ADVANCED CLEANING
PRODUCT FORMULATIONS
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ADVANCED
CLEANING
PRODUCT
FORMULATIONS
Volume 4
Ernest W. Flick
NOYES PUBLICATIONS
Westwood, New JOrsey, U.S.A.
Copyright 0 19% by Ernest W. Flick
No part of this book may be reproduced or utilized in
any form or by any means. electronic or mechanical,
including photocopying. recording or by any informa-
tion storage and retrieval system. without permission
in writing from the Publisher.
Library of Congress Catalog Cud Number: 89-30274
Printed in the United States
ISBN 0-8155-1396-8
Published in the United States of America by
Noyes Publications
369 Fairview Avenue
Weshvood, New Jersey 07675
10 9 8 7 6 5 4 3 2 1
Library of Congress Cataloging-in-Publication Data
(Revised for vo1.4)
Flick, Ernest W.
Advanced cleaning produd formulations
Includes bibliographid references and index.
1.Cleaning compounds. I. Title
TP990.F56 1989 668'1 89-30274
ISBN 0-8155-1186-8 (v. 1)
ISBN 0-8155-1346-1 (v. 2)
ISBN 0-8155-1382-1 (v. 3)
ISBN 0-8155-1396-8 (v. 4)
To
Ernie and Jeanne
and
AIIp and Barbara
and
Chris and Rachel
V
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This book (Volume 4) presents more than 435 up-to-date advanced cleaning
product formulations for household, industrial and automotive applications. It is
the result of information received fromnumerous industrial companies and other
organizations. The data represent selections made at no cost to, nor influence
from, the makers or distributors of these materials. Only the most recent
formulas have been included. All formulations are completely different than
those contained in Volumes 1, 2 and 3 published earlier.
Formulation in the cleaning product industry has gradually been undergoing
significant change during the past years. Raw materials costs have risen and
manufacturers have been reluctant to pass along these increases. Environmental
considerations have also played a part. By changing formulations to improve
cost/performance characteristics, manufacturers have been able to control costs
but still enhance performance. This book presents manufacturers' suggested
formulations which might meet new performance criteria.
The formulations in this book are divided into the following sections and
chapters, with the number of formulations indicated in ( ):
I. Household and Industrial Cleaners and Polishes
1. Bathroom Cleaners (26)
2. Dairy, Food and General Industrial Cleaners (15)
3. Degreasers (5)
4. Dishwashing Detergents (47)
5. General Purpose Cleaners (34)
6. Glass Cleaners/Polishes (25)
7. Hard Surface Cleaners (44)
8. Laundry Products (65)
9. Metal Cleaners and Polishes (22)
10. Oven, Grill and Hot Plate Cleaners (3)
11. Polishes, Coatings and Finishes (30)
12. Rinse Aids (4)
13. Rug, Floor, Carpet, Upholstery Shampoos and Cleaners (32)
14. Miscellaneous (32)
vii
Preface
viii Preface
11. Transportation Cleaners and Polishes
15. Auto Cleaners and Polishes (14)
16. Car and Truck Wash Compounds (27)
17. Whitewall Tire Cleaners (4)
18. Miscellaneous (8)
Each formula is located in the chapter which is most applicable. The reader,
seeking a formula for a specific end use, should check each chapter which could
possibly apply. In addition to the above, there are two other sections which will
be helpful to the reader.
111. Achemical trademark section where each tradenamed raw material
included in the book is listed with a chemical description and the
supplier's name. The specifications which each raw material meets
are included, if applicable.
IV. Main office addresses of the suppliers of trademarked raw
materials.
Each formulation in the book lists the following information, as available, in the
manufacturer's own words:
0
Description of end use and most outstanding properties.
The percent by weight or volume of each raw material included in
the formula, rounded to a decimal figure.
Key properties of the formula, which are the features that the
source considers to be more outstanding than other formulations
of the same type.
The formula source, which is the company or organization that
supplied the formula. The secondary source may be the originating
company and/or the primary source's publication title, or both. A
formula number is included, if applicable.
0
The table of contents is organized in such a way as to serve as a subject index.
My fullest appreciation is expressed to the companies and organizations who
supplied the original starting formulations included in this book. I also thank the
suppliers of the raw materials included in these formulations, who furnished
information describing their trademarked raw materials.
Newburyport, Massachusetts
August 1996
Ernest W. Flick
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NOTICE
To the best of our knowledge the information in this pub-
lication is accurate; however, the Publisher does not assume
any responsibility or liability for the accuracy or completeness
of, or consequences arising from, such information. This book
is intended for informational purposes only. Mention of trade
names or commercial products doesnot constitute endorsement
or recommendation for use by the Publisher. Final determ-
ination of the suitability of any information or product for use
contemplated by any user, and the manner of that use, is the
sole responsibility of the user. We recommend that anyone in-
tending to rely on any recommendation of materials or pro-
cedures mentioned in this publication should satisfy himself as
to such suitability, and that he can meet all applicable safety
and health standards.
X
1.
Contents and Subject Index
SECl'ION I
HOUSEHOLDAND INDU-
CLEANERS AND POLISHES
BATHROOM CLEANERS .............................. 2
Bathtub and Faucet Cleaner ............................ 3
Bathroom Cleaner ................................... 3
Toilet Bowl Cleaner ................................. 3
Tub and Tile Cleaner ................................ 3
Thick Toilet Bowl Cleaner ............................ 4
Foamable Acid Tile Cleaner ........................... 5
Liquid Toilet Bowl Cleaner ............................ 5
Solid Automatic Toilet Bowl Cleaner Formulation ........... 6
Acid Toilet Bowl Cleaner ............................. 6
Tub. Tile and Bathroom Cleaner ........................ 6
Tile. Porcelain and Bathroom Cleaner. Acid ................ 7
Hypochlorite Tub and Tile Cleaner and Mildew Stain
Remover ....................................... 7
Soap Scum RemoverICleaner ........................... 7
Toilet Cleaner
LiquidA ...................................... 8
Liquid B ...................................... 8
Clear Liquid Bowl Cleaner ............................ 4
Medium Viscosity-A ............................. 8
Medium Viscosity-B ............................. 8
Medium Viscosity-A ............................. 9
Medium Viscosity-B ............................. 9
Powder ....................................... 9
Powder-B ..................................... 9
Extruded-A ................................... 10
Extruded-B ................................... 10
Cast-A ...................................... 10
Cast-B ...................................... 10
Toilet Cleaning Block
xi
xii Contents and Subject Index
2. DAIRY. FOOD AND GENERAL INDUSTRIAL CLEANERS . . . 11
Acid Dilutable Concentrate ........................ 12
Low Cost Acid Dilutable Concentrate . . . . . . . . . . . . . . . . 12
Dairy Milkstone Remover
Dairy Pipeline Cleaner-High Alkaline Low Foam
Institutional Stainless Steel Cleaner ..................... 13
High Pressure Cleaner for Industrial Use . . . . . . . . . . . . . . . . . 14
Cleaner for Milking Equipment ........................ 14
Cleaner for Meat Plants ............................. 14
Meat Packaging Plant Cleaner Concentrate . . . . . . . . . . . . . . . . 15
Steam Cleaners
Light Duty .................................... 16
Hypochlorite Cleaner .............................. 13
Medium Duty .................................. 16
Heavy Duty (for Oily Soils) ....................... 16
General Purpose ................................ 16
Light Duty for Soft Metals ........................ 16
Compound .................................... 16
3. DEGREASERS ...................................... 17
d-Limonene Microemulsion Cleanermegreaser . . . . . . . . . . . . . 18
Concentrated d-Limonene Biodegradable Degreaser . . . . . . . . . 18
Solvent Degreasing ................................. 19
4. DISHWASHING DETERGENTS ......................... 20
Clear Liquid Dishwash .............................. 21
Non-Chlorinated Machine Dishwashing Compound. Liquid . . . . 21
Clear. Colorless Manual Dish Wash ..................... 21
Powder for Automatic Dishwashing Machines . . . . . . . . . . . . . . 23
Dishwashing Detergent
Medium Viscosity
Dish Washing Agent ................................ 22
Basis Marlon A-A ........................... 24
Basis Marlon A-B ........................... 24
Basis Marlon AS3-A ......................... 24
Basis Marlon AS3-B ......................... 24
Basis Marlon PS-A .......................... 25
Basis Marlon PS-B .......................... 25
Basis Marlon Compounds-A ..................... 25
Basis Marlon Compounds-B .................... 25
Powdered
Spray Mixing Process-A ...................... 26
Spray Mixing Process B ....................... 26
Phosphate-Free. Spray Mixing. Process A . . . . . . . . . . 26
Contents and Subject Index xiii
Phosphate.Free. Spray Mixing. Process B .......... 26
40% Solids-A .............................. 27
40% Solids-B .............................. 27
Hand Dishwashing Liquid ............................ 27
Dish Wash w/Amine Oxide/LABS/SLES ................. 28
Dish Wash w/Amine Oxide/LABS/ALES ................. 28
Dish Wash w/Amine Oxide/LABS ...................... 28
High-Performance Hand Dish Detergent ................. 29
Mild Liquid Hand Dish Detergent ...................... 29
Starting Formulations for Home Machine Dishwashing
Detergents
8.7% Phosphorous(A) ............................ 30
8.7% Phosphorous(l3) ............................ 30
Nonphosphate ................................. 30
Pilot Formula #LDL-010-01 ...................... 31
Pilot Formula #LDL-013-01 ...................... 31
Pilot Formula #LDL-005-01 ...................... 31
Pilot Formula #LDL-O15-01 ...................... 31
Premium Hand Dishwash ......................... 32
Economy Hand Dishwash ......................... 32
Liquid Hand Dish Detergent .......................... 33
Mechanical Dishwashing Detergent. Chlorinated ............ 34
Mechanical Dishwashing Detergent. Liquid ............... 34
Non-DDBSA Dishwashing Liquid ...................... 35
Starting Formulations for Commercial Machine
Light Duty Liquid Detergents
Dishwashing Detergents
Nonchlorine/Noncaustic .......................... 36
Noncaustic .................................... 36
ChlorineKaustic ................................ 36
5. GENERAL PURPOSE CLEANERS ....................... 37
Phosphate Free All Purpose Cleaner ..................... 38
Bathroom Tile Cleaner .............................. 38
All Purpose Cleaner ................................ 39
Hard-surface Cleaner ............................... 39
All-Purpose Cleaner
Cleaner-A .................................... 40
Cleaner-B .................................... 40
With Microbicidal Properties. Liquid-B ............... 40
All Purpose Cleaner ................................ 38
Liquid-A ..................................... 41
Liquid-B ..................................... 41
With Microbicidal Properties. Liquid-A ...............41
xiv Contents and Subject Index
Pasty-A ...................................... 42
With Soap. High Viscosity-A ...................... 42
With Soap. High Viscosity-B
Pasty-B ...................................... 42
...................... 42
D-Limonene Emulsifiable Concentrate . . . . . . . . . . . . . . . . . . . 43
D-Limonene All Purpose Cleaner ...................... 43
General Cleaners
Household .................................... 44
Alkaline Cleaner ............................... 44
Liquid Hand Cleaner ............................ 44
Germicidal Cleaner .............................. 44
High-Performance General Purpose Cleaner Concentrate . . . . . . 45
Heavy-Duty Cleaner Powder .......................... 45
Neutral All-Purpose Cleaner. with Pearlescence Effect
High Viscosity-A ............................... 46
High Viscosity-B ............................... 46
With Acetic Acid-A ............................. 46
With Acetic Acid-B ............................. 46
Non-Phosphate All Purpose Cleaner .................... 47
Oil Splitting General Purpose Cleaner ................... 47
Scouring Cleaner
Medium Viscosity-A ............................ 48
Medium Viscosity-B ............................ 48
Powder-A .................................... 48
Powder-B .................................... 48
All-Purpose Cleaner
6. GLASS CLEANERSD’OLISHES ......................... 49
For Application to Cloth .......................... 50
For Direct Application to Glass ..................... 51
Anti-Fogging. Anti-Static Glass Cleaner ................. 52
Ammoniated Glass Cleaner ........................... 52
Glass Cleaners
Ammonia ..................................... 53
Vinegar ...................................... 53
Antifog Composition
Glassware and Bottle Cleaners
Bottle Cleaner
Alkaline-Powder ............................ 54
Acid-Powder ............................... 54
Acid-Liquid ............................... 54
Highly Alkaline ............................. 54
Household Window Cleaner .......................... 55
Premium Household Window Cleaner ................... 55
Contents and Subject Index xv
Low VOC Antistat/Cleaner for Glass .................... 56
Anti-Fog Glass Cleaner ............................. 56
Glass Cleaner ..................................... 56
Traditional Consumer Glass Cleaner .................... 57
Consumer Acid Glass Cleaner ......................... 57
7. HARD SURFACE CLEANERS .......................... 58
Abrasive Cleaner-1 ................................ 59
Abrasive Cleaner-2 ................................ 59
Abrasive Cleaner-3 ................................ 59
Concentrated Liquid Household Hard-surface Cleaner ....... 60
All-Purpose Household Spray Cleaner ................... 60
Consumer Tile Cleaner .............................. 61
Industrial Strength Chlorine Cleaner ..................... 61
D-Limonene Hard-surface Cleaners .................... 62
d'limonene Spray Cleaner ............................ 63
d'limonene Cleaner Concentrate ....................... 63
General Purpose Hard Surface Cleaner ................... 64
Alkaline Hard Surface Cleaner ........................ 64
General Purpose Hard-surface Cleaners .................. 65
Unbuilt. High-Sudsing. Hard-surface Cleaner ............. 65
Hard Surface Cleaner ............................... 66
Non-Abrasive Cleanser .............................. 66
Hard Surface Cleaner ............................... 66
Floor Cleaner Products .............................. 68
Rug Cleaner ...................................... 68
Plastic. Vinyl and Leather Cleaner ...................... 68
Hard Surface Cleaners .............................. 69
Tub and Tile Cleaners ............................... 69
Counter Top/Wall Cleaners
AlIPurposeType ............................... 69
Ammoniated Type .............................. 69
Hard Surface Cleaner w/Amphoteric .................... 70
Hard Surface Cleaner Concentrate
w/d'Limonene ................................. 70
Alkaline All-Purpose Cleaner Concentrate ............. 71
All-Purpose Alkaline Cleaner for Sponge or Spray
Application ................................. 71
High-Performance. Hard Surface Cleaners ................ 72
Economical Pine Oil Hard-surface Cleaner ............... 72
Mild Abrasive Hard Surface Cleaner .................... 73
Non-Phosphate Household Hard-surface Cleaner ........... 74
Non-Phosphate Concentrated Household Hard-surface
Cleaner ....................................... 74
xvi Contents and Subject Index
Pine Oil Cleaner Concentrate .......................... 75
Liquid Super Concentrate ............................ 75
8. LAUNDRY PRODUCTS ............................... 76
Anionic/Nonionic Heavy-Duty Laundry Detergent . . . . . . . . . . 77
Nonionic/Amphoteric Heavy-Duty Laundry Liquid . . . . . . . . . . 78
Cold Water Detergent ............................... 79
Fine Fabric Detergent . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79
Process-A .................................... 80
P~OUXS-B. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80
Medium Viscosity-A ............................ 81
Medium Viscosity-B ............................ 81
Medium Viscosity-A ............................ 81
Medium Viscosity-B ............................ 81
Detergent for Fine Fabrics-1 .......................... 82
Detergent for Fine Fabrics-2 .......................... 82
Enzymatic Heavy-Duty Laundry Detergent
Non-Phosphate Laundry Powder ....................... 83
Fabric Pretreatment Spritz ............................ 84
Low VOC Pump Fabric Antistatic Spray
Laundry Pre-Spotter and Stain Remover
Detergent for Colored Fabrics. Powder. Spray Mixing
Detergent for Curtains
Manual-Wash Detergent. Foaming
. . . . . . . . . . . . . . . 83
. . . . . . . . . . . . . . . . . 84
. . . . . . . . . . . . . . . . . 84
Process-1 .................................... 85
Pr0~ess-2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85
Process-3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85
Low Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86
Low Viscosity-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86
Concentrate. Low Viscosity-A ..................... 86
Concentrate. Low Viscosity-B ..................... 86
Spray Mixing Process-A .......................... 87
Spray Mixing Process-B . . . . . . . . . . . . . . . . . . . . . . . . . . 87
Spray Mixing Process-A .......................... 88
Spray Mixing Process-B .......................... 88
Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88
Fabric Softener
Heavy-Duty Detergent. Powder
Liquid Heavy-Duty Detergent. Built Type. High
Heavy Duty Liquid Laundry Detergent-Type DN . . . . . . . . . . 89
Built Formulation #1 ................................ 89
Heavy Duty Liquid Laundry Detergent-Type TA . . . . . . . . . . 90
Heavy Duty Liquid Laundry Detergent-Type WA . . . . . . . . . . 91
Liquid Laundry Detergents ........................... 90
Contents and Subject Index xvii
Built Formulation #2 ................................ 91
Liquid Heavy-Duty Detergent
Low Viscosity-A ............................... 92
Low Viscosity-B ............................... 92
Built Type.High Viscosity-B ...................... 92
Light-Duty Detergent. Powder
Spray Mixing Process-A .......................... 93
Spray M i n g Process-B .......................... 93
With Incorporated Softener. Low Viscosity-A .......... 93
Low VisCosity-A ............................... 94
Low Viscosity-B ............................... 94
With Incorporated Softener. Low Viscosity-B .......... 94
Industrial Laundry Two-Part Systems. Uniforms
(Petroleum Greases and Oils) ........................ 95
HoteVLinen Supply (Animal and Vegetable Grease) ......... 95
Industrial Laundry Powder. Uniforms .................... 95
Laundry Liquids ................................... 96
"Fine Care" Fabric Detergents
Pilot Formula #LDY-OO3-01 ...................... %
Pilot Formula #LDL-003-01 ...................... 96
Pilot Formula #HDL-004-01 ...................... %
Pilot Formula #HDL-005-01 ...................... %
Laundry Powder Detergent ........................... 97
Industrial Laundry One-Shot Liquid .................... 97
Liquid Heavy Duty Detergent HDLD .................... 98
Liquid Detergent "FSL" A ............................ 98
Thick Bleach-2 ................................... 99
Wool Detergent
Medium Viscosity-A ........................... 100
Medium Viscosity-B ........................... 100
Liquid Light-Duty Detergent
Heavy Duty Laundry Liquids
Thick Bleach-1 ................................... 99
9. METAL CLEANERS AND POLISHES ................... 101
Aluminum CleanerDrightener ........................ 102
Aluminum Smut Cleaner ............................ 102
Aluminum Cleaner Concentrate ....................... 103
Aluminum Wash ................................. 103
Cleaners and Cleaning Solutions ...................... 104
Metal Cleaning
Alkaline .................................... 104
Acid ....................................... 104
Paint Removal ................................ 104
xviii Contents and Subject Index
Rust Removal ................................ 104
Copper Cleaning .................................. 105
Acid ....................................... 105
Brightening .................................. 105
Aluminum Aircraft-Brightener (U.S. Patent 2.687.346) . . . . . . 105
Electrocleaner ................................... 106
Moderate Alkalinity. Soil Splitting Soak Cleaner . . . . . . . . . . . 106
High-Foaming Acid Scrubber ........................ 107
Acid Cleaner .................................... 107
Metal Cleaner and Degreaser .........................
Thickened Clear Degreaser Concentrate . . . . . . . . . . . . . . . . . 108
Cleaner-A ................................... 109
Cleaner-B ................................... 109
Liquid-A .................................... 109
Liquid-B .................................... 109
Aluminum Cleaning
108
Stainless Steel
Silver Polish
10.OVEN. GRILL AND HOT PLATE CLEANERS . . . . . . . . . . . . 110
Pump Spray Oven Cleaner .......................... 111
Caustic Oven Cleaner .............................. 111
Oven/Grill Cleaner ................................ 111
11. POLISHES. COATINGS AND FINISHES ................. 112
Aerosol Furniture Polish (Carbon Dioxide Propellant) . . . . . . . 113
General Purpose Liquid Polish (Oil-in-Water Type) . . . . . . . . 113
Aerosol Furniture Polish (Hydrocarbon Propellant) . . . . . . . . . 114
Furniture Paste Wax ............................... 114
Detergent Resistant. Cream Cleaner Polish . . . . . . . . . . . . . . . 115
Non-Abrasive. Detergent Resistant. Glaze Emulsion . . . . . . . . 115
High Gloss. Detergent Resistant. Soft Paste Polish . . . . . . . . . 116
Detergent Resistant Cream Polish ..................... 116
For Clear Coat Finishes ......................... 117
No Solvent .................................. 117
Outer Phase Oil ............................... 118
Non-Wax Liquid Polish (Oil-in-Water Type) ............ 118
Liquid Furniture Polish ............................. 119
20% Wax Emulsion-1 ............................. 119
20% Was Emulsion-2 ............................. 119
Liquid Water-Based Glaze .......................... 120
Solvent Wax Glaze ................................ 120
Paste Polish (Oil-in-Water Type) ..................... 121
Liquid Polish
Contents and Subject Index xir
Spray-and-Wipe Polish ............................ 121
Paste Polish
Oil-in-Water Type
Type-1 .................................. 122
Type-2 .................................. 122
Type-3 .................................. 123
Outer Phase Oil ............................... 123
Spray-and-Wipe Polish (Pump) ...................... 124
20%Wax Emulsion-1 ............................. 124
20% Wax Emulsion-2 ............................. 124
Spray and Wipe Type
Aerosol or Non-Aerosol (1) ...................... 125
Aerosol or Non-Aerosol (3) ...................... 125
Aerosol or Non-Aerosol (2) ...................... 125
Liquid Wax-Solvent Furniture or Floor Polish ............ 125
12.RINSE AIDS ....................................... 126
For Hard Water ............................... 127
For Neutral or Soft Water ........................ 127
Rinse Aid ...................................... 128
Automatic Dishwash Rinse Aid
13.RUG. FJ.DOR, CARPET. UPHOLSTERY SHAMPOOS
ANDCLEANERS ................................... 129
Liquid-A .................................... 130
Liquid-B .................................... 130
Liquid-A .................................... 130
Liquid-B .................................... 130
Dry-Foam Cleaner
Basic Floor Cleaner
Floor Cleaner. for Everyday Use
Carpet and Upholstery Cleaners
Liquid-A ................................ 131
Liquid-B ................................. 131
Powder-A ................................ 131
Powder-B ................................. 131
Carpet Shampoo. High Foam ......................... 132
Evaporative (No Rinse) Wax Stripper ................... 133
Waxed Floor Cleaner .............................. 133
Floor Cleaner .................................... 134
Floor Polish
Mor-Glo 2-457 20% Solids ...................... 135
ML-870-389 20%Solids ........................ 136
Liquid Carpet Cleaner .............................. 137
XT Contents and Subject Index
Carpet Stain Remover-Liquid ........................ 137
Carpet Cleaner/Booster.Dry. Destainer . . . . . . . . . . . . . . . . . 137
Low Cost Extraction Carpet Cleaner . . . . . . . . . . . . . . . . . . . 138
Non-Ammoniated Floor Stripper ...................... 139
Quarry Tile Cleaner ............................... 140
Low Foam Floor Cleaner ........................... 140
Special-Purpose Floor Cleaner
Liquid-A .................................... 141
Liquid-A .................................... 141
Medium Cost Steam Extraction Carpet Cleaner . . . . . . . . . . . . 138
Premium. Heavy Duty Steam Extraction Carpet Cleaner . . . . . 138
Liquid-B .................................... 141
Wash-and-Wax Floor Cleaner
Liquid-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 141
14.MISCELLANEOUS .................................. 142
Condensate T L Typical Formulations . . . . . . . . . . . . . . . . . . 143
All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143
Dilutable Shampoo ................................ 143
Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143
Opacified Hand Soap .............................. 143
d'lmonene Waterless Hand Cleaner . . . . . . . . . . . . . . . . . . . 144
Waterless Hand Cleaner ............................ 144
Dry Cleaning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 145
Dust Control . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 146
Hand and Body Cleanser ............................ 147
Heavy Duty Degreaser ............................. 148
Burnishing Compound .............................. 148
Bubble Bath . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143
Viscous Floor Cleaner .............................. 143
Corrosion Inhibiting Coating Oil-Emulsifiable . . . . . . . . . . . . 148
Heavy Duty Industrial Spray Metal Cleaner Concentrate . . . . . 149
Low Foam Hypochlorite Cleaner ...................... 149
Metal CleanerBrightener ........................... 149
Low Foam Heavy Duty Alkaline Cleaner-A . . . . . . . . . . . . . . 150
Low Foam Heavy Duty Alkaline Cleaner-B . . . . . . . . . . . . . . 150
Paint Brush Cleaners ............................... 151
Steam Cleaner ................................... 152
Heavy Duty Industrial Spray Cleaner Concentrate . . . . . . . . . . 152
Hot Tank Stripper/Cleaner/Derster .................... 150
High Solids Alkaline Cleaner ........................ 152
Wallpaper Removal ............................... 153
Contents and Subject Index m-
SECTION II
TRANSPORTATION CLEANERS AND POLISHES
15.AUTO CLEANERS AND POLISHES .................... 155
Auto Polishlcleanser. Oil in Water Emulsion ............. 156
Detergent Resistant Auto PolishlCleanser. Paste Wax ....... 156
Camauba Hotwax ................................. 157
Pressure Spray Truckwash ........................... 157
Detergent Resistant Auto Polish. Oil in Water Emulsion ..... 158
High Luster Auto Finish. Paste Wax ................... 158
High Gloss. Detergent Resistant Polish .................. 159
High Gloss Auto PolishPinish ........................ 159
Spraywax ....................................... 160
Spraywax Ladder of Formulas ........................ 161
Spraywax Concentrate .............................. 160
16.CAR AND TRUCK WASH COMPOUNDS ................ 162
Automatic Car Wash Concentrate ..................... 163
General Purpose Car Wash .......................... 163
Auto Shampoo Concentrate .......................... 164
High Foaming Car Wash ............................ 164
Car Wash ....................................... 164
Car Wash Liquid ................................. 165
Car Wash Powder ................................. 165
Economy Truck Wash .............................. 166
Truck Wash Liquid ................................ 166
Foamy Brush Car Wash. Liquid ....................... 167
1:2 Dilutable Car Wash ............................. 167
High Oil Splitting Vehicle
Wash-A .................................... 168
Wash-B .................................... 168
Liquid Car Wash ................................. 169
Spray-On Car Wash Concentrate ...................... 169
Liquid Hi@ Pressure Coocentrate ..................... 170
Tmck Wash w/varamide A-83 ....................... 170
Liquid Tmck Wash ................................ 171
Mild Car Shampoo ................................ 172
Cgrspray CW Concentrate ........................... 172
Automotive "Wash t Wax" ......................... 172
Premium Carspray 500 Concentrate .................... 173
Standard Carspray 500 Concentrate .................... 173
Premium Carspray 700 Concentrate .................... 174
Standard Carspray 700 Concentrate .................... 174
xxii Contents and Subject Index
17.WHITEWALL TIRE CLEANERS ....................... 175
White Wall Tire Cleaner ............................ 176
Bug Remover Concentrate ........................... 176
Whitewall Tire Cleaner Concentrate .................... 177
Whitewall Tire Cleaner Liquid ....................... 177
18.MISCELLANEOUS .................................. 178
Automobile Windshield Cleaners ...................... 179
General Purpose Liquid Boat Polish-(l) ................. 180
General Purpose Liquid Boat Polish-(2) ................. 180
Liquid Aluminum Engine Block Cleaner ................ 181
Foaming Engine Cleaner ............................ 181
SECTION Ilk TRADE-D RAW MATERIAIS ........... 182
SECTION N:SUPPLIERS'ADDRESSES .................... 197
Section I
Household and Industrial
Cleaners and Polishes
1
1 Bathroom Cleaners
2
Bathroom Cleaners 3
Bathtub and Faucet Cleaner
I n g r e d i e n t : Percent by We1q h t
Ammoni um hydroxide s o l u t i o n 28% 3.2
Cellosolve solvent 5.0
Nonionic s u r f a c t a n t (Neodol 25-9) 6.0
Water 65.8
L i q u i d C i t r i c Acid-50% (Haarman & Reimer Corp.) 20.0
Fragrance, dye q . s .
Mix t h e L i q u i d C i t r i c Acid-50% w i t h an equal volume o f water.
Slowly add t h e ammonium hydroxide s o l u t i o n . The n e u t r a l i z a t i o n
should be done c a u t i o u s l y and under a g i t a t i o n , as t h e r e a c t i o n
i s exothermic. Add Cellosolve, s u r f a c t a n t , remaining water,
fragrance and dye. The formula i s s u i t a b l e f o r a pump spray.
Bathtub, sinks, faucets and other hard surfaces should be
sprayed from a distance o f about 10 inches. For maximum e f f e c t -
iveness, t h e deposited cleaner f l u i d should be e f t a t work
f o r a t l e a s t f i v e minutes and then r i n s e d o f f w t h water o r
removed w i t h a wet c l o t h o r sponge.
SOURCE: Haarman 81 Reimer Corp.: Suggested Formu
__Bathroom_ _ _ - ~Cleaner
Water
Sodium C i t r a t e
Glucopon 425 CS
Propylene Glycol nButy1 Ether
T o i l e t B o w l Cleaner
Water
Phosphoric Acid
Glucopon 425 CS
Tub 8 7 1 l e Cleaner
a t i o n
Water
Sodium C i t r a t e
STPP
Standapol ES-2
Velvetex A0-45
Standamid KD
Isopropyl Alcohol
SOURCE: Henkel Corp., CD D i v i s i o n : S t a r t i n g Formulations
"rtb
79
9
9
3
W t %
79
15
6
W t %
75
4
1
12
4
1
3
4 Advonced CleoningRoduct Formulotions
Clear Liquid Bowl Cleaner
Formula BC-0001
Miranol FBS
Hydrochloric A c i d (20Be)
Water
Wt.%
3.0
20.0
77.0
Procedure
Add t h e Miranol FBS. Mix u n t i l uniform.
Phvsi-1 Prooerties
Add t h e water. Slowly add t h e h y d r o c h l o r i c acid, w i t h mixing.
Appearance: Clear, l i g h t y e l l o w
V i s c o s i t y : <10 cps
S p e c i f i c G r a v i t y : 1-03
pH (as i s ) : <1.0
Thick T o i l e t Bowl Cleaner
Formula BC-0002
Wt.%
M i r a t a i ne TM 5.0
Hydrochloric Acid (20Be)
Water
32.0
Q.S
Prowdur g
add t h e M i r a t a i n e TM and mix u n t i l uniform.
PhvsiG a l Prooerties
Add t h e h y d r o c h l o r i c a c i d t o t h e water, w i t h s t i r r i n g . Slow
Appearance: C1ear, ye11ow 1iqui d
V i scosi t y : 1.035 cps
Speci f ic Gravi t y : 1,037
pH (as i s ) : <1.0
Y
SOURCE: Rhone-Poulenc S u r f a c t a n t s & S p e c i a l t i e s : Formulas
Bathroom Cleaners 5
Foarnable A c i d T i l e Cleaner
Hard Foaming Hard Surface Cleaner f o r Soap Scum Removal
Inaredi e n t :
Dei oni zed Water
C i t r i c Acid (50%)
Mazon 98
Wt.%
87.00
10.00
3.00
pH (as i s ) : 2.0-2.5
Appearance: Clear, water-white l i q u i d
S p e c i f i c G r a v i t y : 1 .01
Procedure:
above. Mix u n t i l c l e a r .
Notes :
This formula produces a copious, dense foam. I t i s s u i t a b l e
f o r cleaning soap scum from shower s t a l l t i l e s and other bath-
room and household f i x t u r e s .
To a mixing vessel, charge t h e i n g r e d i e n t s i n t h e order l i s t e d
Formula CH-105
L i a u i d T o i l e t Bowl Cleaner
A L i q u i d S t a i n and Rust Remover
I n s r e d i e n t :
Deionized Water
Phosphoric Acid (75%)
Avanel S-70
pH (as i s ) : t1.5
Appearance: Clear, water-white l i q u i d
S p e c i f i c G r a v i t y : 1.124
Wt.%
66.00
30.00
4 . 0 0
Procedure:
phosphoric a c i d under a g i t a t i o n . Use c a u t i o n during a c i d add-
i t i o n t o avoid s p a t t e r i n g . When a l l o f t h e a c i d i s dissolved,
cool t o room temperature and add t h e Avanel s u r f a c t a n t .
Notes:
i c u l a r l y e f f e c t i v e i n t h e removal o f scale build-up and r u s t
s t a i n s .
This m a t e r i a l may be marketed i n an appropriate squeeze
b o t t l e t o f a c i l i t a t e "under t h e r i m " bowl cleaning by t h e
consumer.
Formula CT-101
SOURCE: Mazer Chemicals: Suggested Formulations
Charge t h e water t o t h e mixing vessel, and slowly charge t h e
This formulation i s designed t o be used "as i s " and i s p a r t -
S o l i d Automatic T o i l e t Bowl Cleaner Formulation
I n g r e d i e n t :
Macol DNP 150
Incromide L90
Carbowax PEG 8000
Macol 27
Versaflex 207 ( d r y )
Water
%-
25.0
25.0
20.0
20.0
5.0
5.0
Procedure:
1. Melt t h e Macol 27, Macol DNP 150, and Carbowax PEG 8000, and
2. Maintain a temperature o f about 70C, and add t h e Incromide
3. Add water and Versaflex 207 ( d r y ) and mix.
4. Pour formulation i n t o a mold, and a l l o w t o cool.
SOURCE: National Starch and Chemical Co.: Reference #8069:49
mix together.
L90 w h i l e mixing.
__A c i d T o i l e t Bowl Cleaner
Water, D . I .
Hydrochloric Acid (37%)
Rewoteric AM TEG
% bv Weiaht
71 . O
27.0
2.0
B1endi ng Procedure:
Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between
each addi t i on.
Typical Properties:
V i s c o s i t y , cps: 135
Solids: 1.0%
pH: 2.8
SOURCE: Witco Corp.: Formula 532
Tub, T i l e and Bathroom Cleaner
Water
Sodium Carbonate
Tetrasodium EDTA (40%)
Phosphoteric T-C6
Nonoxynol 10
Procedure:
% bv Wei aht
81.5
5.0
10.0
1.5
2.0
Add i n g r e d i e n t s i n order l i s t e d , a l l o w i n g s u f f i c i e n t time
between a d d i t i o n s .
This product may be applied w i t h a t r i g g e r pump o r by aerosol.
Formulation Properties:
Physical Appearance: Clear l i q u i d
Cloud Point: 42C
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formulation
6 Advanced CleaningRoabct Formulations
Bathroom Cleaners 7
T i l e , Porcelain and Bathroom Cleaner, Acid
Water. D . 1
% by Weiqht
75.5
Rhodopol 23 0.5
Petro BAF Powder 2.0
Phosphori c Acid, 75% 12.0
Hydroxyacetic Acid, 70% 10.0
Perfume, Dye q . s .
B1endi ng Procedure :
t o mix u n t i l material thickens. Add remaining ingredients i n
order l i s t e d . If problems develop adding Rhodopol t o water,
premix the Rhodopol 23 i n some isopropanol before adding t o
water.
Formula 529
Add Rhodopol 23 slowly t o water w i t h high speed mixing. Allow
Hypochlorite Tub and T i l e Cleaner and Mildew S t a i n Remover
% by Weiqht
Water, D.I. 44.9
Sodium Hydroxide (30%) 1 .o
Varox 365 1.5
Sodium Hypochlorite (5.7%) 52.6
81endi ng Procedure :
between each addi t ion.
Typical Properties:
Viscosity, cps: 4
Solids: 3.8%
pH: 13.5
Formula 531
Add ingredients i n order shown and dissolve completely
Soap Scum Remover/Cleaner
% by Weiaht
Water, D.I. q . s .
*Builder Solution 0.20
Tetrasodi um EDTA 0.25
Rewoteric AM V 1 .oo
Dowanol EB 0.50
81ending Procedure:
Blend ingredients i n the order shown, mixing thoroughly
between each a d d i t i o n .
Typical Properti es :
Viscosity, cps: 4
Solids: 2.0%
pH: 11-12
Comments:
*Builder Solution: Sodium Carbonate (Na2C03): 4%
Potassi um Hydroxide (KOH) : 3%
DI Water 93%
Formula 544
SOURCE: Witco Corp.: Suggested Formulations
8 Advanced CleaningRoabct Formulations
T o i l e t Cleaner. Liquid-A
Marl ipal 013/99
Acetic acid*
Balance water, fragrance, dyestuff
A c t i v e matter: 2.7%
Toi 1e t Cleaner . L iquid-B
Marl ipal 013/99
C i t r i c a c i d
Balance water, fragrance, d y e s t u f f
A c t i v e matter: 4.5%
Toi 1e t C1eaner , Medi urn V i scosi t y - A
Marlazin OL 2
M a r l i p a l 013/99
C i t r i c a c i d
Na Cumene sulphonate 40 (approx.)
Balance water, fragrance, d y e s t u f f
A c t i v e matter: 2.0%
T o i l e t Cleaner, Medi urn V i scosi tv-B
Marlazin OL2
Marl ip a l 013/99
C i t r i c a c i d
Phosphoric acid, 85%
KNA cumene sulphonate 40 (approx.)
Balance waser, fragrance, d y e s t u f f
A c t i v e matter: 2.0
* f u r t h e r products o f Huls AG
96
3.0
6.0
t o 100
%
5.0
1.7
t o 100
%
1.5
0.5
5.0
1.5
t o 100
%
1.5
0.5
2.5
7.5
1.3
t o 100
SOURCE: Huls America, I n c . : Baslc Formulations o f Detergents
and Cleaning Agents f o r Household Purposes
Bathroom Cleaners 9
Toi 1e t Cleaners, Mediurn V i scosi t y - A
Marlazin 7102
Phosphoric acid, 85%
Sodium c h l o r i d e
Balance water, fragrance, d y e s t u f f
Active matter: 4.0%
Toi 1e t C l eaner . Mediurn V i scosi ty-B
Marlazin OL 2
M a r l i p a l 013/99
Acetic Acid*
KNA cumene sulphonate 40 (approx.)
Balance water, fragrance, dyestuff
Active matter: 3.5%
Toi 1e t Cleaner. Powder
Marlon ARL
Amidosulphonic a c i d
Magnesium carbonate
Sodi um b i sulphate
Sodium bicarbonate, fragrance, d y e s t u f f
Active matter: 4.0%
T o i l e t Cleaner. Powder-B
Marlon A 390
C i t r i c a c i d
Sodi um sulphate
Sodium bicarbonate, fragrance, dyestuff
A c t i v e matter: 4.5%
96
4.0
5.0
3.5
t o 100
%
3 . 0
0.5
6.0
3.1
t o 100
96
5 . 0
20.0
5 . 0
6 0 . 0
t o 100
%
5.0
25.0
55.0
t o 100
SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and
Cleaning Agents for Household Purposes
10 Advanced Cleaning Roduct Formulations
T o i l e t Cleaning Block, Extruded-A
Marlon ARL
M a r l i p a l 1618/25 powder
Marlamid M1618
Vestinol C*
Sodium sulphate, d y e s t u f f
Active matter: 42.0%
T o i l e t Cleaning Block. Extruded-B
Marlon ARL
Marlon A390
Lipoxol 6000*
Sodi um tripolyphosphate
Fragrance
Sodium sulphate, d y e s t u f f
Active matter: 59.0%
T o i l e t Cleanino Block. Cast-A
Marl i n a t 242/70
Marlon A375
M a r l i p a l 1618/25 powder
M a r l i p a l 1618/40
Marlamid M 1618
L ipoxol 12000*
Fragrance
Dyestuff
Active matter: 80.8%
T o i l e t Cleaning Block. Cast-B
Marl i pal 013/90
M a r l i p a l 1618/40
M a r l i p a l M 1618
L ipoxol 12000*
Fragrance
Dyestuff
Active matter: 79.0%
* f u r t h e r products o f Huls Ag
96
40.0
4.0
6.0
4.0
t o 100
ss
40.0
30.0
8.0
1.o
5.0
t o 100
%
3.0
13.0
30.0
24.0
15.0
10.0
4.0
1.o
96
12.0
60.0
10.0
13.0
4.0
1.o
SOURCE: Huls Chemical Co.: Basic Formulations o f Detergents and
Cleaning Agents f o r Household Products
2. Dairy, Food and
General Industrial Cleaners
11
12 Advanced CleaningRoduct Formulations
An
Inaredient :
Deionized Water
G l y c o l i c Acid (70%)
Phosphoric Acid (85%)
Avanel S-150
Dairy Mi 1kstone Remover
Acid D i l u t a b l e Concentrate
Wt.%
53.40
28.60
10.00
8 . 0 0
pH (as i s ) : ~ 2 . 0
Appearance: Clear, water-white t o l i g h t - y e l l o w l i q u i d
Procedure:
Charge water t o t h e mixing vessel and s t a r t a g i t a t i o n . Under
a g i t a t i o n , charge t h e G l y c o l i c Acid followed by t h e Phosphoric
Acid. Charge t h e Phosphoric Acid slowly t o avoid s p l a t t e r i n g .
Charge t h e Avanel S-150 and cool t o room temperature. F i l l o f f .
Notes :
m i 1kstone from dai r y equipment .
Brush thoroughly, then r i n s e .
Formula CD-101
This formulation i s h i g h l y e f f e c t i v e a t removing d a i r y
Use concentration i s 1/2 t o 1 ounce per g a l l o n o f water.
Dairy M i 1kstone Remover
Low Cost Acid D i l u t a b l e Concentrate
Inaredient :
Deioni zed Water
Phosphoric Acid (85%)
Gluconic Acid (50%)
Avanel 5-70
pH (as i s ) : < 2 . 0
Appearance: Clear, water-white l i q u i d
Wt.%
55.00
37.50
3 . 5 0
4 . 0 0
Procedure:
To mixing vessel, charge t h e water and s t a r t a g i t a t i o n .
Slowly charge t h e Phosphoric Acid t o avoid s p l a t t e r i n g . Cool
t o room temperature and charge t h e Gluconic Acid and Avanel S-70.
Notes:
A lower cost s u b s t i t u t e f o r PPG/Mazers CD-101 d a i r y cleaner
formulation. I t r e t a i n s t h e general performance a t t r i b u t e s o f
t h e o r i g i n a l formulation.
Use concentration i s 1/2 t o 1 ounce per g a l l o n o f water.
Brush thoroughly, then r i n s e .
Formula CD-102
SOURCE: Mazer Chemicals: Suggested Formulations
&ky, Food and GeneralI . . Cleaners 13
D a i r y P i p e l i n e Cleaner
H i g h A1 k a l ine Low Foam Hvpochlorit e Cleaner
I n n r e d ient:
Deionized Water
Sodium Hydroxide (50%)
Avanel S-74
Sodium Cumene Sulfonate (40%)
Sodium Hypochlorite (12.5%)
pH (as i s ) : 12.5-13.5
Appearance: Clear, 1ight-ye1 low 1i q u i d
Speci f ic G r a v i t y : 1 . 1 5
Wt.%
52.00
20.00
2.50
1 .50
24.00
Procedure:
Hydroxide, and cool t o l e s s than 9OF. Add t h e Avanel 5-74 and
Sodium Cumene Sulfonate. Mix u n t i l c l e a r and add t h e Sodium
Hypochlorite.
Notes:
a l k a l i n i t y o f common p i p e l i n e cleaners r e s u l t i n g i n a s i n g l e
cleaning system.
Shelf s t a b i l i t y o f h y p o c h l o r i t e cleaners i s dependent on t h e
absence o f t r a c e metals. Care should be taken t o i n s u r e good
q u a l i t y water and hypochlorite.
Formula may be adjusted t o use other commercially a v a i l a b l e
concentrations o f Sodium Hypochlorite. Absolute concentration o f
a v a i l a b l e c h l o r i n e i s 3.0%.
SOURCE: Mazer Chemicals: Formulation CD-103
Charge water t o mixing vessel and s t a r t a g i t a t i o n . Add Sodium
This formulation combines a c h l o r i n e cleaner w i t h t h e h i g h
I n s t i t u t i o n a l S t a i n l e s s Steel Cleaner
Components:
Water
50% C i t r i c Acid
Burcosperse LP
Dequest 2000*
Burco NPS 50%
45% KOH
% by Weight
52.75
20.00
5.00
5.00
5.00
12.25
*From Monsanto o r use equivalent product.
Procedure:
Add components i n t h e order l i s t e d . Blend u n t i l uniform
between each a d d i t i o n .
SOURCE: B u r l i n g t o n Chemical Co., I n c . : Suggested Formulation
14 Advanced CleaningProduct Formulations
High Pressure Cleaner for I n d u s t r i a l Use
L i q u i d , transparent, a l k a l i n e
I n q r e d i ents:
A Genapol UD-050
Genapol UD-080
Genopur ASA
KOH (85%)
B Water (ca.5OC)
C Sodi ummetasi 1ic a t e x 5H20
Manufacturing:
I The components o f A a r e mixed.
I 1 Then B i s added.
I11 F i n a l l y t h e components o f C are added
Aquamollin 8C Powder h i g h l y conc.
2,50%
2,50%
3,00%
5.00%
67,00%
10,00%
10,00%
Cleaner f o r M i 1k i n a EauiDment
L i q u i d
I n g r e d i e n t s :
A Tetrapotassiumpyrophosphate
Sodi ummetasi 1i c a t e x 5H20
Sodiumcarbonate
B Water
C Genopur ASA
KOH (85%)
D Genapol UD - 080
Manufacturing:
I One a f t e r another, t h e components o f A
I 1 S t i r one a f t e r another, t h e components
I11 A t l a s t D i s added.
7.00%
5,00%
3,00%
70,00%
5.00%
5,00%
5,00%
are added t o 8.
o f c t o I.
Cleaner f o r Meat P l a n t s
L i q u i d
I n g r e d i e n t s :
A Tetrapotassiumpyrophosphate
B Water
C Genopur ASA
KOH (65%)
D Hostapur SAS 60
Genapol UD - 080
Solvent GX 5
Manufacturing:
I Add one a f t e r another, t h e components o f A t o
I 1 C i s added t o Iby c o n t i n u i n g s t i r r i n g .
I11 A t l a s t t h e components o f D are added.
Potassium water g l a s (40 Be)
5,00%
76,00%
3,50%
3,50%
5.00%
2,00%
3,00%
2,00%
B.
SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Detergents and Cleaning
Agents: Guide Formulations
he,Food and GeneralIndustrial Cleaners 15
Meat Packaaina Plant Cleaner Concentrate
An A l k a l i n e High Foaming Hypochlorite Hard Surface Cleaner
w i t h Improved S a l t Tolerance
Inaredi ent :
Oeioni zed Water
Hostapur SAS-60
Potassi um Hydroxide
Tetrapotassium Pyrophosphate
Mazon 98
Sodium Cumene Sulfonate (40%)
Sodium Hypochlorite (12.5%)
Oeioni zed Water
Wt.%
59.20
2.50
0.90
2.10
5.00
1.30
10.00
19.00
pH (as i s ) : 12.5-13.5
Appearance: Clear-to-translucent, s l i g h t l y viscous, l i g h t -
Speci f ic Gravity: 1.04
Charge t h e water t o a mixing vessel and s t a r t a g i t a t i o n .
yellow l i q u i d .
Procedure:
Charge t h e Hostapur, followed by t h e Potassium Hydroxide and
t h e Tetrapotassium Pyrophosphate. Apply cooling and then add
t h e Mazon 98 and t h e Sodium Cumene Sulfonate. When product
i s l e s s than 85 degrees F. add t h e Sodium Hypochlorite and t h e
balance o f t h e water.
Notes:
This formula i s designed t o be d i l u t e d t o 3-6 ounces per
g a l l o n i n hot water and t o be applied as a foam t o meat packing
house w a l l s and other surfaces. A f t e r an appropriate time, these
surfaces should be thoroughly rinsed.
Shelf s t a b i l i t y o f c h l o r i n e cleansers i s dependent upon t h e
absence o f t r a c e metals. Care should be taken t o insure good
q u a l i t y water and Sodium Hypochlorite.
Revision o f CB-102 t o provide greater s a l t tolerance.
SOURCE: PPG Industries, I n c . : Formula CB-102-A
16 Advanced CleaningProdccct Formulations
Steam Cleaners
C1eaner-Li ght Duty
Inaredients :
Sodi urn Metasi 1ia t e
Sodi um T r i p o lyphosphate
Trisodium Phosphate
Aerosol 22 Surfactant
T r i t o n CF-10
Inqredients:
Sodi urn Orthosi 1i c a t e
Sodium Carbonate
T r i sodi urn Phosphate
Aerosol 22 Surfactant
T r i t o n CF-10
C l eaner-Medi urn Duty
% by Weiaht
30.0
58.0
10.0
1 .o
1.o
% by Wei aht
33.0
20.0
44.0
1.5
1.5_ _
Cleaner-Heavy D u t y (For O i l y S o i l s )
% by WeiahtInaredients:
Aerosol 22 Surfactant 7.0~ ~~~
Sodium M e t a s i l i c a t e
Dowanol DE
Water
Inaredients:
Aerosol 0s Surfactant
Soda Ash
Sodi urn Hydroxide
Sodium M e t a s i l i c a t e (5H20)
Sodi um T r i polyphosphate
Cleaner-General Purpose
Use 0.5 t o 2.0 0 2 . t o 1 a a l l o n o f water.
35.0
3.0
55.0
% by Weight
10.0
35.0
15.0
30.0
10.0
_ _ _
Cleaner-Lipht Duty f o r S o f t Metals
Ingredients: % by Weiaht
Aerosol 0s Surfactant 7.14~ ~~~
Sodium Sesquicarbonate 92.86
Inpredients: % by Weiaht
Cleaner-General Purpose
Sodi um Metasi 1icate
Aerosol 22 Surfactant 5.0
Water 73-78
15-20
Aerosol 0s Surfactant 2- 3
Cleaner-Compound
Inaredi ents : % by Weiaht
Sodi urn Hydroxide 30.0
Borax 30.0
D i sodi um Phosphate 15.0
Aerosol C-61 Surfactant 5.0
Add t h e desired amount o f cleaner t o water which has been
preheated t o 140F.
SOURCE: Cytec I n d u s t r i e s I n c . : Suggested Formulations
Soda Ash 20.0
3. Degreasers
17
18 Advanced CleaningProduct Formulations
d-Liaonene Microemulsion Cleaner/Desreaser
Burco TME
Burco FAE
d-Li monene
Water
11 p a r t s
11 p a r t s
16 p a r t s
62 p a r t s
Mix i n order l i s t e d ; add water slowlv. Product w i l l
No co-solvent i s required when mixed i n proprortions given
thicken, then break as water i s added.
above. Produces a c l e a r product. Burco FAE imparts corrosion
resistance i n a d d i t i o n t o emulsion c h a r a c t e r i s t i c s .
but r a t i o s o f t h e other a c t i v e s must remain s i m i l a r t o the
above. Example :
To make a more concentrated product, l e s s water can be used,
TME
FAE
d-Limonene
Water
22 p a r t s
22 p a r t s
32 p a r t s
24 p a r t s
High a c t i v e products can reach a g e l - l i k e v i s c o s i t y , but can
be t h i nned w i t h Isopropanol and Butyl Propyl sol v.
SOURCE: Burlington Chemical Co., I n c . : Suggested Formulation
Concentrated d-Limonene Biodearadable Deareaser
A Natural All-Purpose Micro-Emulsion Cleaner o r Concentrate
Inaredi ent :
d-Limonene. Grade M
Mazclean EP
Deionized Water
Wt.%
30.00
20.00
50.00
pH (as i s ) : 9.0-10.0
Appearance: Clear, l i g h t - y e l l o w l i q u i d
S p e c i f i c Gravity: 0.97
Odor: Sweet Orange
Procedure:
Charge t h e d-Limonene and Mazon 245-103 t o an apprDopriate
mixing vessel and s t a r t a g i t a t i o n . Under good a g i t a t i o n , slowly
add t h e water and mix u n t i l s o l u t i o n i s c l e a r .
Notes :
duty use, product should be sprayed "as i s " onto t h e o i l y
substrate, followed by a water r i n s e .
SOURCE: PPG I n d u s t r i e s , Inc.: Formulation CS-101
This formulation may be used "as i s " o r d i l u t e d . For heavy-
Degreasers 19
Solvent Deareasi rig
The s o l u b i l i t y o f Aerosol OT Surfactant i s extremely high i n
a l l solvents used f o r degreasing. I t w i l l d i s s o l v e e a s i l y a t
room temperature i n most cases. I f heating i s required f o r
s o l u b i l i z a t i o n , t h e s o l u t i o n w i l l be s t a b l e upon r e t u r n t o room
temperature.
As an example, Aerosol OT-75% i s soluble t o over 50% a t room
temperature i n carbon t e t r a c h l o r i d e , b u t naphtha solvent requires
heating. Both are c l e a r s o l u t i o n s a t room temperature. The
presence o f t h e water i n Aerosol OT-75% p o r t i o n i s an a i d i n
t h e removal o f any water-soluble p a r t i c l e s present i n t h e work
being degreased.
Formulations such as:
Aerosol GPG o r OT-75%
High Flash Naphtha
0.5%
99.5%
can be used f o r l i g h t - d u t y cleaning, t h e solvent removing t h e
o i l s , waxes, etc. and t h e Aerosol OT a i d i n g not o n l y i n t h e
penetration o f t h e covering material, b u t a l s o i n d r a i n i n g .
This type o f cleaner can be sprayed on, brushed on, o r t h e
work can be immersed i n t o i t followed by a r i n s e .
Heavy-Duty Degreasing:
To remove heavy l u b r i c a t i n g and preservative o i l s and
greases, many solvents may be used t o s p e c i f i c needs. Aerosol
GPG Surfactant w i l l be found t o be soluble i n a l l o f these
solvents. A t y p i c a l formulation used i s :
Aerosol GPG o r OT-75%
Kerosene
1- 3%
97-99%
Preparation i s by simple mixing. T r i - o r tetrachloroethylene,
high f l a s h naphtha o r other s u i t a b l e solvents can be s u b s t i t u t e d
f o r t h e kerosene.
Carbonaceous deposits can be removed by d i p p i n g i n formula-
t i o n s such as:
Kerosene
Perchloroethylene
Carbon Tetrachloride
Cresyl ic Acid
Aerosol GPG o r OT-75%
40%
30%
16%
10%
4%
Normally, 3 g a l l o n s o f t h e above are added t o 1 g a l l o n of
water which, f l o a t i n g on t h e surface, minimizes l o s s o f solvent.
The work t o be cleaned i s immersed i n t h e solvent phase f o r
time periods o f a few minutes t o several hours, i f required,
t o o b t a i n cleanliness. Upon removal from t h e solvent layer, and
a s h o r t r i n s e i n t h e aqueous l a y e r , t h e cleaned a r t i c l e s are
rinsed, d r i e d o r c a r r i e d onto t h e next operation.
SOURCE: Cytec I n d u s t r i e s , Inc.: Suggested Formulations
4. Dishwashing Detergents
20
Dishwashing Detergents 21
C1ear L i q u i d D ishwash
W i t c o l a t e AE-3
Witco 1298 S o f t Acid
Sodi um Hydroxide, 50%
W i tconate SXS L i q u i d
W i tcami de 5195
Phosphoric Acid
Water
% by Weiqht
12.5
19.0
5.2
13.5
2.5
q.s. t o pH = 6.4-6.8
q.s. t o 100
Blending Procedure
between each a d d i t i o n .
Formula 108
B1end ingredients in t h e order shown, m i x i ng thoroughly
Non-Chlori nated Machine D i shwashi na Compound, L i q u i d
% by Weight
Water, D.I. 79.5
Sodi um Tripolyphosphate 2.0
Versene 220, Powder 1.0
Sodium Gluconate 1 .o
Sodium M e t a s i l i c a t e , Pentahydrate 7.0
Caustic Soda 50% 8.5
Petro ULF L i q u i d 1.0
Blending Procedure:
between each a d d i t i o n .
Formula 109
Blend i n g r e d i e n t s i n t h e order shown, mixing thoroughly
Clear, Colorless Manual Dish Wash
Water, D.I.
W i t c o l a t e ES-3
Rewoteric AM 8-14
Ethanol
Sodium Chloride
% by Weiqht
57.5
31.2
5.0
3.0
3.3
Blending Procedure:
between each a d d i t i o n .
Comment :
B1end ingredi ents in t h e order 1isted. Dissolve completely
Rewoteric AM 8-14; Grease c u t t e r and foam booster.
Formula 132
SOURCE: Witco Corp.: Suggested Formulations
22 Advanced Cleaning Roduct Formulations
Dish Washina Agent
Clear, l i q u i d , 25% WAS
Alkanesulphonate:ethersulfate=4.1
Ingredients:
A Hostapur SAS 60
B Water
Genapol ZRO l i q u i d
Preservative
Dye
Perfume
Hoe S 3924
Manufacturing:
One a f t e r another, t h e components o f B are added t o A.
Tests:
V i s c o s i t y (mPas) : 90
Cloud p o i n t : <-5C
33.36%
17.90%
47.50%
0.10%
q.s.
0.20%
1.00%
Dish Washin A ent
c l e a r , liquid: 2:% WAS
alkanesulphonate:ethersulphate=4.1
Ingredients :
A Hostapur SAS 60
B Water
Genapol ZRO l i q u i d
Preservative
W e
Perfume
Hoe S 3924
Manufacturing:
One a f t e r another, t h e components o f B are added
Tests
V i s c o s i t y (mPas): 410
Cloud p o i n t : <-5C
33.30%
17.90%
44.50%
0.10%
q.s.
0.20%
4.00%
t o A.
Dish Washing Aaent
Clear, l i q u i d , 30% WAS
alkanesulphonate:ethersulphate=4.1
Ingredients:
A Hostapur SAS 60 40.00%
Genapol ZRO l i q u i d 21.40%
B Water 30.30%
Preservative O.lO%
Dye q.s.
Perfume 01.20%
Manufacturing:
Tests:
One a f t e r another, t h e components o f 0 are added t o A.
V i s c o s i t y (mPas): 330
Cloud p o i n t : <-5C
SOURCE: Hoechst Aktiengesellschaft: Detergents and Cleaningal
Agents: Guide Formulations
DishwashingDetergents 23
Dish Washi na Agent
Clear, l i q u i d , 30% WAS
alkanesulphonate:ethersulphate=4:1
I n a r e d i e n t s :
A Hostapur SAS 60
Genapol ZRO l i q u i d
8 Water
Preservative
Dye
Perfume
Hoe S 3924
Manufacturing:
Tests:
One a f t e r another, t h e components o f 0 are added
V i s c o s i t y (mPas): 610
Cloud p o i n t : <-5C
Powder f o r Automatic Dishwashina Machines
40.00%
21.40%
34.30%
0.10%
q.s.
0.20%
4.00%
t o A.
I n a r e d i e n t s :
A Genapol 2908
B Sodiummetasilicate x 5H20
C Sodiumcarbonate
Sodi umdichloroi socyanurate
Thermphos NW
Manufacturi no:
1;. 00%
52.00%
10.00%
2.00%
35.00%
I Spray A on 0 .
I 1 One a f t e r another, t h e components o f C a r e added t o 1.
A p p l i c a t i o n :
SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Detergents and Cleaning
1-2 g detergent/L dishwashing l i q u o r
Agents: Guide Formulations
24 Advanced Cleoning Product Formulations
Dishwashing Deteraent. Medium Viscositv. Basis Marlon A-A
%
Marlon A 350 30.0
Marl inat 242/70 5.7
D i o n i l OC 1.o
Na cumene sulphonate 40 1.o
Balance water, fragrance, dyestuff, preservative,
sodium c h l o r i d e t o 100
A c t i v e matter: 20.0%
Dishwashing DeterQent. Medium Viscositv. Basis Marlon A-B
%
Marl inat 242/70 4.3
sodium c h l o r i d e t o 100
Marlon A 365 18.5
Balance water, fragrance, d y e s t u f f , preservative,
A c t i v e matter: 15.0%
D ishwashi na Detergent, Medi urn V i m s i t y . B a s i s Marlon AS3-A
%
Marlon AS3 10.5
Caustic soda, 50% (approx.) 2.6
Marl ip a l 013/120 2.7
Balance water, fragrance, dyestuff, preservative,
sodium c h l o r i d e t o 100
A c t i v e matter: 14.0%
D i shwashi n Q Detergent, Medi urn Viscosity. Bas4s Marlon AS3-B
%
Marlon AS3 4.5
Caustic soda, 50% (approx.) 1.1
M a r l i n a t 242/70 4.5
Balance water, fragrance, dyestuff, perservative,
sodium c h l o r i d e t o 100
A c t i v e matter: 8.0%
SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and
Cleaning Agents f o r Household Purposes
M w h i n g Detergents 25
D i shwashi nq Detergent, Medi um V i s c o s i t y . Basis Marlon PS-A
%
Marlon PS 65 49.0
Marlamid DF 1218 3.0
Ethanol * 4.0
Balance water, fragrance, d y e s t u f f , p r e s e r v a t i v e ,
Marl in a t 242/70 11.5
sodium c h l o r i d e t o 100
A c t i v e m a t t e r : 43.0%
D i shwashi ng Detergent, Medi um V i s c o s i t y , Basis Marlon PS-B
%
Marlon PF 40 71.3
Balance water, fragrance, d y e s t u f f , p r e s e r v a t i v e ,
Marlamid DF 1218 1 . 5
sodium c h l o r i d e t o 100
A c t i v e m a t t e r : 30.0%
* f u r t h e r products o f Huls AG
D i shwashi ng Detergent, Medium V i scos t y . Basis Marlon Compounds-A
%
Marlon AFO 40 46.3
Marlamid D 1885 1.5
Balance water, fragrance, d y e s t u f f , p r e s e r v a t i v e ,
sodium c h l o r i d e t o 100
A c t i v e m a t t e r : 20.0%
D i shwashi ng Detergent, Medi um V i s c o s i t y , Basis Marlon Compounds-B
%
Marlon AFO 50 30.0
Balance water, fragrance, d y e s t u f f , p r e s e r v a t i v e ,
sodium c h l o r i d e t o 100
A c t i v e m a t t e r : 15.0%
SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and
Cleaning Agents for Household Purposes
26 Advanced CleaningRoduct Formulations
D i shwashi n Q Deteraent . Powdered. SDrav M i x i na Process-A
%
Marlox FK 64 1.o
Sodium tripolyphosphate 40.0
Sodium m e t a s i l i c a t e pentahydrate 35.0
Sodium carbonate, dehydrated 22.0
Sodium dichloroisocyanurate 2.0
A c t i v e matter: 1.0%
A p p l i c a t i o n : Use 3-5 g/1 water (depending on water hardness)
D i shwashi ng Detergent, Powdered, Spray M i x i ng Process-I3
Marlox B 24/80
Sodium tripolyphosphate
Sodium m e t a s i l i c a t e pentahydrate
Sodium m e t a s i l i c a t e , dehydrated
Sodium carbonate, dehydrated
Sodi um d i c h l o r o i socyanurate
Phosphonate HEDP, e.g. Sequion 10
Sodi um hydroxide
A c t i v e matter: 1.0
A p p l i c a t i o n : Use 3-5 g/1 water
Na 2
%
1.o
25.0
25.0
20.0
15.0
2.0
2.0
10.0
(depending on water hardness)
D i shwashi ng Detergent, Powder, Phosphate-Free, Spray M i x i ng
Process-A
Marlox MO 154
Sodi um c i t r a t e d i hydrate
Sodium d i s i l i c a t e granulate
Polycarboxylate, e.g. Sokalan PA 40 granulate
Sodium perborate monohydrate
Tetraacetylethylenediami ne (TAED)
Enzyme Esperase
Sodium sesquicarbonate
A c t i v e matter: 2.5%
%
2.5
35.0
25.0
5 . 0
15.0
4.0
2.0
t o 100
Dishwashing Detergents, Powder, Phosphate-Free, Spray Mixing
Process-I3
Marlox MO 154
Sodium carbonate, dehydrated
Polycarboxylate, e.g. Permulsin SP
Phosphonate HEDP, e.g. Sequion 10 Na 2
Sodi um metasi 1i c a t e
A c t i v e matter: 2.0%
%
2.0
15.0
10.0
5.0
t o 100
SOURCE: Huls America, I n c . : Basic Formulations o f Detergents
and Cleaning Agents f o r Household Purposes
DishwashingDetergents 27
DishwashtnLDeterpent (4096 Sol ids)-A
Witconate 1260 S l u r r y
W i t c o l ate LES-6OA
W i tcami de 128T
Water
% by W e i m
37.0
17.5
4.0
34.0
Blending Procedure:
between each a d d i t i o n .
Blend ingredients i n t h e order shown. mixing thoroughly
Dishwashing Deteraent (40% Solids)-8
W i tconate 45LX
W i tconate SXS L i q u i d
Witcolate LES-6OA
W i tcamide 128T
Water
% bv Weiqht
59.0
6.0
17.5
4.0
16.5
Blending Procedure:
between each addition.
Formula 105
Blend ingredients i n t h e order shown. mixing thoroughly
Hand D i shwashi ng L i q u i d
W i tconate AOS
Witcolate S-1285C
Witcamide 128T
Water
% by Weiaht
60.0
10.0
4.0
26.0
Blending Procedure:
between each a d d i t i o n .
Formula 106
SOURCE: Witco Corp.: Suggested Formulations
Blend ingredi ents in the order shown, m i x i ng thorough1y
28 Advanced Cleaning R&t Formulations
Dish Wash w/Ami ne Oxide/LABS/SLES
Water, D . I .
Witconate 30DS
Varox 1770
W i t c o l ate SE-5
Blending Procedure:
between each a d d i t i o n . Add Ethanol as needed t o
Typical Properties:
Viscosity, cps: 620
Solids: 16.8%
pH: 9.12
Formula 117
Add ingredients i n order shown and d i s s l v e
Dish Wash w / h i ne Oxide/LABS/ALES
Water, 0.1.
W i tconate 30DS
Varox 1770
Witcolate LES-6OA
Ethanol
% by Weiqht
62.9
13.7
5.3
18.1
ompl e t e l y
lower v i s c o s i t y .
% by Weiaht
70.0
13.8
3.1
8.2
5.0
B1endi ng Procedure:
Add ingredients i n order shown and dissolve completely
between each a d d i t i o n . A c i d i f y w i t h C i t r i c Acid t o pH = 6.5.
Typical Properties:
Viscosity, cps: 4
Solids: 10.1%
pH: 6.68
Formula 118
Dish Wash w/Ami ne Oxide/LABS
Water, D . I .
W i tconate 30DS
Varox 1770
Ethanol
% by Weiaht
69.8
20.3
4.9
5.0
Blending Procedure:
Add ingredients i n order shown and dissolve completely
between each a d d i t i o n .
Typical Properties:
Viscosity, cps: 4
Solids: 7.8%
pH: 9.16
Formula 119
SOURCE: Witco Corp.: Suggested Formulations
DishwashingDetergents 29
High-Performance Hand Dish Detergent
Formula DW-0013
Water
SXS, 40
Caustic Soda, 50%
Dodecylbenzene s u l f o n i c Acid
Rhodapex NA-61
A1 kamide DC-212/S
Rhodacal A-246/L
Rhodasurf 25-9
C i t r i c Acid (50%). t o pH 8
Ethanol SD-3A
Preservative
Fragrance
Dye
Wt.%
3.0
6.6
25.0
8.0
3.0
10.0
6.0
Q.S.
2.0
0.1
To 100
-
Procedure
Add t h e ingredients i n t h e order l i s t e d w i t h mixing. Mix
u n t i l uniform a f t e r each a d d i t i o n . C i t r i c Acid and Caustic Soda
are used f o r pH adjustment.
Physical ProDerties
Appearance: Clear gold l i q u i d , dyed t o preference
pH. as i s : 8
Viscosity: 400 cps
S p e c i f i c Gravity: 1.05
M i l d L i a u i d Hand Dish Detergent
Water
Caustic Soda (50%)
Dodecylbenzene s u l f o n i c acid
Miranol CS Conc.
A1kamide DC-212/S
Rhodasurf 25-9
Cheelox BF-13
C i t r i c Acid (50%). t o pH 8
Fragrance
Dye
Wt.%
To 100
3
12
15
3
3
0.2
Q . S .
-
-
Procedur e
u n t i l uniform a f t e r each addition. C i t r i c a c i d and c a u s t i c
soda are used f o r pH adjustment. Dissolve t h e dye i n water
before a d d i t i o n .
Phvsical Properties
Appearance: Clear gold l i q u i d , dyed t o preference
pH. as i s : 8
S p e c i f i c Gravity: 1.04
V i s c o s i t y : 150 cps
Add t h e ingredients i n t h e order l i s t e d w i t h mixing. Mix
SOURCE: Rhone-Poulenc Surfactants & S p e c i a l t i e s : Formulas
30 Advanced Cleaning Product Formulations
S t a r t i n g Formulations f o r Home Machine Dishwashinq Detergents
8.7% Phosphorous(A)
Compounds:
BASF S u r f a c t a n t *
Sodium t r i p o l y p h o s p h a t e
B r i t e s i 1 H24 hydrous sodium s i 1i c a t e * *
Sodium s u l f a t e
Sodium carbonate
C h l o r i n a t e d isocyanurate***
Water
8.7% Phosphorous(B1
Coflpounds :
BASF S u r f a c t a n t *
B r i t e s i l H24 hydrous sodium s i l i c a t e * *
Sodi um s u l f a t e
Sodium carbonate
C h l o r i n a t e d isocynaurate***
Sodium t r i p o l y p h o s p h a t e hexahydrate
Nonphosphate
Compounds2
BASF S u r f a c t a n t *
Sokalan PABOCL
B r i t e s i l ti24 hydrous sodium s i l i c a t e * *
C h l o r i n a t e d t r i s o d i u m phosphate
Sodium s u l f a t e
Sodium carbonate
Sodi um c i t r a t e d i hydrate
?4 b y WSi¶h_t.
3
34
17
15
19
2
10
% -by__W!sht
3
17
1 4 . 5
20
1 . 5
44
”/._ bY. W!%lb t
4 . 0
2****
20
1 2 . 5
30
1 . 5
30
* P l u r o n i c , P l u r a f a c , and I n d u s t r o l s u r f a c t a n t
**Other r a t i o s o f Si02 can be used. L i q u i d s i l i c a t e s can a l s o
be used i n p l a c e o f powders.
***Such as ACL-59.
****Active
M i x i n g Procedures:
gent, t h e f o l l o w i n g process i s suggested f o r t h e mixing of raw
mater ia1s :
1 . Spray a m i x t u r e o f t h e s u r f a c t a n t and water ( o r s u r f a c t a n t ,
To achieve maximum c h l o r i n e s t a b i l i t y o f t h e formulated d e t e r -
water, and l i q u i d s i l i c a t e ) onto t h e phosphate b u i l d e r s , soda
ash, o r m i x t u r e t h e r e o f . S t i r continuously w h i l e spraying.
w i t h simul-T h i s process r e s u l t s i n h y d r a t i o n o f t h e b u l d e r s
taneous adsorption o f t h e s u r f a c t a n t .
2. Add t h e c h l o r i n e - c o n t a i n i n g compound and any f i l
m i x t u r e and continue mixing u n t i l t h e e n t i r e m i x
homogeneous. A d r y , f r e e - f l o w i n g granular produc
obtained w i t h t h i s method.
SOURCE: BASF Corp.: Suggested Formulations
e r s t o t h e
u r e i s
should be
-washing Detergents 31
L i g h t Duty L i q u i d Deteraents
L i q u i d detergents based on P i l o t Calsoft, Calsuds and Calfoam
s u r f a c t a n t s produce safe, e f f e c t i v e suds w i t h e x c e l l e n t grease-
c u t t i n g p r o p e r t i e s f o r hand dishwashing. Detergents containing
Calamide C are e s p e c i a l l y m i l d t o s e n s i t i v e skin.
Water
C a l s o f t L-60
Calfax DB-45
Cal foam EA-603
Calamide C
C i t r i c Acid
Perfume
Ammonium Chloride
Dye
Calsuds A
Cal foam ES-303
Water*
C i t r i c Acid
Perfume and Color
C a l s o f t L-40
Cal foam EA-603
Calamide C
P i l o t SXS-40
Water*
C i t r i c Acid
Perfume and Color
Calsuds CD-6
Cal foam EA-603
P i l o t SXS-40
Cal s o f t LAS-99
Water*
C i t r i c Acid
Perfume and Color
P i l o t Formula #LDL-010-01
% bv Weipht
61 .OO
19.80
9.90
5.00
3.00
0.10
0.10
0.10
1 .oo
P i l o t Formula #LDL-013-01
% by Weiaht
70.00
10.00
20.00
Q.S. pH 7
Q . S .
P i 1o t Formul a #LDL-005-01
% bv Weiaht
40.00
10.00
6.00
12.50
26.50
Q.S. pH 7
Q . S .
P i 1o t Formula #LDL-015-01
% bv Weight
25.00
10.00
8.80
6.00
50.20
Q.S. pH 7
Q . S .
*May be o p a c i f i e d by r e p l a c i n g 1% o f water w i t h 1% l a t e x
opaci f ie r . Opaci f i e r should be d i 1uted w i t h water before
a d d i t i o n .
SOURCE: P i 1o t Chemi c a l Co. : Household C1eaner Formula t i on8
32 Advanced CleaningPromcct Formulations
L i g h t Duty Liauid. Premium Hand Dishwash
Water, D . I .
W i t c o l a t e SE-5
W i tconate 1260 S1u r r y
W i tcami de 128T
Petro LEA L i q u i d
Sodium S u l f a t e
Ethanol
Formal i n
Perfume, Dye
% by Weight
30.2
36.7
5.0
1.9
2.6
1.8
0.1
q . s .
21.7
Blending Procedure:
using C i t r i c Acid.
Typical P r o p e r t i es :
Blend i n g r e d i e n t s i n t h e order l i s t e d . Adjust pH = 6.5-7.0
V i s c o s i t y , cps: 230
Appearance: Clear L i q u i d
Formula 113
L i g h t Duty L i q u i d
Water, D. I.
W i t c o l a t e SE-5
Witconate 1260 S l u r r y
W i tcami de 128T
Petro LEA L i q u i d
Sodium S u l f a t e
Sodium Chloride
Formal in
Perfume, Dye
Economy Hand D i shwash
% by Weiqht
73.6
8.3
13.5
1.9
1.o
0.6
1.o
0.1
q . s .
81ending Procedure:
using C i t r i c Acid.
Typi c a l P r o p e r t i es :
Blend i n g r e d i e n t s i n t h e order l i s t e d . Adjust pH = 6.5-7.0
V i s c o s i t y , cps: 180
Appearance: C1ear L iqui d
Formula 115
SOURCE: Witco Corp.: Suggested Formulations
LXshwashing Detergents 33
Water
Caustic Soda (50%)
L i a u i d Hand Dish Detergent
Formula DW-0016
Wt.% Wt.% Wt.%
To 100 To 100 To 100
2.5 3.3 4.1
Dodecylbenzene sui f o n i c a c i d 10 13
Rhodapex NA-61 4.5 4.5
A1kamide DC 212/S 1 2
Cheelox BF-13 0.5 0.5
C i t r i c Acid (50%), t o pH 8 Q.S. Q . S .
Sodium c h l o r i d e 1 1
Fragrance - -
Dye
Opaci f ie r (Morton) - -
- -
16
5
3
0.5
Q.S.
1
Procedur e
Add t h e ingredients i n t h e order l i s t e d , w i t h mixing. Mix
u n t i l uniform a f t e r each addition. C i t r i c a c i d and c a u s t i c soda
are used f o r pH adjustment. Sodium c h l o r i d e b u i l d s v i s c o s i t y .
Dissolve i t i n water before a d d i t i o n .
Dissolve t h e dye i n water before a d d i t i o n . I f o p a c i f i e r i s
used, i t should be d i l u t e d w i t h water before addition. A l l pH
adjustments must be completed before t h e o p a c i f i e r i s added.
Phvsical ProDertieg
Appearance: Liquid, colored and o p a c i f i e d t o preference
pH. as i s : 8
Viscosity: 200-400 cps
Speci f ic Gravi t y : 1.02+-0.05
pH, 1%: 7.2
SOURCE: Rhone-Poulenc Surfactants & S p e c i a l t i e s : Formula
34 Advanced CleaningProduct Formulations
Mechanical D ishwashi ng Detergent
Chlorinated
Formula DW-0009
Sodium Carbonate ( L t . Density)
Antarox BL-330
Sodium Tripolyphosphate. Powder
Sodium M e t a s i l i c a t e Pentahydrate
Clearon CDB (FMC)
Wt.%
41 . O
2.0
34.0
20.0
3.0
ProcedurQ
Add t h e sodium carbonate t o t h e mixer. Spray on t h e Antarox
EL 330. Add t h e remaining ingredients i n t h e order l i s t e d . Mix
u n t i 1 uniform.
Phvsical ProDertieg
Appearance: White, free-flowing powder
pH (1%): 11.2
S p e c i f i c Gravity: 0.70
Uechanic a l D ishwashing DeterQent L isuid
Formula DW-0010
Igepal CO-730
Gantrez AN-149
Potassium Hydroxide (45% Active)
Sodium S i l i c a t e (46% Active)
Antarox BL-330
Tetrapotassium Pyrophosphate (60% Active)
Water
Wt.%
0.5
1.o
3.0
17.0
3.0
63.3
12.2
Proctndur e
1. Add Gantrez AN-149 t o Igepal CO-730/water mixture and s t i r
a t room temperature u n t i l dissolved. Heat t o 45-50C i f not
t o t a l l y i n s o l u t i o n .
2. Maintain heat a t 45C and add r e s t o f ingredients i n d i v i d u a l l y .
Physical P r o m r t ieg
pH (as i s ) : 13.2
pH (1%): 10.4
V i s c o s i t y : 1060 cps
S p e c i f i c Gravity: 1.14
SOURCE: Rhone-Poulenc S p e c i a l t i e s 6 Surfactants: Formulas
DishwashingDetergents 35
L i a u i d
Formula DW-0008
Rhodacal A-246/L
Rhodapex MA-460
Alkamide DC-212/S
Sodium Xylene Sulfonate (40%)
O p a c i f i e r (Morton)
Water
C i t r i c Acid t o pH 6.5-7.5
Perfume and Color
Wt.%
60.0
10.0
5.0
4.0
1.0
20.0
Q . S .
P.S.
Procedure
1. Charge water and sodium xylene sulfonate t o vessel equipped
w i t h a g i t a t i o n .
u n t i 1 uniform.
2. Add Rhodacal A-246/L and Rhodapex MA-360 t o vessel and mix
3. Add Alkamide DC-212/S and mix as above.
4. Adjust pH 6.5-7.5 w i t h c i t r i c acid.
5. Add o p a c i f i e r ( o p t i o n a l ) , perfume and colorant, as desired.
Physical P r o m r t i e s :
Appearance: Clear gold l i q u i d , dye and opacify t o preference.
pH, as i s : 6.5-7.5
S p e c i f i c Gravity: 1.02-1.04
V i s c o s i t y : 200-300 cps
SOURCE: Rhone-Poulenc Surfactants EL S p e c i a l t i e s : Formula
36 Advanced CleaningProduct Formulations
S t a r t i n a Formulations f o r Commercial Machine Dishwashing
Deteraents
Nonchlorine/Noncaustic
BASF Surfactant*
Sodium tripolyphosphate
Sodium carbonate
Sodium s u l f a t e
Sodium m e t a s i l i c a t e pentahydrate
Water
Noncaustic
BASF Surfactant*
Sodium tripolyphosphate
Sodium carbonate
Sodium m e t a s i l i c a t e pentahydrate
Chlorinated isocyanurate**
Water
C h l o r i n e K a u s t i c
BASF Surfactant*
Sodium tripolyphosphate
Sodium carbonate
Sodium m e t a s i l i c a t e pentahydrate
Chlorinated isocyanurate**
Sodium hydroxide (90%)
Water
*Pluronic, Plurafac, I n d u s t r o l surfactant
**Such as ACL-59
% by Weight
3
34
22
11
25
5
% bv Weiaht
3
31.5
20
31.5
1.5
12.5
% bv Weiqht
3
34
18
22.5
2.5
15
5
M i x i ng Procedures :
1. Thoroughly mix t h e phosphate and carbonate.
2. I n a separate container, mix t h e surfactant and water. Next,
spray th'is l i q u i d onto the phosphate/carbonate mixture. Mix
continuously w h i l e spraying, and continue mixing u n t i l t h e
l i q u i d i s completely adsorbed and t h e mixture i s homogeneous.
3. Add t h e m e t a s i l i c a t e , s u l f a t e , and/or caustic and mix.
4. F i n a l l y , add t h e c h l o r i n a t e d cyanurate and mix thoroughly.
Note:
maximum c h l o r i n e s t a b i l i t y .
SOURCE: BASF Corp.: Suggested Formulations
The mixing sequence given above i s necessary f o r maintaining
5. General Purpose Cleaners
37
38 Advanced CleaningRoduct Formulatioiu
A11 Purpose Cleaner
Mackam 2CSF
Tetrapotassium Pyrophosphate
T r i sodium Polyphosphate
KOH (45%)
Low Rosin T a l l O i l F a t t y Acid
Deioni zed Water
Weight.%
10.0
5.0
5.0
4.0
10.0
66.0
Procedure:
1. Dissolve Tetrapotassi um Pyrophosphate and T r i sodi um Po
2. Add KOH.
3. Disperse T a l l O i l F a t t y Acid.
4. Cool t o 50C and slowly add Mackam 2CSF.
phosphate a t 70C.
PhosDhate Free A l l PurDose Cleaner
Sodium M e t a s i l i c a t e Pentahydrate
Mackamine C-10
Caustic Soda (50%)
Mackam 2CYSF
Tetrasodium EDTA (40%)
Deioni zed Water
Y-
Weight .%
22.0
9.0
2.0
4.0
1.o
62.0
Procedure:
1. Add Sodium M e t a s i l i c a t e and Tetrasodium EOTA t o water and
2. Add Mackamine C-10 and Caustic Soda (50%).
3. Add Mackam 2CYSF and blend u n t i l c l e a r .
heat t o 60C.
Bathroom T i l e Cleaner
Sodium Hypochlorite (35%)
Mackamine LO
Tetrasodi um EDTA
Deioni zed Water
Procedure:
Add components t o water and blend u n t i l c
SOURCE: McIntyre Qroup Ltd.: Suggested Formu
Wei aht .%
4.7
5.0
1.o
89.3
ear.
a t i one
Water
Sodi um Carbonate
Tetrasodium EDTA, 40%
W i t c o l a t e 7031
Sodium Chloride
W i tconate SXS L i q u i d
C i t r i c Acid, 50%
A l l Purgose Cleaner
% bv Weiqht
61.2
5.0
6.0
15.0
10.8
2.0
9.s. t o pH=11.0-11.5
Blending Procedure:
Typical Properties:
V i s c o s i t y , cps: Water t h
S o l i d s : 25.6%
pH, as i s : 11.2
Blend i n g r e d i e n t s i n t h e order l i s t e d .
n
SOURCE: Witco Corp.: Formula 518
All-PurDose Cleaner
Eastman E8 solvent
Na4EDTA*
Nonionic s u r f a c t a n t * *
Isopropyl alcohol
Water
*Tetrasodi um e t h y l enedi ami n e t e t r a c e t a t e
**Such as Neodol 23-7 alcohol ethoxylate
N-95 ethoxylated nonylphenol (Texaco).
