0 2.90 8 0 . 0 9.29 9.5 1 . l o 24.0 2.79 8 . 0 0.93 11.5 1.33 468.4 54.38 20.2 2.32 SOURCE: King I n d u s t r i e s : WR-31: A d d i t i v e s f o r Waterborne Wood Formulations
  • 214.
    Miscellaneous 213 Anquamine 401Clear Coat Semi-Solid EDOXYDispersion Part A: Dow XUS19000.01 Epoxy Resin* Benzyl Alcohol Water & Gals 346.93 38.70 17.35 1.99 216.83 25.98 Part 8 : Anquami ne 401 Curing Agent (Ai r Products) 177.00 19.37 Water 35.40 4.24 Dowanol PM Solvent (Dow) 35.40 4.66 Benzyl Alcohol 44.25 5.07 * A l t e r n a t e l y use Epi-Rez 3515 a t same loading Typical Properties: W t s o l i d s (%): 57.45 VOC s o l i d s (%I: 52.43 VOC ( l b / g a l ) : 1.05 VOC ( g / l ) : 126 Anauamine 401 Clear Coat ProDerties: Pot L i f e , h r : >4 Gloss, 60 spec, 1 day: 100 Gloss, 60 spec, 8 wk: >90 Mix Ratio: 2 : l Mixed V i s c o s i t y , cP: 320 Tack Free Time, h r : 1.0 Hard Dry Time, h r : 6-8 Penci 1 Hardness, overnight VOC, l b / g a l : 1.1 Volume Solids, %: 56 SOURCE: A i r Products and Chem Agent: Formulation 5 F cals, I n c . : Anquamine 401 Curing
  • 215.
    214 Water-Based PaintFormulations Anquamine 401 Clear Coat S o l i d EDOXV Dispersion Part A: €pi-Rez 3520 Water Part 8: Anquami ne 401 Water Defoamer PnP Solvent Typical Propert ies : W t S o l i d s (%): 70.0 Volume S o l i d s (%): 41.35 VOC ( l b / g a l ) : 1.13 VOC ( g / l ) : 136 Pot L i f e , h r : >5 Gloss, 60 spec, 1 day: 100 Gloss, 60 spec, 8 wk: >SO Mix Ratio: 4:l Mixed V i s c o s i t y , CP: 390 Tack Free Time, h r : 0.5 Hard Dry Time: 6-8 Pencil Hardness, overnight: F VOC, l b / g a l : 1 . 1 Volume Solids, %: 42 Anquami ne 401 C1ear Coat Propert ies: Anquami ne 401 L i q u i d EDOXVClear Coat Part A: DER 331 Epoxy Resin (Dow) Benzyl Alcohol & 621.68 89.20 79.06 61.59 4.25 24.85 Lbs 411 .SO 65.04 Part B: Anquami ne 401 Curing Agent (Ai r Products) 270.98 Water 169.91 Letdown : Water 416.50 Typical Properties: W t S o l i d s (%): 47.5 VOC ( l b / g a l ) : 0.47 Volume S o l i d s (%I: 44.2 VOC ( g / l ) : 56 Resin Stoichiometry: 1.6:l Gloss, 60 specular: >90 Hard Dry: Overnight Pot l i f e , h r : 1 VOC l b / g a l : 0.47 Set t o Touch, h r : 3 L i q u i d Epoxy C1ear Coat Properti8s: 69.30 10.69 8.74 7.38 0.53 3.36 Gals 42.54 7.46 29.65 20.36 50.00 SOURCE: A i r Products and Chemicals, I n c . : Anquamine 401 Curing Agent: Formulations 8 & 7
  • 216.
    Miscellaneous 215 Aaueous Polyester-UrethaneP iqment D i s p e r s i on K-Flex XM-2311 and K-Flex XM-4310 a r e b o t h experimental a l i p h a t i c polyester-urethane aqueous d i s p e r s i o n s recommended f o r thermoset water-borne c o a t i n g s . K-Flex XM-2311 provides excel 1e n t p i gment w e t t i ng p r o p e r t i e s . K-F1 ex XM-4310 has a 1ower a c i d number, higher hydroxyl number and i s recommended as a modifying r e s i n f o r thermoset water-borne a c r y l i c s , p o l y e s t e r s , alkyds o r urethanes o r primary r e s i n f o r c r o s s l i n k i n g w i t h ami nopl a s t r e s i ns. Grind: (Cowles) Grind t o 8 N.S. Hegman Gauge: Component: % by Weight K-F1 ex XM-2311 10.00 Water 0.70 T i -Pure R-900 23.85 Letdown : K-F1 ex XM-4310 43.89 HMMM 7.45 S i l i c o n e A (25%)* 0.18 S i l i c o n e B (25%)** 0.18 Water 9.45 Nacure 2547 0.30 Dimethylethanolamine 1.43 Water 2.57 Characteri s t i cs: XM-2311/XM-4310/HMMM: 14/61/25 T o t a l Solids, %: 54.54 T h e o r e t i c a l VOC, g / l : 32.2 Pigment/Binder R a t i o : 0.8/1 .O pH Value ( A s i s ) : 8.45 V i s c o s i t y , cps***: 200 ***Brookfield, Spindle #16, 60 RPM Substrate: I r o n Phosphated Cold R o l l e d S t e e l Cure: 15 Minutes/l49C (300F) Dry F i l m Thickness: 20-25 microns (0.8-1.0 m i l s ) Pencil Hardness: 2H Knoop Hardness, 259: 4.4 MEK Double Rubs: 200+ Impact Resistance ( i n . l b s . ) : D i r e c t : 160+ 60 Gloss, %: 94.10 Cleveland Humidity Resistance (325 Hours): 60 Gloss,%: 90.54 Taber Abrasion Index (CS 17, 5009): 274 F i l m P r o p e r t i e s : Properties : Reverse: 160+ Formulation Notes: 1. Slowly add n e u t r a l i z i n g amine (10% i n H20) under good a g i t a - t i o n t o g r i n d and/or f i n a l f o r m u l a t i o n s f o r pH and v i s c o s i t y adjustment. 2. Cosolvent i s n o t recommended f o r v i s c o s i t y adjustment. 3. C a t a l y s t l e v e l recommendation range: 0.1-0.25% a c t i v e p-TSA 5 . Immediate letdown o f g r i n d i s recommended. SOURCE: King I n d u s t r i e s : Formulation WR-29 on t o t a l r e s i n s o l i d s . 4. Recommended pH i s 7.5-8.0. * S i l w e t L-7604 **Si l w e t L-7605
  • 217.
    216 Water-Based PaintFormulations Black Gloss Enanel Materi a1 : Spensol L52 Aerosol OT-75 Surfynol 104H Ammoni um Hydroxide Regal 330 Carbon Black Lbs. Gals. 175.4 20.00 2.3 0.25 2.0 0.25 1.9 0.25 15.0 1.oo Add t h e above materials i n t h e order l i s t e d under good a g i t a t i o n , then pebble m i l l g r i n d t o 7 N.S. Letdown : Spensol L52 Add t h e f o l use and mix XAMA- 7 Anal y s i s: owing cross w e l l . i n k i n g agent opt iona 679.7 77.50 ) j u s t p r i o r t o 7.4 P;gment Volume Concentration, Percent: 3.5 Pigment/Binder Ratio: 0.6/1 . O Percent Solids, Weight: 31.9 Percent Solids, Volume: 28.4 V i s c o s i t y @ 25C, #4 Ford, Secs.: 25-30 Pounds/Gal 1on : 8.82 VOC (excluding water): Grams/Liter: 275 Pounds/Gallon: 2.3 pH: 8.5t-0.3 Formulation 2154-1 0 Clear B a r r i e r / T i e Coat f o r V i n y l Material : Arolon 840-W-39 Water Carbi t o 1 Ammoni um Hydroxide Spensol L54 Aerosol OT-75 Add t h e above m a t e r i a l s i n Lbs. 599.2 33.3 35.0 1.9 194.8 2.9 order under good a g i t a t i o n . 0.75 Gal s. 68.87 4.00 4.25 0.25 22.31 0.32 Analysis: Percent Solids, Weight: 33.9 Percent Solids, Volume: 31.2 V i s c o s i t y I3 25C, #2 Zahn. Secs.: 20-25 VOC (excluding water): Grams/Liter: 209 Pounds/Gallon: 8.7 PH: 8.5-9.0 Pounds/Gallon: 1.7 Formulation 2262-831) SOURCE: Reichhold Chemicals, I n c . : Sponsol L: Formulations
  • 218.
