This document provides an overview of a workshop on mathematical modelling and simulation of power plants and CO2 capture. [1] It discusses modelling of supercritical coal-fired power plants, including models of the coal mill, supercritical boiler, steam turbine, and synchronous generator. [2] The models are implemented in MATLAB/Simulink and include differential equations representing the various components. [3] The workshop aims to understand the dynamic responses of supercritical power plants and investigate strategies to improve their ability to respond quickly to changes in electricity demand as required by grid codes.