Hard-surface Cleaner
Eastman DB solvent
Anionic surfactant***
N a4EDTA* ***
Ammonium Hydroxide (28%)
Water
2.
2
1
90
39%)
S h e l l ) o r Sulfon
% bv Weisht
3.2
7
3
5
3
C
% bv Weiaht
7.0
1 .o
1.25
2.0
88.75
***Such as Rhodapex CO-433 (Rhone-Poulenc)
****Tetrasodium ethylenediaminetetraacetate (39%)
SOURCE: Eastman.Chemica1 Co.: Eastman EB and D0 Solvents f o r
Cleaners: Suggested Formulations
GeneralPurpose Cleaners 39
40 Advanced CleaningProduct Formulations
A11-Purpose C1eaner-A
%
Marl i p a l 24/90 7.5
Methoxypropanol 6.0
Sodium carbonate 3.0
N i t r i l o t r i a c e t a t e , 40% 0 . 4
Balance water, fragrance, dyestuff, preservative,
sodium c h l o r i d e t o 100
Active matter: 7.5%
V i s c o s i t y : L i q u i d
A11-PUrDOSe C l e a n e r 4
%
M a r l i p a l 1012/6 1.o
M a r l i n a t 242/28 10.0
Sodium carbonate 3.0
Sodium c i t r a t e dihydrate 1.5
Sodium t a r t r a t e 1.5
Balance water, fragrance, dyestuff, preservative,
sodium c h l o r i d e t o 100
Active matter: 3.8%
V i s c o s i t y : Low
Al1-PUrDOSe Cleaner. w i t h Y i c r o b i c i d a l Prooerties. Liauid-B
Marl ip a l 013/99
Warlazin KC 21/50
Nit ri1o t riacetate, 40%
Sodium carbonate
Balance water, fragrance, d y e s t u f f
%
8.0
5.0
0.5
3.0
t o 100
Active matter: 9.7%
SOURCE: Huls America, Inc.: Basic Formulations o f Detergents
and Cleaning Agents f o r Household Purposes
GeneralPurpose Cleaners 41
A-Jl-Purpose Cleaner, Liquid-A
Marlon PS 65
Marl ip a l 013/69
Coconut f a t t y a c i d
C i t r i c terpene
Methoxypropanol
Sodium carbonate
Sodium c i t r a t e d i h y d r a t e
Ethylenediamine t e t r a a c e t a t e , 40%
Balance water, fragrance, d y e s t u f f , p r e s e r v a t i v e
A c t i v e matter: 3.1%
A l l -Pu_rpose C1eaner , L iqui d-6
Marl ip a l 013/69
C i t r i c terpene
Methoxypropanol
Sodi um carbonate
C i t r i c a c i d
N i t r i l o t r i a c e t a t e , 40%
KNA cumene sulphonate 40
Balance water, fragrance, d y e s t u f f , p r e s e r v a t i v e
A c t i v e matter: 4.5%
%
3.0
1 .o
0.2
2.0
3.0
3.0
3.0
0 . 2
t o 100
'16
5 . 0
0.2
5 . 0
3.0
1 .o
0 . 2
1 . o
t o 100
All-Purpose CleaKer, w i t h - M i c r o b i c i d a l Properties, Liquid-A
Marl ip a l 013/99
N i t r i l o t r i a c e t a t e , 40%
Lonzabac 12.30
Sodium carbonate
KNA cumene sulphate 40
Balance water, fragrance, d y e s t u f f
%
7.5
2.0
3.0
3.0
2.0
t o 100
A c t i v e matter: 6.8%
SOURCE: Huls America, I n c . : Basic Formulations o f Detergents
and Cleaning Agents f o r Household Purposes
42 Advanced Cleaningproduct Formulations
All-Purpose Cleaner, Pastv-A
Marlon AS3
Caustic soda, 50% (approx.)
Marl inat 242/28
Marl ip a l 013/30
Tylose CBR 10000
Titanium d i o x i d e
Sodium c h l o r i d e (approx.)
Balance water, fragrance, p r e s e r v a t i v e
A c t i v e matter: 18.0%
A11-Purpose Cleaner ,
Marlon PF 40
M i lip a l 013/30
Marlamid DF 1218
Tylose CBR 10000
Titanium d i o x i d e
Sodium c h l o r i d e (approx.)
Balance water, fragrance, p r e s e r v a t i v e
A c t i v e matter: 22.0%
96
10.0
2.6
15.5
3.0
4.0
0.1
2.0
t o 100
Pastv-B
%
45.0
2.0
2.0
4.0
0.1
8.0
t o 100
All-Purpose Cleaner, W i t h Soap, High Viscosity-A
%
Marlon PF 40 5.0
O l e i c a c i d 10.0
Caustic potash, 50%* (approx.) 3.9
Potassium carbonate* 1 .o
Ethylenediamine t e t r a a c e t a t e , 40% 0.2
Balance water, fragrance, d y e s t u f f , p r e s e r v a t i v e t o 100
A c t i v e matter: 12.8%
All-Purpose Cleaner. W i t h Soap. High Viscositv-B
Marl ip a l 24/79
Marl ip a l 242/28
O l e i c Acid
Caustic potash, 50%* (approx.)
Sodi um c i t r a t e d i hydrate
Ethylenedi amine t e t r a a c e t a t e , 40%
Ethanol*
Balance water, fragrance, d y e s t u f f , p r e s e r v a t i v e
A c t i v e matter: 11.8%
96
2.0
5.0
8.0
3.1
1.5
0.2
1.5
t o 100
SOURCE: Huls America, Inc.: Basic Formulations o f Detergents
and Cleaning Agents f o r Household Products
General Purpose Cleaners 43
D-Lilnonene Emulsifiable Concentrate
Formul a HS-0094
Component
D-Li monene
Rhodacal I PAM
Igepal CQ-720
T r i ethanol ami ne
Wt.%
80.0
1 5 . 0
4 . 0
1 .o
Procedure
Phvsical Prooerti es
Blend ingredients i n order l i s t e d and m i x u n t i l uniform.
Appearance: Clear, yellow l i q u i d
S p e c i f i c Gravity: 0.9
V i s c o s i t y : t10 cps
pH, as i s : 10.0
Note: Product forms milky white emulsions when d i l u t e d w i t h
water.
D-Limonene All-PurDose Cleaner
Formula HS-0033
Comoonent:
Water
Sodium Metasilicate-Pentahydrate
Miranol FBS
Rhodasurf 91-6
Cheelox BF-13
A1kamide DC-212/M
D-Li monene
Wt.%
73.5
2.0
10.0
3.5
5.0
3.0
2.0
Procedur e
Blend ingredients i n order l i s t e d and m i x u n t i l uniform.
Phvsicsl Pronerties
Appearance: S l i g h t l y hazy, yellow l i q u i d
pH, as i s : 1.25
S p e c i f i c Gravity: 1.02
V i s c o s i t y : <I0 cps
SOURCE: Rhone-Poulenc Surfactants 81 Specialties: Formulas
44 Advanced Cleaning Rorluct Formulations
General C1eaners
Cleaner-Household
I n s r e d ients:
Tetrapotassium Pyrophosphate
Dodecylbenzene Sul fonate T r i ethanol ami ne S a l t
Aerosol A-103 Surfactant
Lauric Diethanolamide
Sodium Xylene Sulfonate
Mix a l l o f t h e above together a t one time.
A1k a line Cleaner
I n s r e d ients:
Aerosol 0s Surfactant
Sodium Metasi 1icate
Caustic Soda
Tetrasodi um Pyrophosphate
T r i sodi um Phosphate
L i a u i d Hand Cleaner
Insredients:
Aerosol A-102 Surfactant
Mineral O i l
Coconut O i l
n-Propanol o r Isopropanol
Triethanolamine
Germicide
Water
% by Weiaht
8 . 0
4.0
4.0
2.0
7 6 . 0
% bv Wei aht
5 . 0
50.0
5.0
7 . 0
3 3 . 0
% by Weiaht
60.0
10.0
5 . 0
5 . 0
0.5
0.1
19.4
Germicidal C1eaner
Inaredi ents: % bv Weiaht
Aerosol 22, Aerosol 0s. Aerosol A-102 Surfactant
o r mixture 10.0
Tetrapotassium Pyrophosphate 7.0
Dowicide 32 5 . 0
Isopropanol 3 . 0
Water 7 5 . 0
SOURCE: Cytec I n d u s t r i e s Inc.: Suggested Formulations
General Purpose Cleaners 45
Hiph-Performance General Purpose Cleaner Concentrate
Formula HS-0038
Water
STPP (Anhydrous Granular)
Rhodapon UB
Rhodapon BOS
A1codet HSC-1000
Butoxyethanol
Miranol FBS
Procedur e
Blend ingredients i n order 1
Phvsical ProDertles
Appearance: Clear, l i g h t ye1
pH, as i s : 9 . 4
S p e c i f i c Gravity: 1.06
V i s c o s i t y : t10 cps
sted
ow 1
and mix unt
q u i d
Heavy-Dutv Cleaner Powder
Formula HS-0039
Wt.%
65.0
6.0
13.0
5.0
5.0
4 . 0
2 . 0
1 uniform.
Trisodium Phosphate o r Sodium Carbonate
Sodium S i 1icate
Rhodacal DS-10
Sodium S u l f a t e
Fragrance
Procedur g
uniform.
Physical ProDerti es
Add ingredients i n order l i s t e d t o powder blender
Appearance: Whi t e , f ree-f 1owi ng powder
pH, 1% Solution: 10.8
Wt.96
40
10
20
30
Q.S
Mix u n t i l
SOURCE: Rhone-Poulenc Surfactants & Specialties: Formulas
46 Advanced CleaningPr&t Formulations
N e u t r a l A11-PurDose C1eaner, w i t h Pearlescence
High V i scosi t y - A
Marlon PS 65
Marl inat 242/28
Marlamid DF 1218
Marlamid PG 20
Cellobond HEC l O O O O O A
Balance water, fragrance, d y e s t u f f , p r e s e r v a t i v e
A c t i v e matter: 7.2%
E f f e c t ,
96
7.5
4.5
1.o
2.0
0.7
t o 100
N e u t r a l All-PUrDOSe Cleaner, w i t h Pearlescence E f f e c t .
H iah V i scosi ty-B
M a r l i n a t OFK 30
Marl in a t 242/28
Marlamid DF 1218
Marl ip a l 24/90
Marlamid PG 20
Cellobond HEC lOOOOOA
Balance water, fragrance,
A c t i v e matter: 5.0%
96
5.0
2.0
1.o
I .o
1.o
0.9
d y e s t u f f , p r e s e r v a t i v e t o 100
A1l-PUrDOSe Cleaner, w i t h A c e t i c A c i d - A
M a r l i p a l 1012/6
M a r l i n a t 242/28
Sodium c i t r a t e d i h y d r a t e
A c e t i c a c i d *
Sodi um c h l o r i d e (approx. )
Balance water, fragrance, d y e s t u f f
A c t i v e matter: 5.7%
V i s c o s i t y : low
A11-PUrDOSe Cleaner. w i t h A c e t i c Acid-B
Marlon PS 65
A c e t i c acid*
Balance water, fragrance, d y e s t u f f
A c t i v e matter: 3.3%
V i s c o s i t y : 1i q u i d
* f u r t h e r products o f Huls AG
96
1.5
15.0
1.o
2.0
6.5
to 100
s6
5.0
6.0
t o 100
SOURCE: Huls America, Inc. : Basic Formulations o f Detergents and
Cleaning Agents f o r Household Purposes
General Purpose Cleaners 47
Non-PhosDhate A l l PurDose Cleaner
Components:
Water
45% KOH
Burcosperse AP L i q u i d
Sodium Xylene Sulfonates 40%
Sodi um C i t r a t e
Dodecylbenzene S u l f o n i c Acid
Burco TME
Butyl Propasol
Varsol o r Mineral S p i r i t s
% by Weight
77.15
0.75
3.00
3.40
1.oo
1.75
6 . 0 0
6 . 0 0
0.95
Procedure:
between each a d d i t i o n .
Add components i n t h e order l i s t e d . Blend u n t i l uniform
O i l S D l i t t i n s General PurDose Cleaner
Components:
Water
Sodium M e t a s i l i c a t e Pentahydrate
Burco ADS-40
Burco TME
Burco LAA-38
Burco EHS
% by Wei Qht
82.5
5.0
2.5
5.0
2.5
2.5
Procedure:
Add components i n t h e order l i s t e d . Blend u n t i l f u l l y diss-
olved between each addition.
This i s a use as i s formulation f o r heavy duty cleaning. For
l i g h t e r duty applications, d i l u t i o n w i t h water may be possible.
This formulation w i l l suspend o i l t o a s s i s t w i t h removal. The
suspended o i l w i l l then f l o a t f o r easy removal.
SOURCE: B u r l ington Chemical Co., I n c . : Suggested Formulations
48 Advanced CleaningProduct Formulations
Scouri ng Cleaner, Mediurn V i scosi tv-A
Marlon PS65
Marl ipal 013/30
Sodium sulphate
Calcium carbonate, e.g. Durcal 40
Balance water, dyestuff, fragrance, preservative
Active matter: 5.5%
Scouring Cleaner. Mediurn V i scosi t y - B
Marlon PS 65
M a r l i p a l 013/30
Marl inat 242/28
Sodium carbonate
Calcium carbonate, e.g. Durcal 40
Balance water, d y e s t u f f , fragrance, preservative
Active matter: 5.8%
Scouring Cl-eaner. Powder-A
Marlon ARL
Sodium carbonate, dehydrated
Sodi um d i c h l o r o i socyanurate
Calci um carbonate powder (abrasive)
Active matter: 4.0%
%
4.3
2.7
1.5
50.0
t o 100
%
3.5
3.0
2 . 0
1.5
5 0 . 0
t o 100
%
5.0
5.0
1.o
t o 100
Scouring Cleaner, Powder-B
%
Marlon ARL 5.0
Sodium carbonate, dehydrated 5.0
Sodium tripolyphosphate 2.0
Calcium carbonate powder (abrasive) t o 100
Active matter: 4.0%
SOURCE: Huls America, I n c . : Basic Formulations o f Detergents
and Cleaning Agents f o r Household Purposes
6. Glass Cleaners/Polishes
49
50 Advanced CleaningRoduct Formulations
A n t i f o g Compositions f o r A p p l i c a t i o n t o C l o t h
Special wiping c l o t h s impregnated w i t h Aerosol OT Surfactant
are used t o clean and t o prevent fogging o f eye glasses, b i n -
oculars, goggles, eyepieces i n gas masks, and automobile, t r a i n ,
plane, and boat windshields. Such wiping c l o t h s are prepared by
impregnating c o t t o n f l a n n e l w i t h Aerosol OT Surfactant s o l u t i o n s
followed by a run through squeeze r o l l s t o remove t h e excess
1iquor .
a t 25% s o l i d s and one formulation a t 50% s o l i d s are as f o l l o w s :
Three successful formulations containing Aerosol OT Surfactant
Ingredients-1 :
Aerosol OT-75% Surfactant ( l b . )
Varsol No. 2 Petroleum Solvent ( g a l . )
Isopropyl Alcohol ( g a l . )
Water ( g a l . )
Inaredi ents-2 :
Aerosol OT-75% Surfactant ( l b . )
Varsol No. 2 Petroleum Solvent ( g a l . )
Isopropyl Alcohol ( g a l . )
Water ( g a l . )
I n ~ r e d i e n t s - 3 :
Aerosol OT-75% Surfactant ( l b . )
Varsol No. 2 Petroleum Solvent ( g a l . )
Isopropyl Alcohol ( g a l . )
Water (gal . )
Inqredients-4:
Aerosol OT-75% Surfactant ( l b . )
Varsol No. 2 Petroleum Solvent ( g a l . )
Isopropyl Alcohol ( g a l . )
Water ( g a l . )
25% S o l u t i o n
113
15
3
19
25% S o l u t i o n
113
6
6
25
25% S o l u t i o n
113
-
8
29
50% S o l u t i o n
66
2
3
-
The solvents and water are mixed a t 80F t o 1OOF. The Aerosol
OT-75% Surfactant i s added slowly w i t h continued mixing. A f t e r
t h e Aerosol OT has dissolved, a l l s o l u t i o n s w i l l remain c l e a r
and l i q u i d a t temperatures as low as 5OF. No scumming o f t h e
surface w i l l occur because o f evaporation d u r i n g a normal run
o f c l o t h through t h e bath. The s o l u t i o n s t h a t are allowed t o
stand should be covered t o prevent l o s s o f solvent.
The optimum amount o f Aerosol OT Surfactant t o be l e f t on t h e
c l o t h i s 40-50%, based on t h e weight o f t h e c l o t h . However, a
range o f 25-50% w i l l g i v e s a t i s f a c t o r y r e s u l t s .
SOURCE: Cytec I n d u s t r i e s Inc.: Suggested Formulations
Glass CleanerslPolishes 51
A n t i f o g Compositions f o r D i r e c t Application t o Glass
Aerosol OT Surfactant i s used i n special formulations t h a t are
applied d i r e c t l y t o glass surfaces t o prevent fogging under ad-
verse weather conditions. Some o f these formulations g i v e dur-
able f i l m s t h a t stand up under severe t e s t s . An example o f an
excel l e n t "Anti fog" paste i s as follows:
Aerosol OT-75% Surfactant
Gum Tragacanth
Petrolatum
Water
10.7 l b .
2.0 l b .
2.0 l b .
85.3 l b .
Heat t h e water t o 18OF and add t h e Aerosol OT-75% slowly
w i t h mixing. S i f t i n powdered gum tragacanth. Continue mixing
u n t i l a l l gum i s dispersed, cool t o 105F, and add petrolatum.
Application o f A n t i f o g Paste:
Dampen t h e corner of a piece o f c l o t h w i t h paste and rub
over e n t i r e glass surface. Before f i l m becomes dry, p o l i s h w e l l
w i t h clean p o r t i o n o f t h e c l o t h .
A spray bomb o f A n t i f o g may be prepared as follows:
Aerosol OT-75% Surfactant
Butyl Cellosolve Solvent
Propel 1ant
10 p a r t s
10 p a r t s
80 p a r t s
Aerosol OT Surfactant may a l s o be cast i n t o s t i c k form.
Softening agents such as glycerine o r ethylene g l y c o l are
incorporated t o s i m p l i f y a p p l i c a t i o n t o t h e glass surface.
Such s t i c k s , usually two t o f o u r inches long and one-half inch
i n diameter, are sold i n k i t s f o r a p p l i c a t i o n t o goggles,
w i ndshie l d w i pes and bthroom m i r r o r s .
SOURCE: Cytec I n d u s t r i e s , Inc.: Suggested Formulations
52 Advonced Cleoning product FormulotiOnr
Water, D . I .
Isopropanol
Adogen 66
Varox 365
Emcol 4500
Anti-Foggina. A n t i - S t a t i c Glass Cleaner
% bv We
Blending Procedure:
Combine ingredients i n t h e order shown and mix thorough
I f product i s hazy, a d d i t i o n a l Isopropanol can be used t o
c l a r i f y t h e s o l u t i o n . Gentle heating can be used t o f a c i l -
i i t a t e mixing o f t h e Emcol 4500.
Use I n s t r u c t i o n s :
sht
0.0
9.0
0.1
0.5
0.4
Y.
Apply f i n i s h e d product t o a t o w e l l e t e (Kimwipe, e t c . ) and
wipe onto t h e glass. Allow t o dry.
Product Informat
Product:
Varox 365
Adogen 66
Emcol 4500
This formulat
on :
B e n e f i t :
Wetting agent, degreaser. and detergent
A n t i - s t a t i c agent
Wetting agent, coupler, and detergent
on presents a t h i n b a r r i e r between t h e water
vapor ( i . e . , fog, steam, e t c . ) and t h e glass which w i l l prevent
fogging. The a b i l i t y t o lower t h e surface tension o f t h e
water prevents t h e c l i n g i n g o f i n d i v i d u a l water d r o p l e t s t o t h e
glass; t h e r e f o r e l i g h t i s not scattered as much as i t i s when
passing through i n d i v i d u a l droplets.
Formula 708
Annoniated Glass Cleaner
Water
W i t c o l a t e 2310
Butyl Cel l o s o l v e
Aqua Ammonia, 26 Be'
% by Weight
94.0
3.0
2.0
2.0
Blending Procedure:
between each a d d i t i o n .
Formula 704
SOURCE: Witco Corp.: Suggested Formulations
Blend ingredients i n t h e order shown, mixing thoroughly
Glass CleanersfPolbhes 53
Glass C1eaners
Ammonia
Formula GC-0017
Water
Rhodacal DSB
Butoxyethanol
Ammonium Hydroxide (28%)
Dye
Economical Heavy-Duty
Wt.% Wt.%
94.60 88.70~~
0.15 0.30
5.00 10.00
0.25 1.oo
- -
ProcedurQ
Blend ingredients i n order l i s t e d and mix u n t i l uniform.
Phvsica1 Prooerties
Appearance: Clear l i q u i d , dye t o preference
pH (as i s ) : 10.5
pH (1%): 9.0
S p e c i f i c G r a v i t y : 0.99
V i s c o s i t y : t10 cps
10.8
9.7
0.99
t10 cps
G1ass C1eaners
Vinegar
Formula GC-0018
Water
Rhodacal DSB
Butoxyethanol
Acetic Acid
Dye
Economical Heavv-Duty
Wt.% Wt.%
94.85 89.70
0.15 0.30
5.00 10.00
To pH=4 To pH=4
- -
ProcedurQ
Blend ingredients i n order l i s t e d and mix u n t i l uniform.
Physical Prooerti eg
Appearance: Clear l i q u i d , dye t o preference
pH (as i s ) : 4.0 4.0
pH (1%): 3.5 3.5
Speci f ic Gravity: 0.99 0.99
V i scosl t y : t10 cps t10 cps
SOURCE: Rhone-Poulenc Surfactants 6 S p e c i a l t i e r : Formulas
54 Advanced CleaningRoduct Formulations
Glassware and B o t t l e Cleaners
B o t t l e Cleaner (Alkaline-Powder)
Inaredi ents:
Aerosol OT-8 Surfactant
Sodium NTA Powder
Cyanamer A-100L Polyacrylamide
Sodi um Metasi 1icate
Tetrasodium Pyrophosphate
B o t t l e Cleaner (Acid-Powder)
Inaredients:
Aerosol OT-0 Surfactant
NTA Acid
Sodium Dihydrogen Phosphate
Sodium Hydrogen S u l f a t e
B o t t l e Cleaner (A1 k a line-Powder)
Inaredients:
Aerosol 0s Surfactant
Aerosol OT-8 Surfactant
Sodium NTA Powder
Sodi um Metasi 1icate
Tetrasodi um Pyrophosphate
% by Weiaht
2.0
20.0
5.0
8.0
65.0
% by Weiaht
2 . 0
20.0
58.0
20.0
% bv Weiaht
5-1 0
1- 2
20.0
8.0
60-66
B o t t l e C1eaner ( A c i d-Li quid)
Inaredients:
Aerosol GPG Surfactant
Phosphoric Acid (85%)
NTA Acid
Water
% by Weiaht
5.0
t o pH 3.0 or l e s s
20.0
75.0
B o t t l e C1eaner (Acid-Liqui d l
Inaredi ents:
Aerosol 0s Surfactant
NTA Acid
Phosphoric Acid (85%)
Water
% bv Weight
10.0. .
20.0
t o pH 3.0 o r l e s s
70.0
B o t t l e Cleaner (Hiahly Alkaline)
% bv WeiahtInaredi ents :
Aerosol 0s Surfactant 10.0
Aerosol 22 Surfactant 2.0
Sodium NTA 20.0
Sodi um Hydroxi de ( 1 0%) 68.0
SOURCE: Cytec I n d u s t r i e s Inc.: Suggested Formulations
Glass CleanerslPolishes 55
Water, D . I .
Isopropanol
Varox 365
Methylene B1ue
Household Window Cleaner
% by Weight
89.3
10.0
0.7
q . s .
Blending Procedure:
between each addition.
Typical Properties:
Viscosity, cps: 4
Solids: 0.2%
pH: 7.4
Add ingredients i n order shown and dissolve completely
Formula 706
Prerniurn Household W i ndow C1eaner
Water, D . I .
Isopropanol
Varox 1770
Methylene 81ue
% by Weight
89.4
10.0
0 . 6
q . s .
Blending Procedure:
between each a d d i t i o n .
Typical Properties:
V i s c o s i t y , cps: 4
Solids: 0.23%
pH: 6.2
Add ingredients i n order shown and dissolve completely
Formula 707
SOURCE: Witco Corp.: Suggested Formulations
56 Advanced CleaningProduct Formulations
Low VOC Antistat/Cleaner f o r Glass
I n q r e d i e n t :
Versaf 1ex 7000
Isopropanol
Ammonium Hydroxide (30%)
Neodol 25-35 (58%)
Water, Fragrance, and Preservative
%w/w
1 .oo
5.00
0.50
0.15
q . s .
Procedure:
1. Dissolve Versaflex 7000 i n water.
2 . Add ammonium hydroxide and Neodol 25-35, and mix.
3. Add isopropanol and mix.
4. Add fragrance and preservative.
SOURCE: National Starch and Chemical Co.: Reference: #8069:32
A n t i -Fog G1ass C1g a s
I n q r e d ients:_
Water
Monawet MO-70R
IPA
Procedure:
Blend i n order l i s t e d and package.
% by We-
93.0
2.0
5.0
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formulation
G1ass C1eaner
Eastman EB solvent
Isopropyl alcohol
Nonionic s u r f a c tant*
Water
% by We-
3.0
5.0
0.1
91.9
*Such as T e r g i t o l 15-S-7, Cll-C15 secondary alcohol e t h o x y l a t e
(Union Carbide) o r Genapol 24-L-60 l i n e a r alcohol ethoxylate
(Hoechst Celanese).
SOURCE: Eastman Chemical Co.: Eastman EB and DB Solvents f o r
Cleaners: Suggested Formulation
Glass CleaturslPolisks 57
T r a d i t i o n a l Consumer Glass Cleaner
Ammoniated Anionic Non-Streaki na G1ass C1eaner-Inaredient : Wt.%
Deionized Water 94.05
2-Butoxyethanol 5.70
Avanel S-70 0.25
C . I . D i r e c t Blue #86 Q.S.
Monoethanolami ne t o pH 10.5-11.5
pH (as i s ) : 10.5-11.5
Appearance: Clear, l i g h t - b l u e l i q u i d
Odor: Sweet, ethereal
Charge under a g i t a t i o n most o f t h e water, t h e 2-butoxyethanol.
Procedure:
and t h e Avanel S-70 i n t o t h e mixing vessel. I n a separate
vessel, under a g i t a t i o n , dissolve t h e dye i n t h e balance of
t h e water. Add t h e dye s o l u t i o n t o t h e batch. Adjust p H t o
10.5-11.5 w i t h Monoethanolamine.
Notes :
This formulation incorporates a novel anionic surfactant i n t o
a t r a d i t i o n a l ammoniated glass cleaner.
On prolonged storage, g l y c o l ethers have been shown t o form
peroxy compounds which can adversely a f f e c t t h e dyes normally
used i n glass cleaners. Morpholine, Ammonia, o r other v o l a t i l e
amines may be used i n place o f t h e Monoethanolamine.
Formula CG-101
Consumer Aci d G1ass C1eaner
Acid Anionic Non-Streaking Glass Cleaner
I n s r e d ient : Wt.%
Deioni zed Water 89.70
2-Butoxyethanol 10.00
Avanel S-70 0.30
Color Q.S.
Acetic Acid t o p H 3.5-4.0
pH (as i s ) : 3.5-4.0
Appearance: Clear 1i q u i d
Odor: Sweet, ethereal
Charge under a g i t a t i o n most o f the water, t h e 2-butoxyethanol,
Procedure:
and t h e Avanel S-70 i n t o the mixing vessel. I n a separate
vessel, under a g i t a t i o n , dissolve the dye i n t h e balance o f
the water. Add t h e dye s o l u t i o n t o t h e batch. Adjust p H t o
3.5-4.0 w i t h Acetic Acid.
Notes:
This formulation i s p a r t i c u l a r l y e f f e c t i v e a t removing
o i l . greases and other atmospheric contaminants from glass
surfaces.
On prolonged storage, g l y c o l ethers have been shown t o
form peroxy compounds which can adversely a f f e c t t h e dyes
normally used i n glass cleaners. Dyes should be thoroughly
screened f o r s h e l f s t a b i l i t y i n t h e f i n i s h e d product p r i o r t o
adoption i n t o t h e f i n i s h e d formulation.
Formula CG-102
SOURCE: Mazer Chemicals: Suggested Formulations
7. Hard Surface Cleaners
58
Hard swface Cleaners 59
Abrasive Cleaner-1
I n a r e d i e n t s :
A Hostapur SAS 60
Genapol UD-030
B Water (40-5OC)
C Preservative
D C a l i b r i t e SL
Tests:
Perfume
V i s c o s i t y (mPas): 1700 ( B r o o k f i e l d RVT)
pH: 1 0 , O
Abrasive C1eaner-2
1.n qr e dients :
A Hostapur SAS 60
Genapol UD-030
B Water (40-50C)
C Preservative
Perfume
D C a l i b r i t e SL
Tests:
V i s c o s i t y (mPas): 2800 ( B r o o k f i e l d RVT)
pH: 1 0 , O
Abrasive C1eaner-3
I n s r e d i e n t s :
A Hostapur SAS 60
Genapol UD-030
B Water (40-5OC)
C Preservative
Perfume
D C a l i b r i t e SL
4.50%
5.40%
59.00%
0.10%
0.20%
30.00%
4.50%
5.40%
49.00%
0.10%
0.20%
40.00%
4.50%
5.40%
39.00%
0.10%
0.20%
50.00%
Tests:
Manufacturing(l,2,3):
I One a f t e r another, t h e components o f A are added t o 0.
I1 A t 30C t h e components o f C a r e added t o I.
I11 A t l a s t , s t i r D to 11.
any longer. Modern l i q u i d products a r e based on calcium
carbonate.
SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Detergents and Cleaning
V i s c o s i t y (mPas) : 6400 (Brookf ie l d RVT)
pH: 1 0 , O O
Abrasive powders, based on s i l i c i u m dioxyde a r e n o t common
Agents: Guide Formulations
60 Advanced Cleaningproduct Forrnulaiions
Concentrated L i q u i d Household Hard-surface Cleaner
P i ne O i 1 A11-Purpose D i l u t a b l e Concentrate
Inaredi ent :
Deioni zed Water
Macol TD-12
Macol TD-3
Mazamide 80
Macol 40
Pine O i l
Tetrapotassium Pyrophosphate
Sodium M e t a s i l i c a t e Pentahydrate
Sodium Xylene Sulfonate (40%)
Wt.96
79.30
5.00
2.50
0.50
4.00
0.20
3.00
2.00
3.50
pH (as i s ) : 12.5-13.5
Appearance: Clear, l i g h t - y e l l o w l i q u i d
Speci f ic Gravity: 1.03
Procedure:
Charge t h e water t o a mixing vessel and s t a r t a g i t a t i o n .
Charge t h e Macol TD-12, Macol TD-3. and Macol 48 and m i x u n t i l
product i s c l e a r and f r e e o f " f i s h eyes." Charge t h e Pine O i l
and mix 5 minutes. Charge t h e remaining ingredients and mix
u n t i l c l e a r .
Notes:
This i s a concentrated household hard-surface cleaner
designed t o be used a t a d i l u t i o n o f 1-3 ounces per gallon.
Formula CH-103
All-PurDose Household Spray Cleaner
Ready t o Use A l k a l i n e Hard Surface Spray Cleaner
Ineredi ent :
Deioni zed Water
Macol TD-12
Sodi um C i t r a t e
Tetrapotassium Pyrophosphate
Macol 48
Wt.96
95.15
1.oo
0.25
0.60
3.00
pH (as i s ) : 9.5-10.5
Appearance: Clear, water-white l i q u i d
S p e c i f i c Gravity: 0.99
Charge t h e water t o a mixing vessel and s t a r t a g i t a t i o n .
Procedure:
Charge t h e Macol TD-12 and mix u n t i l dissolved and f r e e o f
" f i s h eyes.'' Charge t h e remaining ingredients and m i x u n t i l
c l e a r .
Notes :
This i s an all-purpose household cleaner designed t o be
used "as i s " from a spray b o t t l e .
Formula CH-104
SOURCE: Mazer Chemicals: Suggested Formulations
Hard Surface Cleaners 61
Consumer T i 1e C1eaner
A Hard Surface Hypochlorite Spray Cleaner
Inpredient:
Deioni zed Water
Sodium Hydroxide (50%)
Sodium Hypochlorite (12.5%)
Avanel S-70
Wt.%
81 .OO
2.00
18.00
1.oo
pH (as i s ) : >12.5
Appearance: Clear, water-white t o l i g h t - y e l l o w l i q u i d
Charge t h e ingredients w i t h a g i t a t i o n i n t h e order l i s t e d .
This formula i s s u i t a b l e f o r pump spray a p p l i c a t i o n . I t can
Shelf s t a b i l i t y o f c h l o r i n e cleaners i s dependent on t h e
Formula may be adjusted t o use other commercially a v a i l a b l e
Procedure:
Notes :
be used on shower t i l e s and l i k e surfaces.
absence o f t r a c e metals. Care should be taken t o insure good
q u a l i t y water and Sodium Hypochlorite.
concentrations o f Sodium Hypochlorite. Absolute concentration
o f a v a i l a b l e c h l o r i n e i s 2.0%.
Formula CC-101
I n d u s t r i a l Strenath Chlorine Cleaner
A Hard Surface I n d u s t r i a l Strength Hypochlorite Spray Cleaner
Inaredient:
Deionized Water
Sodium Hydroxide (50%)
Sodium Hypochlorite (12.5%)
Avanel S-70
Wt.Sb
56.00
3 . 0 0
40.00
1 .oo
pH (as i s ) : >12.5
Appearance: Clear, water-white t o l i g h t - y e l l o w l i q u i d
Odor: Chlorine
Procedure:
Charge t h e ingredients w i t h a g i t a t i o n i n t h e order l i s t e d .
Notes :
This formulation can be used i n high-pressure spray washing
cleaners, d i l u t e d f o r hard-surface cleaning o r used as i s f o r
an enhanced consumer household bleach.
Shelf s t a b i l i t y o f c h l o r i n e cleaners i s dependent on t h e
absence o f t r a c e metals. Care should be taken t o insure good
qua1it y water and Sodi um Hypochlori t e .
concentrations o f Sodium Hypochlorite. Absolute concentration
of a v a i l a b l e c h l o r i n e i s 5.0%.
Formula CC-102
SOURCE: Mazer Chemicals: Suggested Formulations
Formula may be adjusted t o use other commercially a v a i l a b l e
62 Advanced CleaningRoduct Formulations
D-Limonene Hard-surface Cleaners
Formula HS-0093
D-Limonene
Concentrate
Component Wt.%
D-Li monene 20.0
Alcodet HSC-1000 30.0
Igepal CO-720 30.0
Miranol FBS 19.0
Triethanolamine 1.o
Water ---
All-Purpose
Spray C1eaner
Type
(1:9 D i l u t i o n )
Wt.%
2.0
3.0
3.0
1.9
0.1
90.0
Heavy-Duty
Degreaser Type
(1:3 D i l u t i o n )
Wt.%
5.0
7.5
7.5
4.75
0.25
75.0
Procedur e
A. Concentrate Blend i n g r e d i e n t s i n order l i s t e d and mix
u n t i 1 uniform.
B. SDrav Cleaner D i l u t e concentrate 1:9 w i t h water or charge
"Vessel A" w i t h D-Limonene, Alcodet HSC-1000,
and then Igepal CQ-720. Mix u n t i l uniform.
Charge a separate "Vessel B" w i t h water,
triethanolamine and M i ranol FBS. Mix u n t i l
uniform. F i n a l l y , add t h e contents o f "Vessel
A" t o "Vessel B" and mix u n t i l uniform.
C.DeQreaSer D i l u t e concentrate 1:3 w i t h water or blend
i n g r e d i e n t s i n t h e same manner as s p e c i f i e d
i n t h e spray cleaner procedure.
Phvsi cal P r o o e r t i es
Appearance Clear, gold Clear, l i g h t Clear,
Concentrate S w a y Cleaner DegreaSer
l i q u i d yellow l i q u i d yellow l i q u i d
S p e c i f i c G r a v i t y 1.02 1.oo 1.oo
V i s c o s i t y 110 cps <10 cps <10 cps
pH. as i s 10.0 9.5 9.5
SOURCE: Rhone-Poulenc Surfactants & Specialtlea: Formulas
Hard Surface Cleaners 63
d ' l i a o n e n e SDrav Cleaner
Phase A:
Water, D . I .
Tetrapotassium Pyrophosphate
Sodium M e t a s i l i c a t e , Anhydrous
Petro LBA L i q u i d
W i tconate AOS
Phase B:
DeSonic 9N
W i tcami de 128T
d ' L imonene*
% bv Weiaht
68.0
6.0
2.0
10.0
3.0
5.0
3.0
3.0
*Sunkist Growers, I n c . o r Union Camp
Blending Procedure:
speed, add Phase B t o Phase A.
Use D i l u t i o n : use as i s .
Formula 802
Blend Phase A and Phase B separately. W i t h mixer a t h i g h
~-d'Lirnonene Cleaner Concentrate
Phase I:
Isopropanol
O l e i c Acid
Varonic K205
d ' L imonene
Phase 11:
Water, D . I .
Potassium Hydroxide, 87%
% by Weiaht
10.0
8.8
5.0
12.0
62.2
2.0
Blending Procedure:
I 1 i n g r e d i e n t s and mix thoroughly. While mixing, add Phase I t o
Phase 11.
T y p i c a l P r o p e r t i e s :
V i s c o s i t y , cps: 75
S o l i d s : 13.8%
pH: 10.2
Formula 808
SOURCE: Witco Corp.: Suggested Formulations
Combine Phase Ii n g r e d i e n t s and mix thoroughly. Combine Phase
64 Advanced Cleaningproduct Formulations
General Purpose Hard Surface Cleaner
This general purpose cleaner i s a v e r s a t i l e product. The
combination o f Sandoxylate SX-408 and Sandoxylate SX-424 provide
excellent surface a c t i v i t y and s o i l removal allowing i t t o be
used i n many a p p l i c a t i o n s .
Inaredi ents:
Water
Sodi urn S i 1icate
Sodium Hydroxide (20% Solution)
Butyl C e l losolve
Sandoxylate SX-408
Sandoxylate SX-424
Sodium Xylene Sulfonate
Drimarine Turquoise XB
% bv W t
79.9
1.o
0.5
0.5
5.0
11.5
1.5
0.1
Procedure:
i d e (20%), Butyl Cellosolve, Sandoxylate SX-408. Sandoxylate
SX-424, Sodium Xylene Sulfonate and Drimarine Turquoise XB.
Charge vessel w i t h water. Add sodium s i l i c a t e , sodium hydrox-
Suggested Use: 4 t o 6 ounces per g a l l o n o f water.
SOURCE: Sandoz Chemicals Corp. : Formul a t i on HHG-11
A l k a l i n e Hard Surface Cleaner
Water, D.I.
Sodium M e t a s i l i c a t e
Varami de A-83
Witconate 30DS
W i tconate SXS L i q u i d
% by Weiaht
34.0
8.0
12.0
40.0
6.0
Blending Procedure:
each a d d i t i o n .
Typical Properties:
Viscosity, cps: 205
Solids: 34.4%
pH: 12.5
Add ingredients i n order shown and dissolve completely between
SOURCE: Wltco Corp.: Formula 5 1 6
Hard swface Cleaners 65
General Puroose Hard-surface Cleaners
Formula HS-0034
Comoonent
Water
Sodi um Metasi 1icate
Pentahydrate
Rhodasurf 91-6
Cheelox BF-13
Miranol FBS
Rhodafac RA-600
Butoxyethanol
Solvent-Free
Non-Phosphate
IYPe
Wt.%
83.5
2.0
7.5
3.0
4.0
-
Solvent-Free
Phosphate
mWt.%
85.5
2.0
7.5
3.0
2.0
-
-
Heavy-Duty
Solvent
I Y P S
Wt.%
83.0
I .o
6.0
2.0
2.0
6.0
-
Procedure
Phvsi c a l P r o o e r t i 8s
Blend i n g r e d i e n t s i n order l i s t e d and mix u n t i l uniform.
Appearance C1ear, C1ear, C1ear,
S p e c i f i c G r a v i t y 1.035 1.012 0.994
V i s c o s i t y <I0 cps <I0 cps <I0 cps
pH, as i s 12.3 11.85 12.20
It. yellow water-white water-white
U n b u i l t . Hiah-Sudsina. Hard-surface Cleaner
Formula HS-0036
Comoonent
Water
C a l s o f t F-90
Miranol FBS
Sodi um S i 1i c a t e
Igepal CO-710
A1 kami de DC-212/S
M-Pyrol, N-methyl-2-pyrrolidone
Wt.%
79.7
5.3
3.0
5.5
1 .o
2.0
3.5
Procedure
81end i n g r e d i e n t s i n order l i s t e d and mix u n t i l uniform.
TvDi cal ProDerti88
Appearance: C1ear, ye11ow 1iquid
V i s c o s i t y : t 1 0 cps
pH, as i s : 9.85
S p e c i f i c Gravity: 1.07
SOURCE: Rhone-Poulenc Surfactants h S p e c i a l t i e s : Formulas
66 Advanced Cleaning Product Formulations
Hard-surface Cleaner
I n q r e d i e n t :
L i q u i d C i t r i c Acid-50% (Haarman &
Sodium h y d r o x i d e s o l u t i o n 50%
N o n i o n i c s u r f a c t a n t (Neodol 25-9)
Methyl C a r b i t o l s o l v e n t
Sodi um x y l ene s u l f o n a t e
Sodium carbonate
P i n e o i 1
Water
Percent by Wei q h t
Rei mer C o r p l - j 4 . 0
2 . 5
0 . 0
7 . 0
5.0
3.0
0 . 3
70.2
M i x t h e L i q u i d C i t r i c Acid-50% s o l u t i o n w i t h an equal volume
o f water and n e u t r a l i z e by adding sodium h y d r o x i d e . The neut-
r a l i z a t i o n r e a c t i o n s h o u l d be done s l o w l y and c a u t i o u s l y under
a g i t a t i o n , as t h e r e a c t i o n i s h i g h l y exothermic. Blend t h e neut-
r a l i z e d s o l u t i o n w i t h t h e n o n i o n i c s u r f a c t a n t , Methyl C a r b i t o l ,
sodium x y l e n e s u l f o n a t e and sodium carbonate. Add p i n e o i l l a s t .
M n - A b r a s i v e C l e a n s e r
In g redient :
L i q u i d C i t r i c Acid-50% (Haarman
Sodium h y d r o x i d e s o l u t i o n 50%
Xanthan gum
Vegetable gum (Veegum HS)
Amphoteric s u r f a c t a n t
Noni o n i c s u r f a c t a n t
Calcium c a r b o n a t e (100 mesh)
Water
Percent by Wet q h t
& Reimer Corp. ) 6 . 0
3.7
25.0
2 . 5
3.0
1 . 5
45.0
13.3
-~
Prepare a 1% s o l u t i o n o f xanthan gum w i t h t h e i n c l u s i o n o f a
p r e s e r v a t i v e . S l o w l y add t h e v e g e t a b l e gum t o water and s t i r
u n t i l t h o r o u g h l y h y d r a t e d . Add t h e c a l c i u m carbonate, f o l l o w e d by
t h e amphoteric s u r f a c t a n t , t h e n o n i o n i c s u r f a c t a n t and t h e
xanthan gum s o l u t i o n .
SOURCE: Haarman 8, Reimer Corp.: Suggested F o r m u l a t i o n s
-Hard-Surf ace Cleaner
Eastman DB s o l v e n t
A n i o n i c s u r f a c t a n t *
Na4EDTA**
Ammoni um h y d r o x i d e (28%)
Water
*Such as Rhodapex CO-433 (Rhone-Poulenc)
**Tetrasodium ethylenediaminetetracetate (39%)
SOURCE: Eastman Chemical Co.: Suggested F o r m u l a t i o n
Yo by W t .
7 . 0
1 .o
1.25
2 . 0
00.75
Hard swface Cleaners 67
Hard-surface Cleaner
All-Surface Bathroom Acid Type
Formula BC-0005
M-Pyrol, N-Methyl-2-Pyrrolidone (ISP)
Igepal CO-630
Hydroxyethylcel l u l o s e
Phosphori c Acid
Water
Perfume and colorants may be added.
W> 3
4.0
1 .o
0.2
9.5
85.3
Procedure
1 . D i sperse hydroxyethylcel 1ulose i n water.
2. I n a separate vessel, mix M-pyrol, Igepal CO-630 together.
Add hydroxyethylcellulose/water mixture.
3. Add a c i d and mix thoroughly.
Phvsic a l P r w e r t igg
pH (as i s ) : 2.0
pH (1%): 2.4
V i s c o s i t y : 30 cps
Speci f ic Gravity: 1 .02
--Surface Cleaner
All-Surface Bathroom Type
Formula BC-0006
Wt.%
Water 70.5
I gepal CO-630 2.5
Cheelox NTA-Na3 20.0
Sodi um Xylene Sul fonate 5.5
Sodi um Hydroxide 1.5
Perfume and colorants added, as desired, replacing water.
Procedure
1 . Dissolve Igepal CO-630 i n water. Add Cheelox NTA-Na3.
2 . Add sodium-xylene sulfonate and sodium hydroxide, mixing w e l l
Physical P r w e r t i e s
pH, as i s : 12.9
pH (1%): 11.4
V i s c o s i t y : 10 cps
S p e c i f i c Gravity: 1.05
a f t e r each addition.
SOURCE: Rhone-Poulenc Surfactants 6 Specialties: Formulas
68 Advanced Cleaning Product Formulotiotu
Hard Surface Cleaners
Calsuds, C a l s o f t and Calamide concentrates can be formulated
t o create powerful, non-corrosive, non-filming cleaners f o r
f l o o r s , woodwork, walls, windows, counter tops, tubs, t i l e and
s i m i l a r hard surfaces. Use l e v e l s : 1-4 oz./gal o f water.
F l o o r Cleaner Products
P i 1o t Formula #HSC-003-01
Water
Na4EDTA
Calsoft F-90
Cal oxyl a t e N-9
B u t y l Cellosolve
Calsuds 81
TKPP
P i l o t SXS-40
Water
Cal foam SLS-30
Calamide C
Propylene G1ycol
Water
% by Weiaht
81 .OO
10.00
4.00
2.00
3.00
P i l o t Formula #HDC-003-01
% bv Weight
5.00
7.80
10.00
77.20
Rua Cleaner
P i l o t Formula #CPT-003-01
% by Weiqht
40.09
4.04
20.11
35.76
P l a s t i c , V i n y l and Leather Cleaner
P i l o t Formula #UPC-001-01
Caloxylate N-9
Dowanol D (PnB)
Propylene G1ycol
B u t y l Cellosolve
Water
SOURCE: P i l o t Chemical Co. : Household C1eaner Formu
by Weight
10.10
5.02
2.56
1.13
81.19
a t ions
Hard Surface Cleaners 69
Hard Surface Cleaners
Calsuds, C a l s o f t and Calamide concentrates can be formulated
t o c r e a t e powerful, non-corrosive, non-filming cleaners f o r
f l o o r s , woodwork, w a l l s , windows, counter tops, tubs, t i l e
and s i m i l a r hard surfaces. Use l e v e l s : 1-4 oz./gal. o f water.
Tub and T i l e Cleaners
Pi l o t Formula #APC-004-01
Water
Versene 100
Calsuds A
Isopropyl Alcohol
Propyl ene G1 ycol
Pine O i 1
D-1 imonene
Cal imul se PRS
Caloxylate N-9
Water
C a l s o f t L-40
P i l o t sxs-40
Calamide 0
Water
TKPP
Calsuds 81
P i l o t sxs-40
Water
Ammonia (29%)
Na4EDTA
Butyl C e l l osol ve
Calsuds 81
Pi 1o t Formula #HDC-006-01
Counter Top/Wall Cleaners
P i l o t Formula #HDC-003-01
A l l Purpose Type
P i l o t Formula #HSC-008-01
Ammoniated T-
% bv Weiqht
65.00
1 .oo
25.00
5.00
3.00
1.oo
?&by Wei a h t
30.00
5.00
5.00
26.50
16.50
10.00
7 . 0 0
% by Weight
77.20
7.80
5.00
10.00
% by Weiaht
86.50
3.00
0.50
5.00
5.00
SOURCE: P i lot Chemical Con: Household C1eaner Formulations
70 Advanced Cleaning Product Formulations
Hard Surface Cleaner w/AmDhoteric
Water, 0.1.
Sodium Carbonate
Rewoteric AM KSF-40
Oowanol DPM
Versene 100
Witconate SXS (40%)
% by Weinht
75.0
4.0
10.0
5.0
2.0
4.0
Blending Procedure:
each a d d i t i o n .
Typi cal Propert ies :
Add ingredients i n order shown and dissolve completely between
Viscosity, cps: 4
Solids: 10.2%
pH: 10.8
Formula 507
Hard Surface Cleaner Concentrate w/d'Lilnonene
Phase I:
Isopropanol
Oleic Acid
Varonic K205
d ' L imonene
Phase 11:
Water, 0.1.
Potassium Hydroxide (87%)
% by Weiciht
10.0
8.8
5.0
12.0
62.2
2.0
B1endi ng Procedure :
I 1 ingredients and mix thoroughly. While mixing, add Phase I t o
Phase 11.
Typical Properties:
Viscosity, cps: 75
Solids: 13.8%
pn: 10.2
Combine Phase I ingredients and mix thoroughly. Combine Phase
Formula 508
SOURCE: Witco Corp.: Suggested Formulations
Hard Swface Cleaners 71
Hard-surface Cleaner Concentrate
A l k a l i n e All-Purpose Cleaner Concentrate
Inaredi ent :
Deionized Water
Sodium Hydroxide (50%)
Tetrapotassium Pyrophosphate
Sodium M e t a s i l i c a t e Pentahydrate
Avanel S-150
Sodium Cumene Sulfonate (40%)
Wt.%
76.00
2.00
12.00
1.oo
6.00
3.00
pH (as i s ) : 10.5-11.5
Appearance: Clear, l i g h t - y e l l o w l i q u i d
S p e c i f i c Gravity: 1.13
Procedure:
Charge t h e water t o an appropriate mixing vessel and s t a r t
a a i t a t i o n . I n t h e sequence l i s t e d above, charge t h e remaining
ingredients and mix u n t i l t h e s o l u t i o n i s c l e a r .
Notes :
This i s a hard-surface cleaner concentrate which i s
on many d i f f e r e n t s o i l s and surfaces. For concrete sur
use "as i s . " For walls, f l o o r s , and other surfaces, d i
1O:l w i t h water.
Formula CH-101
Household Hard-surface Cleaner
All-Purpose A l k a l i n e Cleaner f o r Sponge o r Spray Apt
Inaredient :
Deionized Water
Sodium Laureth (3) Sulfate
Mazamide 00
Tetrapotassium Pyrophosphate
Sodium M e t a s i l i c a t e Pentahydrate
Macol 40
Deionized Water, Dye, etc.
pH (as i s ) : 12.0-13.0
Appearance: Clear, water-white l i q u i d (without dye)
S p e c i f i c Gravity: 1.01
Procedure:
e f f e c t i ve
aces,
ute
Iic a t ion
Wt.%
80.00
2.50
0.50
1.oo
2.00
4.00
Q.S.
Charge t h e f i r s t p o r t i o n o f water t o a mixing vessel and
s t a r t a g i t a t i o n . I f product i s t o be colored, d i s s o l v e dye i n
t h e reserved p o r t i o n o f the water i n a separate vessel. Charge
a l l remaining ingredients, i n c l u d i n g t h e dye solution, t o t h e
mixing vessel and mix u n t i l c l e a r .
Notes :
cleaner. The product may be used w i t h a sponge o r may be used
i n a spray b o t t l e .
Formula CH-102
SOURCE: Mazer Chemicals: Suggested Formulations
This formulation i s designed as a general purpose household
72 Advanced CleaningRoduct Formulations
Hiah-Performance. Hard-surface Cleaners
Formula HS-0035
Component
Water
Sodi um Metasi 1icate
Miranol FBS
A1codet HSC-1 000
Cheelox BF-13
Rhodafac RA-600
Butoxyethanol
Pentahydrate
6 . 0
Solvent-Free Solvent-Free
Non-Phosphate Phosphate
IYPe IYIzz
Wt.% Wt.%
88.0 87.0
2.0 2.0
3.0 1 .o
4.0 4.0
3.0 3.0
- 3.0
- -
Heavy-Duty
Solvent
TYDe
Wt.%
85.0
2.0
2.0
3.0
2.0
-
Procedur e
Physical ProDerties
Blend ingredients i n order l i s t e d and mix u n t i l uniform.
Appearance Clear, l i g h t yellow l i q u i d
pH, as i s 12.6 11.5 12.55
V i s c o s i t y <I0 cps
Speci f ic G r a v i t y 0.978 1.013 1.016
<I0 cps <10 cps
Econoaic a l Pine O i 1 Hard-surface C1eaner
Formula HS-0037
Component
Pine O i l
Rhodasurf 0C-840
Water
Wt.%
5 . 0
10.0
8 5 . 0
Procedur e
1 . Add Rhodasurf BC-840 t o pine o i l . Mix w e l l . Heat t o approx-
imately 35-40C t o o b t a i n homogeneous s o l u t i o n .
2. Add water and mix thoroughly.
Physical Prooerties
Appearance: Clear, water-white l i q u i d
pH. as i s : 3.08
S p e c i f i c Gravity: 0.99
V i s c o s i t y : <10 cps
SOURCE: Rhone-Poulenc Surfactants & S p e c i a l t i e s : Formulas
Hard swface Cleaners 73
M i l d Abrasive Hard Surface Cleaner
A m i l d abrasive cleaner f o r consumer use. E f f e c t i v e on
S t a i n l e s s S t e e l , Porcelain and other hard surfaces.
P a r t : I n q r e d i e n t s :
A Deioni zed Water
C a l c i t e (t100 mesh)
Mazox LDA
Potassium C i t r a t e
B C a l s o f t F-90
Deionized Water
Appearance: White pasty 1iqui d
p H (as i s ) : 7.0-8.0
S p e c i f i c G r a v i t y : 1.47
Procedure:
charge t h e water and s t a r t a g i t a t i o n . Do not
i n t o t h e product. Slowly add t h e C a l c i t e f o l
Mazox LDA and t h e Potassium C i t r a t e .
To a mixing vessel w i t h sweep and scrape
Wt.%
30.00
50.00
6.70
1 .oo
3.30
9.00
ype a g i t a t i o n ,
mix a i r
owed by t h e
I n a separate vessel, d i s s o l v e t h e C a l s o f t F-90 i n t h e
remaining water. When completely dissolved, add t h e f i r s t p a r t
o f t h e mix. Again avoid mixing excess a i r i n t o t h e system.
Notes :
I t i s a m i l d abrasive hard surface cleaner e f f e c t i v e
against mast common s o i l s . I t can be used on s t a i n l e s s s t e e l ,
p o r c e l a i n and other hard surfaces.
I n t h e manufacture o f t h i s product, care should be taken t o
avoid mixing a i r i n t o t h e f i n i s h e d product. Being a pasty l i q u i d ,
once a i r i s entrained i n t o t h e system, i t i s d i f f i c u l t and t i m e
consuming t o remove.
SOURCE: Mazer Chemicals: Formulation CH-109
This f o r m u l a t i o n i s designed t o be used as i s by t h e consumer.
74 Advanced CleaningProduct Formulations
Non-Phosphate Household Hard-surface Cleaner
All-Purpose A l k a l i n e Cleaner f o r Sponge or Spray A p p l i c a t i o n
Inaredi ent : INt.%
Deioni zed Water 79.75
Sodi um Laureth S u l f a t e 2.50
Mazamide 80 0.50
Sodi um C i t r a t e 1.25
Macol 40 4.00
Sodium M e t a s i l i c a t e Pentahydrate 2.00
Deionized Water, Dye, e t c . a.s.
pH (as i s ) : 12.0-13.0
Appearance: Clear, water-white l i q u i d (without dye)
S p e c i f i c Gravity: 1. O l
Procedure:
Charge t h e f i r s t p o r t i o n o f water t o a mixing vessel and
s t a r t a g i t a t i o n . I f product i s t o be colored, add t h e dye t o
reserved p o r t i o n o f t h e water i n a separate vessel. Charge a l l
remaining ingredients, i n c l u d i n g t h e dye solution, t o t h e mixing
vessel and mix u n t i l c l e a r .
Notes :
This formulation i s a non-phosphate version o f formulation
CH-102. This formulation i s designed as a general purpose
household cleaner. The product may be used w i t h a sponge or may
be used i n a spray vessel.
Formula CH-106
Won-Phosphate Concentrated Household Hard-surface Cleaner
Concentrated Pine O i l All-Purpose Cleaner
Inqredi ent : Wt.%
Deioni zed Water 78.05
Macol TD-12 5.00
Macol TD-3 2.50
Mazamide 00 0.50
Macol 40 4.50
Pine O i 1 0.20
Sodi um C i t r a t e 3.75
Sodium M e t a s i l i c a t e Pentahydrate 2.00
Sodium Xylene Sulfonate (40%) 3.50
pH (as i s ) : 12.5-13.5
Appearance: Clear, l i g h t yellow l i q u i d
S p e c i f i c Gravity: 1.02
Procedure:
Charge t h e water t o a mixing vessel and s t a r t a g i t a t i o n .
Charge t h e Macol TD-12, Macol TD-3, Mazamide 80 and Macol 48
and continue a g i t a t i o n . Charge t h e Pine O i l and mix 5 minutes.
Charge t h e remaining ingredients and mix u n t i l c l e a r and f r e e
o f "fish eyes. I'
Notes :
This formulation i s a non-phosphate version o f formulation
CH-103. This i s a concentrated household hard-surface cleaner
designed t o be used a t a d i l u t i o n o f 1-3 ounces per gallon.
Formula CH-107
SOURCE: Mazer Chemicals: Suggested Formulations
Hard Surface Cleaners 75
P i n e O i l Cleaner C o n c e n t r a t e
~~I n g r e d i en.Lsl
P i n e 01 I
N i n o l 11-CM
Makon 12
Ammonyx LO
I s o p r o p a n o l
Water, D.I.
B i o - S o f t S-100
% by W t .
20.0
9.0
5 . 0
0 . 5
2.0
10.0
53.5
M i x i n g Procedure:
w a t e r s l o w l y w h i l e under a g i t a t i o n . M i x u n t i l c l e a r .
P r o p e r t i e s :
Combine p i n e o i l , s u r f a c t a n t s and IPA. Mix u n t i l c l e a r . Add
Appearance: C l e a r y e l l o w l i q u i d
Odor: P i n e
V i s c o s i t y C 25C, c p s : 50
pH ( a s i s ) : 8 . 1
D e n s i t y l b s / g a l : 8 . 0 6
Freeze/Thaw ( 3 c y c l e s ) : Pass
50C oven ( 1 week): Pass
Use I n s t r u c t i o n s :
D i l u t e 1-2 ozs i n t o one g a l l o n
Performance:
Gardner S t r a i g h t L i n e W a s h a b i l i t y T e s t :
Above f o r m u l a t i o n : 73.0% s o i l removed f r o m t i l e s
Commercial p r o d u c t : 55.5% s o i l removed f r o m t i l e s
SOURCE: Stepan Co.: F o r m u l a t i o n No. 208
L i q u i d Super C o n c e n t r a t e
%_by Wei ght
Water, D . I . 30.0
T e t r a p o t a s s i u m Pyrophosphate (60%) 25.0
B u t y l C e l l o s o l v e 5.0
W i t c o n a t e SXS L i q u i d 10.0
Varamide A-83 30.0
B l e n d i n g Procedure:
each add1t ion.
T y p i c a l P r o p e r t i e s :
S o l i d s : 49.0%
SOURCE: W i t c o Corp. : Formula 502
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
8. Laundry Products
76
Anionic/Nonionic Heavy-Duty Laundry Deteraent
Formula LY-0042
Water
C a l s o f t F-90
Rhodasurf 25-7
Rhodacal A-246/L
Sodi um C i t r a t e
Brightener
Fragrance
Dye
Wt.%
63
5
7
15
10
Q.S.
Q.S.
Q . S .
Procedur g
a g i t a t i o n . Then, add Rhodasurf A-246/L and Calsoft F-90.
Begin c o o l i n g and add remaining ingredients s i n g l y , w i t h
a g i t a t i o n t o o b t a i n uniform mixture, before making next
a d d i t i o n .
Phveical ProDert1ea
Appearance: C1ear 1iquid, dyed t o preference
pH. as i s : 7.4
S p e c i f i c Gravity: 1.09
V i s c o s i t y : 200 cps
Heat water t o 60C. Add Rhodasurf 25-7 slowly, w i t h moderate
Anionic/Nonionic Heavy-Duty Laundry Deteraent
Formula LY-0043
Part A
Water
Na C i t r a t e
Calsoft F-90
l!artJ!
Rhodasurf 25-7
MEA
sxs
Part C
Colorant
Perfume
Water
Procedurg
Dissolve Sodi um C i t r a t e
add C a l s o f t F-90. Mix Part
"B" . Add colorant, perfume
Phvsf ca1 Prooerties
pH: 11.0
pH (1% Solution): 9.50
S p e c i f i c Gravity: 1.120
V i s c o s i t y : 75 cps
30.0
8 . 0
17.0
8 . 0
2.0
6.0
0.02-1
0.1-0.5
Q . S .
i n water by s t i r r i n g a t 45-50C and
and water. Adjust pH t o 11.0.
i n t h e order l i s t e d . Add "A" t ollgll
SOURCE: Rhone-Poulenc Surfactants 6 Specialties: Formulas
Laundry Products 77
78 Advanced Cleaning Product Formulations
Anionic/Nonionic Heavy-Duty Laundry Deteraent
Formula LY-0044
Part A
Water
Na C i t r a t e
Calsoft F-90
P a r t B
Rhodasurf 25-7
MEA
sxs
Part C
Colorant
Perfume
Water
Wt.%
30.0
8.0
17.0
8 . 0
2.0
6 . 0
0.02-1
0.1- 0.5
Q . S .
Procedure
Dissolve sodium c i t r a t e i n water by s t i r r i n g a t 45C-5OC.
add C a l s o f t F-90. Mix Part "B" i n the order l i s t e d . Add "A" t o
"8" . Add colorant, perfume and water. Adjust pH t o 11.0.
Nonionic/Amphoteric Heavy-Duty Laundry L i q u i d
Formula LY-0045
Water
G1ycosi des
Miranol FBS
MEA
Colorant
Perfume '
Wt.%
Q.S.
20.0
7.0
2 . 0
0.02-1
0.1 -0.5
Procedure
each a d d i t i o n . Adjust pH t o 11.0.
Add t h e ingredients i n t h e order l i s t e d . M i x well a f t e r
Phvsical P r o m r t ieg
pH: 11.0
pH (1% Solution): 9.50
S p e c i f i c Gravity: 1 .lo0
Viscosity: 300 cps
SOURCE: Rhone-Poulenc Surfactants & S p e c i a l t i e s : Formulas
Cold Water Deterpent
JFor W o o l and D e l i c a t e Fabrics)
Formula LY-0040
Water
Miranol CS Conc.
Rhodapex ES-2
A1kamide DC-212
Fluorescent Whitening Agent
Wt.%
55.9
10.0
30.0
4 . 0
0.1
Procedur Q
c l e a r .
Phvsic a l Pronerti8s
Add ingredients i n order l i s t e d . Heat t o 50C and mix u n t i l
Appearance: Clear, yellow l i q u i d
pH. as i s : 8.16
S p e c i f i c Gravity: 1.02
V i s c o s i t y : 700 cps
F ine Fabric Deterpent
Formula LY-0041
Rhodacal DS-10
Sodium Hexametaphosphate
Sodium Bicarbonate
Optical Brightener
Wt.%
32.0
30.0
38.0
P.S.
Procedure
t o t h e blender. Mix f i v e minutes. Add t h e Rhodacal DS-10 w i t h
mixing. Add t h e o p t i c a l brightener w i t h mixing. Mix u n t i l
uniform.
Phvaical Prooert i e s
Add t h e sodium bicarbonate and t h e sodium hexametaphosphate
Appearance: White, free-flowing powder
pH, 1% Solution: 8.5
SOURCE: Rhone-Poulenc Surfactants & Specialties: Formulas
Laundry Products 79
80 Advanced CleaningProduct Formulations
Deteraent f o r Colored Fabrics. Powder, Spray MixinQ Process-A
Spray Mix:
M a r l i p a l 24/939 o r 013/939
Fragrance
O p t i c a l b r i g h t e n e r
B u i l d e r Mix:
Z e o l i t e A
Sodium m e t a s i l i c a t e pentahydrite
Sodium carbonate, dehydrated
Carboxymethyl c e l l ulose
Polycarboxylate, e.g. Sokalan CP 5 powder
Sodi um s u l phate 1ight
A c t i v e matter: 9.0%
%
10.0
0.2
0 . 2
35.0
5 . 0
15.0
2.0
4.0
t o 100
Detergent f o r Colored Fabrics, Powder, Spray M j x i n ~Pro_cess-B
Spray M i x :
M a r l i p a l 24/30
Marl ip a l 24/90
Fragrance
O p t i c a l brightener
B u i l d e r Mix:
Marlon ARL
Z e o l i t e A
Sodium soap powder
Sodium m e t a s i l i c a t e pentahydrate
Sodium carbonate, dehydrated
Polycarboxylate, e.g. Sokalan CP 5 powder
P o l y v i n y l p y r r o l i d o n e , e.g. Sokalan HP 50
Sodium sulphate l i g h t
%
2.0
4.0
0 . 2
0 . 2
10.0
40.0
4.0
5.0
15.0
4 . 0
2.0
t o 100
A c t i v e matter: 14.0%
SOURCE: Huls America, I n c . : Basic Formulations o f Detergents
and Cleaning Agents f o r Household Purposes
Detergent for Curtains, Medium V i s c o s i t v - A
%
M a r l i n a t DFK 30 20.0
Marl ip a l 24/70 15.0
Coconut f a t t y acid, potassium s a l t 5.0
Ethylenedi ami ne t e t r a a c e t a t e 40 0.2
Balance water, fragrance, d y e s t u f f , o p t i c a l b r i g h t e n e r ,
preservat ive t o 100
A c t i v e m a t t e r : 26.0%
Detergent f o r Curtains, Medium V i s c o s i t v - 8
%
Marlon PS 65 10.0
Marlox M 606/1 15.0
Ethylenediamine t e t r a a c e t a t e 40 0.2
Balance water, fragrance, d y e s t u f f , o p t i c a l b r i g h t e n e r ,
p r e s e r v a t i v e t o 100
A c t i v e matter: 20.7%
Manual-Wash Detergent, Foaming Medium V i scosit y - A
%
Marlon PS 65 10.0
M a r l i p a l 013/70 15.0
Marlamid DF 1218 2.5
Na cumene sulphonate, 40% 1 .o
Ethanol* 1.5
Balance water, fragrance, d y e s t u f f , preservative,
sodium c h l o r i d e t o 100
A c t i v e matter: 24.0%
Manual-Wash Detergent. Foaming Medium Viscosity-B
%
Marl in a t 242/28 12.0
sodium c h l o r i d e t o 100
Marlon A 365 18.5
Balance water, fragrance, d y e s t u f f , p r e s e r v a t i v e ,
A c t i v e matter: 15.3%
SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and
Cleaning Agents f o r Household Purposes
Laundry Products 81
82 Advanced CleaningProduct Formulations
Detergent f o r F i n e Fabrics-1
L i q u i d
I n r e d i e n t s :
i ? F a t t y a c i d (Cocos + Olein. P r i f a c 7976)
KOH (85%)
H20 (40-50C)
B Hostapur SAS 60
Genapol ZRO l i q u i d
Genapol UD-080
3.00%
0.60%
41.90%
23.30%
25.00%
6.00%
C C i t r i c a c i d x 1H20 0.20%
Manufacturing:
I One a f t e r another, t h e components o f B are added t o A .
I 1 A t l a s t C i s added.
Deteraent f o r F i n e Fabrics-2
m r e d i e n t s :
A F a t t y a c i d (Cocos + Olein, P r i f a c 7976) 4.00%
KOH (85%) 0.80%
H20 (40-5OC) 63.00%
8 Hostapur SAS 60
Genapol UO-080
a. 00%
24.00%
C C i t r i c a c i d x 1H20 0.20%
Manufacturing:
I One a f t e r another, t h e components o f B are added t o A.
I 1 A t l a s t C i s added.
SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Detergents and Cleaning
Agents: Guide Formulations
Laundry Products 83
Enzymatic Heavy-Duty Laundry Deteraent
Formula LY-0046
P a r t A
Water
C i t r a t e
C a l s o f t F-90
P a r t
Rhodasurf 25-7
MEA
TEA
sxs
Rhodapex NA 61
P a r t C
Na Formate
Calcium Chloride
Enzymes
Colorant
Perfume
Water
Wt.%
10.0
5.0
8.0
6.0
2.0
2.0
3.0
8.0
1.2
0.2
0.4
0.02-1
0.1 - 0 . 8
Q.S.
Procedure
C a l s o f t F-90. Mix Part "B" i n t h e o r e r l i s t e d . Add "A" t o "B".
Add sodium formate and calcium chlOP&e. Cool t o room temper-
ature. Add t h e enzymes. Add coloraat, perfume and water. Adjust
pH t o 10.0.
Phvsi c a l P r o o e r t i
pH: 10.0
pH (1% S o l u t i o n ) : 8.8
Speci f ic G r a v i t y : 1 . l o 0
V i s c o s i t y : 100 cps
Dissolve sodium c i t r a t e i n water by s t i r r i n g a t 45-5OC. add
Won-Phosphate Laundry Powder
Formula LY-0048
Sodium Carbonate
Igepal CO-630
Sodi um S i 1icate
Sodium S u l f a t e
Carboxymethyl c e l l u lose
O p t i c a l Brightener
Wt.%
50.0
12.0
12.0
24.5
1.o
0.5
Procedur g
Add t h e sodium carbonate t o t h e mixer. Spray t h e Igepal
02-630 onto t h e sodium carbonate. Add t h e remaining ingredients
i n t h e order l i s t e d . Mix u n t i l a homogeneous, f r e e - f l o w i n g
product r e s u l t s .
Phvsi c a l P r o m r t 1os
Appearance: White, f r e e - f l o w i n g powder
pH, 1%Solution: 11.0
SOURCE: Rhone-Poulrnc Surfactanta & S p e c i a l t i e s : Formulas
84 Advanced Cleaning product Formulations
Fabric Pretreatment S p r i t z
Ingredients:
Neodol 25-7
Neodol 25-3
Versaflex 207 (25%)
Sodium Xylene Sulfonate (40%)
EDTA, Disodium S a l t
Water, Dye, Perfume, and Enzymes
Procedure:
1. Mix melted Neodol 25-7 and Neodol 25-3.
2. Add sodium xylene sulfonate and mix.
3. Add water and Versaflex 207, mix, and cool.
4. Add EDTA. dye, perfume, and enzymes.
Reference #8069:21
Low VOC Pump F a b r i c Antist-
Insredients:
Versaf 1ex 2004 (30%)
Ethanol
Propylene G1ycol
Preservative, Water, and Fragrance
9.75
5.25
20.00
15.00
0.50
4.s.
%%.
5.00
10.00
0.50
Q . S .
Procedure:
1. Mix Versaflex 2004 and water.
2. Add ethanol and mix.
3. Add propyl ene g l y c o l , preservative, and fragrance. and mix.
Reference #8069:97
SOURCE: National Strach and Chemical Corp.: Suggested Formula-
t i o n s
Laundrv Pre-Spotter and S t a i n Remover
Water
Sodium Meta S i l i c a t e (Anhydrous)
Detergent Concentrate 840
% by Weiaht
83.0
2.0
15.0
Procedure:
preservative as requi red.
SOURCE: Mona I n d u s t r i e s , Inc.: Suggested Formulation
Blend i n g r e d i e n t s i n order l i s t e d . Add c o l o r , fragrance and
Fabric Softener-1
Ingredients:
A H20 (50-6OC)
B Prapagen WK
C MgC12 (10% b . w . )
D Perfume
Dye
ad 100.00%
6.70%
0.10%
0.20%
q . s .
Fabric Softener-2
Ingredients:
A Genamin S-250
H3P04 (1 M; 9,5% b . w . )
H20 (50-60C)
8 Prapagen WK
C MgClP (10% b . w . )
D Perfume
Dye
Fabric Softener-3
Inqredients:
A Genamin 5-250 0.90%
H3P04 (1 M; 9,5% b . w . ) 0.45%
H20 (50-6OC) ad 100.00%
8 Prapagen WK 13.80%
Polyglykol 400 3.70%
C MgClZ (10% b . w . 1 1.OO%
0 Perfume 0.60%
Dye q . s .
Manufacturing:
I One a f t e r another, t h e components o f B are added t o A.
I 1 A t 40C, a d j u s t t h e v i s c o s i t y w i t h C (ca. 100-150 mPas).
I11 A t 30C the-components o f D are added.
Appl ic a t ion :
SOURCE: Hoechst Aktiengesellschaft: Detergents and C
1.0-2.0 g a c t i v e ingredient/kg t e x t i l e
Agents: Guide Formulations
2.00%
1.00%
ad 100.00%
17.30%
3.00%
0.60%
Q . S .
eani ng
Laundry Products 85
86 Advanced CleaningProduct Formulatiom
Fabric Softener. Low V i scosi tv-A
Marlosoft IQ 90
Balance water, fragrance, dyestuff
Active matter: 5.0%
Fabric Softener. Low V i scosi ty-B
Marlosoft IQ 90
Balance water, fragrance, d y e s t u f f
Active matter: 7.5%
%
5 . 6
t o 100
%
8.3
t o 100
Fabric Softener Concentrate. Low Viscosity-A
Marlosoft IQ 90
Calcium chloride, 25% (approx.)
Balance water, fragrance, d y e s t u f f
Active matter: 10.0%
Formulation A: double concentrate
%
11.1
0.1
t o 100
Fabric Softener Concentrate. Low Viscosity-B
Marlosoft IQ 90
Calcium c h l o r i d e , 25% (approx.)
Balance water, fragrance, d y e s t u f f
%
16.7
1.1
t o 100
Active matter: 15.0%
Formulation 8: t r i p l e concentrate
SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and
Cleaning Agents f o r Household Purposes
Heavy-dutv Detergent, Powder, SDrav Y i x i n a Process-A
Spray Mix:
M a r l i p a l 24/70 o r 013/70
O p t i c a l brightener
Ethylenediamine tetraacetate. 40%
Fragrance
%
4.0
0.2
0 . 8
0.2
B u i l d e r Mix:
Marlon ARL
Sodium soap powder
Z e o l i t e A
Sodium m e t a s i l i c a t e pentahydrate
Sodium perborate tetrahydrate
Tetraacetyl ethylenedi ami ne (TAED)
Sodium carbonate
Polycarboxylate, e.g. Sokalan CP 5
Carboxymethyl c e l l u l o s e
Sodium sulphate l i g h t , enzymes
A c t i v e matter: 13.2%
powder
8 . 0
2.8
25.0
5.0
20.0
3.0
10.0
4.0
1 .o
t o 100
Heavy-Duty Detergent. Powder, Soray Mixing Process-8
Spray Mix:
M a r l i p a l 24/70 o r 013/70
O p t i c a l brightener
Ethylenediamine tetraacetate, 40%
Fragrance
%
4.0
0.2
0 . 8
0.2
B u i l d e r Mix:
Marlon ARL
Sodium soap powder
Sodium t r i polyphosphate
Sodium d i s i l i c a t e
Sodi um perborate tetrahydrate
Tetraacetyethylenediamine (TAED)
Carboxymethyl c e l l u l o s e
Sodium sulphate l i g h t , enzymes
8 . 0
3.0
30.0
9.0
20.0
3.0
1.o
t o 100
A c t i v e matter: 13.4%
SOURCE: Huls America, I n c . : Basic Formulations o f Detergents
and Cleaning Agents f o r Household Purposes
Laundry Products 87
88 Advanced CleaningRoduct Formulations
Heavy-Duty Deteraent. Powder. Sprav Mixing Process-A
Spray Mix:
M a r l i p a l 013/939 o r 24/939
Fragrance
Ethylenediamine tetraacetate. 40%
Optical brightener
Builder Mix:
Z e o l i t e A
Sodium m e t a s i l i c a t e pentahydrate
Magnesium s i licate
Sodium perborate tetrahydrate
Tetraacetylethylenedi ami ne (TAED)
Sodi um carbonate
Carboxymethyl c e l l u l o s e
Sodium sulphate l i g h t , enzymes
Active matter: 9.0%
E!
10.0
0.2
1.o
0.2
30.0
5.0
1.o
25.0
3.0
15.0
1.5
t o 100
Heavy-Duty Deteraent. Powder. Sprav Mixing Process-8
Spray Mix:
M a r l i p a l 013/939 o r 24/939
Fragrance
Optical brightener
Builder Mix:
Sodium tripolyphosphate
Sodi um d i s i 1icate
Magnesi um s i 1icate
Sodium perborate tetrahydrate
Tetraacetylethylenediamine (TAED)
Carboxymethyl c e l l u l o s e
Sodium sulphate l i g h t , enzymes
Active matter: 9.0%
E!
10.0
0.2
0.2
28.0
5.0
1.o
25.0
3.0
1.o
t o 100
L i a u i d Heavy-Duty Deteraent. B u i l t Tvoe. Hieh Viscosity-A
%
Marlon PS 65 10.0
M a r l i p a l 013/30 5.0
1,2-Propylene g l y c o l * 5.0
C i t r i c a c i d 2.0
Z e o l i t e A, 50% s l u r r y 45.0
Balance water, fragrance, dyestuff, o p t i c a l brightener,
enzymes, preservative t o 100
Active matter: 11.5%
+ f u r t h e r products o f Huls AG
SOURCE: Hula America, I n c . : Basic Formulations o f Detergents and
Cleaning Agents f o r Household Purposes
Heavy D u t y L ia u i d Laundry Deterqent
Type DN
I n q r e d ients:
Stepan B i o S o f t D-62 ( a n i o n i c s u r f a c t a n t )
Neodol 25-7 (nonionic s u r f a c t a n t )
Propyl ene g l y c o l
E t h y l alcohol
Sodium C i t r a t e (Haarman & Reimer)
Sodium xylene s u l f o n a t e
Sodium borate (borax)
T r i ethanol ami ne (TEA) o r sodi um hydroxide
Parts by Weiqht
7.0
16.0
7.0
5.0
5.0
10.0
1.o
t o pH 9.5
Dissolve the Sodium C i t r a t e and sodium borate i n approxim-
a t e l y 20 m l water. Apply heat i f necessary t o d i s s o l v e . Combine
t h e s u r f a c t a n t s , propylene g l y c o l and e t h y l a l c o h o l . Add t h e
Sodium C i t r a t e and sodium borate s o l u t i o n t o t h e s u r f a c t a n t s
mixture. Add t h e sodium xylene s u l f o n a t e . Adjust t h e pH t o 9 . 5
using TEA o r d i l u t e sodium hydroxide. B r i n g t h e volume o f t h e
m i x t u r e t o 100 m l using water.
I f an enzyme detergent i s desired, t h e f o l l o w i n g should be
added :
Sodium borate (borax) add an a d d i t i o n a l 2.0
Calcium c h l o r i d e 0.1
Protease 0 . 6
Dissolve t h e Sodium C i t r a t e , sodium borate and calcium chlo-
r i d e i n water. Apply heat i f necessary t o d i s s o l v e . Combine the
s u r f a c t a n t s , propylene g l y c o l and e t h y l a l c o h o l . Add t h e Sodium
C i t r a t e , sodium borate and calcium c h l o r i d e s o l u t i o n t o t h i s
mixture. Add sodium xylene sulfonate. Adjust t h e pH t o 8.0
w i t h TEA o r d i l u t e sodium hydroxide. Add t h e Protease. B r i n g
t h e volume o f t h e mixture t o 100 m l using water.
The a d d i t i o n o f fragrance, dye, o p t i c a l brightener, a n t i -
r e d e p o s i t i o n agent, corrosium i n h i b i t o r , e t c . , i s o p t i o n a l .
SOURCE: Haarman & Reimer Corp.: Suggested Formulation
B u i l t Formulation #1
I n a r e d ient :
Water
Na3NTA
Na Gluconate
45% KOH
42 S i l i c a t e N
Glycol Ether
Nonion ic Surfa c tant
Amphoteric
Weight .%
68% -
1%
1%
10%
10%
5%
2% '
3%
Both t h e Amphoteric SC and t h e competitive imidazoline coupled
t h e f o r m u l a t i o n together w i t h 3% o f amphoteric.
SOURCE: Tomah Products, I n c . : Suggested Formultion
Laundry Products 89
90 Advanced CleaningProduct Formulations
I n q r e d
Neodol
Neodol
Heavy Duty L i q u i d Laundry Detergent
Type TA
ie n t s :
25-7 ( n o n i o n i c s u r f a c t a n t )
25-35 ( a n i o n i c s u r f a c t a n t )
Sodium l a u r y l s u l f a t e ( a n i o n i c s u r f a c t a n t )
Stepan B i o S o f t D-62 (LAS-anionic s u r f a c t a n t )
T r i ethanolami ne (TEA)
Propylene g l y c o l
Potassium C i t r a t e (Haarman & Reimer Corp.)
E t h y l a l c o h o l
Calcium c h l o r i d e
Sodium b o r a t e (borax)
Protease
Water q.s
P a r t s I
t o
a L ! W s h t
5.0
10.0
12.0
8.0
5.0
7.0
6.0
7.0
0 . 1
3 . 0
0.6
100 p a r t s
Dissolve t h e Potassium C i t r a t e , calcium c h l o r de and sodium
b o r a t e i n approximately 20 m l water. Apply heat f necessary
t o d i s s o l v e . Combine t h e s u r f a c t a n t s , TEA, propy ene g l y c o l and
e t h y l a l c o h o l . Add t h e Potassium C i t r a t e , calcium c h l o r i d e
and sodium b o r a t e s o l u t i o n . A d j u s t t h e pH of t h e s o l u t i o n t o
8 . 0 w i t h TEA o r d i l u t e sodium hydroxide. Add t h e Protease.
B r i n g t h e volume o f t h e m i x t u r e t o 100 m l using water.
The a d d i t i o n o f fragrance, dye, o p t i c a l b r i g h t e n e r , a n t i -
r e d e p o s i t i o n agent, c o r r o s i o n agent, c o r r o s i o n i n h i b i t o r , e t c . ,
i s o p t i o n a l .
SOURCE: Haarman & Reimer Corp.: Suggested Formulation
!&Md Laundry_ D_etergents
InQ r e dj.=ts:
Water
Glucopon 6OOCSUP (50%)
E thano1
Trycol 5963
I n redients.;
i a F e r
Sodi um C i t r a t e
S u l f o t e x SXS
Glucopon 6OOCSUP (50%)
Ethanol
S u l f o t e x 6040 S (59%)
We 1 ght%
72
10
3
15
Weight%
32
5
5
15
5
38
Add i n t h e order l i s t e d , d i s s o l v i n g each i n g r e d i e n t com-
p l e t e l y . Use moderate a g i t a t i o n and i n c o r p o r a t e c o l o r s and
fragrances as r e q u i r e d .