    Miscellaneous 217 Clear Ti n t Base M a t e r i a l : Kels o l 3931-WG4-45 Strodex P-1 00 I n t e r c ide T-0 Lbs. Gals. 370.0 44.52 1.6 0.19 4.2 0.43 Premix t h e next t h r e e m a t e r i a l s i n order, then add under good a g i t a t i o n : Act iv-8 Cobalt Hydrocure I1 Manganese Hydrocure Add t h e f o l l o w i n g i n order: Polymekon SPP-W Polyphase AFl Water Ammoni um Hydroxi de Analysis: Percent Solids, Weight: 23.3 2.1 0.36 1.3 0.17 5 . 0 0.66 33.3 4.16 8.4 0 . 8 1 405.9 48.73 0 . 5 0.07 Percent S o l i d s ] Volume: 21.6 (approx) V i s c o s i t y @ 25C, #2 Zahn, Secs.: 20-25 VOC (excluding water): Grams/Li t e r : 185 Pounds/Gal 1on : 1 .54 pH: 8.2-8.6 SOURCE: Reichhold Chemicals, I n c . : Kelsol 3931: Formula 2099-32
  • 219.
    218 Water-Based PaintFormulations FCA’s f o r Waterborne B u i l d i n g Product Formulations Clear Waterborne Cement Sealer Mater ia1 : Rhoplex AC-3001 (Rohm and Haas) FCA (Foam Control Agent) B u t y l Cellosolve Surfynol 104E ( A i r Products) Properties : % N o n v o l a t i l e (by weight): 45.78 V i s c o s i t y , CPS: 150+-10% pH: 7.7-8.7 Waterborne Black Topcoat Grind: Water Natrosol 250MR (Hercules) Ammoni a (28%) Tamol 731-25 (Rohm and Haas) FCA (Foam Control Agent) Bayferrox 318M ( M i l e s ) WG-325 Mica (KMG Minerals) Grind a t h i g h speed f o r 15 minutes Letdown : Rhoplex AC-3001 (Rohm and Haas) Butyl Cellosolve Surfynol 104H ( A i r Products) Water Properties: % N o n v o l a t i l e (by weight): 50.0 (by volume): 37.9 pH, 25C: approx. 9.0 V i s c o s i t y , #4 Ford cup, 25C, seconds: 18 Coalescent, % on polymer s o l i d s : 15 T h e r e t i c a l VOC ( g r a m s / l i t e r ) : 119.8 (pounds/gallon): 1.0 & 761.68 0.88 36.40 1.04 & 121.8 1.1 0.5 12.1 3.8 174.5 48.3 605.1 43.6 3.2 13.7 95.21 0.11 4.55 0.13 11.85 0.11 0.05 1.18 0.37 16.98 4.70 58.88 4.24 0.31 1.33 Results demonstrate the v e r s a t i l i t y o f Agitan 260 as a p e r s i s t e n t foam c o n t r o l agent and i t s a b i l i t y t o improve c o l o r (represented by t h e L Value and yellow index) and prevent pigment f l o a t . SOURCE: King I n d u s t r i e s : Formulation WR-33
  • 220.
    Miscellaneous 219 E xt e r i o r / I n t e r i s r B l o c k F i l l e r I n q r e d i e n t s : Pigment G r i nd: Water Potassi um Tripolyphosphate (KTPP) Drewplus L-475 Tamol 731 Propylene G1y c o l T r i t o n Nonionic S u r f a c t a n t N-101 Kathon LX T i -Pure R-900 ASP 400 325 Mesh White Waterground Mica Minex 4 Snowf 1ake Ammonium Hydroxide, 28% Aqueous S o l u t i o n Water NeoCar Latex 2300 Ucar F i l m e r IBT Water 1 C e l l o s i z e Hydroxyethyl C e l l u l o s e )Premix ER-15,000 1 Pounds 240.0 2.0 3.0 10.0 20.0 3.0 1.5 40.0 150.0 50.0 100.0 400.0 2.0 25.0 230.0 15.0 22.0 4 . 0 Gal 1ons 28.80 0.09 0.39 1.09 2.31 0.34 0.18 1.20 6.97 2.12 4.61 17.76 0.26 3.00 25.99 1.89 2.63 0.35 P a i n t P r o p e r t i e s : PVC. %: 70.6 Volume S o l i d s , %: 47.2 Weight S o l i d s , %: 67.0 Weight per Gal on, l b : 13.17 Stormer, KU: 115 I C I , p o i s e : 1.55 pH Value: 9.2 Freeze-Thaw S t a b i l i t y , 3 c y c l e s : F a i l Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass Reflectance, %: 83.5 Gloss, 60: 2.3 Mudcracking, 50 m i l : Pass Sag Resistance, m i l s : 16 F i l l e d Appearance on Block: Exc F i l m P r o p e r t i e s : SOURCE: Ucar Emulsion Systems: NeoCar Polymers: Formulation Suggestion K-2216
  • 221.
    220 Water-Based PaintFormulations High S o l i d s Self Priming A l k y d I n a r e d i e n t s : Pigment Grind: C a r g i l l 57-5766/High S o l i d s Alkyd Ye1k i ns-TS/Soya L e c i t h i n Bentone 38 Methyl Alcohol Ti-Pure R-SOO/Titanium Dioxide- B u t r o l 23/Modi f i e d Bari um Meta- Atomite/Calcium Carbonate Nytal 300/Talc-Magnesium S i l i c a t e Mineral S p i r i t s (Rule 66) Let Down: C a r g i l l 57-5766/High S o l i d s Resin Z i rconium 6% Cobalt Naphthenate-6%/Drier A n t i s k i n n i ng Agent Mineral S p i r i t s (Rule 66) Paint P r o p e r t ies: Total Vehicle 49.94 Pigment 50.06 Vol a t i 1e 15.95 Organic Solvent 15.95 Non-Volati l e 84.05 Non-Volatile Vehicle 33.98 Density (lb/U.S. g a l ) : 11.99 S p e c i f i c G r a v i t y : 1.44 P . V . C . : 31 .55% P/B Ratio: 1.473 Spread @ 1 M i 1 : 1133 F2 Coating VOC: 229 G/L M a t e r i a l VOC: 229 G/L R u t i l e borate j& Gal 224.26 27.35 2.99 0.35 1.99 0.14 1.50 0.23 199.35 5.99 99.68 3.24 149.51 6.62 149.51 6.31 37 * 88 5.89 224.26 27.35 6.98 0.98 1.99 0.27 1.99 0.26 96.68 15.04 77.71 22.29 29.35 29.35 70.65 48.36 18.71 0.25 0.17 0.12 16.63 8.32 12.47 12.47 3.16 18.71 0.58 0.17 0.17 8.07 SOURCE: Buckman Laboratories: Formulation Suggestion: KQ-20
  • 222.
    Miscellaneous 221 Masonry Bl o c k M a t e r i a1 : P a r t A: 2-Propoxyet hanol T r i t o n X-100 S u r f a c t a n t Tamol 731 (25% N . V . ) S u r f a c t a n t C o l l o i d 640 Defoamer R u t i l e T i t a n i u m D i o x i d e Atomi t e C a l c i um Carbonate Water Pounds 11.6 3 . 5 3.5 4 . 0 50.0 100.0 50.0 Gal l o n s 1.50 0.39 0.38 0.50 1.46 4 . 4 4 6.00 Mix a t h i g h speed 10 minutes; t h e n add and mix 3 m i n u t e s : S h o r t S t u f f P o l y e t h y l e n e F i b e r s 7 . 0 0 . 9 3 Add under reduced speed: Water E p i -Rez 3520-WY-55 Resin P a r t B: €pi-Cure 8536-MY-60 C u r i n g Agent ASP 170 Aluminum S i l i c a t e 325 Mesh Water Ground Mica Water 48.6 5.83 260.0 28.57 124.5 15.00 50.0 2 . 3 8 100.0 4.24 166.0 20.00 Mix a t h i g h speed 10 minutes; t h e n add and mix 3 m i n u t e s : S h o r t S t u f f P o l y e t h y l e n e F i b e r s Water T y p i c a l C o a t i n g P r o p e r t i e s : T o t a l Volume S o l i d s , %: 41.7 T o t a l Weight S o l i d s , %: 57.7 PVC, 94: 45.6 V o l a t i l e O r g a n i c Compounds (VOC): Pounds/Gallon: 1.60 Grams/Li t e r : 192 A p p l i c a t i o n : Brush and R o l l e r Resin Composition ( s o l i d s ) : Epoxy Resin, %: 65.7 C u r i n g Agent, %: 34.3 T o t a l , %: 100.0 Composite Blend: V i s c o s i t y P a r t A 97 KU P a r t 0 >141 KU P a r t s A and B 131 KU 1 . o 0.13 22.4 2.69 Pounds Gal 1ons 538.2 50.00 588.9 50.00 SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1615: Masonry B l o c k F i l l : Epi-Rez 3520-WY-55 Resin/Epi-Cure 8536-MY-60 C u r i n g Agent
  • 223.
