Thermocouples are transducers that convert heat directly into electricity according to the Seebeck effect. They consist of two conductors welded together at one end to form a junction, with the voltage difference between the junctions proportional to the temperature difference. The main types are K, J, T, E, N, S, B, and R, which differ in temperature range and sensitivity. Thermocouples are used to measure temperature and generate power due to their ruggedness, low cost, and ability to function over a wide range of temperatures. However, they also have low accuracy and can be vulnerable to corrosion.