SOURCE: Henkel Corp.: CD D i v i s i o n : Glucopon S u r f a c t a n t s :
Suggested Formulations
Heavv Dutv L i q u i d Laundry Deterqent
Type WA
I n a r e d ie n t s : __P a r t s by Weiaht
Stepan B i o S o f t D-62 (LAS-anionic s u r f a c t a n t ) 28.0
Neodol 25-7 ( n o n i o n i c s u r f a c t a n t ) 7 . 0
Sodium xylene s u l f o n a t e 12.0
T r i ethanolami ne (TEA) 2 . 0
Sodium C i t r a t e (Haarman & Reimer Corp.) 12.0
Water 9 , s . t o 100 p a r t s
Dissolve Sodium C i t r a t e i n approximately 20 m l water. Combine
t h e s u r f a c t a n t s , sodium xylene s u l f o n a t e and TEA. Add t h e
Sodium C i t r a t e . Adjust t h e pH o f t h e s o l u t i o n t o 11 u s i n g
d i l u t e sodium hydroxide. B r i n g t h e volume o f t h e m i x t u r e t o
100 m l u s i n g water.
added :
I f an enzyme detergent i s desired, t h e f o l l o w i n g should be
Sodi um b o r a t e (borax) 3.0
Cal c i um c h l o r i d e 0.1
Propylene g l y c o l 7 . 0
Protease 0.6
D i s s o l v e t h e sodium borate, calcium c h l o r i d e and Sodium i
C i t r a t e water. Apply heat i f necessary t o d i s s o l v e . Combine
t h e s u r f s t a n t s , sodium xylene s u l f o n a t e , TEA and propylene
g l y c o l . Add t h e sodium borate, Sodium C i t r a t e and calcium
c h l o r i d e s o l u t i o n t o t h i s m i x t u r e . Adjust t h e pH t o 8.0 w i t h
TEA o r d i l u t e sodium hydroxide. Add t h e Protease. B r i n g t h e
volume o f t h e m i x t u r e t o 100 m l using water.
r e d e p o s i t i o n agent, c o r r o s i o n i n h i b i t o r , e t c . , i s o p t i o n a l .
SOURCE: Haarman & Reimer Corp.: Suggested Formulation
The a d d i t i o n of fragrance, dye, o p t i c a l b r i g h t e n e r , a n t i -
B u i l t Formulation #2
I n a r e d i e n t :
Water
Na M e t a s i l i c a t e pentahydrate
STPP
Nonionic s u r f a c t a n t
Amphoteric s u r f a c t a n t
Weight .%
79%
1%
10%
5%
5%
Both t h e Amphoteric SC and t h e c o m p e t i t i v e amphoteric coupled
t h e f o r m u l a t i o n together w i t h 5% o f amphoteric.
SOURCE: Tomah Products, I n c . : Suggested Formulation
Laundry Products 91
92 Advanced CIeaningRoduct Formulations
L iauid Heavv-Duty Detergent. Low V i scosit v - A
Marlon PS 65
Marl ipal 013/89
Caustic potash, 50% (approx.)*
Coconut f a t t y a c i d
T r i ethhnol ami ne R*
1.2-Propylene g l y c o l *
Ethanol*
Phosphonate, e.g. Dequest 2060 S
Sodi um formi ate*
Balance water, fragrance, dyestuff,
enzymes, preservative
Active matter: 45.0%
%
20.0
17.2
3.9
10.0
5.0
3.0
8.0
1.5
1.o
o p t i c a l brightener,
t o 100
L i a u i d Heavy-Dutv Detergent. Low Viscositv-B
s6
Marlon PS 65 20.0
M a r l i p a l 013/129 3.9
Marlox FK 64 12.0
Caustic potash, 50% (approx.)* 3.9
Coconut f a t t y a c i d 10.0
Triethanolamine R* 5.0
1,P-Propyl ene g l y c o l * 3.0
Ethanol* 8.0
Phosphonate, e.g. Dequest 2060s 1.5
Sodi urn formi ate* 1.o
Balance water, fragrance, d y e s t u f f , o p t i c a l brightener,
enzymes, preservative t o 100
Active matter: 45.0%
L i a u i d Heavy-Duty Deteraent. B u i l t Type. H i g h Viscositv-B
%
Marl ip a l 013/30 5.0
C i t r i c a c i d 1. o
Z e o l i t e A, 50% s l u r r y 45.0
Balance water, fragrance, dyestuff, o p t i c a l brightener,
enzymes, preservative t o 100
Marlon PS 65 10.0
Active matter: 11.5%
* f u r t h e r products o f Huls AG
SOURCE: Huls America, I n c . : Basic Formulations o f Detergents
and Cleaning Agents f o r Household Purposes
Light-Duty Deterqent. Powder. Spray M i x i n q Process-A
Spray Mix:
M a r l i p a l 013/939 o r 24/939
Marlamid DF 1218
Fragrance
%
5.0
1.0
0.2
B u i l d e r Mix:
Z e o l i t e A
Sodi um d i s i 1ic a t e
Carboxymethyl c e l l ulose
Sodium sulphate l i g h t
Post Mix:
Marlon ARL
A c t i v e matter: 17.5%
40.0
3 . 0
1.o
34.8
15.0
L i ght-Duty Deterqent ~ Powder, Spray M i x i ng Process-€3
Spray Mix:
M a r l i p a l 013/939 o r 24/939
Fragrance
%
3.0
0.2
B u i l d e r Mix:
Z e o l i t e A
Sodi um d i s i 1i c a t e
Carboxymethyl c e l l u l o s e
Sodium sulphate l i g h t
Post Mix:
Marlon ARL
A c t i v e Matter: 17.1%
45.0
5.0
1 .o
22.8
18.0
L i q u i d Light-Duty Detergent, w i t h Incorporated Softener,
Low V i scosi ty-A
Marl i p a l 24/99
Marlox FK 64
Marlosoft I0 90
Ethanol *
Balance water, fragrance, d y e s t u f f
9b
15.0
5.0
5 . 0
10.0
t o 100
A c t i v e Matter: 23.0%
* f u r t h e r products o f Huls AG
SOURCE: Huls America, I n c . : Basic Formulations o f Detergents
and Cleaning Agents f o r Household Purposes
Laundry Products 93
94 Advanced Cleaning Product Formulations
L iQuid L ight-Duty Detergent. Low V i scosit y - A
Marlon PS 65
Marl inat 242/28
Marlamid DF 1218
Coconut f a t t y a c i d
Caustic potash, 50% (approx.)*
Ethylenediamine tetraacetate, 40%
Balance water, fragrance, dyestuff,
sodium c h l o r i d e
Active matter: 23.5%
Formulation A f o r machine-wash
%
20.0
12.0
3.0
4.0
1.4
0.2
preservative,
t o 100
L iauid L ight-Duty Detergent, Low V i scosity-B
%
M a r l i n a t 242/28 40.0
Marlamid DF 1218 3.0
Marlamid PG 20 3.0
Balance water, fragrance, dyestuff, preservative,
sodium c h l o r i d e t o 100
Active matter: 16.2%
Formulation B f o r manual-wash
L i q u i d Light-Duty Detergent, w i t h Incorporated Softener,
Low V i scosity-B
Marl i p a l 24/99
Marlox FK 64
Ampholyt JB 130
Marlosoft I Q 90
Balance water, fragrance, d y e s t u f f
%
5 . 0
5 . 0
25.0
5.0
t o 100
Active matter: 21.5%
* f u r t h e r products o f Huls AG
SOURCE: Huls America, I n c . : Basic Formulations o f Detergents
and Cleaning Agents f o r Household Purposes
Part A
Igepal CO-660
Calsoft F-90
Water
I n d u s t r ia1 Laundry Two-Part Systems
Formula LY-0052
Uniforms (Petroleum Greases and O i l s )
2
90
Part B
Sodium S i l i c a t e (Si02/Na20 1.6-2.5) 100
Hotel/ L i nen SUDD~Y(Ani ma1 and Vegetable Greaser
Part A
Igepal CO-660
Calsoft F-90
Water
Part B
Potassi um Hydroxide (45%)
STPP, TKPP o r KTPP
Sodium Carbonate
Igapal CO-660
Sodi um Tripolyphosphate
Sodium M e t a s i l i c a t e
Optical B r i ghtener
t o t h mixer. S
CO-660. Add t h e remaining ingredients i n t h
Mix u n t i l uniform.
Wt.%
10
2
88
85
15
I n d u s t r i a l Laundry Powder
Uniforms
Formula LY-0050
Procedure
Add t h e sodi um carbona
Wt.%
52.5
15
20
12
0 . 5
ray on t h e Igepal
order 1isted.
Phvsic a l ProDerti8s
Appearance: White, free-flowing powder
pH, 1% Solution: 11.4
SOURCE: Rhone-Poulenc Surfactants & Specialties: Formulas
Laundry Products 95
96 Advanced CleaningProduct Formulations
Laundry Liauids
Calsuds o r C a l s o f t based products remove ground-in d i r t and
grease i n heavy f a b r i c s and g e n t l y clean d e l i c a t e k n i t s i n c o l d
water. They i n h i b i t s t a t i c build-up and provide l u b r i c i t y ,
f u l l i n g and softening.
"Fine Care" Fabric Detergents
P i l o t Formula ULDY-003-01
Calsuds CD-6
Cal foam ES-303
P i l o t SXS-40
Cal s o f t LAS-99
Water
Calsuds CD-6
Cal foam ES-303
P i l o t SXS-40
Cal s o f t LAS-99
Water
C i t r i c Acid
Perfume and Color
Preservative
Water
50% NaOH
D i ethanol ami ne
Propylene Glycol
Cal s o f t LAS-99
Caloxyl a t e N-9
Water
50% NaOH
D i ethanol ami ne
P i l o t SXS-40
C a l s o f t LAS-99
Cal oxyl a t e N-9
P i l o t Formula ULDL-003-01
Heavy Duty Laundry Liquids
P i 1o t Formula #HDL-004-01
Pi l o t Formula #HDL-005-01
% bv Weipht
19.90
15.15
10.20
4.96
49.79
% by Weiqht
20.00
15.00
10.00
5.00
50.00
Q.S. pH 7
Q . S .
Q.S.
% by Weiqht
36.60
6.40
7.00
5.00
40.00
5.00
% bv Weiqht
30.40
4.60
5.00
25.00
30.00
5.00
SOURCE: P i l o t Chemical Co. : Household C1eaner Formul a t i ons
Laundry Powder Deteraent
Formula LY-0047
Sodium Carbonate
C a l s o f t F-90
Rhodapex NA-61
Rhodasurf 25-7
Sodium M e t a s i l i c a t e Pentahydrate
Sodi um S u l f a t e
Zeol it e
Sodi um Perborate
Enzymes can be added
Dye
Perfume
Procedure
Add t h e sodium carbonate t o t h e mixer.
pex NA-61 and t h e Rhodasurf 25-7. Add t h e
i n t h e order l i s t e d and mix u n t i l uniform.
Wt.%
44.0
14.0
6.0
2.0
4.0
10.0
18.0
2.0
Spray on t h e Rhoda-
remai n i ng ingredients
Physical ProDerties
Appearance: White, free-flowing powder, dyed t o preference.
pH, 1 % Solution: 11
I n d u s t r i a l Laundry One-Shot L i a u i d
Formula LY-0049
Water
Igepal CO-630
Igepal CO-710
Cheelox BF-13
Potassi urn Hydroxide (45%)
Miranol FBS
Wt.%
69
3
3
10
10
5
Procedur e
Phvsi cal P r o v e r t iea
Add t h e ingredients i n t h e order l i s t e d . Mix u n t i l uniform.
Appearance: Clear l i q u i d
pH. as i s : 13.0
pH, 1% s o l u t i o n : 11.8
S p e c i f i c Gravity: 1.06
V i s c o s i t y : <lo cps
SOURCE: Rhone-Poulenc Surfactants a S p e c i a l t i e s : Formulas
Laundry Products 97
98 Advanced CleaningProduct Formulafions
L i q u i d Heavy Duty Detergent HDLD
Soap based
Ingredients:
A Genapol OA-080
F a t t y a c i d (2/3 o l e i c , 1/3 COCO)
KOH (85%)
1,2 Propyleneglycol
Water (50-6OC)
T r i sodi um-ci t r a t e x 2H20
Savi nase
Alcalase
Termamyl
Parfum
F a r b s t o f f
8 Tinopal CBS-X
C Hostapur SAS 60
D Ethanol
12.00%
14.00%
3.50%
5 .OO%
0.10%
39.40%
17.00%
5.00%
3.00%
0.50%
0.20%
0.30%
0.20%
0.10%
Manufacturing:
I Dissolve 8 i n A.
11 One a f t e r another, t h e components o f C are added t o I
I11 A t 25C, t h e components o f D t o 11.
L i q u i d Detergent "FSL" A
Ingredients I
r- Genapol CIA-080
F a t t y a c i d ( P r i f a c 7976)
KOH (85%)
T r i ethanolamine
1.2 Propyleneglycol
8 Tinopal CBS-X
Water (50-6OC)
C Hostapur SAS 60
T r i sodi um-ci r a t e x 2H20
Dequest 2066
D Ethanol
Savi nase
A1c a lase
Termamyl
Perfume
Dye
12.00%
14.00%
2.60%
2.00%
5.00%
0.20%
34.20%
17.00%
5.00%
4.00%
3.00%
0.50%
0.20%
0.30%
q . s .
q.s.
Manufacturing:
I Dissolve 8 i n A.
I 1 One a f t e r another, t h e components o f C are added t o I.
I11 A t 25C, t h e components o f D t o I.
SOURCE: Hoechst Aktiengesellschaft: Detergents and Cleaning
Agents: Guide Formulations
Thick Bleach-1
L iqui d
Ingredients.;
A Genaminox MY
Medialan LD
NaOH (100%)
B Water
C Sodiumhypochlorite - s o l u t i o n
(150 g/L a c t i v e c h l o r i n e )
D Perfume (e.g. Hypofresh)
Manufacturing:
I B i s added t o A.
I 1 S t i r C t o I.
I11 A t l a s t D i s added.
V i s c o s i t y ( B r o o k f i e l d RVT, sp.4, 22C, mPas): 4800
m g k Bleach-2
I n g r e d i e n t s :
A Genaminox MY
Medialan LD
NaOH (100%)
B Water
C Sodiumhypochlorite - s o l u t i o n
(150 g/L a c t i v e c h l o r i n e )
D Perfume (e.g. Hypofresh)
Manufacturing:
I B i s added t o A.
I 1 S t i r C t o 1.
111 A t l a s t D i s added.
V i s c o s i t y ( B r o o k f i e l d RVT, sp.4, 22C. mPas): 600
12.000%
2.500%
1 .OOO%
34.475%
50.000%
0.025%
6.000%
1.000%
1.000%
41.975%
50.000%
0.025%
SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Detergents and Cleaning
Agents: Guide Formulations
Laundry Products 99
100 Advanced CleaningR&ct Formulotions
Wool DeterQent, Medium Viscosity-A
Marlon PS 65
Marl inat 242/28
Marlamid DF 1218
Balance water. dyestuff, fragrance, preservative.
sodium c h l o r i d e
Active matter: 20.5%
Wool Detergent. Medium Viscosity-B
Marlon PS 65
M a r l i n a t SRN 30
D i o n i l OC
Balance water, dyestuff, fragrance, preservative,
sodium c h l o r i d e
Active matter: 20.0%
Wool Detergent. Medium V i scositv-A
Marlon AS3
Marl inat 242/28
Ammonium hydroxide, 25%
Urea
Balance water, fragrance, dyestuff, preservative.
sodium c h l o r i d e
Active matter: 19.0%
Wool Detergent. Medium Viscosity-B
Marlon A 375
Marl inat 242/28
Marlamid DF 1218
Balance water, fragrance, dyestuff, preservative,
sodium c h l o r i d e
Active matter: 20.5%
%
18.0
28.0
1.o
t o 100
%
20.0
20.0
1.o
t o 100
%
12.0
18.0
3.0
3.0
to 100
%
15.6
28.0
1.o
t o 100
SOURCE: Huls America, Inc.: Basic Formulations o f Detergents
and Cleaning Agents f o r Household Purposes
9. Metal Cleaners and Polishes
101
102 Advanced Cleoning Product Formulations
A l u m i nun C1eaner/Bri shtener
Acid Cleaner for Aluminum Wheels and T r a i l e r s
Inqredi ent :
Deionized Water
Phosphoric Acid (85%)
C i t r i c Acid (50%)
N i t r i c Acid (70%)
Avanel S-70
Wt.%
83.00
6.00
8.00
1.oo
2.00
pH (as i s ) : <2.0
Appearance: Clear, white-water l i q u i d
Charge t h e water t o an appropriate mixing vessel. Charge
WARNING: Use a l l manufacturer precautionary s a f e t y meas-
Procedure:
remaining ingredients i n t h e order l i s t e d w h i l e continuing
a g i t a t i o n .
ures when hand1 ing concentrated a c i d s o l u t i o n s .
Formula CM-101
A1urninum Smut C1eaner
High Temperature D i l u t a b l e Acid Concentrate
I n s r e d i ent :
Deioni zed Water
C i t r i c Acid (50%)
Gluconic Acid (50%)
Avanel N-1525-90
Avanel S-70
Ammoni um B i f 1u o r i de
Wt.%
19.00
50.00
25.00
3.00
1.50
1.50
pH (as i s ) : <2.0
Appearance: Clear, water-white t o l i g h t - y e l l o w l i q u i d
S p e c i f i c G r a v i t y : 1 .18
Procedure:
Charge t h e water and two acids under a g i t a t i o n . Continue
a g i t a t i o n and add t h e Avanel surfactants; mix u n t i l dissolved.
Add Ammonium B i f l u o r i d e and mix u n t i l dissolved.
Use D i r e c t ion8 :
Use temperature o f d i l u t i o n i s normally 140-15OF.
Notes:
This formula was developed t o remove stamping o i l smut from
aluminum cans. Cans should be thoroughly r i n s e d a f t e r cleaning
Formula CM-104
SOURCE: Mazer Chemicals: SUQQeSted Formulations
Use i n pressure wash a t a r a t e o f 2-4 ounces per gallon.
Metal Cleaners and Polishes 103
Alumcnum Cleaner Concentrate
Water
Sodium M e t a s i l i c a t e (Anhydrous)
Tetrapotassium Pyrophosphate (Powder)
Mona NF-10
% by Weiqht
75
10
5
10
Procedure:
i n water w i t h mixing, then add Mona NF-10.
Typical Properties:
Appearance: Clear l i q u i d
Cloud Point: 88C
Dissolve sodium m e t a s i l i c a t e and tetrapotassium pyrophosphate
Recommended Use D i l u t i o n :
1 t o 4 oz/gal.
Formula F-498
A1umi num Wash
Water
Sodium M e t a s i l i c a t e (Anhydrous)
Tetrasodium Pyrophosphate (Powder)
B u t y l Carbi t o 1
Mona NF-10
% by Weight
88
2
3
2
5
Procedure:
i n water, then add Butyl C a r b i t o l and Mona NF-10.
Typi c a l Properties :
Dissolve sodium m e t a s i l i c a t e and tetrasodium pyrophosphate
Appearance: Clear l i q u i d
pH: 1 2 . 8
Recommended Use D i l u t i o n :
1:lO w i t h water
Formula F-499
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formulations
104 Advanced CleaningR&t Formulations
Cleaners and Cleanina Solutionq
Metal Cleani na-A1 k a line
Inaredients:
Aerosol 22 Surfactant
Sodium Carbonate
Sodi um Metasi 1icate
Sodium Hydroxide
% by Weiaht
10.0
40.0
20.0
10.0
Grind the powders together and add t h e Aerosol 22 slowly while
grinding.
Metal C1eani na-Aci d
Inqredients:
Dowanol EB
Phosphoric Acid (85%)
Aerosol 22 Surfactant
Water
Metal C leanina-Pai n t Removal
Insredients:
Aerosol C-61 Surfactant
Sodium Carbonate
Sodium Metasilicate
Sodi um Hydroxide
% by Wei aht
6.0
7 . 0
0 . 3
8 6 . 7
% by Wei aht
20.0
40.0
30.0
10.0
Grind t h e powders together and add t h e Aerosol C-61 slowly
while mixing.
Metal Cleaning-Rust Removal
Ineredients:
Aerosol 0s Surfactant
Sodium B i f l u o r i d e
Sodium Tetraphosphate
Sodium B i s u l f i t e
% by Weight
10.0
7 5 . 0
10.0
15.0
SOURCE: Cytec Industries Inc.: Suggested Formulations
Metal Cleanersand Polishes 105
Comer C leani ng
Inaredients:
Aerosol A-102 Surfactant
Sodium Chloride
C i t r i c Acid
Eentonit e
Water
Aluminum Cleaning - A c i d
Inaredients:
Phosphoric Acid (65%)
Hydrofluoric Acid (48%)
Glacial Acetic Acid
Aerosol 0s Surfactant
Water
A1uninum C1eanina-Bri ahtening
Ingredients:
Phosphoric Acid (85%)
Aerosol 22 Surfactant
Aerosol 0s Surfactant
Butyl Cellosolve
Water
Aluminum Aircraft-Brightener (U.S.
Ingredients:
Aerosol 0s Surfactant
Aerosol 22 Surfactant
C i t r i c Acid
Arnmoni urn B i f 1u o r ide
Benzenesulfoni c Acid
Phosphoric Acid (85%)
Water
% bv Weiaht
2.0
5.0
5.0
22.0
66.0
% bv Wei Qht
15.0
2.0
3.0
5.0
75.0
% by Wei Qht
47.2
1.o
1.o
16.0
34.8
Patent 2.68Y.3461
% bv Weiaht
3.0
9.0
5.0
3.0
10.0
2.4
26.4-52.6
SOURCE: Cytec In d u stri e s Inc.: Suggested Formulatlons
lo6 Advanced CleaningProduct Formulations
E le c t r o c leaner
Components:
Water
Burco BSGH-400
Burco NPS-225
Burco TME
50% NaOH
% by Weiaht
2-0
1-4
0.75-3
0.25-1
To 100% Total
Basic formulating guidelines:
1) Ratio o f Burco NPS-225/Burco TME should be 3/1.
2) The l e v e l o f Burco BSGH-400 i s p r e fe r ably equal t o the sum
3 ) The water charge should be equal t o the sum o f Burco BSGH-400,
4) Premix a l l components but NaOH. then add NaOH w i t h s t i r r i n g .
This formulation w i l l provide moderate foam l e v e l s and i s
s u i t a b l e f o r use as an electrocleaner, food p l a n t cleaner o r
other applicatio n s where high ca u sti c concentrates are used.
For reduced foam l e v e l s as i n an a l k a l i n e spray cleaner, replace
Burco NPS-225 w i t h Burco HCS-50NF.
o f Burco NPS-225 and Burco TME.
Burco NPS-225 and Burco TME.
Moderate A1k a l in it y , Soi 1 So1it t i n a Soak Cleaner
ComDonents:
Water
Sodium Metasilica te (Pentahydrate)
Trisodium Phosphate (Crystals)
Burco ADS-40
Burco EHS
Burco TME
% bv Weiaht
70
5
10
5
5
5
Procedure:
Add components i n th e order l i s t e d . S t i r u n t i l homogeneous
between each addition.
SOURCE: Burlington Chemical Co., I n c . : Suggested Formulations
Metal Cleanersand Polirhes 107
Hiah-Foaming A c i d Scrubber*
Formula BC-0003
Miranol FBS
Igepal CO 630
Sulfamic A c i d
G1ycol ic (Hydroxyaceti c ) Acid (70%)
Butoxyethanol
Water
Wt.%
5.0
2.0
4.0
4.0
3.0
82.0
Procedure
olved. Add t h e remaining i n g r e d i e n t s , w i t h mixing. Mix u n t i l
uniform.
Add t h e water, sulfamic and g l y c o l i c acids. Mix u n t i l d i s s -
Physical ProDerties
Appearance: Clear l i q u i d. .
pH, as i s : 1.5
S p e c i f i c G r a v i t y : 1
V i s c o s i t y : t10 cps
* S u i t a b l e f o r appl i c a t
Rhodafac RE-61 0
Igepal CO-630
Phosphoric Acid, 75%
Water
027
ons w i t h a t r i g g e r - t y p e sprayer.
A c i d Cleaner
Formula BC-0004
Wt.%
3.0
4.0
10.0
83.0
Procedure
Add phosphoric a c i d t o water and heat w i t h a g i t a t i o n t o 50C.
w i t h r a p i d b u t smooth a g i t a t i o n . Slowly blend i n Rhodafac RE-610
and Igepal CO-630. Once system i s completely uniform, cool w i t h
s t i r r i n g t o 40-45C, and package.
Physical ProDertiea
Appearance: S l i g h t l y hazy l i q u i d
pH, as i s : 1.6
Speci f i c G r a v i t y : 1.03
V i s c o s i t y : 20 cps
SOURCE: Rhone-Poulenc S u r f a c t a n t s 8 Speci'alties: Formulas
108 Advanced CleaningProduct Fotmulations
Metal C1eaner and Deereaser
InQredi ents:
Monoethanolamine
Sodium DDBSA, 35%
Sandoxylate SX 400
Sodium EDTA
Water
Oleic Acid
D-Li monene
Butyl Cellosolve
% bv Weight
5.0
12.0
5.0
0.5
50.5
10.0
3.0
6.0
Procedure:
add DDBSA. Mix i n Sandoxylate SX 400, and EDTA. Warm t o 50C,
add the o l e i c a ci d slowly, w h i l e increasing t h e a g i t a t i o n . When
t h e o l e i c a c i d has completely reacted, add D-Limonene and Butyl
Cellosolve. Cool w i t h s t i r r i n g t o 40C. B o t t l e .
Properties:
Charge monoethanolamine and water t o vessel. With s t i r r i n g .
pH (as i s ) : 10.0
Viscosity: Approx. 100 cps Br o o kfi e l d LVT, Spindle #2 @ 12 rpm
% Solids: 26%
SOURCE: Sandoz Chemicals Corp.: Formulation HHG-10
Thickened Clear Deareaser Concentrate
Water, D . I .
DeSonic 9N
Varonic DM55
d ' L imonene
% by Weight
42.5
25.0
12.5
20.0
Blend1ng Procedure:
each addition.
Typical Properties:
Viscosity, cps: 363
Solids: 37.5%
pH: 5.9
Add ingredients i n order shown and dissolve completely between
SOURCE: Witco Corp.: Formula 805
Metal Cleanersand Polishes 109
Stainless Steel Cleaner-A
M a r l i p a l KF
Marlophor CS a c i d
Solvent BG*
Balance water, fragrance, dyestuff, preservative
Active matter: 1.0
V i scosi t y : 1iqui d
S t a i n less Steel C1eaner-B
Mar1ip a l 013/99
Aluminum oxide FPTO
I s o p a r a f f i n . e.g. Shellsol T
Balance water, fragrance, dyestuff, preservative
A c t i v e matter: 5.4
V i s c o s i t y : medi um
Formulation B w i t h abrasive
S i l v e r Polish, Liauid-A
M a r l i p a l KF
Thiourea
Phosphoric acid, 85%
Isopropanol*
Balance water
Active matter: 0.5%
S i l v e r Polish. Liauid-B
Marlazin L 10
Marlophor CS a c i d
Thiourea
Phosphoric acid, 85%
Balance water
%
1.o
10.0
5.0
t o 100
%
6.0
25.0
40.0
t o 100
%
0.5
6.0
2.0
3.0
t o 100
%
1.5
5.0
2.5
20.0
t o 100
Active matter: 1.5%
SOURCE: Huls America, Inc.: Basic Formulations o f Detergents and
Cleaning Agents f o r Household Purposes
10. Oven, Grill and
Hot Plate Cleaners
110
Oven, Grill and Hot Plate Cleaners 111
Pump Sprav Oven Cleaner
-Ingredient;
P a r t A :
Vegetable gum (Veegum T)
Xanthan gum
Water
-.Percent b v Wei q h t
1.2
0 . 4
78.9
P a r t B:
L i q u i d C i t r i c Acid--50% (Haarman & Reimer Corp.) 7 . 0
Sodium h y d r o x i d e s o l u t i o n 50% 4.5
P a r t C:
Amphoteric s u r f a c t a n t 8 . 0
Prepare P a r t A by s l o w l y adding v e g e t a b l e gum and xanthan
gum t o t h e w a t e r . Continue a g i t a t i n g u n t i l smooth d i s p e r s i o n
i s o b t a i n e d .
t o a separate t a n k and n e u t r a l i z i n g i t w i t h t h e sodium h y d r o x i d e
s o l u t i o n . The n e u t r a l i z a t i o n s h o u l d be done s l o w l y and c o n t i n -
u o u s l y under a g i t a t i o n , as t h e r e a c t i o n i s h i g h l y exothermic.
Prepare P a r t B ( t r i s o d i u m c i t r a t e ) by adding t h e c i t r i c a c i d
Add P a r t B t o P a r t A, and f i n a l l y P a r t C .
The f o r m u l a t i o n has t h e c o n s i s t e n c y o f a f l u i d g e l . I t may be
used i n e i t h e r warm o r c o l d ovens. The s p r a y i n g s h o u l d be done
a t a d i s t a n c e o f f r o m 10 t o 15 inches. Clean by w i p i n g a f t e r
a t l e a s t 10 minutes o f r e a c t i o n t i m e .
SOURCE: Haarman & Reimer Corp.: Suggested F o r m u l a t i o n
C a u s t i c Oven C1eaner
I n g r e d i egt_s_: % b y Weight
( 1 ) K o r t h i x H 2 . 0
( 2 ) Kelzan 0.3
( 3 ) Deionized Water 8 6 . 7
( 4 ) Sodium Hydroxide (50%) 10.0
( 5 ) Avanel S-74 1 .o
Procedure:
Add ( 1 ) t o ( 3 ) and mix a t h i g h speed. A f t e r ( 1 ) i s w e l l d i s -
persed, add (2) and ( 5 ) . Reduce speed and add ( 4 ) c a r e f u l l y and
s l o w l y .
F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s of
each p r o d u c t used.
SOURCE: K a o p o l i t e , I n c . : Suggested F o r m u l a t i o n
O v e n / G r i l l Cleaner
Wt%
Water 78
Tetrasodium EDTA 2
Sodium Hydroxide (50%) 15
Glucopon 425 CS 5
SOURCE: Henkel Corp., CD D i v i s i o n : Suggested F o r m u l a t i o n
11 Polishes, Coatings and Finishes
112
Polishes, Coatings and Finishes 113
Aerosol F u r n i t u r e P o l i s h
(Carbon D i o x i d e Propel l a n t l
Materi a1s:
P a r t A:
Isopar E
Hoechst Wax A3 CS
SF 96 (100)
V i s c a s i l (10,000)
Span 80
P a r t 8:
Water
Procedure:
1.) Heat P a r t A t o 85C.
2 . ) Heat P a r t 8 t o 70C.
3.) Add P a r t 8 t o P a r t A w i t h h i g h shear mixing.
4.) Cool t o room temperature when homogeneous.
Preparation o f Aerosol:
Loadi ng:
P o l i s h Concentrate
Carbon Dioxide
Aerosol Valve:
P r e c i s i o n Valve P a r t Numbers:
*This w i l l g i v e a can pressure o f approximately
Button: P a r t No. 01-5843 (0.020" MBFT RS)
Stem: P a r t No. 04-1215 (0.016")
Gasket: P a r t No. 05-0310 (BUNA)
Body: P a r t No. 07-1901 (0.080")
5.) Package i n s u i t a b l e containers.
Part/Wt(%)
22.5
0.5
2.3
0.5
0.3
73.9
Part/Wt(%)
97.5
2.5*
105 p s i g .
General Purpose L iauid Pol ish
(Oil-In-Water Type)
Mater ia1s : Part/Wt (%l
P a r t A:
SF 96 (350) 2.50
Hoechst Wax E 1.50
O l e i c Acid 1.50
P a r t 8:
Water 70.05
Carbopol 934 0.25
Morphol ine 1.60
Kathon CG 0.10
P a r t C:
Isopar M 2.00
SF 1706 1.50
P a r t D:
K a o p o l i t e SF 8 . 0 0
Procedure:
1.) Heat P a r t A t o 95C. (2.) Heat P a r t B t o 85C. (3.) Add P a r t
A t o P a r t 8 w i t h h i g h shear mixing. ( 4 . ) When homogeneous,
cool t o 60C and add P a r t C w i t h h i g h shear mixing. ( 5 . ) Add
P a r t D w i t h moderate mixing. ( 6 . ) Cool and package i n
s u i t a b l e containers.
V i s c a s i l (10,000) 1 .oo
Isopar M 10.00
SOURCE: GE Si14cones: Formula FP 3003/Formula AP 1000
114 Advanced Cleaning Roduct Formulatiom
Aerosol F u r n i t u r e P o l i s h
IHydrocarbon ProDellant)
M a t e r i a l s :
P a r t A:
Isopar E
Hoechst Wax A3 CS
S F 96 (100)
V i scasi 1 ( 10,000)
Span 80
Tween 81
P a r t B:
Water
Procedure:
1 . ) Heat P a r t A t o 85C.
2 . ) Heat P a r t B t o 70C.
3.) Add P a r t B t o P a r t A w i t h h i g h shear mixing.
4.) Cool t o room temperature when homogeneous.
Preparation o f Aerosol:
i o a d i ng :
P o l i s h Concentrate
A 46 P r o p e l l a n t
Aerosol Valve :
Preci s i on Valve P a r t Numbers :
Button: Part No. 01-5843 (0.020" MBFT RS)
Stem: P a r t No. 04-1240 (0.024")
Gasket: P a r t No. 05-0310 (BUNA)
Body: P a r t No. 07-1901 (0.080")
5. Package i n sui tab1e contai ners.
F u r n i t u r e P a s t e m
Materi a1s :
Part A:
Part/ W t 1%)
14.75
0.50
2.30
0.50
0.25
0.08
81.62
Part/WtC%)
90.0
10.0
V i scasi 1 (30,000)
Hoechst Wax E
Hoechst Wax F
Ross Micro Wax 1135/15#
Ross Ozokerite Wax 77Y
P a r t B:
Isopar L
Procedure:
1.) Heat P a r t A t o 1OOC.
2.) Heat P a r t B t o 9%.
3.) Add P a r t 8 t o P a r t A w i t h g e n t l e mixing.
4.) Cool t o 50-52C w i t h g e n t l e mixing and pour i n t o containers.
Allow c o n t a i n e r s t o cool b e f o r e capping. A f l o w o f a i r across
surface o f c o n t a i n e r w i l l improve c o o l i n g process. M u l t i p l e
pour c y c l e s can be used f o r deep containers.
A l t e r n a t e Method:
1 . ) Heat P a r t A t o 100C.
2 . ) Add P a r t B (unheated) slowly w h i l e blending.
3 . ) Reheat P a r t AB u n t i l a c l e a r s o l u t i o n i s obtained. Follow
above procedure from here.
7.0
7.0
3.0
6 . 0
1.o
76.0
SOURCE: GE S i l i c o n e s : Formula FP 3002/Formula FP 3004
Polishes, Coatingsand Finishes I15
Detergent Resistant. Cream Cleaner P o l i s h
I n g r e d i e n t s : % by
( 1) Deodori zed Kerosene
( 2 ) Hoechst Wax S
(3) GP-7104 ( S i l i c o n e F l u i d )
( 4 ) GP-10-1,000 c s t k (Dimethyl S i l i c o n e F l u i d )
( 5 ) O l e i c Acid
( 6 ) S o f t Water
( 7 ) Morphol ine
(8) S o f t Water
( 9 ) Mineral S p i r i t s (Low Odor)
(10)Kaopolite SF
Weight
10.0
8 . 0
3.0
4.0
1.o
2.4
0.8
38.8
20.0
12.0
Procedure:
Combine (1) through ( 5 ) and heat t o 212F w i t h low t o moderate
mixing. Remove heat, increase mixing and add ( 6 ) through (10) as
i n s t r u c t e d below.
Heat (6) t o 21OF, s t i r i n ( 7 ) , then pour i n t o t h e batch. Heat
( 8 ) t o 210F and add t o t h e batch. Add ( 9 ) then (10) slowly t o
t h e batch, a l l o w i n g complete mixing o f each.
Mix slowly u n t i l temperature o f batch reaches llOF. Package.
Formula 4-2
Non-Abrasive, Detergent Resistant, Glaze Emulsion
I n g r e d i e n t s : % by Weight
( A ) ( 1 ) GP-10-1,000 c s t k (Dimethyl S i l i c o n e F l u i d ) 3.0
(2) GP-7104 ( S i l i c o n e F l u i d ) 3 . 0
( 3 ) Hoechst Wax S 1.5
( 4 ) Carnauba Wax #3 1.o
( 5 ) O l e i c Acid 1.5
( 6 ) Mineral S p i r i t s 4.6
(B) ( 7 ) S o f t Water
( 8 ) Carbopol 934
( 9 ) Triethanolamine 99%
(10) Morphol ine
83.6
0 . 2
0.2
1.4
Procedure:
(A) Combine (1) through (6) and heat t o 150F w i t h mixing.
(B) Heat ( 7 ) t o 1OOF. With h i g h shear mixing add ( 8 ) t o ( 7 ) .
Once (8) i s dissolved add (9) and then add (10).
Add ( A ) t o (B) slowly, w i t h high shear mixing. Continue
mixing u n t i l emulsion reaches 70F. Package.
Formula 8-1
SOURCE: Genesee Polymers Corp.: Suggested Formulations
I16 Advanced CleaningProduct Formulations
Hiah G1oss. Detereent Resistant. S o f t Paste Pol ish
Inqredients:
(A) ( 1 ) Hoechst Wax OP
(2) Hoechst Wax E
(3) Ozokerit e
% bv Weight
7.0
8.0
1.5
(B) ( 4 ) GP-7104 ( S i l i c o n e F l u i d ) 3.0
(5) GP-10-1,000 c s t k (Dimethyl S i l i c o n e F l u i d ) 3.0
(6) GP-10-12,500 c s t k (Dimethyl S i l i c o n e F l u i d ) 2.0
(7) Mineral S p i r i t s (Low Odor) 36.0
( 8 ) Deodorized Kerosene 9.5
(9) Kaopolite SF 12.0
(10) Mineral S p i r i t s (Low Odor) 18.0
Procedure:
(A) Combine ( I ) , (2), and (3), heat t o 230F t o melt waxes.
(B) Separately mix and heat ( 4 ) , ( 5 ) , ( 6 ) , (7), and (8) t o 160F.
Slowly add (B) t o (A) w i t h mixing. Temperature o f batch
a f t e r adding (B) t o (A) should be 195F. Add (9) then (10)
t o batch w i t h mixing. Remove heat and mix w e l l u n t i l
temperature reaches 140F. Package.
Formula 5-2
Detergent Resistant Cream P o l i s h
Inqredi ents:
( 1 ) Witconol 14
(2) GP-10-1,000 c s t k (Dimethyl S i l i c o n e
(3) Carnauba Wax #3
(4) Isopar L
(5) Morphol ine
(6) GP-7104 ( S i l i c o n e F l u i d )
(7) S o f t Water
( 8 ) Kaopolite SF
% by Wei aht
1.5
F l u i d ) 3.0
10.0
25.0
0.4
3.1
47.1
10.0
Procedure:
t o 195F w i t h mixing t o melt wax. Once wax i s melted, add ( 5 )
w i t h mixing. Add (6) t o mixture followed by t h e r e s t o f (41,
keeping t h e temperature a t 175F. Remove from heat and mix u n t i l
temperature reaches 130F. Package.
Formula 3-2
SOURCE: Genesee Polymers Corp.: Suggested FormulatSons
Combine ( I ) , (2), (3). and 50% o f (4) i n a container and heat
Polishes, Coatingsand Finishes 117
L i q u i d P o l i s h For Clear Coat F i n i s h e s
Mater ia1_s ; Part/Wt(%)
P a r t A:
SF 96 (350) 3.50
Hoechst Wax S 1 .oo
Hoechst Wax E 1.60
O l e i c A c i d 1.50
Isopar M 5.00
P a r t 0:
Water 77.75
Carbopol 934 0.20
Morphol ine 1.60
Kathon CG 0.10
P a r t C:
Isopar M I.oo
SF 1706 0.75
P a r t D:
Kaopol it e 1152 6.00
Procedure:
1.) Heat P a r t A t o 95C.
2 . ) Heat P a r t B t o 8%.
3.) Add P a r t A t o P a r t B w i t h h i g h shear mixing.
4 . ) When homogeneous, cool t o 60C and add P a r t C w i t h h i g h
5 . ) Add P a r t D w i t h moderate mixing.
6.) Cool and package i n s u i t a b l e containers.
Mater ia1s : Part/Wt(%)
P a r t A:
SF 96 (350) 5.00
Hoechst Wax E 1.50
O l e i c Acid 1.50
P a r t 8:
Carbopol 934 0.25
Morphol ine 1.50
Water 74.15
Kathon CG 0.10
Part C:
SF 96 (100) 2.00
SF 1706 2.00
P a r t D:
Kaopol it e 1152 7.80
Snow Floss 4.20
Procedure:
1 . ) Heat P a r t A t o 95-IOOC.
2 . ) Heat Part B t o 85C.
3 . ) Add P a r t A t o P a r t B w i t h h i g h shear mixing.
4 . ) When homogeneous, cool t o 60-70C and add P a r t C w i t h c o n t i n -
5 . ) When homogeneous, reduce mixing t o medium speed and s l o w l y
6.) Cool and package i n s u i t a b l e containers.
SOURCE: GE S i l i c o n e s : Formula APlOOl/Formula AP1002
shear m i x i ng.
L i q u i d Polish-No Solvent
ued h i g h shear mixing.
blend i n P a r t D.
I18 Advanced Cleaning Product Formulations
L i a u i d P o l i s h (Outer Phase O i l l
Materials:
Part A:
V i s c a s i l (10,000)
W i tcamide 511
Tween 81
Hoechst Wax OP
Ross Ozokerite 77Y
Isopar M
Part 9:
Water
Kaopol it e 1152
Kaopolite SF
Part C:
Isopar L
SF 1705
SF 1706
Procedure:
1.) Heat Part A t o 90-95C.
2.) Heat Part B t o 80C.
3 . ) Add Part B t o Part A w i t h high shear mixing.
4.) When homogeneous, cool t o 50-60C and add Part C
5 . ) Cool and package i n s u i t a b l e containers.
Formula AP 1003
continued high shear m i x i ng.
Part/Wt (%l
1.50
1.oo
0.15
1.30
0.20
20.00
55.85
4.50
4.50
6.00
3.00
2.00
w i t h
Non-Wax L i a u i d P o l i s h (Oil-Pn-Water Tvoe)
Materia1s:
Part A:
Part/Wt C%l
SF 96 (350) 4.00
V i scasi 1 (10,000) 1.oo
Isopar L 11.oo
Oleic A c i d 1.50
Part 0 :
Water 65.95
Carbopol 934 0.25
Morpholine 1.70
Kathon CG 0.10
Part C:
Isopar M 4.00
SF 1706 1.50
Part D:
Kaopol it e 1152 6.00
Snow Floss 3.00
Procedura:
1. ) Add Part A t o Part B w i t h high shear mixing.
2 . ) When AB i s homogeneous, add Part C. a l s o w i t h high shear
m ix i ng.
3 . ) Add Part D w i t h moderate mixing u n t i l homogeneous.
4.) Package i n s u i t a b l e containers.
Formula AP 1004
SOURCE: BE Slllconea: Suggested Formulations
M a t e r i a l s :
SM 2133
20% Wax Emulsion
Carbopol 934
Triethanolamine
Water
B i o c i de
sm 2135
M a t e r i a l s :
P a r t A:
Cardis 36 Wax
Hoechst Wax A3 CS
O l e i c Acid
Morpholine
Part B:
Water
B i o c i de
Polishes, Coatings and Finishes 119
L isuid F u r n i t u r e P o lish
Part/Wt (%I
4.0
2.0
2.5
0.2
0.2
91.1
q . s
20% Wax Emulsion-1
20% Wax Emulsion-2
M a t e r i a l s :
Part A:
Cardis 36 Wax
Hoechst Wax A3 CS
O l e i c Acid
D i e t h y l ami noethanol (DEAE)
Part 8:
Water
B i oci de
Part/Wt(%)
10.0
10.0
3.0
4.0
73.0
q . s .
Part/Wt (%)
10.0
10.0
3.0
2.5
74.5
q . s .
Preparation o f Wax Emulsion:
1.) Add Cardis 36 wax, Hoechst wax A3 CS, and o l e i c a c i d t o a
2.) When completely melted, add e i t h e r t h e morpholine o r DEAE
u n t i l mixture i s homogeneous.
3.) Add P a r t B, preheated t o 95C, slowly s t i r r i n g t h e wax/soap
mixture, maintaining temperature between 93 t o 98C during
t h i s a d d i t i o n .
4.) Continue s t i r r i n g u n t i l temperature reaches 45C.
5 . ) Cool t o room temperature.
Preparation o f Polish:
1 . ) Add water, biocide, and Carbopol 934 t o a vessel, and
2. ) Add t r i ethanol ami ne and mix u n t i 1 homogeneous.
3 . ) Add other ingredients.
4.) Combine w i t h m i l d mixing, and when homogeneous, package
SOURCE: GE S i l i c o n e s : Formula FP 3000
vessel, and w i t h m i l d s t i r r i n g b r i n g t h e temperature up t o
96-1 OOC.
d i s s o l v e t h e Carbopol w i t h good mixing. Warm water w i l l
improve t h i s process.
in s u i tab1e contai ners.
120 Advanced CleaningRoduct Formulatiotu
L ia u i d Water-Based Glaze
Mater ia1s :
Part A:
SF 96 (350)
O l e i c Acid
Hoechst Wax OP
Cardis 36 Wax
Isopar M
Part B:
Water
Carbopol 934
Morpholine
Kathon CG
Part C:
Isopar M
SF 1706
Part/Wt(%)
3.50
1.50
1 .oo
1.50
6.00
82.55
0.25
1.60
0.10
1.so
0.50
Procedure:
1 . ) Heat Part A t o 95-1OOC.
2.) Heat P a r t B t o 90-95C.
3 . ) Add Part A t o Part B w i t h high shear mixing.
4.) Cool t o 60-70C and add Part C w i t h high shear mixing.
5 . ) Cool w i t h continued moderate mixing.
6.) Package i n s u i t a b l e containers.
Formu la AP 1005
Solvent Wax G l aze
M a t e r i a l s :
Part A:
SF 96 (1000)
Hoechst Wax OM
Hoechst Wax F
Deodorized Kerosene
Part B:
Odorless Mineral S p i r i t s
SR 107
Part/Wt (%l
3.0
0.6
1.4
1 0 . 0
84.0
1.0
Procedure:
1.) Heat P a r t A to 95C. Be sure a l l wax i s completely melted
2.) Add Part B w i t h moderate mixing.
3 . ) Continue mixing and cool t o room temperature.
4.) Package i n s u i t a b l e containers.
Formula AP 1008
SOURCE: GE S i l i c o n e s : Suggested Formulations
and d i spersed.
Polishes, Coatingsand Finishes 121
Paste P o l i s h (Oil-In-Water Type1
Part/Wt (%lMateri a1s:
Part A:
Hoechst Wax S
Hoechst Wax OP
SF 96 (350)
V i s c a s i l (10,000)
Stearic Acid
Isopar M
Isopar L
Part 0:
Water
Morpholine
Kaopol it e 1168
Super Floss
Part C:
Isopar M
SF 1706
Procedure:
1 . ) Heat Part A t o 90-95C.
2.) Heat Part 8 t o 80-85C.
3.) Add Part A to Part B w i t h good mixing.
4.) When homogeneous, cool t o 60C and add Part C w i t h continued
5.) Cool t o s u i t a b l e pour temperature (<50C).
6.) Package i n s u i t a b l e containers.
Comments:
degree o f cooling a v a i l a b l e on t h e f i l l i n g l i n e . With slow
c o o l i n g rate, t h e c o o l i n g c y c l e must be done without covers
t o prevent condensation i n s i d e containers.
mixing.
The pour temperature w i l l depend on equipment and r a t e and
5.0
1.o
4.5
2.0
1.o
8.0
18.0
42.8
0.7
8.0
2.0
5.0
2.0
Spray-And-Wipe P o l i s h
Mate r ia1s:
SM 2109
AF 9020
Part/Wt(%)
8 . 0 0
0.05
Veegum Pro 0 . 8 0
Proxcel GXL 0.15
Kaopolite SF 5.00
Water 86.00
Procedure:
1 . ) Add water, Proxcel GXL. and Veegum Pro t o a mixing vessel,
2.) Add Kaopolite SF and continue mixing w i t h high shear u n t i l
3 . ) Reduce mixing t o low t o moderate and add AF 9020 and
4 . ) Package i n s u i t a b l e sprayable containers.
SOURCE: GE Silicones: Formula BP 2001/Formula AP 1010
and, using high shear, disperse u n t i l uniform.
a uniform f i n e dispersion i s obtained.
SM 2109 emulsions. Do Not Overmix. These materials
e a s i l y disperse i n a very short time period.
122 Advonced CleaningProduct Formulations
Paste P o l i s h (Oil-In-Water TYDe)-(l)
Materia1s : Part/Wt (%)
Part A:
SF 96 (350) 4.5
V i s c a s i l (10,000) 2.0
Hoechst Wax S 5.0
Hoechst Wax OP 1 .o
S t e a r i c Acid
Isopar M
Isopar L
Part 0:
Water
Morpholine
Kaopolite SF
Snow F1oss
Kathon CG
Part C:
Isopar M
SF 1706
Materi a1s :
Part A:
SF 96 (350)
1.o
8.0
18.0
42.7
0.7
8.0
2.0
0.1
5.0
2.0
Paste P o l i s h (Oil-In-Water Tyoe)-(Zl
Part/Wt(%l
4 . 5
v i scasi 1 (i0,ooo)
Hoechst Wax S
Hoechst Wax OP
S t e a r i c Acid
Isopar M
Isopar L
Part 0:
Water
Morpholine
Kaopolite 1152
Snow F1oss
Kathon CG
Part C:
Isopar M
SF 1706
2.0
5.0
1 .o
1.o
8.0
18.0
41.7
0.7
7.8
4.2
0.1
4.0
2.0
Procedure:
1.) Heat Part A t o 90-95C. (2.) Heat Part B t o 80-8512.
3.) Add Part A t o Part 0 w i t h good mixing. (4.) When homogeneous,
6.) Pour i n t o s u i t a b l e containers.
Comments:
The pour temperature w i l l depend on equipment, r a t e and degree
o f c o o l i n g a v a i l a b l e on the f i l l i n g l i n e . With slow c o o l i n g r a t e ,
t h e c o o l i n g c y c l e must be done without covers t o prevent
condensation i n s i d e containers.
SOURCE: GE S i l i c o n e s : Formula AP 1008
cool t o 60C and add Part C w i t h continued mixing. ( 5 . ) Cool
t o s u i t a b l e pour temperature, e.g., >50C.
Polishes, Coatingsand Finishes 123
Paste Polish ( O i p
Meteri a1s: Part/Wt t % l
Part A:
SF 96 (350) 4.5
V i scasi 1 (10,000) 2.0
Hoechst Wax S 5.0
Hoechst Wax OP 1.o
S t e a r i c Acid 1.o
Isopar M 8 . 0
Isopar L 18.0
Part B:
Water 42.7
Morphol ine 0.7
Kaopolit e 1152 7.5
Snow Floss 2.5
Kathon CG 0.1
Part C:
Isopar M 5.0
SF 1706 2.0
1 . ) Heat Part A t o 90-95C.
2 . ) Heat Part 8 t o 80-85C.
3 . ) Add Part A t o Part B w i t h good mixing.
4 . ) When homogeneous, cool t o 60C and add Part C w i t h cont-
5 . ) Cool t o s u i t a b l e pour temperature, e.g., >5OC.
6. ) Pour in t o s u i t a b l e contai ners.
Comments :
The pour temperature w i l l depend on equipment, r a t e and
degree o f cooling on t h e f i l l i n g l i n e . With slow cooling rate,
t h e c o o l i n g c y c l e must be done without covers t o prevent
condensation inside contai ners.
Materials: Part/Wtt%)
Part A:
V i s c a s i l (10,000) 2.50
Hoechst Wax S 1.80
Hoechst Wax E 2.00
Ross Ozokerite 77Y 0.15
Span 80 2.00
Tween 81 0.15
Isopar L 17.00
Isopar M 5.00
Part B:
Water 52.40
Kaopol it e 1152 6.00
Snow Floss 3.00
Part C:
Isopar M 2.00
SF 1705 4.00
SF 1706 2.00
1. Heat Part A t o 95C. ( 2 . ) Heat Part B t o 8OC. ( 3 . ) Add Part
B t o Part A w i t h high shear mixing. (4.) Cool t o 60-65C
and add Part C w i t h good mixing. (5.) Cool t o 55C and pour
i n t o s u i t a b l e containers.
inued m i x i ng.
Paste P o l i s h (Outer Phase O i l 2
SOURCE: GE Silicones: Formula AP 1006(3)/AP 1007
124 Advanced CleaningProduct Formulations
Spray-And-Wipe P o l i s h (Pump)
Mater ia1s 1
SM 2133
SM 2135
20% Wax Emulsion
Water
B i o c i de
M a t e r i a l s
Part A :
Cardis 36 Wax
Hoechst Wax A3 CS
O l e i c Acid
Morpholine
Part B:
Water
B i o c i de
20% Wax EmulKion-.(a
Mateyjal s :
Part A:
Cardis 36 Wax
Hoechst Wax A3 CS
O l e i c Acid
Diethylaminoethanol (DEAE)
Part B:
Water
B i o c i de
Part/Wt(%)
3.0
2 . 0
2 . 5
92.5
q . s .
20%Wax .Emu 1sionr--l )
SartfW t f U
10.0
10.0
3.0
4.0
73.0
q . s
10.0
10.0
3.0
2.5
74.5
q . s .
Preparation o f Wax Emulsion:
1 . ) Add Cardis 36 wax, Hoechst wax A3 CS, and o l e i c a c i d t o a
vessel and, w i t h m i l d s t i r r i n g , b r i n g temperature up t o
98-1ooc.
2.) When completely melted, add e i t h e r t h e morpholine or DEAE
u n t i l m i x t u r e i s homogeneous.
3.) Add Part B, preheated t o 95C, slowly s t i r r i n g t h e wax/soap
mixture, maintaining temperature between 93 and 9BC d u r i n g
t h e a d d i t i o n .
4.) Continue s t i r r i n g u n t i l temperature reaches 45C.
5.) Cool t o room temperature.
Preparation o f P o l i s h :
package i n s u i t a b l e containers.
SOURCE: GE S i l i c o n e s : Formula FP 3001
Blend a l l i n g r e d i e n t s together w i t h m i l d s t i r r i n g , and
Polishes, Coatings and Finishes 125
Spray 8 Wipe Type-Aerosol o r Non-Aerosol(1)
Concord Co-Wax Emulsion, 12%
S i 1icone (Union Carbide LE-461)
D i s t i 11ed Water
% by Weiaht
4.1
7.0
88.9
Spray 8 Wipe- Type-Aerosol o r Non-Aerosol(E]
Concord Co-Wax Emulsion, 12%
S i l i c o n e (Union Carbide LE-461)
S i l i c o n e (Union Carbide LE-462)
D i s t i 11ed Water
Weisht
7.5
12.5
2.5
77.5
Spray & Wipe Type-Aerosol o r Non-Aerosol(3)
Concord Co-Wax Emulsion, 12%
S i 1icone (Union Carbide LE-461)
S i l i c o n e (Union Carbide LE-462)
T r i ethanol ami ne Lauryl S u l f a t e
D i s t i 1l e d Water
% by Weiqht
7.5
12.5
2.5
1 . 5
76.0
The formulas l i s t e d above a r e suggested formulas. Every
e f f o r t has been made t o o p t i m i z e a l l p r o p e r t i e s t o get t h e best
p o l i s h w i t h regard t o s p e c i f i c amounts o f i n g r e d i e n t s . Formula #1
i s t h e b e s t a l l around p o l i s h . I t f e a t u r e s e x c e l l e n t gloss,
a p p l i c a t i o n ease and economy. Formula #3 i s an example o f l i g h t
foam-type p o l i s h , and o f f e r s b e t t e r removal o f s o i l and emuls-
i f i c a t i o n o f p r o p e l l e n t s . Formula #2 i l l u s t r a t e s a h i g h g l o s s
formula w i t h e x c e l l e n t p r o t e c t i v e q u a l i t i e s .
L i q u i d Wax-Solvent F u r n i t u r e o r F l o o r P o l i s h
Concord Wax #1600
S i l i c o n e General E l e c t r i c SF 96-100
Safety Solvent (Stoddard Solvent)
% by Weight
6.0
1 .o
93.0
Procedure:
M e l t wax and s i l i c o n e together a t a temperature o f 195-200F
i n one h a l f o f t h e s o l v e n t . The balance o f t h e c o l d s o l v e n t i s
then added t o t h i s s o l u t i o n a f t e r t h e waxes a r e melted.
SOURCE: Concord Chemical Co., I n c . : Suggested Formulations
12. Rinse Aids
126
RinseAids 127
Automatic Dishwash Rinse A i d (For Hard Water1
A c i d Hard Water Tolerant Formulation
Inaredient :
Oeioni zed Water
Mazawet 36
G l y c o l i c Acid (57%)
Isopropyl Alcohol
pH, 1%: 2.0-3.0
Appearance: Clear, s l ight
S p r c i f i c Gravity: 1.01
y viscous, l i g h t - y e l l o w
Wt.%
30.00
55.00
10.00
5.00
iqui d
Procedure:
Charge t h e water and Mazawet 36 t o t h e mixing vessel and
s t a r t a g i t a t i o n . Charge the G l y c o l i c Acid and Isopropyl Alcohol
and mix u n t i l c l e a r and f r e e o f " f i s h eyes."
Notes :
Formulated f o r areas w i t h hard water.
Normal use d i l u t i o n i s 100 ppm i n f i n a l r i n s e cycle. Conc-
e n t r a t i o n s o f use s o l u t i o n s may be adjusted t o meet l o c a l needs
o r v a r t a t i o n s i n equipment.
Formula CR-101
Automatic Dishwash Rinse A i d
<For Neutral o r S o f t Water)
Standard Formulation f o r Neutral o r Soft Water
Ingredient:
Mazawet 36
Oeioni zed Water
Isopropyl A1coho1
Sodi um Hydroxide
Wt.%
55.00
40.00
5 . 0 0
P.S. t o pH 6.0-7.0
pH. 1%: 6.0-7.0
Appearance; Clear, s l i g h t l y viscous, l i g h t - y e l l o w l i q u i d
S p e c i f i c Gravity: 1.01
Procedure:
u n t i l c l e a r and f r e e o f " f i s h eyes."
Notes :
Formulated f o r areas w i t h neutral o r s o f t water.
Normal use d i l u t i o n i s 100 ppm i n f i n a l r i n s e cycle. Conc-
e n t r a t i o n s o f use s o l u t i o n s may be adjusted t o meet l o c a l needs
o r v a r i a t i o n s i n equipment.
The formulator may adjust t h e cloud-point o f t h i s system
by using a d d i t i o n a l alcohol t o increase i t o r Sodium Hydroxide
t o decrease i t .
Formula CR-102
SOURCE: Mazer Chemicals: Suggested Formulations
Charge t h e ingredients i n t h e sequence given above and mix
128 Advanced CleaningProduct Formulations
Rinse A i d
Formula DW-0011
Antarox BL-240
Urea
Water
Dye
Wt.%
50.0
9.0
41 . O
Procedure
1. Dissolve urea i n water.
2. Add Antarox BL-240 t o water/urea s o l u t i o n . Mix thoroughly.
Physical PrpDertiea
pH (as i s ) : 7.5
pH (1%): 8.1
Viscosity: 50 cps
S p e c i f i c G r a v i t y : 1.01
Rinse A i d
Formula DW-0012
Antarox BL-225
Isopropanol
Water
Dye
Procedure
1. Dissolve Antarox BL-225 i n water. Mix thoroughly.
2. Add isopropanol.
Physical Properties
pH (as i s ) ; 6.1
pH (1%): 8.3
V i s c o s i t y : 30 cps
S p e c i f i c Gravity: 0.99
SOURCE: Rhone-Poulenc Surfactants & Specialties: Formulas
Wt.%
70.0
20.0
10.0
-
13. Rug, Floor, Carpet,
Upholstery Shampoos and Cleaners
129
130 Advanced Cleaning product Formdations
Basic Floor Cleaner. Liauid-A
Marlon A 360 o r A 365
Marl ipal 013/99
Solvent BG*
Tetrapotassium pyrophosphate
Sodi um metasi 1i c a t e pentahydrate
KNA cumene sulphonate 40
Ammonia, 25%
Balance water, fragrance, preservative
Active matter: 7.0%
Basic Floor C1eaner, L iauid-B
M a r l i p a l 013/99
Marlowet 5622
Solvent BG*
Tetrapotassium pyrophosphate
Ammonia, 25%
Balance water, fragrance, preservative
Active matter: 6.7%
Floor Cleaner. f o r Everyday Use. Liauid-A
Marlon PS 65
L ipoxol 12000*
Marlamid DF 1218
Isopropanol*
Fragrance
Balance water, d y e s t u f f
Active matter: 4.7%
Floor Cleaner. f o r Everyday Use. Liauid-B
M a r l i p a l KF
C i t r i c a c i d
Isopropanol*
Fragrance
Balance water, d y e s t u f f
%
7.0
3.0
3.0
5.0
5.0
10.0
1 .o
t o 100
!%
3.0
4.0
20.0
3.0
1 .o
t o 100
%
5.0
6.0
1.5
20.0
0 . 5
t o 100
!%
3.0
0.2
25.0
0.5
t o 100
Active matter: 3.0%
SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and
Cleaning Agents f o r Household Purposes
&g, Floor, Catpet, UpholsteryShampOchF and Cleaners 131
CarDet and UDhols t e w C1eaners
Dry-Foam C 1eaner. L iauid-A
M a r l i n a t SRN 30
Methacrylate copolymer, e.g. Syntran 6520
N i t r i l o t r i a c e t a t e powder
Balance water, fragrance, preservative
A c t i v e matter: 9.0%
Dry-Foam C1eaner . L iauid-B
M a r l i n a t SRN 30
N i t r i l o t r i a c e t a t e powder
Balance water, fragrance, preservative
A c t i v e matter: 12.0%
Dry-Foam Cleaner. Powder-A
M a r l i n a t SRN 30
Methoxypropanol
Technocell 90 DU
Balance water, fragrance, preservative
A c t i v e matter: 1.5%
Dry-Foam Cleaner, Powder-B
M a r l i n a t DFK 30
Methoxypropanol
Technocell 90 DU
Balance water, fragrance, preservative
%
3 0 . 0
20.0
1.o
t o 100
%
40.0
0.5
t o 100
%
5 . 0
5 . 0
50.0
t o 100
%
5.0
5.0
50.0
t o 100
A c t i v e matter: 1.5%
SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and
Cleaning Agents f o r Houaehold Purposes
132 Advanced CleaningProduct Formulations
Carpet Shampoo, Hiah Foam
Water
P e t r o BAF L i q u i d
W i t c o l a t e WAC-LA
Blending Procedure:
Blend i n g r e d i e n t s i n t h e order l i s t e d .
%__byWeigh2
10.0
15.0
75.0
P e t r o BAF, i n combination w i t h sodium l a u r y l s u l f a t e , reduces
t h e low temperature c l o u d p o i n t , g i v i n g e x c e l l e n t freeze/thaw
p r o p e r t i e s . The Petro BAF combination d r i e s l e s s tacky than
sodium l a u r y l s u l f a t e alone.
Formula 911
Carpet. Shampoo, H i &h -Foam
Water
P e t r o BAF L i q u i d
W i t c o l a t e WAC-LA
?4 by Weight
78.3
5 . 0
1 6 . 7
B1endi ng Procedure:
Blend i n g r e d i e n t s i n t h e order l i s t e d .
P e t r o BAF, i n combination w i t h sodium l a u r y l s u l f a t e , reduces
t h e low temperature c l o u d p o i n t , g i v i n g e x c e l l e n t freeze/thaw
p r o p e r t i e s . The P e t r o BAF combination d r i e s l e s s tacky than
sodium l a u r y l s u l f a t e alone.
Formula 908
SOURCE: Witco Corp.: Suggested Formulations
Rug Floor, Carper, Uphktety Shampoos and Cleaners 133
Evaporative (No Rinse) Wax S t r i p p e r
Formula FC-0056
Miranol JEM Concentrate
Monoethanolami ne
Butoxyethoxypropanol
Isopropanol
Water
Procedure
Phvsic a l ProDerti es
Add t h e ingredients and mix u n t i l uniform.
Appearance: Clear s o l u t i o n
pH, as i s : 1 1 . 4
Viscosity: t 1 0 cps
S p e c i f i c Gravity: 0.97
Waxed F l o o r Cleaner
Formula FC-0055
Rhodafac RA-600
A1kamide DC 212/S
Tetrapotassium Pyrophosphate (60% Active)
Water
Wt.%
0.5
6.5
2.5
1 9 . 0
'72.5
Wt.%
5.0
1 .o
25.0
69.0
=Q
a f t e r each a d d i t i o n .
Add ingredients one by one, i n order l i s t e d above, mixing well
Phvsi c a l ProDerti es
pH. as i s : 8.6
pH (1%): 8.6
V i s c o s i t y : 10 cps
S p e c i f i c Gravity: 1 . 0 4
SOURCE: Rhone-Poulenc Surfactants & Specialties: Formulas
134 Advanced Cleaningproduct Formulations
F1oor C leaner
Formula FC-0053
Rhodafac LO-529
Sodi um Tripolyphosphate
Tetrasodium Pyrophosphate
Water
Wt.%
6.0
3.0
3.0
8 8 . 0
Procedure
1. Dissolve s o l i d s i n t h e t o t a l amount o f water.
2. Add Rhodafac LO-529. Mix thoroughly.
Phvsic a l ProDerties
pH, as i s : 13.9
pH (1%): 8.9
V i s c o s i t y : 60 cps
S p e c i f i c G r a v i t y : 1.09
F l o o r Cleaner
Formula FC-0054
Wt.%
Rhodafac LO-529 5.0
A1kami de DC-212/S 1.o
Tetrasodium Pyrophosphate (65% Active) 2.0
T r i sodi um Phosphate 1.o
Diethylene Glycol Monoethyl Ether 1.o
Water 90.0
Perfume and Colorants added, as desired, r e p l a c i n g water
Procedur e
1. Dissolve Tetrasodium Pyrophosphate i n water. Add Trisodium
2. Add Rhodafac LO-529 and Alkamide DC-212/S.
3. Add solvent.
Phosphate. D i ssol ve thorough1 y .
1
pH. as i s : 11.0
pH (1%?: 9.0
V i s c o s i t y : 290 cps
S p e c i f i c Gravity: 1.01
SOURCE: Rhone-Poulenc Surfactants & S p e c i a l t i e s : Formulas
F l o o r P o l i s h
Mor-Glo 2-457 20% S o l i d s
Use w i t h low speed spray b u f f i n g and high speed maintenance
programs using p l u g - i n e l e c t r i c burnishers and s y n t h e t i c pads.
Produces higher i n i t i a l gloss than t h e 442 formulation. Can be
burnished d a i l y o r on an i n t e r m i t t e n t schedule without producing
excessive amounts o f dust. M u l t i p l e recoats o f 4-5 coats per
a p p l i c a t i o n are recommended w i t h 30-45 min. d r y i n g time depending
on s o l i d s . With these maintainance procedures a consistent h i g h
l e v e l o f appearance can be sustained over an extended p e r i o d
o f time.
___Item:
1
2
3
4
5
6
7
8
9
10
Components: Wei Qht
Water
Diethylene Glycol Monoethyl Ether
T r i butoxyethyl Phosphate
Fluorad FC-129 (1% a c t i v e s o l u t i o n )
A n t i foam Emu1s i on*
Proxel GXL
Mor-Glo 2 Latex (38%)
Morton Conrez 510 (25% s o l u t i o n )
AC-325 Anionic (35%)
E-43 Nonionic (40%)
Percent
47.07
3.37
2.95
0.50
0.02
0.10
39 9 49
1.oo
2.51
2.19
Procedure:
With good a g i t a t i o n add t h e components i n t h e order l i s t e d .
A f t e r t h e a d d i t i o n o f i t e m #6, a l l o w t o mix f o r 30 min. b e f o r e
continuing. Add t h e remaining components slowly.
Formulation Constants:
Polymer/Resin/Wax Ratio: 90/0/10
Typical pH: 8 . 5
Formulation Density: 8.54 l b s . / g a l .
S p e c i f i c G r a v i t y : 1.026
TvDi c a l Densi t y Val ues:
__-S o l i d s : Pounds/Qal.
25% 8.60
20% 8.54
S p e c i f i c G r a v i t y
1.032
1.026
15% 8.49 1.019
*SAG 1010 from Union Carbide Corp., o r SWS 211 from Wacker
S i 1icones Corp.
SOURCE: Morton I n t e r n a t i o n a l , I n c . : Formula Mor-Glo 2-457
20% Sol i d s
Rug, Floor, Carpet, UpholsferyShampom and Cleaners 135
136 Advanced Cleaning Roduct Formulations
Floor P o l i s h
ML-870-389 20% S o l i d s
Use w i t h low speed spray b u f f i n g and high speed maintenance
programs. This product maintains a high i n i t i a l gloss and can
be burnished on an i n t e r m i t t e n t schedule. With these mainten-
ance procedures, a consistent high l e v e l o f appearance can be
sustained over an extended p e r i o d o f time. Up t o f i v e coats
per a p p l i c a t i o n may be applied w i t h 30-45 min. d r y i n g t i m e
depending on s o l i d s and conditions.
Item:
1
2
3
4
5
6
7
8
9
10
1 1
12
Components:
Water
Diethylene Glycol Monoethyl Ether
T r i butoxyethyl Phosphate
D i b u t y l Phthalate
Igepal CO 977
F l uorad FC-129 (1% s o l u t i o n )
Anti foam*
Proxel GXL
ML-870 Latex (38%)
Morton Conrez 510 (25% s o l u t i o n )
AC-325 Noni oni c (35%)
E-43 Nonionic (40%)
W_eiqht Percent
42.36
4.97
1.24
0.65
0.20
0.60
0.02
0.10
34.89
7.45
4.01
3.51
Procedure:
A f t e r t h e a d d i t i o n o f item #8, allow t o mix f o r 30 minutes
before continuing. Add t h e remaining components slowly.
Formulation Constants:
Polymer/Resin/Wax Ratio: 74/10/16
Typical pH: 8.0
Formulation Density: 8.52 l b s . / g a l .
Speci f ic Gravity: 1 .023
With good a g i t a t i o n , add t h e components i n the order l i s t e d .
Typical Density Values:
Sol i d s : Pounds/Gal . Speci f ic Gravity
25% 8.57 1.029
20% 8.52 1.023
15% 8.47 1.017
*SAG 1010 from Union Carbide Corp., o r SWS 211 from Wacker
SOURCE: Morton I n t e r n a t i o n a l : Formulation ML-870-389 20% Solids
S i 1icones Corp.
Water
SXS-40%
Sodi um Bicarbonate
STPP
Burcosperse AP-Liq
Burco LAF-6
Water
Burcoterge DG-40
Burcosperse AP-Liq
Propylene Glycol
S o r b i t o l 70%
Burcotase SL-80
Rug, Floor, Carpet, UpholsferyShampom and Cleaners 137
L iauid Carpet Cleaner
Carpet S t a i n Remover-Liauid
Carpet Cleaner/Booster-Dry
Destainer
Burco LAF-6
Soda Ash
FB-Sodi um Percarbonate
% bv We-
72.5
10.0
5.0
5.0
5.0
2.5
% by Weight
To 100
40
10
20
15
0.5-1 .o
96 bv Weipht
2.0-6.0
40-60
40-60
Above a l s o eliminates odors such as those caused by pet urine.
Generally 5 ounces o f above added t o 5 gallons o f detergent
Oxidizes s t a i n s such as coffee, wine, j u i c e , e t c .
s o l u t i o n i s s u f f i c i e n t f o r good performance.
SOURCE: Burlington Chemical Co., Inc.: Suggested Formulations
138 Advanced CleaningProduct Formulations
Low Cost E x t r a c t i o n CarDet Cleaner
Water, D . I .
Petro 22 Powder
EDTA Powder
Perfume
Blending Procedure:
Use D i l u t i o n : 1-2 ot/gal o f water
Formula 901
Blend ingredients i n t h e order l i s t e d .
% bv Weight
91 .o
5.0
4.0
Q . S .
Medium Cost Steam E x t r a c t i o n Carpet Cleaner
Water, D . I .
Petro 22 Powder
Sodi um T r i p o lyphosphate
Sodium S i l i c a t e 42 Be' (Star)*
T r i sodi um Phosphate, Crystal
DeSonic 9N
Perfume
*Pa Corp.
Blend ingredients i n t h e order l i s t e d
01end1ng Procedure:
Use D i l u t i o n : 1-2 oz/gal . o f water
Formula 902
% bv Weight
76.5
3.5
5.0
9.0
2.0
4.0
q . s .
Premium. Heavy Duty Steam E x t r a c t i o n Carpet Cleaner
Sodium Tripolyphosphate, L i g h t Density
Sodium M e t a s i l i c a t e , Pentahydrate
Petro 22 Powder
Optical Brightener
01endi ng Procedure:
Use D i l u t i o n : 1-2 oz/gal
Formula 906
SOURCE: Witco Corp.: Suggested Formulations
Blend ingredients i n t h e order l i s t e d .
% by Weight
40.0
54.5
5 . 0
0 . 5
Rug, Floor, Carper, Upholsteryshonrpocrs and Cleaners 139
Non-Ammaniated Floor S t r i m e r
Water
Sodium Metasilicate, Pentahydrate
Monoethanolamine
Potassium Hydroxide, 45%
Witcamide S-771
Butyl Cellosolve
Witconate SXS L i q u i d
%-by Weight
65.44
1.oo
16.25
3.25
8.00
4.06
2.00
Blending Procedure:
between each a d d i t i o n .
Typical Properties:
Solids: 13.3%
pH, as i s : 13.3
Blend ingredients i n t h e order shown, mixing thoroughly
Formula 924
Non-Ammoniated Floor S t r i m e r
Monoethanolamine
Witcamide S-771
Butyl Cellosolve
9b bv Weiaht
40.0
20.0
40.0
81endi ng Procedure:
between each addition.
Typical Properties:
Solids: 20.0%
pH, as i s : 11.4
Blend ingredients i n t h e order shown, mixing thoroughly
Formula 923
SOURCE: Witco Corp.: Suggested Formulations
I40 Advanced CleaningR h t FormJatiotu
Quarry T i l e Cleaner
I n q r e d i e n t s :
Water
Bi o-Soft S-1 00
Makon 10
Hydroxy A c e t i c A c i d (70%)
HC1 (37%)
M i x i ng Procedure :
T y p i c a l P r o p e r t i e s :
Mix thoroughly i n order given.
Appearance: L i g h t yellow, c l e a r l i q u i d
p H , as i s : 1.87
S p e c i f i c G r a v i t y , g/ml: 1.01
V i s c o s i t y , @ 25C, cps: 15
S t a b i l i t y :
40F ( 7 days): Pass
75F ( 7 days): Pass
120F ( 7 days): Pass
Freeze/Thaw ( 3 c y c l e s ) : Pass
% bv WeiQht
88.0
4.0
3.5
3.0
1 . 5
Use I n s t r u c t i o n s :
pour concentrate d i r e c t l y on. Spread w i t h mop and leave f o r t e n
minutes. Scrub and squeegee, r i n s e w i t h water. Dry w i t h c l e a n
mop.
leave f o r f i v e minutes, then scrub, r i n s e , and d r y .
SOURCE: Stepan Co.: Formulation No. 582
One t i m e o n l y : H e a v i l y s o i l e d f l o o r : wet f l o o r w i t h water and
D a i l y Cleaning: 4 oz/l gal water d i l u t i o n . Apply w i t h mop and
Low Foam Floor Cleaner
Water
Sodium M e t a s i l i c a t e (Anhydrous)
Tetrapotassium Pyrophosphate
Mona NF-10
% by Weisht
70
5
14
11
Procedure:
Add i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n .
Typi c a l Propert ies :
Cloud P o i n t : 93C
K r a f t P o i n t : COC
Recommended Use D i l u t i o n : 1 t o 4 o z . / g a l .
SOURCE: Mona I n d u s t r i e s , I n c . : Formulation F-545
Rug, Floor, Carpet, Uphoktery Shampoos and Cleaners 141
SDecia1-PurDose F l o o r C1eaner . L iauid-A
Marlon A 365
Marlophor ND-DEA-salt
Marlowet T or 5622
Na cumene sulphonate 40
T r i ethanol ami ne*
Tetrapotassium pyrophosphate
Balance water, fragrance, preservative
Active matter: 16.5%
Formulation A w i t h a n t i s t a t i c p r o p e r t i e s
Special-Purpose Floor Cleaner. Liauid-6
Marlon PS 65
Isopropanol*
Lonzabac 12.30
N i t r i l o t r i a c e t a t e , 40%
Balance water, fragrance, preservative
Active matter: 3.3%
Formulation B w i t h microbicidal p r o p e r t i e s
Wash-and-Wax Floor Cleaner. L iauid-A
M a r l i p a l 013/79
Marlox FK 64
Marlowet 5622
N i t r i l o t r i a c e t a t e powder
C i t r i c a c i d
Wax emulsion. 15%. basis Vestowax AW 1060*
Balance water, fragrance, preservative
Active matter: 9.5%
%
5.0
10.0
5.0
10.0
4.0
6.0
t o 100
%
5.0
25.0
3.0
0.5
t o 100
%
5.0
3.0
2.0
0.2
0.3
10.0
t o 100
Wash-and-Wax F1oor Cleaner, L iauid-B
%
Marl ip a l 013/60 8.0
Marlowet 5622 2.0
N i t r i l o t r i a c e t a t e powder 0.2
C i t r i c a c i d 0.3
Wax emulsion, 15%, basis Vestowax AW 1060* 10.0
Balance water, fragrance, preservative t o 100
Active matter: 10.0%
SOURCE: Huls America, I n c . : Basic Formulations o f Detergents
and Cleaning Agents f o r Household Purposes
14. Miscellaneous
142
Miscellaneous 143
Condensate TL: Typical Formulations
A l l Purpose Cleaner
Condensate TL
Harco 20% Soap
STPP
Water
Bubble Bath
Diethanolamine Laurel S u l f a t e (35% A c t i v e )
Stepanol DEA
Condensate TL
Water
D i l u t a b l e Shampoo(l:8)
Diethanolamine Laurel S u l f a t e (35% Active)
Stepanol DEA
Condensate TL
Isopropanol
H2S04 (conc.) (TO pH 7.0-7.5)
V i scous Floor Cleaner
Condensate TL
TSPP
STPP
Harco 20% Soap
Water
5 . 0 %
50.0%
1-2%
To 100%
30.0%
5.0%
65.0%
60.0%
35.0%
1.15%
4%
9.0%
4.0%
4.0%
20.0%
63.0%
Dishwashi ne L iaui d
Sodium Xylene Sulfonate 4.0%
Dodecylbenzene S u l f o n i c Acid 12.5%
Noni oni c Detergent 6.0%
Condensate TL 3.0%
50% Caustic Soda Adjust t o pH o f 7 . 0 + - 0 . 5
SDA 3A Alcohol 2.0
Dye 8 Perfume
Water To 100%
ODacified Hand SoaD
Opaci f ie r
Water Soluble Lanolin
Condensate TL
Conc. Coconut/Veg. O i l Potash Soap
Perfume 8 Dye
Water
0.70%
1.25%
12.5%
20.0%
To 100%
SOURCE: Concord Chemical Co., I n c . : Suggested Formulations
I44 Advanced Cleaning product Formulations
d' Limonene Waterless Hand Cleaner
Phase I:
Water, D.I.
T r i sodi um Phosphate
Sodium C i t r a t e
G1y c e r i ne
Phase 11:
d ' L imonene
DeSonic 9N
Varonic T202
% by Weight
81 .o
1. o
2.0
2.0
7.0
5.0
2.0
Blending Procedure:
Heat t o 140F. Combine Phase I1 ingredients i n separate vessel
and mix thoroughly. Heat t o 140F. While mixing r a p i d l y , add
Phase I1 t o Phase I. Cool q u i c k l y t o s t a b i l i z e emulsion.
Typical Properties:
Appearance, Room Temp.: Heavy Cream
Solids: 12.0%
pH: 10.4
I n vessel #1 combine Phase I ingredients and mix thoroughly.
Formula 1120
Water1ess Hand C1eaner
Emphos PS-220
Kerosene, deodorized
Stoddard Solvent, deodorized
T r i ethanol ami ne, 99%
Water
% by Weight
8.7
37.9
15.4
2.2
35.8
81ending Procedure:
between each a d d i t i o n .
Formula 1119
SOURCE: Witco Corp.: Suggested Formulations
01end ingredi ents in t h e order shown, m i x i ng thorough1y
Miscellaneous 145
D r y Cleanina
By using Aerosol OT-100% Surfactant i n d r y cleaning solvent
a t a concentration o f ca. 0.1 oz./gal. t h e soaps used as aids
i n water-soluble s t a i n removal can be replaced i n t h e d r y
cleaning industry. I n contrast t o many soaps, Aerosol OT does
not o x i d i z e w i t h consequent development o f undesirable odor
upon aging.
Aerosol OT-100% dissolved i n a s u i t a b l e solvent, such as
t r i c h l o r o e t h y l e n e . naphtha, carbon t e t r a c h l o r i d e , or comb-
i n a t i o n s o f these, can be used t o remove solvent-soluble
s t a i n s a f t e r f a b r i c s have become wet w i t h water. The mixture
can then be flushed out w i t h a d d i t i o n a l water.
As a whitener f o r k i d gloves, i t i s recommended t h a t 4 oz.
o f Aerosol OT-100% be dissolved i n a g a l l o n o f Stoddard solvent,
t o which may be added from 4 t o 8 oz. o f zinc stearate.
A water brushing f o r r e t a i n i n g p l e a t s i s made by
d i s s o l v i n g 4 oz. o f Aerosol OT-100% Surfactant i n one-half
g a l l o n o f Stoddard solvent, t o which i s added one p i n t o f wet
spotter and one-half p i n t o f water. The pleated items should
be brushed thoroughly w i t h t h e mixture, then simply hung i n t h e
a i r t o dry, t o e l i m i n a t e water. The item should be re-cleaned
w i t h solvent t o dispose o f t h e other agents present. It w i l l come
out without wrinkles o r disturbed p l e a t s .
S a t i s f a c t o r y s p o t t i n g mixtures can be made as follows:
To1uol 3 q t .
Perch1oroethyl ene 1 q t .
Water 1/2 p t .
1 . Aerosol MA-80 Surfactant* 1 l b .
* I f Aerosol OT i s used instead o f Aerosol MA, t h e mixture
becomes t u r b i d when water i s added.
2. Aerosol OT-100% Surfactant 1 l b .
Stoddard Solvent 2 g a l .
Water 3 p t .