    222 Water-Based PaintFormulations Masonry B l o c k f i 11 M a t e r i a1 : P a r t A: 2-Propoxyethanol T r i t o n X-100 S u r f a c t a n t Tamol 731 S u r f a c t a n t C o l l o i d 640 Defoamer Tap Water Mix and add: R u t i l e Titanium Dioxide Atomite Calcium Carbonate ASP 170 Alumi num S i 1i c a t e H i speed disperse 10 minutes; then add: Short S t u f f Polyethylene F i b e r s Tap Water Add a t reduced speed: Epi -Rez 3520-W-55 Resin P a r t 8 : Epi -Cure 8537-W-60 Curing Agent Tap Water Mix we1 1 and add: ASP 170 Aluminum S i 1i c a t e 325 Mesh Water Ground Mica Atomite Calcium Carbonate H i speed disperse 10 minutes; then add: Short S t u f f Polyethylene F i b e r s Tap Water Composi t e 81end : P a r t A Part B T y p i c a l Coat V i s c o s i t y P . V . C . . % Pounds 11.6 3.5 3.5 4.0 71 .O 50.0 75.0 35.0 7.0 11.4 260.0 129.0 166.0 50.0 100.0 125.0 1.o 28.7 532.0 599.7 ng P r o p e r t ies : P a r t A: 128 Krebs U n i t s P a r t B: 108 Krebs U n i t s P a r t s A and B: Fresh: 108 Krebs U n i t s 42.2 T o t a l Weight S o l i d s , %: 67.4 T o t a l Volume S o l i d s , %: 46.2 Resin Composition: Epoxy Resin, %: 65 V o l a t i l e s Composition: Water. l b s . : 393.6 V o l a t i l e Organic Compounds (VOC): Curing Agent, %: 35 Organic, l b s . : 63.6 Pounds/Gal 1on : 1.21 Grams/Liter: 145 A p p l i c a t i o n : Brush and R o l l e r Gal 1ons 1.50 0.39 0.38 0.50 8.50 1.46 3.30 1.67 0.93 1.37 30.00 14.25 20.00 2.38 4.24 5.56 0.13 3.44 50.00 50.00 SOURCE: S h e l l Chemical Co.: S t a r t i n g Formulation No. 1616: €pi-Rez 3520-WY-55 Resin/Epi-Cure 8537-WY-60 Curing Agent
  • 224.
    Miscellaneous 223 Water ReducibleA1kyd I n g r e d i e n t s : -Lb Pigment G r i n d : Water 132.72 Busperse 39/Dispersant 5.90 Bubreak 448/Defoamer 2.95 Z i n c S u l f a t e - H e p t a h y d r a t e 1.97 I g e p a l CTA 6 3 9 / S u r f a c t a n t 1.97 B u t r o l 2 3 / M o d i f i e d Barium Metaborate 49.16 Red I r o n Oxide 98.31 N y t a l 300/Talc-Magnesi um S i 1ic a t @ 196.63 L e t Down: C a r g i l l 74-7450/Water Reducible A1 kyd 252.67 n-Butyl A l c o h o l 84.55 Ammoni urn Hydroxi de-28% 9.83 Water 216.29 C o b a l t Napthenate-6%/Drier 1.97 Z i r c o n i u m 6% 3.93 P a i n t P r o p e r t i e s : %Wt T o t a l V e h i c l e 67.32 87.47 P i grnent 32.68 12.53 Vol a t i1e 50.16 68.37 Organic S o l v e n t 17.20 26.47 N o n - V o l a t i l e 49.84 31.63 N o n - V o l a t i l e V e h i c l e 17.16 19.11 D e n s i t y (lb./U.S. g a l ) : 10.59 S p e c i f i c G r a v i t y : 1.27 P.V.C.: 39.60% P/B R a t i o : 1.905 Spread F 1 M i l : 507 F2 C o a t i n g VOC: 376 G/L M a t e r i a l VOC: 218 G/L Gal 5 15.93 12.53 0.55 0.56 0.44 0.28 0.12 0.19 0.22 0.19 1.60 4.64 2.51 9.29 8.30 18.57 29.71 23.86 12.53 7.99 1.31 0.93 25.97 20.43 0.27 0.19 0.55 0.37 SOURCE: Buckman L a b o r a t o r i e s : F o r m u l a t i o n Suggestion: KQ-22
  • 225.
    224 Water-Based PaintFormulations 2-Component Waterborne System Formulation WR-41 demonstrates the improved performance o f a 2-component waterborne system when modified w i t h K-Flex XM-4316, a polyester-urethane dispersion. A t both NCO/OH r a t i o s , improve- ments were made i n gloss, MEK resistance, and f l e x i b i l i t y . NCO/OH Ratio: 1.6 Acryl ic/PU-Di spersi on: 80/20 Component A : Emulsion E-3275 K-Flex XM-4316 Sodium N i t r i t e (5% aq) Proglyde DMM Edaplan LA 402 S i l w e t 7001 (5% aq) S i l w e t 7605 (25% aq) S i l w e t 7604 (25% aq) Dimethyl ethanol ami ne Component B: Bayhydur XP-7063 Formulation C h a r a c t e r i s t i c s : Nonvolatile, t h e o r e t i c a l , %: 48.7 Theoretical VOC, g/L, ( l b . / g a l l o n ) : 48, (0.4) Wt% 69.31 16.89 0.00 1 .23 0.07 0.00 0.00 0.00 0.00 12.50 Formulation Properties, A i r-Dry 20-25C, 2 weeks: Substrate: Bonderite 1000 c o l d r o l l e d s t e e l F i l m thickness, micron ( m i l . ) : 32+-2 (1.3+-0.1) Dry Time (minutes): Set t o touch: 4.5 Surface d r y : 12 Through dry: 18 20, %: 74 MEK Double Rubs: 120 Gloss 60, %: 96 Knoop Hardness: 5 . 5 Koenig Hardness (sec): 108 Impact, D i r e c t , i n c h . l b . : >160 Pencil Hardness: 2H-3H Impact, Reverse, i n c h . l b . : >160 Formulation Properties, Bake 80C 20 min. Post-cure 20-25C, 2 weeks: Substrate: Bonderite 1000 c o l d r o l l e d s t e e l F i l m thickness, micron ( m i l . ) : 32+-2 (1.3+-0.1) NCO/OH R a t i o : 1.6 Gloss 60, %: 100 Knoop Hardness: 7 Koenig Hardness (sec): 134 Impact, Forward, i n c h x lb.:>160 Pencil Hardness: 3H Impact, Reverse, i n c h x lb.:>160 20, %: 80 MEK Double Rubs: 135 Formulation Preparation: a g i t a t i o n f o r approx. 5 minutes. SOURCE: King I n d u s t r i e s : Preliminary Formulation WR-41 Add component B t o component A under low shear mechanical
  • 226.
    226 Water-Eased PaintFormulations RAW MATERIAL CHEMICAL DESCRIPTION SOURCE AC 1024 Acryl ic r e s i n Rohm& Acronal DS 6183 Copolymer a c r y l i c ester dispersion BASF Acrysol ASE-60/G-110/ Water-soluble a c r y l i c r e s i n s Rohm& RM-S25/RM-l02O/RM-2020/ TT-935/WS-68 SCT-200/SCT-275/ Act iv-8 D r i et-, accelerator, s t a b i 1izer RTVan Aero Me1ami ne Powdered grade Aerosi 1 R-972 Fumed s i l i c a Aerosol OT-75/OTS Surface a c t i v e agent A1umi num L243 A1umi num Paste #82255 AMP-95 Dispersant Ancamide 500/2353/ 2410 Anquami ne 401 Aquabead 519 Aquacat Aquamac 640/700 Aquamac 1085/1090 Aqua-sperse 877-9907 Arcosolv DPM Arcosolv DPNP Arcosolv D P t B Arcosolv PNB Arcosolv PNP AmCyan Degussa AmCyan S i 1ber A1coa 2-amino-2-methyl-1-propanol Angus Curing agents f o r epoxy r e s i n s Paci f ic L i q u i d polyamide c u r i n g agent Paci f ic Micro D r i e r c a t a l y s t U l t r a A c r y l i c l a t e x e a l k y dWater-sol ub .ampblack Co D i propylene Sol vent Coalescent Solvent Solvent McWhort McWhort o r Dispersant Hul s g l y c o l monomethyl ether Arc0 Arco Arc0 Arc0 Arc0
  • 227.
