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5000TOCi Sensor
Fast, continuous measurement
Reliable operation
Reagent and chemical free
USP <643>, <645>, Ch P, 			
EP 2.2.44, and JP compliant
Compact sensor design
ISM diagnostics
5000TOCiwithISM
Fast, Continuous and Reliable
Total Organic Carbon Measurement
Alliance Technical Sales
Clarendon Hills, IL USA
630-321-9646
www.alliancets.com
2
5000TOCi
Total Organic Carbon Sensor
5000TOCiSensor
The 5000TOCi Total Organic Carbon Sensor with ISM from METTLER TOLEDO
Thornton delivers the power of an analyzer with the convenience of a sensor.
Offering the fastest response to TOC changes available, the 5000TOCi is an ideal
instrument for TOC measurement in all pure water applications where rapid detec-
tion of changes in TOC is critical.
Strength in Operation
Pure and Ultrapure water produc-
tion requires monitoring of organic
contamination throughout the treat-
ment process. The 5000TOCi Sensor
provides continuous, fast, and reli-
able monitoring of TOC levels from
post RO waters to point-of-use. With
continuous on-line measurements,
the 5000TOCi Sensor ensures TOC
excursions will not be missed.
Power of an Analyzer
Complete process control and precise data trending with real-time
continuous TOC measurement and the fastest response available.
Improve measurement reliability of your continuous, real-time
TOC analysis by eliminating sensitivity to pressure changes
with an automated flow control system.
Simplify record keeping for the release of water through
simplified data collection with innovative Peak and Average
TOC measurements by analyzing up to 24 hours of readings with
only two measurements.
Perform trouble-free maintenance with consistent results through a 	
semi-automated Calibration and System Suitability Testing process.
Conduct fast and easy service planning through convenient
diagnostics and sensor status information using iMonitor to quickly
determine routine maintenance requirements and sensor health.
Convenience of a Sensor
Maximize uptime with a robust, reliable design virtually free from 	
moving parts.
Reduce complexity of your pure water instrumentation by integrating 	
TOC measurement into a comprehensive UPW monitoring system 	
with multi-parameter capability.
Lower costs with the ability to monitor up to four TOC sensors on a 	
single M800 transmitter.
3
Pharmaceutical-grade waters
must meet strict water quality re-
quirements for Purified Water (PW),
Water for Injection (WFI) and
Highly Purified Water (HPW). TOC
instruments used must also un-
dergo periodic testing to verify the
ability to accurately measure TOC.
The 5000TOCi Sensor provides the
performance needed to meet all
regulatory requirements, including
USP <645> for conductivity, while
offering added benefits such as
continuous on-line measurement
in a low-maintenance, industrial
package.
Power generation makeup water
treatment – from reverse osmosis
to demineralizers, the 5000TOCi
Sensor provides fast reliable moni-
toring of TOC contamination in the
water system. Organic contamina-
tion can be detected before it enters
the steam cycle where its break-
down to organic acids can acceler-
ate corrosion.
Recycle and reclaim applications
take advantage of the fast analysis
time. The 5000TOCi Sensor pro-
vides continuous monitoring, not
lengthy batch cycles. This enables
rapid response to TOC excursions
caused by process variability, al-
lowing for a higher percentage of
recycle and reclaiming to reduce
water usage and costs.
4
5000TOCi
Fast, Continuous, Reliable Measurement
5000TOCiSensor
Continuous
The 5000TOCi ensures detection
of even the shortest water system
changes through the use of con-
tinuous flow-through analysis. This
design results in an ideal process
control instrument which delivers
a continuous, real-time measure-
ment, enabling detection of all TOC
changes regardless of duration.
Reliable
Utilizing high performance,
Thornton conductivity sensors con-
structed from titanium, and con-
taining virtually no moving parts,
the 5000TOCi offers a robust
construction to maximize up-time
and assure reliable measurement
performance.
Fast
Equipped with a spiral quartz tube
design, the 5000TOCi maximizes
sample exposure to the 185 nano-
meter UV light to provide rapid
sample oxidation. This configura-
tion minimizes measurement re-
sponse time and delivers measure-
ment performance ideal for process
control.
5
5000TOCi Sensor Dimension Diagram
5000TOCi Sensor Installation
The Thornton 5000TOCi Sensor minimizes installation and setup time. Two tubing connections are required, one for the sample
inlet, and one for the oxidized sample outlet. An isolation valve is required at the sample point for shutoff (valve not supplied).