I n order t o increase the wetting out (reduce t h e break time)
o f exceptionally greasy a r t i c l e s , t h e use o f 0.25% to 1.0% of a
10% aqueous s o l u t i o n o f Aerosol OT Surfactant (based upon t h e
weight o f t h e water) i s resorted t o occasionally i n laundry
practices. During exceptionally busy periods, t h e use o f 10%
aqueous Aerosol OT solutions w i l l reduce the treatment t me
and thus increase e f f i c i e n c y , although i t i s t r u e t h a t a k a l i
together w i t h hot water over a longer treatment period w 11
accomplish t h e same r e s u l t s . A l k a l i w i t h hot water f i x e s egg
albumin whereas Aerosol OT Surfactant does n o t .
SOURCE: Cytec I n d u s t r i e s Inc.: Suggested Formulations
146 Advanced Cleaningproduct Formulations
Dust Control
Areas o f Use:
o f t a l c o r face powder, m i l l i n g g r a i n and sawing wood are a l l
f i r e , explosion and/or h e a l t h hazards. Such dusty conditions can
be a l l e v i a t e d o r c o n t r o l l e d by water sprays containing small
amounts o f Aerosol GPG Surfactant.
Reasons f o r Using Aerosol GPO Surfactant:
r a t i o n s o f o n l y 0.01% t o 0.05% o f Aerosol GPG Surfactant i n
water provide e f f i c i e n t and economical wetting.
Areas t o be Sprayed:
c r e a t i o n o f dust. Dusty m a t e r i a l s being conveyed may a l s o be
sprayed. This p r a c t i c e not o n l y minimizes t h e problem o f
airborne dust, b u t simultaneously reduces product loss. Spray
heads may be located a t as many l o c a t i o n s as have dust problems
because t h e equipment required i s moderate i n cost and t h e r e i s
no hazard t o personnel from Aerosol GPG Surfactant.
Dust r e s u l t i n g from operations such as mining coal, production
Most dusts are r e s i s t a n t t o w e t t i n g by water alone. Concent-
Work surfaces may be wetted w i t h a f i n e spray t o prevent
Concentrations o f Aerosol GPG Surfactant
cWe1 h t
Inoredi ents:
Aerosol GPG Surfactant
Ethanol
Water
Inaredi ents :
Aerosol GPG Surfactant
Ethanol
Water
Inaredients:
Aerosol GPG Surfactant
Ethanol
Water
Ingredients:
Aerosol GPG Surfactant
Ethanol
Water
Ingredients:
Aerosol GPG Surfactant
Ethanol
Water
Procedure:
The stock s o l u t i o n may
stream by a p r o p o r t i o n i n g
t h e f i n a l s o l u t i o n may be
-1%
1.43
none
t o make 100 p a r t s
-5%
7.15
t o make 100 p a r t s
-10%
14.3
t o make 100 Darts
10-20
15-20
25%
35.7
10-15
t o make 100 Darts
-50%
71.5
15-20
t o make 100 p a r t s
be introduced i n t o t h e main water
DumD o r an eductor. The strenath o f. .
adjusted by changing t h e amount o r
s t r e n g t h o f t h e stock s o l u t i o n being added. The range o f strength
concentrations shown i n t h e t a b l e above w i l l a l l o w any ordinary
method o f metering.
Further c o n t r o l may be provided by use o f adjustable spray
heads.
SOURCE: Cytec I n d u s t r i e s Inc.: Suggested Formulations
Miscellaneous 147
Hand and Body Cleanser
Phase I:
Water, D . I .
Witconate AOS
Varonic LI-48
Varonic LI-67
Ethylene Glycol Monostearate
Varamide ML-1
Phase 11:
Glycerine
Lanoquat 50
EDTA
Rewoteric AM 8-15
Phase 111:
C i t r i c Acid
Phase I V :
Sodium Chloride
Phase V:
Preservat ive
96 by Weight
67.0
20.0
3.7
1.3
1.6
2 . 5
0.2
0.5
0.1
3.1
q.s.
q.s.
q.s.
Blending Procedure:
Heat Phase I water t o 8OC. Blend i n Witconate AOS w i t h good
a g i t a t i o n . When t h i s i s blended completely, add t h e remaining
Phase I ingredients, melting them f i r s t before adding. Cool t o
45C and add Phase 11, i n the order l i s t e d . Cool t o 35C and
adjust pH = 7.0-7.7 w i t h c i t r i c acid. Add sodium c h l o r i d e t o
desired v i s c o s i t y .
Typical Properties:
Solids: 19.5%
pH: 7.3
SOURCE: Witco Corp.: Formula 1125
148 Advanced CleaningProduct Formulations
Heavv Dutv Deareaser
Butoxyethanol
Mackam JS
Sodium M e t a s i l i c a t e Pentahydrate
Sodium T r i p o lyphosphate
T r i sodi urn Phosphate
T a l l O i l F a t t y Acid
KOH (45%)
EDTA (40%)
Deionized Water
Procedure:
1. Add components t o water and heat t o 40C.
2 . Blend u n t i l c l e a r .
Mackamide CD
TKPP
Glycerin
Mackadet 40K
Procedure:
Burni shi na Colnpound
(Cocamide DEA)
(Potassium Coconut Soap)
Weiqht,%
8 . 0
3.5
3.0
1.5
2.5
2.0
2.1
0.3
77.3
Wei qht .%
93.0
1.5
2.7
2.7
1. Disperse TKPP i n Glycerin and add Mackadet 40K.
2. Then blend i n Mackamide CD.
Remarks:
The product upon d i l u t i o n w i t h water w i l l form a cloudy emulsion
which requires shaking before use.
The f i n a l product w i l l form an almost water c l e a r product.
Corrosion I n h i b i t i n g Coating O i 1-Emulsifiable
Wei aht .%
Mackazoline 0 (Oleyl Hydroxyethyl Imidazoline) 16.5
L i g h t Mineral O i l 75.0
Glacial Acetic Acid 1.5
Oleic Acid 7.0
Procedure:
1. Blend Mackazol i n e 0 and Mineral O i 1.
2. Add Acetic Acid and Oleic Acid.
3. Blend u n t i l c l e a r .
SOURCE: McIntyre Group Ltd.: I n d u s t r l a l Formulary
Miscellaneous 149
Heavy D u t y I n d u s t r i a l Spray Metal Cleaner Concentrate
Water
Potassi um Hydroxide
Sodium M e t a s i l i c a t e (Anhydrous)
Sodium Carbonate
Mona NF-25
% by Weiaht
65
10
10
5
10
Procedure:
Typical Properties:
Cloud P o i n t : 43C
K r a f t Point: COC
Add i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n .
Recommended Use D i l u t i o n : 6 t o 8 o z . / g a l .
Formulation F-544
Low Foam Hypochlorite Cleaner
I n redients;.
water
Sodium Hypochlorite (5.25%)
Mona NF-10
% bv Wei qht
79.0
19.0
2 . 0
Procedure:
Blend i n g r e d i e n t s i n order l i s t e d . Adjust pH t o 13-14 w i t h 45%
KOH .
Formulation F-655
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formulations
Metal CleanerJBri nhtener
Eastman EB solvent
C i t r i c a c i d
Phosphoric a c i d (85%)
Nonionic s u r f a c t a n t *
Water
% by WeixhL
4.5
4.0
2.5
3.0
86.0
*Such as Neodol 91-8 alcohol ethoxylate (Shell Chemical Co.)
o r Rhodasurf LA-9 alcohol ethoxylate (Rhone-Poulenc).
SOURCE: Eastman Chemical Co.: Eastman EB and DB Solvents f o r
Cleaners: Suggested Formulation
150 Advanced CleaningProduct Formulations
Hot l a n k- StripperjCleaner/Deruster
Component:
Caustic Potash C r y s t a l
Anhydrous Sodium M e t a s i l i c a t e
Burco BSGH-270 o r BSGH-Crystals
Burco ADS-100
Burco TME
Dodecylbenzenesulfonate Powder
10.0
15.0
5.0
2.5
5.0
Procedure:
onto m i x t u r e and blend u n t i l f u l l y absorbed. Add 8urco ADS-100,
Gluconate o r Glucoheptonate and Dodecylbenzenesulfonate. Blend
u n t i 1 uniform.
increase p a i n t s t r i p p i n g e f f i c i e n c y provided s u f f i c i e n t a l k a l -
i n i t y i s present. The Gluconate o r Glucoheptonate p r o v i d e t h e
d e r u s t i n g . Burco TME and 8urco ADS-100 provide removal and d i s p -
e r s i o n o f p a r t i c u l a t e s o i l s w h i l e t h e Dodecylbenzenesulfonate
adds w e t t i n g and o i l y s o i l detergency. Each component can be
adjusted according t o t h e improvement needed.
Blend Caustic Potash and Sodium M e t a s i l i c a t e . Spray Burco TME
Each component has a s p e c i f i c f u n c t i o n . The M e t a s i l i c a t e w i l l
~~Low Foam_Heavy Duty A1k a l ine C leaner-A
CommDonent: %. bx_Wei.&t
Water 58
Sodium M e t a s i l i c a t e , Pentahydrate
Burcene 100
Burcosolv TM
Burco TME
Burcowet TM-LF
5
2
10
20
5
Procedure:
eous between each a d d i t i o n .
Add a l l components i n t h e order l i s t e d . S t i r u n t i l homogen-
Formulation A i s low foaming a t temperatures above 160F.
Low Foam Heavy-Duty A1k a l ine. Cleaner-6
Component:
Water
Sodium M e t a s i l i c a t e , Pentahydrate
Sodi um Xylene Sul fonates 40%
Burcosolv TM
Burco TME
Burco LAF-125
% by Weight
55
5
8.5
10
20
5
Procedure:
between each a d d i t i o n .
SOURCE: B u r l i n g t o n Chemical Co., I n c . : Suggested Formulations
Add a l l components i n t h e order l i s t e d . S t i r u n t i l homogeneous
Formulation B i s low foaming above 1OOF.
Miscelloneous 151
Pain t Brush C1eaners
Aerosol C-61 Surfactant i s a c a t i o n i c reagent t h a t w i l l
a c t i v a t e s t r o n g l y t h e v o l a t i l e solvents commonly used f o r
removing p a i n t . B r i s t l e brushes and r o l l e r s , glass, porcelain,
metal, p l a s t i c , and c l o t h i n g have been t r e a t e d successfully.
A 5 1 0 % s o l u t i o n o f Aerosol C-61 i n a solvent, o r mixed solvents
is recommended.
Extremely r a p i d sedimentation o f p a i n t pigment has been
obtained w i t h t h e f o l l o w i n g composition:
Inaredients:
Aerosol C-61 Surfactant
Butyl Cellosolve Solvent
Xyl ene
% by Weight
o r Volume
5
5
90
Brushes and r o l l e r s may be cleaned immediately a f t e r use by
being suspended i n t h i s mixture. I n a few hours p r a c t i c a l l y a l l
o f t h e p a i n t pigment s e t t l e s i n a l a y e r beneath t h e b r i s t l e s .
The solvent mixture may be reused repeatedly. When t h e pigment
has s e t t l e d t h e brush may be removed and hung i n c i r c u l a t i n g
a i r t o dry. For best r e s u l t s , t h e brush then should be washed
i n soapy water and rinsed. I f t h e brush i s t o be used again
immediately, i t may be rinsed i n solvent instead o f d r y i n g and
waterwashi ng.
w i t h hard, dry p a i n t , t h e f o l l o w i n g formulation has proved suc-
essf u l .
For renovating brushes t h a t have been allowed t o become caked
Ingredients:
Aerosol C-61 Surfactant
Xyl ene
Butanol
Mineral Spi r it s
?4 by Weight
o r Volume
10
45
5
40
The brush i s soaked i n t h e mixture f o r a time, then worked
up and down t o a i d t h e penetration i n t o t h e caked p a i n t . The
soaking and working may be repeated several times i f the p a i n t i s
very hard and d r y . When t h e o l d p a i n t has soaked out o f t h e
brush, t h e brush i s rinsed i n clean, warm water and f i n a l l y
washed i n soapy water and r i n s e d again, then hung up t o d r y .
A f t e r being d r i e d t h e b r i s t l e s have t h e appearance and f e e l of
those o f a new brush.
SOURCE: Cytec I n d u s t r i e s Inc.: Suggested Formulations
I52 Advanced Cleaningproduct Formulations
Steam Cleaner
Water
Potassi um Hydroxide
Sodium M e t a s i l i c a t e (Anhydrous)
Tetrapotassium Pyrophosphate
Mona NF-15
% by WeiQht
65
3
10
10
12
Procedure:
Add i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n .
Typical P r o p e r t ies :
Cloud P o i n t : 75C
K r a f t P o i n t : >OC
Recommended Use D i l u t i o n : 4 t o 6 o z . / g a l .
Formulation F-541
Water
Sodium Hydroxide (50%)
Mona NF-25
Helvy Duty Indus-ray c l e a n e r Concentrate
% by Weigh%
40
50
10
Procedure:
Add i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n .
Typical P r o p e r t i e s:
Cloud P o i n t : 75C
K r a f t P o i n t : >5C
Recommended Use D i l u t i o n : 1 t o 4 o z . / g a l .
Formulation F-543
High Sol i d s A1 k a l ine C1eaner
Water
Potassium Hydroxide
Sodium M e t a s i l i c a t e (Anhydrous)
Tetrapotassium Pyrophosphate
Mona NF-25
% bv Weiclht
45.0
10.0
10.0
25.0
10.0
Procedure:
Mix i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n .
Formulation F-555
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formulations
Miscellaneous 153
WallDaDer Removal
A stock s o l u t i o n o f Aerosol OT-75% Surfactant, o r a powder
containing Aerosol OT-B Surfactant can be prepared f o r use as
a wallpaper remover. D i l u t e d w i t h water by t h e user t o a con-
c e n t r a t i o n o f 0.025% Aerosol OT, t h e s o l u t i o n i s h i g h l y e f f e c t -
i v e i n soaking o f f o l d wallpaper, and o f t e n renders t h e use of
an expensive and bulky steamer unnecessary.
A t y p i c a l l i q u i d concentrate wallpaper remover can be prep-
ared as follows.
Inqredi ents:
Aerosol OT-75% Surfactant
Isopropyl Alcohol
Water
% by Weisht
15.0
15.0
70.0
D i r e c t i o n s :
Use one tablespoon o f t h e above formulation per g a l l o n o f
warm water. Apply t o a l a r g e section o f wallpaper and w a i t a
few minutes. I f necessary, apply again.
Aerosol OT-B Surfactant:
The f o l l o w i n g powdered concentrate may be prepared using
Inqredients:
Sodium S u l f a t e (Powder)
Aerosol OT-B Surfactant
% by Weiqht
90.0
10.0
D i r e c t i o n s :
recommended above.
SOURCE: Cytec I n d u s t r i e s , Inc.: Suggested Formulations
Use one teaspoonful per g a l l o n o f warm water and apply as
Section II
Transportation Cleaners
and Polishes
154
15. Auto Cleaners and Polishes
155
156 Advanced CleaningRoduct Formulations
Auto Pol ish/Cl eanser
O i l i n Water Emulsion
Phase A:
1 Deionized Water
2 668 P o l i s h i n g Powder
3 Volclay NF-BC
Phase 0:
4 PEG-10 Carnauba
6 Montan Wax "S"
7 O l e i c Acid
8 Morpholine
Phase C:
9 Odorless Mineral S p i r i t s
5 SF96-350
% by Weiqht
40.5
15.0
1. o
7.0
4.0
2.5
1.5
1 .o
27.5
Procedure:
hydrate f o r 15 minutes. Bring temperature up t o 75C. I n a
separate vessel, combine Phase B and w h i l e mixing, b r i n g
temperature up t o 85C t o melt t h e waxes. Gently heat t h e mineral
s p i r i t s t o 65C and add t o Phase 0. Once uniform and a 75C temp-
e r a t u r e i s reached, slowly add t h i s t o Phase A, maintaining
good a g i t a t i o n . Continue mixing u n t i l emulsion cools t o 40C.
Pour i n t o appropriate containers.
emulsion, w h i l e preserving t h e strength and i n t e g r i t y o f a
n a t u r a l carnauba f in i sh.
Combine Phase A under a g i t a t i o n and a l l o w t h e Volclay t o
The PEG-10 Carnauba i n t h i s formula helps t o create a s t a b l e
Detergent Resistant Auto Pol ish/Cleanser
Paste Wax
1 Odorless Mineral Spi r it s
2 787 P o l i s h i n g Alumina P-10 Feinst
3 Ozokerite 170
4 #3 Carnauba
5 Synthetic Carnauba
6 SF1706
7 Hexanedi o l Behenyl Beeswax
8 V i s c a s i l 12M
% by WeiQht
57.0
12.0
8.0
6.0
6.0
5.0
4.0
2.0
Procedure:
8OC. Mix u n t i l homogeneous. Add t h e alumina w h i l e mixing, and
cool t o 35c.
equal p a r t s o f #3 Carnauba and Synthetic Carnauba. This s u b s t i -
t u t i o n has no e f f e c t on t h e f i n i s h e d product and w i l l y i e l d t h e
same r e s u l t s . The o n l y d i f f e r e n c e i s a reduction i n cost.
SOURCE: Koster Keunen I n c . : Suggested Formulations
Combine a l l ingredients, leaving out t h e alumina, and heat t o
The #1 Yellow Carnauba i n t h i s formula has been replaced by
Auto Cleanersand Polishes 157
Carnauba Hotwax
Carnauba spraywax w i t h excellent performance and s t a b i l i t y
i s produced using:
Inaredient :
Mineral seal o i l
Tomah Emu1s i f ie r Four
9-10 mole ethox. nonionic
Ethylene g l y c o l monobutyl ether
Water (70-9OF)
Emulsion C-340
Wei aht%
9.0
6.9
0.3
1.3
67.5
15.0
Add ingredients sequentially and mix completely p r i o r t o each
a d d i t i o n . The carwash w i l l use the "hotwax" by d i l u t i n g 1:lO
w i t h water and then i n j e c t i n g 6-8 0 2 . o f the d i l u t e product
onto each car. The product w i l l not separate or g e l l .
Pressure Spray Truckwash
Water
Sodium M e t a s i l i c a t e Pentahydrate
EDTA ( l i q u i d 46%)
Tomah Q-17-2
Tomah AO-14-2
Texstim 0741
45% Caustic Potash
Tomah A l k a l i Surfactant
Wei aht%
05.7
4.2
1.8
1 .o
1 .o
2.0
2.6
1.7
Texstim 0741 i s a nonionic surfactant which performs as a
"self-demulsifying" detergent. This i s extremely useful i n
truckwash applications. I n most o i l / w a t e r separators, the
formulation " s p l i t " t h e o i l and water i n t o two phases without
f u r t h e r treatment. The o i l phase can then be skimmed o f f f o r
recovery o r disposal and not be sent t o t h e sewage treatment
p l a n t .
SOURCE: Tomah Products, Inc.: Suggested Formulations
158 Advanced CleaningProduct Formulations
D e t e r q e n t R e s i s t a n t A u t o P o l i s h
O i l i n Water Emulsion
% bv Weight
Phase A:
1 D e i o n i z e d Water 44.3
2 678 P o l i s h i n g Powder 8.0
3 V o l c l a y NF-BC 1 .o
4 Morpholine 0 . 7
Phase B:
5 I s o p a r L 1 8 . 0
6 I s o p a r M 8 . 0
7 PEG-I0 Carnauba 6.0
8 S i l i c o n y l Beeswax 6.0
9 SF96-350 3.0
10 S t e a r i c A c i d 1 .o
Phase C :
11 I s o p a r M 5 . 0
12 SF1706 2.0
Procedure:
Combine Phase A under a g i t a t i o n and b r i n g temperature up t o
85C. I n a s e p a r a t e v e s s e l , combine Phase B and w h i l e m i x i n g ,
b r i n g t h e temperature up t o 9OC. Once b o t h phases a r e up t o
temperature, add Phase B t o Phase A and m a i n t a i n moderate a g i t -
a t i o n . S l o w l y c o o l and a t 60C add Phase C .
The S i l i c o n y l Beeswax p e r f o r m s w h i l e a p p l y i n g t h e p o l i s h b y
c r e a t i n g a smooth, even c o a t i n g on t h e s u r f a c e o f t h e automobile.
The PEG-10 Carnauba t o g e t h e r w i t h t h e amine f u n c t i o n a l s i l i c o n e ,
g i v e s t h e p o l i s h e d s u r f a c e a deep g l o s s and an e x t r e m e l y d u r a b l e
f i n i s h .
H i g h L u s t e r Auto F i n i s h
Paste Wax
1 Odorless M i n e r a l S p i r i t s
2 I s o p a r L
3 I s o p a r M
5 #3 Carnauba
6 S y n t h e t i c Carnauba
7 O z o k e r i t e 170
8 White Beeswax
9 V i s c a s i l 12M
4 SF96-350
% by Weight
49.0
14.0
10.0
8 . 0
6.0
6.0
3.0
2.0
2 . 0
Procedure:
Combine a l l waxes and s i l i c o n e s . Heat t o 85C. W h i l e m i x i n g ,
s l o w l y add t h e s o l v e n t s . Continue m i x i n g and c o o l t o 40C.
Equal p a r t s o f #3 Carnauba and S y n t h e t i c Carnauba a r e used
w i t h t h e i n t e n t i o n s o f t h e s e b e i n g a d i r e c t s u b s t i t u t e f o r #1
Y e l l o w Carnauba. The #3 Carnauba and S y n t h e t i c Carnauba w i l l
y i e l d t h e same r e s u l t s as #1 Y e l l o w Carnauba, b u t a t a s i g n i f -
i c a n t c o s t s a v i n g s .
SOURCE: K o s t e r Keunen I n c . : Suggested F o r m u l a t i o n s
Auto Cleoners ond Polish 159
High Gloss, Detergent Resistant P o l i s h
Formulation 20-6 i s a wax-free p o l i s h , which provides a high-
gloss, detergent r e s i s t a n t f i n i s h on non-porous substrates.
Simple a p p l i c a t i o n , without hard rubbing o r b u f f i n g r e s u l t s i n
both depth o f gloss and detergent resistance f o r extended
p r o p e r t i e s .
Ingredients:
( 1 ) GP-121 S i l i c o n e P o l i s h A d d i t i v e
( 2 ) GP-10-1,000 S i l i c o n e F l u i d
( 3 ) Stoddard Solvent
( 4 ) Mineral S p i r i t s (Odorless)
( 5 ) Witcamide 511
(6) Kaopolite SF
(7) S o f t Water
( 8 ) Giv-Gard DXN
Combine i n order shown w i t h high shear mixing unt
i n g occurs. Mix u n t i l homogeneous and package.
Formul a t i on Properties:
*Contains no wax *Non-smeari ng
*High gloss *Cost e f f i c i e n t
*Detergent r e s i s t a n t *Cold blend(0nly mix
* E a s i l y a p p l i e d *Resistant t o wash-o
Formula 20-6
High Gloss Auto P o l i s h f F i n i s h
% by weight
13.0
2.0
5.5
1.4
5.0
67.5
0.1
5.5 ,
1 thicken-
ng required)
f
Ingredients:
( 1 ) GP-121 ( S i l i c o n e P o l i s h A d d i t i v e )
(2) Witcamide 511
(3) Kaopolite SF
( 4 ) S o f t Water
( 5 ) Giv-Gard DXN
% by. Weight
26.0
1.4
5.0
67.5
0.1
Combine i n order shown w i t h high shear mixing u n t i l t h i c k e n i n g
occurs. Mix u n t i l homogeneous and package.
Formulation Properties:
*Contains no wax *High gloss
*Detergent r e s i s t a n t *Easi 1y appl i e d
*Non-smeari ng *Cost e f f ic i ent
*Cold blend Only mixing required
Formula 20-5
SOURCE: Genesee Polymers Corp.: Suggested Formulations
160 Advanced CleaningRoduct Formulations
Spravwax Concentrate
The f o l l o w i n g formula should produce a c l e a r , s t a b l e spraywax
concentrate.
Comonent:
Kerr-McGee Mineral seal o i 1
Emuls i f ie r 827
Ethylene g l y c o l monobutyl ether
Water (70-9OF)
Grams
18.0
15.0
4 . 0
63.0
D i r e c t ions :
monobutyl ether and m i x u n t i l c l e a r . Add water slowly w h i l e
mixing. When water has been added, mix about 5 more minutes.
Add dye i f desired. Addition o f a fragrance may r e q u i r e a s l i g h t
formulation change. The f i n a l product w i l l be c l e a r and i s
normally packaged i n 5 g a l l o n p a i l s . The carwash should d i l u t e
5 gallons o f concentrate w i t h 50 gallons o f water and then
i n j e c t about 6 02s. o f t h e d i l u t e spraywax through a DEMA
system onto each c a r .
Charge t h e mineral seal o i l , E m u l s i f i e r 827, ethylene g l y c o l
Spraywax
The f o l l o w i n g t y p i c a l formulation i s h i g h l y e f f e c t i v e ,
problem free, and s t a b l e i n both concentrate and d i l u t e form.
Inaredient :
Kerr McGee Mineral Seal O i l
Emuls i f ie r Four-HF
9-10 mole ethoxylated nonionic
Ethylene g l y c o l monobutyl ether
Tap Water
Weiaht %
20.0
15.0
1.o
3.0
61 . O
D i r e c t i o n s :
nonionic, ethylene g l y c o l monobutyl ether and mix u n t i l c l e a r .
Add water slowly w h i l e mixing. When water has been added, mix
about 5 more minutes. Add dye i f desired. Addition o f a frag-
rance may r e q u i r e a s l i g h t formulation change. The f i n a l product
w i l l be c l e a r and i s normally packaged i n 5 g a l l o n p a i l s . The
carwash should d i l u t e 5 gallons o f concentrate w i t h 50 gallons
o f water and then i n j e c t about 6 02s. o f t h e d i l u t e spraywax
through a DEMA system onto each car.
SOURCE: Tomah Products, I n c . : Suggested Formulations
Charge t h e mineral seal o i 1, Emulsifier Four-HF, ethoxylated
Auto Cleaners andPolishes 161
Spravwax Ladder of Formulas
Because mineral seal o i l s d i f f e r i n e m u l s i f i c a t i o n char-
a c t e r i s t i c s , i t i s necessary t o modify t h e formulation t o
achieve optimum performance. The best formula can be deter-
mined by running a ladder o f formulas. Typical examples are:
Comonent:
Mineral seal o i l
Emuls i f ie r Four-HF
9-10 mole ethoxylated nonionic
Ethylene g l y c o l monobutyl ether
Water
Component:
Mineral seal o i l
Emuls i f ie r Four-HF
9-10 mole ethoxylated nonionic
Ethylene g l y c o l monobutyl ether
Water
Comoonent:
Mineral seal o i l
E m u l s i f i e r Four-HF
9-1 0 mole ethoxylated nonioni c
Ethylene g l y c o l monobutyl ether
Water
Components:
Mineral seal o i l
Emul s i f i e r Four-HF
9-10 mole ethoxylated nonionic
Ethylene g l y c o l monobutyl ether
Water
Grams-B
40.0
31 . O
1.o
6.0
122.0
Grams-C
40.0
30.5
1.5
6.0
122.0
Grams-D
40.0
30.0
2.0
6.0
122.0
Grams-E
40.0
29.5
2.5
6.0
122.0
Check a l l formulas f o r :
1. 1:lO d i l u t i o n i n water.
2. 120F s t a b i l i t y ( 3 hours i n sealed container i n water bath a t
3 . Freeze/thaw-24 hour recovery (sealed container).
The optimum formula w i 11 :
1. D i l u t e c l e a r and e a s i l y a t 1:lO d T l u t i o n .
2. Not cloud at. 120F.
3. Recover completely from freeze/thaw c y c l e (without shaking).
SOURCE: Tomah Products, I n c . : E m u l s i f i e r Four-HF: Formulas
120F).
16. Car and Truck Wash Compounds
162
Car and Truck Wash Compounds 163
Automatic Car Wash Concentrate
A High A l k a l i n e D i l u t a b l e Concentrate
Inaredient :
Oeioni zed Water
Maphos 60-A
Potassi um Hydroxide
Tetrapotassium Pyrophosphate
Sodium M e t a s i l i c a t e , Anhydrous
Macol LF-120
Mazamide 80
Sodium Xylene Sulfonate (40%)
Macol 48
Oeioni zed Water
pH (as i s ) : 12.5-13.5
Appearance: Clear, l i g h t - y e l l o w l i q u i d
S p e c i f i c Gravity: 1.06
Procedure:
Charge t h e f i r s t water p o r t i o n t o t h e mixing vessel and
s t a r t a g i t a t i o n . Add t h e ingredients i n t h e given sequence
and mix u n t i l c l e a r .
Notes :
This i s a h i g h l y a l k a l i n e cleaner designed t o be used i n
commercial automatic car washes a t a d i l u t i o n r a t e o f 1-2
ounces per gallon. Do not use d i r e c t l y on automotive f i n i s h e s .
Formula CA-102
Wt.%
50.00
6 . 0 0
3.00
2.00
2.00
2.00
2.00
3.00
3.00
27.00
General Purtmse Car Wash
High Foaming A11-Purpose D i 1u t a b le Concentrate
Ineredi ent : Wt.%
Deioni zed Water 50.00
Mazon 98 9.50
Macol TD-3 1.50
SLS (Sodi um Lauryl Sulfate) 2.50
Mazamide 80 3.00
Macol 48 1.oo
Triethanolamine (85%) 1.50
Deionized Water 31 .OO
pH (as i s ) : 8.5-9.5
Appearance: Clear, l i g h t - y e l l o w l i q u i d
S p e c i f i c Gravity: 1.02
Procedure:
Charge t h e f i r s t p o r t i o n o f water t o t h e mixing vessel and
s t a r t slow a g i t a t i o n . Excessive a g i t a t i o n w i 11 produce a foami ng
problem. Add t h e remaining ingredients i n t h e given sequence
and mix u n t i l c l e a r .
Notes:
t o be safe on car f i n i s h e s , yet e f f e c t i v e i n t h e removal o f
road grime and other s o i l s .
Formula CA-103
SWRCE: Mazer Chemicals: Supposted Formulations
This i s a copious-foaming, all-purpose car wash formulated
Use concentration i s 1-2 ounces per g a l l o n o f warm water.
164 Advanced Cleaning R h c t Formulations
Auto Shampoo Concentrate
Water, D.I.
Rewoteric AM KSF-40
Witcolate SE-5
% by Weight
80.0
15.0
5.0
Blending Procedure:
between each a d d i t i o n .
Typical Properties:
Viscosity, cps: 4.0
Solids: Q.O%
pH: 9.5
Add ingredients i n order shown and dissolve completely
Formula 628
High Foaming Car Wash
Water, D.I.
D i ethanol ami ne
Witco 1298SA
Varox 1770
Butyl Cellosolve
Sodi urn Metasi 1i c a t e
Sodium Tripolyphosphate
% by Weight
65.0
5.0
15.0
10.0
1.o
1.o
3.0
01endi ng Procedure:
1298 i n t o s o l u t i o n . Next, add remai n i ng ingredients a1lowi ng
t o dissolve completely between additions.
Typical Propert ies :
Viscosity. cps: 77.0
Solids: 27.5%
pH: 9.3
Add DEA t o water and mix thoroughly. Slowly dissolve Witco
Formula 631
Car Wash
Water
Witcolate A
W i t c o l ate S-l285C
Emcol NA-30
Preservative
Blending Procedure:
Blend i n g r e d i e n t s i n t h e order l i s t e d .
Typi cal Propert ies :
Solids: 28.4%
pH: 6.9
V i s c o s i t y , cps: Gel
Formula 623
SOURCE: Witco Corp.: Suggested Formulations
% by Wei aht
34.9
25.0
25.0
15.0
0.1
Car and l h c k Wash Compowrds 165
Car Wash L i q u i d
Formula TR-0023
A1 k y l benzene s u l f o n i c a c i d
Sodium xylene s u l f o n a t e
Igepal CO-710
Tetrapotassium pyrophosphate (60% a c t i v e )
Potassium hydroxide (45% a c t i v e )
Water
W t .%
6 . 0
11.5
3 . 0
2 5 . 0
2 . 5
5 2 . 0
-
Procedure
1 . D i ssol ve a1k y lbenzene s u l f o n i c a c i d i n water.
2 . A d d sodium xylene sulfonate, Igepal CO-710, tetrapotassium
pyrophosphate and potassium hydroxide, mixing w e l l a f t e r
each a d d i t i o n .
3. F i l t e r product.
Physical P r o p e r t i e s
pH (as i s ) : 9 . 5
pH (1%): 9.9
V i s c o s i t y : 10 cps
S p e c i f i c G r a v i t y : 1 .05
Car Wash Powder
Formula TR-0022
Igepal CO-710
Sodi um tripolyphosphate
Sodium m e t a s i l i c a t e pentahydrate
Sodium carbonate ( L t . d e n s i t y )
W t .%
1 0 . 0
50.0
5 . 0
35.0
Procedure:
1 . Mix Igepal CO-710 w i t h sodium tripolyphosphate.
2 . Add sodium m e t a s i l i c a t e pentahydrate and sodium carbonate
Physical Properties:
Appearance: White, f r e e - f l o w i n g powder
pH (1%): 11.2
S p e c i f i c G r a v i t y : 0 . 7 3
SOURCE: Rhone-Poulenc Surfactants & S p e c i a l t i e s : Formulas
166 Advanced CleaningProduct Formulotiom
Igepal CO-660
Cheel ox BF-13
Sodi um Xylene Sul fonate
Water
Procedure
1 . Dissolve sodium xy
2. Add Igepal CO-660.
Physical Properti-eg
pH (as i s ) : 10.3
DH (1%): 10.1
Economy Truck Wash
High-pressure Spray
(Formula TR-0024)
ene s u l fonate
Mix thoroughly.
n water.
Add Cheelox BF 13.
V i s c o s i t y : 10 cps
Speci f ic G r a v i t y : 1 .02
Truck Wash L i q u i d
Formula TR-0025
Igepal CO-630
Rhodapex CO-436
A1kami de DC-212/S
Cheelox BF-13
Ethylene Glycol Monobutyl Ether
Water
W t .%
3.0
1.o
1.5
84.5
Procedure
1. Dissolve s u r f a c t a n t s Igepal GO-630, Rhodapex CO-436 and
2. Add Cheelox BF-13. Mix w e l l .
3. Add ethylene g l y c o l monobutyl ether.
Physical PrQpe-rti89
pH (as i s ) : 9.9
pH (1%): 9.6
V i s c o s i t y : 10 cps
S p e c i f i c G r a v i t y : 1.01
A1 kami de DC-212/5 in water.
SOURCE: Rhone-Poulenc Surfactants & S p e c i a l t i e s : Formulas
W t .%
3.0
3.5
2.0
3.5
3.0
85.0
Gar and h k Wash Compounds 167
Water, D . I . *
Caustic Soda, 50%
Witco 1298SA
Witcolate SE-5
Petro BAF L i q u i d
W i tcami de 128T
Formal i n
Sodium Chloride
Foamy Brush Car Wash. L i q u i d
% by Weight
79.75
1.40
5.00
7.00
3.00
3.00
0.10
0.75
Blending Procedure:
used t o adjust v i s c o s i t y o f t h e product.
Typical Propert ies:
Blend ingredients i n t h e order l i s t e d . Sodium Chloride i s
S p e c i f i c Gravity: 1.015
Wt./Gal. l b s . : 8.46
pH, as i s : 9.8
Viscosity, cps: 410
D i l u t i o n Ratio a t Wand = 1:40
* I f unsoftened t a p water i s used, add 0.25% l i q u i d EDTA,
40% t o counteract hardness.
Formula 621
1:2 D i l u t a b l e Car Wash
Water
Sodium Hydroxide, 50%
Witconate SXS (40%)
Witco 12988
W i tcami de 128T
W i tcami de CDA
Blend4 ng Procedure:
Typi c a l Properties:
Blend ingredients i n t h e order l i s t e d .
Solids: 54.0%
pH. as i s : 8.5
Viscosity, as i s , cps: 580
Viscosity, 1:2. cps: 440
Formula 622
SOURCE: Witco Corp.: Sugueated Formulations
% by Weight
33.71
5.96
14.90
25.88
16.76
2.79
I68 Advanced CleaningProduct Formulations
High O i l S p l i t t i n g Vehicle Wash-A
Components:
Water
Sodium M e t a s i l i c a t e Pentahydrate
TKPP
Sodi um Xylene Sul fonates 40%
Burco TME
% by Weiqht
71.5
10.0
2.5
6.0
10.0
Add i n t h e order l i s t e d . Blend u n t i l dissolved between each
a d d i t i o n .
High O i l S D l i t t i n g Vehicle Wash-B
Components:
Water
Sodium M e t a s i l i c a t e Pentahydrate
Burcosol ADS-40
Glycol Ether
Burco TME
Burcotrope 1250
% by Weiqht
73.5
10.0
5.0
5.0
10.0
As Required
Add i n t h e order l i s t e d . Blend u n t i l dissolved between each
a d d i t i o n .
SOURCE: B u r l i n g t o n Chemical Co., I n c . : Suggested Formulations
Car and Truck Wosh Cornpout& 169
L iauid Car Wash
Formula TR-0020
Rhodapon SB
Alcodet SK
Rhodasurf 25-9
Tetrapotassium pyrophosphate
Sodi um metasi 1i c a t e
Water
Perfume
Dye
Formula Formula
A B
WtT% wtT%
1 8 . 0 18.0
----8 . 0
--- 8 . 0
3.0 3.0
2.0 2.0
69.0 69.0
Q . S . Q . S .
Q . S . Q . S .
Procedure
i n water. Add Rhodapon SB. A g i t a t e u n t i l c l e a r . Add Alcodet SK
and Rhodasurf 25-9 and mix u n t i l uniform and c l e a r . Add perfume
and dye, as desired.
Physical ProDertiea
Dissolve tetrapotassium pyrophosphate and sodium m e t a s i l i c a t e
Appearance: Clear l i q u i d , dyed t o preference
pH: 12.0
S p e c i f i c Gravity: 1.03
V i s c o s i t y : t50 cps
Spray-On Car Wash Concentrate
"Grease and Grime" Remover
Formula TR-0021
Rhodacal A-246/L
Rhodacal 330
Rhodapon BOS
Alcodet SK
Water
Wt.%
5.0
20.0
3.3
5.0
66.7
Procedure:
1. Charge water t o a vessel equipped w i t h a g i t a t i o n .
2 . Add Rhodacal A-246/L and Rhodapon 00s t o ( 1 ) above. Mix u n t i l
3. Add Rhodacal 330 and Alcodet SK t o (2) above. Mix u n t i l
Phvsica1 Propertigp
Appearance: Viscous, gel -1 ike 1i q u id
pH. as i s : 9.0
S p e c i f i c Gravity: 1.02-1.04
V i s c o s i t y : t50 cps
uniform (5-10 minutes).
uniform (15-30 minutes).
SOURCE: Rhone-Poulenc Specialtiem a Surfactmtm: Formulas
I70 Advanced Cleaning Product Formulotions
L i q u i d Hiah Pressure Concentrate
Water, D.I.
Oowanol EB
Witconate SXS L i q u i d
Sodium Benzoate
Sodium M e t a s i l i c a t e
Tetrapotassium Pyrophosphate
Varion AM-KSF-40%
% by Weiaht
46.0
2.0
1 .o
1 .o
10.0
20.0
20.0
Blending Procedure:
between each a d d i t i o n .
Typical Properties:
V i s c o s i t y , cps: 15
Solids: 39.4%
pH: 13.4
Formula 605
Add ingredients i n order shown and dissolve completely
Truck Wash w/Vararide A-83
Water, D . I .
Sodium Tripolyphosphate
T r i sodi um Phosphate
Sodium M e t a s i l i c a t e
Varami de A-83
Butyl C e l l osol ve
% by Weight
81 .o
3.0
3.0
1 .o
9.0
3.0
Blending Procedure:
between each addition.
Typical Properties:
Viscosity, cps: 1 2
Solids: 16.0%
pH: 11.0
Formula 608
SOURCE: Witco Corp.: Suggested Formulations
Add ingredients i n order shown and dissolve completely
Car and Truck Wash Compounds 171
L i q u i d Truck Wash
Formula TR-0029
Water
Miranol FBS
Igepal CA-630
Dowanol EB (Dow Chemical )
Potassi um Hydroxide (45%)
T a l l O i l
Tetrapotassium Pyrophosphate
Sodium M e t a s i l i c a t e , Pentahydrate
Wt.%
73.6
6.0
3.0
2.0
4.0
3.4
4.0
4.0
Procedure
Premix t h e t a l l o i l and Dowanol EB. Add t h e water t o
t h e mixer. Add t h e sodium m e t a s i l i c a t e , t h e potassium hydroxide
and t h e TKPP. Add t h e Miranol FBS and Igepal CA-630. Add t h e
t a l l oil/Dowanol EB premix. Mix u n t i l uniform.
Physical ProDerties
Appearance: Clear, amber l i q u i d
pH, as i s : 12.7
S p e c i f i c G r a v i t y : 1.08
V i s c o s i t y : 6 0 cps
L i q u i d Truck Wash
Formula TR-0030
Water
Miranol FBS
Rhodafac RA-600
Igepal CA-720
Cheel ox BF-13
Tetrapotassi um Pyrophosphate
Potassi um Hydroxide (45%)
Sodium M e t a s i l i c a t e Pentahydrate
Arcosolv PTB
Wt.%
63.0
4 . 0
2.0
2.0
17.5
1 .o
6.0
2.0
2.5
Phvsl c a l Prooerti es
Appearance: C1ear, ye11ow 1iqui d
pH, as i s : 12.9
S p e c i f i c Gravity: 1.10
V i s c o s i t y : <SO cps
SOURCE: Rhone-Poulenc Surfactants & Spec
Procedure
Add t h e ingredients i n t h e order l i s t e d and mix u n t i l uniform.
asa1t i8s: Formu
172 Advanced Cleaningproduct Formulations
M i l d Car Shampoo
A m i l d r i c h foaming car shampoo w i t h e x c e l l e n t detergency and
sheeting a c t i o n ,
I n a r e d ients: % ComDosit o n W/W
Sandobet SC 4.5
DDBSA, 60% 10.8
Sandoxylate SX-424 3.6
Triethanolamine 0 . 8
Dye, Fragrance, Preservative, Water Q.S.
Procedure:
Charge water t o mixing vessel w i t h moderate a g i t a t i o n . Hold
out small p o r t i o n o f t h e water t o d i s s o l v e dye. Charge t h e r e -
maining components i n sequence, mixing a f t e r each a d d i t i o n .
Dissolve t h e dye w i t h a g i t a t i o n i n t h e water p r e v i o u s l y h e l d
out and add t o t h e product.
Properties:
Appearance: C1ear 1iqui d
A p p l i c a t i o n : Use 1 t o 2 oz per 5 g a l l o n bucket
SOURCE: Sandoz Chemicals Corp. : Formulation HHA-01
pH: 7.0-8.0
Carspray CW Concentrate
% by Weight
Water, D . I . 80.0
Blending Procedure:
s o l u t i o n i s homogeneous.
Typical Properties:
S o l i d s : 11.6%
Formula 632
Carspray CW 20.0
Add Carspray t o water w h i l e mixing. Continue mixing u n t i l
Automotive "Wash 8 Wax"
% by Weiqht
Witcamine AL42-12 6.9
Isopropanol 1.o
G l a c i a l A c e t i c Acid 2.1
Water 65.0
Witcamide 5195 25.0
Blending Procedure:
Heat t h e m i x t u r e t o 70C and then add Witcamide 5195. Continue
mixing u n t i l s o l u t i o n i s c l e a r .
T h i s f o r m u l a t i o n leaves a water "beading" f i l m on t h e auto-
mobile f i n i s h ,
Formula 636
Mix a l l i n g r e d i e n t s except Witcamide 5195 i n t h e order l i s t e d .
SOURCE: Witco Corp.: Suggested Formulations
Car and Truck WaFhCompounds I73
Premium CarsDrav 500 Concentrate
Carspray 500
B u t y l C e l l osol ve
Mineral Seal O i l *
Water, D . I .
?6 by Weight
20.0
5.0
25.0
50.0
*Kermac 600 Solvent: Kerr McGee O i l Co.
D i a l a A O i 1: Shel 1 Chemical
Isopar V : Exxon Chemical
B1endi ng Procedure :
thoroughly. I n a separate vessel weigh i n t h e water. While
mixing t h e water, pour i n t h e blend. Mix u n t i l s o l u t i o n i s
homogeneous.
Use D i l u t i o n :
Combine Carspray, B u t y l Cellosolve and O i l i n vessel and mix
5 g a l l o n s Concentrate t o 50 g a l l o n s water.
Carspray 500: Beading Agent w i t h s i l i c o n e .
Comments:
Formula 687
Standard Carspray 500 Concentrate
Carspray 500
B u t y l Cel l o s o l v e
Mineral Seal O i l *
Water, D . I .
*Kermac 600 Solvent: Kerr McGee O i l Co
D i a l a A O i 1: Shel 1 Chemical
Isopar V: Exxon Chemical
% by Weipht
16.0
3.0
20.0
61 .O
81endi ng Procedure:
Combine Carspray, B u t y l Cellosolve and O i l i n vessel and
mix thoroughly. I n a separate vessel weigh i n t h e water. While
mixing t h e water, pour i n t h e blend. Mix u n t i l s o l u t i o n i s
homogeneous.
Use D i 1u t ion :
Comments:
5 g a l l o n s Concentrate t o 50 g a l l o n s water.
Carspray 500: Beading Agent i n s i l i c o n e
Formula 688
SOURCE: Witco Corp.: Suggested Formulations
174 Advanced Cleaning Product Formulations
Premium Carspray 700 Concentrate
Carspray 700
Mineral Seal O i l *
Water, D . I .
*Kermac 600 Solvent: Kerr McGee O i l Co.
D i a1a A O i 1: She11 Chemical
Isopar V: Exxon Chemical
%_by Wei qht
25.0
25.0
50.0
Blending Procedure:
heat t o l l O F w i t h thorough mixing. I n vessel #2, weigh i n t h e
water and mix u n t i l a v o r t e x i s formed. While mixing t h e water,
pour t h e blend i n t o t h e v o r t e x . Mix u n t i l s o l u t i o n i s homo-
geneous.
Use D i l u t i o n :
I n vessel #1, combine Carspray 700 and Mineral Seal O i l and
5 g a l l o n s Concentrate t o 50 g a l l o n s water.
Comments:
Carspray 700: Foaming beading agent
Formula 685
Standard Carspray 70-0 Concentrate
Carspray 700
Mineral Seal O i l *
Water, D . I .
*Kermac 600 Solvent: Kerr McGee O i l Co.
D i a l a A O i l : S h e l l Chemical
Isopar V: Exxon Chemical
% u Y A ! h t
16.0
16.0
68.0
Blending Procedure:
heat t o l l O F w i t h thorough mixing. I n vessel #2, weigh i n t h e
water and mix u n t i l a v o r t e x i s formed. While mixing t h e water,
pour t h e blend i n t o t h e v o r t e x . Mix u n t i l s o l u t i o n i s homog-
eneous.
Use D i l u t i o n :
I n vessel #1, combine Carspray 700 and Mineral Seal O i l and
5 g a l l o n s Concentrate t o 50 g a l l o n s water.
Comments:
Formula 686
SOURCE: Witco Corp.: Suggested Formulations
Carspray 700: Foaming beading agent
17. Whitewall Tire Cleaners
175
176 Advanced Cleaning Product Formulations
W h i t e Wal 1 T i r e Cleaner
I n g r e d i e n t s :
Sodium Metasi 1 i c a t e
Sodium T r i p o l y p h o s p h a t e
T e t r a p o t a s s i u m Pyrophosphate
Sodium L a u r y l E t h e r S u l f a t e
S o l i n (35%)
Sandopan B
Water (warm)
%by.Wt.
2.00
2.00
2.00
4.00
2.30
5.00
83.00
Procedure:
Charge t h e w a t e r t o a vessel w i t h good a g i t a t i o n . Charge t h e
f i r s t t h r e e components and m i x t i l l d i s s o l v e d . Charge t h e remain-
i n g p r o d u c t s and mix t i l l comp e t e l y d i s s o l v e d and f r e e o f g e l
p a r t i c l e s .
P h y s i c a l P r o p e r t i e s :
Appearance: C l e a r w a t e r whi
pH ( a s i s ) : >9.0
T o t a l S o l i d s : 11.0-12.0%
Use L e v e l s :
e t o l i g h t y e l l o w l i q u i d
For f i n a l use, d i l u t e between 4:l and B : l w i t h w a t e r
SOURCE: Sandoz Chemicals C o r p . : F o r m u l a t i o n HHA-03
Bug Remover C o n c e n t r a t e
T r i ethanolami ne (TEA)
B u t y l C e l l o s o l v e
I s o p r o p a n o l
R e w o t e r i c AM 8-15
% by W e i . a
17.14
42.86
17.14
22.86
81ending Procedure:
B l e n d t h e components i n t h e o r d e r shown. Mix u n t i l homogeneous
D i l u t i o n Rates:
1 : 2 E x t r a Heavy Duty
1 : 4 Heavy Duty
1 : 16 Medi um Duty
1 :32 L i g h t Duty
D i 1 u t i on I n s t r u c t i o n s :
m i x i n g u n t i l homogeneous.
Comments:
Add Bug Remover C o n c e n t r a t e t o water w h i l e m
Appearance @ 77F: C r y s t a l c l e a r , y e l l o w l i q u
SOURCE: W i t c o Corp.: Formula 677
Xing; c o n t i n u e
d
Whitewall Ere Cleaners 177
Whitewall T i r e Cleaner Concentrate
Formula TR-0031
Water
Miranol FBS
Sodium M e t a s i l i c a t e , Pentahydrate
Potassium Hydroxide (45%)
Butoxyethanol
Procedure
Physical ProDerties
Add i n g r e d i e n t s i n order l i s t e d . Mix u n t i l uniform.
Appearance: Clear, yellow l i q u i d
pH, as i s : 12.7
V i s c o s i t y : <50 cps
S p e c i f i c G r a v i t y : 1.16
W h i tewal 1 T i r e C1eaner L iauid
Formula TR-0027
Igepal CA-630
Rhodafac RA-600
M-Pyrol N-Methyl-2-Pyrrolidone (ISP)
Sodium M e t a s i l i c a t e , Anhydrous
Sodi um Tripolyphosphate
Potassi um Hydroxide
Water
Wt.%
48.0
22.0
25.0
3.0
2.0
Wt.%
2.0
6.0
2.0
3.0
5.0
1 . 5
8 0 . 5
ProceduPQ
1. Dissolve sodium m e t a s i l i c a t e , anhydrous, sodium t r i p o l y -
phosphate and potassium hydroxide i n t o water.
2. Add Igepal CA-630, Rhodafac RA-BOO, and M-Pyrol separately,
mixing w e l l a f t e r each a d d i t i o n .
Physical ProDertiea
pH (as i s ) : 13.3
pH (1%): 10.7
V i s c o s i t y : 10 cps
S p e c i f i c Gravity: 1.03
SOURCE; Rhone-Poulenc Surfactants a S p e c i a l t i e s : Formulas
18. Miscellaneous
178
Miscellaneous 179
Automobi 1e W i ndshie ld Cleaners
Inaredients:
Aerosol MA-80 Surfactant
Surfonic N-95
Isopropanol
Water
% by Weiaht
3.5
0.5
51 .o
45.0
The above i s d i l u t e d 5 oz. t o 1 g a l l o n o f water f o r use. I n
wintertime, t h e recommended d i l u t i o n i s 10 oz. per gallon.
Freezi ng i s prevented by t h e isopropanol . Thi s formulation leaves
a small amount o f residue on t h e unwiped p o r t i o n o f t h e wind-
s h i e l d upon drying. There are several ways o f preventing these
v i s i b le residues.
1 . Use a mixture o f v o l a t i l e solvents w i t h o r without
surfactants. A suggested formulation i s :
Inaredients:
2-Ethyl Hexanol
Aerosol OT-75% Surfactant
Isopropanol
Water
% by Weiaht
5.0
1.o
47.0
47.0
The above i s d i l u t e d 5-10 0 2 . per g a l l o n o f water, and w i l l
n o t freeze a t t h e higher l e v e l o f concentration.
2. Using surfactants, but i n c l u d i n g small amounts o f non-
v o l a t i l e solvents which g i v e a transparent f i l m on t h e glass
w i t h t h e s u r f a c t a n t . Non-volatile solvents having approximately
t h e same r e f r a c t i v e index o f glass should be selected. A
suggested formulation i s :
Innredients:
Aerosol MA-80 Surfactant
Aerosol OT-75% Surfactant
Diethylene Glycol
Isopropanol
n-Butyl-p-Hydroxy Benzoate
Methyl-p-Hydroxy Benzoate
Water
% by Weight
2.5
3.3
4.4
40.0
0.1
0.1
49.78
The above concentrate i s used a t 5 02. per g a l l o n (10 02'. per
g a l l o n i n w i n t e r ) . The b a c t e r i c i d e s a r e present t o keep t h e
window cleaning s o l u t i o n f r e e o f slime and t u r b i d i t y due t o
b a c t e r i a .
Inaredients: % by Weight
Aerosol OT-75% Surfactant 3.5
D i b u t y l phthalate 0.5-2.0
Isopropanol 40.0
Water 46-48
The above s o l u t i o n i s d i l u t e d 5-10 02. per g a l l o n o f water
and w i l l not freeze a t t h e higher l e v e l o f concentration.
SOURCE: Cytec I n d u s t r i e s Inc.: Suggested Formulations
180 Advanced CleaningProduct Formulations
General PurDose L i q u i d Boat Polish-(1 1
M a t e r i a l s :
Part A:
SF 96 (350)
V i scasi 1 (10,000)
O l e i c a c i d
Isopar M
Hoechst Wax E
Part B:
Water
Morphol ine
Carbopol 934
Part C:
Isopar M
SF 1706
Part D:
Snow Floss
Super Floss
General Purpose L i q u i d Boat Polish-(2)
Materi a1s :
Part A:
SF 96 (350)
V i scasi 1 ( 10,000)
O l e i c a c i d
Isopar M
Hoechst Wax E
Part B:
Water
Morphol ine
Carbopol 934
Part C :
Isopar M
SF 1706
Part D:
Kaopol it e 1 1 68
Part/Wt (%Z
3.50
1 .oo
1.50
10.00
1.50
65.65
1.60
0.25
3.00
2.00
7.50
2.50
Part/Wt(%)
3.50
1 .oo
1.50
10.00
1.50
63.65
1.60
0.25
3.00
2.00
12.00
Procedure:
1.) Heat Part A t o 90-95C. (2.) Heat Part B t o 60-85C.
3.) Add Part A t o Part B w i t h good mixing.
4 . ) When homogeneous, cool t o 60-65C and add Part C w i t h
continued high shear mixing.
5.) Add Part D w i t h good mixing.
6.) When uniform, cool and package i n s u i t a b l e containers
SOURCE: GE S i l i c o n e s : Formula BP 2000
Miscellaneous 181
L i a u i d Aluminum Engine Block Cleaner
Formula TR-0032
Water
Sodium Metasi 1i c a t e , Anh
Miranol FBS
M i ranol JEM Conc.
Alcodet HSC-1000
D-Limonene
W t .%
82.5
4.5
5.0
2.0
4.0
2.0
Procedure
Completely d i s s o l v e t h e sodium m e t a s i l i c a t e i n t h e water
Add t h e remaining components, w i t h a g i t a t i o n , i n t h e order
l i s t e d . Premix t h e 0-Limonene w i t h t h e Alcodet HSC-1000 and
add together.
T y p i c a l PropertJ es
Appearance: Clear, yellow t o amber l i q u i d
pH, Conc.: 12.75
pH, 10%: 12.15
S p e c i f i c G r a v i t y : 1.04
V i s c o s i t y : t50 cps
Foami ng Engi ne C1eaner
Formula TR-0019
Alcodet 260
Rhodacal 330
Water
Isopar "K" (Exxon)
W t .%
2.0
8.0
80.0
10.0
Procedure
1. Add Alcodet 260 and Rhodacal 330 t o water a t ambient temp-
e r a t u r e , s t i r u n t i l dissolved (10-15 minutes).
2. Add Isopar K a t ambient temperature. S t i r u n t i l dissolved
(30 minutes) .
Physi cal Proeerties
Appearance: Clear l i q u i d
pH, as i s : 7 . 5
Speci f ic G r a v i t y : 0.99
V i s c o s i t y : 10 cps
SOURCE: Rhone-Poulenc Surfactants & S p e c i a l t i e s : Formulas
Section 111
Trademarked Raw Materials
182
TrademarkedRaw Materials 183
RAW MATERIALS
AC-325 Nonionic
ACL-59
Acrysol ICS-1
Aerosol A-102
Aerosol A-1 03
Aerosol C-61
Aerosol GPG
Aerosol MA-80
Aerosol 0s
Aerosol OT
Aerosol OT-B
Aerosol OT-75%
Aerosol OT-100%
Aerosol 22
AF 9020
Alcodet HSC-1000
Alcodet SK
Alcodet 260
A1kami de DC-212
A1kamide DC-212/M
A1kamide DC-212/S
Aluminum Oxide FPTO
Ammonyx LO
CHEMICAL DESCRIPTION SOURCE
Polymer A l l i e d
Chlorinated isocyanurate Monsanto
Water-soluble a c r y l i c r e s i n Rohm&
Mono-ester sul fosucci nate Cytec
Mono-ester sul fosucci nate Cytec
s u r f a c t a n t
s u r f a c t a n t
A1 k y lami ne-guani d
Sodium d i o c t y l su
Sodium dihexyl su
A1k y l naphthalane
Sodium d i o c t y l su
ne ethoxylate Cytec
fosucci nate Cytec
fosuccinate Cytec
oxide sulfonate Cytec
fosucci nate Cytec
Sodium d i o c t y l sulfosuccinate Cytec
Sodi um d i o c t y l s u l fosucci nate( 75%) Cytec
Sodi um d i o c t y l s u l fosucci nate Cytec
Sul fosucci namate Cytec
T e r t i a r y t h i o e t h e r surfactant Rhone-
Cleaning s u r f a c t a n t Rhone-
Cleaning s u r f a c t a n t Rhone-
F a t t y a1kanolamide ISP
F a t t y a1kanolamide I S P
F a t t y a1kanolanide ISP
Laurami ne oxide Stepan
184 Advanced Cleaning Product Formulations
RAW MATERIALS
Ampholy t JB130
Antarox BL-225
Antarox BL-240
Antarox BL-330
Aquamoll i n BC Powder
Arcosolv PTB
Avanel N-1525-90
Avanel S-70/5-74/
S-l50/590
BASF Surfactants
B r i t e s i l H24
Burcene 100
Burco ADS-40
Burco ADS-100
Burco BSGH-270
Burco BSGH-Crystals
Burco BSGH-400
Burco EHS
Burco FAE
Burco LAA-38
Burco LAF-6
Burco LAF-125
Burco NPS-225
CHEMICAL DESCRIPTION
Coconut f a t t y a c i d amidopropyl
b e t a i ne
A l i p h a t i c polyether nonionic
onic
oni c
A l i p h a t i c polyether non
A l i p h a t i c polyether non
Sol vent
Surfactant
Sodi urn 1inear a1k y l pol yether
sulfonate s u r f a c t a n t
Pluronic, Plurafac, I n d u s t r o l
Hydrous sodi um s i 1icate
Surfactant
Surfactant
Surfactant
Surfactant
Surfactant
Surfactant
P r o p r i e t a r y t e x t i l e aux
Surfactant
Surfactant
P r o p r i e t a r y t e x t i l e aux
Surfactant
l i a r y
1iary
SOURCE
Huls
Rhone-
Rhone-
Rhone-
Arco
PPG
PPG
BASF
PQ
B u r l
B u r l
B u r l
ng-
ng-
ng-
Bur1ing-
B u r l ing-
B u r l ing-
Burl ing-
B u r l ing-
B u r l ing-
B u r l ing-
B u r l ing-
B u r l ing-
TrademarkedRaw Materials 185
RAW MATERIALS
Burco NPS 50%
Burcosolv TM
Burcosperse AP
Burcosperse LP
Burcotase SL-80
Burco TM€
Burcotrope 1250
Burcowet TM-LF
B u t y l Carbit07
Butyl Cellosolve
Butyl Propasol
Calamide C
Calamide 0
Calfax DB-45
Cal foam €A-603
Cal foam ES-303
Cal foam SLS-30
C a l i b r i t e SL
Cal irnul se PRS
Caloxylate N-9
Calsoft F-90
Calsoft L-40
CHEMICAL DESCRIPTION
Proprietary t e x t i l e a u x i l i a r y
Water soluble solvent mixture
L i q u i d detergent polymer
Proprietary detergent polymer
Proprietary detergent enzyme
Nonionic t h i o e t h e r surfactant
I n d u s t r
I n d u s t r
I n d u s t r
Surfactant
a7 solvent
a1 solvent
a1 solvent
Foam s t a b i 1iz e r 8 emu1s i f ie r
Super amide
D i sul fonate
L i q u i d detergent
L i q u i d detergent
Sodium l a u r y l s u l f a t e 30%
Emu1s i f ie r
Sodi um 1inear a1k y lbenzene
Linear sodium dodecylbenzene
sulfonate 90%
sul fonate
SOURCE
Burling-
Burl ing-
Burl ing-
Burl ing-
Burl ing-
Burling-
Burl ing-
Burl ing-
UnCarb
UnCarb
UnCarb
P i 1o t
P i l o t
P i l o t
P i l o t
P i l o t
P i l o t
P i l o t
P i l o t
P i 1o t
P i l o t
186 Advanced Cleaning Product Formulationr
RAW MATERIALS CHEMICAL DESCRIPTION
C a l s o f t L-60 Sodium alkylbenzene sulfonate(60%)
Cal s o f t LAS-99 Dodecylbenzene s u l f o n i c acid(60%)
Calsuds A L i q u i d detergent blend
Calsuds CD-6 Coconut o i 1 amide w/sul fonate
Calsuds 81 Concentrated detergent blend
Carbopol 934 A c r y l i c a c i d polymer.MW:3,000,000
Cardis 36 Wax Oxidized m i c r o c r y s t a l l i n e wax
Carspray 500 Beadi ng agent w i t h s i 1icone
Carspray 700 Foaming beading agent
Cellobond HEC 1OOOOOA
Cheel ox BF-13
Cheelox NTA-Na3
Clearon CDB Sodi um d i c h l o r o i socyanurate
Concord Co-Wax Emulsion, 12%
Concord Wax #1600
Condensate TL
Cyanamer A-100L Polyacrylamide
Dequest 20605
Dequest 2066
Desonic 9N
D i a l a A O i l
Dionic OC
Organophosphorous product
Organophosphorous product
Nonionic s u r f a c t a n t
Mineral seal o i l
F a t t y a c i d methanolamide
p o l y g l y c o l ether
SOURCE
P i l o t
P i l o t
P i l o t
P i l o t
P i l o t
Goodri ch
P e t r o l -
W i t c o
W i t c o
FMC
Concord
Concord
Concord
Cyt ec
Monsanto
Monsanto
DeSoto
She11
n u i s
Trademarked Raw Materials 187
RAW MATERIALS
Dowanol D
Dowanol DE
Dowanol DPM
Dowanol EB
Dowanol PnB
Dow Corning EP-1-14
Dowfax 2A-1
Dowicide 32
Durcal 40
Durer Resin 15546
CHEMICAL DESCRIPTION
Glycol ether
Glycol ether
Dipropylene g l y c o l methyl ether
Ethylene g l y c o l n-butyl ether
Glycol ether
Anionic s u r f a c t a n t
Antimicrobial agent
Cal c i um carbonate
E Sodium s i l i c a t e 40 Be'
E-43 Noni oni c
Emcol NA-30 Surface a c t i v e agent
Emcol 4500 Surface a c t i v e agent
Emersol 213 F a t t y a c i d
Emphos PS-220
Emu1s i f i e r Four-HF D i a1k y l quaternary
E m u l s i f i e r 827
Emulsion C-340
F7uorad FC- 129 F7uorochemica7 surfactant
SOURCE
Dow
Dow
Dow
Dow
Dow
DowCorn
Dow
Dow
PQ
W i t c o
W i t c o
Henkel
W i t c o
Tomah
Tomah
Tomah
3M
I88 Advanced Cleaning product Formulations
RAW MATERIALS CHEMICAL DESCRIPTION
Gantrez AN-149 V i n y l ether polymer
Genagen LAB
Genamin 5-250
Genaminox MY
Genapol OA-80
Genapol UD-030
Genapol UD-050
Genapol UD-080
Genapol ZRO L i q u i d
Genapol 2908
General E l e c t r i c SF96-100 S i 1icone
Genopur ASA
Giv-Gard DXN
GP-10-1.000 c s t k Dimethyl s i l i c o n e f
GP-10-12,500 c s t k Dimethyl s i l i c o n e f
GP-121 S i l i c o n e p o l i s h add
GP-7104 S i l i c o n e f l u i d
u i d
u i d
t i v e
SOURCE
ISP
Hoechst
Hoechst
Hoechst
Hoechst
Hoechst
Hoechst
Hoechst
Hoechst
Hoechst
GESi 1i-
Hoechst
Genesee
Genesee
Genesee
Genesee
Harco 20% Soap
Hoe S 3924
Hoechst Wax A3 CS
Hoechst Wax E
Hoechst Wax F
Hoechst Wax OM
Hoechst
Hoechst
Ester t y p e wax. Drop point:175F Hoechst
Hoechst
Hoechst
nademarked Raw Materials 189
CHEMICAL DESCRIPTIONRAW MATERIALS
Hoechst Wax OP
Hoechst Wax S
Hostapur SAS 60
Hypofresh Perfume
Igepal CA-630 A l k y l ethoxylate nonionic
Igepal CA-720 A1k y l phenol ethoxyl a t e nonioni c
Igepal C0-630/C0-660/ Alkylphenol ethoxylate
CO-710
Igepal CO-977
Isopar E/K/L/M/V
Lanoquat 50
L i poxol
Lipoxol 6000 & 12000
Lonzabac 12.30
L y t r o n 295 Latex
Kaopolite SF/1152/
Kathon CG
Kelzan
Kermac 600
K o r t h i x Thixotropic
1168
Agent
Water soluble s u r f a c t a n t (70%)
Isoparaff in i c s o l vent
Quaternary product
Polystyrene
Anhydrous a
emu1s i on
uminum s i 1icate
Fungic i de (Bio c i de)
Xanthan gum
Mineral seal o i l
Refined white bentonite
SOURCE
Hoechst
Hoechst
Hoechst
I S P
ISP
ISP
ISP
Exxon
Henkel
Hul s
Hul s
Lonza
Morton
Kaopol-
Rohm&
Kelco
Kerr-Mc
Kaopol-
190 Advanced Cleaning Product Formulations
RAW MATERIALS
Mackadet 40K
Mackam JS
Mackam MEJ
Mackam 2CSF
Mackam 2CYSF
Mackam 35
Mackamide CD
Mackami ne C-10
Mackamine LO
Mackazol ine 0
Mackstat DM
Macol 48
Macol LF-120
Macol TD-3
Macol TD-12
Maphos 60-A
Marl ami ds
Marlazi ns
Marl in a t s
Marl ip a l s
Marlons
Marlophors
CHEMICAL DESCRIPTION
Potassium coconut soap
Low foam s u r f a c t a n t
Amphoteric w e t t i n g agent
Surfactant
Low foaming s u r f a c t a n t
Cocamidopropyl b e t a i ne
Cocamide DEA
Amine oxide s u r f a c t a n t
Amine oxide s u r f a c t a n t
01e y l hydroxyethyl im i dazol ine
DMDM hydantoin
Block p o l y o l
Rinse a i d . MW: 1,000
Nonionic s u r f a c t a n t . HLB: 8.0
Nonionic s u r f a c t a n t . HLB: 14.1
Phosphate ester
F a t t y a c i d a1kanol ami des
F a t t y amine p o l y g l y c o l ethers
F a t t y alcohol ether sulphates
F a t t y alcohol p o l y g l y c o l e t h e r s
A1kylbenzenesulphonates, sodium
s a l t s
P a r t i a l phosphate e s t e r s
SOURCE
M c In t y r e
McInt y r e
M c Int y r e
McIn t y r e
McIntyr e
McInt y r e
McInt y r e
McIn t y r e
McInt y r e
McInt y r e
McIntyre
PPG
PPG
PPG
PPG
PPG
Hul s
Hul s
Hul s
Hul s
Hul s
Huls
TrademarkedRmu Materials 191
RAW MATERIALS CHEMICAL DESCRIPTION
Marlosoft IQ 90 Quaternary im i dazol ines
Mar1owets Emu1s i f iers
Mar1ox I s
Mazamide 80
Mazawet 36
F a t t y a1coho1 a1k y lene oxide
a d d i t i o n products
Speci a1t y a1kanolamide
Surfactant
Mazclean EP
Mazon 98 Proprietary surfactant
Medialan LD
Methyl C a r b i t o l Solvent
Metso Pentabead 20 Sodium metasilicate, pentahydrate
Miranol CS Conc. Cocoamphopropylsulfonate
Miranol FBS Surfactant
M i ranol JEM Conc. Mixed C8 amphocarboxylate
amphoteric surfactant
amphoteric
M i r a t a i n e TM D i hydroxyethyl t a l l ow g l y c i nate
amphoteric surfactant
ML-870 Latex A c r y l i c polymer emulsion
Montan Wax "S'I
Mor-Glo 2 Latex Floor p o l i s h l a t e x (38%)
Morton Conrez 510 Polymer emu1s i on
M- Py1-01 N-Methyl-2-Pyrrolidone
SOURCE
Huls
Huls
Huls
PPG
PPG
PPG
PPG
UnCarb
PQ
M i ranol
M i ranol
M i ranol
M i ranol
Morton
Stroh-
Morton
Morton
I S P
192 Advanced Cleaning Product Formulotions
RAW MATERIALS
Neodol 25-3 Ethoxy
Neodol 25-3s
Neodol 25-7 Ethoxy
Neodol 91-8 Ethoxy
Ozokeri t e 170
PEG-10 Carnauba
Permulsin SP
Petro BAF L i q u i d
B e t r o BAF Powder
Petro LBA/ULF/22
Petro SXS-40
Prapagen WK
P r i f a c 7976
Proxel GXL
CHEMICAL DESCRIPTION
a t e Linear primary alcohol
Ethoxysulfate. Sodium c a t i o n
a t e Alcohol ethoxylate. MW: 519
a t e Lineal primary a l c o h o l . MW: 529
Pol ycarboxyl a t e
Anionic s u r f a c t a n t & dispersant
Anionic s u r f a c t a n t & dispersant
Anionic s u r f a c t a n t & dispersant
Sodium xylene s u l f o n a t e 40%
F a t t y a c i d
Chemical b io c i de
Refined Concord Wax #407
Rewoteric AM B-15
Rewoteric AM KSF-40
Rewoteric AM V
Rhodacal A-246/L
Rhodacal DS-10
Rhodacal DSB
Surfactant
SOURCE
Shel 1
Shel 1
Shel 1
Shel 1
Koster
Koster
DeSoto
DeSoto
DeSoto
DeSoto
Unichema
I C I
Concord
w i t C O
w i t c o
w i t c o
Rhone-
Rhone-
Rhone-
TrademarkedRcmt Materials 193
RAW MATERIALS
Rhodacal I PAM
Rhodacal 330
Rhodafac LO-529
Rhodafac RA-600
Rhodafac RE-610
Rhodapex GO-436
Rhodapex ES-2
Rhodapax MA-460
Rhodapex NA-61
Rhodopol 23
Rhodapon BOS
Rhodapon S0
Rhodapon U0
Rhodasurf 0C-840
Rhodasurf 25-7
Rhodasurf 25-9
Rhodasurf 91-6
Ross Micro Wax 1133/15W
Ross Ozokerite Wax 77Y
CHEMICAL DESCRIPTION
Phosphate ester nonioni c
PhosDhate ester anionic
SOURCE
Rhone-
Rhone-
Rhone-
Rhone-
Rhone-
Rhone-
Rhone-
Rhone-
Rhone-
Rhone-
Rhone-
Rhone-
Rhone-
Ethoxylated t r i d e c y l alcohol Rhone-
Rhone-
Rhone-
Rhone-
Ross
Ross
SAG 1010 S i l i c o n e a n t i foam UnGarb
Sequi on 1ONa2 Phosphonate HEDP
SF96(100)/SF96(350)/ Polydimethyl s i l i c o n e f l u i d GESi 1
Shellsol T I s o p a r a f fin i c solvent She11
SM 2109 GESi 1
SF96(1OOO)/SF 1705/SF 1706
194 Advanced Cleaning Product Formulations
RAW MATERIALS
SM 2133/SM 2135
Snow Floss S i l i c a
Sokalan CP 5
Sokalan HP 22
Sokalan HP 50
Sokalan PA 40
Solvent BG
Solvent
Span 80
SR 107
S t a r
Stepano
GX 5
DEA (35%)
Super Floss
Surfonic N-95
SWS 211 S i l i c o n e
Syntran 6520
Technocell 90 DU
Texstim 8741
Thermphos NW
T i nopal CBS-X
CHEMICAL DESCRIPTION
Processed diatomaceous s i l i c a
Polycarboxylate
P o l y v i n y lp y r r o l idone
Polycarboxylate
Surfactant
Sodium s i l i c a t e 42 Be’
D i ethanol ami ne 1a u r y l s u l f a t e
Mineral f i l l e r
Nonionic s u r f a c t a n t . HLB: 12.9
A n t i foam
Acryl ic emu1s i on
Nonionic s u r f a c t a n t
F1uorescent
Tomah A l k a l i Surfactant: Amphoter
Tomah AO-14-2 Ether amine
Tomah A0-728 Special Amine oxide
whitening agent
c (35% A c t i v e )
oxide s u r f a c t a n t
s u r f a c t a n t
SOURCE
GESi 1
Manvi 11e
I C I
PQ
Step n
Manvi 11e
Texaco
Wac ker
I n t e r -
Tomah
C i ba-
Tomah
Tomah
Tomah
TrademarkmiRaw Materials 195
RAW MATERIALS CHEMICAL DESCRIPTION
Tomah E m u l s i f i e r Four D i a l k y l quaternary s u r f a c t a n t
Tomah Q-17-2
Triethanolamine R
T r i t o n CF-10 A l k y l a r y l polyether nonionic
Tween 81 Surfactant
Tylose CBR 10000
Ucon
Ucon
Union
Union
1 Propel 1ant
2 Propel l a n t
Carbide L-45, 100 cstks. S i l i c o n e
Carbide L-45, 30,000 cstks. S i l i c o n e
Union Carbide L-46
Union Carbide LE-461
Union Carbide LE-462
Varami de A-83
Varamide ML-1
Varion AM-KSF-40%
Varonic K205/LI-48/
LI-67
Varox 365
Varox 1770
Varsol 81 Varsol No.2
Veegum Pro
S i 1icone
S i 1icone
S i 1icone
Detergent a1kanolamide
Detergent a1kanolamide
Surfactant
Nonionic w e t t i n g agent
Wetting agent,degreaser,detergent
Amine oxide
Mineral spi r it s
Complex c o l 1o i dal magnesi urn
aluminum s i l i c a t e
SOURCE
Tonah
Tomah
UnCarb
I C I
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
W i t c o
W i t c o
W i t c o
W i t c o
W i t c o
W i t c o
Exxon
Vander-
1% Advanced Cleaning Product Formulations
RAW MATERIALS CHEMICAL DESCRIPTION SOURCE
Versene 100/220 S o l u t i o n o f tetrasodium s a l t o f Dow
EDTA
Vestinol C Huls
Vestowax AW 1060 Wax emulsion, 15% basis Hul s
V i s c a s i l l O , O O O / S i l i c o n e f l u i d
12,000/30,000
GESi 1
Vol c l ay NF-BC Western b e n t o n i t e AmColl
Wessalith P Z e o l i t h A
W i tcami de CDA/ A1kanolami de s u r f a c t a n t Witco
5-771 /128T/511/5195
Witco 1298 S o f t Acid W i t c o
W i t c o l a t e A Sodium l a u r y l s u l f a t e . Anionic W i t c o
W i t c o l a t e AE-3/ S u l f a t e d s u r f a c t a n t s
ES-3/LES-60A/S-1285C/SE-5/WAC-LA/2310/7031
W i tconate AOS/ Sul fonate s u r f a c t a n t
SXS/3ODS/45LX
Witconate 1260 S l u r r y C-12 LAS (60%)
Witconol 14 Noni oni c
Z e o l i t h A
#3 Carnauba
668 P o l i s h i n g Powder
678 Pol is h i ng Powder
787 P o l i s h i n g Alumina P-10 F e i n s t
W i t c o
W i t c o
W i t c o
W i t c o
Koster
Whi ttCD
Whi t t C D
Whi t t C D
Section IV
Suppliers' Addresses
197
198 Advanced Cleaning Product Formulations
A1 1ied-Si gnal I n c .
P.O. Box 2332R
Morristown, NJ 07962
(201)-455-2000/(800)-526-0717
American C o l l o i d Co.
1500 W. Shure D r .
A r l i n g t o n Heights, I L 60004
(312)-392-4600
Arc0 Chemical Co.
3801 West Chester Pike
Newtown Square, PA 19073
(215)-359-2000
BASF Corp.
100 Cherry H i l l Rd.
Parsi ppany, NJ 07054
(201)-316-3000/(800)-526-1072
BP O i l I n c .
200 P u b l i c Square
Cleveland, OH 44114
(216)-586-6364/(800)-321-8598
B u r l ington Chemical Co. , I n c .
P.O. Box 111
615 Huffman M i l l Rd.
Burlington, NC 27215
(919)-584-0111/(800)-672-5888
Concord Chemical Co.
17th and Federal Sts.
Camden, NJ 08105
(609)-966-1526
Cytec I n d u s t r i e s , I n c .
F i v e Garret Mountain Plaza
West Paterson, NJ 07424
(908)-B62-6000/(800)-253-4078
DeSoto, I n c .
1700 S. M t . Prospect Rd.
Des Plaines, I L 60018
(312)-391-9000
Dow Chemical Co.
Midland, M I 48674
(800)-258-CHEM
Dow Corning Corp.
Box 0994
Midland, M I 48686
(517)-496-4000
Eastman Chemical Co.
P.O. Box 431
Kingsport, TN 37662
(615)-229-2318/(800)-327-8626
Exxon Chemica? Americas
13501 Katy Frwy
Houston, TX 77079
(713)-870-6000/(800)-231-6633
FMC Corp.
2000 Market S t .
Philadelphia, PA 19103
(215)-299-6000/(800)-526-3649
ISP/GAF Corp.
1361 Alps Road
Wayne, NJ 07470
Genesee Polymers Corp.
Fenton Rd.
P.O. Box 7047
F l i n t , M I 48507
(201)-628-3000/(800)-848-7659
(313 ) -238-4966
GE S i 1icones
260 Hudson River Rd.
Waterford, NY 12188
(518)-237-3330/(800)-255-8886
BF Goodrich Co.
9911 Brecksvi 11e Rd.
B r e c k s v i l l e , OH 44141
(216)-447-5000/(800)-332-1144
Haarman & Reimer Corp.
P.O. Box 175
70 Diamond Rd.
S p r i n g f i e l d , NJ 07081
(201)-467-5600/(800)-422-1559
Suppliers' Addresses 199
Henkel Corp.
5325 S. N i n t h Ave.
LaGrange, I L 60525
(708)-530-7300/(800)-543-7370
Hoechst-Celanese Corp.
26 Main St.
Chatham, NJ 07960
Huls America I n c .
Turner P1.
P i scataway, NJ 08855
Interpolymer Corp.
330 Pine St.
Canton, MA 02021
Kaopolite, I n c .
2444 M o r r i s Ave.
Union, NJ 07083
(201)-635-2600/(800)-526-4960
(201)-981-5000/(800)-526-0339
(617)-828-7120/(800)-444-1281
(908)-769-0609
Kelco Div.
Merck & Co., Inc.
8355 Aero D r i v e
San Diego, CA 92123
Kerr-McGee Chemical Corp.
Kerr-McGee C t r .
P.O. Box 25861
Oklahoma C i t y , OK 73125
(619)292-4900/(800)-535-2656
(405)-270-1313/(800)-654-3911
Koster Keunen I n c .
P.O. Box 447
90 Bourne Blvd.
S a y v i l l e , NY 11782
(516)-589-0456
Johns-Manville
Ken Caryl Ranch
Denver, CO 80217
McIntyre Group Ltd.
4851 S. St. Louis Ave.
Chicago, I L 60513
(312)-927-2401
Miranol I n c .
P.O. Box 436
Dayton, NJ 08810
Mona I n d u s t r i e s I n c .
76 E. 24 S t .
P.O. Box 425
Paterson, NJ 07544
Monsanto Chemical Co.
800 N. Lindbergh Blvd.
S t . Louis, MO 63167
Morton I n t e r n a t i o n a l Inc.
100 N. Riverside Plaza
Chicago, I L 60606
P e t r o l i t e Corp.
6910 E. 14 S t .
Tulsa, OK 74112
(918)-838-1601
(201)-329-3900
(201)-345-8220/(800)-553-6662
(314)-694-1000/(800)-325-4330
(312)-807-2000/(800)-367-3318
P i l o t Chemical Co.
11756 Burke S t .
Santa Fe Springs, CA 90670
(310)-723-0036
PPG Chemical s
3938 P o r e t t D r i v e
Gurnee, I L 60031
PQ Corp.
P.O. Box 840
Valley Forge, PA 19482
Rhone-Poulenc
CN 7500
Prospect P l a i n s Rd.
Cranbury, NJ 08512
Rohm & Haas Co.
Independence Mall West
Philadelphia, PA 19105
(708)-244-3410/(800)-323-0856
(215)-293-7200
(609)-860-4000/(800)-620-2613
(215)-592-3000
200 Advanced Cleaning Product Formulations
Ross Chemical I n c .
303 Dale O r .
F o u n t a i n I n n , SC 29644
(803)-862-4474
Sandoz Chemical s Corp.
4000 Monroe Rd.
C h a r l o t t e , NC 28205
(704)-331-7078/(800)-631-6077
S h e l l Chemical Co.
P . O . Box 2463
Houston, TX 77252
(713)-241-6161
Stepan Co.
22 W. Frontage Rd.
N o r t h f i e l d , I L 60093
(708)-446-7500/(800)-745-7837
Strohmeyer & Arpe Co., I n c .
89 M i 1b u r n Ave.
M i l b u r n , N J 07041
(201)-761-7600
Texaco Chemical Co.
3040 Post Oak B l v d .
Houston, TX 77056
(713)-961-3711
Tomah Products, I n c .
1012 T e r r a D r i v e
M i l t o n , W 1 53563
(608)-868-6811/(800)-441-0708
3M
3M Center
S t . Paul, MN 55144
(612)-733-5454
Unichema Chemicals, I p c .
4650 S. Racine Ave. /'
Chicago, I L 60609
(312)-376-9000/(800)-833-2864
Union Carbide Corp.
39 O l d Ridgebury R d .
Danbury, CT 06817
(203)-794-2000
RT V a n d e r b i l t Co., I n c .
P.O. Box 5150
30 W i n f i e l d S t .
N o r f o l k , CT 06856
Wacker S i l i c o n e s Corp.
3301 S u t t o n Rd.
Adrian, M I 49221
(203)-853-1400/(800)-243-6064
(517)-264-8500/(800)-246-0063
W h i t t a k e r , C l a r k & D a n i e l s , I n c .
1000 Coolidge S t .
S. P l a i n f i e l d , NJ 07080
(201)-561-6100
W i t c o Chemical Co.
5777 F r a n t z Rd.
P.O. Box 646
D u b l i n , OH 43017
(614)-765-6500/(800)-366-6500
Witco Corp.