    TradeNamed Raw Materials227 RAW MATERIAL Arcosolv PP Arcosolv PTB Arolon 500-W-42 A r o l on 020-W-49 Arolon 840-W-39 Aromatic 100 Aromatic 150 Atomi t e Aroplaz 1271 Aroplaz 1272 Aroplaz 3859-2-80 ASA 35.3 ASP-NCP/ASP-l70/ ASP-400 Atomi t e A t t a g e l 50 CHEMICAL DESCRIPTION Solvent Sol vent O x i d i z i n g alkyd. % s o l i d s : 42 A c r y l i c polymer. % s o l i d s : 49 A c r y l i c polymer. % s o l i d s : 39 Hydrocarbon s o l v e n t Hydrocarbon s o l v e n t Cal c i um carbonate Long-oil l i n s e e d a l k y d r e s i n 100% s o l i d s v e r s i o n o f Aroplaz 1271 Alkyd r e s i n Wax emulsion A1uminum s i 1i c a extender pigments SOURCE Arc0 Arc0 Rei chh Reichh Rei chh Exxon Exxon ECC Rei ch Reich Reich CCA Engel Calcium carbonate, n a t u r a l ECC C o l l o i d a l a t t a p u l g i t e t h i c k e n e r Engel Aurasperse W-1021 Y I O Yellow i r o n o x i d e Harshaw Aurasperse W-3041 R I O Red i r o n oxide Harshaw Aurasperse W-4123 Harshaw Aurasperse W-7012 LB Carbon b l a c k Harshaw AZO-33 Zinc oxide Asarco AZO-55 Z i nc o x i de. American process Asarco
  • 228.
    228 Water-Based PaintFormulatiom RAW MATERIAL CHEMICAL DESCRIPTION B a r y t e s No. 1 Barium s u l f a t e extender pigment Basic Lead S i l i c o Chromate Bayhydur XP-7063 W a t e r - d i s p e r s i b l e i s o c y a n a t e B a y f e r r o x 318M S y n t h e t i c i r o n o x i d e pigment Beaverwhi t e 325 T a l c extender pigment Beckosol 13-402 Water r e d u c i b l e a1kyd B e e t l e 65/80/216-8 Urea-formaldehyde compound Bentone AD/EW/LT/ R h e o l o g i c a l a d d i t i v e SD-1/38 Benzof 1ex 9-88 P l a s t i c i z e r BK5000 Pigment BK5099 Pigment B l a s t i t e #220 Aluminum o x i d e Brown I r o n Oxide 444 Pigment Bubble Breaker 776-P/ Defoamers 3295 Bubond 357 C a t i o n i c polymer Bubreak 448/4400 Defoamer Burgess No. 98/No. 128 Hydrous c l a y Busan 11-M1 Barium metaborate m i c r o b i o c i d e Busperse-39/203 D i s p e r s i n g agent B u t r o l 23/35 C o r r o s i o n and s c a l e i n h i b i t o r B u t y l Carbi t o 1 D i e t h y l e n e g l y c o l monobutyl e t h e r B u t y l C a r b i t o l A c e t a t e D i e t h y l e n e g l y c o l monobutyl e t h e r a c e t a t e SOURCE WC&D Rheox Bayer M i l e s Cyprus Rei c h AmCyan Rheox Vel s i c P f iz e r Harcros SOHIO Col umb W i t c o Buckman Buckman Burgess Buckman Buckman Buckman Union Union
  • 229.
    Trade Named RawMaterials 229 RAW MATERIAL CHEMICAL DESCRIPTION SOURCE B u t y l Cel l o s o l v e Ethylene g l y c o l monobutyl ether UnCarb Butyl O x i t o l Glycol ether She11 Byk 020/023/025 Defoamers Bykchem acetate 0yk 155/156/301/306/ A d d i t i v e s 320/321/346 BykChem Bykumen WS Wetti ng/di spersi ng agent BykChem Cab-0-Si 1 L-SO/LM-130 Fumed s i 1icas TS-61 O/TS-720 Calcium Hydrocem D r i e r c a t a l y s t f o r water systems Calcium Hydro-Cure Catalyst f o r water systems Camel Cal Extra f i n e ground limestone s l u r r y Camel Carb Calcium carbonate extender Camel F i l CAO- 1 Carbi t o 1 Calci um carbonate Antioxidant Diethylene g l y c o l monoethyl ether and e t h y l ene g l y c o l mixture Carbopol 941 Thickening agent Cargi 11 57-5766 WR High s o l i d s a l k y d Cargi 11 72-7203 WR O i l f r e e polyester Cargi 11 74-7450 WR Short soya a l k y d Cargi 11 74-7474 WR chain-stopped a l k y d C a r g i l l 7412 Non-oxi d i z i ng a1kyd Cabot Mooney Mooney Genst ar Genstar Genst ar PMCSpec UnCarb BFGood Cargi 11 Cargi 11 Cargi 11 Cargi 11 Cargi 11
  • 230.
    230 Water-Based PaintFormulations RAW MATERIAL CHEMICAL DESCRIPTION Cargill 7464 Water reducible a1 kyd Cel i te 281 /499 Di atomaceous si 1 i cas Cellosize ER-52M Hydroxyethyl cellulose thickeners ER-15,000/ER-30,000/ QP-44OO/QP-44OOH/QP-l5,OOO/ QP-15,OOOH Chemcor AS-35-3 Wax emulsion Chempol 10-0091 WR short oxidizing oil alkyd Chlorez 700 Chlorinated paraffin resin Chromi um Green Oxide 5-5310 Pigment CL 27NA Cobalt Chem-All 12% Cobalt Hydrocure 12%/ Catalysts for water systems I1 Cobalt Naphthenate-6% Drier Colloid 107/111/111M/ Dispersants 226/35 Colloid 640/643/650/ Defoamer/Antifoams 653/675/677/679/ 694/770 Composi ti on R/T Surfactants Cosan 101/158/234 Preservat i ves Cycat 4040 Acid catalyst Cyclo Sol 63 Aromatic solvent Cyme1 303/324/325/ Melamine-formaldehyde resins 327/350/385 SOURCE Cargi 11 Manvi 1 1 UNCarb CCA Freeman Dover Mi nPi g Dow Mooney Mooney Interst Rhone- Rhone- Cal gon Cosan AmCyan She1 1 AmCyan
  • 231.
    Trade Named RawMaterials 231 RAW MATERIAL Dalpad A Daxad 30-30 DC F l u i d 593 DC-14 DeeFo HG-12/PI-4/ 806-1 15 Dehydran 1293 DER 331/660X80 D i cyandi ami de D i sperbyk Disperse-Ayd/W22/W28 DMEA Dowanol DPM/DPnB/ EPh/ PM/ PnB/Pn P/PPH Dow Corning 14/57 Dowicil 75 Dow XUS19000.01 Drewpl us L-475/ L-493/Y-281 D r i k a l it e Durami t e CHEMICAL DESCIPTION Coal esci ng agent Dispersant Phenyl trimethicone S i 1icone Antifoam/defoamers Defoamer Epoxy r e s i n s Dispersant Dispersants N e u t r a l i z i n g amine Glycol ether products S i 1icone a d d i t i v e s A n t i m i c r o b i a l agent Epoxy r e s i n Foam c o n t r o l agents Calcium carbonate extender pigment Calcium carbonate extender pigment E-845 Thickener Eagle Zinc 417W Zinc oxide Edaplan LA 402 Flow and l e v e l i n g agent SOURCE Dow Grace DowCorn DowCorn U l t r a Henkel Dow AmCyan BykChem Daniel UnCarb DowChem DowCorn DowChem DowChem Drew ECC ECC Rohm& Eagle King
  • 232.