6
5000TOCi
Product Specifications
5000TOCiSensor
TOC Sensor
Measurement Range	 0.05 - 2000 ppbC (µgC/L)
Accuracy	 ± 0.1 ppb C for TOC < 2.0 ppb (for water quality > 15 mΩ-cm [.067 µS/cm])
	 ± 0.2 ppb C for TOC > 2.0 ppb and < 10.0 ppb (for water quality > 15 mΩ-cm)
	 ± 5% of measurement for TOC > 10.0 ppb (for water quality 0.5 to
	18.2mΩ-cm)
Repeatability	 ± 0.05 ppb C < 5 ppb, ± 1.0% > 5 ppb
Resolution	 0.001 ppbC (µgC/L)
Analysis Time	 Continuous
Initial Response Time	 < 60 seconds
Update Rate 1 second
Limit of Detection	 0.025 ppbC
Conductivity Sensor
Conductivity Accuracy	 ±2%,0.02-20 µS/cm ±3%, 20-100 µS/cm; 0.1 Constant Sensor*
Cell Constant Accuracy	 ± 2%
Temperature Sensor	 Pt1000 RTD, Class A
Temperature Accuracy	 ± 0.25°C
Sample Water Requirements
Temperature	 0 to 100 °C **
Particle Size	 <100 micron
Minimum Water Quality	 > 0.5 mΩ–cm (< 2 µS/cm), pH < 7.5 ***
Flow Rate	 > 20 mL/min
Pressure	 4 to 200 psig (0.3 bar to 13.6 bar) at sample inlet connection ****
7
General Specifications
Case Dimensions	 11” [280mm] W x 7.4” [188mm] H x 5.25” [133mm] D
Weight	 5.0 lb. (2.3 kg)
Enclosure Material	 Polycarbonate plastic, flame retardant, UV and chemical resistant
	 UL # E75645, Vol.1, Set 2, CSA #LR 49336
Enclosure Rating	 NEMA 4X, IP65 Industrial environment
Ambient Temperature/	 5 to 50°C / 5 to 80% Humidity, non-condensing
Humidity Rating
Power Requirements	 100 - 130VAC or 200 - 240VAC, 50/60 Hz, 25W Maximum
Local Indicators	 Four LED lights for Fault, Error, Sensor Status and UV Lamp ON
Ratings/Approvals 	 CE Compliant, UL and cUL (CSA Standards) listed, NEMA 4X, IP65 Conductivity
and temperature sensors traceable to NIST, ASTM D1125 and D5391. Meets
ASTM D5173 Standard Test Method for On-Line Monitoring of Carbon Com-
pounds in Water by UV Light Oxidation
Installation/Power/Enclosure
Inlet Connection	 0.125” [3mm] O.D. (6’ [2m] FDA compliant PTFE tubing supplied)
Outlet Connection	 0.125” [6mm] O.D. Barb connection (5’ [1.5m] flexible tubing provided)
Inlet Filter	 316SS, inline 60 micron
Wetted Parts	 316SS/Quartz/PEEK/Titanium/PTFE/Polyurethane (outlet tubing only)/EPDM
Wall Mount	 Standard, mounting tabs provided
Pipe Mount	 Optional, with pipe-mount bracket accessory
	 (for nominal pipe sizes 1” [2.4 cm] to 4” [10 cm])
Maximum Sensor Distance	 300ft [91m]
* Readout in equivalent S/m ranges selectable at M800								
** Temperature above 70°C requires Sample Conditioning Coil (included)
*** For power plant cycle chemistry samples, pH may be adjusted by measurement after cation exchange.
**** Process pressure above 85 psig (5.9 bar) requires optional High Pressure Regulator p/n 58 091 552.
Specifications subject to change without notice.
Visit for more information
www.mt.com/thornton
Mettler-Toledo Thornton, Inc.
900 Middlesex Turnpike, Bldg. 8
Billerica, MA 01821 USA
Tel +1-781-301-8618
Fax. +1-781-301-8701
Toll Free +1-800-510-PURE(US & Canada Only)
Subject to technical changes
©Mettler-Toledo Thornton, Inc.
Printed in USA
58 087 019 Rev D 01/2014
			
5000TOCi Ordering Information
Description Order No.