520 Madison Ave.
New York, NY 10022
(212)-605-3941/(800)-634-4010
Other Noyes Arblications
ADVANCED CLEANING
PRODUCT FORMULATIONS
Volume 3
by
Ernest W. Flick
Thisbook(Volume3)presentsmorethan630
up-to-date advanced cleaning product form-
ulationsfor household,industrialandautomotive
applications.Itistheresultofinformationreceived
from numerous industrial companies and other
organizations. The data represent selections
madeatnocostto,norinfluencefrom,themakers
or distributors of these materials. Onlythe most
recent formulas have been included. All
formulationsarecompletelydifferent thanthose
contained in Volume 1 published in 1989 and
Volume 2publishedin 1994.
Formulationin the cleaning product industry
hasgraduallybeenundergoingsignificantchange
duringthe pastyears. Rawmaterialscosts have
risen and manufacturers have beenreluctant to
passalongtheseincreases. Environmentalcon-
siderationshavealsoplayedapart. Bychanging
formulationsto improvecost/performance char-
acteristics, manufacturers have been able to
controlcostsbutstillenhanceperformance.This
bookpresentsmanufacturers' suggestedformu-
lationswhich might meet new performancecri-
teria.
The formulationsinthis book are divided into
the following sections and chapters, with the
numberofformulationsindicatedin():
1.
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
Household and Industrial Cleaners and
Polishes
BathroomCleaners (14)
DairyFoodand GeneralIndustrial
Cleaners (52)
Degreasers(25)
Dishwashing Detergents (70)
General PurposeCleaners (29)
GlassCleanarsPolishes (18)
HardSurface Cleaners (59)
Laundry Products (100)
MetalCleaners and Polishes(52)
Oven, Grilland Hot PlateCleaners(11)
Polishes, Coatingsand Finishes(19)
RinseAids (5)
13.
14.
II.
15.
16.
17.
18.
Rug, Floor, Carpet, Upholstery Sham-
Miscellaneous (49)
TransportationCleanersandPolishes
AutoCleanersand Polishes (32)
CarandTruck WashCompounds (34)
Whitewall TireCleaners (11)
Miscellaneous
poos and Cleaners (41)
Eachformulaislocatedinthechapterwhichis
most applicable. The reader, seeking a formula
foraspecificenduse, shouldcheckeachchapter
which could possibly apply. In addition to the
above,therearetwo other sectionswhichwillbe
helpfultothereader.
111. A chemical trademark section where
each tradenamed raw material in-
cluded in the book is listed with a
chemicaldescriptionandthesupplier's
name. The specificationswhich each
raw material meets are included, if
applicable.
IV. Mainofficeaddressesof thesuppliers
of trademarkedrawmaterials.
Eachformulation inthebook liststhefollowing
information, as available, inthe manufacturets
ownwords:
0 Descriptionof enduseandmostoutstanding
properties.
0 The percentbyweight orvolumeof eachraw
materialincludedintheformula, roundedtoa
decimalfigure.
0 Keypropertii of the formula, which arethe
featuresthatthesourceconsidentobemore
outstanding than other formulations of the
sametype.
0 Theformulasource, which isthecompanyor
organization that supplied the formula. The
secondary source may be the originating
company and/or the primary source's
publicationtitle,orboth.Aformulanumberis
included,if applicable.
ISBN0-8155-1382-8 (1995) 6"x9' 280pages
Other Noyes Publications
ADVANCED CLEANING
PRODUCT FORMULATIONS
Volume 2
by
Ernest W. Flick
This book (volume 2) presents more than
800 up-to-date advanced cleaning product
formulations for household, industrial and
automotive applications. It is the result of
information received from numerous industrial
companies and other organizations. The data
represent selections made at no cost to, nor
influencefrom, themakersordistributorsofthese
materials. Only the most recent formulas have
been included. All formulations are completely
different than those contained in Volume 1,
which was publishedin 1989.
Formulation in the cleaning product in-
dustry has gradually been undergoing sig-
nificant change during the past years. Raw
materials costs have risen and manufacturers
have been reluctant to pass along these in-
creases. Environmental considerations have
also played a part. By changing formulations to
improve cost-performance characteristics.
manufacturers have been able to control costs
but still enhance performance. This book pre-
sents supplier's suggested formulations which
might meet new performance criteria.
Theformulationsinthisbookaredividedinto
the following sections and chapters, with the
number of formulations indicated in():
1.
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
Household and industrial Cleaners and
Polishes(733)
Bathroom Cleaners (29)
Dairyand Food IndustryCleaners (15)
Degreasers(20)
Dishwashing Detergents(67)
DetergentsDisinfectants(36)
General Purpose Cleaners(47)
Hard Surface Cleaners (60)
Laundry Products (217)
Metal Cleaners(87)
Polishes, Coatings and Sealers(32)
RinseAids (6)
ISBN0-8155-1346-1 (1994)
12.
13.
/I.
14.
15.
16.
17.
Rug,Carpet and Upholstery Shampoos
Miscellaneous Cleaners(96)
Transportation Cleanersand Polishes(76)
Auto Cleanersand Polishes (9)
Car and Truck Wash Compounds (38)
Whitewall Tire Cleaners(10)
Miscellaneous (19)
Inaddition to the above, there aretwoother
and Cleaners (21)
sections which will be helpful to the reader.
111. A chemical trademark section where
each tradenamed raw material
included in the book is listed with a
chemical description and the sup-
plier's name. The specifications which
each rawmaterial meets are included,
if applicable.
lV. Mainoffice addresses of the suppliers
of trademarked rawmaterials.
Each formulation in the book lists the
following information, as available:
1. Description of end use and most
outstanding properties.
2. The percent by weight or volume of
each raw material included in the
formula.
3. Key properties of the formula, which
are the features that the source
considerstobemoreoutstandingthan
other formulations of thesametype.
4. The formula source, which is the
company or organizationthat supplied
the formula. The secondary source
maybetheoriginatingcompanyand/or
the primary source's publication title.
or both.A formula number is included,
if applicable.
f64 6"x9" 394pages

Advanced cleaning product formulations Vol. 4

  • 2.
  • 3.
  • 4.
    ADVANCED CLEANING PRODUCT FORMULATIONS Volume 4 Ernest W.Flick NOYES PUBLICATIONS Westwood, New JOrsey, U.S.A.
  • 5.
    Copyright 0 19%by Ernest W. Flick No part of this book may be reproduced or utilized in any form or by any means. electronic or mechanical, including photocopying. recording or by any informa- tion storage and retrieval system. without permission in writing from the Publisher. Library of Congress Catalog Cud Number: 89-30274 Printed in the United States ISBN 0-8155-1396-8 Published in the United States of America by Noyes Publications 369 Fairview Avenue Weshvood, New Jersey 07675 10 9 8 7 6 5 4 3 2 1 Library of Congress Cataloging-in-Publication Data (Revised for vo1.4) Flick, Ernest W. Advanced cleaning produd formulations Includes bibliographid references and index. 1.Cleaning compounds. I. Title TP990.F56 1989 668'1 89-30274 ISBN 0-8155-1186-8 (v. 1) ISBN 0-8155-1346-1 (v. 2) ISBN 0-8155-1382-1 (v. 3) ISBN 0-8155-1396-8 (v. 4)
  • 6.
    To Ernie and Jeanne and AIIpand Barbara and Chris and Rachel V
  • 7.
  • 8.
    This book (Volume4) presents more than 435 up-to-date advanced cleaning product formulations for household, industrial and automotive applications. It is the result of information received fromnumerous industrial companies and other organizations. The data represent selections made at no cost to, nor influence from, the makers or distributors of these materials. Only the most recent formulas have been included. All formulations are completely different than those contained in Volumes 1, 2 and 3 published earlier. Formulation in the cleaning product industry has gradually been undergoing significant change during the past years. Raw materials costs have risen and manufacturers have been reluctant to pass along these increases. Environmental considerations have also played a part. By changing formulations to improve cost/performance characteristics, manufacturers have been able to control costs but still enhance performance. This book presents manufacturers' suggested formulations which might meet new performance criteria. The formulations in this book are divided into the following sections and chapters, with the number of formulations indicated in ( ): I. Household and Industrial Cleaners and Polishes 1. Bathroom Cleaners (26) 2. Dairy, Food and General Industrial Cleaners (15) 3. Degreasers (5) 4. Dishwashing Detergents (47) 5. General Purpose Cleaners (34) 6. Glass Cleaners/Polishes (25) 7. Hard Surface Cleaners (44) 8. Laundry Products (65) 9. Metal Cleaners and Polishes (22) 10. Oven, Grill and Hot Plate Cleaners (3) 11. Polishes, Coatings and Finishes (30) 12. Rinse Aids (4) 13. Rug, Floor, Carpet, Upholstery Shampoos and Cleaners (32) 14. Miscellaneous (32) vii Preface
  • 9.
    viii Preface 11. TransportationCleaners and Polishes 15. Auto Cleaners and Polishes (14) 16. Car and Truck Wash Compounds (27) 17. Whitewall Tire Cleaners (4) 18. Miscellaneous (8) Each formula is located in the chapter which is most applicable. The reader, seeking a formula for a specific end use, should check each chapter which could possibly apply. In addition to the above, there are two other sections which will be helpful to the reader. 111. Achemical trademark section where each tradenamed raw material included in the book is listed with a chemical description and the supplier's name. The specifications which each raw material meets are included, if applicable. IV. Main office addresses of the suppliers of trademarked raw materials. Each formulation in the book lists the following information, as available, in the manufacturer's own words: 0 Description of end use and most outstanding properties. The percent by weight or volume of each raw material included in the formula, rounded to a decimal figure. Key properties of the formula, which are the features that the source considers to be more outstanding than other formulations of the same type. The formula source, which is the company or organization that supplied the formula. The secondary source may be the originating company and/or the primary source's publication title, or both. A formula number is included, if applicable. 0 The table of contents is organized in such a way as to serve as a subject index. My fullest appreciation is expressed to the companies and organizations who supplied the original starting formulations included in this book. I also thank the suppliers of the raw materials included in these formulations, who furnished information describing their trademarked raw materials. Newburyport, Massachusetts August 1996 Ernest W. Flick
  • 10.
  • 11.
    NOTICE To the bestof our knowledge the information in this pub- lication is accurate; however, the Publisher does not assume any responsibility or liability for the accuracy or completeness of, or consequences arising from, such information. This book is intended for informational purposes only. Mention of trade names or commercial products doesnot constitute endorsement or recommendation for use by the Publisher. Final determ- ination of the suitability of any information or product for use contemplated by any user, and the manner of that use, is the sole responsibility of the user. We recommend that anyone in- tending to rely on any recommendation of materials or pro- cedures mentioned in this publication should satisfy himself as to such suitability, and that he can meet all applicable safety and health standards. X
  • 12.
    1. Contents and SubjectIndex SECl'ION I HOUSEHOLDAND INDU- CLEANERS AND POLISHES BATHROOM CLEANERS .............................. 2 Bathtub and Faucet Cleaner ............................ 3 Bathroom Cleaner ................................... 3 Toilet Bowl Cleaner ................................. 3 Tub and Tile Cleaner ................................ 3 Thick Toilet Bowl Cleaner ............................ 4 Foamable Acid Tile Cleaner ........................... 5 Liquid Toilet Bowl Cleaner ............................ 5 Solid Automatic Toilet Bowl Cleaner Formulation ........... 6 Acid Toilet Bowl Cleaner ............................. 6 Tub. Tile and Bathroom Cleaner ........................ 6 Tile. Porcelain and Bathroom Cleaner. Acid ................ 7 Hypochlorite Tub and Tile Cleaner and Mildew Stain Remover ....................................... 7 Soap Scum RemoverICleaner ........................... 7 Toilet Cleaner LiquidA ...................................... 8 Liquid B ...................................... 8 Clear Liquid Bowl Cleaner ............................ 4 Medium Viscosity-A ............................. 8 Medium Viscosity-B ............................. 8 Medium Viscosity-A ............................. 9 Medium Viscosity-B ............................. 9 Powder ....................................... 9 Powder-B ..................................... 9 Extruded-A ................................... 10 Extruded-B ................................... 10 Cast-A ...................................... 10 Cast-B ...................................... 10 Toilet Cleaning Block xi
  • 13.
    xii Contents andSubject Index 2. DAIRY. FOOD AND GENERAL INDUSTRIAL CLEANERS . . . 11 Acid Dilutable Concentrate ........................ 12 Low Cost Acid Dilutable Concentrate . . . . . . . . . . . . . . . . 12 Dairy Milkstone Remover Dairy Pipeline Cleaner-High Alkaline Low Foam Institutional Stainless Steel Cleaner ..................... 13 High Pressure Cleaner for Industrial Use . . . . . . . . . . . . . . . . . 14 Cleaner for Milking Equipment ........................ 14 Cleaner for Meat Plants ............................. 14 Meat Packaging Plant Cleaner Concentrate . . . . . . . . . . . . . . . . 15 Steam Cleaners Light Duty .................................... 16 Hypochlorite Cleaner .............................. 13 Medium Duty .................................. 16 Heavy Duty (for Oily Soils) ....................... 16 General Purpose ................................ 16 Light Duty for Soft Metals ........................ 16 Compound .................................... 16 3. DEGREASERS ...................................... 17 d-Limonene Microemulsion Cleanermegreaser . . . . . . . . . . . . . 18 Concentrated d-Limonene Biodegradable Degreaser . . . . . . . . . 18 Solvent Degreasing ................................. 19 4. DISHWASHING DETERGENTS ......................... 20 Clear Liquid Dishwash .............................. 21 Non-Chlorinated Machine Dishwashing Compound. Liquid . . . . 21 Clear. Colorless Manual Dish Wash ..................... 21 Powder for Automatic Dishwashing Machines . . . . . . . . . . . . . . 23 Dishwashing Detergent Medium Viscosity Dish Washing Agent ................................ 22 Basis Marlon A-A ........................... 24 Basis Marlon A-B ........................... 24 Basis Marlon AS3-A ......................... 24 Basis Marlon AS3-B ......................... 24 Basis Marlon PS-A .......................... 25 Basis Marlon PS-B .......................... 25 Basis Marlon Compounds-A ..................... 25 Basis Marlon Compounds-B .................... 25 Powdered Spray Mixing Process-A ...................... 26 Spray Mixing Process B ....................... 26 Phosphate-Free. Spray Mixing. Process A . . . . . . . . . . 26
  • 14.
    Contents and SubjectIndex xiii Phosphate.Free. Spray Mixing. Process B .......... 26 40% Solids-A .............................. 27 40% Solids-B .............................. 27 Hand Dishwashing Liquid ............................ 27 Dish Wash w/Amine Oxide/LABS/SLES ................. 28 Dish Wash w/Amine Oxide/LABS/ALES ................. 28 Dish Wash w/Amine Oxide/LABS ...................... 28 High-Performance Hand Dish Detergent ................. 29 Mild Liquid Hand Dish Detergent ...................... 29 Starting Formulations for Home Machine Dishwashing Detergents 8.7% Phosphorous(A) ............................ 30 8.7% Phosphorous(l3) ............................ 30 Nonphosphate ................................. 30 Pilot Formula #LDL-010-01 ...................... 31 Pilot Formula #LDL-013-01 ...................... 31 Pilot Formula #LDL-005-01 ...................... 31 Pilot Formula #LDL-O15-01 ...................... 31 Premium Hand Dishwash ......................... 32 Economy Hand Dishwash ......................... 32 Liquid Hand Dish Detergent .......................... 33 Mechanical Dishwashing Detergent. Chlorinated ............ 34 Mechanical Dishwashing Detergent. Liquid ............... 34 Non-DDBSA Dishwashing Liquid ...................... 35 Starting Formulations for Commercial Machine Light Duty Liquid Detergents Dishwashing Detergents Nonchlorine/Noncaustic .......................... 36 Noncaustic .................................... 36 ChlorineKaustic ................................ 36 5. GENERAL PURPOSE CLEANERS ....................... 37 Phosphate Free All Purpose Cleaner ..................... 38 Bathroom Tile Cleaner .............................. 38 All Purpose Cleaner ................................ 39 Hard-surface Cleaner ............................... 39 All-Purpose Cleaner Cleaner-A .................................... 40 Cleaner-B .................................... 40 With Microbicidal Properties. Liquid-B ............... 40 All Purpose Cleaner ................................ 38 Liquid-A ..................................... 41 Liquid-B ..................................... 41 With Microbicidal Properties. Liquid-A ...............41
  • 15.
    xiv Contents andSubject Index Pasty-A ...................................... 42 With Soap. High Viscosity-A ...................... 42 With Soap. High Viscosity-B Pasty-B ...................................... 42 ...................... 42 D-Limonene Emulsifiable Concentrate . . . . . . . . . . . . . . . . . . . 43 D-Limonene All Purpose Cleaner ...................... 43 General Cleaners Household .................................... 44 Alkaline Cleaner ............................... 44 Liquid Hand Cleaner ............................ 44 Germicidal Cleaner .............................. 44 High-Performance General Purpose Cleaner Concentrate . . . . . . 45 Heavy-Duty Cleaner Powder .......................... 45 Neutral All-Purpose Cleaner. with Pearlescence Effect High Viscosity-A ............................... 46 High Viscosity-B ............................... 46 With Acetic Acid-A ............................. 46 With Acetic Acid-B ............................. 46 Non-Phosphate All Purpose Cleaner .................... 47 Oil Splitting General Purpose Cleaner ................... 47 Scouring Cleaner Medium Viscosity-A ............................ 48 Medium Viscosity-B ............................ 48 Powder-A .................................... 48 Powder-B .................................... 48 All-Purpose Cleaner 6. GLASS CLEANERSD’OLISHES ......................... 49 For Application to Cloth .......................... 50 For Direct Application to Glass ..................... 51 Anti-Fogging. Anti-Static Glass Cleaner ................. 52 Ammoniated Glass Cleaner ........................... 52 Glass Cleaners Ammonia ..................................... 53 Vinegar ...................................... 53 Antifog Composition Glassware and Bottle Cleaners Bottle Cleaner Alkaline-Powder ............................ 54 Acid-Powder ............................... 54 Acid-Liquid ............................... 54 Highly Alkaline ............................. 54 Household Window Cleaner .......................... 55 Premium Household Window Cleaner ................... 55
  • 16.
    Contents and SubjectIndex xv Low VOC Antistat/Cleaner for Glass .................... 56 Anti-Fog Glass Cleaner ............................. 56 Glass Cleaner ..................................... 56 Traditional Consumer Glass Cleaner .................... 57 Consumer Acid Glass Cleaner ......................... 57 7. HARD SURFACE CLEANERS .......................... 58 Abrasive Cleaner-1 ................................ 59 Abrasive Cleaner-2 ................................ 59 Abrasive Cleaner-3 ................................ 59 Concentrated Liquid Household Hard-surface Cleaner ....... 60 All-Purpose Household Spray Cleaner ................... 60 Consumer Tile Cleaner .............................. 61 Industrial Strength Chlorine Cleaner ..................... 61 D-Limonene Hard-surface Cleaners .................... 62 d'limonene Spray Cleaner ............................ 63 d'limonene Cleaner Concentrate ....................... 63 General Purpose Hard Surface Cleaner ................... 64 Alkaline Hard Surface Cleaner ........................ 64 General Purpose Hard-surface Cleaners .................. 65 Unbuilt. High-Sudsing. Hard-surface Cleaner ............. 65 Hard Surface Cleaner ............................... 66 Non-Abrasive Cleanser .............................. 66 Hard Surface Cleaner ............................... 66 Floor Cleaner Products .............................. 68 Rug Cleaner ...................................... 68 Plastic. Vinyl and Leather Cleaner ...................... 68 Hard Surface Cleaners .............................. 69 Tub and Tile Cleaners ............................... 69 Counter Top/Wall Cleaners AlIPurposeType ............................... 69 Ammoniated Type .............................. 69 Hard Surface Cleaner w/Amphoteric .................... 70 Hard Surface Cleaner Concentrate w/d'Limonene ................................. 70 Alkaline All-Purpose Cleaner Concentrate ............. 71 All-Purpose Alkaline Cleaner for Sponge or Spray Application ................................. 71 High-Performance. Hard Surface Cleaners ................ 72 Economical Pine Oil Hard-surface Cleaner ............... 72 Mild Abrasive Hard Surface Cleaner .................... 73 Non-Phosphate Household Hard-surface Cleaner ........... 74 Non-Phosphate Concentrated Household Hard-surface Cleaner ....................................... 74
  • 17.
    xvi Contents andSubject Index Pine Oil Cleaner Concentrate .......................... 75 Liquid Super Concentrate ............................ 75 8. LAUNDRY PRODUCTS ............................... 76 Anionic/Nonionic Heavy-Duty Laundry Detergent . . . . . . . . . . 77 Nonionic/Amphoteric Heavy-Duty Laundry Liquid . . . . . . . . . . 78 Cold Water Detergent ............................... 79 Fine Fabric Detergent . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79 Process-A .................................... 80 P~OUXS-B. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80 Medium Viscosity-A ............................ 81 Medium Viscosity-B ............................ 81 Medium Viscosity-A ............................ 81 Medium Viscosity-B ............................ 81 Detergent for Fine Fabrics-1 .......................... 82 Detergent for Fine Fabrics-2 .......................... 82 Enzymatic Heavy-Duty Laundry Detergent Non-Phosphate Laundry Powder ....................... 83 Fabric Pretreatment Spritz ............................ 84 Low VOC Pump Fabric Antistatic Spray Laundry Pre-Spotter and Stain Remover Detergent for Colored Fabrics. Powder. Spray Mixing Detergent for Curtains Manual-Wash Detergent. Foaming . . . . . . . . . . . . . . . 83 . . . . . . . . . . . . . . . . . 84 . . . . . . . . . . . . . . . . . 84 Process-1 .................................... 85 Pr0~ess-2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85 Process-3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85 Low Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86 Low Viscosity-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86 Concentrate. Low Viscosity-A ..................... 86 Concentrate. Low Viscosity-B ..................... 86 Spray Mixing Process-A .......................... 87 Spray Mixing Process-B . . . . . . . . . . . . . . . . . . . . . . . . . . 87 Spray Mixing Process-A .......................... 88 Spray Mixing Process-B .......................... 88 Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88 Fabric Softener Heavy-Duty Detergent. Powder Liquid Heavy-Duty Detergent. Built Type. High Heavy Duty Liquid Laundry Detergent-Type DN . . . . . . . . . . 89 Built Formulation #1 ................................ 89 Heavy Duty Liquid Laundry Detergent-Type TA . . . . . . . . . . 90 Heavy Duty Liquid Laundry Detergent-Type WA . . . . . . . . . . 91 Liquid Laundry Detergents ........................... 90
  • 18.
    Contents and SubjectIndex xvii Built Formulation #2 ................................ 91 Liquid Heavy-Duty Detergent Low Viscosity-A ............................... 92 Low Viscosity-B ............................... 92 Built Type.High Viscosity-B ...................... 92 Light-Duty Detergent. Powder Spray Mixing Process-A .......................... 93 Spray M i n g Process-B .......................... 93 With Incorporated Softener. Low Viscosity-A .......... 93 Low VisCosity-A ............................... 94 Low Viscosity-B ............................... 94 With Incorporated Softener. Low Viscosity-B .......... 94 Industrial Laundry Two-Part Systems. Uniforms (Petroleum Greases and Oils) ........................ 95 HoteVLinen Supply (Animal and Vegetable Grease) ......... 95 Industrial Laundry Powder. Uniforms .................... 95 Laundry Liquids ................................... 96 "Fine Care" Fabric Detergents Pilot Formula #LDY-OO3-01 ...................... % Pilot Formula #LDL-003-01 ...................... 96 Pilot Formula #HDL-004-01 ...................... % Pilot Formula #HDL-005-01 ...................... % Laundry Powder Detergent ........................... 97 Industrial Laundry One-Shot Liquid .................... 97 Liquid Heavy Duty Detergent HDLD .................... 98 Liquid Detergent "FSL" A ............................ 98 Thick Bleach-2 ................................... 99 Wool Detergent Medium Viscosity-A ........................... 100 Medium Viscosity-B ........................... 100 Liquid Light-Duty Detergent Heavy Duty Laundry Liquids Thick Bleach-1 ................................... 99 9. METAL CLEANERS AND POLISHES ................... 101 Aluminum CleanerDrightener ........................ 102 Aluminum Smut Cleaner ............................ 102 Aluminum Cleaner Concentrate ....................... 103 Aluminum Wash ................................. 103 Cleaners and Cleaning Solutions ...................... 104 Metal Cleaning Alkaline .................................... 104 Acid ....................................... 104 Paint Removal ................................ 104
  • 19.
    xviii Contents andSubject Index Rust Removal ................................ 104 Copper Cleaning .................................. 105 Acid ....................................... 105 Brightening .................................. 105 Aluminum Aircraft-Brightener (U.S. Patent 2.687.346) . . . . . . 105 Electrocleaner ................................... 106 Moderate Alkalinity. Soil Splitting Soak Cleaner . . . . . . . . . . . 106 High-Foaming Acid Scrubber ........................ 107 Acid Cleaner .................................... 107 Metal Cleaner and Degreaser ......................... Thickened Clear Degreaser Concentrate . . . . . . . . . . . . . . . . . 108 Cleaner-A ................................... 109 Cleaner-B ................................... 109 Liquid-A .................................... 109 Liquid-B .................................... 109 Aluminum Cleaning 108 Stainless Steel Silver Polish 10.OVEN. GRILL AND HOT PLATE CLEANERS . . . . . . . . . . . . 110 Pump Spray Oven Cleaner .......................... 111 Caustic Oven Cleaner .............................. 111 Oven/Grill Cleaner ................................ 111 11. POLISHES. COATINGS AND FINISHES ................. 112 Aerosol Furniture Polish (Carbon Dioxide Propellant) . . . . . . . 113 General Purpose Liquid Polish (Oil-in-Water Type) . . . . . . . . 113 Aerosol Furniture Polish (Hydrocarbon Propellant) . . . . . . . . . 114 Furniture Paste Wax ............................... 114 Detergent Resistant. Cream Cleaner Polish . . . . . . . . . . . . . . . 115 Non-Abrasive. Detergent Resistant. Glaze Emulsion . . . . . . . . 115 High Gloss. Detergent Resistant. Soft Paste Polish . . . . . . . . . 116 Detergent Resistant Cream Polish ..................... 116 For Clear Coat Finishes ......................... 117 No Solvent .................................. 117 Outer Phase Oil ............................... 118 Non-Wax Liquid Polish (Oil-in-Water Type) ............ 118 Liquid Furniture Polish ............................. 119 20% Wax Emulsion-1 ............................. 119 20% Was Emulsion-2 ............................. 119 Liquid Water-Based Glaze .......................... 120 Solvent Wax Glaze ................................ 120 Paste Polish (Oil-in-Water Type) ..................... 121 Liquid Polish
  • 20.
    Contents and SubjectIndex xir Spray-and-Wipe Polish ............................ 121 Paste Polish Oil-in-Water Type Type-1 .................................. 122 Type-2 .................................. 122 Type-3 .................................. 123 Outer Phase Oil ............................... 123 Spray-and-Wipe Polish (Pump) ...................... 124 20%Wax Emulsion-1 ............................. 124 20% Wax Emulsion-2 ............................. 124 Spray and Wipe Type Aerosol or Non-Aerosol (1) ...................... 125 Aerosol or Non-Aerosol (3) ...................... 125 Aerosol or Non-Aerosol (2) ...................... 125 Liquid Wax-Solvent Furniture or Floor Polish ............ 125 12.RINSE AIDS ....................................... 126 For Hard Water ............................... 127 For Neutral or Soft Water ........................ 127 Rinse Aid ...................................... 128 Automatic Dishwash Rinse Aid 13.RUG. FJ.DOR, CARPET. UPHOLSTERY SHAMPOOS ANDCLEANERS ................................... 129 Liquid-A .................................... 130 Liquid-B .................................... 130 Liquid-A .................................... 130 Liquid-B .................................... 130 Dry-Foam Cleaner Basic Floor Cleaner Floor Cleaner. for Everyday Use Carpet and Upholstery Cleaners Liquid-A ................................ 131 Liquid-B ................................. 131 Powder-A ................................ 131 Powder-B ................................. 131 Carpet Shampoo. High Foam ......................... 132 Evaporative (No Rinse) Wax Stripper ................... 133 Waxed Floor Cleaner .............................. 133 Floor Cleaner .................................... 134 Floor Polish Mor-Glo 2-457 20% Solids ...................... 135 ML-870-389 20%Solids ........................ 136 Liquid Carpet Cleaner .............................. 137
  • 21.
    XT Contents andSubject Index Carpet Stain Remover-Liquid ........................ 137 Carpet Cleaner/Booster.Dry. Destainer . . . . . . . . . . . . . . . . . 137 Low Cost Extraction Carpet Cleaner . . . . . . . . . . . . . . . . . . . 138 Non-Ammoniated Floor Stripper ...................... 139 Quarry Tile Cleaner ............................... 140 Low Foam Floor Cleaner ........................... 140 Special-Purpose Floor Cleaner Liquid-A .................................... 141 Liquid-A .................................... 141 Medium Cost Steam Extraction Carpet Cleaner . . . . . . . . . . . . 138 Premium. Heavy Duty Steam Extraction Carpet Cleaner . . . . . 138 Liquid-B .................................... 141 Wash-and-Wax Floor Cleaner Liquid-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 141 14.MISCELLANEOUS .................................. 142 Condensate T L Typical Formulations . . . . . . . . . . . . . . . . . . 143 All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143 Dilutable Shampoo ................................ 143 Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143 Opacified Hand Soap .............................. 143 d'lmonene Waterless Hand Cleaner . . . . . . . . . . . . . . . . . . . 144 Waterless Hand Cleaner ............................ 144 Dry Cleaning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 145 Dust Control . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 146 Hand and Body Cleanser ............................ 147 Heavy Duty Degreaser ............................. 148 Burnishing Compound .............................. 148 Bubble Bath . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143 Viscous Floor Cleaner .............................. 143 Corrosion Inhibiting Coating Oil-Emulsifiable . . . . . . . . . . . . 148 Heavy Duty Industrial Spray Metal Cleaner Concentrate . . . . . 149 Low Foam Hypochlorite Cleaner ...................... 149 Metal CleanerBrightener ........................... 149 Low Foam Heavy Duty Alkaline Cleaner-A . . . . . . . . . . . . . . 150 Low Foam Heavy Duty Alkaline Cleaner-B . . . . . . . . . . . . . . 150 Paint Brush Cleaners ............................... 151 Steam Cleaner ................................... 152 Heavy Duty Industrial Spray Cleaner Concentrate . . . . . . . . . . 152 Hot Tank Stripper/Cleaner/Derster .................... 150 High Solids Alkaline Cleaner ........................ 152 Wallpaper Removal ............................... 153
  • 22.
    Contents and SubjectIndex m- SECTION II TRANSPORTATION CLEANERS AND POLISHES 15.AUTO CLEANERS AND POLISHES .................... 155 Auto Polishlcleanser. Oil in Water Emulsion ............. 156 Detergent Resistant Auto PolishlCleanser. Paste Wax ....... 156 Camauba Hotwax ................................. 157 Pressure Spray Truckwash ........................... 157 Detergent Resistant Auto Polish. Oil in Water Emulsion ..... 158 High Luster Auto Finish. Paste Wax ................... 158 High Gloss. Detergent Resistant Polish .................. 159 High Gloss Auto PolishPinish ........................ 159 Spraywax ....................................... 160 Spraywax Ladder of Formulas ........................ 161 Spraywax Concentrate .............................. 160 16.CAR AND TRUCK WASH COMPOUNDS ................ 162 Automatic Car Wash Concentrate ..................... 163 General Purpose Car Wash .......................... 163 Auto Shampoo Concentrate .......................... 164 High Foaming Car Wash ............................ 164 Car Wash ....................................... 164 Car Wash Liquid ................................. 165 Car Wash Powder ................................. 165 Economy Truck Wash .............................. 166 Truck Wash Liquid ................................ 166 Foamy Brush Car Wash. Liquid ....................... 167 1:2 Dilutable Car Wash ............................. 167 High Oil Splitting Vehicle Wash-A .................................... 168 Wash-B .................................... 168 Liquid Car Wash ................................. 169 Spray-On Car Wash Concentrate ...................... 169 Liquid Hi@ Pressure Coocentrate ..................... 170 Tmck Wash w/varamide A-83 ....................... 170 Liquid Tmck Wash ................................ 171 Mild Car Shampoo ................................ 172 Cgrspray CW Concentrate ........................... 172 Automotive "Wash t Wax" ......................... 172 Premium Carspray 500 Concentrate .................... 173 Standard Carspray 500 Concentrate .................... 173 Premium Carspray 700 Concentrate .................... 174 Standard Carspray 700 Concentrate .................... 174
  • 23.
    xxii Contents andSubject Index 17.WHITEWALL TIRE CLEANERS ....................... 175 White Wall Tire Cleaner ............................ 176 Bug Remover Concentrate ........................... 176 Whitewall Tire Cleaner Concentrate .................... 177 Whitewall Tire Cleaner Liquid ....................... 177 18.MISCELLANEOUS .................................. 178 Automobile Windshield Cleaners ...................... 179 General Purpose Liquid Boat Polish-(l) ................. 180 General Purpose Liquid Boat Polish-(2) ................. 180 Liquid Aluminum Engine Block Cleaner ................ 181 Foaming Engine Cleaner ............................ 181 SECTION Ilk TRADE-D RAW MATERIAIS ........... 182 SECTION N:SUPPLIERS'ADDRESSES .................... 197
  • 24.
    Section I Household andIndustrial Cleaners and Polishes 1
  • 25.
  • 26.
    Bathroom Cleaners 3 Bathtuband Faucet Cleaner I n g r e d i e n t : Percent by We1q h t Ammoni um hydroxide s o l u t i o n 28% 3.2 Cellosolve solvent 5.0 Nonionic s u r f a c t a n t (Neodol 25-9) 6.0 Water 65.8 L i q u i d C i t r i c Acid-50% (Haarman & Reimer Corp.) 20.0 Fragrance, dye q . s . Mix t h e L i q u i d C i t r i c Acid-50% w i t h an equal volume o f water. Slowly add t h e ammonium hydroxide s o l u t i o n . The n e u t r a l i z a t i o n should be done c a u t i o u s l y and under a g i t a t i o n , as t h e r e a c t i o n i s exothermic. Add Cellosolve, s u r f a c t a n t , remaining water, fragrance and dye. The formula i s s u i t a b l e f o r a pump spray. Bathtub, sinks, faucets and other hard surfaces should be sprayed from a distance o f about 10 inches. For maximum e f f e c t - iveness, t h e deposited cleaner f l u i d should be e f t a t work f o r a t l e a s t f i v e minutes and then r i n s e d o f f w t h water o r removed w i t h a wet c l o t h o r sponge. SOURCE: Haarman 81 Reimer Corp.: Suggested Formu __Bathroom_ _ _ - ~Cleaner Water Sodium C i t r a t e Glucopon 425 CS Propylene Glycol nButy1 Ether T o i l e t B o w l Cleaner Water Phosphoric Acid Glucopon 425 CS Tub 8 7 1 l e Cleaner a t i o n Water Sodium C i t r a t e STPP Standapol ES-2 Velvetex A0-45 Standamid KD Isopropyl Alcohol SOURCE: Henkel Corp., CD D i v i s i o n : S t a r t i n g Formulations "rtb 79 9 9 3 W t % 79 15 6 W t % 75 4 1 12 4 1 3
  • 27.
    4 Advonced CleoningRoductFormulotions Clear Liquid Bowl Cleaner Formula BC-0001 Miranol FBS Hydrochloric A c i d (20Be) Water Wt.% 3.0 20.0 77.0 Procedure Add t h e Miranol FBS. Mix u n t i l uniform. Phvsi-1 Prooerties Add t h e water. Slowly add t h e h y d r o c h l o r i c acid, w i t h mixing. Appearance: Clear, l i g h t y e l l o w V i s c o s i t y : <10 cps S p e c i f i c G r a v i t y : 1-03 pH (as i s ) : <1.0 Thick T o i l e t Bowl Cleaner Formula BC-0002 Wt.% M i r a t a i ne TM 5.0 Hydrochloric Acid (20Be) Water 32.0 Q.S Prowdur g add t h e M i r a t a i n e TM and mix u n t i l uniform. PhvsiG a l Prooerties Add t h e h y d r o c h l o r i c a c i d t o t h e water, w i t h s t i r r i n g . Slow Appearance: C1ear, ye11ow 1iqui d V i scosi t y : 1.035 cps Speci f ic Gravi t y : 1,037 pH (as i s ) : <1.0 Y SOURCE: Rhone-Poulenc S u r f a c t a n t s & S p e c i a l t i e s : Formulas
  • 28.
    Bathroom Cleaners 5 FoarnableA c i d T i l e Cleaner Hard Foaming Hard Surface Cleaner f o r Soap Scum Removal Inaredi e n t : Dei oni zed Water C i t r i c Acid (50%) Mazon 98 Wt.% 87.00 10.00 3.00 pH (as i s ) : 2.0-2.5 Appearance: Clear, water-white l i q u i d S p e c i f i c G r a v i t y : 1 .01 Procedure: above. Mix u n t i l c l e a r . Notes : This formula produces a copious, dense foam. I t i s s u i t a b l e f o r cleaning soap scum from shower s t a l l t i l e s and other bath- room and household f i x t u r e s . To a mixing vessel, charge t h e i n g r e d i e n t s i n t h e order l i s t e d Formula CH-105 L i a u i d T o i l e t Bowl Cleaner A L i q u i d S t a i n and Rust Remover I n s r e d i e n t : Deionized Water Phosphoric Acid (75%) Avanel S-70 pH (as i s ) : t1.5 Appearance: Clear, water-white l i q u i d S p e c i f i c G r a v i t y : 1.124 Wt.% 66.00 30.00 4 . 0 0 Procedure: phosphoric a c i d under a g i t a t i o n . Use c a u t i o n during a c i d add- i t i o n t o avoid s p a t t e r i n g . When a l l o f t h e a c i d i s dissolved, cool t o room temperature and add t h e Avanel s u r f a c t a n t . Notes: i c u l a r l y e f f e c t i v e i n t h e removal o f scale build-up and r u s t s t a i n s . This m a t e r i a l may be marketed i n an appropriate squeeze b o t t l e t o f a c i l i t a t e "under t h e r i m " bowl cleaning by t h e consumer. Formula CT-101 SOURCE: Mazer Chemicals: Suggested Formulations Charge t h e water t o t h e mixing vessel, and slowly charge t h e This formulation i s designed t o be used "as i s " and i s p a r t -
  • 29.
    S o li d Automatic T o i l e t Bowl Cleaner Formulation I n g r e d i e n t : Macol DNP 150 Incromide L90 Carbowax PEG 8000 Macol 27 Versaflex 207 ( d r y ) Water %- 25.0 25.0 20.0 20.0 5.0 5.0 Procedure: 1. Melt t h e Macol 27, Macol DNP 150, and Carbowax PEG 8000, and 2. Maintain a temperature o f about 70C, and add t h e Incromide 3. Add water and Versaflex 207 ( d r y ) and mix. 4. Pour formulation i n t o a mold, and a l l o w t o cool. SOURCE: National Starch and Chemical Co.: Reference #8069:49 mix together. L90 w h i l e mixing. __A c i d T o i l e t Bowl Cleaner Water, D . I . Hydrochloric Acid (37%) Rewoteric AM TEG % bv Weiaht 71 . O 27.0 2.0 B1endi ng Procedure: Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between each addi t i on. Typical Properties: V i s c o s i t y , cps: 135 Solids: 1.0% pH: 2.8 SOURCE: Witco Corp.: Formula 532 Tub, T i l e and Bathroom Cleaner Water Sodium Carbonate Tetrasodium EDTA (40%) Phosphoteric T-C6 Nonoxynol 10 Procedure: % bv Wei aht 81.5 5.0 10.0 1.5 2.0 Add i n g r e d i e n t s i n order l i s t e d , a l l o w i n g s u f f i c i e n t time between a d d i t i o n s . This product may be applied w i t h a t r i g g e r pump o r by aerosol. Formulation Properties: Physical Appearance: Clear l i q u i d Cloud Point: 42C SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formulation 6 Advanced CleaningRoabct Formulations
  • 30.
    Bathroom Cleaners 7 Ti l e , Porcelain and Bathroom Cleaner, Acid Water. D . 1 % by Weiqht 75.5 Rhodopol 23 0.5 Petro BAF Powder 2.0 Phosphori c Acid, 75% 12.0 Hydroxyacetic Acid, 70% 10.0 Perfume, Dye q . s . B1endi ng Procedure : t o mix u n t i l material thickens. Add remaining ingredients i n order l i s t e d . If problems develop adding Rhodopol t o water, premix the Rhodopol 23 i n some isopropanol before adding t o water. Formula 529 Add Rhodopol 23 slowly t o water w i t h high speed mixing. Allow Hypochlorite Tub and T i l e Cleaner and Mildew S t a i n Remover % by Weiqht Water, D.I. 44.9 Sodium Hydroxide (30%) 1 .o Varox 365 1.5 Sodium Hypochlorite (5.7%) 52.6 81endi ng Procedure : between each addi t ion. Typical Properties: Viscosity, cps: 4 Solids: 3.8% pH: 13.5 Formula 531 Add ingredients i n order shown and dissolve completely Soap Scum Remover/Cleaner % by Weiaht Water, D.I. q . s . *Builder Solution 0.20 Tetrasodi um EDTA 0.25 Rewoteric AM V 1 .oo Dowanol EB 0.50 81ending Procedure: Blend ingredients i n the order shown, mixing thoroughly between each a d d i t i o n . Typical Properti es : Viscosity, cps: 4 Solids: 2.0% pH: 11-12 Comments: *Builder Solution: Sodium Carbonate (Na2C03): 4% Potassi um Hydroxide (KOH) : 3% DI Water 93% Formula 544 SOURCE: Witco Corp.: Suggested Formulations
  • 31.
    8 Advanced CleaningRoabctFormulations T o i l e t Cleaner. Liquid-A Marl ipal 013/99 Acetic acid* Balance water, fragrance, dyestuff A c t i v e matter: 2.7% Toi 1e t Cleaner . L iquid-B Marl ipal 013/99 C i t r i c a c i d Balance water, fragrance, d y e s t u f f A c t i v e matter: 4.5% Toi 1e t C1eaner , Medi urn V i scosi t y - A Marlazin OL 2 M a r l i p a l 013/99 C i t r i c a c i d Na Cumene sulphonate 40 (approx.) Balance water, fragrance, d y e s t u f f A c t i v e matter: 2.0% T o i l e t Cleaner, Medi urn V i scosi tv-B Marlazin OL2 Marl ip a l 013/99 C i t r i c a c i d Phosphoric acid, 85% KNA cumene sulphonate 40 (approx.) Balance waser, fragrance, d y e s t u f f A c t i v e matter: 2.0 * f u r t h e r products o f Huls AG 96 3.0 6.0 t o 100 % 5.0 1.7 t o 100 % 1.5 0.5 5.0 1.5 t o 100 % 1.5 0.5 2.5 7.5 1.3 t o 100 SOURCE: Huls America, I n c . : Baslc Formulations o f Detergents and Cleaning Agents f o r Household Purposes
  • 32.
    Bathroom Cleaners 9 Toi1e t Cleaners, Mediurn V i scosi t y - A Marlazin 7102 Phosphoric acid, 85% Sodium c h l o r i d e Balance water, fragrance, d y e s t u f f Active matter: 4.0% Toi 1e t C l eaner . Mediurn V i scosi ty-B Marlazin OL 2 M a r l i p a l 013/99 Acetic Acid* KNA cumene sulphonate 40 (approx.) Balance water, fragrance, dyestuff Active matter: 3.5% Toi 1e t Cleaner. Powder Marlon ARL Amidosulphonic a c i d Magnesium carbonate Sodi um b i sulphate Sodium bicarbonate, fragrance, d y e s t u f f Active matter: 4.0% T o i l e t Cleaner. Powder-B Marlon A 390 C i t r i c a c i d Sodi um sulphate Sodium bicarbonate, fragrance, dyestuff A c t i v e matter: 4.5% 96 4.0 5.0 3.5 t o 100 % 3 . 0 0.5 6.0 3.1 t o 100 96 5 . 0 20.0 5 . 0 6 0 . 0 t o 100 % 5.0 25.0 55.0 t o 100 SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and Cleaning Agents for Household Purposes
  • 33.
    10 Advanced CleaningRoduct Formulations T o i l e t Cleaning Block, Extruded-A Marlon ARL M a r l i p a l 1618/25 powder Marlamid M1618 Vestinol C* Sodium sulphate, d y e s t u f f Active matter: 42.0% T o i l e t Cleaning Block. Extruded-B Marlon ARL Marlon A390 Lipoxol 6000* Sodi um tripolyphosphate Fragrance Sodium sulphate, d y e s t u f f Active matter: 59.0% T o i l e t Cleanino Block. Cast-A Marl i n a t 242/70 Marlon A375 M a r l i p a l 1618/25 powder M a r l i p a l 1618/40 Marlamid M 1618 L ipoxol 12000* Fragrance Dyestuff Active matter: 80.8% T o i l e t Cleaning Block. Cast-B Marl i pal 013/90 M a r l i p a l 1618/40 M a r l i p a l M 1618 L ipoxol 12000* Fragrance Dyestuff Active matter: 79.0% * f u r t h e r products o f Huls Ag 96 40.0 4.0 6.0 4.0 t o 100 ss 40.0 30.0 8.0 1.o 5.0 t o 100 % 3.0 13.0 30.0 24.0 15.0 10.0 4.0 1.o 96 12.0 60.0 10.0 13.0 4.0 1.o SOURCE: Huls Chemical Co.: Basic Formulations o f Detergents and Cleaning Agents f o r Household Products
  • 34.
    2. Dairy, Foodand General Industrial Cleaners 11
  • 35.
    12 Advanced CleaningRoductFormulations An Inaredient : Deionized Water G l y c o l i c Acid (70%) Phosphoric Acid (85%) Avanel S-150 Dairy Mi 1kstone Remover Acid D i l u t a b l e Concentrate Wt.% 53.40 28.60 10.00 8 . 0 0 pH (as i s ) : ~ 2 . 0 Appearance: Clear, water-white t o l i g h t - y e l l o w l i q u i d Procedure: Charge water t o t h e mixing vessel and s t a r t a g i t a t i o n . Under a g i t a t i o n , charge t h e G l y c o l i c Acid followed by t h e Phosphoric Acid. Charge t h e Phosphoric Acid slowly t o avoid s p l a t t e r i n g . Charge t h e Avanel S-150 and cool t o room temperature. F i l l o f f . Notes : m i 1kstone from dai r y equipment . Brush thoroughly, then r i n s e . Formula CD-101 This formulation i s h i g h l y e f f e c t i v e a t removing d a i r y Use concentration i s 1/2 t o 1 ounce per g a l l o n o f water. Dairy M i 1kstone Remover Low Cost Acid D i l u t a b l e Concentrate Inaredient : Deioni zed Water Phosphoric Acid (85%) Gluconic Acid (50%) Avanel 5-70 pH (as i s ) : < 2 . 0 Appearance: Clear, water-white l i q u i d Wt.% 55.00 37.50 3 . 5 0 4 . 0 0 Procedure: To mixing vessel, charge t h e water and s t a r t a g i t a t i o n . Slowly charge t h e Phosphoric Acid t o avoid s p l a t t e r i n g . Cool t o room temperature and charge t h e Gluconic Acid and Avanel S-70. Notes: A lower cost s u b s t i t u t e f o r PPG/Mazers CD-101 d a i r y cleaner formulation. I t r e t a i n s t h e general performance a t t r i b u t e s o f t h e o r i g i n a l formulation. Use concentration i s 1/2 t o 1 ounce per g a l l o n o f water. Brush thoroughly, then r i n s e . Formula CD-102 SOURCE: Mazer Chemicals: Suggested Formulations
  • 36.
    &ky, Food andGeneralI . . Cleaners 13 D a i r y P i p e l i n e Cleaner H i g h A1 k a l ine Low Foam Hvpochlorit e Cleaner I n n r e d ient: Deionized Water Sodium Hydroxide (50%) Avanel S-74 Sodium Cumene Sulfonate (40%) Sodium Hypochlorite (12.5%) pH (as i s ) : 12.5-13.5 Appearance: Clear, 1ight-ye1 low 1i q u i d Speci f ic G r a v i t y : 1 . 1 5 Wt.% 52.00 20.00 2.50 1 .50 24.00 Procedure: Hydroxide, and cool t o l e s s than 9OF. Add t h e Avanel 5-74 and Sodium Cumene Sulfonate. Mix u n t i l c l e a r and add t h e Sodium Hypochlorite. Notes: a l k a l i n i t y o f common p i p e l i n e cleaners r e s u l t i n g i n a s i n g l e cleaning system. Shelf s t a b i l i t y o f h y p o c h l o r i t e cleaners i s dependent on t h e absence o f t r a c e metals. Care should be taken t o i n s u r e good q u a l i t y water and hypochlorite. Formula may be adjusted t o use other commercially a v a i l a b l e concentrations o f Sodium Hypochlorite. Absolute concentration o f a v a i l a b l e c h l o r i n e i s 3.0%. SOURCE: Mazer Chemicals: Formulation CD-103 Charge water t o mixing vessel and s t a r t a g i t a t i o n . Add Sodium This formulation combines a c h l o r i n e cleaner w i t h t h e h i g h I n s t i t u t i o n a l S t a i n l e s s Steel Cleaner Components: Water 50% C i t r i c Acid Burcosperse LP Dequest 2000* Burco NPS 50% 45% KOH % by Weight 52.75 20.00 5.00 5.00 5.00 12.25 *From Monsanto o r use equivalent product. Procedure: Add components i n t h e order l i s t e d . Blend u n t i l uniform between each a d d i t i o n . SOURCE: B u r l i n g t o n Chemical Co., I n c . : Suggested Formulation
  • 37.
    14 Advanced CleaningProductFormulations High Pressure Cleaner for I n d u s t r i a l Use L i q u i d , transparent, a l k a l i n e I n q r e d i ents: A Genapol UD-050 Genapol UD-080 Genopur ASA KOH (85%) B Water (ca.5OC) C Sodi ummetasi 1ic a t e x 5H20 Manufacturing: I The components o f A a r e mixed. I 1 Then B i s added. I11 F i n a l l y t h e components o f C are added Aquamollin 8C Powder h i g h l y conc. 2,50% 2,50% 3,00% 5.00% 67,00% 10,00% 10,00% Cleaner f o r M i 1k i n a EauiDment L i q u i d I n g r e d i e n t s : A Tetrapotassiumpyrophosphate Sodi ummetasi 1i c a t e x 5H20 Sodiumcarbonate B Water C Genopur ASA KOH (85%) D Genapol UD - 080 Manufacturing: I One a f t e r another, t h e components o f A I 1 S t i r one a f t e r another, t h e components I11 A t l a s t D i s added. 7.00% 5,00% 3,00% 70,00% 5.00% 5,00% 5,00% are added t o 8. o f c t o I. Cleaner f o r Meat P l a n t s L i q u i d I n g r e d i e n t s : A Tetrapotassiumpyrophosphate B Water C Genopur ASA KOH (65%) D Hostapur SAS 60 Genapol UD - 080 Solvent GX 5 Manufacturing: I Add one a f t e r another, t h e components o f A t o I 1 C i s added t o Iby c o n t i n u i n g s t i r r i n g . I11 A t l a s t t h e components o f D are added. Potassium water g l a s (40 Be) 5,00% 76,00% 3,50% 3,50% 5.00% 2,00% 3,00% 2,00% B. SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Detergents and Cleaning Agents: Guide Formulations
  • 38.
    he,Food and GeneralIndustrialCleaners 15 Meat Packaaina Plant Cleaner Concentrate An A l k a l i n e High Foaming Hypochlorite Hard Surface Cleaner w i t h Improved S a l t Tolerance Inaredi ent : Oeioni zed Water Hostapur SAS-60 Potassi um Hydroxide Tetrapotassium Pyrophosphate Mazon 98 Sodium Cumene Sulfonate (40%) Sodium Hypochlorite (12.5%) Oeioni zed Water Wt.% 59.20 2.50 0.90 2.10 5.00 1.30 10.00 19.00 pH (as i s ) : 12.5-13.5 Appearance: Clear-to-translucent, s l i g h t l y viscous, l i g h t - Speci f ic Gravity: 1.04 Charge t h e water t o a mixing vessel and s t a r t a g i t a t i o n . yellow l i q u i d . Procedure: Charge t h e Hostapur, followed by t h e Potassium Hydroxide and t h e Tetrapotassium Pyrophosphate. Apply cooling and then add t h e Mazon 98 and t h e Sodium Cumene Sulfonate. When product i s l e s s than 85 degrees F. add t h e Sodium Hypochlorite and t h e balance o f t h e water. Notes: This formula i s designed t o be d i l u t e d t o 3-6 ounces per g a l l o n i n hot water and t o be applied as a foam t o meat packing house w a l l s and other surfaces. A f t e r an appropriate time, these surfaces should be thoroughly rinsed. Shelf s t a b i l i t y o f c h l o r i n e cleansers i s dependent upon t h e absence o f t r a c e metals. Care should be taken t o insure good q u a l i t y water and Sodium Hypochlorite. Revision o f CB-102 t o provide greater s a l t tolerance. SOURCE: PPG Industries, I n c . : Formula CB-102-A
  • 39.
    16 Advanced CleaningProdccctFormulations Steam Cleaners C1eaner-Li ght Duty Inaredients : Sodi urn Metasi 1ia t e Sodi um T r i p o lyphosphate Trisodium Phosphate Aerosol 22 Surfactant T r i t o n CF-10 Inqredients: Sodi urn Orthosi 1i c a t e Sodium Carbonate T r i sodi urn Phosphate Aerosol 22 Surfactant T r i t o n CF-10 C l eaner-Medi urn Duty % by Weiaht 30.0 58.0 10.0 1 .o 1.o % by Wei aht 33.0 20.0 44.0 1.5 1.5_ _ Cleaner-Heavy D u t y (For O i l y S o i l s ) % by WeiahtInaredients: Aerosol 22 Surfactant 7.0~ ~~~ Sodium M e t a s i l i c a t e Dowanol DE Water Inaredients: Aerosol 0s Surfactant Soda Ash Sodi urn Hydroxide Sodium M e t a s i l i c a t e (5H20) Sodi um T r i polyphosphate Cleaner-General Purpose Use 0.5 t o 2.0 0 2 . t o 1 a a l l o n o f water. 35.0 3.0 55.0 % by Weight 10.0 35.0 15.0 30.0 10.0 _ _ _ Cleaner-Lipht Duty f o r S o f t Metals Ingredients: % by Weiaht Aerosol 0s Surfactant 7.14~ ~~~ Sodium Sesquicarbonate 92.86 Inpredients: % by Weiaht Cleaner-General Purpose Sodi um Metasi 1icate Aerosol 22 Surfactant 5.0 Water 73-78 15-20 Aerosol 0s Surfactant 2- 3 Cleaner-Compound Inaredi ents : % by Weiaht Sodi urn Hydroxide 30.0 Borax 30.0 D i sodi um Phosphate 15.0 Aerosol C-61 Surfactant 5.0 Add t h e desired amount o f cleaner t o water which has been preheated t o 140F. SOURCE: Cytec I n d u s t r i e s I n c . : Suggested Formulations Soda Ash 20.0
  • 40.
  • 41.
    18 Advanced CleaningProductFormulations d-Liaonene Microemulsion Cleaner/Desreaser Burco TME Burco FAE d-Li monene Water 11 p a r t s 11 p a r t s 16 p a r t s 62 p a r t s Mix i n order l i s t e d ; add water slowlv. Product w i l l No co-solvent i s required when mixed i n proprortions given thicken, then break as water i s added. above. Produces a c l e a r product. Burco FAE imparts corrosion resistance i n a d d i t i o n t o emulsion c h a r a c t e r i s t i c s . but r a t i o s o f t h e other a c t i v e s must remain s i m i l a r t o the above. Example : To make a more concentrated product, l e s s water can be used, TME FAE d-Limonene Water 22 p a r t s 22 p a r t s 32 p a r t s 24 p a r t s High a c t i v e products can reach a g e l - l i k e v i s c o s i t y , but can be t h i nned w i t h Isopropanol and Butyl Propyl sol v. SOURCE: Burlington Chemical Co., I n c . : Suggested Formulation Concentrated d-Limonene Biodearadable Deareaser A Natural All-Purpose Micro-Emulsion Cleaner o r Concentrate Inaredi ent : d-Limonene. Grade M Mazclean EP Deionized Water Wt.% 30.00 20.00 50.00 pH (as i s ) : 9.0-10.0 Appearance: Clear, l i g h t - y e l l o w l i q u i d S p e c i f i c Gravity: 0.97 Odor: Sweet Orange Procedure: Charge t h e d-Limonene and Mazon 245-103 t o an apprDopriate mixing vessel and s t a r t a g i t a t i o n . Under good a g i t a t i o n , slowly add t h e water and mix u n t i l s o l u t i o n i s c l e a r . Notes : duty use, product should be sprayed "as i s " onto t h e o i l y substrate, followed by a water r i n s e . SOURCE: PPG I n d u s t r i e s , Inc.: Formulation CS-101 This formulation may be used "as i s " o r d i l u t e d . For heavy-
  • 42.
    Degreasers 19 Solvent Deareasirig The s o l u b i l i t y o f Aerosol OT Surfactant i s extremely high i n a l l solvents used f o r degreasing. I t w i l l d i s s o l v e e a s i l y a t room temperature i n most cases. I f heating i s required f o r s o l u b i l i z a t i o n , t h e s o l u t i o n w i l l be s t a b l e upon r e t u r n t o room temperature. As an example, Aerosol OT-75% i s soluble t o over 50% a t room temperature i n carbon t e t r a c h l o r i d e , b u t naphtha solvent requires heating. Both are c l e a r s o l u t i o n s a t room temperature. The presence o f t h e water i n Aerosol OT-75% p o r t i o n i s an a i d i n t h e removal o f any water-soluble p a r t i c l e s present i n t h e work being degreased. Formulations such as: Aerosol GPG o r OT-75% High Flash Naphtha 0.5% 99.5% can be used f o r l i g h t - d u t y cleaning, t h e solvent removing t h e o i l s , waxes, etc. and t h e Aerosol OT a i d i n g not o n l y i n t h e penetration o f t h e covering material, b u t a l s o i n d r a i n i n g . This type o f cleaner can be sprayed on, brushed on, o r t h e work can be immersed i n t o i t followed by a r i n s e . Heavy-Duty Degreasing: To remove heavy l u b r i c a t i n g and preservative o i l s and greases, many solvents may be used t o s p e c i f i c needs. Aerosol GPG Surfactant w i l l be found t o be soluble i n a l l o f these solvents. A t y p i c a l formulation used i s : Aerosol GPG o r OT-75% Kerosene 1- 3% 97-99% Preparation i s by simple mixing. T r i - o r tetrachloroethylene, high f l a s h naphtha o r other s u i t a b l e solvents can be s u b s t i t u t e d f o r t h e kerosene. Carbonaceous deposits can be removed by d i p p i n g i n formula- t i o n s such as: Kerosene Perchloroethylene Carbon Tetrachloride Cresyl ic Acid Aerosol GPG o r OT-75% 40% 30% 16% 10% 4% Normally, 3 g a l l o n s o f t h e above are added t o 1 g a l l o n of water which, f l o a t i n g on t h e surface, minimizes l o s s o f solvent. The work t o be cleaned i s immersed i n t h e solvent phase f o r time periods o f a few minutes t o several hours, i f required, t o o b t a i n cleanliness. Upon removal from t h e solvent layer, and a s h o r t r i n s e i n t h e aqueous l a y e r , t h e cleaned a r t i c l e s are rinsed, d r i e d o r c a r r i e d onto t h e next operation. SOURCE: Cytec I n d u s t r i e s , Inc.: Suggested Formulations
  • 43.
  • 44.
    Dishwashing Detergents 21 C1earL i q u i d D ishwash W i t c o l a t e AE-3 Witco 1298 S o f t Acid Sodi um Hydroxide, 50% W i tconate SXS L i q u i d W i tcami de 5195 Phosphoric Acid Water % by Weiqht 12.5 19.0 5.2 13.5 2.5 q.s. t o pH = 6.4-6.8 q.s. t o 100 Blending Procedure between each a d d i t i o n . Formula 108 B1end ingredients in t h e order shown, m i x i ng thoroughly Non-Chlori nated Machine D i shwashi na Compound, L i q u i d % by Weight Water, D.I. 79.5 Sodi um Tripolyphosphate 2.0 Versene 220, Powder 1.0 Sodium Gluconate 1 .o Sodium M e t a s i l i c a t e , Pentahydrate 7.0 Caustic Soda 50% 8.5 Petro ULF L i q u i d 1.0 Blending Procedure: between each a d d i t i o n . Formula 109 Blend i n g r e d i e n t s i n t h e order shown, mixing thoroughly Clear, Colorless Manual Dish Wash Water, D.I. W i t c o l a t e ES-3 Rewoteric AM 8-14 Ethanol Sodium Chloride % by Weiqht 57.5 31.2 5.0 3.0 3.3 Blending Procedure: between each a d d i t i o n . Comment : B1end ingredi ents in t h e order 1isted. Dissolve completely Rewoteric AM 8-14; Grease c u t t e r and foam booster. Formula 132 SOURCE: Witco Corp.: Suggested Formulations
  • 45.
    22 Advanced CleaningRoduct Formulations Dish Washina Agent Clear, l i q u i d , 25% WAS Alkanesulphonate:ethersulfate=4.1 Ingredients: A Hostapur SAS 60 B Water Genapol ZRO l i q u i d Preservative Dye Perfume Hoe S 3924 Manufacturing: One a f t e r another, t h e components o f B are added t o A. Tests: V i s c o s i t y (mPas) : 90 Cloud p o i n t : <-5C 33.36% 17.90% 47.50% 0.10% q.s. 0.20% 1.00% Dish Washin A ent c l e a r , liquid: 2:% WAS alkanesulphonate:ethersulphate=4.1 Ingredients : A Hostapur SAS 60 B Water Genapol ZRO l i q u i d Preservative W e Perfume Hoe S 3924 Manufacturing: One a f t e r another, t h e components o f B are added Tests V i s c o s i t y (mPas): 410 Cloud p o i n t : <-5C 33.30% 17.90% 44.50% 0.10% q.s. 0.20% 4.00% t o A. Dish Washing Aaent Clear, l i q u i d , 30% WAS alkanesulphonate:ethersulphate=4.1 Ingredients: A Hostapur SAS 60 40.00% Genapol ZRO l i q u i d 21.40% B Water 30.30% Preservative O.lO% Dye q.s. Perfume 01.20% Manufacturing: Tests: One a f t e r another, t h e components o f 0 are added t o A. V i s c o s i t y (mPas): 330 Cloud p o i n t : <-5C SOURCE: Hoechst Aktiengesellschaft: Detergents and Cleaningal Agents: Guide Formulations
  • 46.
    DishwashingDetergents 23 Dish Washina Agent Clear, l i q u i d , 30% WAS alkanesulphonate:ethersulphate=4:1 I n a r e d i e n t s : A Hostapur SAS 60 Genapol ZRO l i q u i d 8 Water Preservative Dye Perfume Hoe S 3924 Manufacturing: Tests: One a f t e r another, t h e components o f 0 are added V i s c o s i t y (mPas): 610 Cloud p o i n t : <-5C Powder f o r Automatic Dishwashina Machines 40.00% 21.40% 34.30% 0.10% q.s. 0.20% 4.00% t o A. I n a r e d i e n t s : A Genapol 2908 B Sodiummetasilicate x 5H20 C Sodiumcarbonate Sodi umdichloroi socyanurate Thermphos NW Manufacturi no: 1;. 00% 52.00% 10.00% 2.00% 35.00% I Spray A on 0 . I 1 One a f t e r another, t h e components o f C a r e added t o 1. A p p l i c a t i o n : SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Detergents and Cleaning 1-2 g detergent/L dishwashing l i q u o r Agents: Guide Formulations
  • 47.
    24 Advanced CleoningProduct Formulations Dishwashing Deteraent. Medium Viscositv. Basis Marlon A-A % Marlon A 350 30.0 Marl inat 242/70 5.7 D i o n i l OC 1.o Na cumene sulphonate 40 1.o Balance water, fragrance, dyestuff, preservative, sodium c h l o r i d e t o 100 A c t i v e matter: 20.0% Dishwashing DeterQent. Medium Viscositv. Basis Marlon A-B % Marl inat 242/70 4.3 sodium c h l o r i d e t o 100 Marlon A 365 18.5 Balance water, fragrance, d y e s t u f f , preservative, A c t i v e matter: 15.0% D ishwashi na Detergent, Medi urn V i m s i t y . B a s i s Marlon AS3-A % Marlon AS3 10.5 Caustic soda, 50% (approx.) 2.6 Marl ip a l 013/120 2.7 Balance water, fragrance, dyestuff, preservative, sodium c h l o r i d e t o 100 A c t i v e matter: 14.0% D i shwashi n Q Detergent, Medi urn Viscosity. Bas4s Marlon AS3-B % Marlon AS3 4.5 Caustic soda, 50% (approx.) 1.1 M a r l i n a t 242/70 4.5 Balance water, fragrance, dyestuff, perservative, sodium c h l o r i d e t o 100 A c t i v e matter: 8.0% SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes
  • 48.
    M w hi n g Detergents 25 D i shwashi nq Detergent, Medi um V i s c o s i t y . Basis Marlon PS-A % Marlon PS 65 49.0 Marlamid DF 1218 3.0 Ethanol * 4.0 Balance water, fragrance, d y e s t u f f , p r e s e r v a t i v e , Marl in a t 242/70 11.5 sodium c h l o r i d e t o 100 A c t i v e m a t t e r : 43.0% D i shwashi ng Detergent, Medi um V i s c o s i t y , Basis Marlon PS-B % Marlon PF 40 71.3 Balance water, fragrance, d y e s t u f f , p r e s e r v a t i v e , Marlamid DF 1218 1 . 5 sodium c h l o r i d e t o 100 A c t i v e m a t t e r : 30.0% * f u r t h e r products o f Huls AG D i shwashi ng Detergent, Medium V i scos t y . Basis Marlon Compounds-A % Marlon AFO 40 46.3 Marlamid D 1885 1.5 Balance water, fragrance, d y e s t u f f , p r e s e r v a t i v e , sodium c h l o r i d e t o 100 A c t i v e m a t t e r : 20.0% D i shwashi ng Detergent, Medi um V i s c o s i t y , Basis Marlon Compounds-B % Marlon AFO 50 30.0 Balance water, fragrance, d y e s t u f f , p r e s e r v a t i v e , sodium c h l o r i d e t o 100 A c t i v e m a t t e r : 15.0% SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and Cleaning Agents for Household Purposes
  • 49.
    26 Advanced CleaningRoductFormulations D i shwashi n Q Deteraent . Powdered. SDrav M i x i na Process-A % Marlox FK 64 1.o Sodium tripolyphosphate 40.0 Sodium m e t a s i l i c a t e pentahydrate 35.0 Sodium carbonate, dehydrated 22.0 Sodium dichloroisocyanurate 2.0 A c t i v e matter: 1.0% A p p l i c a t i o n : Use 3-5 g/1 water (depending on water hardness) D i shwashi ng Detergent, Powdered, Spray M i x i ng Process-I3 Marlox B 24/80 Sodium tripolyphosphate Sodium m e t a s i l i c a t e pentahydrate Sodium m e t a s i l i c a t e , dehydrated Sodium carbonate, dehydrated Sodi um d i c h l o r o i socyanurate Phosphonate HEDP, e.g. Sequion 10 Sodi um hydroxide A c t i v e matter: 1.0 A p p l i c a t i o n : Use 3-5 g/1 water Na 2 % 1.o 25.0 25.0 20.0 15.0 2.0 2.0 10.0 (depending on water hardness) D i shwashi ng Detergent, Powder, Phosphate-Free, Spray M i x i ng Process-A Marlox MO 154 Sodi um c i t r a t e d i hydrate Sodium d i s i l i c a t e granulate Polycarboxylate, e.g. Sokalan PA 40 granulate Sodium perborate monohydrate Tetraacetylethylenediami ne (TAED) Enzyme Esperase Sodium sesquicarbonate A c t i v e matter: 2.5% % 2.5 35.0 25.0 5 . 0 15.0 4.0 2.0 t o 100 Dishwashing Detergents, Powder, Phosphate-Free, Spray Mixing Process-I3 Marlox MO 154 Sodium carbonate, dehydrated Polycarboxylate, e.g. Permulsin SP Phosphonate HEDP, e.g. Sequion 10 Na 2 Sodi um metasi 1i c a t e A c t i v e matter: 2.0% % 2.0 15.0 10.0 5.0 t o 100 SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes
  • 50.
    DishwashingDetergents 27 DishwashtnLDeterpent (4096Sol ids)-A Witconate 1260 S l u r r y W i t c o l ate LES-6OA W i tcami de 128T Water % by W e i m 37.0 17.5 4.0 34.0 Blending Procedure: between each a d d i t i o n . Blend ingredients i n t h e order shown. mixing thoroughly Dishwashing Deteraent (40% Solids)-8 W i tconate 45LX W i tconate SXS L i q u i d Witcolate LES-6OA W i tcamide 128T Water % bv Weiqht 59.0 6.0 17.5 4.0 16.5 Blending Procedure: between each addition. Formula 105 Blend ingredients i n t h e order shown. mixing thoroughly Hand D i shwashi ng L i q u i d W i tconate AOS Witcolate S-1285C Witcamide 128T Water % by Weiaht 60.0 10.0 4.0 26.0 Blending Procedure: between each a d d i t i o n . Formula 106 SOURCE: Witco Corp.: Suggested Formulations Blend ingredi ents in the order shown, m i x i ng thorough1y
  • 51.
    28 Advanced CleaningR&t Formulations Dish Wash w/Ami ne Oxide/LABS/SLES Water, D . I . Witconate 30DS Varox 1770 W i t c o l ate SE-5 Blending Procedure: between each a d d i t i o n . Add Ethanol as needed t o Typical Properties: Viscosity, cps: 620 Solids: 16.8% pH: 9.12 Formula 117 Add ingredients i n order shown and d i s s l v e Dish Wash w / h i ne Oxide/LABS/ALES Water, 0.1. W i tconate 30DS Varox 1770 Witcolate LES-6OA Ethanol % by Weiqht 62.9 13.7 5.3 18.1 ompl e t e l y lower v i s c o s i t y . % by Weiaht 70.0 13.8 3.1 8.2 5.0 B1endi ng Procedure: Add ingredients i n order shown and dissolve completely between each a d d i t i o n . A c i d i f y w i t h C i t r i c Acid t o pH = 6.5. Typical Properties: Viscosity, cps: 4 Solids: 10.1% pH: 6.68 Formula 118 Dish Wash w/Ami ne Oxide/LABS Water, D . I . W i tconate 30DS Varox 1770 Ethanol % by Weiaht 69.8 20.3 4.9 5.0 Blending Procedure: Add ingredients i n order shown and dissolve completely between each a d d i t i o n . Typical Properties: Viscosity, cps: 4 Solids: 7.8% pH: 9.16 Formula 119 SOURCE: Witco Corp.: Suggested Formulations
  • 52.
    DishwashingDetergents 29 High-Performance HandDish Detergent Formula DW-0013 Water SXS, 40 Caustic Soda, 50% Dodecylbenzene s u l f o n i c Acid Rhodapex NA-61 A1 kamide DC-212/S Rhodacal A-246/L Rhodasurf 25-9 C i t r i c Acid (50%). t o pH 8 Ethanol SD-3A Preservative Fragrance Dye Wt.% 3.0 6.6 25.0 8.0 3.0 10.0 6.0 Q.S. 2.0 0.1 To 100 - Procedure Add t h e ingredients i n t h e order l i s t e d w i t h mixing. Mix u n t i l uniform a f t e r each a d d i t i o n . C i t r i c Acid and Caustic Soda are used f o r pH adjustment. Physical ProDerties Appearance: Clear gold l i q u i d , dyed t o preference pH. as i s : 8 Viscosity: 400 cps S p e c i f i c Gravity: 1.05 M i l d L i a u i d Hand Dish Detergent Water Caustic Soda (50%) Dodecylbenzene s u l f o n i c acid Miranol CS Conc. A1kamide DC-212/S Rhodasurf 25-9 Cheelox BF-13 C i t r i c Acid (50%). t o pH 8 Fragrance Dye Wt.% To 100 3 12 15 3 3 0.2 Q . S . - - Procedur e u n t i l uniform a f t e r each addition. C i t r i c a c i d and c a u s t i c soda are used f o r pH adjustment. Dissolve t h e dye i n water before a d d i t i o n . Phvsical Properties Appearance: Clear gold l i q u i d , dyed t o preference pH. as i s : 8 S p e c i f i c Gravity: 1.04 V i s c o s i t y : 150 cps Add t h e ingredients i n t h e order l i s t e d w i t h mixing. Mix SOURCE: Rhone-Poulenc Surfactants & S p e c i a l t i e s : Formulas
  • 53.
    30 Advanced CleaningProduct Formulations S t a r t i n g Formulations f o r Home Machine Dishwashinq Detergents 8.7% Phosphorous(A) Compounds: BASF S u r f a c t a n t * Sodium t r i p o l y p h o s p h a t e B r i t e s i 1 H24 hydrous sodium s i 1i c a t e * * Sodium s u l f a t e Sodium carbonate C h l o r i n a t e d isocyanurate*** Water 8.7% Phosphorous(B1 Coflpounds : BASF S u r f a c t a n t * B r i t e s i l H24 hydrous sodium s i l i c a t e * * Sodi um s u l f a t e Sodium carbonate C h l o r i n a t e d isocynaurate*** Sodium t r i p o l y p h o s p h a t e hexahydrate Nonphosphate Compounds2 BASF S u r f a c t a n t * Sokalan PABOCL B r i t e s i l ti24 hydrous sodium s i l i c a t e * * C h l o r i n a t e d t r i s o d i u m phosphate Sodium s u l f a t e Sodium carbonate Sodi um c i t r a t e d i hydrate ?4 b y WSi¶h_t. 3 34 17 15 19 2 10 % -by__W!sht 3 17 1 4 . 5 20 1 . 5 44 ”/._ bY. W!%lb t 4 . 0 2**** 20 1 2 . 5 30 1 . 5 30 * P l u r o n i c , P l u r a f a c , and I n d u s t r o l s u r f a c t a n t **Other r a t i o s o f Si02 can be used. L i q u i d s i l i c a t e s can a l s o be used i n p l a c e o f powders. ***Such as ACL-59. ****Active M i x i n g Procedures: gent, t h e f o l l o w i n g process i s suggested f o r t h e mixing of raw mater ia1s : 1 . Spray a m i x t u r e o f t h e s u r f a c t a n t and water ( o r s u r f a c t a n t , To achieve maximum c h l o r i n e s t a b i l i t y o f t h e formulated d e t e r - water, and l i q u i d s i l i c a t e ) onto t h e phosphate b u i l d e r s , soda ash, o r m i x t u r e t h e r e o f . S t i r continuously w h i l e spraying. w i t h simul-T h i s process r e s u l t s i n h y d r a t i o n o f t h e b u l d e r s taneous adsorption o f t h e s u r f a c t a n t . 2. Add t h e c h l o r i n e - c o n t a i n i n g compound and any f i l m i x t u r e and continue mixing u n t i l t h e e n t i r e m i x homogeneous. A d r y , f r e e - f l o w i n g granular produc obtained w i t h t h i s method. SOURCE: BASF Corp.: Suggested Formulations e r s t o t h e u r e i s should be
  • 54.
    -washing Detergents 31 Li g h t Duty L i q u i d Deteraents L i q u i d detergents based on P i l o t Calsoft, Calsuds and Calfoam s u r f a c t a n t s produce safe, e f f e c t i v e suds w i t h e x c e l l e n t grease- c u t t i n g p r o p e r t i e s f o r hand dishwashing. Detergents containing Calamide C are e s p e c i a l l y m i l d t o s e n s i t i v e skin. Water C a l s o f t L-60 Calfax DB-45 Cal foam EA-603 Calamide C C i t r i c Acid Perfume Ammonium Chloride Dye Calsuds A Cal foam ES-303 Water* C i t r i c Acid Perfume and Color C a l s o f t L-40 Cal foam EA-603 Calamide C P i l o t SXS-40 Water* C i t r i c Acid Perfume and Color Calsuds CD-6 Cal foam EA-603 P i l o t SXS-40 Cal s o f t LAS-99 Water* C i t r i c Acid Perfume and Color P i l o t Formula #LDL-010-01 % bv Weipht 61 .OO 19.80 9.90 5.00 3.00 0.10 0.10 0.10 1 .oo P i l o t Formula #LDL-013-01 % by Weiaht 70.00 10.00 20.00 Q.S. pH 7 Q . S . P i 1o t Formul a #LDL-005-01 % bv Weiaht 40.00 10.00 6.00 12.50 26.50 Q.S. pH 7 Q . S . P i 1o t Formula #LDL-015-01 % bv Weight 25.00 10.00 8.80 6.00 50.20 Q.S. pH 7 Q . S . *May be o p a c i f i e d by r e p l a c i n g 1% o f water w i t h 1% l a t e x opaci f ie r . Opaci f i e r should be d i 1uted w i t h water before a d d i t i o n . SOURCE: P i 1o t Chemi c a l Co. : Household C1eaner Formula t i on8
  • 55.
    32 Advanced CleaningPromcctFormulations L i g h t Duty Liauid. Premium Hand Dishwash Water, D . I . W i t c o l a t e SE-5 W i tconate 1260 S1u r r y W i tcami de 128T Petro LEA L i q u i d Sodium S u l f a t e Ethanol Formal i n Perfume, Dye % by Weight 30.2 36.7 5.0 1.9 2.6 1.8 0.1 q . s . 21.7 Blending Procedure: using C i t r i c Acid. Typical P r o p e r t i es : Blend i n g r e d i e n t s i n t h e order l i s t e d . Adjust pH = 6.5-7.0 V i s c o s i t y , cps: 230 Appearance: Clear L i q u i d Formula 113 L i g h t Duty L i q u i d Water, D. I. W i t c o l a t e SE-5 Witconate 1260 S l u r r y W i tcami de 128T Petro LEA L i q u i d Sodium S u l f a t e Sodium Chloride Formal in Perfume, Dye Economy Hand D i shwash % by Weiqht 73.6 8.3 13.5 1.9 1.o 0.6 1.o 0.1 q . s . 81ending Procedure: using C i t r i c Acid. Typi c a l P r o p e r t i es : Blend i n g r e d i e n t s i n t h e order l i s t e d . Adjust pH = 6.5-7.0 V i s c o s i t y , cps: 180 Appearance: C1ear L iqui d Formula 115 SOURCE: Witco Corp.: Suggested Formulations
  • 56.
    LXshwashing Detergents 33 Water CausticSoda (50%) L i a u i d Hand Dish Detergent Formula DW-0016 Wt.% Wt.% Wt.% To 100 To 100 To 100 2.5 3.3 4.1 Dodecylbenzene sui f o n i c a c i d 10 13 Rhodapex NA-61 4.5 4.5 A1kamide DC 212/S 1 2 Cheelox BF-13 0.5 0.5 C i t r i c Acid (50%), t o pH 8 Q.S. Q . S . Sodium c h l o r i d e 1 1 Fragrance - - Dye Opaci f ie r (Morton) - - - - 16 5 3 0.5 Q.S. 1 Procedur e Add t h e ingredients i n t h e order l i s t e d , w i t h mixing. Mix u n t i l uniform a f t e r each addition. C i t r i c a c i d and c a u s t i c soda are used f o r pH adjustment. Sodium c h l o r i d e b u i l d s v i s c o s i t y . Dissolve i t i n water before a d d i t i o n . Dissolve t h e dye i n water before a d d i t i o n . I f o p a c i f i e r i s used, i t should be d i l u t e d w i t h water before addition. A l l pH adjustments must be completed before t h e o p a c i f i e r i s added. Phvsical ProDertieg Appearance: Liquid, colored and o p a c i f i e d t o preference pH. as i s : 8 Viscosity: 200-400 cps Speci f ic Gravi t y : 1.02+-0.05 pH, 1%: 7.2 SOURCE: Rhone-Poulenc Surfactants & S p e c i a l t i e s : Formula
  • 57.
    34 Advanced CleaningProductFormulations Mechanical D ishwashi ng Detergent Chlorinated Formula DW-0009 Sodium Carbonate ( L t . Density) Antarox BL-330 Sodium Tripolyphosphate. Powder Sodium M e t a s i l i c a t e Pentahydrate Clearon CDB (FMC) Wt.% 41 . O 2.0 34.0 20.0 3.0 ProcedurQ Add t h e sodium carbonate t o t h e mixer. Spray on t h e Antarox EL 330. Add t h e remaining ingredients i n t h e order l i s t e d . Mix u n t i 1 uniform. Phvsical ProDertieg Appearance: White, free-flowing powder pH (1%): 11.2 S p e c i f i c Gravity: 0.70 Uechanic a l D ishwashing DeterQent L isuid Formula DW-0010 Igepal CO-730 Gantrez AN-149 Potassium Hydroxide (45% Active) Sodium S i l i c a t e (46% Active) Antarox BL-330 Tetrapotassium Pyrophosphate (60% Active) Water Wt.% 0.5 1.o 3.0 17.0 3.0 63.3 12.2 Proctndur e 1. Add Gantrez AN-149 t o Igepal CO-730/water mixture and s t i r a t room temperature u n t i l dissolved. Heat t o 45-50C i f not t o t a l l y i n s o l u t i o n . 2. Maintain heat a t 45C and add r e s t o f ingredients i n d i v i d u a l l y . Physical P r o m r t ieg pH (as i s ) : 13.2 pH (1%): 10.4 V i s c o s i t y : 1060 cps S p e c i f i c Gravity: 1.14 SOURCE: Rhone-Poulenc S p e c i a l t i e s 6 Surfactants: Formulas
  • 58.
    DishwashingDetergents 35 L ia u i d Formula DW-0008 Rhodacal A-246/L Rhodapex MA-460 Alkamide DC-212/S Sodium Xylene Sulfonate (40%) O p a c i f i e r (Morton) Water C i t r i c Acid t o pH 6.5-7.5 Perfume and Color Wt.% 60.0 10.0 5.0 4.0 1.0 20.0 Q . S . P.S. Procedure 1. Charge water and sodium xylene sulfonate t o vessel equipped w i t h a g i t a t i o n . u n t i 1 uniform. 2. Add Rhodacal A-246/L and Rhodapex MA-360 t o vessel and mix 3. Add Alkamide DC-212/S and mix as above. 4. Adjust pH 6.5-7.5 w i t h c i t r i c acid. 5. Add o p a c i f i e r ( o p t i o n a l ) , perfume and colorant, as desired. Physical P r o m r t i e s : Appearance: Clear gold l i q u i d , dye and opacify t o preference. pH, as i s : 6.5-7.5 S p e c i f i c Gravity: 1.02-1.04 V i s c o s i t y : 200-300 cps SOURCE: Rhone-Poulenc Surfactants EL S p e c i a l t i e s : Formula
  • 59.