    232 Water-Based PaintFormulations RAW MATERIAL E k t a p r o EEP E k t a s o l v e DB E k t a s o l v e DB A c e t a t e E k t a s o l v e DE E k t a s o l v e EB E k t a s o l v e EP Emul s i o n E-2977 Emulsion E-3122 Emul s i on E-3275 € p i -Cure 8290-Y-60 Epi -Cure 8292-Y-60 Epi -Cure 8536-MY-60 Epi -Cure 8537-WY-60 Epi -Rez 3515-W-60 Epi-Rez 3520-WY-55 Epi -Rez 3522-W-60 E p i -Rez 3540-WY-55 Epi -Rez 3551-WY-43 Epi-Rez 5522-WY-55 E p o d i l L E p o d i l 759 E p o t u f 37-058 E p o t u f 37-143 E p o t u f 37-618 CHEMICAL DESCRIPTION E t h e r e s t e r Sol vent S o l v e n t Sol v e n t Sol vent 2-propoxyethanol s o l v e n t A c r y l i c emulsion A c r y l ic d i s p e r s i on Epoxy c u r i n g agent Epoxy c u r i n g agent Epoxy c u r i n g agent Epoxy c u r i n g agent Epoxy r e s i n SOURCE Eastman Eastman Eastman Eastman Eastman Eastman Rohm& Rohm& Rohm& Shel 1 Shel 1 Shel 1 Shel 1 Shel 1 Epoxy r e s i n Shel Epoxy r e s i n Shel Epoxy r e s i n Shel Epoxy r e s i n Shel Epoxy r e s i n Shel Hydrocarbon d i l u e n t f o r epoxy r e s i n s R e a c t i v e d i 1uent Epoxy r e s i n Epoxy r e s i n Epoxy r e s i n hardener Rei ch Rei ch Rei ch
  • 233.
    Trade Named RawMaterials 233 RAW MATERIAL EpotUf 37-680 E p o t u f 38-501 Exxate 700 CHEMICAL DESCRIPTION Epoxy r e s i n Epoxy r e s i n Oxo-acetate c o s o l v e n t FC-430 F1u o r o s u r f a c t a n t F1a t t i ng Agent TS-100 F l u o r a d FC-129 F1uorochemi c a l Foamaster R/VF/VL/ Antifoam/defoamers 333 Foamex 825 A n t i foam Foamki 11 639AA Foam c o n t r o l agent F u n g i t r o l 234 Fungi c i de Gold Bond R M i c r o c r y s t a l l i n e s i l i c a H a l o f l e x 202 Polymer emu1s i on Halox 8W-100 C a l c i um b a r i u m phospho-si 1ic a t e Halox BW-191/CW-191/ W h i t e non-lead pigments CW-49l/SW-lll/SW-1116/ szP-39 1 Halox X t a i n A HEC QP-4400 H y d r o x y e t h y l c e l l u l o s e Heucophos ZMP/ZPZ Z i n c y e l l o w s Hexyl C a r b i t o 1 S o l v e n t SOURCE Rei c h Rei ch Exxon 3M Degussa 3M Henkel TegoChe C r u c i b Cosan Tamms ICIRes Halox Hal ox Hal ox UnCarb Heubach UnCarb
  • 234.
    234 Water-Based PaintFormulations RAW MATERIAL Hodag PX-218 H y d r i t e F l a t D Iceberg Igepal GO-630/ CTA-639 I m s i l A25 I n t e r c i d e T-0 I n t e r w e t #33 5-1365 5-31 03 Joncryl SCX-1520/ 56/95/540/554 Jonwax 26 Kadox-515/911/915 Kathon LX K-Cure 129W Kelecin 1081 Kels o l 3931-WG4-45 K-F1 ex UD-320W/ XM-2304 K-F1 ex XM-2311 K-Flex XM-4310 CHEMICAL DESCRIPTION Antifoam Kaolin extender pigment Anhydrous aluminum s i l i c a t e Surfactants M i c r o c r y s t a l l i n e s i l i c a M i c r o b i o s t a t Wetting agent Strontium chromate A c r y l i c polymers Wax emulsion Zinc oxide Fungicide Catalyst Soybean o i l O i l copolymer. % s o l i d s : 45 Poly01s Pigment d i s p e r s i n g r e s i n Polyester-urethane dispersion SOURCE Hodag Georgia Burgess Rhone- Unimin Akzo Davis M i nPi g Johnson Johnson N J Z i nc Rohm& King Rei ch Reich King King King
  • 235.
    Tra& Named RawMaterials 235 RAW MATERIAL K-Flex XM-4316 K-Flex 188 Kodaflex DBP KP-140 Kroma Red R0-7097 Kronos 2020 Kronos 2160 Kronos 2310 K-Sperse 152MS L-203-D Lampblack #E77 Lansford L243 Lodyne S107/S107B LVT 400 Magnacat Mai ncote HG-54 Mai ncote PR-71 Manganese Hydrocure CHEMICAL DESCRIPTION Polyester-urethane dispersion Pol yo1 P l a s t i c i z e r P1a s t i c i zer I r o n oxide pigment Rut i1e t i t a n i um d i o x i de T i t a n i um d i o x i d e Titanium d i o x i d e Dispersant Strontium chromate Talc D r i e r - c a t a l y s t Acryl ic 1atex A c r y l i c l a t e x Catalyst Manganese Hydrocure I 1 Catalyst Mapico Red 297 I r o n oxide Mapico Red 347A I r o n oxide Mapico 567 I r o n oxide Mapico 1075 I r o n oxide SOURCE King King Eastman Eastman P f izer Kronos Kronos Kronos King Cookson Hul s S i 1ber C i ba- B a r r e t t U l t r a Rohm& Rohm& OMGroup OMGroup Col umb Col umb Col umb Col umb
  • 236.
    236 Water-Based PaintFormulations RAW MATERIAL McWhorter 73-7358 McWhorter 248-5409 Merbac 35 Methocel J-12-MS/856 Methyl Carbi t o 1 Methylon 75108 Mica M i chem 392-25 M i chem Lube 110/182/ 511/737/743/02925 M i c r o t a l c MP12-50 Microwhit e 25 Minex 4/10 Min-U-Si1 40 Moly-White 212 Monarch 1300 Mor-Lok 1035/1043 MPA- 1078 Nacor r Nacorr 1552/1754 CHEMICAL DESCRIPTION SOURCE Modi f ied p o lyo1e f in A c r y l i c emulsion McWhort McWhort B a c t e r i c i d e Cal gon Hydroxypropyl m e t h y l c e l l u l o s e s Dow Diethylene g l y c o l monomethyl e t h e r UnCarb Occi den 325 mesh, water ground Engl i s h KMG/ Uni m i n Wax emulsion Michel M i chelWax a d d i t i v e s P fizer GeoMarb Low micron t a l c Sodium potassium aluminum s i l i c a t e s Unimin S i l i c a p a i n t f i l l e r Corrosion i n h i b i t i v e pigment F l u f f y carbon b l a c k A n t i - s e t t l i n g agent Corrosion i n h i b i t o r Corrosion i n h i b i t o r s Nacure X49-11O/XP-l81/Catalysts f o r polymeric c o a t i n g s XP-188/155/25OO-X/ 2547 Unim i n Sherwi n Cabot Morton Rheox King King K i ng
  • 237.
    Trade Named RawMaterials 237 RAW MATERIAL Nalco 2300 Nal z i n SC-l/2 N a t r o s o l P l us/P1 us 330/P1 us 330PA N a t r o s o l 250 HBR/ 1on 250HR/250MHR/250MR/ 250MXR NeoCar L a t e x 2300 NeoCar L a t e x 6035 NeoCar L a t e x 6040 Neocryl XA-6085 N i c r o n 400 T a l c Nopco NDW/NXZ Nopcoci de N-96 No. 1 White Novoperm Red F3RK-70 NuoCide 404-D/960 Nuocure C o b a l t 10% Nuocure Manganese 6% Nuosept 95/951/145/ 6 3 5 1 Nuosperse 657 Nyad 1250 N y t a l 300/400 CHEMICAL DESCRIPTION SOURCE A n t i foam Nal c o C o r r o s i o n i n h i b i t i v e pigments Rheox H y d r o x y e t h y l c e l l u l oses-modi f ied Aqua1 on H y d r o x y e t h y l c e l l u l o s e s Aqua- NeoCar polymer. 55% s o l i d s E x t e r i o r polymer. 53.5% s o l i d s For in t e r i o r semigloss appl ic a t i ons A c r y l ic copolymer Defoamers M i 1dewci des Calcium c a r b o n a t e M i 1dewci de P o l y u r e t h a n e c a t a l y s t P o l y u r e t h a n e c a t a l y s t P r e s e r v a t i v e s D i s p e r s i n g agent W o l l a s t o n i t e T a l c s UnCarb UnCarb UnCarb IC I Res- Luzenec Henk e l Henkel ECC Hoechs t H u l s Hul s Hul s Hul s Hul s Nyco Vander
  • 238.