5000TOCi Sensor, 110VAC, 50/60 Hz
5000TOCi Sensor, 220VAC, 50/60 Hz
5000TOCi Sensor, Low ppb calibration, 110VAC, 50/60 Hz
5000TOCi Sensor, Low ppb calibration, 220VAC, 50/60 Hz
Accessories
Kit, Calibration and System Suitability Test with UniCond®
Sensor (SST and calibration standards sold separately)
Validation Support Package, 5000TOCi
Pump Module
Pipe Mounting Kit, 1-1/2” (3.8cm) pipe
Pipe Mounting Kit, 2” (5cm) pipe
Pipe Mounting Kit, 3” (7.6cm) pipe
Pipe Mounting Kit, 4” (10cm) pipe
Filter Assembly, High capacity
High pressure regulator
Stainless steel outlet tube
Patch Cord, 1 ft(0.3 m)
Patch Cord, 5 ft(1.5 m)
Patch Cord, 10 ft(3.0 m)
Patch Cord, 15 ft(4.5 m)
Patch Cord, 25 ft(7.6 m)
Patch Cord, 50 ft(15.2 m)
Patch Cord, 100 ft(30.5 m)
Patch Cord, 150 ft(45.7 m)
Patch Cord, 200 ft(61.0 m)
Patch Cord, 300 ft(91.4 m)
Consumables and Spare Parts
Replacement UV Lamp (recommended every 4,500 hours of operation)
System Suitability Standards (For use with Cal/SST KIT
P/N 58 091 559 and 58 091 566)
Calibration Standards (For use with Cal/SST KIT
P/N 58 091 559 and 58 091 566)
Combined Calibration and SST Standards (For use with Cal/SST KIT
P/N58 091 559 and 58 091 566; contains 58 091 526 and 58 091 529)
Calibration Standards for Extended Range Calibration
(For use with Cal/SST KIT P/N 58 091 559 and 58 091 566)
Combined Calibration and SST Solutions for Extended Range Calibration
(For use with Cal/SST KIT P/N 58 091 559 and 58 091 566; contains
58 091 526 and 58 091 568)
Fuse, 1.25A, Sensor PCB (For use on both 110 VAC and 220 VAC Models)
Filter element, High Capacity (Pkg. 2)
58 036 031
58 036 032
58 036 033
58 036 034
58 091 566
58 091 570
58 091 565
58 091 521
58 091 522
58 091 523
58 091 524
58 091 550
58 091 552
58 091 553
58 080 270
58 080 271
58 080 272
58 080 273
58 080 274
58 080 275
58 080 276
58 080 277
58 080 278
58 080 279
58 079 513
58 091 526
58 091 529
58 091 537
58 091 568
58 091 569
58 091 519
58 091 551

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TOC Total Organic Carbon Analyzer

  • 1. 5000TOCi Sensor Fast, continuous measurement Reliable operation Reagent and chemical free USP <643>, <645>, Ch P, EP 2.2.44, and JP compliant Compact sensor design ISM diagnostics 5000TOCiwithISM Fast, Continuous and Reliable Total Organic Carbon Measurement Alliance Technical Sales Clarendon Hills, IL USA 630-321-9646 www.alliancets.com
  • 2. 2 5000TOCi Total Organic Carbon Sensor 5000TOCiSensor The 5000TOCi Total Organic Carbon Sensor with ISM from METTLER TOLEDO Thornton delivers the power of an analyzer with the convenience of a sensor. Offering the fastest response to TOC changes available, the 5000TOCi is an ideal instrument for TOC measurement in all pure water applications where rapid detec- tion of changes in TOC is critical. Strength in Operation Pure and Ultrapure water produc- tion requires monitoring of organic contamination throughout the treat- ment process. The 5000TOCi Sensor provides continuous, fast, and reli- able monitoring of TOC levels from post RO waters to point-of-use. With continuous on-line measurements, the 5000TOCi Sensor ensures TOC excursions will not be missed. Power of an Analyzer Complete process control and precise data trending with real-time continuous TOC measurement and the fastest response available. Improve measurement reliability of your continuous, real-time TOC analysis by eliminating sensitivity to pressure changes with an automated flow control system. Simplify record keeping for the release of water through simplified data collection with innovative Peak and Average TOC measurements by analyzing up to 24 hours of readings with only two measurements. Perform trouble-free maintenance with consistent results through a semi-automated Calibration and System Suitability Testing process. Conduct fast and easy service planning through convenient diagnostics and sensor status information using iMonitor to quickly determine routine maintenance requirements and sensor health. Convenience of a Sensor Maximize uptime with a robust, reliable design virtually free from moving parts. Reduce complexity of your pure water instrumentation by integrating TOC measurement into a comprehensive UPW monitoring system with multi-parameter capability. Lower costs with the ability to monitor up to four TOC sensors on a single M800 transmitter.