    36 Advanced CleaningProductFormulations S t a r t i n a Formulations f o r Commercial Machine Dishwashing Deteraents Nonchlorine/Noncaustic BASF Surfactant* Sodium tripolyphosphate Sodium carbonate Sodium s u l f a t e Sodium m e t a s i l i c a t e pentahydrate Water Noncaustic BASF Surfactant* Sodium tripolyphosphate Sodium carbonate Sodium m e t a s i l i c a t e pentahydrate Chlorinated isocyanurate** Water C h l o r i n e K a u s t i c BASF Surfactant* Sodium tripolyphosphate Sodium carbonate Sodium m e t a s i l i c a t e pentahydrate Chlorinated isocyanurate** Sodium hydroxide (90%) Water *Pluronic, Plurafac, I n d u s t r o l surfactant **Such as ACL-59 % by Weight 3 34 22 11 25 5 % bv Weiaht 3 31.5 20 31.5 1.5 12.5 % bv Weiqht 3 34 18 22.5 2.5 15 5 M i x i ng Procedures : 1. Thoroughly mix t h e phosphate and carbonate. 2. I n a separate container, mix t h e surfactant and water. Next, spray th'is l i q u i d onto the phosphate/carbonate mixture. Mix continuously w h i l e spraying, and continue mixing u n t i l t h e l i q u i d i s completely adsorbed and t h e mixture i s homogeneous. 3. Add t h e m e t a s i l i c a t e , s u l f a t e , and/or caustic and mix. 4. F i n a l l y , add t h e c h l o r i n a t e d cyanurate and mix thoroughly. Note: maximum c h l o r i n e s t a b i l i t y . SOURCE: BASF Corp.: Suggested Formulations The mixing sequence given above i s necessary f o r maintaining
  • 60.
    5. General PurposeCleaners 37
  • 61.
    38 Advanced CleaningRoductFormulatioiu A11 Purpose Cleaner Mackam 2CSF Tetrapotassium Pyrophosphate T r i sodium Polyphosphate KOH (45%) Low Rosin T a l l O i l F a t t y Acid Deioni zed Water Weight.% 10.0 5.0 5.0 4.0 10.0 66.0 Procedure: 1. Dissolve Tetrapotassi um Pyrophosphate and T r i sodi um Po 2. Add KOH. 3. Disperse T a l l O i l F a t t y Acid. 4. Cool t o 50C and slowly add Mackam 2CSF. phosphate a t 70C. PhosDhate Free A l l PurDose Cleaner Sodium M e t a s i l i c a t e Pentahydrate Mackamine C-10 Caustic Soda (50%) Mackam 2CYSF Tetrasodium EDTA (40%) Deioni zed Water Y- Weight .% 22.0 9.0 2.0 4.0 1.o 62.0 Procedure: 1. Add Sodium M e t a s i l i c a t e and Tetrasodium EOTA t o water and 2. Add Mackamine C-10 and Caustic Soda (50%). 3. Add Mackam 2CYSF and blend u n t i l c l e a r . heat t o 60C. Bathroom T i l e Cleaner Sodium Hypochlorite (35%) Mackamine LO Tetrasodi um EDTA Deioni zed Water Procedure: Add components t o water and blend u n t i l c SOURCE: McIntyre Qroup Ltd.: Suggested Formu Wei aht .% 4.7 5.0 1.o 89.3 ear. a t i one
  • 62.
    Water Sodi um Carbonate TetrasodiumEDTA, 40% W i t c o l a t e 7031 Sodium Chloride W i tconate SXS L i q u i d C i t r i c Acid, 50% A l l Purgose Cleaner % bv Weiqht 61.2 5.0 6.0 15.0 10.8 2.0 9.s. t o pH=11.0-11.5 Blending Procedure: Typical Properties: V i s c o s i t y , cps: Water t h S o l i d s : 25.6% pH, as i s : 11.2 Blend i n g r e d i e n t s i n t h e order l i s t e d . n SOURCE: Witco Corp.: Formula 518 All-PurDose Cleaner Eastman E8 solvent Na4EDTA* Nonionic s u r f a c t a n t * * Isopropyl alcohol Water *Tetrasodi um e t h y l enedi ami n e t e t r a c e t a t e **Such as Neodol 23-7 alcohol ethoxylate N-95 ethoxylated nonylphenol (Texaco). Hard-surface Cleaner Eastman DB solvent Anionic surfactant*** N a4EDTA* *** Ammonium Hydroxide (28%) Water 2. 2 1 90 39%) S h e l l ) o r Sulfon % bv Weisht 3.2 7 3 5 3 C % bv Weiaht 7.0 1 .o 1.25 2.0 88.75 ***Such as Rhodapex CO-433 (Rhone-Poulenc) ****Tetrasodium ethylenediaminetetraacetate (39%) SOURCE: Eastman.Chemica1 Co.: Eastman EB and D0 Solvents f o r Cleaners: Suggested Formulations GeneralPurpose Cleaners 39
  • 63.
    40 Advanced CleaningProductFormulations A11-Purpose C1eaner-A % Marl i p a l 24/90 7.5 Methoxypropanol 6.0 Sodium carbonate 3.0 N i t r i l o t r i a c e t a t e , 40% 0 . 4 Balance water, fragrance, dyestuff, preservative, sodium c h l o r i d e t o 100 Active matter: 7.5% V i s c o s i t y : L i q u i d A11-PUrDOSe C l e a n e r 4 % M a r l i p a l 1012/6 1.o M a r l i n a t 242/28 10.0 Sodium carbonate 3.0 Sodium c i t r a t e dihydrate 1.5 Sodium t a r t r a t e 1.5 Balance water, fragrance, dyestuff, preservative, sodium c h l o r i d e t o 100 Active matter: 3.8% V i s c o s i t y : Low Al1-PUrDOSe Cleaner. w i t h Y i c r o b i c i d a l Prooerties. Liauid-B Marl ip a l 013/99 Warlazin KC 21/50 Nit ri1o t riacetate, 40% Sodium carbonate Balance water, fragrance, d y e s t u f f % 8.0 5.0 0.5 3.0 t o 100 Active matter: 9.7% SOURCE: Huls America, Inc.: Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes
  • 64.
    GeneralPurpose Cleaners 41 A-Jl-PurposeCleaner, Liquid-A Marlon PS 65 Marl ip a l 013/69 Coconut f a t t y a c i d C i t r i c terpene Methoxypropanol Sodium carbonate Sodium c i t r a t e d i h y d r a t e Ethylenediamine t e t r a a c e t a t e , 40% Balance water, fragrance, d y e s t u f f , p r e s e r v a t i v e A c t i v e matter: 3.1% A l l -Pu_rpose C1eaner , L iqui d-6 Marl ip a l 013/69 C i t r i c terpene Methoxypropanol Sodi um carbonate C i t r i c a c i d N i t r i l o t r i a c e t a t e , 40% KNA cumene sulphonate 40 Balance water, fragrance, d y e s t u f f , p r e s e r v a t i v e A c t i v e matter: 4.5% % 3.0 1 .o 0.2 2.0 3.0 3.0 3.0 0 . 2 t o 100 '16 5 . 0 0.2 5 . 0 3.0 1 .o 0 . 2 1 . o t o 100 All-Purpose CleaKer, w i t h - M i c r o b i c i d a l Properties, Liquid-A Marl ip a l 013/99 N i t r i l o t r i a c e t a t e , 40% Lonzabac 12.30 Sodium carbonate KNA cumene sulphate 40 Balance water, fragrance, d y e s t u f f % 7.5 2.0 3.0 3.0 2.0 t o 100 A c t i v e matter: 6.8% SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes
  • 65.
    42 Advanced CleaningproductFormulations All-Purpose Cleaner, Pastv-A Marlon AS3 Caustic soda, 50% (approx.) Marl inat 242/28 Marl ip a l 013/30 Tylose CBR 10000 Titanium d i o x i d e Sodium c h l o r i d e (approx.) Balance water, fragrance, p r e s e r v a t i v e A c t i v e matter: 18.0% A11-Purpose Cleaner , Marlon PF 40 M i lip a l 013/30 Marlamid DF 1218 Tylose CBR 10000 Titanium d i o x i d e Sodium c h l o r i d e (approx.) Balance water, fragrance, p r e s e r v a t i v e A c t i v e matter: 22.0% 96 10.0 2.6 15.5 3.0 4.0 0.1 2.0 t o 100 Pastv-B % 45.0 2.0 2.0 4.0 0.1 8.0 t o 100 All-Purpose Cleaner, W i t h Soap, High Viscosity-A % Marlon PF 40 5.0 O l e i c a c i d 10.0 Caustic potash, 50%* (approx.) 3.9 Potassium carbonate* 1 .o Ethylenediamine t e t r a a c e t a t e , 40% 0.2 Balance water, fragrance, d y e s t u f f , p r e s e r v a t i v e t o 100 A c t i v e matter: 12.8% All-Purpose Cleaner. W i t h Soap. High Viscositv-B Marl ip a l 24/79 Marl ip a l 242/28 O l e i c Acid Caustic potash, 50%* (approx.) Sodi um c i t r a t e d i hydrate Ethylenedi amine t e t r a a c e t a t e , 40% Ethanol* Balance water, fragrance, d y e s t u f f , p r e s e r v a t i v e A c t i v e matter: 11.8% 96 2.0 5.0 8.0 3.1 1.5 0.2 1.5 t o 100 SOURCE: Huls America, Inc.: Basic Formulations o f Detergents and Cleaning Agents f o r Household Products
  • 66.
    General Purpose Cleaners43 D-Lilnonene Emulsifiable Concentrate Formul a HS-0094 Component D-Li monene Rhodacal I PAM Igepal CQ-720 T r i ethanol ami ne Wt.% 80.0 1 5 . 0 4 . 0 1 .o Procedure Phvsical Prooerti es Blend ingredients i n order l i s t e d and m i x u n t i l uniform. Appearance: Clear, yellow l i q u i d S p e c i f i c Gravity: 0.9 V i s c o s i t y : t10 cps pH, as i s : 10.0 Note: Product forms milky white emulsions when d i l u t e d w i t h water. D-Limonene All-PurDose Cleaner Formula HS-0033 Comoonent: Water Sodium Metasilicate-Pentahydrate Miranol FBS Rhodasurf 91-6 Cheelox BF-13 A1kamide DC-212/M D-Li monene Wt.% 73.5 2.0 10.0 3.5 5.0 3.0 2.0 Procedur e Blend ingredients i n order l i s t e d and m i x u n t i l uniform. Phvsicsl Pronerties Appearance: S l i g h t l y hazy, yellow l i q u i d pH, as i s : 1.25 S p e c i f i c Gravity: 1.02 V i s c o s i t y : <I0 cps SOURCE: Rhone-Poulenc Surfactants 81 Specialties: Formulas
  • 67.
    44 Advanced CleaningRorluct Formulations General C1eaners Cleaner-Household I n s r e d ients: Tetrapotassium Pyrophosphate Dodecylbenzene Sul fonate T r i ethanol ami ne S a l t Aerosol A-103 Surfactant Lauric Diethanolamide Sodium Xylene Sulfonate Mix a l l o f t h e above together a t one time. A1k a line Cleaner I n s r e d ients: Aerosol 0s Surfactant Sodium Metasi 1icate Caustic Soda Tetrasodi um Pyrophosphate T r i sodi um Phosphate L i a u i d Hand Cleaner Insredients: Aerosol A-102 Surfactant Mineral O i l Coconut O i l n-Propanol o r Isopropanol Triethanolamine Germicide Water % by Weiaht 8 . 0 4.0 4.0 2.0 7 6 . 0 % bv Wei aht 5 . 0 50.0 5.0 7 . 0 3 3 . 0 % by Weiaht 60.0 10.0 5 . 0 5 . 0 0.5 0.1 19.4 Germicidal C1eaner Inaredi ents: % bv Weiaht Aerosol 22, Aerosol 0s. Aerosol A-102 Surfactant o r mixture 10.0 Tetrapotassium Pyrophosphate 7.0 Dowicide 32 5 . 0 Isopropanol 3 . 0 Water 7 5 . 0 SOURCE: Cytec I n d u s t r i e s Inc.: Suggested Formulations
  • 68.
    General Purpose Cleaners45 Hiph-Performance General Purpose Cleaner Concentrate Formula HS-0038 Water STPP (Anhydrous Granular) Rhodapon UB Rhodapon BOS A1codet HSC-1000 Butoxyethanol Miranol FBS Procedur e Blend ingredients i n order 1 Phvsical ProDertles Appearance: Clear, l i g h t ye1 pH, as i s : 9 . 4 S p e c i f i c Gravity: 1.06 V i s c o s i t y : t10 cps sted ow 1 and mix unt q u i d Heavy-Dutv Cleaner Powder Formula HS-0039 Wt.% 65.0 6.0 13.0 5.0 5.0 4 . 0 2 . 0 1 uniform. Trisodium Phosphate o r Sodium Carbonate Sodium S i 1icate Rhodacal DS-10 Sodium S u l f a t e Fragrance Procedur g uniform. Physical ProDerti es Add ingredients i n order l i s t e d t o powder blender Appearance: Whi t e , f ree-f 1owi ng powder pH, 1% Solution: 10.8 Wt.96 40 10 20 30 Q.S Mix u n t i l SOURCE: Rhone-Poulenc Surfactants & Specialties: Formulas
  • 69.
    46 Advanced CleaningPr&tFormulations N e u t r a l A11-PurDose C1eaner, w i t h Pearlescence High V i scosi t y - A Marlon PS 65 Marl inat 242/28 Marlamid DF 1218 Marlamid PG 20 Cellobond HEC l O O O O O A Balance water, fragrance, d y e s t u f f , p r e s e r v a t i v e A c t i v e matter: 7.2% E f f e c t , 96 7.5 4.5 1.o 2.0 0.7 t o 100 N e u t r a l All-PUrDOSe Cleaner, w i t h Pearlescence E f f e c t . H iah V i scosi ty-B M a r l i n a t OFK 30 Marl in a t 242/28 Marlamid DF 1218 Marl ip a l 24/90 Marlamid PG 20 Cellobond HEC lOOOOOA Balance water, fragrance, A c t i v e matter: 5.0% 96 5.0 2.0 1.o I .o 1.o 0.9 d y e s t u f f , p r e s e r v a t i v e t o 100 A1l-PUrDOSe Cleaner, w i t h A c e t i c A c i d - A M a r l i p a l 1012/6 M a r l i n a t 242/28 Sodium c i t r a t e d i h y d r a t e A c e t i c a c i d * Sodi um c h l o r i d e (approx. ) Balance water, fragrance, d y e s t u f f A c t i v e matter: 5.7% V i s c o s i t y : low A11-PUrDOSe Cleaner. w i t h A c e t i c Acid-B Marlon PS 65 A c e t i c acid* Balance water, fragrance, d y e s t u f f A c t i v e matter: 3.3% V i s c o s i t y : 1i q u i d * f u r t h e r products o f Huls AG 96 1.5 15.0 1.o 2.0 6.5 to 100 s6 5.0 6.0 t o 100 SOURCE: Huls America, Inc. : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes
  • 70.
    General Purpose Cleaners47 Non-PhosDhate A l l PurDose Cleaner Components: Water 45% KOH Burcosperse AP L i q u i d Sodium Xylene Sulfonates 40% Sodi um C i t r a t e Dodecylbenzene S u l f o n i c Acid Burco TME Butyl Propasol Varsol o r Mineral S p i r i t s % by Weight 77.15 0.75 3.00 3.40 1.oo 1.75 6 . 0 0 6 . 0 0 0.95 Procedure: between each a d d i t i o n . Add components i n t h e order l i s t e d . Blend u n t i l uniform O i l S D l i t t i n s General PurDose Cleaner Components: Water Sodium M e t a s i l i c a t e Pentahydrate Burco ADS-40 Burco TME Burco LAA-38 Burco EHS % by Wei Qht 82.5 5.0 2.5 5.0 2.5 2.5 Procedure: Add components i n t h e order l i s t e d . Blend u n t i l f u l l y diss- olved between each addition. This i s a use as i s formulation f o r heavy duty cleaning. For l i g h t e r duty applications, d i l u t i o n w i t h water may be possible. This formulation w i l l suspend o i l t o a s s i s t w i t h removal. The suspended o i l w i l l then f l o a t f o r easy removal. SOURCE: B u r l ington Chemical Co., I n c . : Suggested Formulations
  • 71.
    48 Advanced CleaningProductFormulations Scouri ng Cleaner, Mediurn V i scosi tv-A Marlon PS65 Marl ipal 013/30 Sodium sulphate Calcium carbonate, e.g. Durcal 40 Balance water, dyestuff, fragrance, preservative Active matter: 5.5% Scouring Cleaner. Mediurn V i scosi t y - B Marlon PS 65 M a r l i p a l 013/30 Marl inat 242/28 Sodium carbonate Calcium carbonate, e.g. Durcal 40 Balance water, d y e s t u f f , fragrance, preservative Active matter: 5.8% Scouring Cl-eaner. Powder-A Marlon ARL Sodium carbonate, dehydrated Sodi um d i c h l o r o i socyanurate Calci um carbonate powder (abrasive) Active matter: 4.0% % 4.3 2.7 1.5 50.0 t o 100 % 3.5 3.0 2 . 0 1.5 5 0 . 0 t o 100 % 5.0 5.0 1.o t o 100 Scouring Cleaner, Powder-B % Marlon ARL 5.0 Sodium carbonate, dehydrated 5.0 Sodium tripolyphosphate 2.0 Calcium carbonate powder (abrasive) t o 100 Active matter: 4.0% SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes
  • 72.
  • 73.
    50 Advanced CleaningRoductFormulations A n t i f o g Compositions f o r A p p l i c a t i o n t o C l o t h Special wiping c l o t h s impregnated w i t h Aerosol OT Surfactant are used t o clean and t o prevent fogging o f eye glasses, b i n - oculars, goggles, eyepieces i n gas masks, and automobile, t r a i n , plane, and boat windshields. Such wiping c l o t h s are prepared by impregnating c o t t o n f l a n n e l w i t h Aerosol OT Surfactant s o l u t i o n s followed by a run through squeeze r o l l s t o remove t h e excess 1iquor . a t 25% s o l i d s and one formulation a t 50% s o l i d s are as f o l l o w s : Three successful formulations containing Aerosol OT Surfactant Ingredients-1 : Aerosol OT-75% Surfactant ( l b . ) Varsol No. 2 Petroleum Solvent ( g a l . ) Isopropyl Alcohol ( g a l . ) Water ( g a l . ) Inaredi ents-2 : Aerosol OT-75% Surfactant ( l b . ) Varsol No. 2 Petroleum Solvent ( g a l . ) Isopropyl Alcohol ( g a l . ) Water ( g a l . ) I n ~ r e d i e n t s - 3 : Aerosol OT-75% Surfactant ( l b . ) Varsol No. 2 Petroleum Solvent ( g a l . ) Isopropyl Alcohol ( g a l . ) Water (gal . ) Inqredients-4: Aerosol OT-75% Surfactant ( l b . ) Varsol No. 2 Petroleum Solvent ( g a l . ) Isopropyl Alcohol ( g a l . ) Water ( g a l . ) 25% S o l u t i o n 113 15 3 19 25% S o l u t i o n 113 6 6 25 25% S o l u t i o n 113 - 8 29 50% S o l u t i o n 66 2 3 - The solvents and water are mixed a t 80F t o 1OOF. The Aerosol OT-75% Surfactant i s added slowly w i t h continued mixing. A f t e r t h e Aerosol OT has dissolved, a l l s o l u t i o n s w i l l remain c l e a r and l i q u i d a t temperatures as low as 5OF. No scumming o f t h e surface w i l l occur because o f evaporation d u r i n g a normal run o f c l o t h through t h e bath. The s o l u t i o n s t h a t are allowed t o stand should be covered t o prevent l o s s o f solvent. The optimum amount o f Aerosol OT Surfactant t o be l e f t on t h e c l o t h i s 40-50%, based on t h e weight o f t h e c l o t h . However, a range o f 25-50% w i l l g i v e s a t i s f a c t o r y r e s u l t s . SOURCE: Cytec I n d u s t r i e s Inc.: Suggested Formulations
  • 74.
    Glass CleanerslPolishes 51 An t i f o g Compositions f o r D i r e c t Application t o Glass Aerosol OT Surfactant i s used i n special formulations t h a t are applied d i r e c t l y t o glass surfaces t o prevent fogging under ad- verse weather conditions. Some o f these formulations g i v e dur- able f i l m s t h a t stand up under severe t e s t s . An example o f an excel l e n t "Anti fog" paste i s as follows: Aerosol OT-75% Surfactant Gum Tragacanth Petrolatum Water 10.7 l b . 2.0 l b . 2.0 l b . 85.3 l b . Heat t h e water t o 18OF and add t h e Aerosol OT-75% slowly w i t h mixing. S i f t i n powdered gum tragacanth. Continue mixing u n t i l a l l gum i s dispersed, cool t o 105F, and add petrolatum. Application o f A n t i f o g Paste: Dampen t h e corner of a piece o f c l o t h w i t h paste and rub over e n t i r e glass surface. Before f i l m becomes dry, p o l i s h w e l l w i t h clean p o r t i o n o f t h e c l o t h . A spray bomb o f A n t i f o g may be prepared as follows: Aerosol OT-75% Surfactant Butyl Cellosolve Solvent Propel 1ant 10 p a r t s 10 p a r t s 80 p a r t s Aerosol OT Surfactant may a l s o be cast i n t o s t i c k form. Softening agents such as glycerine o r ethylene g l y c o l are incorporated t o s i m p l i f y a p p l i c a t i o n t o t h e glass surface. Such s t i c k s , usually two t o f o u r inches long and one-half inch i n diameter, are sold i n k i t s f o r a p p l i c a t i o n t o goggles, w i ndshie l d w i pes and bthroom m i r r o r s . SOURCE: Cytec I n d u s t r i e s , Inc.: Suggested Formulations
  • 75.
    52 Advonced Cleoningproduct FormulotiOnr Water, D . I . Isopropanol Adogen 66 Varox 365 Emcol 4500 Anti-Foggina. A n t i - S t a t i c Glass Cleaner % bv We Blending Procedure: Combine ingredients i n t h e order shown and mix thorough I f product i s hazy, a d d i t i o n a l Isopropanol can be used t o c l a r i f y t h e s o l u t i o n . Gentle heating can be used t o f a c i l - i i t a t e mixing o f t h e Emcol 4500. Use I n s t r u c t i o n s : sht 0.0 9.0 0.1 0.5 0.4 Y. Apply f i n i s h e d product t o a t o w e l l e t e (Kimwipe, e t c . ) and wipe onto t h e glass. Allow t o dry. Product Informat Product: Varox 365 Adogen 66 Emcol 4500 This formulat on : B e n e f i t : Wetting agent, degreaser. and detergent A n t i - s t a t i c agent Wetting agent, coupler, and detergent on presents a t h i n b a r r i e r between t h e water vapor ( i . e . , fog, steam, e t c . ) and t h e glass which w i l l prevent fogging. The a b i l i t y t o lower t h e surface tension o f t h e water prevents t h e c l i n g i n g o f i n d i v i d u a l water d r o p l e t s t o t h e glass; t h e r e f o r e l i g h t i s not scattered as much as i t i s when passing through i n d i v i d u a l droplets. Formula 708 Annoniated Glass Cleaner Water W i t c o l a t e 2310 Butyl Cel l o s o l v e Aqua Ammonia, 26 Be' % by Weight 94.0 3.0 2.0 2.0 Blending Procedure: between each a d d i t i o n . Formula 704 SOURCE: Witco Corp.: Suggested Formulations Blend ingredients i n t h e order shown, mixing thoroughly
  • 76.
    Glass CleanersfPolbhes 53 GlassC1eaners Ammonia Formula GC-0017 Water Rhodacal DSB Butoxyethanol Ammonium Hydroxide (28%) Dye Economical Heavy-Duty Wt.% Wt.% 94.60 88.70~~ 0.15 0.30 5.00 10.00 0.25 1.oo - - ProcedurQ Blend ingredients i n order l i s t e d and mix u n t i l uniform. Phvsica1 Prooerties Appearance: Clear l i q u i d , dye t o preference pH (as i s ) : 10.5 pH (1%): 9.0 S p e c i f i c G r a v i t y : 0.99 V i s c o s i t y : t10 cps 10.8 9.7 0.99 t10 cps G1ass C1eaners Vinegar Formula GC-0018 Water Rhodacal DSB Butoxyethanol Acetic Acid Dye Economical Heavv-Duty Wt.% Wt.% 94.85 89.70 0.15 0.30 5.00 10.00 To pH=4 To pH=4 - - ProcedurQ Blend ingredients i n order l i s t e d and mix u n t i l uniform. Physical Prooerti eg Appearance: Clear l i q u i d , dye t o preference pH (as i s ) : 4.0 4.0 pH (1%): 3.5 3.5 Speci f ic Gravity: 0.99 0.99 V i scosl t y : t10 cps t10 cps SOURCE: Rhone-Poulenc Surfactants 6 S p e c i a l t i e r : Formulas
  • 77.
    54 Advanced CleaningRoductFormulations Glassware and B o t t l e Cleaners B o t t l e Cleaner (Alkaline-Powder) Inaredi ents: Aerosol OT-8 Surfactant Sodium NTA Powder Cyanamer A-100L Polyacrylamide Sodi um Metasi 1icate Tetrasodium Pyrophosphate B o t t l e Cleaner (Acid-Powder) Inaredients: Aerosol OT-0 Surfactant NTA Acid Sodium Dihydrogen Phosphate Sodium Hydrogen S u l f a t e B o t t l e Cleaner (A1 k a line-Powder) Inaredients: Aerosol 0s Surfactant Aerosol OT-8 Surfactant Sodium NTA Powder Sodi um Metasi 1icate Tetrasodi um Pyrophosphate % by Weiaht 2.0 20.0 5.0 8.0 65.0 % by Weiaht 2 . 0 20.0 58.0 20.0 % bv Weiaht 5-1 0 1- 2 20.0 8.0 60-66 B o t t l e C1eaner ( A c i d-Li quid) Inaredients: Aerosol GPG Surfactant Phosphoric Acid (85%) NTA Acid Water % by Weiaht 5.0 t o pH 3.0 or l e s s 20.0 75.0 B o t t l e C1eaner (Acid-Liqui d l Inaredi ents: Aerosol 0s Surfactant NTA Acid Phosphoric Acid (85%) Water % bv Weight 10.0. . 20.0 t o pH 3.0 o r l e s s 70.0 B o t t l e Cleaner (Hiahly Alkaline) % bv WeiahtInaredi ents : Aerosol 0s Surfactant 10.0 Aerosol 22 Surfactant 2.0 Sodium NTA 20.0 Sodi um Hydroxi de ( 1 0%) 68.0 SOURCE: Cytec I n d u s t r i e s Inc.: Suggested Formulations
  • 78.
    Glass CleanerslPolishes 55 Water,D . I . Isopropanol Varox 365 Methylene B1ue Household Window Cleaner % by Weight 89.3 10.0 0.7 q . s . Blending Procedure: between each addition. Typical Properties: Viscosity, cps: 4 Solids: 0.2% pH: 7.4 Add ingredients i n order shown and dissolve completely Formula 706 Prerniurn Household W i ndow C1eaner Water, D . I . Isopropanol Varox 1770 Methylene 81ue % by Weight 89.4 10.0 0 . 6 q . s . Blending Procedure: between each a d d i t i o n . Typical Properties: V i s c o s i t y , cps: 4 Solids: 0.23% pH: 6.2 Add ingredients i n order shown and dissolve completely Formula 707 SOURCE: Witco Corp.: Suggested Formulations
  • 79.
    56 Advanced CleaningProductFormulations Low VOC Antistat/Cleaner f o r Glass I n q r e d i e n t : Versaf 1ex 7000 Isopropanol Ammonium Hydroxide (30%) Neodol 25-35 (58%) Water, Fragrance, and Preservative %w/w 1 .oo 5.00 0.50 0.15 q . s . Procedure: 1. Dissolve Versaflex 7000 i n water. 2 . Add ammonium hydroxide and Neodol 25-35, and mix. 3. Add isopropanol and mix. 4. Add fragrance and preservative. SOURCE: National Starch and Chemical Co.: Reference: #8069:32 A n t i -Fog G1ass C1g a s I n q r e d ients:_ Water Monawet MO-70R IPA Procedure: Blend i n order l i s t e d and package. % by We- 93.0 2.0 5.0 SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formulation G1ass C1eaner Eastman EB solvent Isopropyl alcohol Nonionic s u r f a c tant* Water % by We- 3.0 5.0 0.1 91.9 *Such as T e r g i t o l 15-S-7, Cll-C15 secondary alcohol e t h o x y l a t e (Union Carbide) o r Genapol 24-L-60 l i n e a r alcohol ethoxylate (Hoechst Celanese). SOURCE: Eastman Chemical Co.: Eastman EB and DB Solvents f o r Cleaners: Suggested Formulation
  • 80.
    Glass CleaturslPolisks 57 Tr a d i t i o n a l Consumer Glass Cleaner Ammoniated Anionic Non-Streaki na G1ass C1eaner-Inaredient : Wt.% Deionized Water 94.05 2-Butoxyethanol 5.70 Avanel S-70 0.25 C . I . D i r e c t Blue #86 Q.S. Monoethanolami ne t o pH 10.5-11.5 pH (as i s ) : 10.5-11.5 Appearance: Clear, l i g h t - b l u e l i q u i d Odor: Sweet, ethereal Charge under a g i t a t i o n most o f t h e water, t h e 2-butoxyethanol. Procedure: and t h e Avanel S-70 i n t o t h e mixing vessel. I n a separate vessel, under a g i t a t i o n , dissolve t h e dye i n t h e balance of t h e water. Add t h e dye s o l u t i o n t o t h e batch. Adjust p H t o 10.5-11.5 w i t h Monoethanolamine. Notes : This formulation incorporates a novel anionic surfactant i n t o a t r a d i t i o n a l ammoniated glass cleaner. On prolonged storage, g l y c o l ethers have been shown t o form peroxy compounds which can adversely a f f e c t t h e dyes normally used i n glass cleaners. Morpholine, Ammonia, o r other v o l a t i l e amines may be used i n place o f t h e Monoethanolamine. Formula CG-101 Consumer Aci d G1ass C1eaner Acid Anionic Non-Streaking Glass Cleaner I n s r e d ient : Wt.% Deioni zed Water 89.70 2-Butoxyethanol 10.00 Avanel S-70 0.30 Color Q.S. Acetic Acid t o p H 3.5-4.0 pH (as i s ) : 3.5-4.0 Appearance: Clear 1i q u i d Odor: Sweet, ethereal Charge under a g i t a t i o n most o f the water, t h e 2-butoxyethanol, Procedure: and t h e Avanel S-70 i n t o the mixing vessel. I n a separate vessel, under a g i t a t i o n , dissolve the dye i n t h e balance o f the water. Add t h e dye s o l u t i o n t o t h e batch. Adjust p H t o 3.5-4.0 w i t h Acetic Acid. Notes: This formulation i s p a r t i c u l a r l y e f f e c t i v e a t removing o i l . greases and other atmospheric contaminants from glass surfaces. On prolonged storage, g l y c o l ethers have been shown t o form peroxy compounds which can adversely a f f e c t t h e dyes normally used i n glass cleaners. Dyes should be thoroughly screened f o r s h e l f s t a b i l i t y i n t h e f i n i s h e d product p r i o r t o adoption i n t o t h e f i n i s h e d formulation. Formula CG-102 SOURCE: Mazer Chemicals: Suggested Formulations
  • 81.
    7. Hard SurfaceCleaners 58
  • 82.
    Hard swface Cleaners59 Abrasive Cleaner-1 I n a r e d i e n t s : A Hostapur SAS 60 Genapol UD-030 B Water (40-5OC) C Preservative D C a l i b r i t e SL Tests: Perfume V i s c o s i t y (mPas): 1700 ( B r o o k f i e l d RVT) pH: 1 0 , O Abrasive C1eaner-2 1.n qr e dients : A Hostapur SAS 60 Genapol UD-030 B Water (40-50C) C Preservative Perfume D C a l i b r i t e SL Tests: V i s c o s i t y (mPas): 2800 ( B r o o k f i e l d RVT) pH: 1 0 , O Abrasive C1eaner-3 I n s r e d i e n t s : A Hostapur SAS 60 Genapol UD-030 B Water (40-5OC) C Preservative Perfume D C a l i b r i t e SL 4.50% 5.40% 59.00% 0.10% 0.20% 30.00% 4.50% 5.40% 49.00% 0.10% 0.20% 40.00% 4.50% 5.40% 39.00% 0.10% 0.20% 50.00% Tests: Manufacturing(l,2,3): I One a f t e r another, t h e components o f A are added t o 0. I1 A t 30C t h e components o f C a r e added t o I. I11 A t l a s t , s t i r D to 11. any longer. Modern l i q u i d products a r e based on calcium carbonate. SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Detergents and Cleaning V i s c o s i t y (mPas) : 6400 (Brookf ie l d RVT) pH: 1 0 , O O Abrasive powders, based on s i l i c i u m dioxyde a r e n o t common Agents: Guide Formulations
  • 83.
    60 Advanced CleaningproductForrnulaiions Concentrated L i q u i d Household Hard-surface Cleaner P i ne O i 1 A11-Purpose D i l u t a b l e Concentrate Inaredi ent : Deioni zed Water Macol TD-12 Macol TD-3 Mazamide 80 Macol 40 Pine O i l Tetrapotassium Pyrophosphate Sodium M e t a s i l i c a t e Pentahydrate Sodium Xylene Sulfonate (40%) Wt.96 79.30 5.00 2.50 0.50 4.00 0.20 3.00 2.00 3.50 pH (as i s ) : 12.5-13.5 Appearance: Clear, l i g h t - y e l l o w l i q u i d Speci f ic Gravity: 1.03 Procedure: Charge t h e water t o a mixing vessel and s t a r t a g i t a t i o n . Charge t h e Macol TD-12, Macol TD-3. and Macol 48 and m i x u n t i l product i s c l e a r and f r e e o f " f i s h eyes." Charge t h e Pine O i l and mix 5 minutes. Charge t h e remaining ingredients and mix u n t i l c l e a r . Notes: This i s a concentrated household hard-surface cleaner designed t o be used a t a d i l u t i o n o f 1-3 ounces per gallon. Formula CH-103 All-PurDose Household Spray Cleaner Ready t o Use A l k a l i n e Hard Surface Spray Cleaner Ineredi ent : Deioni zed Water Macol TD-12 Sodi um C i t r a t e Tetrapotassium Pyrophosphate Macol 48 Wt.96 95.15 1.oo 0.25 0.60 3.00 pH (as i s ) : 9.5-10.5 Appearance: Clear, water-white l i q u i d S p e c i f i c Gravity: 0.99 Charge t h e water t o a mixing vessel and s t a r t a g i t a t i o n . Procedure: Charge t h e Macol TD-12 and mix u n t i l dissolved and f r e e o f " f i s h eyes.'' Charge t h e remaining ingredients and m i x u n t i l c l e a r . Notes : This i s an all-purpose household cleaner designed t o be used "as i s " from a spray b o t t l e . Formula CH-104 SOURCE: Mazer Chemicals: Suggested Formulations
  • 84.
    Hard Surface Cleaners61 Consumer T i 1e C1eaner A Hard Surface Hypochlorite Spray Cleaner Inpredient: Deioni zed Water Sodium Hydroxide (50%) Sodium Hypochlorite (12.5%) Avanel S-70 Wt.% 81 .OO 2.00 18.00 1.oo pH (as i s ) : >12.5 Appearance: Clear, water-white t o l i g h t - y e l l o w l i q u i d Charge t h e ingredients w i t h a g i t a t i o n i n t h e order l i s t e d . This formula i s s u i t a b l e f o r pump spray a p p l i c a t i o n . I t can Shelf s t a b i l i t y o f c h l o r i n e cleaners i s dependent on t h e Formula may be adjusted t o use other commercially a v a i l a b l e Procedure: Notes : be used on shower t i l e s and l i k e surfaces. absence o f t r a c e metals. Care should be taken t o insure good q u a l i t y water and Sodium Hypochlorite. concentrations o f Sodium Hypochlorite. Absolute concentration o f a v a i l a b l e c h l o r i n e i s 2.0%. Formula CC-101 I n d u s t r i a l Strenath Chlorine Cleaner A Hard Surface I n d u s t r i a l Strength Hypochlorite Spray Cleaner Inaredient: Deionized Water Sodium Hydroxide (50%) Sodium Hypochlorite (12.5%) Avanel S-70 Wt.Sb 56.00 3 . 0 0 40.00 1 .oo pH (as i s ) : >12.5 Appearance: Clear, water-white t o l i g h t - y e l l o w l i q u i d Odor: Chlorine Procedure: Charge t h e ingredients w i t h a g i t a t i o n i n t h e order l i s t e d . Notes : This formulation can be used i n high-pressure spray washing cleaners, d i l u t e d f o r hard-surface cleaning o r used as i s f o r an enhanced consumer household bleach. Shelf s t a b i l i t y o f c h l o r i n e cleaners i s dependent on t h e absence o f t r a c e metals. Care should be taken t o insure good qua1it y water and Sodi um Hypochlori t e . concentrations o f Sodium Hypochlorite. Absolute concentration of a v a i l a b l e c h l o r i n e i s 5.0%. Formula CC-102 SOURCE: Mazer Chemicals: Suggested Formulations Formula may be adjusted t o use other commercially a v a i l a b l e
  • 85.
    62 Advanced CleaningRoductFormulations D-Limonene Hard-surface Cleaners Formula HS-0093 D-Limonene Concentrate Component Wt.% D-Li monene 20.0 Alcodet HSC-1000 30.0 Igepal CO-720 30.0 Miranol FBS 19.0 Triethanolamine 1.o Water --- All-Purpose Spray C1eaner Type (1:9 D i l u t i o n ) Wt.% 2.0 3.0 3.0 1.9 0.1 90.0 Heavy-Duty Degreaser Type (1:3 D i l u t i o n ) Wt.% 5.0 7.5 7.5 4.75 0.25 75.0 Procedur e A. Concentrate Blend i n g r e d i e n t s i n order l i s t e d and mix u n t i 1 uniform. B. SDrav Cleaner D i l u t e concentrate 1:9 w i t h water or charge "Vessel A" w i t h D-Limonene, Alcodet HSC-1000, and then Igepal CQ-720. Mix u n t i l uniform. Charge a separate "Vessel B" w i t h water, triethanolamine and M i ranol FBS. Mix u n t i l uniform. F i n a l l y , add t h e contents o f "Vessel A" t o "Vessel B" and mix u n t i l uniform. C.DeQreaSer D i l u t e concentrate 1:3 w i t h water or blend i n g r e d i e n t s i n t h e same manner as s p e c i f i e d i n t h e spray cleaner procedure. Phvsi cal P r o o e r t i es Appearance Clear, gold Clear, l i g h t Clear, Concentrate S w a y Cleaner DegreaSer l i q u i d yellow l i q u i d yellow l i q u i d S p e c i f i c G r a v i t y 1.02 1.oo 1.oo V i s c o s i t y 110 cps <10 cps <10 cps pH. as i s 10.0 9.5 9.5 SOURCE: Rhone-Poulenc Surfactants & Specialtlea: Formulas
  • 86.
    Hard Surface Cleaners63 d ' l i a o n e n e SDrav Cleaner Phase A: Water, D . I . Tetrapotassium Pyrophosphate Sodium M e t a s i l i c a t e , Anhydrous Petro LBA L i q u i d W i tconate AOS Phase B: DeSonic 9N W i tcami de 128T d ' L imonene* % bv Weiaht 68.0 6.0 2.0 10.0 3.0 5.0 3.0 3.0 *Sunkist Growers, I n c . o r Union Camp Blending Procedure: speed, add Phase B t o Phase A. Use D i l u t i o n : use as i s . Formula 802 Blend Phase A and Phase B separately. W i t h mixer a t h i g h ~-d'Lirnonene Cleaner Concentrate Phase I: Isopropanol O l e i c Acid Varonic K205 d ' L imonene Phase 11: Water, D . I . Potassium Hydroxide, 87% % by Weiaht 10.0 8.8 5.0 12.0 62.2 2.0 Blending Procedure: I 1 i n g r e d i e n t s and mix thoroughly. While mixing, add Phase I t o Phase 11. T y p i c a l P r o p e r t i e s : V i s c o s i t y , cps: 75 S o l i d s : 13.8% pH: 10.2 Formula 808 SOURCE: Witco Corp.: Suggested Formulations Combine Phase Ii n g r e d i e n t s and mix thoroughly. Combine Phase
  • 87.
    64 Advanced CleaningproductFormulations General Purpose Hard Surface Cleaner This general purpose cleaner i s a v e r s a t i l e product. The combination o f Sandoxylate SX-408 and Sandoxylate SX-424 provide excellent surface a c t i v i t y and s o i l removal allowing i t t o be used i n many a p p l i c a t i o n s . Inaredi ents: Water Sodi urn S i 1icate Sodium Hydroxide (20% Solution) Butyl C e l losolve Sandoxylate SX-408 Sandoxylate SX-424 Sodium Xylene Sulfonate Drimarine Turquoise XB % bv W t 79.9 1.o 0.5 0.5 5.0 11.5 1.5 0.1 Procedure: i d e (20%), Butyl Cellosolve, Sandoxylate SX-408. Sandoxylate SX-424, Sodium Xylene Sulfonate and Drimarine Turquoise XB. Charge vessel w i t h water. Add sodium s i l i c a t e , sodium hydrox- Suggested Use: 4 t o 6 ounces per g a l l o n o f water. SOURCE: Sandoz Chemicals Corp. : Formul a t i on HHG-11 A l k a l i n e Hard Surface Cleaner Water, D.I. Sodium M e t a s i l i c a t e Varami de A-83 Witconate 30DS W i tconate SXS L i q u i d % by Weiaht 34.0 8.0 12.0 40.0 6.0 Blending Procedure: each a d d i t i o n . Typical Properties: Viscosity, cps: 205 Solids: 34.4% pH: 12.5 Add ingredients i n order shown and dissolve completely between SOURCE: Wltco Corp.: Formula 5 1 6
  • 88.
    Hard swface Cleaners65 General Puroose Hard-surface Cleaners Formula HS-0034 Comoonent Water Sodi um Metasi 1icate Pentahydrate Rhodasurf 91-6 Cheelox BF-13 Miranol FBS Rhodafac RA-600 Butoxyethanol Solvent-Free Non-Phosphate IYPe Wt.% 83.5 2.0 7.5 3.0 4.0 - Solvent-Free Phosphate mWt.% 85.5 2.0 7.5 3.0 2.0 - - Heavy-Duty Solvent I Y P S Wt.% 83.0 I .o 6.0 2.0 2.0 6.0 - Procedure Phvsi c a l P r o o e r t i 8s Blend i n g r e d i e n t s i n order l i s t e d and mix u n t i l uniform. Appearance C1ear, C1ear, C1ear, S p e c i f i c G r a v i t y 1.035 1.012 0.994 V i s c o s i t y <I0 cps <I0 cps <I0 cps pH, as i s 12.3 11.85 12.20 It. yellow water-white water-white U n b u i l t . Hiah-Sudsina. Hard-surface Cleaner Formula HS-0036 Comoonent Water C a l s o f t F-90 Miranol FBS Sodi um S i 1i c a t e Igepal CO-710 A1 kami de DC-212/S M-Pyrol, N-methyl-2-pyrrolidone Wt.% 79.7 5.3 3.0 5.5 1 .o 2.0 3.5 Procedure 81end i n g r e d i e n t s i n order l i s t e d and mix u n t i l uniform. TvDi cal ProDerti88 Appearance: C1ear, ye11ow 1iquid V i s c o s i t y : t 1 0 cps pH, as i s : 9.85 S p e c i f i c Gravity: 1.07 SOURCE: Rhone-Poulenc Surfactants h S p e c i a l t i e s : Formulas
  • 89.
    66 Advanced CleaningProduct Formulations Hard-surface Cleaner I n q r e d i e n t : L i q u i d C i t r i c Acid-50% (Haarman & Sodium h y d r o x i d e s o l u t i o n 50% N o n i o n i c s u r f a c t a n t (Neodol 25-9) Methyl C a r b i t o l s o l v e n t Sodi um x y l ene s u l f o n a t e Sodium carbonate P i n e o i 1 Water Percent by Wei q h t Rei mer C o r p l - j 4 . 0 2 . 5 0 . 0 7 . 0 5.0 3.0 0 . 3 70.2 M i x t h e L i q u i d C i t r i c Acid-50% s o l u t i o n w i t h an equal volume o f water and n e u t r a l i z e by adding sodium h y d r o x i d e . The neut- r a l i z a t i o n r e a c t i o n s h o u l d be done s l o w l y and c a u t i o u s l y under a g i t a t i o n , as t h e r e a c t i o n i s h i g h l y exothermic. Blend t h e neut- r a l i z e d s o l u t i o n w i t h t h e n o n i o n i c s u r f a c t a n t , Methyl C a r b i t o l , sodium x y l e n e s u l f o n a t e and sodium carbonate. Add p i n e o i l l a s t . M n - A b r a s i v e C l e a n s e r In g redient : L i q u i d C i t r i c Acid-50% (Haarman Sodium h y d r o x i d e s o l u t i o n 50% Xanthan gum Vegetable gum (Veegum HS) Amphoteric s u r f a c t a n t Noni o n i c s u r f a c t a n t Calcium c a r b o n a t e (100 mesh) Water Percent by Wet q h t & Reimer Corp. ) 6 . 0 3.7 25.0 2 . 5 3.0 1 . 5 45.0 13.3 -~ Prepare a 1% s o l u t i o n o f xanthan gum w i t h t h e i n c l u s i o n o f a p r e s e r v a t i v e . S l o w l y add t h e v e g e t a b l e gum t o water and s t i r u n t i l t h o r o u g h l y h y d r a t e d . Add t h e c a l c i u m carbonate, f o l l o w e d by t h e amphoteric s u r f a c t a n t , t h e n o n i o n i c s u r f a c t a n t and t h e xanthan gum s o l u t i o n . SOURCE: Haarman 8, Reimer Corp.: Suggested F o r m u l a t i o n s -Hard-Surf ace Cleaner Eastman DB s o l v e n t A n i o n i c s u r f a c t a n t * Na4EDTA** Ammoni um h y d r o x i d e (28%) Water *Such as Rhodapex CO-433 (Rhone-Poulenc) **Tetrasodium ethylenediaminetetracetate (39%) SOURCE: Eastman Chemical Co.: Suggested F o r m u l a t i o n Yo by W t . 7 . 0 1 .o 1.25 2 . 0 00.75
  • 90.
    Hard swface Cleaners67 Hard-surface Cleaner All-Surface Bathroom Acid Type Formula BC-0005 M-Pyrol, N-Methyl-2-Pyrrolidone (ISP) Igepal CO-630 Hydroxyethylcel l u l o s e Phosphori c Acid Water Perfume and colorants may be added. W> 3 4.0 1 .o 0.2 9.5 85.3 Procedure 1 . D i sperse hydroxyethylcel 1ulose i n water. 2. I n a separate vessel, mix M-pyrol, Igepal CO-630 together. Add hydroxyethylcellulose/water mixture. 3. Add a c i d and mix thoroughly. Phvsic a l P r w e r t igg pH (as i s ) : 2.0 pH (1%): 2.4 V i s c o s i t y : 30 cps Speci f ic Gravity: 1 .02 --Surface Cleaner All-Surface Bathroom Type Formula BC-0006 Wt.% Water 70.5 I gepal CO-630 2.5 Cheelox NTA-Na3 20.0 Sodi um Xylene Sul fonate 5.5 Sodi um Hydroxide 1.5 Perfume and colorants added, as desired, replacing water. Procedure 1 . Dissolve Igepal CO-630 i n water. Add Cheelox NTA-Na3. 2 . Add sodium-xylene sulfonate and sodium hydroxide, mixing w e l l Physical P r w e r t i e s pH, as i s : 12.9 pH (1%): 11.4 V i s c o s i t y : 10 cps S p e c i f i c Gravity: 1.05 a f t e r each addition. SOURCE: Rhone-Poulenc Surfactants 6 Specialties: Formulas
  • 91.
    68 Advanced CleaningProduct Formulotiotu Hard Surface Cleaners Calsuds, C a l s o f t and Calamide concentrates can be formulated t o create powerful, non-corrosive, non-filming cleaners f o r f l o o r s , woodwork, walls, windows, counter tops, tubs, t i l e and s i m i l a r hard surfaces. Use l e v e l s : 1-4 oz./gal o f water. F l o o r Cleaner Products P i 1o t Formula #HSC-003-01 Water Na4EDTA Calsoft F-90 Cal oxyl a t e N-9 B u t y l Cellosolve Calsuds 81 TKPP P i l o t SXS-40 Water Cal foam SLS-30 Calamide C Propylene G1ycol Water % by Weiaht 81 .OO 10.00 4.00 2.00 3.00 P i l o t Formula #HDC-003-01 % bv Weight 5.00 7.80 10.00 77.20 Rua Cleaner P i l o t Formula #CPT-003-01 % by Weiqht 40.09 4.04 20.11 35.76 P l a s t i c , V i n y l and Leather Cleaner P i l o t Formula #UPC-001-01 Caloxylate N-9 Dowanol D (PnB) Propylene G1ycol B u t y l Cellosolve Water SOURCE: P i l o t Chemical Co. : Household C1eaner Formu by Weight 10.10 5.02 2.56 1.13 81.19 a t ions
  • 92.
    Hard Surface Cleaners69 Hard Surface Cleaners Calsuds, C a l s o f t and Calamide concentrates can be formulated t o c r e a t e powerful, non-corrosive, non-filming cleaners f o r f l o o r s , woodwork, w a l l s , windows, counter tops, tubs, t i l e and s i m i l a r hard surfaces. Use l e v e l s : 1-4 oz./gal. o f water. Tub and T i l e Cleaners Pi l o t Formula #APC-004-01 Water Versene 100 Calsuds A Isopropyl Alcohol Propyl ene G1 ycol Pine O i 1 D-1 imonene Cal imul se PRS Caloxylate N-9 Water C a l s o f t L-40 P i l o t sxs-40 Calamide 0 Water TKPP Calsuds 81 P i l o t sxs-40 Water Ammonia (29%) Na4EDTA Butyl C e l l osol ve Calsuds 81 Pi 1o t Formula #HDC-006-01 Counter Top/Wall Cleaners P i l o t Formula #HDC-003-01 A l l Purpose Type P i l o t Formula #HSC-008-01 Ammoniated T- % bv Weiqht 65.00 1 .oo 25.00 5.00 3.00 1.oo ?&by Wei a h t 30.00 5.00 5.00 26.50 16.50 10.00 7 . 0 0 % by Weight 77.20 7.80 5.00 10.00 % by Weiaht 86.50 3.00 0.50 5.00 5.00 SOURCE: P i lot Chemical Con: Household C1eaner Formulations
  • 93.
    70 Advanced CleaningProduct Formulations Hard Surface Cleaner w/AmDhoteric Water, 0.1. Sodium Carbonate Rewoteric AM KSF-40 Oowanol DPM Versene 100 Witconate SXS (40%) % by Weinht 75.0 4.0 10.0 5.0 2.0 4.0 Blending Procedure: each a d d i t i o n . Typi cal Propert ies : Add ingredients i n order shown and dissolve completely between Viscosity, cps: 4 Solids: 10.2% pH: 10.8 Formula 507 Hard Surface Cleaner Concentrate w/d'Lilnonene Phase I: Isopropanol Oleic Acid Varonic K205 d ' L imonene Phase 11: Water, 0.1. Potassium Hydroxide (87%) % by Weiciht 10.0 8.8 5.0 12.0 62.2 2.0 B1endi ng Procedure : I 1 ingredients and mix thoroughly. While mixing, add Phase I t o Phase 11. Typical Properties: Viscosity, cps: 75 Solids: 13.8% pn: 10.2 Combine Phase I ingredients and mix thoroughly. Combine Phase Formula 508 SOURCE: Witco Corp.: Suggested Formulations
  • 94.
    Hard Swface Cleaners71 Hard-surface Cleaner Concentrate A l k a l i n e All-Purpose Cleaner Concentrate Inaredi ent : Deionized Water Sodium Hydroxide (50%) Tetrapotassium Pyrophosphate Sodium M e t a s i l i c a t e Pentahydrate Avanel S-150 Sodium Cumene Sulfonate (40%) Wt.% 76.00 2.00 12.00 1.oo 6.00 3.00 pH (as i s ) : 10.5-11.5 Appearance: Clear, l i g h t - y e l l o w l i q u i d S p e c i f i c Gravity: 1.13 Procedure: Charge t h e water t o an appropriate mixing vessel and s t a r t a a i t a t i o n . I n t h e sequence l i s t e d above, charge t h e remaining ingredients and mix u n t i l t h e s o l u t i o n i s c l e a r . Notes : This i s a hard-surface cleaner concentrate which i s on many d i f f e r e n t s o i l s and surfaces. For concrete sur use "as i s . " For walls, f l o o r s , and other surfaces, d i 1O:l w i t h water. Formula CH-101 Household Hard-surface Cleaner All-Purpose A l k a l i n e Cleaner f o r Sponge o r Spray Apt Inaredient : Deionized Water Sodium Laureth (3) Sulfate Mazamide 00 Tetrapotassium Pyrophosphate Sodium M e t a s i l i c a t e Pentahydrate Macol 40 Deionized Water, Dye, etc. pH (as i s ) : 12.0-13.0 Appearance: Clear, water-white l i q u i d (without dye) S p e c i f i c Gravity: 1.01 Procedure: e f f e c t i ve aces, ute Iic a t ion Wt.% 80.00 2.50 0.50 1.oo 2.00 4.00 Q.S. Charge t h e f i r s t p o r t i o n o f water t o a mixing vessel and s t a r t a g i t a t i o n . I f product i s t o be colored, d i s s o l v e dye i n t h e reserved p o r t i o n o f the water i n a separate vessel. Charge a l l remaining ingredients, i n c l u d i n g t h e dye solution, t o t h e mixing vessel and mix u n t i l c l e a r . Notes : cleaner. The product may be used w i t h a sponge o r may be used i n a spray b o t t l e . Formula CH-102 SOURCE: Mazer Chemicals: Suggested Formulations This formulation i s designed as a general purpose household
  • 95.
    72 Advanced CleaningRoductFormulations Hiah-Performance. Hard-surface Cleaners Formula HS-0035 Component Water Sodi um Metasi 1icate Miranol FBS A1codet HSC-1 000 Cheelox BF-13 Rhodafac RA-600 Butoxyethanol Pentahydrate 6 . 0 Solvent-Free Solvent-Free Non-Phosphate Phosphate IYPe IYIzz Wt.% Wt.% 88.0 87.0 2.0 2.0 3.0 1 .o 4.0 4.0 3.0 3.0 - 3.0 - - Heavy-Duty Solvent TYDe Wt.% 85.0 2.0 2.0 3.0 2.0 - Procedur e Physical ProDerties Blend ingredients i n order l i s t e d and mix u n t i l uniform. Appearance Clear, l i g h t yellow l i q u i d pH, as i s 12.6 11.5 12.55 V i s c o s i t y <I0 cps Speci f ic G r a v i t y 0.978 1.013 1.016 <I0 cps <10 cps Econoaic a l Pine O i 1 Hard-surface C1eaner Formula HS-0037 Component Pine O i l Rhodasurf 0C-840 Water Wt.% 5 . 0 10.0 8 5 . 0 Procedur e 1 . Add Rhodasurf BC-840 t o pine o i l . Mix w e l l . Heat t o approx- imately 35-40C t o o b t a i n homogeneous s o l u t i o n . 2. Add water and mix thoroughly. Physical Prooerties Appearance: Clear, water-white l i q u i d pH. as i s : 3.08 S p e c i f i c Gravity: 0.99 V i s c o s i t y : <10 cps SOURCE: Rhone-Poulenc Surfactants & S p e c i a l t i e s : Formulas
  • 96.
    Hard swface Cleaners73 M i l d Abrasive Hard Surface Cleaner A m i l d abrasive cleaner f o r consumer use. E f f e c t i v e on S t a i n l e s s S t e e l , Porcelain and other hard surfaces. P a r t : I n q r e d i e n t s : A Deioni zed Water C a l c i t e (t100 mesh) Mazox LDA Potassium C i t r a t e B C a l s o f t F-90 Deionized Water Appearance: White pasty 1iqui d p H (as i s ) : 7.0-8.0 S p e c i f i c G r a v i t y : 1.47 Procedure: charge t h e water and s t a r t a g i t a t i o n . Do not i n t o t h e product. Slowly add t h e C a l c i t e f o l Mazox LDA and t h e Potassium C i t r a t e . To a mixing vessel w i t h sweep and scrape Wt.% 30.00 50.00 6.70 1 .oo 3.30 9.00 ype a g i t a t i o n , mix a i r owed by t h e I n a separate vessel, d i s s o l v e t h e C a l s o f t F-90 i n t h e remaining water. When completely dissolved, add t h e f i r s t p a r t o f t h e mix. Again avoid mixing excess a i r i n t o t h e system. Notes : I t i s a m i l d abrasive hard surface cleaner e f f e c t i v e against mast common s o i l s . I t can be used on s t a i n l e s s s t e e l , p o r c e l a i n and other hard surfaces. I n t h e manufacture o f t h i s product, care should be taken t o avoid mixing a i r i n t o t h e f i n i s h e d product. Being a pasty l i q u i d , once a i r i s entrained i n t o t h e system, i t i s d i f f i c u l t and t i m e consuming t o remove. SOURCE: Mazer Chemicals: Formulation CH-109 This f o r m u l a t i o n i s designed t o be used as i s by t h e consumer.
  • 97.
    74 Advanced CleaningProductFormulations Non-Phosphate Household Hard-surface Cleaner All-Purpose A l k a l i n e Cleaner f o r Sponge or Spray A p p l i c a t i o n Inaredi ent : INt.% Deioni zed Water 79.75 Sodi um Laureth S u l f a t e 2.50 Mazamide 80 0.50 Sodi um C i t r a t e 1.25 Macol 40 4.00 Sodium M e t a s i l i c a t e Pentahydrate 2.00 Deionized Water, Dye, e t c . a.s. pH (as i s ) : 12.0-13.0 Appearance: Clear, water-white l i q u i d (without dye) S p e c i f i c Gravity: 1. O l Procedure: Charge t h e f i r s t p o r t i o n o f water t o a mixing vessel and s t a r t a g i t a t i o n . I f product i s t o be colored, add t h e dye t o reserved p o r t i o n o f t h e water i n a separate vessel. Charge a l l remaining ingredients, i n c l u d i n g t h e dye solution, t o t h e mixing vessel and mix u n t i l c l e a r . Notes : This formulation i s a non-phosphate version o f formulation CH-102. This formulation i s designed as a general purpose household cleaner. The product may be used w i t h a sponge or may be used i n a spray vessel. Formula CH-106 Won-Phosphate Concentrated Household Hard-surface Cleaner Concentrated Pine O i l All-Purpose Cleaner Inqredi ent : Wt.% Deioni zed Water 78.05 Macol TD-12 5.00 Macol TD-3 2.50 Mazamide 00 0.50 Macol 40 4.50 Pine O i 1 0.20 Sodi um C i t r a t e 3.75 Sodium M e t a s i l i c a t e Pentahydrate 2.00 Sodium Xylene Sulfonate (40%) 3.50 pH (as i s ) : 12.5-13.5 Appearance: Clear, l i g h t yellow l i q u i d S p e c i f i c Gravity: 1.02 Procedure: Charge t h e water t o a mixing vessel and s t a r t a g i t a t i o n . Charge t h e Macol TD-12, Macol TD-3, Mazamide 80 and Macol 48 and continue a g i t a t i o n . Charge t h e Pine O i l and mix 5 minutes. Charge t h e remaining ingredients and mix u n t i l c l e a r and f r e e o f "fish eyes. I' Notes : This formulation i s a non-phosphate version o f formulation CH-103. This i s a concentrated household hard-surface cleaner designed t o be used a t a d i l u t i o n o f 1-3 ounces per gallon. Formula CH-107 SOURCE: Mazer Chemicals: Suggested Formulations
  • 98.
    Hard Surface Cleaners75 P i n e O i l Cleaner C o n c e n t r a t e ~~I n g r e d i en.Lsl P i n e 01 I N i n o l 11-CM Makon 12 Ammonyx LO I s o p r o p a n o l Water, D.I. B i o - S o f t S-100 % by W t . 20.0 9.0 5 . 0 0 . 5 2.0 10.0 53.5 M i x i n g Procedure: w a t e r s l o w l y w h i l e under a g i t a t i o n . M i x u n t i l c l e a r . P r o p e r t i e s : Combine p i n e o i l , s u r f a c t a n t s and IPA. Mix u n t i l c l e a r . Add Appearance: C l e a r y e l l o w l i q u i d Odor: P i n e V i s c o s i t y C 25C, c p s : 50 pH ( a s i s ) : 8 . 1 D e n s i t y l b s / g a l : 8 . 0 6 Freeze/Thaw ( 3 c y c l e s ) : Pass 50C oven ( 1 week): Pass Use I n s t r u c t i o n s : D i l u t e 1-2 ozs i n t o one g a l l o n Performance: Gardner S t r a i g h t L i n e W a s h a b i l i t y T e s t : Above f o r m u l a t i o n : 73.0% s o i l removed f r o m t i l e s Commercial p r o d u c t : 55.5% s o i l removed f r o m t i l e s SOURCE: Stepan Co.: F o r m u l a t i o n No. 208 L i q u i d Super C o n c e n t r a t e %_by Wei ght Water, D . I . 30.0 T e t r a p o t a s s i u m Pyrophosphate (60%) 25.0 B u t y l C e l l o s o l v e 5.0 W i t c o n a t e SXS L i q u i d 10.0 Varamide A-83 30.0 B l e n d i n g Procedure: each add1t ion. T y p i c a l P r o p e r t i e s : S o l i d s : 49.0% SOURCE: W i t c o Corp. : Formula 502 Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
  • 99.
  • 100.
    Anionic/Nonionic Heavy-Duty LaundryDeteraent Formula LY-0042 Water C a l s o f t F-90 Rhodasurf 25-7 Rhodacal A-246/L Sodi um C i t r a t e Brightener Fragrance Dye Wt.% 63 5 7 15 10 Q.S. Q.S. Q . S . Procedur g a g i t a t i o n . Then, add Rhodasurf A-246/L and Calsoft F-90. Begin c o o l i n g and add remaining ingredients s i n g l y , w i t h a g i t a t i o n t o o b t a i n uniform mixture, before making next a d d i t i o n . Phveical ProDert1ea Appearance: C1ear 1iquid, dyed t o preference pH. as i s : 7.4 S p e c i f i c Gravity: 1.09 V i s c o s i t y : 200 cps Heat water t o 60C. Add Rhodasurf 25-7 slowly, w i t h moderate Anionic/Nonionic Heavy-Duty Laundry Deteraent Formula LY-0043 Part A Water Na C i t r a t e Calsoft F-90 l!artJ! Rhodasurf 25-7 MEA sxs Part C Colorant Perfume Water Procedurg Dissolve Sodi um C i t r a t e add C a l s o f t F-90. Mix Part "B" . Add colorant, perfume Phvsf ca1 Prooerties pH: 11.0 pH (1% Solution): 9.50 S p e c i f i c Gravity: 1.120 V i s c o s i t y : 75 cps 30.0 8 . 0 17.0 8 . 0 2.0 6.0 0.02-1 0.1-0.5 Q . S . i n water by s t i r r i n g a t 45-50C and and water. Adjust pH t o 11.0. i n t h e order l i s t e d . Add "A" t ollgll SOURCE: Rhone-Poulenc Surfactants 6 Specialties: Formulas Laundry Products 77
  • 101.
    78 Advanced CleaningProduct Formulations Anionic/Nonionic Heavy-Duty Laundry Deteraent Formula LY-0044 Part A Water Na C i t r a t e Calsoft F-90 P a r t B Rhodasurf 25-7 MEA sxs Part C Colorant Perfume Water Wt.% 30.0 8.0 17.0 8 . 0 2.0 6 . 0 0.02-1 0.1- 0.5 Q . S . Procedure Dissolve sodium c i t r a t e i n water by s t i r r i n g a t 45C-5OC. add C a l s o f t F-90. Mix Part "B" i n the order l i s t e d . Add "A" t o "8" . Add colorant, perfume and water. Adjust pH t o 11.0. Nonionic/Amphoteric Heavy-Duty Laundry L i q u i d Formula LY-0045 Water G1ycosi des Miranol FBS MEA Colorant Perfume ' Wt.% Q.S. 20.0 7.0 2 . 0 0.02-1 0.1 -0.5 Procedure each a d d i t i o n . Adjust pH t o 11.0. Add t h e ingredients i n t h e order l i s t e d . M i x well a f t e r Phvsical P r o m r t ieg pH: 11.0 pH (1% Solution): 9.50 S p e c i f i c Gravity: 1 .lo0 Viscosity: 300 cps SOURCE: Rhone-Poulenc Surfactants & S p e c i a l t i e s : Formulas
  • 102.
    Cold Water Deterpent JForW o o l and D e l i c a t e Fabrics) Formula LY-0040 Water Miranol CS Conc. Rhodapex ES-2 A1kamide DC-212 Fluorescent Whitening Agent Wt.% 55.9 10.0 30.0 4 . 0 0.1 Procedur Q c l e a r . Phvsic a l Pronerti8s Add ingredients i n order l i s t e d . Heat t o 50C and mix u n t i l Appearance: Clear, yellow l i q u i d pH. as i s : 8.16 S p e c i f i c Gravity: 1.02 V i s c o s i t y : 700 cps F ine Fabric Deterpent Formula LY-0041 Rhodacal DS-10 Sodium Hexametaphosphate Sodium Bicarbonate Optical Brightener Wt.% 32.0 30.0 38.0 P.S. Procedure t o t h e blender. Mix f i v e minutes. Add t h e Rhodacal DS-10 w i t h mixing. Add t h e o p t i c a l brightener w i t h mixing. Mix u n t i l uniform. Phvaical Prooert i e s Add t h e sodium bicarbonate and t h e sodium hexametaphosphate Appearance: White, free-flowing powder pH, 1% Solution: 8.5 SOURCE: Rhone-Poulenc Surfactants & Specialties: Formulas Laundry Products 79
  • 103.
    80 Advanced CleaningProductFormulations Deteraent f o r Colored Fabrics. Powder, Spray MixinQ Process-A Spray Mix: M a r l i p a l 24/939 o r 013/939 Fragrance O p t i c a l b r i g h t e n e r B u i l d e r Mix: Z e o l i t e A Sodium m e t a s i l i c a t e pentahydrite Sodium carbonate, dehydrated Carboxymethyl c e l l ulose Polycarboxylate, e.g. Sokalan CP 5 powder Sodi um s u l phate 1ight A c t i v e matter: 9.0% % 10.0 0.2 0 . 2 35.0 5 . 0 15.0 2.0 4.0 t o 100 Detergent f o r Colored Fabrics, Powder, Spray M j x i n ~Pro_cess-B Spray M i x : M a r l i p a l 24/30 Marl ip a l 24/90 Fragrance O p t i c a l brightener B u i l d e r Mix: Marlon ARL Z e o l i t e A Sodium soap powder Sodium m e t a s i l i c a t e pentahydrate Sodium carbonate, dehydrated Polycarboxylate, e.g. Sokalan CP 5 powder P o l y v i n y l p y r r o l i d o n e , e.g. Sokalan HP 50 Sodium sulphate l i g h t % 2.0 4.0 0 . 2 0 . 2 10.0 40.0 4.0 5.0 15.0 4 . 0 2.0 t o 100 A c t i v e matter: 14.0% SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes
  • 104.
    Detergent for Curtains,Medium V i s c o s i t v - A % M a r l i n a t DFK 30 20.0 Marl ip a l 24/70 15.0 Coconut f a t t y acid, potassium s a l t 5.0 Ethylenedi ami ne t e t r a a c e t a t e 40 0.2 Balance water, fragrance, d y e s t u f f , o p t i c a l b r i g h t e n e r , preservat ive t o 100 A c t i v e m a t t e r : 26.0% Detergent f o r Curtains, Medium V i s c o s i t v - 8 % Marlon PS 65 10.0 Marlox M 606/1 15.0 Ethylenediamine t e t r a a c e t a t e 40 0.2 Balance water, fragrance, d y e s t u f f , o p t i c a l b r i g h t e n e r , p r e s e r v a t i v e t o 100 A c t i v e matter: 20.7% Manual-Wash Detergent, Foaming Medium V i scosit y - A % Marlon PS 65 10.0 M a r l i p a l 013/70 15.0 Marlamid DF 1218 2.5 Na cumene sulphonate, 40% 1 .o Ethanol* 1.5 Balance water, fragrance, d y e s t u f f , preservative, sodium c h l o r i d e t o 100 A c t i v e matter: 24.0% Manual-Wash Detergent. Foaming Medium Viscosity-B % Marl in a t 242/28 12.0 sodium c h l o r i d e t o 100 Marlon A 365 18.5 Balance water, fragrance, d y e s t u f f , p r e s e r v a t i v e , A c t i v e matter: 15.3% SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes Laundry Products 81
  • 105.
    82 Advanced CleaningProductFormulations Detergent f o r F i n e Fabrics-1 L i q u i d I n r e d i e n t s : i ? F a t t y a c i d (Cocos + Olein. P r i f a c 7976) KOH (85%) H20 (40-50C) B Hostapur SAS 60 Genapol ZRO l i q u i d Genapol UD-080 3.00% 0.60% 41.90% 23.30% 25.00% 6.00% C C i t r i c a c i d x 1H20 0.20% Manufacturing: I One a f t e r another, t h e components o f B are added t o A . I 1 A t l a s t C i s added. Deteraent f o r F i n e Fabrics-2 m r e d i e n t s : A F a t t y a c i d (Cocos + Olein, P r i f a c 7976) 4.00% KOH (85%) 0.80% H20 (40-5OC) 63.00% 8 Hostapur SAS 60 Genapol UO-080 a. 00% 24.00% C C i t r i c a c i d x 1H20 0.20% Manufacturing: I One a f t e r another, t h e components o f B are added t o A. I 1 A t l a s t C i s added. SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Detergents and Cleaning Agents: Guide Formulations
  • 106.
    Laundry Products 83 EnzymaticHeavy-Duty Laundry Deteraent Formula LY-0046 P a r t A Water C i t r a t e C a l s o f t F-90 P a r t Rhodasurf 25-7 MEA TEA sxs Rhodapex NA 61 P a r t C Na Formate Calcium Chloride Enzymes Colorant Perfume Water Wt.% 10.0 5.0 8.0 6.0 2.0 2.0 3.0 8.0 1.2 0.2 0.4 0.02-1 0.1 - 0 . 8 Q.S. Procedure C a l s o f t F-90. Mix Part "B" i n t h e o r e r l i s t e d . Add "A" t o "B". Add sodium formate and calcium chlOP&e. Cool t o room temper- ature. Add t h e enzymes. Add coloraat, perfume and water. Adjust pH t o 10.0. Phvsi c a l P r o o e r t i pH: 10.0 pH (1% S o l u t i o n ) : 8.8 Speci f ic G r a v i t y : 1 . l o 0 V i s c o s i t y : 100 cps Dissolve sodium c i t r a t e i n water by s t i r r i n g a t 45-5OC. add Won-Phosphate Laundry Powder Formula LY-0048 Sodium Carbonate Igepal CO-630 Sodi um S i 1icate Sodium S u l f a t e Carboxymethyl c e l l u lose O p t i c a l Brightener Wt.% 50.0 12.0 12.0 24.5 1.o 0.5 Procedur g Add t h e sodium carbonate t o t h e mixer. Spray t h e Igepal 02-630 onto t h e sodium carbonate. Add t h e remaining ingredients i n t h e order l i s t e d . Mix u n t i l a homogeneous, f r e e - f l o w i n g product r e s u l t s . Phvsi c a l P r o m r t 1os Appearance: White, f r e e - f l o w i n g powder pH, 1%Solution: 11.0 SOURCE: Rhone-Poulrnc Surfactanta & S p e c i a l t i e s : Formulas
  • 107.
    84 Advanced Cleaningproduct Formulations Fabric Pretreatment S p r i t z Ingredients: Neodol 25-7 Neodol 25-3 Versaflex 207 (25%) Sodium Xylene Sulfonate (40%) EDTA, Disodium S a l t Water, Dye, Perfume, and Enzymes Procedure: 1. Mix melted Neodol 25-7 and Neodol 25-3. 2. Add sodium xylene sulfonate and mix. 3. Add water and Versaflex 207, mix, and cool. 4. Add EDTA. dye, perfume, and enzymes. Reference #8069:21 Low VOC Pump F a b r i c Antist- Insredients: Versaf 1ex 2004 (30%) Ethanol Propylene G1ycol Preservative, Water, and Fragrance 9.75 5.25 20.00 15.00 0.50 4.s. %%. 5.00 10.00 0.50 Q . S . Procedure: 1. Mix Versaflex 2004 and water. 2. Add ethanol and mix. 3. Add propyl ene g l y c o l , preservative, and fragrance. and mix. Reference #8069:97 SOURCE: National Strach and Chemical Corp.: Suggested Formula- t i o n s Laundrv Pre-Spotter and S t a i n Remover Water Sodium Meta S i l i c a t e (Anhydrous) Detergent Concentrate 840 % by Weiaht 83.0 2.0 15.0 Procedure: preservative as requi red. SOURCE: Mona I n d u s t r i e s , Inc.: Suggested Formulation Blend i n g r e d i e n t s i n order l i s t e d . Add c o l o r , fragrance and
  • 108.
    Fabric Softener-1 Ingredients: A H20(50-6OC) B Prapagen WK C MgC12 (10% b . w . ) D Perfume Dye ad 100.00% 6.70% 0.10% 0.20% q . s . Fabric Softener-2 Ingredients: A Genamin S-250 H3P04 (1 M; 9,5% b . w . ) H20 (50-60C) 8 Prapagen WK C MgClP (10% b . w . ) D Perfume Dye Fabric Softener-3 Inqredients: A Genamin 5-250 0.90% H3P04 (1 M; 9,5% b . w . ) 0.45% H20 (50-6OC) ad 100.00% 8 Prapagen WK 13.80% Polyglykol 400 3.70% C MgClZ (10% b . w . 1 1.OO% 0 Perfume 0.60% Dye q . s . Manufacturing: I One a f t e r another, t h e components o f B are added t o A. I 1 A t 40C, a d j u s t t h e v i s c o s i t y w i t h C (ca. 100-150 mPas). I11 A t 30C the-components o f D are added. Appl ic a t ion : SOURCE: Hoechst Aktiengesellschaft: Detergents and C 1.0-2.0 g a c t i v e ingredient/kg t e x t i l e Agents: Guide Formulations 2.00% 1.00% ad 100.00% 17.30% 3.00% 0.60% Q . S . eani ng Laundry Products 85
  • 109.
    86 Advanced CleaningProductFormulatiom Fabric Softener. Low V i scosi tv-A Marlosoft IQ 90 Balance water, fragrance, dyestuff Active matter: 5.0% Fabric Softener. Low V i scosi ty-B Marlosoft IQ 90 Balance water, fragrance, d y e s t u f f Active matter: 7.5% % 5 . 6 t o 100 % 8.3 t o 100 Fabric Softener Concentrate. Low Viscosity-A Marlosoft IQ 90 Calcium chloride, 25% (approx.) Balance water, fragrance, d y e s t u f f Active matter: 10.0% Formulation A: double concentrate % 11.1 0.1 t o 100 Fabric Softener Concentrate. Low Viscosity-B Marlosoft IQ 90 Calcium c h l o r i d e , 25% (approx.) Balance water, fragrance, d y e s t u f f % 16.7 1.1 t o 100 Active matter: 15.0% Formulation 8: t r i p l e concentrate SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes
  • 110.
    Heavy-dutv Detergent, Powder,SDrav Y i x i n a Process-A Spray Mix: M a r l i p a l 24/70 o r 013/70 O p t i c a l brightener Ethylenediamine tetraacetate. 40% Fragrance % 4.0 0.2 0 . 8 0.2 B u i l d e r Mix: Marlon ARL Sodium soap powder Z e o l i t e A Sodium m e t a s i l i c a t e pentahydrate Sodium perborate tetrahydrate Tetraacetyl ethylenedi ami ne (TAED) Sodium carbonate Polycarboxylate, e.g. Sokalan CP 5 Carboxymethyl c e l l u l o s e Sodium sulphate l i g h t , enzymes A c t i v e matter: 13.2% powder 8 . 0 2.8 25.0 5.0 20.0 3.0 10.0 4.0 1 .o t o 100 Heavy-Duty Detergent. Powder, Soray Mixing Process-8 Spray Mix: M a r l i p a l 24/70 o r 013/70 O p t i c a l brightener Ethylenediamine tetraacetate, 40% Fragrance % 4.0 0.2 0 . 8 0.2 B u i l d e r Mix: Marlon ARL Sodium soap powder Sodium t r i polyphosphate Sodium d i s i l i c a t e Sodi um perborate tetrahydrate Tetraacetyethylenediamine (TAED) Carboxymethyl c e l l u l o s e Sodium sulphate l i g h t , enzymes 8 . 0 3.0 30.0 9.0 20.0 3.0 1.o t o 100 A c t i v e matter: 13.4% SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes Laundry Products 87
  • 111.
    88 Advanced CleaningRoductFormulations Heavy-Duty Deteraent. Powder. Sprav Mixing Process-A Spray Mix: M a r l i p a l 013/939 o r 24/939 Fragrance Ethylenediamine tetraacetate. 40% Optical brightener Builder Mix: Z e o l i t e A Sodium m e t a s i l i c a t e pentahydrate Magnesium s i licate Sodium perborate tetrahydrate Tetraacetylethylenedi ami ne (TAED) Sodi um carbonate Carboxymethyl c e l l u l o s e Sodium sulphate l i g h t , enzymes Active matter: 9.0% E! 10.0 0.2 1.o 0.2 30.0 5.0 1.o 25.0 3.0 15.0 1.5 t o 100 Heavy-Duty Deteraent. Powder. Sprav Mixing Process-8 Spray Mix: M a r l i p a l 013/939 o r 24/939 Fragrance Optical brightener Builder Mix: Sodium tripolyphosphate Sodi um d i s i 1icate Magnesi um s i 1icate Sodium perborate tetrahydrate Tetraacetylethylenediamine (TAED) Carboxymethyl c e l l u l o s e Sodium sulphate l i g h t , enzymes Active matter: 9.0% E! 10.0 0.2 0.2 28.0 5.0 1.o 25.0 3.0 1.o t o 100 L i a u i d Heavy-Duty Deteraent. B u i l t Tvoe. Hieh Viscosity-A % Marlon PS 65 10.0 M a r l i p a l 013/30 5.0 1,2-Propylene g l y c o l * 5.0 C i t r i c a c i d 2.0 Z e o l i t e A, 50% s l u r r y 45.0 Balance water, fragrance, dyestuff, o p t i c a l brightener, enzymes, preservative t o 100 Active matter: 11.5% + f u r t h e r products o f Huls AG SOURCE: Hula America, I n c . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes
  • 112.
    Heavy D ut y L ia u i d Laundry Deterqent Type DN I n q r e d ients: Stepan B i o S o f t D-62 ( a n i o n i c s u r f a c t a n t ) Neodol 25-7 (nonionic s u r f a c t a n t ) Propyl ene g l y c o l E t h y l alcohol Sodium C i t r a t e (Haarman & Reimer) Sodium xylene s u l f o n a t e Sodium borate (borax) T r i ethanol ami ne (TEA) o r sodi um hydroxide Parts by Weiqht 7.0 16.0 7.0 5.0 5.0 10.0 1.o t o pH 9.5 Dissolve the Sodium C i t r a t e and sodium borate i n approxim- a t e l y 20 m l water. Apply heat i f necessary t o d i s s o l v e . Combine t h e s u r f a c t a n t s , propylene g l y c o l and e t h y l a l c o h o l . Add t h e Sodium C i t r a t e and sodium borate s o l u t i o n t o t h e s u r f a c t a n t s mixture. Add t h e sodium xylene s u l f o n a t e . Adjust t h e pH t o 9 . 5 using TEA o r d i l u t e sodium hydroxide. B r i n g t h e volume o f t h e m i x t u r e t o 100 m l using water. I f an enzyme detergent i s desired, t h e f o l l o w i n g should be added : Sodium borate (borax) add an a d d i t i o n a l 2.0 Calcium c h l o r i d e 0.1 Protease 0 . 6 Dissolve t h e Sodium C i t r a t e , sodium borate and calcium chlo- r i d e i n water. Apply heat i f necessary t o d i s s o l v e . Combine the s u r f a c t a n t s , propylene g l y c o l and e t h y l a l c o h o l . Add t h e Sodium C i t r a t e , sodium borate and calcium c h l o r i d e s o l u t i o n t o t h i s mixture. Add sodium xylene sulfonate. Adjust t h e pH t o 8.0 w i t h TEA o r d i l u t e sodium hydroxide. Add t h e Protease. B r i n g t h e volume o f t h e mixture t o 100 m l using water. The a d d i t i o n o f fragrance, dye, o p t i c a l brightener, a n t i - r e d e p o s i t i o n agent, corrosium i n h i b i t o r , e t c . , i s o p t i o n a l . SOURCE: Haarman & Reimer Corp.: Suggested Formulation B u i l t Formulation #1 I n a r e d ient : Water Na3NTA Na Gluconate 45% KOH 42 S i l i c a t e N Glycol Ether Nonion ic Surfa c tant Amphoteric Weight .% 68% - 1% 1% 10% 10% 5% 2% ' 3% Both t h e Amphoteric SC and t h e competitive imidazoline coupled t h e f o r m u l a t i o n together w i t h 3% o f amphoteric. SOURCE: Tomah Products, I n c . : Suggested Formultion Laundry Products 89
  • 113.
    90 Advanced CleaningProductFormulations I n q r e d Neodol Neodol Heavy Duty L i q u i d Laundry Detergent Type TA ie n t s : 25-7 ( n o n i o n i c s u r f a c t a n t ) 25-35 ( a n i o n i c s u r f a c t a n t ) Sodium l a u r y l s u l f a t e ( a n i o n i c s u r f a c t a n t ) Stepan B i o S o f t D-62 (LAS-anionic s u r f a c t a n t ) T r i ethanolami ne (TEA) Propylene g l y c o l Potassium C i t r a t e (Haarman & Reimer Corp.) E t h y l a l c o h o l Calcium c h l o r i d e Sodium b o r a t e (borax) Protease Water q.s P a r t s I t o a L ! W s h t 5.0 10.0 12.0 8.0 5.0 7.0 6.0 7.0 0 . 1 3 . 0 0.6 100 p a r t s Dissolve t h e Potassium C i t r a t e , calcium c h l o r de and sodium b o r a t e i n approximately 20 m l water. Apply heat f necessary t o d i s s o l v e . Combine t h e s u r f a c t a n t s , TEA, propy ene g l y c o l and e t h y l a l c o h o l . Add t h e Potassium C i t r a t e , calcium c h l o r i d e and sodium b o r a t e s o l u t i o n . A d j u s t t h e pH of t h e s o l u t i o n t o 8 . 0 w i t h TEA o r d i l u t e sodium hydroxide. Add t h e Protease. B r i n g t h e volume o f t h e m i x t u r e t o 100 m l using water. The a d d i t i o n o f fragrance, dye, o p t i c a l b r i g h t e n e r , a n t i - r e d e p o s i t i o n agent, c o r r o s i o n agent, c o r r o s i o n i n h i b i t o r , e t c . , i s o p t i o n a l . SOURCE: Haarman & Reimer Corp.: Suggested Formulation !&Md Laundry_ D_etergents InQ r e dj.=ts: Water Glucopon 6OOCSUP (50%) E thano1 Trycol 5963 I n redients.; i a F e r Sodi um C i t r a t e S u l f o t e x SXS Glucopon 6OOCSUP (50%) Ethanol S u l f o t e x 6040 S (59%) We 1 ght% 72 10 3 15 Weight% 32 5 5 15 5 38 Add i n t h e order l i s t e d , d i s s o l v i n g each i n g r e d i e n t com- p l e t e l y . Use moderate a g i t a t i o n and i n c o r p o r a t e c o l o r s and fragrances as r e q u i r e d . SOURCE: Henkel Corp.: CD D i v i s i o n : Glucopon S u r f a c t a n t s : Suggested Formulations
  • 114.