    238 Water-Based PaintFormulations RAW MATERIAL CHEMICAL DESCRIPTION OK 412 F l a t t i n g agent Omyacarb UF Natural calcium carbonate Oncor M50 A n t i - c o r r o s i v e pigment Optiwhi t e Anhydrous aluminum s i l i c a t e Organofunctional S i lane A-187 Patcote 513/519/531/ Defoamers 047 Phos-Chek P/30 Flame r e t a r d a n t Phosguard 5-0806/ 5-0013/5-0015/5-0053 Pigment Disperser NL Dispersant P1i01it e 7104 Styrene-butadiene copolymer PMA-100 Fungicide PM Acetate Polygloss 90 C1ay Polymekon SPP-W POlyOX WSR-301 Water s o l u b l e r e s i n Polyphase AF-1 B a c t e r i c i d e f u n g i c i d e Poly-Tex 611-Q Polywet ND-Z/ND-35 D i s p e r s a n t / s u r f a c t a n t s Proglyde DMM Dipropylene g l y c o l dimethyl e t h e r Propasol Solvent B I n d u s t r i a l s o l v e n t Proxel GXL Chemical b i o c i d e SOURCE Degussa Omya NLChem Burgess OSISpec P a t t e r Monsant M i nPi g BASF Goodyea Dow Arco Huber Mooney UnCarb Troy I n t e r e z Uni r o y DowChem UnCarb I C 1
  • 239.
    Trade Named RawMaterials 239 RAW MATERIAL CHEMICAL DESCRIPTION 9148 Defoamer QR-708/OR-7088/ Rheology modifiers QR-1374 R-2899 I r o n Oxide Red iron oxide Raven 16/410/1020 Carbon blacks Raybo 60 F1ash r u s t i n h i b i t o r Red I r o n Oxide 5-3100 Pigment Red I r o n Oxide 5-3106 Pigment Red I r o n Oxide R-2899/R-4098/R-5098 Pigments Red I r o n Oxide R0-4097 Pigment Regal 330 Carbon black Resi mene 747/797 Me1ami ne r e s i ns Rhoplex AC-1024/ A c r y l i c emulsions AC-3001/CL-lO4/CL-l05/ E-3188/MV-23/R-AC-507/WL-96 Ropaque OP-62 LO Opaque polymer Ross & Rowe 551 Modi f ied 1eci t h i n Rovace SF-091 V i n y l a c r y l ic copolymer R u f f B u f f Coarse s i l i c a SOURCE Troy Rohm& P f izer Col umb Raybo M i nPi g M i nPi g P f izer Harcros Cabot Monsan Rohm& Rohm& Ross& Rohm& Tammsco Sancure 815/825 S a n t i c i z e r 160 Santolink EP-560 SF-69 Shi eldex Short S t u f f Waterborne urethane r e s i n Sanncor P l a s t i c i z e r Monsanto Cross1inker Monsanto S i 1icone GE Anti-corrosion pigment, nontoxic Davison Polyethylene f i b e r s Mini F i b
  • 240.
    240 Water-Based PaintFormulations RAW MATERIAL CHEMICAL DESCRIPTION S i c o r ZNP-S A n t i - c o r r o s i o n pigment S i 1ane A-187 S i l c r o n G-601 F i n e p a r t i c l e s i l i c a g e l S i 1wet L-77/7001/ S i l i c o n e w e t t i n g agents L-7604/L-7605 Skane M-8 M i l d e w c i d e f o r p a i n t S k i n o #2 A n t i s k i n n i ng agent Snowf 1ake Calcium c a r b o n a t e S o l v e n t 142HT Sparmi t e B a r i um s u l f a t e S p e c i a l B l a c k 4 Carbon b l a c k Spensol L44/L51/L52/ Urethane p o l y o l s L53/L54 Strodex MO-lOO/P-100/ S u r f a c t a n t s PK-90/PK-95G S u n b r i t e Green 264-8142/ Pigments Sunbri t e Ye11ow 74/ S u n b r i t e Y e l l o w 272-0558/ S u n f a s t B l u e 248-3750 Super Seatone B u r n t Umber Pigment S u r f a c t o l 365 D i s p e r s a n t S u r f y n o l C T - l l l / S u r f a c t a n t s CT-131/CT-151/DF-37/ DF-62 S u r f y n o l DF-58/ Defoamers DF-70/DF-75 S u r f y n o l DF-llOD/ S u r f a c t a n t s DF-11 OL/DF-21 O/GA/ TG/104/104DPM/104€/ 104H/104PG-50/420/ 485 SOURCE BASF OSISpec SCM UnCarb Rohm& OMGroup ECC She11 H a r c r o s Degussa Reich D e x t e r Sun H i 1t o n CasChem A i r P r o d A i r P r o d A i r P r o d
  • 241.
    Trade Named RawMaterials 241 RAW MATERIAL CHEMICAL DESCRIPTION sws 211 A n t i foam S y l o i d 234 S i 1ic a f 1a t t i ng agent Syntex 3981 A c c e l e r a t o r T a l c 399 Extender pigment Tamol 165/681/731/ D i s p e r s a n t s 731A/050/960/983/ 1124/SG-1 Tan 10A T e r g i t o l NP-4/NP-10/ N o n i o n i c s u r f a c t a n t s NP-40 Texanol Coal e s c i ng agent T h a l o B l u e Aqueous d i s p e r s i on T h i x a t r o l ST T h i x o t r o p e T i n t - A y d WD-2744 P h t h a l o green d i s p e r s i o n T i n u v i n 328 UV absorber T i o n a RCL-9 T i t a n i um d i o x i d e T i o x i de TR-92 T i t a n i um d i o x i d e T i -Pure CR-800/ T i t a n i um d i o x i d e s R-700/R-702/R-706/ R-900/R-901/R-902/ R-960 T i t a n o x 2020/2060/ T i t a n i um d i o x i d e s 2101/2160 T r i t o n GR-7M A n i o n i c s u r f a c t a n t T r i t o n CF-10 W e t t i n g agent T r i t o n CA/GR-SM/ N o n i o n i c s u r f a c t a n t s N-57/N-lOl/X-100/ X-405 SOURCE Wacker Davi son Rhone- WC&D Rohm& Col umb UnCarb Eastman Tenneco Rheox D a n i e l C i ba- SCM T i o x i d e duPont Kronos UnCarb UnCarb UnCarb
  • 242.
    242 Water-Based PointFormulations RAW MATERIAL CHEMICAL DESCRIPTION Tronox CR-800/CR-813/ R u t i l e t i t a n i u m d i o x i d e s CR-828 Troysan Polyphase Fungicides AF-1/174/586 Troysol LAC Detergent/surfactant TS 610 Ucar 515 Ucar F i 1mer I B T Ucar Latex 100 Ucar Latex 105 Ucar Latex 144 Ucar Latex 146 Ucar Latex 161 Ucar Latex 163 Ucar Latex 169 Ucar Latex 353 Ucar Latex 367 Ucar Latex 379 Ucar Latex 3796 Ucar Latex 421 Ucar Latex 422 Ucar Latex 446 Ucar Latex 447 Ucar Latex 461 Ucar Latex 471 A c r y l i c l a t e x High s o l i d s a c r y l i c b i n d e r S e l f - c r o s s l i n k i n g a c r y l i c l a t e x Styrene-acryl ic emu1s i on polymer V i n y l a c r y l ic copolymer A1 1- a c r y l ic b i nder A c r y l ic polymer b i nder V i n y l a c e t a t e copolymer A c r y l ic 1atex polymer A c r y l i c l a t e x polymer V i n y l a c r y l ic polymer S t y r e n e / a c r y l i c l a t e x - s o f t S t y r e n e / a c r y l i c l a t e x - h a r d SOURCE Kerr-Mc Troy Troy Cabot UnCarb UnCarb UnCarb UnCarb UnCarb UnCarb UnCarb UnCarb UnCarb UnCarb UnCarb UnCarb UnCarb UnCarb UnCarb UnCarb UnCarb UnCarb UnCarb
  • 243.