  • 3. 3 Pharmaceutical-grade waters must meet strict water quality re- quirements for Purified Water (PW), Water for Injection (WFI) and Highly Purified Water (HPW). TOC instruments used must also un- dergo periodic testing to verify the ability to accurately measure TOC. The 5000TOCi Sensor provides the performance needed to meet all regulatory requirements, including USP <645> for conductivity, while offering added benefits such as continuous on-line measurement in a low-maintenance, industrial package. Power generation makeup water treatment – from reverse osmosis to demineralizers, the 5000TOCi Sensor provides fast reliable moni- toring of TOC contamination in the water system. Organic contamina- tion can be detected before it enters the steam cycle where its break- down to organic acids can acceler- ate corrosion. Recycle and reclaim applications take advantage of the fast analysis time. The 5000TOCi Sensor pro- vides continuous monitoring, not lengthy batch cycles. This enables rapid response to TOC excursions caused by process variability, al- lowing for a higher percentage of recycle and reclaiming to reduce water usage and costs.
  • 4. 4 5000TOCi Fast, Continuous, Reliable Measurement 5000TOCiSensor Continuous The 5000TOCi ensures detection of even the shortest water system changes through the use of con- tinuous flow-through analysis. This design results in an ideal process control instrument which delivers a continuous, real-time measure- ment, enabling detection of all TOC changes regardless of duration. Reliable Utilizing high performance, Thornton conductivity sensors con- structed from titanium, and con- taining virtually no moving parts, the 5000TOCi offers a robust construction to maximize up-time and assure reliable measurement performance. Fast Equipped with a spiral quartz tube design, the 5000TOCi maximizes sample exposure to the 185 nano- meter UV light to provide rapid sample oxidation. This configura- tion minimizes measurement re- sponse time and delivers measure- ment performance ideal for process control.
  • 5. 5 5000TOCi Sensor Dimension Diagram 5000TOCi Sensor Installation The Thornton 5000TOCi Sensor minimizes installation and setup time. Two tubing connections are required, one for the sample inlet, and one for the oxidized sample outlet. An isolation valve is required at the sample point for shutoff (valve not supplied).
  • 6. 6 5000TOCi Product Specifications 5000TOCiSensor TOC Sensor Measurement Range 0.05 - 2000 ppbC (µgC/L) Accuracy ± 0.1 ppb C for TOC < 2.0 ppb (for water quality > 15 mΩ-cm [.067 µS/cm]) ± 0.2 ppb C for TOC > 2.0 ppb and < 10.0 ppb (for water quality > 15 mΩ-cm) ± 5% of measurement for TOC > 10.0 ppb (for water quality 0.5 to 18.2mΩ-cm) Repeatability ± 0.05 ppb C < 5 ppb, ± 1.0% > 5 ppb Resolution 0.001 ppbC (µgC/L) Analysis Time Continuous Initial Response Time < 60 seconds Update Rate 1 second Limit of Detection 0.025 ppbC Conductivity Sensor Conductivity Accuracy ±2%,0.02-20 µS/cm ±3%, 20-100 µS/cm; 0.1 Constant Sensor* Cell Constant Accuracy ± 2% Temperature Sensor Pt1000 RTD, Class A Temperature Accuracy ± 0.25°C Sample Water Requirements Temperature 0 to 100 °C ** Particle Size <100 micron Minimum Water Quality > 0.5 mΩ–cm (< 2 µS/cm), pH < 7.5 *** Flow Rate > 20 mL/min Pressure 4 to 200 psig (0.3 bar to 13.6 bar) at sample inlet connection ****
  • 7. 7 General Specifications Case Dimensions 11” [280mm] W x 7.4” [188mm] H x 5.25” [133mm] D Weight 5.0 lb. (2.3 kg) Enclosure Material Polycarbonate plastic, flame retardant, UV and chemical resistant UL # E75645, Vol.1, Set 2, CSA #LR 49336 Enclosure Rating NEMA 4X, IP65 Industrial environment Ambient Temperature/ 5 to 50°C / 5 to 80% Humidity, non-condensing Humidity Rating Power Requirements 100 - 130VAC or 200 - 240VAC, 50/60 Hz, 25W Maximum Local Indicators Four LED lights for Fault, Error, Sensor Status and UV Lamp ON Ratings/Approvals CE Compliant, UL and cUL (CSA Standards) listed, NEMA 4X, IP65 Conductivity and temperature sensors traceable to NIST, ASTM D1125 and D5391. Meets ASTM D5173 Standard Test Method for On-Line Monitoring of Carbon Com- pounds in Water by UV Light Oxidation Installation/Power/Enclosure Inlet Connection 0.125” [3mm] O.D. (6’ [2m] FDA compliant PTFE tubing supplied) Outlet Connection 0.125” [6mm] O.D. Barb connection (5’ [1.5m] flexible tubing provided) Inlet Filter 316SS, inline 60 micron Wetted Parts 316SS/Quartz/PEEK/Titanium/PTFE/Polyurethane (outlet tubing only)/EPDM Wall Mount Standard, mounting tabs provided Pipe Mount Optional, with pipe-mount bracket accessory (for nominal pipe sizes 1” [2.4 cm] to 4” [10 cm]) Maximum Sensor Distance 300ft [91m] * Readout in equivalent S/m ranges selectable at M800 ** Temperature above 70°C requires Sample Conditioning Coil (included) *** For power plant cycle chemistry samples, pH may be adjusted by measurement after cation exchange. **** Process pressure above 85 psig (5.9 bar) requires optional High Pressure Regulator p/n 58 091 552. Specifications subject to change without notice.