    Heavv Dutv Li q u i d Laundry Deterqent Type WA I n a r e d ie n t s : __P a r t s by Weiaht Stepan B i o S o f t D-62 (LAS-anionic s u r f a c t a n t ) 28.0 Neodol 25-7 ( n o n i o n i c s u r f a c t a n t ) 7 . 0 Sodium xylene s u l f o n a t e 12.0 T r i ethanolami ne (TEA) 2 . 0 Sodium C i t r a t e (Haarman & Reimer Corp.) 12.0 Water 9 , s . t o 100 p a r t s Dissolve Sodium C i t r a t e i n approximately 20 m l water. Combine t h e s u r f a c t a n t s , sodium xylene s u l f o n a t e and TEA. Add t h e Sodium C i t r a t e . Adjust t h e pH o f t h e s o l u t i o n t o 11 u s i n g d i l u t e sodium hydroxide. B r i n g t h e volume o f t h e m i x t u r e t o 100 m l u s i n g water. added : I f an enzyme detergent i s desired, t h e f o l l o w i n g should be Sodi um b o r a t e (borax) 3.0 Cal c i um c h l o r i d e 0.1 Propylene g l y c o l 7 . 0 Protease 0.6 D i s s o l v e t h e sodium borate, calcium c h l o r i d e and Sodium i C i t r a t e water. Apply heat i f necessary t o d i s s o l v e . Combine t h e s u r f s t a n t s , sodium xylene s u l f o n a t e , TEA and propylene g l y c o l . Add t h e sodium borate, Sodium C i t r a t e and calcium c h l o r i d e s o l u t i o n t o t h i s m i x t u r e . Adjust t h e pH t o 8.0 w i t h TEA o r d i l u t e sodium hydroxide. Add t h e Protease. B r i n g t h e volume o f t h e m i x t u r e t o 100 m l using water. r e d e p o s i t i o n agent, c o r r o s i o n i n h i b i t o r , e t c . , i s o p t i o n a l . SOURCE: Haarman & Reimer Corp.: Suggested Formulation The a d d i t i o n of fragrance, dye, o p t i c a l b r i g h t e n e r , a n t i - B u i l t Formulation #2 I n a r e d i e n t : Water Na M e t a s i l i c a t e pentahydrate STPP Nonionic s u r f a c t a n t Amphoteric s u r f a c t a n t Weight .% 79% 1% 10% 5% 5% Both t h e Amphoteric SC and t h e c o m p e t i t i v e amphoteric coupled t h e f o r m u l a t i o n together w i t h 5% o f amphoteric. SOURCE: Tomah Products, I n c . : Suggested Formulation Laundry Products 91
  • 115.
    92 Advanced CIeaningRoductFormulations L iauid Heavv-Duty Detergent. Low V i scosit v - A Marlon PS 65 Marl ipal 013/89 Caustic potash, 50% (approx.)* Coconut f a t t y a c i d T r i ethhnol ami ne R* 1.2-Propylene g l y c o l * Ethanol* Phosphonate, e.g. Dequest 2060 S Sodi um formi ate* Balance water, fragrance, dyestuff, enzymes, preservative Active matter: 45.0% % 20.0 17.2 3.9 10.0 5.0 3.0 8.0 1.5 1.o o p t i c a l brightener, t o 100 L i a u i d Heavy-Dutv Detergent. Low Viscositv-B s6 Marlon PS 65 20.0 M a r l i p a l 013/129 3.9 Marlox FK 64 12.0 Caustic potash, 50% (approx.)* 3.9 Coconut f a t t y a c i d 10.0 Triethanolamine R* 5.0 1,P-Propyl ene g l y c o l * 3.0 Ethanol* 8.0 Phosphonate, e.g. Dequest 2060s 1.5 Sodi urn formi ate* 1.o Balance water, fragrance, d y e s t u f f , o p t i c a l brightener, enzymes, preservative t o 100 Active matter: 45.0% L i a u i d Heavy-Duty Deteraent. B u i l t Type. H i g h Viscositv-B % Marl ip a l 013/30 5.0 C i t r i c a c i d 1. o Z e o l i t e A, 50% s l u r r y 45.0 Balance water, fragrance, dyestuff, o p t i c a l brightener, enzymes, preservative t o 100 Marlon PS 65 10.0 Active matter: 11.5% * f u r t h e r products o f Huls AG SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes
  • 116.
    Light-Duty Deterqent. Powder.Spray M i x i n q Process-A Spray Mix: M a r l i p a l 013/939 o r 24/939 Marlamid DF 1218 Fragrance % 5.0 1.0 0.2 B u i l d e r Mix: Z e o l i t e A Sodi um d i s i 1ic a t e Carboxymethyl c e l l ulose Sodium sulphate l i g h t Post Mix: Marlon ARL A c t i v e matter: 17.5% 40.0 3 . 0 1.o 34.8 15.0 L i ght-Duty Deterqent ~ Powder, Spray M i x i ng Process-€3 Spray Mix: M a r l i p a l 013/939 o r 24/939 Fragrance % 3.0 0.2 B u i l d e r Mix: Z e o l i t e A Sodi um d i s i 1i c a t e Carboxymethyl c e l l u l o s e Sodium sulphate l i g h t Post Mix: Marlon ARL A c t i v e Matter: 17.1% 45.0 5.0 1 .o 22.8 18.0 L i q u i d Light-Duty Detergent, w i t h Incorporated Softener, Low V i scosi ty-A Marl i p a l 24/99 Marlox FK 64 Marlosoft I0 90 Ethanol * Balance water, fragrance, d y e s t u f f 9b 15.0 5.0 5 . 0 10.0 t o 100 A c t i v e Matter: 23.0% * f u r t h e r products o f Huls AG SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes Laundry Products 93
  • 117.
    94 Advanced CleaningProduct Formulations L iQuid L ight-Duty Detergent. Low V i scosit y - A Marlon PS 65 Marl inat 242/28 Marlamid DF 1218 Coconut f a t t y a c i d Caustic potash, 50% (approx.)* Ethylenediamine tetraacetate, 40% Balance water, fragrance, dyestuff, sodium c h l o r i d e Active matter: 23.5% Formulation A f o r machine-wash % 20.0 12.0 3.0 4.0 1.4 0.2 preservative, t o 100 L iauid L ight-Duty Detergent, Low V i scosity-B % M a r l i n a t 242/28 40.0 Marlamid DF 1218 3.0 Marlamid PG 20 3.0 Balance water, fragrance, dyestuff, preservative, sodium c h l o r i d e t o 100 Active matter: 16.2% Formulation B f o r manual-wash L i q u i d Light-Duty Detergent, w i t h Incorporated Softener, Low V i scosity-B Marl i p a l 24/99 Marlox FK 64 Ampholyt JB 130 Marlosoft I Q 90 Balance water, fragrance, d y e s t u f f % 5 . 0 5 . 0 25.0 5.0 t o 100 Active matter: 21.5% * f u r t h e r products o f Huls AG SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes
  • 118.
    Part A Igepal CO-660 CalsoftF-90 Water I n d u s t r ia1 Laundry Two-Part Systems Formula LY-0052 Uniforms (Petroleum Greases and O i l s ) 2 90 Part B Sodium S i l i c a t e (Si02/Na20 1.6-2.5) 100 Hotel/ L i nen SUDD~Y(Ani ma1 and Vegetable Greaser Part A Igepal CO-660 Calsoft F-90 Water Part B Potassi um Hydroxide (45%) STPP, TKPP o r KTPP Sodium Carbonate Igapal CO-660 Sodi um Tripolyphosphate Sodium M e t a s i l i c a t e Optical B r i ghtener t o t h mixer. S CO-660. Add t h e remaining ingredients i n t h Mix u n t i l uniform. Wt.% 10 2 88 85 15 I n d u s t r i a l Laundry Powder Uniforms Formula LY-0050 Procedure Add t h e sodi um carbona Wt.% 52.5 15 20 12 0 . 5 ray on t h e Igepal order 1isted. Phvsic a l ProDerti8s Appearance: White, free-flowing powder pH, 1% Solution: 11.4 SOURCE: Rhone-Poulenc Surfactants & Specialties: Formulas Laundry Products 95
  • 119.
    96 Advanced CleaningProductFormulations Laundry Liauids Calsuds o r C a l s o f t based products remove ground-in d i r t and grease i n heavy f a b r i c s and g e n t l y clean d e l i c a t e k n i t s i n c o l d water. They i n h i b i t s t a t i c build-up and provide l u b r i c i t y , f u l l i n g and softening. "Fine Care" Fabric Detergents P i l o t Formula ULDY-003-01 Calsuds CD-6 Cal foam ES-303 P i l o t SXS-40 Cal s o f t LAS-99 Water Calsuds CD-6 Cal foam ES-303 P i l o t SXS-40 Cal s o f t LAS-99 Water C i t r i c Acid Perfume and Color Preservative Water 50% NaOH D i ethanol ami ne Propylene Glycol Cal s o f t LAS-99 Caloxyl a t e N-9 Water 50% NaOH D i ethanol ami ne P i l o t SXS-40 C a l s o f t LAS-99 Cal oxyl a t e N-9 P i l o t Formula ULDL-003-01 Heavy Duty Laundry Liquids P i 1o t Formula #HDL-004-01 Pi l o t Formula #HDL-005-01 % bv Weipht 19.90 15.15 10.20 4.96 49.79 % by Weiqht 20.00 15.00 10.00 5.00 50.00 Q.S. pH 7 Q . S . Q.S. % by Weiqht 36.60 6.40 7.00 5.00 40.00 5.00 % bv Weiqht 30.40 4.60 5.00 25.00 30.00 5.00 SOURCE: P i l o t Chemical Co. : Household C1eaner Formul a t i ons
  • 120.
    Laundry Powder Deteraent FormulaLY-0047 Sodium Carbonate C a l s o f t F-90 Rhodapex NA-61 Rhodasurf 25-7 Sodium M e t a s i l i c a t e Pentahydrate Sodi um S u l f a t e Zeol it e Sodi um Perborate Enzymes can be added Dye Perfume Procedure Add t h e sodium carbonate t o t h e mixer. pex NA-61 and t h e Rhodasurf 25-7. Add t h e i n t h e order l i s t e d and mix u n t i l uniform. Wt.% 44.0 14.0 6.0 2.0 4.0 10.0 18.0 2.0 Spray on t h e Rhoda- remai n i ng ingredients Physical ProDerties Appearance: White, free-flowing powder, dyed t o preference. pH, 1 % Solution: 11 I n d u s t r i a l Laundry One-Shot L i a u i d Formula LY-0049 Water Igepal CO-630 Igepal CO-710 Cheelox BF-13 Potassi urn Hydroxide (45%) Miranol FBS Wt.% 69 3 3 10 10 5 Procedur e Phvsi cal P r o v e r t iea Add t h e ingredients i n t h e order l i s t e d . Mix u n t i l uniform. Appearance: Clear l i q u i d pH. as i s : 13.0 pH, 1% s o l u t i o n : 11.8 S p e c i f i c Gravity: 1.06 V i s c o s i t y : <lo cps SOURCE: Rhone-Poulenc Surfactants a S p e c i a l t i e s : Formulas Laundry Products 97
  • 121.
    98 Advanced CleaningProductFormulafions L i q u i d Heavy Duty Detergent HDLD Soap based Ingredients: A Genapol OA-080 F a t t y a c i d (2/3 o l e i c , 1/3 COCO) KOH (85%) 1,2 Propyleneglycol Water (50-6OC) T r i sodi um-ci t r a t e x 2H20 Savi nase Alcalase Termamyl Parfum F a r b s t o f f 8 Tinopal CBS-X C Hostapur SAS 60 D Ethanol 12.00% 14.00% 3.50% 5 .OO% 0.10% 39.40% 17.00% 5.00% 3.00% 0.50% 0.20% 0.30% 0.20% 0.10% Manufacturing: I Dissolve 8 i n A. 11 One a f t e r another, t h e components o f C are added t o I I11 A t 25C, t h e components o f D t o 11. L i q u i d Detergent "FSL" A Ingredients I r- Genapol CIA-080 F a t t y a c i d ( P r i f a c 7976) KOH (85%) T r i ethanolamine 1.2 Propyleneglycol 8 Tinopal CBS-X Water (50-6OC) C Hostapur SAS 60 T r i sodi um-ci r a t e x 2H20 Dequest 2066 D Ethanol Savi nase A1c a lase Termamyl Perfume Dye 12.00% 14.00% 2.60% 2.00% 5.00% 0.20% 34.20% 17.00% 5.00% 4.00% 3.00% 0.50% 0.20% 0.30% q . s . q.s. Manufacturing: I Dissolve 8 i n A. I 1 One a f t e r another, t h e components o f C are added t o I. I11 A t 25C, t h e components o f D t o I. SOURCE: Hoechst Aktiengesellschaft: Detergents and Cleaning Agents: Guide Formulations
  • 122.
    Thick Bleach-1 L iquid Ingredients.; A Genaminox MY Medialan LD NaOH (100%) B Water C Sodiumhypochlorite - s o l u t i o n (150 g/L a c t i v e c h l o r i n e ) D Perfume (e.g. Hypofresh) Manufacturing: I B i s added t o A. I 1 S t i r C t o I. I11 A t l a s t D i s added. V i s c o s i t y ( B r o o k f i e l d RVT, sp.4, 22C, mPas): 4800 m g k Bleach-2 I n g r e d i e n t s : A Genaminox MY Medialan LD NaOH (100%) B Water C Sodiumhypochlorite - s o l u t i o n (150 g/L a c t i v e c h l o r i n e ) D Perfume (e.g. Hypofresh) Manufacturing: I B i s added t o A. I 1 S t i r C t o 1. 111 A t l a s t D i s added. V i s c o s i t y ( B r o o k f i e l d RVT, sp.4, 22C. mPas): 600 12.000% 2.500% 1 .OOO% 34.475% 50.000% 0.025% 6.000% 1.000% 1.000% 41.975% 50.000% 0.025% SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Detergents and Cleaning Agents: Guide Formulations Laundry Products 99
  • 123.
    100 Advanced CleaningR&ctFormulotions Wool DeterQent, Medium Viscosity-A Marlon PS 65 Marl inat 242/28 Marlamid DF 1218 Balance water. dyestuff, fragrance, preservative. sodium c h l o r i d e Active matter: 20.5% Wool Detergent. Medium Viscosity-B Marlon PS 65 M a r l i n a t SRN 30 D i o n i l OC Balance water, dyestuff, fragrance, preservative, sodium c h l o r i d e Active matter: 20.0% Wool Detergent. Medium V i scositv-A Marlon AS3 Marl inat 242/28 Ammonium hydroxide, 25% Urea Balance water, fragrance, dyestuff, preservative. sodium c h l o r i d e Active matter: 19.0% Wool Detergent. Medium Viscosity-B Marlon A 375 Marl inat 242/28 Marlamid DF 1218 Balance water, fragrance, dyestuff, preservative, sodium c h l o r i d e Active matter: 20.5% % 18.0 28.0 1.o t o 100 % 20.0 20.0 1.o t o 100 % 12.0 18.0 3.0 3.0 to 100 % 15.6 28.0 1.o t o 100 SOURCE: Huls America, Inc.: Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes
  • 124.
    9. Metal Cleanersand Polishes 101
  • 125.
    102 Advanced CleoningProduct Formulations A l u m i nun C1eaner/Bri shtener Acid Cleaner for Aluminum Wheels and T r a i l e r s Inqredi ent : Deionized Water Phosphoric Acid (85%) C i t r i c Acid (50%) N i t r i c Acid (70%) Avanel S-70 Wt.% 83.00 6.00 8.00 1.oo 2.00 pH (as i s ) : <2.0 Appearance: Clear, white-water l i q u i d Charge t h e water t o an appropriate mixing vessel. Charge WARNING: Use a l l manufacturer precautionary s a f e t y meas- Procedure: remaining ingredients i n t h e order l i s t e d w h i l e continuing a g i t a t i o n . ures when hand1 ing concentrated a c i d s o l u t i o n s . Formula CM-101 A1urninum Smut C1eaner High Temperature D i l u t a b l e Acid Concentrate I n s r e d i ent : Deioni zed Water C i t r i c Acid (50%) Gluconic Acid (50%) Avanel N-1525-90 Avanel S-70 Ammoni um B i f 1u o r i de Wt.% 19.00 50.00 25.00 3.00 1.50 1.50 pH (as i s ) : <2.0 Appearance: Clear, water-white t o l i g h t - y e l l o w l i q u i d S p e c i f i c G r a v i t y : 1 .18 Procedure: Charge t h e water and two acids under a g i t a t i o n . Continue a g i t a t i o n and add t h e Avanel surfactants; mix u n t i l dissolved. Add Ammonium B i f l u o r i d e and mix u n t i l dissolved. Use D i r e c t ion8 : Use temperature o f d i l u t i o n i s normally 140-15OF. Notes: This formula was developed t o remove stamping o i l smut from aluminum cans. Cans should be thoroughly r i n s e d a f t e r cleaning Formula CM-104 SOURCE: Mazer Chemicals: SUQQeSted Formulations Use i n pressure wash a t a r a t e o f 2-4 ounces per gallon.
  • 126.
    Metal Cleaners andPolishes 103 Alumcnum Cleaner Concentrate Water Sodium M e t a s i l i c a t e (Anhydrous) Tetrapotassium Pyrophosphate (Powder) Mona NF-10 % by Weiqht 75 10 5 10 Procedure: i n water w i t h mixing, then add Mona NF-10. Typical Properties: Appearance: Clear l i q u i d Cloud Point: 88C Dissolve sodium m e t a s i l i c a t e and tetrapotassium pyrophosphate Recommended Use D i l u t i o n : 1 t o 4 oz/gal. Formula F-498 A1umi num Wash Water Sodium M e t a s i l i c a t e (Anhydrous) Tetrasodium Pyrophosphate (Powder) B u t y l Carbi t o 1 Mona NF-10 % by Weight 88 2 3 2 5 Procedure: i n water, then add Butyl C a r b i t o l and Mona NF-10. Typi c a l Properties : Dissolve sodium m e t a s i l i c a t e and tetrasodium pyrophosphate Appearance: Clear l i q u i d pH: 1 2 . 8 Recommended Use D i l u t i o n : 1:lO w i t h water Formula F-499 SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formulations
  • 127.
    104 Advanced CleaningR&tFormulations Cleaners and Cleanina Solutionq Metal Cleani na-A1 k a line Inaredients: Aerosol 22 Surfactant Sodium Carbonate Sodi um Metasi 1icate Sodium Hydroxide % by Weiaht 10.0 40.0 20.0 10.0 Grind the powders together and add t h e Aerosol 22 slowly while grinding. Metal C1eani na-Aci d Inqredients: Dowanol EB Phosphoric Acid (85%) Aerosol 22 Surfactant Water Metal C leanina-Pai n t Removal Insredients: Aerosol C-61 Surfactant Sodium Carbonate Sodium Metasilicate Sodi um Hydroxide % by Wei aht 6.0 7 . 0 0 . 3 8 6 . 7 % by Wei aht 20.0 40.0 30.0 10.0 Grind t h e powders together and add t h e Aerosol C-61 slowly while mixing. Metal Cleaning-Rust Removal Ineredients: Aerosol 0s Surfactant Sodium B i f l u o r i d e Sodium Tetraphosphate Sodium B i s u l f i t e % by Weight 10.0 7 5 . 0 10.0 15.0 SOURCE: Cytec Industries Inc.: Suggested Formulations
  • 128.
    Metal Cleanersand Polishes105 Comer C leani ng Inaredients: Aerosol A-102 Surfactant Sodium Chloride C i t r i c Acid Eentonit e Water Aluminum Cleaning - A c i d Inaredients: Phosphoric Acid (65%) Hydrofluoric Acid (48%) Glacial Acetic Acid Aerosol 0s Surfactant Water A1uninum C1eanina-Bri ahtening Ingredients: Phosphoric Acid (85%) Aerosol 22 Surfactant Aerosol 0s Surfactant Butyl Cellosolve Water Aluminum Aircraft-Brightener (U.S. Ingredients: Aerosol 0s Surfactant Aerosol 22 Surfactant C i t r i c Acid Arnmoni urn B i f 1u o r ide Benzenesulfoni c Acid Phosphoric Acid (85%) Water % bv Weiaht 2.0 5.0 5.0 22.0 66.0 % bv Wei Qht 15.0 2.0 3.0 5.0 75.0 % by Wei Qht 47.2 1.o 1.o 16.0 34.8 Patent 2.68Y.3461 % bv Weiaht 3.0 9.0 5.0 3.0 10.0 2.4 26.4-52.6 SOURCE: Cytec In d u stri e s Inc.: Suggested Formulatlons
  • 129.
    lo6 Advanced CleaningProductFormulations E le c t r o c leaner Components: Water Burco BSGH-400 Burco NPS-225 Burco TME 50% NaOH % by Weiaht 2-0 1-4 0.75-3 0.25-1 To 100% Total Basic formulating guidelines: 1) Ratio o f Burco NPS-225/Burco TME should be 3/1. 2) The l e v e l o f Burco BSGH-400 i s p r e fe r ably equal t o the sum 3 ) The water charge should be equal t o the sum o f Burco BSGH-400, 4) Premix a l l components but NaOH. then add NaOH w i t h s t i r r i n g . This formulation w i l l provide moderate foam l e v e l s and i s s u i t a b l e f o r use as an electrocleaner, food p l a n t cleaner o r other applicatio n s where high ca u sti c concentrates are used. For reduced foam l e v e l s as i n an a l k a l i n e spray cleaner, replace Burco NPS-225 w i t h Burco HCS-50NF. o f Burco NPS-225 and Burco TME. Burco NPS-225 and Burco TME. Moderate A1k a l in it y , Soi 1 So1it t i n a Soak Cleaner ComDonents: Water Sodium Metasilica te (Pentahydrate) Trisodium Phosphate (Crystals) Burco ADS-40 Burco EHS Burco TME % bv Weiaht 70 5 10 5 5 5 Procedure: Add components i n th e order l i s t e d . S t i r u n t i l homogeneous between each addition. SOURCE: Burlington Chemical Co., I n c . : Suggested Formulations
  • 130.
    Metal Cleanersand Polirhes107 Hiah-Foaming A c i d Scrubber* Formula BC-0003 Miranol FBS Igepal CO 630 Sulfamic A c i d G1ycol ic (Hydroxyaceti c ) Acid (70%) Butoxyethanol Water Wt.% 5.0 2.0 4.0 4.0 3.0 82.0 Procedure olved. Add t h e remaining i n g r e d i e n t s , w i t h mixing. Mix u n t i l uniform. Add t h e water, sulfamic and g l y c o l i c acids. Mix u n t i l d i s s - Physical ProDerties Appearance: Clear l i q u i d. . pH, as i s : 1.5 S p e c i f i c G r a v i t y : 1 V i s c o s i t y : t10 cps * S u i t a b l e f o r appl i c a t Rhodafac RE-61 0 Igepal CO-630 Phosphoric Acid, 75% Water 027 ons w i t h a t r i g g e r - t y p e sprayer. A c i d Cleaner Formula BC-0004 Wt.% 3.0 4.0 10.0 83.0 Procedure Add phosphoric a c i d t o water and heat w i t h a g i t a t i o n t o 50C. w i t h r a p i d b u t smooth a g i t a t i o n . Slowly blend i n Rhodafac RE-610 and Igepal CO-630. Once system i s completely uniform, cool w i t h s t i r r i n g t o 40-45C, and package. Physical ProDertiea Appearance: S l i g h t l y hazy l i q u i d pH, as i s : 1.6 Speci f i c G r a v i t y : 1.03 V i s c o s i t y : 20 cps SOURCE: Rhone-Poulenc S u r f a c t a n t s 8 Speci'alties: Formulas
  • 131.
    108 Advanced CleaningProductFotmulations Metal C1eaner and Deereaser InQredi ents: Monoethanolamine Sodium DDBSA, 35% Sandoxylate SX 400 Sodium EDTA Water Oleic Acid D-Li monene Butyl Cellosolve % bv Weight 5.0 12.0 5.0 0.5 50.5 10.0 3.0 6.0 Procedure: add DDBSA. Mix i n Sandoxylate SX 400, and EDTA. Warm t o 50C, add the o l e i c a ci d slowly, w h i l e increasing t h e a g i t a t i o n . When t h e o l e i c a c i d has completely reacted, add D-Limonene and Butyl Cellosolve. Cool w i t h s t i r r i n g t o 40C. B o t t l e . Properties: Charge monoethanolamine and water t o vessel. With s t i r r i n g . pH (as i s ) : 10.0 Viscosity: Approx. 100 cps Br o o kfi e l d LVT, Spindle #2 @ 12 rpm % Solids: 26% SOURCE: Sandoz Chemicals Corp.: Formulation HHG-10 Thickened Clear Deareaser Concentrate Water, D . I . DeSonic 9N Varonic DM55 d ' L imonene % by Weight 42.5 25.0 12.5 20.0 Blend1ng Procedure: each addition. Typical Properties: Viscosity, cps: 363 Solids: 37.5% pH: 5.9 Add ingredients i n order shown and dissolve completely between SOURCE: Witco Corp.: Formula 805
  • 132.
    Metal Cleanersand Polishes109 Stainless Steel Cleaner-A M a r l i p a l KF Marlophor CS a c i d Solvent BG* Balance water, fragrance, dyestuff, preservative Active matter: 1.0 V i scosi t y : 1iqui d S t a i n less Steel C1eaner-B Mar1ip a l 013/99 Aluminum oxide FPTO I s o p a r a f f i n . e.g. Shellsol T Balance water, fragrance, dyestuff, preservative A c t i v e matter: 5.4 V i s c o s i t y : medi um Formulation B w i t h abrasive S i l v e r Polish, Liauid-A M a r l i p a l KF Thiourea Phosphoric acid, 85% Isopropanol* Balance water Active matter: 0.5% S i l v e r Polish. Liauid-B Marlazin L 10 Marlophor CS a c i d Thiourea Phosphoric acid, 85% Balance water % 1.o 10.0 5.0 t o 100 % 6.0 25.0 40.0 t o 100 % 0.5 6.0 2.0 3.0 t o 100 % 1.5 5.0 2.5 20.0 t o 100 Active matter: 1.5% SOURCE: Huls America, Inc.: Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes
  • 133.
    10. Oven, Grilland Hot Plate Cleaners 110
  • 134.
    Oven, Grill andHot Plate Cleaners 111 Pump Sprav Oven Cleaner -Ingredient; P a r t A : Vegetable gum (Veegum T) Xanthan gum Water -.Percent b v Wei q h t 1.2 0 . 4 78.9 P a r t B: L i q u i d C i t r i c Acid--50% (Haarman & Reimer Corp.) 7 . 0 Sodium h y d r o x i d e s o l u t i o n 50% 4.5 P a r t C: Amphoteric s u r f a c t a n t 8 . 0 Prepare P a r t A by s l o w l y adding v e g e t a b l e gum and xanthan gum t o t h e w a t e r . Continue a g i t a t i n g u n t i l smooth d i s p e r s i o n i s o b t a i n e d . t o a separate t a n k and n e u t r a l i z i n g i t w i t h t h e sodium h y d r o x i d e s o l u t i o n . The n e u t r a l i z a t i o n s h o u l d be done s l o w l y and c o n t i n - u o u s l y under a g i t a t i o n , as t h e r e a c t i o n i s h i g h l y exothermic. Prepare P a r t B ( t r i s o d i u m c i t r a t e ) by adding t h e c i t r i c a c i d Add P a r t B t o P a r t A, and f i n a l l y P a r t C . The f o r m u l a t i o n has t h e c o n s i s t e n c y o f a f l u i d g e l . I t may be used i n e i t h e r warm o r c o l d ovens. The s p r a y i n g s h o u l d be done a t a d i s t a n c e o f f r o m 10 t o 15 inches. Clean by w i p i n g a f t e r a t l e a s t 10 minutes o f r e a c t i o n t i m e . SOURCE: Haarman & Reimer Corp.: Suggested F o r m u l a t i o n C a u s t i c Oven C1eaner I n g r e d i egt_s_: % b y Weight ( 1 ) K o r t h i x H 2 . 0 ( 2 ) Kelzan 0.3 ( 3 ) Deionized Water 8 6 . 7 ( 4 ) Sodium Hydroxide (50%) 10.0 ( 5 ) Avanel S-74 1 .o Procedure: Add ( 1 ) t o ( 3 ) and mix a t h i g h speed. A f t e r ( 1 ) i s w e l l d i s - persed, add (2) and ( 5 ) . Reduce speed and add ( 4 ) c a r e f u l l y and s l o w l y . F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s of each p r o d u c t used. SOURCE: K a o p o l i t e , I n c . : Suggested F o r m u l a t i o n O v e n / G r i l l Cleaner Wt% Water 78 Tetrasodium EDTA 2 Sodium Hydroxide (50%) 15 Glucopon 425 CS 5 SOURCE: Henkel Corp., CD D i v i s i o n : Suggested F o r m u l a t i o n
  • 135.
    11 Polishes, Coatingsand Finishes 112
  • 136.
    Polishes, Coatings andFinishes 113 Aerosol F u r n i t u r e P o l i s h (Carbon D i o x i d e Propel l a n t l Materi a1s: P a r t A: Isopar E Hoechst Wax A3 CS SF 96 (100) V i s c a s i l (10,000) Span 80 P a r t 8: Water Procedure: 1.) Heat P a r t A t o 85C. 2 . ) Heat P a r t 8 t o 70C. 3.) Add P a r t 8 t o P a r t A w i t h h i g h shear mixing. 4.) Cool t o room temperature when homogeneous. Preparation o f Aerosol: Loadi ng: P o l i s h Concentrate Carbon Dioxide Aerosol Valve: P r e c i s i o n Valve P a r t Numbers: *This w i l l g i v e a can pressure o f approximately Button: P a r t No. 01-5843 (0.020" MBFT RS) Stem: P a r t No. 04-1215 (0.016") Gasket: P a r t No. 05-0310 (BUNA) Body: P a r t No. 07-1901 (0.080") 5.) Package i n s u i t a b l e containers. Part/Wt(%) 22.5 0.5 2.3 0.5 0.3 73.9 Part/Wt(%) 97.5 2.5* 105 p s i g . General Purpose L iauid Pol ish (Oil-In-Water Type) Mater ia1s : Part/Wt (%l P a r t A: SF 96 (350) 2.50 Hoechst Wax E 1.50 O l e i c Acid 1.50 P a r t 8: Water 70.05 Carbopol 934 0.25 Morphol ine 1.60 Kathon CG 0.10 P a r t C: Isopar M 2.00 SF 1706 1.50 P a r t D: K a o p o l i t e SF 8 . 0 0 Procedure: 1.) Heat P a r t A t o 95C. (2.) Heat P a r t B t o 85C. (3.) Add P a r t A t o P a r t 8 w i t h h i g h shear mixing. ( 4 . ) When homogeneous, cool t o 60C and add P a r t C w i t h h i g h shear mixing. ( 5 . ) Add P a r t D w i t h moderate mixing. ( 6 . ) Cool and package i n s u i t a b l e containers. V i s c a s i l (10,000) 1 .oo Isopar M 10.00 SOURCE: GE Si14cones: Formula FP 3003/Formula AP 1000
  • 137.
    114 Advanced CleaningRoduct Formulatiom Aerosol F u r n i t u r e P o l i s h IHydrocarbon ProDellant) M a t e r i a l s : P a r t A: Isopar E Hoechst Wax A3 CS S F 96 (100) V i scasi 1 ( 10,000) Span 80 Tween 81 P a r t B: Water Procedure: 1 . ) Heat P a r t A t o 85C. 2 . ) Heat P a r t B t o 70C. 3.) Add P a r t B t o P a r t A w i t h h i g h shear mixing. 4.) Cool t o room temperature when homogeneous. Preparation o f Aerosol: i o a d i ng : P o l i s h Concentrate A 46 P r o p e l l a n t Aerosol Valve : Preci s i on Valve P a r t Numbers : Button: Part No. 01-5843 (0.020" MBFT RS) Stem: P a r t No. 04-1240 (0.024") Gasket: P a r t No. 05-0310 (BUNA) Body: P a r t No. 07-1901 (0.080") 5. Package i n sui tab1e contai ners. F u r n i t u r e P a s t e m Materi a1s : Part A: Part/ W t 1%) 14.75 0.50 2.30 0.50 0.25 0.08 81.62 Part/WtC%) 90.0 10.0 V i scasi 1 (30,000) Hoechst Wax E Hoechst Wax F Ross Micro Wax 1135/15# Ross Ozokerite Wax 77Y P a r t B: Isopar L Procedure: 1.) Heat P a r t A t o 1OOC. 2.) Heat P a r t B t o 9%. 3.) Add P a r t 8 t o P a r t A w i t h g e n t l e mixing. 4.) Cool t o 50-52C w i t h g e n t l e mixing and pour i n t o containers. Allow c o n t a i n e r s t o cool b e f o r e capping. A f l o w o f a i r across surface o f c o n t a i n e r w i l l improve c o o l i n g process. M u l t i p l e pour c y c l e s can be used f o r deep containers. A l t e r n a t e Method: 1 . ) Heat P a r t A t o 100C. 2 . ) Add P a r t B (unheated) slowly w h i l e blending. 3 . ) Reheat P a r t AB u n t i l a c l e a r s o l u t i o n i s obtained. Follow above procedure from here. 7.0 7.0 3.0 6 . 0 1.o 76.0 SOURCE: GE S i l i c o n e s : Formula FP 3002/Formula FP 3004
  • 138.
    Polishes, Coatingsand FinishesI15 Detergent Resistant. Cream Cleaner P o l i s h I n g r e d i e n t s : % by ( 1) Deodori zed Kerosene ( 2 ) Hoechst Wax S (3) GP-7104 ( S i l i c o n e F l u i d ) ( 4 ) GP-10-1,000 c s t k (Dimethyl S i l i c o n e F l u i d ) ( 5 ) O l e i c Acid ( 6 ) S o f t Water ( 7 ) Morphol ine (8) S o f t Water ( 9 ) Mineral S p i r i t s (Low Odor) (10)Kaopolite SF Weight 10.0 8 . 0 3.0 4.0 1.o 2.4 0.8 38.8 20.0 12.0 Procedure: Combine (1) through ( 5 ) and heat t o 212F w i t h low t o moderate mixing. Remove heat, increase mixing and add ( 6 ) through (10) as i n s t r u c t e d below. Heat (6) t o 21OF, s t i r i n ( 7 ) , then pour i n t o t h e batch. Heat ( 8 ) t o 210F and add t o t h e batch. Add ( 9 ) then (10) slowly t o t h e batch, a l l o w i n g complete mixing o f each. Mix slowly u n t i l temperature o f batch reaches llOF. Package. Formula 4-2 Non-Abrasive, Detergent Resistant, Glaze Emulsion I n g r e d i e n t s : % by Weight ( A ) ( 1 ) GP-10-1,000 c s t k (Dimethyl S i l i c o n e F l u i d ) 3.0 (2) GP-7104 ( S i l i c o n e F l u i d ) 3 . 0 ( 3 ) Hoechst Wax S 1.5 ( 4 ) Carnauba Wax #3 1.o ( 5 ) O l e i c Acid 1.5 ( 6 ) Mineral S p i r i t s 4.6 (B) ( 7 ) S o f t Water ( 8 ) Carbopol 934 ( 9 ) Triethanolamine 99% (10) Morphol ine 83.6 0 . 2 0.2 1.4 Procedure: (A) Combine (1) through (6) and heat t o 150F w i t h mixing. (B) Heat ( 7 ) t o 1OOF. With h i g h shear mixing add ( 8 ) t o ( 7 ) . Once (8) i s dissolved add (9) and then add (10). Add ( A ) t o (B) slowly, w i t h high shear mixing. Continue mixing u n t i l emulsion reaches 70F. Package. Formula 8-1 SOURCE: Genesee Polymers Corp.: Suggested Formulations
  • 139.
    I16 Advanced CleaningProductFormulations Hiah G1oss. Detereent Resistant. S o f t Paste Pol ish Inqredients: (A) ( 1 ) Hoechst Wax OP (2) Hoechst Wax E (3) Ozokerit e % bv Weight 7.0 8.0 1.5 (B) ( 4 ) GP-7104 ( S i l i c o n e F l u i d ) 3.0 (5) GP-10-1,000 c s t k (Dimethyl S i l i c o n e F l u i d ) 3.0 (6) GP-10-12,500 c s t k (Dimethyl S i l i c o n e F l u i d ) 2.0 (7) Mineral S p i r i t s (Low Odor) 36.0 ( 8 ) Deodorized Kerosene 9.5 (9) Kaopolite SF 12.0 (10) Mineral S p i r i t s (Low Odor) 18.0 Procedure: (A) Combine ( I ) , (2), and (3), heat t o 230F t o melt waxes. (B) Separately mix and heat ( 4 ) , ( 5 ) , ( 6 ) , (7), and (8) t o 160F. Slowly add (B) t o (A) w i t h mixing. Temperature o f batch a f t e r adding (B) t o (A) should be 195F. Add (9) then (10) t o batch w i t h mixing. Remove heat and mix w e l l u n t i l temperature reaches 140F. Package. Formula 5-2 Detergent Resistant Cream P o l i s h Inqredi ents: ( 1 ) Witconol 14 (2) GP-10-1,000 c s t k (Dimethyl S i l i c o n e (3) Carnauba Wax #3 (4) Isopar L (5) Morphol ine (6) GP-7104 ( S i l i c o n e F l u i d ) (7) S o f t Water ( 8 ) Kaopolite SF % by Wei aht 1.5 F l u i d ) 3.0 10.0 25.0 0.4 3.1 47.1 10.0 Procedure: t o 195F w i t h mixing t o melt wax. Once wax i s melted, add ( 5 ) w i t h mixing. Add (6) t o mixture followed by t h e r e s t o f (41, keeping t h e temperature a t 175F. Remove from heat and mix u n t i l temperature reaches 130F. Package. Formula 3-2 SOURCE: Genesee Polymers Corp.: Suggested FormulatSons Combine ( I ) , (2), (3). and 50% o f (4) i n a container and heat
  • 140.
    Polishes, Coatingsand Finishes117 L i q u i d P o l i s h For Clear Coat F i n i s h e s Mater ia1_s ; Part/Wt(%) P a r t A: SF 96 (350) 3.50 Hoechst Wax S 1 .oo Hoechst Wax E 1.60 O l e i c A c i d 1.50 Isopar M 5.00 P a r t 0: Water 77.75 Carbopol 934 0.20 Morphol ine 1.60 Kathon CG 0.10 P a r t C: Isopar M I.oo SF 1706 0.75 P a r t D: Kaopol it e 1152 6.00 Procedure: 1.) Heat P a r t A t o 95C. 2 . ) Heat P a r t B t o 8%. 3.) Add P a r t A t o P a r t B w i t h h i g h shear mixing. 4 . ) When homogeneous, cool t o 60C and add P a r t C w i t h h i g h 5 . ) Add P a r t D w i t h moderate mixing. 6.) Cool and package i n s u i t a b l e containers. Mater ia1s : Part/Wt(%) P a r t A: SF 96 (350) 5.00 Hoechst Wax E 1.50 O l e i c Acid 1.50 P a r t 8: Carbopol 934 0.25 Morphol ine 1.50 Water 74.15 Kathon CG 0.10 Part C: SF 96 (100) 2.00 SF 1706 2.00 P a r t D: Kaopol it e 1152 7.80 Snow Floss 4.20 Procedure: 1 . ) Heat P a r t A t o 95-IOOC. 2 . ) Heat Part B t o 85C. 3 . ) Add P a r t A t o P a r t B w i t h h i g h shear mixing. 4 . ) When homogeneous, cool t o 60-70C and add P a r t C w i t h c o n t i n - 5 . ) When homogeneous, reduce mixing t o medium speed and s l o w l y 6.) Cool and package i n s u i t a b l e containers. SOURCE: GE S i l i c o n e s : Formula APlOOl/Formula AP1002 shear m i x i ng. L i q u i d Polish-No Solvent ued h i g h shear mixing. blend i n P a r t D.
  • 141.
    I18 Advanced CleaningProduct Formulations L i a u i d P o l i s h (Outer Phase O i l l Materials: Part A: V i s c a s i l (10,000) W i tcamide 511 Tween 81 Hoechst Wax OP Ross Ozokerite 77Y Isopar M Part 9: Water Kaopol it e 1152 Kaopolite SF Part C: Isopar L SF 1705 SF 1706 Procedure: 1.) Heat Part A t o 90-95C. 2.) Heat Part B t o 80C. 3 . ) Add Part B t o Part A w i t h high shear mixing. 4.) When homogeneous, cool t o 50-60C and add Part C 5 . ) Cool and package i n s u i t a b l e containers. Formula AP 1003 continued high shear m i x i ng. Part/Wt (%l 1.50 1.oo 0.15 1.30 0.20 20.00 55.85 4.50 4.50 6.00 3.00 2.00 w i t h Non-Wax L i a u i d P o l i s h (Oil-Pn-Water Tvoe) Materia1s: Part A: Part/Wt C%l SF 96 (350) 4.00 V i scasi 1 (10,000) 1.oo Isopar L 11.oo Oleic A c i d 1.50 Part 0 : Water 65.95 Carbopol 934 0.25 Morpholine 1.70 Kathon CG 0.10 Part C: Isopar M 4.00 SF 1706 1.50 Part D: Kaopol it e 1152 6.00 Snow Floss 3.00 Procedura: 1. ) Add Part A t o Part B w i t h high shear mixing. 2 . ) When AB i s homogeneous, add Part C. a l s o w i t h high shear m ix i ng. 3 . ) Add Part D w i t h moderate mixing u n t i l homogeneous. 4.) Package i n s u i t a b l e containers. Formula AP 1004 SOURCE: BE Slllconea: Suggested Formulations
  • 142.
    M a te r i a l s : SM 2133 20% Wax Emulsion Carbopol 934 Triethanolamine Water B i o c i de sm 2135 M a t e r i a l s : P a r t A: Cardis 36 Wax Hoechst Wax A3 CS O l e i c Acid Morpholine Part B: Water B i o c i de Polishes, Coatings and Finishes 119 L isuid F u r n i t u r e P o lish Part/Wt (%I 4.0 2.0 2.5 0.2 0.2 91.1 q . s 20% Wax Emulsion-1 20% Wax Emulsion-2 M a t e r i a l s : Part A: Cardis 36 Wax Hoechst Wax A3 CS O l e i c Acid D i e t h y l ami noethanol (DEAE) Part 8: Water B i oci de Part/Wt(%) 10.0 10.0 3.0 4.0 73.0 q . s . Part/Wt (%) 10.0 10.0 3.0 2.5 74.5 q . s . Preparation o f Wax Emulsion: 1.) Add Cardis 36 wax, Hoechst wax A3 CS, and o l e i c a c i d t o a 2.) When completely melted, add e i t h e r t h e morpholine o r DEAE u n t i l mixture i s homogeneous. 3.) Add P a r t B, preheated t o 95C, slowly s t i r r i n g t h e wax/soap mixture, maintaining temperature between 93 t o 98C during t h i s a d d i t i o n . 4.) Continue s t i r r i n g u n t i l temperature reaches 45C. 5 . ) Cool t o room temperature. Preparation o f Polish: 1 . ) Add water, biocide, and Carbopol 934 t o a vessel, and 2. ) Add t r i ethanol ami ne and mix u n t i 1 homogeneous. 3 . ) Add other ingredients. 4.) Combine w i t h m i l d mixing, and when homogeneous, package SOURCE: GE S i l i c o n e s : Formula FP 3000 vessel, and w i t h m i l d s t i r r i n g b r i n g t h e temperature up t o 96-1 OOC. d i s s o l v e t h e Carbopol w i t h good mixing. Warm water w i l l improve t h i s process. in s u i tab1e contai ners.
  • 143.
    120 Advanced CleaningRoductFormulatiotu L ia u i d Water-Based Glaze Mater ia1s : Part A: SF 96 (350) O l e i c Acid Hoechst Wax OP Cardis 36 Wax Isopar M Part B: Water Carbopol 934 Morpholine Kathon CG Part C: Isopar M SF 1706 Part/Wt(%) 3.50 1.50 1 .oo 1.50 6.00 82.55 0.25 1.60 0.10 1.so 0.50 Procedure: 1 . ) Heat Part A t o 95-1OOC. 2.) Heat P a r t B t o 90-95C. 3 . ) Add Part A t o Part B w i t h high shear mixing. 4.) Cool t o 60-70C and add Part C w i t h high shear mixing. 5 . ) Cool w i t h continued moderate mixing. 6.) Package i n s u i t a b l e containers. Formu la AP 1005 Solvent Wax G l aze M a t e r i a l s : Part A: SF 96 (1000) Hoechst Wax OM Hoechst Wax F Deodorized Kerosene Part B: Odorless Mineral S p i r i t s SR 107 Part/Wt (%l 3.0 0.6 1.4 1 0 . 0 84.0 1.0 Procedure: 1.) Heat P a r t A to 95C. Be sure a l l wax i s completely melted 2.) Add Part B w i t h moderate mixing. 3 . ) Continue mixing and cool t o room temperature. 4.) Package i n s u i t a b l e containers. Formula AP 1008 SOURCE: GE S i l i c o n e s : Suggested Formulations and d i spersed.
  • 144.
    Polishes, Coatingsand Finishes121 Paste P o l i s h (Oil-In-Water Type1 Part/Wt (%lMateri a1s: Part A: Hoechst Wax S Hoechst Wax OP SF 96 (350) V i s c a s i l (10,000) Stearic Acid Isopar M Isopar L Part 0: Water Morpholine Kaopol it e 1168 Super Floss Part C: Isopar M SF 1706 Procedure: 1 . ) Heat Part A t o 90-95C. 2.) Heat Part 8 t o 80-85C. 3.) Add Part A to Part B w i t h good mixing. 4.) When homogeneous, cool t o 60C and add Part C w i t h continued 5.) Cool t o s u i t a b l e pour temperature (<50C). 6.) Package i n s u i t a b l e containers. Comments: degree o f cooling a v a i l a b l e on t h e f i l l i n g l i n e . With slow c o o l i n g rate, t h e c o o l i n g c y c l e must be done without covers t o prevent condensation i n s i d e containers. mixing. The pour temperature w i l l depend on equipment and r a t e and 5.0 1.o 4.5 2.0 1.o 8.0 18.0 42.8 0.7 8.0 2.0 5.0 2.0 Spray-And-Wipe P o l i s h Mate r ia1s: SM 2109 AF 9020 Part/Wt(%) 8 . 0 0 0.05 Veegum Pro 0 . 8 0 Proxcel GXL 0.15 Kaopolite SF 5.00 Water 86.00 Procedure: 1 . ) Add water, Proxcel GXL. and Veegum Pro t o a mixing vessel, 2.) Add Kaopolite SF and continue mixing w i t h high shear u n t i l 3 . ) Reduce mixing t o low t o moderate and add AF 9020 and 4 . ) Package i n s u i t a b l e sprayable containers. SOURCE: GE Silicones: Formula BP 2001/Formula AP 1010 and, using high shear, disperse u n t i l uniform. a uniform f i n e dispersion i s obtained. SM 2109 emulsions. Do Not Overmix. These materials e a s i l y disperse i n a very short time period.
  • 145.
    122 Advonced CleaningProductFormulations Paste P o l i s h (Oil-In-Water TYDe)-(l) Materia1s : Part/Wt (%) Part A: SF 96 (350) 4.5 V i s c a s i l (10,000) 2.0 Hoechst Wax S 5.0 Hoechst Wax OP 1 .o S t e a r i c Acid Isopar M Isopar L Part 0: Water Morpholine Kaopolite SF Snow F1oss Kathon CG Part C: Isopar M SF 1706 Materi a1s : Part A: SF 96 (350) 1.o 8.0 18.0 42.7 0.7 8.0 2.0 0.1 5.0 2.0 Paste P o l i s h (Oil-In-Water Tyoe)-(Zl Part/Wt(%l 4 . 5 v i scasi 1 (i0,ooo) Hoechst Wax S Hoechst Wax OP S t e a r i c Acid Isopar M Isopar L Part 0: Water Morpholine Kaopolite 1152 Snow F1oss Kathon CG Part C: Isopar M SF 1706 2.0 5.0 1 .o 1.o 8.0 18.0 41.7 0.7 7.8 4.2 0.1 4.0 2.0 Procedure: 1.) Heat Part A t o 90-95C. (2.) Heat Part B t o 80-8512. 3.) Add Part A t o Part 0 w i t h good mixing. (4.) When homogeneous, 6.) Pour i n t o s u i t a b l e containers. Comments: The pour temperature w i l l depend on equipment, r a t e and degree o f c o o l i n g a v a i l a b l e on the f i l l i n g l i n e . With slow c o o l i n g r a t e , t h e c o o l i n g c y c l e must be done without covers t o prevent condensation i n s i d e containers. SOURCE: GE S i l i c o n e s : Formula AP 1008 cool t o 60C and add Part C w i t h continued mixing. ( 5 . ) Cool t o s u i t a b l e pour temperature, e.g., >50C.
  • 146.
    Polishes, Coatingsand Finishes123 Paste Polish ( O i p Meteri a1s: Part/Wt t % l Part A: SF 96 (350) 4.5 V i scasi 1 (10,000) 2.0 Hoechst Wax S 5.0 Hoechst Wax OP 1.o S t e a r i c Acid 1.o Isopar M 8 . 0 Isopar L 18.0 Part B: Water 42.7 Morphol ine 0.7 Kaopolit e 1152 7.5 Snow Floss 2.5 Kathon CG 0.1 Part C: Isopar M 5.0 SF 1706 2.0 1 . ) Heat Part A t o 90-95C. 2 . ) Heat Part 8 t o 80-85C. 3 . ) Add Part A t o Part B w i t h good mixing. 4 . ) When homogeneous, cool t o 60C and add Part C w i t h cont- 5 . ) Cool t o s u i t a b l e pour temperature, e.g., >5OC. 6. ) Pour in t o s u i t a b l e contai ners. Comments : The pour temperature w i l l depend on equipment, r a t e and degree o f cooling on t h e f i l l i n g l i n e . With slow cooling rate, t h e c o o l i n g c y c l e must be done without covers t o prevent condensation inside contai ners. Materials: Part/Wtt%) Part A: V i s c a s i l (10,000) 2.50 Hoechst Wax S 1.80 Hoechst Wax E 2.00 Ross Ozokerite 77Y 0.15 Span 80 2.00 Tween 81 0.15 Isopar L 17.00 Isopar M 5.00 Part B: Water 52.40 Kaopol it e 1152 6.00 Snow Floss 3.00 Part C: Isopar M 2.00 SF 1705 4.00 SF 1706 2.00 1. Heat Part A t o 95C. ( 2 . ) Heat Part B t o 8OC. ( 3 . ) Add Part B t o Part A w i t h high shear mixing. (4.) Cool t o 60-65C and add Part C w i t h good mixing. (5.) Cool t o 55C and pour i n t o s u i t a b l e containers. inued m i x i ng. Paste P o l i s h (Outer Phase O i l 2 SOURCE: GE Silicones: Formula AP 1006(3)/AP 1007
  • 147.
    124 Advanced CleaningProductFormulations Spray-And-Wipe P o l i s h (Pump) Mater ia1s 1 SM 2133 SM 2135 20% Wax Emulsion Water B i o c i de M a t e r i a l s Part A : Cardis 36 Wax Hoechst Wax A3 CS O l e i c Acid Morpholine Part B: Water B i o c i de 20% Wax EmulKion-.(a Mateyjal s : Part A: Cardis 36 Wax Hoechst Wax A3 CS O l e i c Acid Diethylaminoethanol (DEAE) Part B: Water B i o c i de Part/Wt(%) 3.0 2 . 0 2 . 5 92.5 q . s . 20%Wax .Emu 1sionr--l ) SartfW t f U 10.0 10.0 3.0 4.0 73.0 q . s 10.0 10.0 3.0 2.5 74.5 q . s . Preparation o f Wax Emulsion: 1 . ) Add Cardis 36 wax, Hoechst wax A3 CS, and o l e i c a c i d t o a vessel and, w i t h m i l d s t i r r i n g , b r i n g temperature up t o 98-1ooc. 2.) When completely melted, add e i t h e r t h e morpholine or DEAE u n t i l m i x t u r e i s homogeneous. 3.) Add Part B, preheated t o 95C, slowly s t i r r i n g t h e wax/soap mixture, maintaining temperature between 93 and 9BC d u r i n g t h e a d d i t i o n . 4.) Continue s t i r r i n g u n t i l temperature reaches 45C. 5.) Cool t o room temperature. Preparation o f P o l i s h : package i n s u i t a b l e containers. SOURCE: GE S i l i c o n e s : Formula FP 3001 Blend a l l i n g r e d i e n t s together w i t h m i l d s t i r r i n g , and
  • 148.
    Polishes, Coatings andFinishes 125 Spray 8 Wipe Type-Aerosol o r Non-Aerosol(1) Concord Co-Wax Emulsion, 12% S i 1icone (Union Carbide LE-461) D i s t i 11ed Water % by Weiaht 4.1 7.0 88.9 Spray 8 Wipe- Type-Aerosol o r Non-Aerosol(E] Concord Co-Wax Emulsion, 12% S i l i c o n e (Union Carbide LE-461) S i l i c o n e (Union Carbide LE-462) D i s t i 11ed Water Weisht 7.5 12.5 2.5 77.5 Spray & Wipe Type-Aerosol o r Non-Aerosol(3) Concord Co-Wax Emulsion, 12% S i 1icone (Union Carbide LE-461) S i l i c o n e (Union Carbide LE-462) T r i ethanol ami ne Lauryl S u l f a t e D i s t i 1l e d Water % by Weiqht 7.5 12.5 2.5 1 . 5 76.0 The formulas l i s t e d above a r e suggested formulas. Every e f f o r t has been made t o o p t i m i z e a l l p r o p e r t i e s t o get t h e best p o l i s h w i t h regard t o s p e c i f i c amounts o f i n g r e d i e n t s . Formula #1 i s t h e b e s t a l l around p o l i s h . I t f e a t u r e s e x c e l l e n t gloss, a p p l i c a t i o n ease and economy. Formula #3 i s an example o f l i g h t foam-type p o l i s h , and o f f e r s b e t t e r removal o f s o i l and emuls- i f i c a t i o n o f p r o p e l l e n t s . Formula #2 i l l u s t r a t e s a h i g h g l o s s formula w i t h e x c e l l e n t p r o t e c t i v e q u a l i t i e s . L i q u i d Wax-Solvent F u r n i t u r e o r F l o o r P o l i s h Concord Wax #1600 S i l i c o n e General E l e c t r i c SF 96-100 Safety Solvent (Stoddard Solvent) % by Weight 6.0 1 .o 93.0 Procedure: M e l t wax and s i l i c o n e together a t a temperature o f 195-200F i n one h a l f o f t h e s o l v e n t . The balance o f t h e c o l d s o l v e n t i s then added t o t h i s s o l u t i o n a f t e r t h e waxes a r e melted. SOURCE: Concord Chemical Co., I n c . : Suggested Formulations
  • 149.
  • 150.
    RinseAids 127 Automatic DishwashRinse A i d (For Hard Water1 A c i d Hard Water Tolerant Formulation Inaredient : Oeioni zed Water Mazawet 36 G l y c o l i c Acid (57%) Isopropyl Alcohol pH, 1%: 2.0-3.0 Appearance: Clear, s l ight S p r c i f i c Gravity: 1.01 y viscous, l i g h t - y e l l o w Wt.% 30.00 55.00 10.00 5.00 iqui d Procedure: Charge t h e water and Mazawet 36 t o t h e mixing vessel and s t a r t a g i t a t i o n . Charge the G l y c o l i c Acid and Isopropyl Alcohol and mix u n t i l c l e a r and f r e e o f " f i s h eyes." Notes : Formulated f o r areas w i t h hard water. Normal use d i l u t i o n i s 100 ppm i n f i n a l r i n s e cycle. Conc- e n t r a t i o n s o f use s o l u t i o n s may be adjusted t o meet l o c a l needs o r v a r t a t i o n s i n equipment. Formula CR-101 Automatic Dishwash Rinse A i d <For Neutral o r S o f t Water) Standard Formulation f o r Neutral o r Soft Water Ingredient: Mazawet 36 Oeioni zed Water Isopropyl A1coho1 Sodi um Hydroxide Wt.% 55.00 40.00 5 . 0 0 P.S. t o pH 6.0-7.0 pH. 1%: 6.0-7.0 Appearance; Clear, s l i g h t l y viscous, l i g h t - y e l l o w l i q u i d S p e c i f i c Gravity: 1.01 Procedure: u n t i l c l e a r and f r e e o f " f i s h eyes." Notes : Formulated f o r areas w i t h neutral o r s o f t water. Normal use d i l u t i o n i s 100 ppm i n f i n a l r i n s e cycle. Conc- e n t r a t i o n s o f use s o l u t i o n s may be adjusted t o meet l o c a l needs o r v a r i a t i o n s i n equipment. The formulator may adjust t h e cloud-point o f t h i s system by using a d d i t i o n a l alcohol t o increase i t o r Sodium Hydroxide t o decrease i t . Formula CR-102 SOURCE: Mazer Chemicals: Suggested Formulations Charge t h e ingredients i n t h e sequence given above and mix
  • 151.
    128 Advanced CleaningProductFormulations Rinse A i d Formula DW-0011 Antarox BL-240 Urea Water Dye Wt.% 50.0 9.0 41 . O Procedure 1. Dissolve urea i n water. 2. Add Antarox BL-240 t o water/urea s o l u t i o n . Mix thoroughly. Physical PrpDertiea pH (as i s ) : 7.5 pH (1%): 8.1 Viscosity: 50 cps S p e c i f i c G r a v i t y : 1.01 Rinse A i d Formula DW-0012 Antarox BL-225 Isopropanol Water Dye Procedure 1. Dissolve Antarox BL-225 i n water. Mix thoroughly. 2. Add isopropanol. Physical Properties pH (as i s ) ; 6.1 pH (1%): 8.3 V i s c o s i t y : 30 cps S p e c i f i c Gravity: 0.99 SOURCE: Rhone-Poulenc Surfactants & Specialties: Formulas Wt.% 70.0 20.0 10.0 -
  • 152.
    13. Rug, Floor,Carpet, Upholstery Shampoos and Cleaners 129
  • 153.
    130 Advanced Cleaningproduct Formdations Basic Floor Cleaner. Liauid-A Marlon A 360 o r A 365 Marl ipal 013/99 Solvent BG* Tetrapotassium pyrophosphate Sodi um metasi 1i c a t e pentahydrate KNA cumene sulphonate 40 Ammonia, 25% Balance water, fragrance, preservative Active matter: 7.0% Basic Floor C1eaner, L iauid-B M a r l i p a l 013/99 Marlowet 5622 Solvent BG* Tetrapotassium pyrophosphate Ammonia, 25% Balance water, fragrance, preservative Active matter: 6.7% Floor Cleaner. f o r Everyday Use. Liauid-A Marlon PS 65 L ipoxol 12000* Marlamid DF 1218 Isopropanol* Fragrance Balance water, d y e s t u f f Active matter: 4.7% Floor Cleaner. f o r Everyday Use. Liauid-B M a r l i p a l KF C i t r i c a c i d Isopropanol* Fragrance Balance water, d y e s t u f f % 7.0 3.0 3.0 5.0 5.0 10.0 1 .o t o 100 !% 3.0 4.0 20.0 3.0 1 .o t o 100 % 5.0 6.0 1.5 20.0 0 . 5 t o 100 !% 3.0 0.2 25.0 0.5 t o 100 Active matter: 3.0% SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes
  • 154.
    &g, Floor, Catpet,UpholsteryShampOchF and Cleaners 131 CarDet and UDhols t e w C1eaners Dry-Foam C 1eaner. L iauid-A M a r l i n a t SRN 30 Methacrylate copolymer, e.g. Syntran 6520 N i t r i l o t r i a c e t a t e powder Balance water, fragrance, preservative A c t i v e matter: 9.0% Dry-Foam C1eaner . L iauid-B M a r l i n a t SRN 30 N i t r i l o t r i a c e t a t e powder Balance water, fragrance, preservative A c t i v e matter: 12.0% Dry-Foam Cleaner. Powder-A M a r l i n a t SRN 30 Methoxypropanol Technocell 90 DU Balance water, fragrance, preservative A c t i v e matter: 1.5% Dry-Foam Cleaner, Powder-B M a r l i n a t DFK 30 Methoxypropanol Technocell 90 DU Balance water, fragrance, preservative % 3 0 . 0 20.0 1.o t o 100 % 40.0 0.5 t o 100 % 5 . 0 5 . 0 50.0 t o 100 % 5.0 5.0 50.0 t o 100 A c t i v e matter: 1.5% SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and Cleaning Agents f o r Houaehold Purposes
  • 155.
    132 Advanced CleaningProductFormulations Carpet Shampoo, Hiah Foam Water P e t r o BAF L i q u i d W i t c o l a t e WAC-LA Blending Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d . %__byWeigh2 10.0 15.0 75.0 P e t r o BAF, i n combination w i t h sodium l a u r y l s u l f a t e , reduces t h e low temperature c l o u d p o i n t , g i v i n g e x c e l l e n t freeze/thaw p r o p e r t i e s . The Petro BAF combination d r i e s l e s s tacky than sodium l a u r y l s u l f a t e alone. Formula 911 Carpet. Shampoo, H i &h -Foam Water P e t r o BAF L i q u i d W i t c o l a t e WAC-LA ?4 by Weight 78.3 5 . 0 1 6 . 7 B1endi ng Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d . P e t r o BAF, i n combination w i t h sodium l a u r y l s u l f a t e , reduces t h e low temperature c l o u d p o i n t , g i v i n g e x c e l l e n t freeze/thaw p r o p e r t i e s . The P e t r o BAF combination d r i e s l e s s tacky than sodium l a u r y l s u l f a t e alone. Formula 908 SOURCE: Witco Corp.: Suggested Formulations
  • 156.
    Rug Floor, Carper,Uphktety Shampoos and Cleaners 133 Evaporative (No Rinse) Wax S t r i p p e r Formula FC-0056 Miranol JEM Concentrate Monoethanolami ne Butoxyethoxypropanol Isopropanol Water Procedure Phvsic a l ProDerti es Add t h e ingredients and mix u n t i l uniform. Appearance: Clear s o l u t i o n pH, as i s : 1 1 . 4 Viscosity: t 1 0 cps S p e c i f i c Gravity: 0.97 Waxed F l o o r Cleaner Formula FC-0055 Rhodafac RA-600 A1kamide DC 212/S Tetrapotassium Pyrophosphate (60% Active) Water Wt.% 0.5 6.5 2.5 1 9 . 0 '72.5 Wt.% 5.0 1 .o 25.0 69.0 =Q a f t e r each a d d i t i o n . Add ingredients one by one, i n order l i s t e d above, mixing well Phvsi c a l ProDerti es pH. as i s : 8.6 pH (1%): 8.6 V i s c o s i t y : 10 cps S p e c i f i c Gravity: 1 . 0 4 SOURCE: Rhone-Poulenc Surfactants & Specialties: Formulas
  • 157.
    134 Advanced CleaningproductFormulations F1oor C leaner Formula FC-0053 Rhodafac LO-529 Sodi um Tripolyphosphate Tetrasodium Pyrophosphate Water Wt.% 6.0 3.0 3.0 8 8 . 0 Procedure 1. Dissolve s o l i d s i n t h e t o t a l amount o f water. 2. Add Rhodafac LO-529. Mix thoroughly. Phvsic a l ProDerties pH, as i s : 13.9 pH (1%): 8.9 V i s c o s i t y : 60 cps S p e c i f i c G r a v i t y : 1.09 F l o o r Cleaner Formula FC-0054 Wt.% Rhodafac LO-529 5.0 A1kami de DC-212/S 1.o Tetrasodium Pyrophosphate (65% Active) 2.0 T r i sodi um Phosphate 1.o Diethylene Glycol Monoethyl Ether 1.o Water 90.0 Perfume and Colorants added, as desired, r e p l a c i n g water Procedur e 1. Dissolve Tetrasodium Pyrophosphate i n water. Add Trisodium 2. Add Rhodafac LO-529 and Alkamide DC-212/S. 3. Add solvent. Phosphate. D i ssol ve thorough1 y . 1 pH. as i s : 11.0 pH (1%?: 9.0 V i s c o s i t y : 290 cps S p e c i f i c Gravity: 1.01 SOURCE: Rhone-Poulenc Surfactants & S p e c i a l t i e s : Formulas
  • 158.
    F l oo r P o l i s h Mor-Glo 2-457 20% S o l i d s Use w i t h low speed spray b u f f i n g and high speed maintenance programs using p l u g - i n e l e c t r i c burnishers and s y n t h e t i c pads. Produces higher i n i t i a l gloss than t h e 442 formulation. Can be burnished d a i l y o r on an i n t e r m i t t e n t schedule without producing excessive amounts o f dust. M u l t i p l e recoats o f 4-5 coats per a p p l i c a t i o n are recommended w i t h 30-45 min. d r y i n g time depending on s o l i d s . With these maintainance procedures a consistent h i g h l e v e l o f appearance can be sustained over an extended p e r i o d o f time. ___Item: 1 2 3 4 5 6 7 8 9 10 Components: Wei Qht Water Diethylene Glycol Monoethyl Ether T r i butoxyethyl Phosphate Fluorad FC-129 (1% a c t i v e s o l u t i o n ) A n t i foam Emu1s i on* Proxel GXL Mor-Glo 2 Latex (38%) Morton Conrez 510 (25% s o l u t i o n ) AC-325 Anionic (35%) E-43 Nonionic (40%) Percent 47.07 3.37 2.95 0.50 0.02 0.10 39 9 49 1.oo 2.51 2.19 Procedure: With good a g i t a t i o n add t h e components i n t h e order l i s t e d . A f t e r t h e a d d i t i o n o f i t e m #6, a l l o w t o mix f o r 30 min. b e f o r e continuing. Add t h e remaining components slowly. Formulation Constants: Polymer/Resin/Wax Ratio: 90/0/10 Typical pH: 8 . 5 Formulation Density: 8.54 l b s . / g a l . S p e c i f i c G r a v i t y : 1.026 TvDi c a l Densi t y Val ues: __-S o l i d s : Pounds/Qal. 25% 8.60 20% 8.54 S p e c i f i c G r a v i t y 1.032 1.026 15% 8.49 1.019 *SAG 1010 from Union Carbide Corp., o r SWS 211 from Wacker S i 1icones Corp. SOURCE: Morton I n t e r n a t i o n a l , I n c . : Formula Mor-Glo 2-457 20% Sol i d s Rug, Floor, Carpet, UpholsferyShampom and Cleaners 135
  • 159.
    136 Advanced CleaningRoduct Formulations Floor P o l i s h ML-870-389 20% S o l i d s Use w i t h low speed spray b u f f i n g and high speed maintenance programs. This product maintains a high i n i t i a l gloss and can be burnished on an i n t e r m i t t e n t schedule. With these mainten- ance procedures, a consistent high l e v e l o f appearance can be sustained over an extended p e r i o d o f time. Up t o f i v e coats per a p p l i c a t i o n may be applied w i t h 30-45 min. d r y i n g t i m e depending on s o l i d s and conditions. Item: 1 2 3 4 5 6 7 8 9 10 1 1 12 Components: Water Diethylene Glycol Monoethyl Ether T r i butoxyethyl Phosphate D i b u t y l Phthalate Igepal CO 977 F l uorad FC-129 (1% s o l u t i o n ) Anti foam* Proxel GXL ML-870 Latex (38%) Morton Conrez 510 (25% s o l u t i o n ) AC-325 Noni oni c (35%) E-43 Nonionic (40%) W_eiqht Percent 42.36 4.97 1.24 0.65 0.20 0.60 0.02 0.10 34.89 7.45 4.01 3.51 Procedure: A f t e r t h e a d d i t i o n o f item #8, allow t o mix f o r 30 minutes before continuing. Add t h e remaining components slowly. Formulation Constants: Polymer/Resin/Wax Ratio: 74/10/16 Typical pH: 8.0 Formulation Density: 8.52 l b s . / g a l . Speci f ic Gravity: 1 .023 With good a g i t a t i o n , add t h e components i n the order l i s t e d . Typical Density Values: Sol i d s : Pounds/Gal . Speci f ic Gravity 25% 8.57 1.029 20% 8.52 1.023 15% 8.47 1.017 *SAG 1010 from Union Carbide Corp., o r SWS 211 from Wacker SOURCE: Morton I n t e r n a t i o n a l : Formulation ML-870-389 20% Solids S i 1icones Corp.
  • 160.
    Water SXS-40% Sodi um Bicarbonate STPP BurcosperseAP-Liq Burco LAF-6 Water Burcoterge DG-40 Burcosperse AP-Liq Propylene Glycol S o r b i t o l 70% Burcotase SL-80 Rug, Floor, Carpet, UpholsferyShampom and Cleaners 137 L iauid Carpet Cleaner Carpet S t a i n Remover-Liauid Carpet Cleaner/Booster-Dry Destainer Burco LAF-6 Soda Ash FB-Sodi um Percarbonate % bv We- 72.5 10.0 5.0 5.0 5.0 2.5 % by Weight To 100 40 10 20 15 0.5-1 .o 96 bv Weipht 2.0-6.0 40-60 40-60 Above a l s o eliminates odors such as those caused by pet urine. Generally 5 ounces o f above added t o 5 gallons o f detergent Oxidizes s t a i n s such as coffee, wine, j u i c e , e t c . s o l u t i o n i s s u f f i c i e n t f o r good performance. SOURCE: Burlington Chemical Co., Inc.: Suggested Formulations
  • 161.
    138 Advanced CleaningProductFormulations Low Cost E x t r a c t i o n CarDet Cleaner Water, D . I . Petro 22 Powder EDTA Powder Perfume Blending Procedure: Use D i l u t i o n : 1-2 ot/gal o f water Formula 901 Blend ingredients i n t h e order l i s t e d . % bv Weight 91 .o 5.0 4.0 Q . S . Medium Cost Steam E x t r a c t i o n Carpet Cleaner Water, D . I . Petro 22 Powder Sodi um T r i p o lyphosphate Sodium S i l i c a t e 42 Be' (Star)* T r i sodi um Phosphate, Crystal DeSonic 9N Perfume *Pa Corp. Blend ingredients i n t h e order l i s t e d 01end1ng Procedure: Use D i l u t i o n : 1-2 oz/gal . o f water Formula 902 % bv Weight 76.5 3.5 5.0 9.0 2.0 4.0 q . s . Premium. Heavy Duty Steam E x t r a c t i o n Carpet Cleaner Sodium Tripolyphosphate, L i g h t Density Sodium M e t a s i l i c a t e , Pentahydrate Petro 22 Powder Optical Brightener 01endi ng Procedure: Use D i l u t i o n : 1-2 oz/gal Formula 906 SOURCE: Witco Corp.: Suggested Formulations Blend ingredients i n t h e order l i s t e d . % by Weight 40.0 54.5 5 . 0 0 . 5
  • 162.
    Rug, Floor, Carper,Upholsteryshonrpocrs and Cleaners 139 Non-Ammaniated Floor S t r i m e r Water Sodium Metasilicate, Pentahydrate Monoethanolamine Potassium Hydroxide, 45% Witcamide S-771 Butyl Cellosolve Witconate SXS L i q u i d %-by Weight 65.44 1.oo 16.25 3.25 8.00 4.06 2.00 Blending Procedure: between each a d d i t i o n . Typical Properties: Solids: 13.3% pH, as i s : 13.3 Blend ingredients i n t h e order shown, mixing thoroughly Formula 924 Non-Ammoniated Floor S t r i m e r Monoethanolamine Witcamide S-771 Butyl Cellosolve 9b bv Weiaht 40.0 20.0 40.0 81endi ng Procedure: between each addition. Typical Properties: Solids: 20.0% pH, as i s : 11.4 Blend ingredients i n t h e order shown, mixing thoroughly Formula 923 SOURCE: Witco Corp.: Suggested Formulations
  • 163.
    I40 Advanced CleaningRh t FormJatiotu Quarry T i l e Cleaner I n q r e d i e n t s : Water Bi o-Soft S-1 00 Makon 10 Hydroxy A c e t i c A c i d (70%) HC1 (37%) M i x i ng Procedure : T y p i c a l P r o p e r t i e s : Mix thoroughly i n order given. Appearance: L i g h t yellow, c l e a r l i q u i d p H , as i s : 1.87 S p e c i f i c G r a v i t y , g/ml: 1.01 V i s c o s i t y , @ 25C, cps: 15 S t a b i l i t y : 40F ( 7 days): Pass 75F ( 7 days): Pass 120F ( 7 days): Pass Freeze/Thaw ( 3 c y c l e s ) : Pass % bv WeiQht 88.0 4.0 3.5 3.0 1 . 5 Use I n s t r u c t i o n s : pour concentrate d i r e c t l y on. Spread w i t h mop and leave f o r t e n minutes. Scrub and squeegee, r i n s e w i t h water. Dry w i t h c l e a n mop. leave f o r f i v e minutes, then scrub, r i n s e , and d r y . SOURCE: Stepan Co.: Formulation No. 582 One t i m e o n l y : H e a v i l y s o i l e d f l o o r : wet f l o o r w i t h water and D a i l y Cleaning: 4 oz/l gal water d i l u t i o n . Apply w i t h mop and Low Foam Floor Cleaner Water Sodium M e t a s i l i c a t e (Anhydrous) Tetrapotassium Pyrophosphate Mona NF-10 % by Weisht 70 5 14 11 Procedure: Add i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n . Typi c a l Propert ies : Cloud P o i n t : 93C K r a f t P o i n t : COC Recommended Use D i l u t i o n : 1 t o 4 o z . / g a l . SOURCE: Mona I n d u s t r i e s , I n c . : Formulation F-545
  • 164.
    Rug, Floor, Carpet,Uphoktery Shampoos and Cleaners 141 SDecia1-PurDose F l o o r C1eaner . L iauid-A Marlon A 365 Marlophor ND-DEA-salt Marlowet T or 5622 Na cumene sulphonate 40 T r i ethanol ami ne* Tetrapotassium pyrophosphate Balance water, fragrance, preservative Active matter: 16.5% Formulation A w i t h a n t i s t a t i c p r o p e r t i e s Special-Purpose Floor Cleaner. Liauid-6 Marlon PS 65 Isopropanol* Lonzabac 12.30 N i t r i l o t r i a c e t a t e , 40% Balance water, fragrance, preservative Active matter: 3.3% Formulation B w i t h microbicidal p r o p e r t i e s Wash-and-Wax Floor Cleaner. L iauid-A M a r l i p a l 013/79 Marlox FK 64 Marlowet 5622 N i t r i l o t r i a c e t a t e powder C i t r i c a c i d Wax emulsion. 15%. basis Vestowax AW 1060* Balance water, fragrance, preservative Active matter: 9.5% % 5.0 10.0 5.0 10.0 4.0 6.0 t o 100 % 5.0 25.0 3.0 0.5 t o 100 % 5.0 3.0 2.0 0.2 0.3 10.0 t o 100 Wash-and-Wax F1oor Cleaner, L iauid-B % Marl ip a l 013/60 8.0 Marlowet 5622 2.0 N i t r i l o t r i a c e t a t e powder 0.2 C i t r i c a c i d 0.3 Wax emulsion, 15%, basis Vestowax AW 1060* 10.0 Balance water, fragrance, preservative t o 100 Active matter: 10.0% SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes
  • 165.
  • 166.
    Miscellaneous 143 Condensate TL:Typical Formulations A l l Purpose Cleaner Condensate TL Harco 20% Soap STPP Water Bubble Bath Diethanolamine Laurel S u l f a t e (35% A c t i v e ) Stepanol DEA Condensate TL Water D i l u t a b l e Shampoo(l:8) Diethanolamine Laurel S u l f a t e (35% Active) Stepanol DEA Condensate TL Isopropanol H2S04 (conc.) (TO pH 7.0-7.5) V i scous Floor Cleaner Condensate TL TSPP STPP Harco 20% Soap Water 5 . 0 % 50.0% 1-2% To 100% 30.0% 5.0% 65.0% 60.0% 35.0% 1.15% 4% 9.0% 4.0% 4.0% 20.0% 63.0% Dishwashi ne L iaui d Sodium Xylene Sulfonate 4.0% Dodecylbenzene S u l f o n i c Acid 12.5% Noni oni c Detergent 6.0% Condensate TL 3.0% 50% Caustic Soda Adjust t o pH o f 7 . 0 + - 0 . 5 SDA 3A Alcohol 2.0 Dye 8 Perfume Water To 100% ODacified Hand SoaD Opaci f ie r Water Soluble Lanolin Condensate TL Conc. Coconut/Veg. O i l Potash Soap Perfume 8 Dye Water 0.70% 1.25% 12.5% 20.0% To 100% SOURCE: Concord Chemical Co., I n c . : Suggested Formulations
  • 167.
    I44 Advanced Cleaningproduct Formulations d' Limonene Waterless Hand Cleaner Phase I: Water, D.I. T r i sodi um Phosphate Sodium C i t r a t e G1y c e r i ne Phase 11: d ' L imonene DeSonic 9N Varonic T202 % by Weight 81 .o 1. o 2.0 2.0 7.0 5.0 2.0 Blending Procedure: Heat t o 140F. Combine Phase I1 ingredients i n separate vessel and mix thoroughly. Heat t o 140F. While mixing r a p i d l y , add Phase I1 t o Phase I. Cool q u i c k l y t o s t a b i l i z e emulsion. Typical Properties: Appearance, Room Temp.: Heavy Cream Solids: 12.0% pH: 10.4 I n vessel #1 combine Phase I ingredients and mix thoroughly. Formula 1120 Water1ess Hand C1eaner Emphos PS-220 Kerosene, deodorized Stoddard Solvent, deodorized T r i ethanol ami ne, 99% Water % by Weight 8.7 37.9 15.4 2.2 35.8 81ending Procedure: between each a d d i t i o n . Formula 1119 SOURCE: Witco Corp.: Suggested Formulations 01end ingredi ents in t h e order shown, m i x i ng thorough1y
  • 168.
    Miscellaneous 145 D ry Cleanina By using Aerosol OT-100% Surfactant i n d r y cleaning solvent a t a concentration o f ca. 0.1 oz./gal. t h e soaps used as aids i n water-soluble s t a i n removal can be replaced i n t h e d r y cleaning industry. I n contrast t o many soaps, Aerosol OT does not o x i d i z e w i t h consequent development o f undesirable odor upon aging. Aerosol OT-100% dissolved i n a s u i t a b l e solvent, such as t r i c h l o r o e t h y l e n e . naphtha, carbon t e t r a c h l o r i d e , or comb- i n a t i o n s o f these, can be used t o remove solvent-soluble s t a i n s a f t e r f a b r i c s have become wet w i t h water. The mixture can then be flushed out w i t h a d d i t i o n a l water. As a whitener f o r k i d gloves, i t i s recommended t h a t 4 oz. o f Aerosol OT-100% be dissolved i n a g a l l o n o f Stoddard solvent, t o which may be added from 4 t o 8 oz. o f zinc stearate. A water brushing f o r r e t a i n i n g p l e a t s i s made by d i s s o l v i n g 4 oz. o f Aerosol OT-100% Surfactant i n one-half g a l l o n o f Stoddard solvent, t o which i s added one p i n t o f wet spotter and one-half p i n t o f water. The pleated items should be brushed thoroughly w i t h t h e mixture, then simply hung i n t h e a i r t o dry, t o e l i m i n a t e water. The item should be re-cleaned w i t h solvent t o dispose o f t h e other agents present. It w i l l come out without wrinkles o r disturbed p l e a t s . S a t i s f a c t o r y s p o t t i n g mixtures can be made as follows: To1uol 3 q t . Perch1oroethyl ene 1 q t . Water 1/2 p t . 1 . Aerosol MA-80 Surfactant* 1 l b . * I f Aerosol OT i s used instead o f Aerosol MA, t h e mixture becomes t u r b i d when water i s added. 2. Aerosol OT-100% Surfactant 1 l b . Stoddard Solvent 2 g a l . Water 3 p t . I n order t o increase the wetting out (reduce t h e break time) o f exceptionally greasy a r t i c l e s , t h e use o f 0.25% to 1.0% of a 10% aqueous s o l u t i o n o f Aerosol OT Surfactant (based upon t h e weight o f t h e water) i s resorted t o occasionally i n laundry practices. During exceptionally busy periods, t h e use o f 10% aqueous Aerosol OT solutions w i l l reduce the treatment t me and thus increase e f f i c i e n c y , although i t i s t r u e t h a t a k a l i together w i t h hot water over a longer treatment period w 11 accomplish t h e same r e s u l t s . A l k a l i w i t h hot water f i x e s egg albumin whereas Aerosol OT Surfactant does n o t . SOURCE: Cytec I n d u s t r i e s Inc.: Suggested Formulations
  • 169.
    146 Advanced CleaningproductFormulations Dust Control Areas o f Use: o f t a l c o r face powder, m i l l i n g g r a i n and sawing wood are a l l f i r e , explosion and/or h e a l t h hazards. Such dusty conditions can be a l l e v i a t e d o r c o n t r o l l e d by water sprays containing small amounts o f Aerosol GPG Surfactant. Reasons f o r Using Aerosol GPO Surfactant: r a t i o n s o f o n l y 0.01% t o 0.05% o f Aerosol GPG Surfactant i n water provide e f f i c i e n t and economical wetting. Areas t o be Sprayed: c r e a t i o n o f dust. Dusty m a t e r i a l s being conveyed may a l s o be sprayed. This p r a c t i c e not o n l y minimizes t h e problem o f airborne dust, b u t simultaneously reduces product loss. Spray heads may be located a t as many l o c a t i o n s as have dust problems because t h e equipment required i s moderate i n cost and t h e r e i s no hazard t o personnel from Aerosol GPG Surfactant. Dust r e s u l t i n g from operations such as mining coal, production Most dusts are r e s i s t a n t t o w e t t i n g by water alone. Concent- Work surfaces may be wetted w i t h a f i n e spray t o prevent Concentrations o f Aerosol GPG Surfactant cWe1 h t Inoredi ents: Aerosol GPG Surfactant Ethanol Water Inaredi ents : Aerosol GPG Surfactant Ethanol Water Inaredients: Aerosol GPG Surfactant Ethanol Water Ingredients: Aerosol GPG Surfactant Ethanol Water Ingredients: Aerosol GPG Surfactant Ethanol Water Procedure: The stock s o l u t i o n may stream by a p r o p o r t i o n i n g t h e f i n a l s o l u t i o n may be -1% 1.43 none t o make 100 p a r t s -5% 7.15 t o make 100 p a r t s -10% 14.3 t o make 100 Darts 10-20 15-20 25% 35.7 10-15 t o make 100 Darts -50% 71.5 15-20 t o make 100 p a r t s be introduced i n t o t h e main water DumD o r an eductor. The strenath o f. . adjusted by changing t h e amount o r s t r e n g t h o f t h e stock s o l u t i o n being added. The range o f strength concentrations shown i n t h e t a b l e above w i l l a l l o w any ordinary method o f metering. Further c o n t r o l may be provided by use o f adjustable spray heads. SOURCE: Cytec I n d u s t r i e s Inc.: Suggested Formulations
  • 170.