    Trade Named RawMaterials 243 RAW MATERIAL CHEMICAL DESCRIPTION Ucar Latex 481 U l t r a - g l o s s l a t e x . Polymer: Hard Ucar Latex 624 100% a c r y l i c l a t e x Ucar Latex 625 A c r y l ic 1atex Ucar l a t e x 626 A11- a c r y l ic b i nder Ucar Latex 651 A c r y l i c l a t e x Ucar Latex 2300 Ucar Latex 6030 F i ne p a r t i c l e s ze "booster" 1atex Ucar Latex 6336 Hard, a l l - a c r y l c l a t e x Ucar Latex 6390 A c r y l i c b i nder . "Booster" 1atex Ucar Pol yphobe 102/103 Rheology modi f ie r s Ucar Polyphobe 106HE/ High e f f i c i e n c y t h i c k e n e r s 107/114- Ucar Polyphobe 9831 Ucar SCT100/SCT200/ 146 Ucar V e h i c l e 435 Ucar V e h i c l e 441 Ucar V e h i c l e 443 Ucar V e h i c l e 455 Ucar V e h i c l e 462 Ucar XYHL Ucar 376 Rheology modi f ie r Thickeners SOURCE UnCarb UnCarb UnCarb UnCarb UnCarb UnCarb UnCarb UnCarb UnCarb UnCarb UnCarb UnCarb UnCarb A c r y l i c polymer (45% s o l i d s ) UnCarb A c r y l ic emu1s i on Uncarb A c r y l i c l a t e x (41% s o l i d s ) UnCarb S e l f -cross1 in k i ng a c r y l ic 1atex UnCarb Thermosetting s t y r e n e a c r y l i c l a t e x UnCarb P o l y v i n y l - b u t y r a l r e s i n UnCarb UnCarb
  • 244.
    244 Water-Based PaintFormulations RAW MATERIAL CHEMICAL DESCRIPTION V a r s o l No. 1 M i n e r a l s p i r i t s Versa-F1 ow 102 Waterpoxy 701/702/1401 Epoxies Wingdale White N a t u r a l ground c a l c i u m c a r b o n a t e W i tcobond 234 P o l y u r e t h a n e d i s p e r s i o n W o l l a s t o c o a t 10AS W o l l a s t o k u p IOES W/R Epoxy E s t e r Resin W/R P o l y e s t e r 72-7203 SOURCE Exxon Shamroc Henkel GeorMar W i t c o Nyco NyCQ Rei ch C a r g i 11 X-3356 C.P. Medium Medium chrome y e l l o w pigment C i ba- XX-503/XX-503R Z i n c o x i d e s NJZinc XAMA- 7 Rohm& YD-2288 Ye1 k i ns-TS Soya l e c i t h i n Y e l l o w I r o n Oxide YO-2087 Pigment Y e l l o w I r o n Oxide 1075A Pigment Zeeospheres 400 Zeeospheres 600 Z i n c Chromate Y539D Z i n c Hydro-Nap Z i n c Oxide 417-W H a r c r o s Ross& H a r c r o s Col umb Zeel and Zeel and Heubach Mooney Eag1e
  • 245.
    Trade Named RawMaterials 245 RAW MATERIAL CHEMICAL DESCRIPTION Z i r c o 6% D r i e r Z i r c o n i um Chem-All 12% Z i r c o n i um Hydro-Cem Z i r c o n i um d r i e r , 12% Zirconium Hydro-Cure 12% C a t a l y s t f o r water systems Zopaque RCL-6 Titanium d i o x i d e . R u t i l e Zopaque RCL-9 T i t a n i um d i o x i d e 1OES Wol 1astocoat 233 Basic Zinc Chromate 399 Lo-Micron T a l c Extender pigment 895-9901 Water-dispersed b l a c k pigment SOURCE I n t e r s t Mooney Mooney Mooney SCM SCM Nyco Wayne WC&D Tenneco
  • 246.
    Suppliers' Addresses 247 Ai r Products and Chemicals 7201 Hami 1t o n Blvd. Allentown, PA 18195 (215)-481-4911/(800)-345-3148 Akzo Chemical s, I n c . 300 S. Riverside Plaza Chicago, I L 60175 (312)-906-7500/(800)-257-8292 Alcoa I n d u s t r i a l Chemicals P.O. Box 67 Bauxite, AR 72011 (501)-776-4981/(800)-643-8771 American Cyanamid Co. Chemicals Group One Cyanamid Plaza Wayne, NJ 07470 (201)-831-2000/(800)-443-0443 Angus Chemical Co. 1500 E. Lake Cook Rd. B u f f a l o Grove, I L 60089 (708)-215-8600/(800)-362-2580 Aqua1on P.O. Box 15417 2711 C e n t r e v i l l e Rd. W i 1m i ngton, DE 19850 (302)-996-2000/(800)-345-8104 ARC0 Chemical Co. 3801 West Chester Pike Newtown Square, PA 19073 (215)-359-2000 Asarco, I n c . 180 Maiden Lane New York, NY 10038 (212)-510-2000 BASF Corp. 100 Cherry H i l l Rd. Parsippany, NJ 07054 Buckman Laboratories I n t ' l I n c . 1256 N. McLean 8lvd. Memphis, TN 38018 (201)-316-3000/(800)-526-1072 (901)-278-0330/(800)-BUCKMAN Burgess Pigment Co. P.O. Box 349 Sandersville, GA 31082 (912)-5552-2544/(800)-641-8999 Byk-Chemi e USA 524 S. Cherry S t . Wall ingford, CT 06492 Cabot Corp. R t . 36 West Tuscola, I L 61953 (203)-265-2086 (217)-253-3370/(800)-222-6745 Calgon Corp. P.O. Box 1346 Pitsburgh, PA 15230 C a r g i l l , I n c . P.O. Box 5630 M i nneapol is , MN 55440 (612)-475-6478/(800)-535-1443 (412)-777-8000/(800)-4-CARBON CasChem, I n c . 40 Avenue A. Bayonne, NJ 07002 Chemical Corp. o f America 2 Carlton Ave. E. Rutherford, NJ 07073 (201)-858-7900/(8OO)-CAS-CHEM (201)-438-5600 C i ba-Gei gy Corp. 7 S k y l i n e D r . Hawthorne, NY 10532 (914)-347-4700/(800)-431-1900 Columbian Chemicals Co. 1600 Parkwood C i r c l e A t l a n t a , GA 30339 (404)-951-5700/(800)-235-4003 Cosan Chemical Corp. 400 14th S t . C a r l s t a d t , N J 27072 (201)-460-9300
  • 247.
    248 Water-Based PaintFormulations C r u c i b l e Chemical Co., I n c . P.O. Box 6786 G r e e n v i l l e , SC 29606 (803)-277-1284/(800)-845-8873 Cyprus I n d u s t r i a l M i n e r a l s P.O. Box 3419 Englewood, CO 80155 (800)-325-0299 Daniel Products 400 Claremont Ave. Jersey C i t y , NJ 07304 (201)-432-0800 Frank D. Davis Co. 7011 M u i r k i r k Rd. Bel t s v i 1l e , MD 20705 (301)-776-2400/(800)-638-4444 Davi son Chemical D i v . W.R. Grace & Co. P.O. Box 2117 B a l t i m o r e , MD 21203 Degussa Corp. 65 Challenger Rd. R i d g e f i e l d Park, N J 07305 (201)-641-6100 Dexter Chemical Corp. 845 Edgewater Rd. Bronx, NY 10474 Dover Chemical Corp W15 & D a v i s P.O. Box 40 Dover, OH 44622 (800)-321-8805 Dow Chemical USA 2020 Dow Center Midland, M I 48674 (800) -258-CHEM Dow C o r n i n g Corp. Box 0994 Midland, M I 48686 (5171-496-4000 Drew I n d u s t r i a l D i v . Ashland Chemical I n c . One Drew Plaza Boonton, NJ 07005 (201)-263-7800/(800)-526-1015 DuPont Co. 1007 Market S t . W i 1m i ngton , DE 19898 (800) -441 -751 5 Eagle-Picher I n d u s t r i e s , I n c . P.O. Box 550 C & P o r t e r S t r e e t s J o p l i n , MO 64802 (417)-623-8000 Eastman Chemical Co. P.O. Box 431 K i n g s p o r t , TN 37662 (615)-229-4006/(8OO)-EASTMAN ECC I n t e r n a t i o n a l 5775 Peachtree-Dunwoody Rd. A t l a n t a , GA 30342 (404)-843-1551/(800)-843-3222 Engelhard Corp. 101 Wood Ave. I s e l i n , N J 08830 (908)-205-5000 E n g l i s h Mica Co. R i dgeway Center B1dg . Stamford, CT 06905 (203)-324-9531 Exxon Chemical Americas 13501 Katy Frwy Houston, TX 77079 (713)-870-6000/(800)-231-6633 Freeman I n d u s t r i e s , I n c . 100 M a r b l e d a l e Rd. Tuckahoe, NY 10707 (914)-961-2100
  • 248.