  • 8. Visit for more information www.mt.com/thornton Mettler-Toledo Thornton, Inc. 900 Middlesex Turnpike, Bldg. 8 Billerica, MA 01821 USA Tel +1-781-301-8618 Fax. +1-781-301-8701 Toll Free +1-800-510-PURE(US & Canada Only) Subject to technical changes ©Mettler-Toledo Thornton, Inc. Printed in USA 58 087 019 Rev D 01/2014 5000TOCi Ordering Information Description Order No. 5000TOCi Sensor, 110VAC, 50/60 Hz 5000TOCi Sensor, 220VAC, 50/60 Hz 5000TOCi Sensor, Low ppb calibration, 110VAC, 50/60 Hz 5000TOCi Sensor, Low ppb calibration, 220VAC, 50/60 Hz Accessories Kit, Calibration and System Suitability Test with UniCond® Sensor (SST and calibration standards sold separately) Validation Support Package, 5000TOCi Pump Module Pipe Mounting Kit, 1-1/2” (3.8cm) pipe Pipe Mounting Kit, 2” (5cm) pipe Pipe Mounting Kit, 3” (7.6cm) pipe Pipe Mounting Kit, 4” (10cm) pipe Filter Assembly, High capacity High pressure regulator Stainless steel outlet tube Patch Cord, 1 ft(0.3 m) Patch Cord, 5 ft(1.5 m) Patch Cord, 10 ft(3.0 m) Patch Cord, 15 ft(4.5 m) Patch Cord, 25 ft(7.6 m) Patch Cord, 50 ft(15.2 m) Patch Cord, 100 ft(30.5 m) Patch Cord, 150 ft(45.7 m) Patch Cord, 200 ft(61.0 m) Patch Cord, 300 ft(91.4 m) Consumables and Spare Parts Replacement UV Lamp (recommended every 4,500 hours of operation) System Suitability Standards (For use with Cal/SST KIT P/N 58 091 559 and 58 091 566) Calibration Standards (For use with Cal/SST KIT P/N 58 091 559 and 58 091 566) Combined Calibration and SST Standards (For use with Cal/SST KIT P/N58 091 559 and 58 091 566; contains 58 091 526 and 58 091 529) Calibration Standards for Extended Range Calibration (For use with Cal/SST KIT P/N 58 091 559 and 58 091 566) Combined Calibration and SST Solutions for Extended Range Calibration (For use with Cal/SST KIT P/N 58 091 559 and 58 091 566; contains 58 091 526 and 58 091 568) Fuse, 1.25A, Sensor PCB (For use on both 110 VAC and 220 VAC Models) Filter element, High Capacity (Pkg. 2) 58 036 031 58 036 032 58 036 033 58 036 034 58 091 566 58 091 570 58 091 565 58 091 521 58 091 522 58 091 523 58 091 524 58 091 550 58 091 552 58 091 553 58 080 270 58 080 271 58 080 272 58 080 273 58 080 274 58 080 275 58 080 276 58 080 277 58 080 278 58 080 279 58 079 513 58 091 526 58 091 529 58 091 537 58 091 568 58 091 569 58 091 519 58 091 551