    Miscellaneous 147 Hand andBody Cleanser Phase I: Water, D . I . Witconate AOS Varonic LI-48 Varonic LI-67 Ethylene Glycol Monostearate Varamide ML-1 Phase 11: Glycerine Lanoquat 50 EDTA Rewoteric AM 8-15 Phase 111: C i t r i c Acid Phase I V : Sodium Chloride Phase V: Preservat ive 96 by Weight 67.0 20.0 3.7 1.3 1.6 2 . 5 0.2 0.5 0.1 3.1 q.s. q.s. q.s. Blending Procedure: Heat Phase I water t o 8OC. Blend i n Witconate AOS w i t h good a g i t a t i o n . When t h i s i s blended completely, add t h e remaining Phase I ingredients, melting them f i r s t before adding. Cool t o 45C and add Phase 11, i n the order l i s t e d . Cool t o 35C and adjust pH = 7.0-7.7 w i t h c i t r i c acid. Add sodium c h l o r i d e t o desired v i s c o s i t y . Typical Properties: Solids: 19.5% pH: 7.3 SOURCE: Witco Corp.: Formula 1125
  • 171.
    148 Advanced CleaningProductFormulations Heavv Dutv Deareaser Butoxyethanol Mackam JS Sodium M e t a s i l i c a t e Pentahydrate Sodium T r i p o lyphosphate T r i sodi urn Phosphate T a l l O i l F a t t y Acid KOH (45%) EDTA (40%) Deionized Water Procedure: 1. Add components t o water and heat t o 40C. 2 . Blend u n t i l c l e a r . Mackamide CD TKPP Glycerin Mackadet 40K Procedure: Burni shi na Colnpound (Cocamide DEA) (Potassium Coconut Soap) Weiqht,% 8 . 0 3.5 3.0 1.5 2.5 2.0 2.1 0.3 77.3 Wei qht .% 93.0 1.5 2.7 2.7 1. Disperse TKPP i n Glycerin and add Mackadet 40K. 2. Then blend i n Mackamide CD. Remarks: The product upon d i l u t i o n w i t h water w i l l form a cloudy emulsion which requires shaking before use. The f i n a l product w i l l form an almost water c l e a r product. Corrosion I n h i b i t i n g Coating O i 1-Emulsifiable Wei aht .% Mackazoline 0 (Oleyl Hydroxyethyl Imidazoline) 16.5 L i g h t Mineral O i l 75.0 Glacial Acetic Acid 1.5 Oleic Acid 7.0 Procedure: 1. Blend Mackazol i n e 0 and Mineral O i 1. 2. Add Acetic Acid and Oleic Acid. 3. Blend u n t i l c l e a r . SOURCE: McIntyre Group Ltd.: I n d u s t r l a l Formulary
  • 172.
    Miscellaneous 149 Heavy Du t y I n d u s t r i a l Spray Metal Cleaner Concentrate Water Potassi um Hydroxide Sodium M e t a s i l i c a t e (Anhydrous) Sodium Carbonate Mona NF-25 % by Weiaht 65 10 10 5 10 Procedure: Typical Properties: Cloud P o i n t : 43C K r a f t Point: COC Add i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n . Recommended Use D i l u t i o n : 6 t o 8 o z . / g a l . Formulation F-544 Low Foam Hypochlorite Cleaner I n redients;. water Sodium Hypochlorite (5.25%) Mona NF-10 % bv Wei qht 79.0 19.0 2 . 0 Procedure: Blend i n g r e d i e n t s i n order l i s t e d . Adjust pH t o 13-14 w i t h 45% KOH . Formulation F-655 SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formulations Metal CleanerJBri nhtener Eastman EB solvent C i t r i c a c i d Phosphoric a c i d (85%) Nonionic s u r f a c t a n t * Water % by WeixhL 4.5 4.0 2.5 3.0 86.0 *Such as Neodol 91-8 alcohol ethoxylate (Shell Chemical Co.) o r Rhodasurf LA-9 alcohol ethoxylate (Rhone-Poulenc). SOURCE: Eastman Chemical Co.: Eastman EB and DB Solvents f o r Cleaners: Suggested Formulation
  • 173.
    150 Advanced CleaningProductFormulations Hot l a n k- StripperjCleaner/Deruster Component: Caustic Potash C r y s t a l Anhydrous Sodium M e t a s i l i c a t e Burco BSGH-270 o r BSGH-Crystals Burco ADS-100 Burco TME Dodecylbenzenesulfonate Powder 10.0 15.0 5.0 2.5 5.0 Procedure: onto m i x t u r e and blend u n t i l f u l l y absorbed. Add 8urco ADS-100, Gluconate o r Glucoheptonate and Dodecylbenzenesulfonate. Blend u n t i 1 uniform. increase p a i n t s t r i p p i n g e f f i c i e n c y provided s u f f i c i e n t a l k a l - i n i t y i s present. The Gluconate o r Glucoheptonate p r o v i d e t h e d e r u s t i n g . Burco TME and 8urco ADS-100 provide removal and d i s p - e r s i o n o f p a r t i c u l a t e s o i l s w h i l e t h e Dodecylbenzenesulfonate adds w e t t i n g and o i l y s o i l detergency. Each component can be adjusted according t o t h e improvement needed. Blend Caustic Potash and Sodium M e t a s i l i c a t e . Spray Burco TME Each component has a s p e c i f i c f u n c t i o n . The M e t a s i l i c a t e w i l l ~~Low Foam_Heavy Duty A1k a l ine C leaner-A CommDonent: %. bx_Wei.&t Water 58 Sodium M e t a s i l i c a t e , Pentahydrate Burcene 100 Burcosolv TM Burco TME Burcowet TM-LF 5 2 10 20 5 Procedure: eous between each a d d i t i o n . Add a l l components i n t h e order l i s t e d . S t i r u n t i l homogen- Formulation A i s low foaming a t temperatures above 160F. Low Foam Heavy-Duty A1k a l ine. Cleaner-6 Component: Water Sodium M e t a s i l i c a t e , Pentahydrate Sodi um Xylene Sul fonates 40% Burcosolv TM Burco TME Burco LAF-125 % by Weight 55 5 8.5 10 20 5 Procedure: between each a d d i t i o n . SOURCE: B u r l i n g t o n Chemical Co., I n c . : Suggested Formulations Add a l l components i n t h e order l i s t e d . S t i r u n t i l homogeneous Formulation B i s low foaming above 1OOF.
  • 174.
    Miscelloneous 151 Pain tBrush C1eaners Aerosol C-61 Surfactant i s a c a t i o n i c reagent t h a t w i l l a c t i v a t e s t r o n g l y t h e v o l a t i l e solvents commonly used f o r removing p a i n t . B r i s t l e brushes and r o l l e r s , glass, porcelain, metal, p l a s t i c , and c l o t h i n g have been t r e a t e d successfully. A 5 1 0 % s o l u t i o n o f Aerosol C-61 i n a solvent, o r mixed solvents is recommended. Extremely r a p i d sedimentation o f p a i n t pigment has been obtained w i t h t h e f o l l o w i n g composition: Inaredients: Aerosol C-61 Surfactant Butyl Cellosolve Solvent Xyl ene % by Weight o r Volume 5 5 90 Brushes and r o l l e r s may be cleaned immediately a f t e r use by being suspended i n t h i s mixture. I n a few hours p r a c t i c a l l y a l l o f t h e p a i n t pigment s e t t l e s i n a l a y e r beneath t h e b r i s t l e s . The solvent mixture may be reused repeatedly. When t h e pigment has s e t t l e d t h e brush may be removed and hung i n c i r c u l a t i n g a i r t o dry. For best r e s u l t s , t h e brush then should be washed i n soapy water and rinsed. I f t h e brush i s t o be used again immediately, i t may be rinsed i n solvent instead o f d r y i n g and waterwashi ng. w i t h hard, dry p a i n t , t h e f o l l o w i n g formulation has proved suc- essf u l . For renovating brushes t h a t have been allowed t o become caked Ingredients: Aerosol C-61 Surfactant Xyl ene Butanol Mineral Spi r it s ?4 by Weight o r Volume 10 45 5 40 The brush i s soaked i n t h e mixture f o r a time, then worked up and down t o a i d t h e penetration i n t o t h e caked p a i n t . The soaking and working may be repeated several times i f the p a i n t i s very hard and d r y . When t h e o l d p a i n t has soaked out o f t h e brush, t h e brush i s rinsed i n clean, warm water and f i n a l l y washed i n soapy water and r i n s e d again, then hung up t o d r y . A f t e r being d r i e d t h e b r i s t l e s have t h e appearance and f e e l of those o f a new brush. SOURCE: Cytec I n d u s t r i e s Inc.: Suggested Formulations
  • 175.
    I52 Advanced CleaningproductFormulations Steam Cleaner Water Potassi um Hydroxide Sodium M e t a s i l i c a t e (Anhydrous) Tetrapotassium Pyrophosphate Mona NF-15 % by WeiQht 65 3 10 10 12 Procedure: Add i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n . Typical P r o p e r t ies : Cloud P o i n t : 75C K r a f t P o i n t : >OC Recommended Use D i l u t i o n : 4 t o 6 o z . / g a l . Formulation F-541 Water Sodium Hydroxide (50%) Mona NF-25 Helvy Duty Indus-ray c l e a n e r Concentrate % by Weigh% 40 50 10 Procedure: Add i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n . Typical P r o p e r t i e s: Cloud P o i n t : 75C K r a f t P o i n t : >5C Recommended Use D i l u t i o n : 1 t o 4 o z . / g a l . Formulation F-543 High Sol i d s A1 k a l ine C1eaner Water Potassium Hydroxide Sodium M e t a s i l i c a t e (Anhydrous) Tetrapotassium Pyrophosphate Mona NF-25 % bv Weiclht 45.0 10.0 10.0 25.0 10.0 Procedure: Mix i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n . Formulation F-555 SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formulations
  • 176.
    Miscellaneous 153 WallDaDer Removal Astock s o l u t i o n o f Aerosol OT-75% Surfactant, o r a powder containing Aerosol OT-B Surfactant can be prepared f o r use as a wallpaper remover. D i l u t e d w i t h water by t h e user t o a con- c e n t r a t i o n o f 0.025% Aerosol OT, t h e s o l u t i o n i s h i g h l y e f f e c t - i v e i n soaking o f f o l d wallpaper, and o f t e n renders t h e use of an expensive and bulky steamer unnecessary. A t y p i c a l l i q u i d concentrate wallpaper remover can be prep- ared as follows. Inqredi ents: Aerosol OT-75% Surfactant Isopropyl Alcohol Water % by Weisht 15.0 15.0 70.0 D i r e c t i o n s : Use one tablespoon o f t h e above formulation per g a l l o n o f warm water. Apply t o a l a r g e section o f wallpaper and w a i t a few minutes. I f necessary, apply again. Aerosol OT-B Surfactant: The f o l l o w i n g powdered concentrate may be prepared using Inqredients: Sodium S u l f a t e (Powder) Aerosol OT-B Surfactant % by Weiqht 90.0 10.0 D i r e c t i o n s : recommended above. SOURCE: Cytec I n d u s t r i e s , Inc.: Suggested Formulations Use one teaspoonful per g a l l o n o f warm water and apply as
  • 177.
  • 178.
    15. Auto Cleanersand Polishes 155
  • 179.
    156 Advanced CleaningRoductFormulations Auto Pol ish/Cl eanser O i l i n Water Emulsion Phase A: 1 Deionized Water 2 668 P o l i s h i n g Powder 3 Volclay NF-BC Phase 0: 4 PEG-10 Carnauba 6 Montan Wax "S" 7 O l e i c Acid 8 Morpholine Phase C: 9 Odorless Mineral S p i r i t s 5 SF96-350 % by Weiqht 40.5 15.0 1. o 7.0 4.0 2.5 1.5 1 .o 27.5 Procedure: hydrate f o r 15 minutes. Bring temperature up t o 75C. I n a separate vessel, combine Phase B and w h i l e mixing, b r i n g temperature up t o 85C t o melt t h e waxes. Gently heat t h e mineral s p i r i t s t o 65C and add t o Phase 0. Once uniform and a 75C temp- e r a t u r e i s reached, slowly add t h i s t o Phase A, maintaining good a g i t a t i o n . Continue mixing u n t i l emulsion cools t o 40C. Pour i n t o appropriate containers. emulsion, w h i l e preserving t h e strength and i n t e g r i t y o f a n a t u r a l carnauba f in i sh. Combine Phase A under a g i t a t i o n and a l l o w t h e Volclay t o The PEG-10 Carnauba i n t h i s formula helps t o create a s t a b l e Detergent Resistant Auto Pol ish/Cleanser Paste Wax 1 Odorless Mineral Spi r it s 2 787 P o l i s h i n g Alumina P-10 Feinst 3 Ozokerite 170 4 #3 Carnauba 5 Synthetic Carnauba 6 SF1706 7 Hexanedi o l Behenyl Beeswax 8 V i s c a s i l 12M % by WeiQht 57.0 12.0 8.0 6.0 6.0 5.0 4.0 2.0 Procedure: 8OC. Mix u n t i l homogeneous. Add t h e alumina w h i l e mixing, and cool t o 35c. equal p a r t s o f #3 Carnauba and Synthetic Carnauba. This s u b s t i - t u t i o n has no e f f e c t on t h e f i n i s h e d product and w i l l y i e l d t h e same r e s u l t s . The o n l y d i f f e r e n c e i s a reduction i n cost. SOURCE: Koster Keunen I n c . : Suggested Formulations Combine a l l ingredients, leaving out t h e alumina, and heat t o The #1 Yellow Carnauba i n t h i s formula has been replaced by
  • 180.
    Auto Cleanersand Polishes157 Carnauba Hotwax Carnauba spraywax w i t h excellent performance and s t a b i l i t y i s produced using: Inaredient : Mineral seal o i l Tomah Emu1s i f ie r Four 9-10 mole ethox. nonionic Ethylene g l y c o l monobutyl ether Water (70-9OF) Emulsion C-340 Wei aht% 9.0 6.9 0.3 1.3 67.5 15.0 Add ingredients sequentially and mix completely p r i o r t o each a d d i t i o n . The carwash w i l l use the "hotwax" by d i l u t i n g 1:lO w i t h water and then i n j e c t i n g 6-8 0 2 . o f the d i l u t e product onto each car. The product w i l l not separate or g e l l . Pressure Spray Truckwash Water Sodium M e t a s i l i c a t e Pentahydrate EDTA ( l i q u i d 46%) Tomah Q-17-2 Tomah AO-14-2 Texstim 0741 45% Caustic Potash Tomah A l k a l i Surfactant Wei aht% 05.7 4.2 1.8 1 .o 1 .o 2.0 2.6 1.7 Texstim 0741 i s a nonionic surfactant which performs as a "self-demulsifying" detergent. This i s extremely useful i n truckwash applications. I n most o i l / w a t e r separators, the formulation " s p l i t " t h e o i l and water i n t o two phases without f u r t h e r treatment. The o i l phase can then be skimmed o f f f o r recovery o r disposal and not be sent t o t h e sewage treatment p l a n t . SOURCE: Tomah Products, Inc.: Suggested Formulations
  • 181.
    158 Advanced CleaningProductFormulations D e t e r q e n t R e s i s t a n t A u t o P o l i s h O i l i n Water Emulsion % bv Weight Phase A: 1 D e i o n i z e d Water 44.3 2 678 P o l i s h i n g Powder 8.0 3 V o l c l a y NF-BC 1 .o 4 Morpholine 0 . 7 Phase B: 5 I s o p a r L 1 8 . 0 6 I s o p a r M 8 . 0 7 PEG-I0 Carnauba 6.0 8 S i l i c o n y l Beeswax 6.0 9 SF96-350 3.0 10 S t e a r i c A c i d 1 .o Phase C : 11 I s o p a r M 5 . 0 12 SF1706 2.0 Procedure: Combine Phase A under a g i t a t i o n and b r i n g temperature up t o 85C. I n a s e p a r a t e v e s s e l , combine Phase B and w h i l e m i x i n g , b r i n g t h e temperature up t o 9OC. Once b o t h phases a r e up t o temperature, add Phase B t o Phase A and m a i n t a i n moderate a g i t - a t i o n . S l o w l y c o o l and a t 60C add Phase C . The S i l i c o n y l Beeswax p e r f o r m s w h i l e a p p l y i n g t h e p o l i s h b y c r e a t i n g a smooth, even c o a t i n g on t h e s u r f a c e o f t h e automobile. The PEG-10 Carnauba t o g e t h e r w i t h t h e amine f u n c t i o n a l s i l i c o n e , g i v e s t h e p o l i s h e d s u r f a c e a deep g l o s s and an e x t r e m e l y d u r a b l e f i n i s h . H i g h L u s t e r Auto F i n i s h Paste Wax 1 Odorless M i n e r a l S p i r i t s 2 I s o p a r L 3 I s o p a r M 5 #3 Carnauba 6 S y n t h e t i c Carnauba 7 O z o k e r i t e 170 8 White Beeswax 9 V i s c a s i l 12M 4 SF96-350 % by Weight 49.0 14.0 10.0 8 . 0 6.0 6.0 3.0 2.0 2 . 0 Procedure: Combine a l l waxes and s i l i c o n e s . Heat t o 85C. W h i l e m i x i n g , s l o w l y add t h e s o l v e n t s . Continue m i x i n g and c o o l t o 40C. Equal p a r t s o f #3 Carnauba and S y n t h e t i c Carnauba a r e used w i t h t h e i n t e n t i o n s o f t h e s e b e i n g a d i r e c t s u b s t i t u t e f o r #1 Y e l l o w Carnauba. The #3 Carnauba and S y n t h e t i c Carnauba w i l l y i e l d t h e same r e s u l t s as #1 Y e l l o w Carnauba, b u t a t a s i g n i f - i c a n t c o s t s a v i n g s . SOURCE: K o s t e r Keunen I n c . : Suggested F o r m u l a t i o n s
  • 182.
    Auto Cleoners ondPolish 159 High Gloss, Detergent Resistant P o l i s h Formulation 20-6 i s a wax-free p o l i s h , which provides a high- gloss, detergent r e s i s t a n t f i n i s h on non-porous substrates. Simple a p p l i c a t i o n , without hard rubbing o r b u f f i n g r e s u l t s i n both depth o f gloss and detergent resistance f o r extended p r o p e r t i e s . Ingredients: ( 1 ) GP-121 S i l i c o n e P o l i s h A d d i t i v e ( 2 ) GP-10-1,000 S i l i c o n e F l u i d ( 3 ) Stoddard Solvent ( 4 ) Mineral S p i r i t s (Odorless) ( 5 ) Witcamide 511 (6) Kaopolite SF (7) S o f t Water ( 8 ) Giv-Gard DXN Combine i n order shown w i t h high shear mixing unt i n g occurs. Mix u n t i l homogeneous and package. Formul a t i on Properties: *Contains no wax *Non-smeari ng *High gloss *Cost e f f i c i e n t *Detergent r e s i s t a n t *Cold blend(0nly mix * E a s i l y a p p l i e d *Resistant t o wash-o Formula 20-6 High Gloss Auto P o l i s h f F i n i s h % by weight 13.0 2.0 5.5 1.4 5.0 67.5 0.1 5.5 , 1 thicken- ng required) f Ingredients: ( 1 ) GP-121 ( S i l i c o n e P o l i s h A d d i t i v e ) (2) Witcamide 511 (3) Kaopolite SF ( 4 ) S o f t Water ( 5 ) Giv-Gard DXN % by. Weight 26.0 1.4 5.0 67.5 0.1 Combine i n order shown w i t h high shear mixing u n t i l t h i c k e n i n g occurs. Mix u n t i l homogeneous and package. Formulation Properties: *Contains no wax *High gloss *Detergent r e s i s t a n t *Easi 1y appl i e d *Non-smeari ng *Cost e f f ic i ent *Cold blend Only mixing required Formula 20-5 SOURCE: Genesee Polymers Corp.: Suggested Formulations
  • 183.
    160 Advanced CleaningRoductFormulations Spravwax Concentrate The f o l l o w i n g formula should produce a c l e a r , s t a b l e spraywax concentrate. Comonent: Kerr-McGee Mineral seal o i 1 Emuls i f ie r 827 Ethylene g l y c o l monobutyl ether Water (70-9OF) Grams 18.0 15.0 4 . 0 63.0 D i r e c t ions : monobutyl ether and m i x u n t i l c l e a r . Add water slowly w h i l e mixing. When water has been added, mix about 5 more minutes. Add dye i f desired. Addition o f a fragrance may r e q u i r e a s l i g h t formulation change. The f i n a l product w i l l be c l e a r and i s normally packaged i n 5 g a l l o n p a i l s . The carwash should d i l u t e 5 gallons o f concentrate w i t h 50 gallons o f water and then i n j e c t about 6 02s. o f t h e d i l u t e spraywax through a DEMA system onto each c a r . Charge t h e mineral seal o i l , E m u l s i f i e r 827, ethylene g l y c o l Spraywax The f o l l o w i n g t y p i c a l formulation i s h i g h l y e f f e c t i v e , problem free, and s t a b l e i n both concentrate and d i l u t e form. Inaredient : Kerr McGee Mineral Seal O i l Emuls i f ie r Four-HF 9-10 mole ethoxylated nonionic Ethylene g l y c o l monobutyl ether Tap Water Weiaht % 20.0 15.0 1.o 3.0 61 . O D i r e c t i o n s : nonionic, ethylene g l y c o l monobutyl ether and mix u n t i l c l e a r . Add water slowly w h i l e mixing. When water has been added, mix about 5 more minutes. Add dye i f desired. Addition o f a frag- rance may r e q u i r e a s l i g h t formulation change. The f i n a l product w i l l be c l e a r and i s normally packaged i n 5 g a l l o n p a i l s . The carwash should d i l u t e 5 gallons o f concentrate w i t h 50 gallons o f water and then i n j e c t about 6 02s. o f t h e d i l u t e spraywax through a DEMA system onto each car. SOURCE: Tomah Products, I n c . : Suggested Formulations Charge t h e mineral seal o i 1, Emulsifier Four-HF, ethoxylated
  • 184.
    Auto Cleaners andPolishes161 Spravwax Ladder of Formulas Because mineral seal o i l s d i f f e r i n e m u l s i f i c a t i o n char- a c t e r i s t i c s , i t i s necessary t o modify t h e formulation t o achieve optimum performance. The best formula can be deter- mined by running a ladder o f formulas. Typical examples are: Comonent: Mineral seal o i l Emuls i f ie r Four-HF 9-10 mole ethoxylated nonionic Ethylene g l y c o l monobutyl ether Water Component: Mineral seal o i l Emuls i f ie r Four-HF 9-10 mole ethoxylated nonionic Ethylene g l y c o l monobutyl ether Water Comoonent: Mineral seal o i l E m u l s i f i e r Four-HF 9-1 0 mole ethoxylated nonioni c Ethylene g l y c o l monobutyl ether Water Components: Mineral seal o i l Emul s i f i e r Four-HF 9-10 mole ethoxylated nonionic Ethylene g l y c o l monobutyl ether Water Grams-B 40.0 31 . O 1.o 6.0 122.0 Grams-C 40.0 30.5 1.5 6.0 122.0 Grams-D 40.0 30.0 2.0 6.0 122.0 Grams-E 40.0 29.5 2.5 6.0 122.0 Check a l l formulas f o r : 1. 1:lO d i l u t i o n i n water. 2. 120F s t a b i l i t y ( 3 hours i n sealed container i n water bath a t 3 . Freeze/thaw-24 hour recovery (sealed container). The optimum formula w i 11 : 1. D i l u t e c l e a r and e a s i l y a t 1:lO d T l u t i o n . 2. Not cloud at. 120F. 3. Recover completely from freeze/thaw c y c l e (without shaking). SOURCE: Tomah Products, I n c . : E m u l s i f i e r Four-HF: Formulas 120F).
  • 185.
    16. Car andTruck Wash Compounds 162
  • 186.
    Car and TruckWash Compounds 163 Automatic Car Wash Concentrate A High A l k a l i n e D i l u t a b l e Concentrate Inaredient : Oeioni zed Water Maphos 60-A Potassi um Hydroxide Tetrapotassium Pyrophosphate Sodium M e t a s i l i c a t e , Anhydrous Macol LF-120 Mazamide 80 Sodium Xylene Sulfonate (40%) Macol 48 Oeioni zed Water pH (as i s ) : 12.5-13.5 Appearance: Clear, l i g h t - y e l l o w l i q u i d S p e c i f i c Gravity: 1.06 Procedure: Charge t h e f i r s t water p o r t i o n t o t h e mixing vessel and s t a r t a g i t a t i o n . Add t h e ingredients i n t h e given sequence and mix u n t i l c l e a r . Notes : This i s a h i g h l y a l k a l i n e cleaner designed t o be used i n commercial automatic car washes a t a d i l u t i o n r a t e o f 1-2 ounces per gallon. Do not use d i r e c t l y on automotive f i n i s h e s . Formula CA-102 Wt.% 50.00 6 . 0 0 3.00 2.00 2.00 2.00 2.00 3.00 3.00 27.00 General Purtmse Car Wash High Foaming A11-Purpose D i 1u t a b le Concentrate Ineredi ent : Wt.% Deioni zed Water 50.00 Mazon 98 9.50 Macol TD-3 1.50 SLS (Sodi um Lauryl Sulfate) 2.50 Mazamide 80 3.00 Macol 48 1.oo Triethanolamine (85%) 1.50 Deionized Water 31 .OO pH (as i s ) : 8.5-9.5 Appearance: Clear, l i g h t - y e l l o w l i q u i d S p e c i f i c Gravity: 1.02 Procedure: Charge t h e f i r s t p o r t i o n o f water t o t h e mixing vessel and s t a r t slow a g i t a t i o n . Excessive a g i t a t i o n w i 11 produce a foami ng problem. Add t h e remaining ingredients i n t h e given sequence and mix u n t i l c l e a r . Notes: t o be safe on car f i n i s h e s , yet e f f e c t i v e i n t h e removal o f road grime and other s o i l s . Formula CA-103 SWRCE: Mazer Chemicals: Supposted Formulations This i s a copious-foaming, all-purpose car wash formulated Use concentration i s 1-2 ounces per g a l l o n o f warm water.
  • 187.
    164 Advanced CleaningR h c t Formulations Auto Shampoo Concentrate Water, D.I. Rewoteric AM KSF-40 Witcolate SE-5 % by Weight 80.0 15.0 5.0 Blending Procedure: between each a d d i t i o n . Typical Properties: Viscosity, cps: 4.0 Solids: Q.O% pH: 9.5 Add ingredients i n order shown and dissolve completely Formula 628 High Foaming Car Wash Water, D.I. D i ethanol ami ne Witco 1298SA Varox 1770 Butyl Cellosolve Sodi urn Metasi 1i c a t e Sodium Tripolyphosphate % by Weight 65.0 5.0 15.0 10.0 1.o 1.o 3.0 01endi ng Procedure: 1298 i n t o s o l u t i o n . Next, add remai n i ng ingredients a1lowi ng t o dissolve completely between additions. Typical Propert ies : Viscosity. cps: 77.0 Solids: 27.5% pH: 9.3 Add DEA t o water and mix thoroughly. Slowly dissolve Witco Formula 631 Car Wash Water Witcolate A W i t c o l ate S-l285C Emcol NA-30 Preservative Blending Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d . Typi cal Propert ies : Solids: 28.4% pH: 6.9 V i s c o s i t y , cps: Gel Formula 623 SOURCE: Witco Corp.: Suggested Formulations % by Wei aht 34.9 25.0 25.0 15.0 0.1
  • 188.
    Car and lh c k Wash Compowrds 165 Car Wash L i q u i d Formula TR-0023 A1 k y l benzene s u l f o n i c a c i d Sodium xylene s u l f o n a t e Igepal CO-710 Tetrapotassium pyrophosphate (60% a c t i v e ) Potassium hydroxide (45% a c t i v e ) Water W t .% 6 . 0 11.5 3 . 0 2 5 . 0 2 . 5 5 2 . 0 - Procedure 1 . D i ssol ve a1k y lbenzene s u l f o n i c a c i d i n water. 2 . A d d sodium xylene sulfonate, Igepal CO-710, tetrapotassium pyrophosphate and potassium hydroxide, mixing w e l l a f t e r each a d d i t i o n . 3. F i l t e r product. Physical P r o p e r t i e s pH (as i s ) : 9 . 5 pH (1%): 9.9 V i s c o s i t y : 10 cps S p e c i f i c G r a v i t y : 1 .05 Car Wash Powder Formula TR-0022 Igepal CO-710 Sodi um tripolyphosphate Sodium m e t a s i l i c a t e pentahydrate Sodium carbonate ( L t . d e n s i t y ) W t .% 1 0 . 0 50.0 5 . 0 35.0 Procedure: 1 . Mix Igepal CO-710 w i t h sodium tripolyphosphate. 2 . Add sodium m e t a s i l i c a t e pentahydrate and sodium carbonate Physical Properties: Appearance: White, f r e e - f l o w i n g powder pH (1%): 11.2 S p e c i f i c G r a v i t y : 0 . 7 3 SOURCE: Rhone-Poulenc Surfactants & S p e c i a l t i e s : Formulas
  • 189.
    166 Advanced CleaningProductFormulotiom Igepal CO-660 Cheel ox BF-13 Sodi um Xylene Sul fonate Water Procedure 1 . Dissolve sodium xy 2. Add Igepal CO-660. Physical Properti-eg pH (as i s ) : 10.3 DH (1%): 10.1 Economy Truck Wash High-pressure Spray (Formula TR-0024) ene s u l fonate Mix thoroughly. n water. Add Cheelox BF 13. V i s c o s i t y : 10 cps Speci f ic G r a v i t y : 1 .02 Truck Wash L i q u i d Formula TR-0025 Igepal CO-630 Rhodapex CO-436 A1kami de DC-212/S Cheelox BF-13 Ethylene Glycol Monobutyl Ether Water W t .% 3.0 1.o 1.5 84.5 Procedure 1. Dissolve s u r f a c t a n t s Igepal GO-630, Rhodapex CO-436 and 2. Add Cheelox BF-13. Mix w e l l . 3. Add ethylene g l y c o l monobutyl ether. Physical PrQpe-rti89 pH (as i s ) : 9.9 pH (1%): 9.6 V i s c o s i t y : 10 cps S p e c i f i c G r a v i t y : 1.01 A1 kami de DC-212/5 in water. SOURCE: Rhone-Poulenc Surfactants & S p e c i a l t i e s : Formulas W t .% 3.0 3.5 2.0 3.5 3.0 85.0
  • 190.
    Gar and hk Wash Compounds 167 Water, D . I . * Caustic Soda, 50% Witco 1298SA Witcolate SE-5 Petro BAF L i q u i d W i tcami de 128T Formal i n Sodium Chloride Foamy Brush Car Wash. L i q u i d % by Weight 79.75 1.40 5.00 7.00 3.00 3.00 0.10 0.75 Blending Procedure: used t o adjust v i s c o s i t y o f t h e product. Typical Propert ies: Blend ingredients i n t h e order l i s t e d . Sodium Chloride i s S p e c i f i c Gravity: 1.015 Wt./Gal. l b s . : 8.46 pH, as i s : 9.8 Viscosity, cps: 410 D i l u t i o n Ratio a t Wand = 1:40 * I f unsoftened t a p water i s used, add 0.25% l i q u i d EDTA, 40% t o counteract hardness. Formula 621 1:2 D i l u t a b l e Car Wash Water Sodium Hydroxide, 50% Witconate SXS (40%) Witco 12988 W i tcami de 128T W i tcami de CDA Blend4 ng Procedure: Typi c a l Properties: Blend ingredients i n t h e order l i s t e d . Solids: 54.0% pH. as i s : 8.5 Viscosity, as i s , cps: 580 Viscosity, 1:2. cps: 440 Formula 622 SOURCE: Witco Corp.: Sugueated Formulations % by Weight 33.71 5.96 14.90 25.88 16.76 2.79
  • 191.
    I68 Advanced CleaningProductFormulations High O i l S p l i t t i n g Vehicle Wash-A Components: Water Sodium M e t a s i l i c a t e Pentahydrate TKPP Sodi um Xylene Sul fonates 40% Burco TME % by Weiqht 71.5 10.0 2.5 6.0 10.0 Add i n t h e order l i s t e d . Blend u n t i l dissolved between each a d d i t i o n . High O i l S D l i t t i n g Vehicle Wash-B Components: Water Sodium M e t a s i l i c a t e Pentahydrate Burcosol ADS-40 Glycol Ether Burco TME Burcotrope 1250 % by Weiqht 73.5 10.0 5.0 5.0 10.0 As Required Add i n t h e order l i s t e d . Blend u n t i l dissolved between each a d d i t i o n . SOURCE: B u r l i n g t o n Chemical Co., I n c . : Suggested Formulations
  • 192.
    Car and TruckWosh Cornpout& 169 L iauid Car Wash Formula TR-0020 Rhodapon SB Alcodet SK Rhodasurf 25-9 Tetrapotassium pyrophosphate Sodi um metasi 1i c a t e Water Perfume Dye Formula Formula A B WtT% wtT% 1 8 . 0 18.0 ----8 . 0 --- 8 . 0 3.0 3.0 2.0 2.0 69.0 69.0 Q . S . Q . S . Q . S . Q . S . Procedure i n water. Add Rhodapon SB. A g i t a t e u n t i l c l e a r . Add Alcodet SK and Rhodasurf 25-9 and mix u n t i l uniform and c l e a r . Add perfume and dye, as desired. Physical ProDertiea Dissolve tetrapotassium pyrophosphate and sodium m e t a s i l i c a t e Appearance: Clear l i q u i d , dyed t o preference pH: 12.0 S p e c i f i c Gravity: 1.03 V i s c o s i t y : t50 cps Spray-On Car Wash Concentrate "Grease and Grime" Remover Formula TR-0021 Rhodacal A-246/L Rhodacal 330 Rhodapon BOS Alcodet SK Water Wt.% 5.0 20.0 3.3 5.0 66.7 Procedure: 1. Charge water t o a vessel equipped w i t h a g i t a t i o n . 2 . Add Rhodacal A-246/L and Rhodapon 00s t o ( 1 ) above. Mix u n t i l 3. Add Rhodacal 330 and Alcodet SK t o (2) above. Mix u n t i l Phvsica1 Propertigp Appearance: Viscous, gel -1 ike 1i q u id pH. as i s : 9.0 S p e c i f i c Gravity: 1.02-1.04 V i s c o s i t y : t50 cps uniform (5-10 minutes). uniform (15-30 minutes). SOURCE: Rhone-Poulenc Specialtiem a Surfactmtm: Formulas
  • 193.
    I70 Advanced CleaningProduct Formulotions L i q u i d Hiah Pressure Concentrate Water, D.I. Oowanol EB Witconate SXS L i q u i d Sodium Benzoate Sodium M e t a s i l i c a t e Tetrapotassium Pyrophosphate Varion AM-KSF-40% % by Weiaht 46.0 2.0 1 .o 1 .o 10.0 20.0 20.0 Blending Procedure: between each a d d i t i o n . Typical Properties: V i s c o s i t y , cps: 15 Solids: 39.4% pH: 13.4 Formula 605 Add ingredients i n order shown and dissolve completely Truck Wash w/Vararide A-83 Water, D . I . Sodium Tripolyphosphate T r i sodi um Phosphate Sodium M e t a s i l i c a t e Varami de A-83 Butyl C e l l osol ve % by Weight 81 .o 3.0 3.0 1 .o 9.0 3.0 Blending Procedure: between each addition. Typical Properties: Viscosity, cps: 1 2 Solids: 16.0% pH: 11.0 Formula 608 SOURCE: Witco Corp.: Suggested Formulations Add ingredients i n order shown and dissolve completely
  • 194.
    Car and TruckWash Compounds 171 L i q u i d Truck Wash Formula TR-0029 Water Miranol FBS Igepal CA-630 Dowanol EB (Dow Chemical ) Potassi um Hydroxide (45%) T a l l O i l Tetrapotassium Pyrophosphate Sodium M e t a s i l i c a t e , Pentahydrate Wt.% 73.6 6.0 3.0 2.0 4.0 3.4 4.0 4.0 Procedure Premix t h e t a l l o i l and Dowanol EB. Add t h e water t o t h e mixer. Add t h e sodium m e t a s i l i c a t e , t h e potassium hydroxide and t h e TKPP. Add t h e Miranol FBS and Igepal CA-630. Add t h e t a l l oil/Dowanol EB premix. Mix u n t i l uniform. Physical ProDerties Appearance: Clear, amber l i q u i d pH, as i s : 12.7 S p e c i f i c G r a v i t y : 1.08 V i s c o s i t y : 6 0 cps L i q u i d Truck Wash Formula TR-0030 Water Miranol FBS Rhodafac RA-600 Igepal CA-720 Cheel ox BF-13 Tetrapotassi um Pyrophosphate Potassi um Hydroxide (45%) Sodium M e t a s i l i c a t e Pentahydrate Arcosolv PTB Wt.% 63.0 4 . 0 2.0 2.0 17.5 1 .o 6.0 2.0 2.5 Phvsl c a l Prooerti es Appearance: C1ear, ye11ow 1iqui d pH, as i s : 12.9 S p e c i f i c Gravity: 1.10 V i s c o s i t y : <SO cps SOURCE: Rhone-Poulenc Surfactants & Spec Procedure Add t h e ingredients i n t h e order l i s t e d and mix u n t i l uniform. asa1t i8s: Formu
  • 195.
    172 Advanced CleaningproductFormulations M i l d Car Shampoo A m i l d r i c h foaming car shampoo w i t h e x c e l l e n t detergency and sheeting a c t i o n , I n a r e d ients: % ComDosit o n W/W Sandobet SC 4.5 DDBSA, 60% 10.8 Sandoxylate SX-424 3.6 Triethanolamine 0 . 8 Dye, Fragrance, Preservative, Water Q.S. Procedure: Charge water t o mixing vessel w i t h moderate a g i t a t i o n . Hold out small p o r t i o n o f t h e water t o d i s s o l v e dye. Charge t h e r e - maining components i n sequence, mixing a f t e r each a d d i t i o n . Dissolve t h e dye w i t h a g i t a t i o n i n t h e water p r e v i o u s l y h e l d out and add t o t h e product. Properties: Appearance: C1ear 1iqui d A p p l i c a t i o n : Use 1 t o 2 oz per 5 g a l l o n bucket SOURCE: Sandoz Chemicals Corp. : Formulation HHA-01 pH: 7.0-8.0 Carspray CW Concentrate % by Weight Water, D . I . 80.0 Blending Procedure: s o l u t i o n i s homogeneous. Typical Properties: S o l i d s : 11.6% Formula 632 Carspray CW 20.0 Add Carspray t o water w h i l e mixing. Continue mixing u n t i l Automotive "Wash 8 Wax" % by Weiqht Witcamine AL42-12 6.9 Isopropanol 1.o G l a c i a l A c e t i c Acid 2.1 Water 65.0 Witcamide 5195 25.0 Blending Procedure: Heat t h e m i x t u r e t o 70C and then add Witcamide 5195. Continue mixing u n t i l s o l u t i o n i s c l e a r . T h i s f o r m u l a t i o n leaves a water "beading" f i l m on t h e auto- mobile f i n i s h , Formula 636 Mix a l l i n g r e d i e n t s except Witcamide 5195 i n t h e order l i s t e d . SOURCE: Witco Corp.: Suggested Formulations
  • 196.
    Car and TruckWaFhCompounds I73 Premium CarsDrav 500 Concentrate Carspray 500 B u t y l C e l l osol ve Mineral Seal O i l * Water, D . I . ?6 by Weight 20.0 5.0 25.0 50.0 *Kermac 600 Solvent: Kerr McGee O i l Co. D i a l a A O i 1: Shel 1 Chemical Isopar V : Exxon Chemical B1endi ng Procedure : thoroughly. I n a separate vessel weigh i n t h e water. While mixing t h e water, pour i n t h e blend. Mix u n t i l s o l u t i o n i s homogeneous. Use D i l u t i o n : Combine Carspray, B u t y l Cellosolve and O i l i n vessel and mix 5 g a l l o n s Concentrate t o 50 g a l l o n s water. Carspray 500: Beading Agent w i t h s i l i c o n e . Comments: Formula 687 Standard Carspray 500 Concentrate Carspray 500 B u t y l Cel l o s o l v e Mineral Seal O i l * Water, D . I . *Kermac 600 Solvent: Kerr McGee O i l Co D i a l a A O i 1: Shel 1 Chemical Isopar V: Exxon Chemical % by Weipht 16.0 3.0 20.0 61 .O 81endi ng Procedure: Combine Carspray, B u t y l Cellosolve and O i l i n vessel and mix thoroughly. I n a separate vessel weigh i n t h e water. While mixing t h e water, pour i n t h e blend. Mix u n t i l s o l u t i o n i s homogeneous. Use D i 1u t ion : Comments: 5 g a l l o n s Concentrate t o 50 g a l l o n s water. Carspray 500: Beading Agent i n s i l i c o n e Formula 688 SOURCE: Witco Corp.: Suggested Formulations
  • 197.
    174 Advanced CleaningProduct Formulations Premium Carspray 700 Concentrate Carspray 700 Mineral Seal O i l * Water, D . I . *Kermac 600 Solvent: Kerr McGee O i l Co. D i a1a A O i 1: She11 Chemical Isopar V: Exxon Chemical %_by Wei qht 25.0 25.0 50.0 Blending Procedure: heat t o l l O F w i t h thorough mixing. I n vessel #2, weigh i n t h e water and mix u n t i l a v o r t e x i s formed. While mixing t h e water, pour t h e blend i n t o t h e v o r t e x . Mix u n t i l s o l u t i o n i s homo- geneous. Use D i l u t i o n : I n vessel #1, combine Carspray 700 and Mineral Seal O i l and 5 g a l l o n s Concentrate t o 50 g a l l o n s water. Comments: Carspray 700: Foaming beading agent Formula 685 Standard Carspray 70-0 Concentrate Carspray 700 Mineral Seal O i l * Water, D . I . *Kermac 600 Solvent: Kerr McGee O i l Co. D i a l a A O i l : S h e l l Chemical Isopar V: Exxon Chemical % u Y A ! h t 16.0 16.0 68.0 Blending Procedure: heat t o l l O F w i t h thorough mixing. I n vessel #2, weigh i n t h e water and mix u n t i l a v o r t e x i s formed. While mixing t h e water, pour t h e blend i n t o t h e v o r t e x . Mix u n t i l s o l u t i o n i s homog- eneous. Use D i l u t i o n : I n vessel #1, combine Carspray 700 and Mineral Seal O i l and 5 g a l l o n s Concentrate t o 50 g a l l o n s water. Comments: Formula 686 SOURCE: Witco Corp.: Suggested Formulations Carspray 700: Foaming beading agent
  • 198.
    17. Whitewall TireCleaners 175
  • 199.
    176 Advanced CleaningProduct Formulations W h i t e Wal 1 T i r e Cleaner I n g r e d i e n t s : Sodium Metasi 1 i c a t e Sodium T r i p o l y p h o s p h a t e T e t r a p o t a s s i u m Pyrophosphate Sodium L a u r y l E t h e r S u l f a t e S o l i n (35%) Sandopan B Water (warm) %by.Wt. 2.00 2.00 2.00 4.00 2.30 5.00 83.00 Procedure: Charge t h e w a t e r t o a vessel w i t h good a g i t a t i o n . Charge t h e f i r s t t h r e e components and m i x t i l l d i s s o l v e d . Charge t h e remain- i n g p r o d u c t s and mix t i l l comp e t e l y d i s s o l v e d and f r e e o f g e l p a r t i c l e s . P h y s i c a l P r o p e r t i e s : Appearance: C l e a r w a t e r whi pH ( a s i s ) : >9.0 T o t a l S o l i d s : 11.0-12.0% Use L e v e l s : e t o l i g h t y e l l o w l i q u i d For f i n a l use, d i l u t e between 4:l and B : l w i t h w a t e r SOURCE: Sandoz Chemicals C o r p . : F o r m u l a t i o n HHA-03 Bug Remover C o n c e n t r a t e T r i ethanolami ne (TEA) B u t y l C e l l o s o l v e I s o p r o p a n o l R e w o t e r i c AM 8-15 % by W e i . a 17.14 42.86 17.14 22.86 81ending Procedure: B l e n d t h e components i n t h e o r d e r shown. Mix u n t i l homogeneous D i l u t i o n Rates: 1 : 2 E x t r a Heavy Duty 1 : 4 Heavy Duty 1 : 16 Medi um Duty 1 :32 L i g h t Duty D i 1 u t i on I n s t r u c t i o n s : m i x i n g u n t i l homogeneous. Comments: Add Bug Remover C o n c e n t r a t e t o water w h i l e m Appearance @ 77F: C r y s t a l c l e a r , y e l l o w l i q u SOURCE: W i t c o Corp.: Formula 677 Xing; c o n t i n u e d
  • 200.
    Whitewall Ere Cleaners177 Whitewall T i r e Cleaner Concentrate Formula TR-0031 Water Miranol FBS Sodium M e t a s i l i c a t e , Pentahydrate Potassium Hydroxide (45%) Butoxyethanol Procedure Physical ProDerties Add i n g r e d i e n t s i n order l i s t e d . Mix u n t i l uniform. Appearance: Clear, yellow l i q u i d pH, as i s : 12.7 V i s c o s i t y : <50 cps S p e c i f i c G r a v i t y : 1.16 W h i tewal 1 T i r e C1eaner L iauid Formula TR-0027 Igepal CA-630 Rhodafac RA-600 M-Pyrol N-Methyl-2-Pyrrolidone (ISP) Sodium M e t a s i l i c a t e , Anhydrous Sodi um Tripolyphosphate Potassi um Hydroxide Water Wt.% 48.0 22.0 25.0 3.0 2.0 Wt.% 2.0 6.0 2.0 3.0 5.0 1 . 5 8 0 . 5 ProceduPQ 1. Dissolve sodium m e t a s i l i c a t e , anhydrous, sodium t r i p o l y - phosphate and potassium hydroxide i n t o water. 2. Add Igepal CA-630, Rhodafac RA-BOO, and M-Pyrol separately, mixing w e l l a f t e r each a d d i t i o n . Physical ProDertiea pH (as i s ) : 13.3 pH (1%): 10.7 V i s c o s i t y : 10 cps S p e c i f i c Gravity: 1.03 SOURCE; Rhone-Poulenc Surfactants a S p e c i a l t i e s : Formulas
  • 201.
  • 202.
    Miscellaneous 179 Automobi 1eW i ndshie ld Cleaners Inaredients: Aerosol MA-80 Surfactant Surfonic N-95 Isopropanol Water % by Weiaht 3.5 0.5 51 .o 45.0 The above i s d i l u t e d 5 oz. t o 1 g a l l o n o f water f o r use. I n wintertime, t h e recommended d i l u t i o n i s 10 oz. per gallon. Freezi ng i s prevented by t h e isopropanol . Thi s formulation leaves a small amount o f residue on t h e unwiped p o r t i o n o f t h e wind- s h i e l d upon drying. There are several ways o f preventing these v i s i b le residues. 1 . Use a mixture o f v o l a t i l e solvents w i t h o r without surfactants. A suggested formulation i s : Inaredients: 2-Ethyl Hexanol Aerosol OT-75% Surfactant Isopropanol Water % by Weiaht 5.0 1.o 47.0 47.0 The above i s d i l u t e d 5-10 0 2 . per g a l l o n o f water, and w i l l n o t freeze a t t h e higher l e v e l o f concentration. 2. Using surfactants, but i n c l u d i n g small amounts o f non- v o l a t i l e solvents which g i v e a transparent f i l m on t h e glass w i t h t h e s u r f a c t a n t . Non-volatile solvents having approximately t h e same r e f r a c t i v e index o f glass should be selected. A suggested formulation i s : Innredients: Aerosol MA-80 Surfactant Aerosol OT-75% Surfactant Diethylene Glycol Isopropanol n-Butyl-p-Hydroxy Benzoate Methyl-p-Hydroxy Benzoate Water % by Weight 2.5 3.3 4.4 40.0 0.1 0.1 49.78 The above concentrate i s used a t 5 02. per g a l l o n (10 02'. per g a l l o n i n w i n t e r ) . The b a c t e r i c i d e s a r e present t o keep t h e window cleaning s o l u t i o n f r e e o f slime and t u r b i d i t y due t o b a c t e r i a . Inaredients: % by Weight Aerosol OT-75% Surfactant 3.5 D i b u t y l phthalate 0.5-2.0 Isopropanol 40.0 Water 46-48 The above s o l u t i o n i s d i l u t e d 5-10 02. per g a l l o n o f water and w i l l not freeze a t t h e higher l e v e l o f concentration. SOURCE: Cytec I n d u s t r i e s Inc.: Suggested Formulations
  • 203.
    180 Advanced CleaningProductFormulations General PurDose L i q u i d Boat Polish-(1 1 M a t e r i a l s : Part A: SF 96 (350) V i scasi 1 (10,000) O l e i c a c i d Isopar M Hoechst Wax E Part B: Water Morphol ine Carbopol 934 Part C: Isopar M SF 1706 Part D: Snow Floss Super Floss General Purpose L i q u i d Boat Polish-(2) Materi a1s : Part A: SF 96 (350) V i scasi 1 ( 10,000) O l e i c a c i d Isopar M Hoechst Wax E Part B: Water Morphol ine Carbopol 934 Part C : Isopar M SF 1706 Part D: Kaopol it e 1 1 68 Part/Wt (%Z 3.50 1 .oo 1.50 10.00 1.50 65.65 1.60 0.25 3.00 2.00 7.50 2.50 Part/Wt(%) 3.50 1 .oo 1.50 10.00 1.50 63.65 1.60 0.25 3.00 2.00 12.00 Procedure: 1.) Heat Part A t o 90-95C. (2.) Heat Part B t o 60-85C. 3.) Add Part A t o Part B w i t h good mixing. 4 . ) When homogeneous, cool t o 60-65C and add Part C w i t h continued high shear mixing. 5.) Add Part D w i t h good mixing. 6.) When uniform, cool and package i n s u i t a b l e containers SOURCE: GE S i l i c o n e s : Formula BP 2000
  • 204.
    Miscellaneous 181 L ia u i d Aluminum Engine Block Cleaner Formula TR-0032 Water Sodium Metasi 1i c a t e , Anh Miranol FBS M i ranol JEM Conc. Alcodet HSC-1000 D-Limonene W t .% 82.5 4.5 5.0 2.0 4.0 2.0 Procedure Completely d i s s o l v e t h e sodium m e t a s i l i c a t e i n t h e water Add t h e remaining components, w i t h a g i t a t i o n , i n t h e order l i s t e d . Premix t h e 0-Limonene w i t h t h e Alcodet HSC-1000 and add together. T y p i c a l PropertJ es Appearance: Clear, yellow t o amber l i q u i d pH, Conc.: 12.75 pH, 10%: 12.15 S p e c i f i c G r a v i t y : 1.04 V i s c o s i t y : t50 cps Foami ng Engi ne C1eaner Formula TR-0019 Alcodet 260 Rhodacal 330 Water Isopar "K" (Exxon) W t .% 2.0 8.0 80.0 10.0 Procedure 1. Add Alcodet 260 and Rhodacal 330 t o water a t ambient temp- e r a t u r e , s t i r u n t i l dissolved (10-15 minutes). 2. Add Isopar K a t ambient temperature. S t i r u n t i l dissolved (30 minutes) . Physi cal Proeerties Appearance: Clear l i q u i d pH, as i s : 7 . 5 Speci f ic G r a v i t y : 0.99 V i s c o s i t y : 10 cps SOURCE: Rhone-Poulenc Surfactants & S p e c i a l t i e s : Formulas
  • 205.
  • 206.
    TrademarkedRaw Materials 183 RAWMATERIALS AC-325 Nonionic ACL-59 Acrysol ICS-1 Aerosol A-102 Aerosol A-1 03 Aerosol C-61 Aerosol GPG Aerosol MA-80 Aerosol 0s Aerosol OT Aerosol OT-B Aerosol OT-75% Aerosol OT-100% Aerosol 22 AF 9020 Alcodet HSC-1000 Alcodet SK Alcodet 260 A1kami de DC-212 A1kamide DC-212/M A1kamide DC-212/S Aluminum Oxide FPTO Ammonyx LO CHEMICAL DESCRIPTION SOURCE Polymer A l l i e d Chlorinated isocyanurate Monsanto Water-soluble a c r y l i c r e s i n Rohm& Mono-ester sul fosucci nate Cytec Mono-ester sul fosucci nate Cytec s u r f a c t a n t s u r f a c t a n t A1 k y lami ne-guani d Sodium d i o c t y l su Sodium dihexyl su A1k y l naphthalane Sodium d i o c t y l su ne ethoxylate Cytec fosucci nate Cytec fosuccinate Cytec oxide sulfonate Cytec fosucci nate Cytec Sodium d i o c t y l sulfosuccinate Cytec Sodi um d i o c t y l s u l fosucci nate( 75%) Cytec Sodi um d i o c t y l s u l fosucci nate Cytec Sul fosucci namate Cytec T e r t i a r y t h i o e t h e r surfactant Rhone- Cleaning s u r f a c t a n t Rhone- Cleaning s u r f a c t a n t Rhone- F a t t y a1kanolamide ISP F a t t y a1kanolamide I S P F a t t y a1kanolanide ISP Laurami ne oxide Stepan
  • 207.
    184 Advanced CleaningProduct Formulations RAW MATERIALS Ampholy t JB130 Antarox BL-225 Antarox BL-240 Antarox BL-330 Aquamoll i n BC Powder Arcosolv PTB Avanel N-1525-90 Avanel S-70/5-74/ S-l50/590 BASF Surfactants B r i t e s i l H24 Burcene 100 Burco ADS-40 Burco ADS-100 Burco BSGH-270 Burco BSGH-Crystals Burco BSGH-400 Burco EHS Burco FAE Burco LAA-38 Burco LAF-6 Burco LAF-125 Burco NPS-225 CHEMICAL DESCRIPTION Coconut f a t t y a c i d amidopropyl b e t a i ne A l i p h a t i c polyether nonionic onic oni c A l i p h a t i c polyether non A l i p h a t i c polyether non Sol vent Surfactant Sodi urn 1inear a1k y l pol yether sulfonate s u r f a c t a n t Pluronic, Plurafac, I n d u s t r o l Hydrous sodi um s i 1icate Surfactant Surfactant Surfactant Surfactant Surfactant Surfactant P r o p r i e t a r y t e x t i l e aux Surfactant Surfactant P r o p r i e t a r y t e x t i l e aux Surfactant l i a r y 1iary SOURCE Huls Rhone- Rhone- Rhone- Arco PPG PPG BASF PQ B u r l B u r l B u r l ng- ng- ng- Bur1ing- B u r l ing- B u r l ing- Burl ing- B u r l ing- B u r l ing- B u r l ing- B u r l ing- B u r l ing-
  • 208.
    TrademarkedRaw Materials 185 RAWMATERIALS Burco NPS 50% Burcosolv TM Burcosperse AP Burcosperse LP Burcotase SL-80 Burco TM€ Burcotrope 1250 Burcowet TM-LF B u t y l Carbit07 Butyl Cellosolve Butyl Propasol Calamide C Calamide 0 Calfax DB-45 Cal foam €A-603 Cal foam ES-303 Cal foam SLS-30 C a l i b r i t e SL Cal irnul se PRS Caloxylate N-9 Calsoft F-90 Calsoft L-40 CHEMICAL DESCRIPTION Proprietary t e x t i l e a u x i l i a r y Water soluble solvent mixture L i q u i d detergent polymer Proprietary detergent polymer Proprietary detergent enzyme Nonionic t h i o e t h e r surfactant I n d u s t r I n d u s t r I n d u s t r Surfactant a7 solvent a1 solvent a1 solvent Foam s t a b i 1iz e r 8 emu1s i f ie r Super amide D i sul fonate L i q u i d detergent L i q u i d detergent Sodium l a u r y l s u l f a t e 30% Emu1s i f ie r Sodi um 1inear a1k y lbenzene Linear sodium dodecylbenzene sulfonate 90% sul fonate SOURCE Burling- Burl ing- Burl ing- Burl ing- Burl ing- Burling- Burl ing- Burl ing- UnCarb UnCarb UnCarb P i 1o t P i l o t P i l o t P i l o t P i l o t P i l o t P i l o t P i l o t P i 1o t P i l o t
  • 209.
    186 Advanced CleaningProduct Formulationr RAW MATERIALS CHEMICAL DESCRIPTION C a l s o f t L-60 Sodium alkylbenzene sulfonate(60%) Cal s o f t LAS-99 Dodecylbenzene s u l f o n i c acid(60%) Calsuds A L i q u i d detergent blend Calsuds CD-6 Coconut o i 1 amide w/sul fonate Calsuds 81 Concentrated detergent blend Carbopol 934 A c r y l i c a c i d polymer.MW:3,000,000 Cardis 36 Wax Oxidized m i c r o c r y s t a l l i n e wax Carspray 500 Beadi ng agent w i t h s i 1icone Carspray 700 Foaming beading agent Cellobond HEC 1OOOOOA Cheel ox BF-13 Cheelox NTA-Na3 Clearon CDB Sodi um d i c h l o r o i socyanurate Concord Co-Wax Emulsion, 12% Concord Wax #1600 Condensate TL Cyanamer A-100L Polyacrylamide Dequest 20605 Dequest 2066 Desonic 9N D i a l a A O i l Dionic OC Organophosphorous product Organophosphorous product Nonionic s u r f a c t a n t Mineral seal o i l F a t t y a c i d methanolamide p o l y g l y c o l ether SOURCE P i l o t P i l o t P i l o t P i l o t P i l o t Goodri ch P e t r o l - W i t c o W i t c o FMC Concord Concord Concord Cyt ec Monsanto Monsanto DeSoto She11 n u i s
  • 210.
    Trademarked Raw Materials187 RAW MATERIALS Dowanol D Dowanol DE Dowanol DPM Dowanol EB Dowanol PnB Dow Corning EP-1-14 Dowfax 2A-1 Dowicide 32 Durcal 40 Durer Resin 15546 CHEMICAL DESCRIPTION Glycol ether Glycol ether Dipropylene g l y c o l methyl ether Ethylene g l y c o l n-butyl ether Glycol ether Anionic s u r f a c t a n t Antimicrobial agent Cal c i um carbonate E Sodium s i l i c a t e 40 Be' E-43 Noni oni c Emcol NA-30 Surface a c t i v e agent Emcol 4500 Surface a c t i v e agent Emersol 213 F a t t y a c i d Emphos PS-220 Emu1s i f i e r Four-HF D i a1k y l quaternary E m u l s i f i e r 827 Emulsion C-340 F7uorad FC- 129 F7uorochemica7 surfactant SOURCE Dow Dow Dow Dow Dow DowCorn Dow Dow PQ W i t c o W i t c o Henkel W i t c o Tomah Tomah Tomah 3M
  • 211.
    I88 Advanced Cleaningproduct Formulations RAW MATERIALS CHEMICAL DESCRIPTION Gantrez AN-149 V i n y l ether polymer Genagen LAB Genamin 5-250 Genaminox MY Genapol OA-80 Genapol UD-030 Genapol UD-050 Genapol UD-080 Genapol ZRO L i q u i d Genapol 2908 General E l e c t r i c SF96-100 S i 1icone Genopur ASA Giv-Gard DXN GP-10-1.000 c s t k Dimethyl s i l i c o n e f GP-10-12,500 c s t k Dimethyl s i l i c o n e f GP-121 S i l i c o n e p o l i s h add GP-7104 S i l i c o n e f l u i d u i d u i d t i v e SOURCE ISP Hoechst Hoechst Hoechst Hoechst Hoechst Hoechst Hoechst Hoechst Hoechst GESi 1i- Hoechst Genesee Genesee Genesee Genesee Harco 20% Soap Hoe S 3924 Hoechst Wax A3 CS Hoechst Wax E Hoechst Wax F Hoechst Wax OM Hoechst Hoechst Ester t y p e wax. Drop point:175F Hoechst Hoechst Hoechst
  • 212.
    nademarked Raw Materials189 CHEMICAL DESCRIPTIONRAW MATERIALS Hoechst Wax OP Hoechst Wax S Hostapur SAS 60 Hypofresh Perfume Igepal CA-630 A l k y l ethoxylate nonionic Igepal CA-720 A1k y l phenol ethoxyl a t e nonioni c Igepal C0-630/C0-660/ Alkylphenol ethoxylate CO-710 Igepal CO-977 Isopar E/K/L/M/V Lanoquat 50 L i poxol Lipoxol 6000 & 12000 Lonzabac 12.30 L y t r o n 295 Latex Kaopolite SF/1152/ Kathon CG Kelzan Kermac 600 K o r t h i x Thixotropic 1168 Agent Water soluble s u r f a c t a n t (70%) Isoparaff in i c s o l vent Quaternary product Polystyrene Anhydrous a emu1s i on uminum s i 1icate Fungic i de (Bio c i de) Xanthan gum Mineral seal o i l Refined white bentonite SOURCE Hoechst Hoechst Hoechst I S P ISP ISP ISP Exxon Henkel Hul s Hul s Lonza Morton Kaopol- Rohm& Kelco Kerr-Mc Kaopol-
  • 213.
    190 Advanced CleaningProduct Formulations RAW MATERIALS Mackadet 40K Mackam JS Mackam MEJ Mackam 2CSF Mackam 2CYSF Mackam 35 Mackamide CD Mackami ne C-10 Mackamine LO Mackazol ine 0 Mackstat DM Macol 48 Macol LF-120 Macol TD-3 Macol TD-12 Maphos 60-A Marl ami ds Marlazi ns Marl in a t s Marl ip a l s Marlons Marlophors CHEMICAL DESCRIPTION Potassium coconut soap Low foam s u r f a c t a n t Amphoteric w e t t i n g agent Surfactant Low foaming s u r f a c t a n t Cocamidopropyl b e t a i ne Cocamide DEA Amine oxide s u r f a c t a n t Amine oxide s u r f a c t a n t 01e y l hydroxyethyl im i dazol ine DMDM hydantoin Block p o l y o l Rinse a i d . MW: 1,000 Nonionic s u r f a c t a n t . HLB: 8.0 Nonionic s u r f a c t a n t . HLB: 14.1 Phosphate ester F a t t y a c i d a1kanol ami des F a t t y amine p o l y g l y c o l ethers F a t t y alcohol ether sulphates F a t t y alcohol p o l y g l y c o l e t h e r s A1kylbenzenesulphonates, sodium s a l t s P a r t i a l phosphate e s t e r s SOURCE M c In t y r e McInt y r e M c Int y r e McIn t y r e McIntyr e McInt y r e McInt y r e McIn t y r e McInt y r e McInt y r e McIntyre PPG PPG PPG PPG PPG Hul s Hul s Hul s Hul s Hul s Huls
  • 214.
    TrademarkedRmu Materials 191 RAWMATERIALS CHEMICAL DESCRIPTION Marlosoft IQ 90 Quaternary im i dazol ines Mar1owets Emu1s i f iers Mar1ox I s Mazamide 80 Mazawet 36 F a t t y a1coho1 a1k y lene oxide a d d i t i o n products Speci a1t y a1kanolamide Surfactant Mazclean EP Mazon 98 Proprietary surfactant Medialan LD Methyl C a r b i t o l Solvent Metso Pentabead 20 Sodium metasilicate, pentahydrate Miranol CS Conc. Cocoamphopropylsulfonate Miranol FBS Surfactant M i ranol JEM Conc. Mixed C8 amphocarboxylate amphoteric surfactant amphoteric M i r a t a i n e TM D i hydroxyethyl t a l l ow g l y c i nate amphoteric surfactant ML-870 Latex A c r y l i c polymer emulsion Montan Wax "S'I Mor-Glo 2 Latex Floor p o l i s h l a t e x (38%) Morton Conrez 510 Polymer emu1s i on M- Py1-01 N-Methyl-2-Pyrrolidone SOURCE Huls Huls Huls PPG PPG PPG PPG UnCarb PQ M i ranol M i ranol M i ranol M i ranol Morton Stroh- Morton Morton I S P
  • 215.
    192 Advanced CleaningProduct Formulotions RAW MATERIALS Neodol 25-3 Ethoxy Neodol 25-3s Neodol 25-7 Ethoxy Neodol 91-8 Ethoxy Ozokeri t e 170 PEG-10 Carnauba Permulsin SP Petro BAF L i q u i d B e t r o BAF Powder Petro LBA/ULF/22 Petro SXS-40 Prapagen WK P r i f a c 7976 Proxel GXL CHEMICAL DESCRIPTION a t e Linear primary alcohol Ethoxysulfate. Sodium c a t i o n a t e Alcohol ethoxylate. MW: 519 a t e Lineal primary a l c o h o l . MW: 529 Pol ycarboxyl a t e Anionic s u r f a c t a n t & dispersant Anionic s u r f a c t a n t & dispersant Anionic s u r f a c t a n t & dispersant Sodium xylene s u l f o n a t e 40% F a t t y a c i d Chemical b io c i de Refined Concord Wax #407 Rewoteric AM B-15 Rewoteric AM KSF-40 Rewoteric AM V Rhodacal A-246/L Rhodacal DS-10 Rhodacal DSB Surfactant SOURCE Shel 1 Shel 1 Shel 1 Shel 1 Koster Koster DeSoto DeSoto DeSoto DeSoto Unichema I C I Concord w i t C O w i t c o w i t c o Rhone- Rhone- Rhone-
  • 216.
    TrademarkedRcmt Materials 193 RAWMATERIALS Rhodacal I PAM Rhodacal 330 Rhodafac LO-529 Rhodafac RA-600 Rhodafac RE-610 Rhodapex GO-436 Rhodapex ES-2 Rhodapax MA-460 Rhodapex NA-61 Rhodopol 23 Rhodapon BOS Rhodapon S0 Rhodapon U0 Rhodasurf 0C-840 Rhodasurf 25-7 Rhodasurf 25-9 Rhodasurf 91-6 Ross Micro Wax 1133/15W Ross Ozokerite Wax 77Y CHEMICAL DESCRIPTION Phosphate ester nonioni c PhosDhate ester anionic SOURCE Rhone- Rhone- Rhone- Rhone- Rhone- Rhone- Rhone- Rhone- Rhone- Rhone- Rhone- Rhone- Rhone- Ethoxylated t r i d e c y l alcohol Rhone- Rhone- Rhone- Rhone- Ross Ross SAG 1010 S i l i c o n e a n t i foam UnGarb Sequi on 1ONa2 Phosphonate HEDP SF96(100)/SF96(350)/ Polydimethyl s i l i c o n e f l u i d GESi 1 Shellsol T I s o p a r a f fin i c solvent She11 SM 2109 GESi 1 SF96(1OOO)/SF 1705/SF 1706
  • 217.
    194 Advanced CleaningProduct Formulations RAW MATERIALS SM 2133/SM 2135 Snow Floss S i l i c a Sokalan CP 5 Sokalan HP 22 Sokalan HP 50 Sokalan PA 40 Solvent BG Solvent Span 80 SR 107 S t a r Stepano GX 5 DEA (35%) Super Floss Surfonic N-95 SWS 211 S i l i c o n e Syntran 6520 Technocell 90 DU Texstim 8741 Thermphos NW T i nopal CBS-X CHEMICAL DESCRIPTION Processed diatomaceous s i l i c a Polycarboxylate P o l y v i n y lp y r r o l idone Polycarboxylate Surfactant Sodium s i l i c a t e 42 Be’ D i ethanol ami ne 1a u r y l s u l f a t e Mineral f i l l e r Nonionic s u r f a c t a n t . HLB: 12.9 A n t i foam Acryl ic emu1s i on Nonionic s u r f a c t a n t F1uorescent Tomah A l k a l i Surfactant: Amphoter Tomah AO-14-2 Ether amine Tomah A0-728 Special Amine oxide whitening agent c (35% A c t i v e ) oxide s u r f a c t a n t s u r f a c t a n t SOURCE GESi 1 Manvi 11e I C I PQ Step n Manvi 11e Texaco Wac ker I n t e r - Tomah C i ba- Tomah Tomah Tomah
  • 218.
    TrademarkmiRaw Materials 195 RAWMATERIALS CHEMICAL DESCRIPTION Tomah E m u l s i f i e r Four D i a l k y l quaternary s u r f a c t a n t Tomah Q-17-2 Triethanolamine R T r i t o n CF-10 A l k y l a r y l polyether nonionic Tween 81 Surfactant Tylose CBR 10000 Ucon Ucon Union Union 1 Propel 1ant 2 Propel l a n t Carbide L-45, 100 cstks. S i l i c o n e Carbide L-45, 30,000 cstks. S i l i c o n e Union Carbide L-46 Union Carbide LE-461 Union Carbide LE-462 Varami de A-83 Varamide ML-1 Varion AM-KSF-40% Varonic K205/LI-48/ LI-67 Varox 365 Varox 1770 Varsol 81 Varsol No.2 Veegum Pro S i 1icone S i 1icone S i 1icone Detergent a1kanolamide Detergent a1kanolamide Surfactant Nonionic w e t t i n g agent Wetting agent,degreaser,detergent Amine oxide Mineral spi r it s Complex c o l 1o i dal magnesi urn aluminum s i l i c a t e SOURCE Tonah Tomah UnCarb I C I UnCarb UnCarb UnCarb UnCarb UnCarb UnCarb UnCarb W i t c o W i t c o W i t c o W i t c o W i t c o W i t c o Exxon Vander-
  • 219.
    1% Advanced CleaningProduct Formulations RAW MATERIALS CHEMICAL DESCRIPTION SOURCE Versene 100/220 S o l u t i o n o f tetrasodium s a l t o f Dow EDTA Vestinol C Huls Vestowax AW 1060 Wax emulsion, 15% basis Hul s V i s c a s i l l O , O O O / S i l i c o n e f l u i d 12,000/30,000 GESi 1 Vol c l ay NF-BC Western b e n t o n i t e AmColl Wessalith P Z e o l i t h A W i tcami de CDA/ A1kanolami de s u r f a c t a n t Witco 5-771 /128T/511/5195 Witco 1298 S o f t Acid W i t c o W i t c o l a t e A Sodium l a u r y l s u l f a t e . Anionic W i t c o W i t c o l a t e AE-3/ S u l f a t e d s u r f a c t a n t s ES-3/LES-60A/S-1285C/SE-5/WAC-LA/2310/7031 W i tconate AOS/ Sul fonate s u r f a c t a n t SXS/3ODS/45LX Witconate 1260 S l u r r y C-12 LAS (60%) Witconol 14 Noni oni c Z e o l i t h A #3 Carnauba 668 P o l i s h i n g Powder 678 Pol is h i ng Powder 787 P o l i s h i n g Alumina P-10 F e i n s t W i t c o W i t c o W i t c o W i t c o Koster Whi ttCD Whi t t C D Whi t t C D
  • 220.
  • 221.
    198 Advanced CleaningProduct Formulations A1 1ied-Si gnal I n c . P.O. Box 2332R Morristown, NJ 07962 (201)-455-2000/(800)-526-0717 American C o l l o i d Co. 1500 W. Shure D r . A r l i n g t o n Heights, I L 60004 (312)-392-4600 Arc0 Chemical Co. 3801 West Chester Pike Newtown Square, PA 19073 (215)-359-2000 BASF Corp. 100 Cherry H i l l Rd. Parsi ppany, NJ 07054 (201)-316-3000/(800)-526-1072 BP O i l I n c . 200 P u b l i c Square Cleveland, OH 44114 (216)-586-6364/(800)-321-8598 B u r l ington Chemical Co. , I n c . P.O. Box 111 615 Huffman M i l l Rd. Burlington, NC 27215 (919)-584-0111/(800)-672-5888 Concord Chemical Co. 17th and Federal Sts. Camden, NJ 08105 (609)-966-1526 Cytec I n d u s t r i e s , I n c . F i v e Garret Mountain Plaza West Paterson, NJ 07424 (908)-B62-6000/(800)-253-4078 DeSoto, I n c . 1700 S. M t . Prospect Rd. Des Plaines, I L 60018 (312)-391-9000 Dow Chemical Co. Midland, M I 48674 (800)-258-CHEM Dow Corning Corp. Box 0994 Midland, M I 48686 (517)-496-4000 Eastman Chemical Co. P.O. Box 431 Kingsport, TN 37662 (615)-229-2318/(800)-327-8626 Exxon Chemica? Americas 13501 Katy Frwy Houston, TX 77079 (713)-870-6000/(800)-231-6633 FMC Corp. 2000 Market S t . Philadelphia, PA 19103 (215)-299-6000/(800)-526-3649 ISP/GAF Corp. 1361 Alps Road Wayne, NJ 07470 Genesee Polymers Corp. Fenton Rd. P.O. Box 7047 F l i n t , M I 48507 (201)-628-3000/(800)-848-7659 (313 ) -238-4966 GE S i 1icones 260 Hudson River Rd. Waterford, NY 12188 (518)-237-3330/(800)-255-8886 BF Goodrich Co. 9911 Brecksvi 11e Rd. B r e c k s v i l l e , OH 44141 (216)-447-5000/(800)-332-1144 Haarman & Reimer Corp. P.O. Box 175 70 Diamond Rd. S p r i n g f i e l d , NJ 07081 (201)-467-5600/(800)-422-1559
  • 222.
    Suppliers' Addresses 199 HenkelCorp. 5325 S. N i n t h Ave. LaGrange, I L 60525 (708)-530-7300/(800)-543-7370 Hoechst-Celanese Corp. 26 Main St. Chatham, NJ 07960 Huls America I n c . Turner P1. P i scataway, NJ 08855 Interpolymer Corp. 330 Pine St. Canton, MA 02021 Kaopolite, I n c . 2444 M o r r i s Ave. Union, NJ 07083 (201)-635-2600/(800)-526-4960 (201)-981-5000/(800)-526-0339 (617)-828-7120/(800)-444-1281 (908)-769-0609 Kelco Div. Merck & Co., Inc. 8355 Aero D r i v e San Diego, CA 92123 Kerr-McGee Chemical Corp. Kerr-McGee C t r . P.O. Box 25861 Oklahoma C i t y , OK 73125 (619)292-4900/(800)-535-2656 (405)-270-1313/(800)-654-3911 Koster Keunen I n c . P.O. Box 447 90 Bourne Blvd. S a y v i l l e , NY 11782 (516)-589-0456 Johns-Manville Ken Caryl Ranch Denver, CO 80217 McIntyre Group Ltd. 4851 S. St. Louis Ave. Chicago, I L 60513 (312)-927-2401 Miranol I n c . P.O. Box 436 Dayton, NJ 08810 Mona I n d u s t r i e s I n c . 76 E. 24 S t . P.O. Box 425 Paterson, NJ 07544 Monsanto Chemical Co. 800 N. Lindbergh Blvd. S t . Louis, MO 63167 Morton I n t e r n a t i o n a l Inc. 100 N. Riverside Plaza Chicago, I L 60606 P e t r o l i t e Corp. 6910 E. 14 S t . Tulsa, OK 74112 (918)-838-1601 (201)-329-3900 (201)-345-8220/(800)-553-6662 (314)-694-1000/(800)-325-4330 (312)-807-2000/(800)-367-3318 P i l o t Chemical Co. 11756 Burke S t . Santa Fe Springs, CA 90670 (310)-723-0036 PPG Chemical s 3938 P o r e t t D r i v e Gurnee, I L 60031 PQ Corp. P.O. Box 840 Valley Forge, PA 19482 Rhone-Poulenc CN 7500 Prospect P l a i n s Rd. Cranbury, NJ 08512 Rohm & Haas Co. Independence Mall West Philadelphia, PA 19105 (708)-244-3410/(800)-323-0856 (215)-293-7200 (609)-860-4000/(800)-620-2613 (215)-592-3000
  • 223.
    200 Advanced CleaningProduct Formulations Ross Chemical I n c . 303 Dale O r . F o u n t a i n I n n , SC 29644 (803)-862-4474 Sandoz Chemical s Corp. 4000 Monroe Rd. C h a r l o t t e , NC 28205 (704)-331-7078/(800)-631-6077 S h e l l Chemical Co. P . O . Box 2463 Houston, TX 77252 (713)-241-6161 Stepan Co. 22 W. Frontage Rd. N o r t h f i e l d , I L 60093 (708)-446-7500/(800)-745-7837 Strohmeyer & Arpe Co., I n c . 89 M i 1b u r n Ave. M i l b u r n , N J 07041 (201)-761-7600 Texaco Chemical Co. 3040 Post Oak B l v d . Houston, TX 77056 (713)-961-3711 Tomah Products, I n c . 1012 T e r r a D r i v e M i l t o n , W 1 53563 (608)-868-6811/(800)-441-0708 3M 3M Center S t . Paul, MN 55144 (612)-733-5454 Unichema Chemicals, I p c . 4650 S. Racine Ave. /' Chicago, I L 60609 (312)-376-9000/(800)-833-2864 Union Carbide Corp. 39 O l d Ridgebury R d . Danbury, CT 06817 (203)-794-2000 RT V a n d e r b i l t Co., I n c . P.O. Box 5150 30 W i n f i e l d S t . N o r f o l k , CT 06856 Wacker S i l i c o n e s Corp. 3301 S u t t o n Rd. Adrian, M I 49221 (203)-853-1400/(800)-243-6064 (517)-264-8500/(800)-246-0063 W h i t t a k e r , C l a r k & D a n i e l s , I n c . 1000 Coolidge S t . S. P l a i n f i e l d , NJ 07080 (201)-561-6100 W i t c o Chemical Co. 5777 F r a n t z Rd. P.O. Box 646 D u b l i n , OH 43017 (614)-765-6500/(800)-366-6500 Witco Corp. 520 Madison Ave. New York, NY 10022 (212)-605-3941/(800)-634-4010
  • 224.
    Other Noyes Arblications ADVANCEDCLEANING PRODUCT FORMULATIONS Volume 3 by Ernest W. Flick Thisbook(Volume3)presentsmorethan630 up-to-date advanced cleaning product form- ulationsfor household,industrialandautomotive applications.Itistheresultofinformationreceived from numerous industrial companies and other organizations. The data represent selections madeatnocostto,norinfluencefrom,themakers or distributors of these materials. Onlythe most recent formulas have been included. All formulationsarecompletelydifferent thanthose contained in Volume 1 published in 1989 and Volume 2publishedin 1994. Formulationin the cleaning product industry hasgraduallybeenundergoingsignificantchange duringthe pastyears. Rawmaterialscosts have risen and manufacturers have beenreluctant to passalongtheseincreases. Environmentalcon- siderationshavealsoplayedapart. Bychanging formulationsto improvecost/performance char- acteristics, manufacturers have been able to controlcostsbutstillenhanceperformance.This bookpresentsmanufacturers' suggestedformu- lationswhich might meet new performancecri- teria. The formulationsinthis book are divided into the following sections and chapters, with the numberofformulationsindicatedin(): 1. 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. Household and Industrial Cleaners and Polishes BathroomCleaners (14) DairyFoodand GeneralIndustrial Cleaners (52) Degreasers(25) Dishwashing Detergents (70) General PurposeCleaners (29) GlassCleanarsPolishes (18) HardSurface Cleaners (59) Laundry Products (100) MetalCleaners and Polishes(52) Oven, Grilland Hot PlateCleaners(11) Polishes, Coatingsand Finishes(19) RinseAids (5) 13. 14. II. 15. 16. 17. 18. Rug, Floor, Carpet, Upholstery Sham- Miscellaneous (49) TransportationCleanersandPolishes AutoCleanersand Polishes (32) CarandTruck WashCompounds (34) Whitewall TireCleaners (11) Miscellaneous poos and Cleaners (41) Eachformulaislocatedinthechapterwhichis most applicable. The reader, seeking a formula foraspecificenduse, shouldcheckeachchapter which could possibly apply. In addition to the above,therearetwo other sectionswhichwillbe helpfultothereader. 111. A chemical trademark section where each tradenamed raw material in- cluded in the book is listed with a chemicaldescriptionandthesupplier's name. The specificationswhich each raw material meets are included, if applicable. IV. Mainofficeaddressesof thesuppliers of trademarkedrawmaterials. Eachformulation inthebook liststhefollowing information, as available, inthe manufacturets ownwords: 0 Descriptionof enduseandmostoutstanding properties. 0 The percentbyweight orvolumeof eachraw materialincludedintheformula, roundedtoa decimalfigure. 0 Keypropertii of the formula, which arethe featuresthatthesourceconsidentobemore outstanding than other formulations of the sametype. 0 Theformulasource, which isthecompanyor organization that supplied the formula. The secondary source may be the originating company and/or the primary source's publicationtitle,orboth.Aformulanumberis included,if applicable. ISBN0-8155-1382-8 (1995) 6"x9' 280pages
  • 225.
    Other Noyes Publications ADVANCEDCLEANING PRODUCT FORMULATIONS Volume 2 by Ernest W. Flick This book (volume 2) presents more than 800 up-to-date advanced cleaning product formulations for household, industrial and automotive applications. It is the result of information received from numerous industrial companies and other organizations. The data represent selections made at no cost to, nor influencefrom, themakersordistributorsofthese materials. Only the most recent formulas have been included. All formulations are completely different than those contained in Volume 1, which was publishedin 1989. Formulation in the cleaning product in- dustry has gradually been undergoing sig- nificant change during the past years. Raw materials costs have risen and manufacturers have been reluctant to pass along these in- creases. Environmental considerations have also played a part. By changing formulations to improve cost-performance characteristics. manufacturers have been able to control costs but still enhance performance. This book pre- sents supplier's suggested formulations which might meet new performance criteria. Theformulationsinthisbookaredividedinto the following sections and chapters, with the number of formulations indicated in(): 1. 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. Household and industrial Cleaners and Polishes(733) Bathroom Cleaners (29) Dairyand Food IndustryCleaners (15) Degreasers(20) Dishwashing Detergents(67) DetergentsDisinfectants(36) General Purpose Cleaners(47) Hard Surface Cleaners (60) Laundry Products (217) Metal Cleaners(87) Polishes, Coatings and Sealers(32) RinseAids (6) ISBN0-8155-1346-1 (1994) 12. 13. /I. 14. 15. 16. 17. Rug,Carpet and Upholstery Shampoos Miscellaneous Cleaners(96) Transportation Cleanersand Polishes(76) Auto Cleanersand Polishes (9) Car and Truck Wash Compounds (38) Whitewall Tire Cleaners(10) Miscellaneous (19) Inaddition to the above, there aretwoother and Cleaners (21) sections which will be helpful to the reader. 111. A chemical trademark section where each tradenamed raw material included in the book is listed with a chemical description and the sup- plier's name. The specifications which each rawmaterial meets are included, if applicable. lV. Mainoffice addresses of the suppliers of trademarked rawmaterials. Each formulation in the book lists the following information, as available: 1. Description of end use and most outstanding properties. 2. The percent by weight or volume of each raw material included in the formula. 3. Key properties of the formula, which are the features that the source considerstobemoreoutstandingthan other formulations of thesametype. 4. The formula source, which is the company or organizationthat supplied the formula. The secondary source maybetheoriginatingcompanyand/or the primary source's publication title. or both.A formula number is included, if applicable. f64 6"x9" 394pages