    Suppliers'Addresses 249 GE Si 1icones 260 Hudson River Rd. Waterford, NY 12188 (518)-237-3330/(800)-255-8886 Genstar Stone Products Co. Exec Plaza I V 11350 McCormick Rd. Hunt Valley, MD 21031 (410)-527-4000 Georgia Marble Co. 1201 Roberts Blvd., 8ldg. 100 Kennesaw, GA 30144 (404)-421 -6500 B.F. Goodrich Co. 9911 Brecksvi 11e Rd. Brecksvi 11e, OH 44141 (216)-447-5000/(800)-331~1144 Goodyear T i r e & Rubber Co. 1144 E . Market S t . Akron, OH 44316 (216)-796-3010 W.R. Grace & Co.-Conn. 55 Hayden Ave. Lexington, MA 02173 (617)-861 -6600 Harcros Chemical s I n c 5200 Speaker Rd. Kansas C i t y , KS 66106 (913)-321-3131 Harshaw/Filtrol Partnership 30100 Chagrin Blvd. Cleveland, OH 44124 Henkel Corp. 11501 Northlake D r . C i n c i n n a t i , OH 45299 (513)-530-7300/(800)-543-7370 Heucotech, L t d . 99 Newbold Rd. F a i r l e s s H i l l s , PA 19030 (215)-736-9533/(800)-HEUEACH H i 1ton-Davi s Co. 2235 Langdon Farm Rd. C i n c i n n a t i , OH 45237 (513)-841-4000/(800)-477-1022 Hoechst Celanese Corp. 5200 77 Center D r i v e Charlotte, NC 28217 (704)-559-6000/(800)-365-2436 J.M. Huber Corp. Clay Div. One Huber Rd. Macon, GA 31298 (912)-745-4751/(800)-637-8176 Huls America I n c . 80 Centennial Ave. P i scataway, N J 08855 (908)-980-6800/(800)-631-5275 I C 1 Resins US 730 Main S t . Wilmington, MA 01887 (508)-658-6600/(800)-225-0947 I n t e r s t a b Chemicals, I n c . 500 Jersey Ave. P.O. Box 638 New Brunswick, NJ 08903 S.C. Johnson Polymer 1525 Howe S t . Raci ne, W I 53403 (414)-631-4875/(800)-231-7868 Kerr-McGee Chemical Corp. Kerr-McGee C t r . P.O. Box 25861 Oklahoma C i t y , OK 73125 (405)-270-1313/(800)-654-3911 King I n d u s t r i e s , I n c . Science Rd. Norwalk, CT 06852 (203)-866-5551/(800)-431-7900
  • 249.
    250 Water-Based PaintFormulations KMG M i n e r a l s , I n c . P.O. Box 729 1433 Grover Rd. K i ngs Mountain, NC 28086 (704)-739-3616/(800)-443-MICA Kronos, I n c . P.O. Box 60087 3000 N . Sam Houston Pkwy Houston, TX 77205 (713)-987-6300 M a n v i l l e F i l t r a t i o n 8, M i n e r a l s P.O. Box 519 Lompoc, CA 93438 (303)-978-4900/(800)-6 McWhorter 400 East Cottage Place C a r p e n t e r s v i l l e , I L 60 4-31 03 10 Michelman, I n c . 9089 S h e l l Road C i n c i n n a t i , OH 45236 (5131-793-7766 M i c r o Powders, I n c . 580 White P l a i n s Rd. Tarrytown, NY 10591 (914)-793-4058 M i l e s I n c . Mobay Road P i t t s b u r g h , PA 15205 (412)-777-2000/(800)-662-2927 M i n e r a l Pi gments Corp. Davis C o l o r s 7011 M u i r k i r k Rd. B e l t s v i l l e , MD 20705 Monsanto Chemi c a l Co. 800 N . Lindbergh B l v d . S t . Loui s, MO 63167 (314)-694-1000/(800)-325-4330 Mooney Chemicals I n c . 2301 Scranton Rd. Cleveland, OH 44113 Morton I n t e r n a t i o n a l 333 W. Wacker D r i v e . Chicago, I L 60606 Nalco Chemical Co. One N a l c o C t r . N a p e r v i l l e , I L 60563 (312)-807-2000 (708)-305-1000 New Jersey Z i n c Co. F o u r t h S t . 8 F r a n k l i n Ave. Palmerton, PA 18071 NL Chemicals, I n c . P.O. Box 700 Hightstown NJ 08520 Nyco M i n e r a l s , I n c . , P.O. Box 368 W i l l s b o r o , NY 12996 (5181-963-4262 O c c i d e n t a l Chemical Corp. 300 Berwyn Park Berwyn, PA 19312 (215)-251-1000 OM Group I n c . 2301 Scranton Rd. Cleveland, OH 44113 (216)-781-8383/(800)-321-9696 Omya I n c . 61 Main S t . P r o c t o r , VT 05765 (802)-459-3311/(800)-451-4468 Paci f ic Anchor Chemical Corp. 1224 Mendon Rd. Cumberland, R I 02864 (401)-333-4100/(800)-874-66668 P f i z e r , I n c . 235 E. 42 S t . New York, NY 10017 (212)-573-7217
  • 250.
    Suppliers'Addresses 251 PMC Sp e c i a l t i e s Group 20525 Center Ridge Rd. Rocky R i v e r , OH 44116 (216)-356-0700 Raybo Chemical Co. P.O. Box 2155K H u n t i n g t o n , WV 25722 R e i c h h o l d Chemicals, I n c . P.O. Box 13582 Research T r i a n g l e Park, NC27709 (919)-990-7500/(800)-448-3482 Rheox, I n c . P.O. Box 700 Hightstown, N J 08520 (609)-443-2500 Rhone-Poulenc I n c . Prospect P l a i n s Rd. Cranbury, NJ 08512 (609)-860-4000 Rohm & Haas Co. Independence M a l l West P h i l a d e l p h i a , PA 19105 (215)-592-3000 Sanncor I n d u s t r i e s , I n c . 300 Whitney S t . P.O. Box 703 Leomi n s t e r , MA 01453 (508)-537-4748 SCM Chemical s 2701 Broening Hwy B a l t i m o r e , MD 21222 (301)-288-8884/(800)-638-3234 Shamrock Technologies, I n c . Foot o f P a c i f i c S t . Newark, NJ 07114 S h e l l Chemical Co. Two She1 1 Plaza P . 0 . 8 0 ~ 1422 Houston, TX 77251 (201 )-242-2999 (EOO)-TEC-EPON Sherwin W i 11iams Co. Chemi c a l s D i v . P.O. Box 6520 Cleveland, OH 44101 (216)-566-2344 S i l b e r l i n e Mfg. Co. P.O. Box A Lansford, PA 18232 (717) -668-6050 Sun Chemical Corp. 4526 C h i c k e r i n g Ave. C i n c i n n a t i , OH 45242 (513)-68l-5950/(800)-543-2323 3M Corp. 3M Center S t . Paul, MN 55144 (612) -733-1 110 Tammsco, I n c . P . O . Box J Tamms, I L 62988 Tenneco M i n e r a l s Co. P.O. Box 281300 Lakewood, CO 80228 (303)-987-6200 Troy Corp. 72 Eagle Rock Ave. East Hanover, N J 07936 (201)-884-4300 U l t r a A d d i t i v e s , I n c . 460 S t r a i g h t S t . Paterson, NJ 07501 (201)-279-1306/(800)-524-0055 Unimin Corp. 258 E l m S t . New Canaan, CT 06840 (203)-966-8880/(800)-243-9004 UCAR Emu1s i o n Systems 410 Gregson D r i v e Cary, NC 27511 (919)-469-6700
  • 251.
    252 Water-Based PaintFormulations R.T. Vanderbilt Co.. I n c . 30 W i n f i e l d S t . P . O . Box 5150 Norwalk, CT 06856 (203)-853-1400 Velsicol Chemical Corp. 5600 N . River Rd. Rosemont, I L 60018 (708)-698-7000 Wacker S i l i c o n e s Corp. 3301 Sutton Rd. Adrian, MI 49221 (517)-264-8500/(800)-248-0063 Whittaker, Clark & Daniels, I n c . 1000 Coolidge St. South P l a i n f i e l d , NJ 07080 (908)-561-6100/(800-732-0562 Witco Corp. 520 Madison Ave. New York, NY 10022 (212)-605-394l/(800)-238-9150