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PAINTS
oPaints are fluid material that after applying over a
surface forms a solid, cohesive, decorative and
protective film.
oIt is primarily used for decorative purposes but also
as a protecting agent for the surface.
oIts use has been investigated in ancient Egypt where
artist would use paints for making paintings.
oPaint has three main ingredients
oPigment
oBinder
osolvent
Pigments (& Extenders)
o Pigments are solids which are responsible for giving color
to the paint system.
o Pigments are primarily opaque and provide opacity to
paints while Extenders are practically transparent and
does not impart color.
o Pigments – organic and inorganic.
o Most organics are manufactured, have brilliant color but
their opacity varies very much.
o Inorganic – natural and manufactured.
o Natural inorganics are oxides and hydroxides of Iron.
o Manufactured inorganics cover a wide range of colors
including whites.
Table Representing concentration of oxides of iron to obtain different colors
o Binders are the continuous phase in which pigments are
dispersed.
o It is responsible for the mechanical and protective
properties the paint has.
o Can be dissolved in solvents or suspended to form
emulsion.
o Provides adhesion to the surface
o Binders – organic and inorganic
o Organics include resins containing fatty acids, polymers.
o Inorganics include silica based materials like ethyl silicate,
alkali silicates and quaternary ammonium silicates.
o Convertible (thermoset binders) and non-convertible.
BINDER
o Solvents are used to render the pigment-binder system.
o It reduces the viscosity to ensure uniform coating
o After application, it is no longer required and should
vaporize quickly.
o Majority of solvents are toxic or are harmful, which is a
cause of concern.
o Solvents chosen are organic in nature.
o Plasticizers are taken in case of non-convertibles and are
mostly oils.
o Apart from these ingredients, additives might also be added to
impart or improve one or more properties.
SOLVENTS
POINTS TO KEEP IN MIND
o Interaction of solvent with other ingredients is
important.
o It should provide appropriate rheological properties
before and during application.
o Solvent release after application is an important
criteria
o If solvent remains in paint film after application, it
may cause internal tension and shrinkage.
o Selection of binder – based on compatibility with
solvents, type of drying etc.
Manufacturing of paints
o Starts with paste grinding process – where pigments
are broken down into fine particles.
o This is then introduced in mixer where binder and
solvents are added.
o It is then sent to another tank where further
materials are added to make it a finished product.
o Quality checking and testing follows after. Color
intensity, matching, viscosity, gloss etc. are being
tested.
o Paint is then filtered to remove any unwanted
particles before being packed.
PASTE MAKING
 It is an important part. Milling machines are preferred
for this.
 High-Speed Disperser (HSD) – Tank jacketed for
cooling, a motor & a shaft with blades bent at 900C.
 Dispersion is near or at the surface of blades.
 Operates at 915-1921.5 m min-1.
 Low maintenance, low labor, easy to operate.
 High power dissipation, needs easily dispersible
pigments.
 Latex, primers, plastisols, PU etc.
CONT…
 Continuous Milling Machine – based upon shearing action.
 Have high speed shafts with multiple discs.
 Have high rates, easy to clean and large batch sizes.
 Expensive to maintain, cannot grind tough pigments, requires
premix tanks.
 Primers, PU, lacquers etc.
 Ball Mill – In use from earlier times. Has a steel cylinder and
filled with 1/3 of it’s volume with steel balls which are
responsible for the grinding action.
 Up to 40% vol. should be of pigments, no solvent loss, low
maintenance, easy handling.
 Takes long time, discoloration from metal may occur,
becomes difficult to clean.
 Primers, alkyds, Polyesters, Acrylics, Lacquers.
DISPERSION/DISSOLVING
 Roller Mills – One to five rollers can be used with
three roll mill being preferable.
 First roller is slowest, second rotates at moderate
speed and third rotates fastest.
 Hopper is above first roller.
 Nip gap between first and second roller is small
which further shears the pigments. The other nip gap
ensures dispersion.
 Provides finish, removes dust and other unwanted
particles. Continuous process of pigment breaking
and dispersion.
 Very slow process; unsuitable if volatile solvents are
used.
 After paste-making, it’s dispersion into binder comes.
 Kneaders are first choice because of the variety it
can produce (highly viscous, putties, rubbery
composition).
 It can also be used for those systems which are
difficult to wet.
 Batch-wise or continuous operation.
 Pug Mixers are also used.
 Heavy-duty machines; provide high consistency.
 Horizontal and vertical arrangements
 Horizontal provides high consistency, while vertical is
used primarily for heavy pastes & putties.
Vertical Pug Mixer Horizontal Pug Mixer
FILTER SYSTEM
 Before filling, cleanliness must be ensured of the
end product.
 Sieves – Mesh or gauges made from steel (or
metals).
 Paints are poured onto a vibrating screen. It vibrates
either horizontally or vertically, allowing paint to pass
through sieves.
 Bag Filters – metal filter with closable and/or
sealable covers.
 Filter Cartridge – multiple cartridges are aligned on
after other through which paint passes. Synthetic
micro fibers are used as filter material (5-100 µm).
References
• Outlines of Paint Technology – W.M. Morgans
• Paints, Coatings and Solvents – D. Stoye & W. Freitag.
• Paint Technology Handbook – Rodger Talbert.
• Wikipedia
• Google (For pictures).
Manufacture of paints

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Manufacture of paints

  • 1. PAINTS oPaints are fluid material that after applying over a surface forms a solid, cohesive, decorative and protective film. oIt is primarily used for decorative purposes but also as a protecting agent for the surface. oIts use has been investigated in ancient Egypt where artist would use paints for making paintings. oPaint has three main ingredients oPigment oBinder osolvent
  • 2. Pigments (& Extenders) o Pigments are solids which are responsible for giving color to the paint system. o Pigments are primarily opaque and provide opacity to paints while Extenders are practically transparent and does not impart color. o Pigments – organic and inorganic. o Most organics are manufactured, have brilliant color but their opacity varies very much. o Inorganic – natural and manufactured. o Natural inorganics are oxides and hydroxides of Iron. o Manufactured inorganics cover a wide range of colors including whites.
  • 3. Table Representing concentration of oxides of iron to obtain different colors
  • 4. o Binders are the continuous phase in which pigments are dispersed. o It is responsible for the mechanical and protective properties the paint has. o Can be dissolved in solvents or suspended to form emulsion. o Provides adhesion to the surface o Binders – organic and inorganic o Organics include resins containing fatty acids, polymers. o Inorganics include silica based materials like ethyl silicate, alkali silicates and quaternary ammonium silicates. o Convertible (thermoset binders) and non-convertible. BINDER
  • 5. o Solvents are used to render the pigment-binder system. o It reduces the viscosity to ensure uniform coating o After application, it is no longer required and should vaporize quickly. o Majority of solvents are toxic or are harmful, which is a cause of concern. o Solvents chosen are organic in nature. o Plasticizers are taken in case of non-convertibles and are mostly oils. o Apart from these ingredients, additives might also be added to impart or improve one or more properties. SOLVENTS
  • 6. POINTS TO KEEP IN MIND o Interaction of solvent with other ingredients is important. o It should provide appropriate rheological properties before and during application. o Solvent release after application is an important criteria o If solvent remains in paint film after application, it may cause internal tension and shrinkage. o Selection of binder – based on compatibility with solvents, type of drying etc.
  • 7. Manufacturing of paints o Starts with paste grinding process – where pigments are broken down into fine particles. o This is then introduced in mixer where binder and solvents are added. o It is then sent to another tank where further materials are added to make it a finished product. o Quality checking and testing follows after. Color intensity, matching, viscosity, gloss etc. are being tested. o Paint is then filtered to remove any unwanted particles before being packed.
  • 8. PASTE MAKING  It is an important part. Milling machines are preferred for this.  High-Speed Disperser (HSD) – Tank jacketed for cooling, a motor & a shaft with blades bent at 900C.  Dispersion is near or at the surface of blades.  Operates at 915-1921.5 m min-1.  Low maintenance, low labor, easy to operate.  High power dissipation, needs easily dispersible pigments.  Latex, primers, plastisols, PU etc.
  • 9. CONT…  Continuous Milling Machine – based upon shearing action.  Have high speed shafts with multiple discs.  Have high rates, easy to clean and large batch sizes.  Expensive to maintain, cannot grind tough pigments, requires premix tanks.  Primers, PU, lacquers etc.  Ball Mill – In use from earlier times. Has a steel cylinder and filled with 1/3 of it’s volume with steel balls which are responsible for the grinding action.  Up to 40% vol. should be of pigments, no solvent loss, low maintenance, easy handling.  Takes long time, discoloration from metal may occur, becomes difficult to clean.  Primers, alkyds, Polyesters, Acrylics, Lacquers.
  • 10. DISPERSION/DISSOLVING  Roller Mills – One to five rollers can be used with three roll mill being preferable.  First roller is slowest, second rotates at moderate speed and third rotates fastest.  Hopper is above first roller.  Nip gap between first and second roller is small which further shears the pigments. The other nip gap ensures dispersion.  Provides finish, removes dust and other unwanted particles. Continuous process of pigment breaking and dispersion.  Very slow process; unsuitable if volatile solvents are used.
  • 11.
  • 12.  After paste-making, it’s dispersion into binder comes.  Kneaders are first choice because of the variety it can produce (highly viscous, putties, rubbery composition).  It can also be used for those systems which are difficult to wet.  Batch-wise or continuous operation.  Pug Mixers are also used.  Heavy-duty machines; provide high consistency.  Horizontal and vertical arrangements  Horizontal provides high consistency, while vertical is used primarily for heavy pastes & putties.
  • 13. Vertical Pug Mixer Horizontal Pug Mixer
  • 14. FILTER SYSTEM  Before filling, cleanliness must be ensured of the end product.  Sieves – Mesh or gauges made from steel (or metals).  Paints are poured onto a vibrating screen. It vibrates either horizontally or vertically, allowing paint to pass through sieves.  Bag Filters – metal filter with closable and/or sealable covers.  Filter Cartridge – multiple cartridges are aligned on after other through which paint passes. Synthetic micro fibers are used as filter material (5-100 µm).
  • 15. References • Outlines of Paint Technology – W.M. Morgans • Paints, Coatings and Solvents – D. Stoye & W. Freitag. • Paint Technology Handbook – Rodger Talbert. • Wikipedia • Google (For pictures).