The document discusses thermally activated delayed fluorescence (TADF) for organic light emitting diodes. It begins with an introduction to TADF and the mechanisms allowing conversion of triplet excitons to light. Key parameters for efficient TADF emitters include a small singlet-triplet energy gap, high photoluminescence quantum yield, and high oscillator strength. Molecular design strategies aim to engineer these parameters, such as introducing strong donor-acceptor motifs or using spiro linkers to separate orbitals. The document concludes that TADF could harvest normally wasted triplet excitons, improving light emission efficiency.
Plenary lecture of the XIII SBPMat (Brazilian MRS) meeting, given on September 30th 2014 by Karl Leo, professor of optoelectronics at Dresden University of Technology (Germany) and director of the Solar and Photovoltaic Engineering Research Center at KAUST (Saudi Arabia).
NQR - DEFINITION - ELECTRIC FIELD GRADIENT - NUCLEAR QUADRUPOLE MOMENT - NUCLEAR QUADRUPOLE COUPLING CONSTANT - PRINCIPLE OF NQR - ENERGY OF INTERACTION - SELECTION RULE - FREQUENCY OF TRANSITION - APPLICATIONS
Plenary lecture of the XIII SBPMat (Brazilian MRS) meeting, given on September 30th 2014 by Karl Leo, professor of optoelectronics at Dresden University of Technology (Germany) and director of the Solar and Photovoltaic Engineering Research Center at KAUST (Saudi Arabia).
NQR - DEFINITION - ELECTRIC FIELD GRADIENT - NUCLEAR QUADRUPOLE MOMENT - NUCLEAR QUADRUPOLE COUPLING CONSTANT - PRINCIPLE OF NQR - ENERGY OF INTERACTION - SELECTION RULE - FREQUENCY OF TRANSITION - APPLICATIONS
Perovskite: introduction, classification, structure of perovskite, method to synthesis, characterization by XRD and UV- vis spectroscopy , lambert beer's law, material properties and advantage and application.
Photoelectron spectroscopy
- a single photon in/ electron out process
• X-ray Photoelectron Spectroscopy (XPS)
- using soft x-ray (200-2000 eV) radiation to
examine core-levels.
• Ultraviolet Photoelectron Spectroscopy (UPS)
- using vacuum UV (10-45 eV) radiation to
examine valence levels.
Optical band gap measurement by diffuse reflectance spectroscopy (drs)Sajjad Ullah
Introduction to Optical band gap measurement
by electronic spectroscopy and diffuse reflectance spectroscopy (DRS) with comparison of the results obtained suing different equation and measurement techniques.
The role of scattering in extinction of light as it passes through media is briefly discussed.
This presentation summarizes history and recent development of perovskite solar cells. If you have any questions or comments, you can reach me at agassifeng@gmail.com
The main objective of my PhD research at CEA Grenoble (M. Mazzanti, R. Demadrille) was related to a better understanding of the structure-property relationship in emissive lanthanide complexes with potential applications in opto-electronic devices. This was achieved by a careful design of lanthanide antennas based on either organic chromophores or transition metals as ligands, followed by a study of the structural and photophysical properties of the resulting complexes, in order to estimate and further predict the sensitization efficiencies.
In a first line of research, we have described and patented the incorporation of tetrazole groups as carboxylic acid replacements for the sensitization of lanthanide emission. We were able to show how the variation of ligand substituents influences the photophysical properties, allowing us to draw predictions and to adapt the structures for improving the emission efficiency. Some of the compounds have been successfully tested in OLED devices.
We also became interested in designing and studying new types of polymetallic architectures based on iridium complexes for the sensitization of lanthanide emission, as well as preliminary investigating the grafting of lanthanide complexes on silicon surfaces.
Perovskite: introduction, classification, structure of perovskite, method to synthesis, characterization by XRD and UV- vis spectroscopy , lambert beer's law, material properties and advantage and application.
Photoelectron spectroscopy
- a single photon in/ electron out process
• X-ray Photoelectron Spectroscopy (XPS)
- using soft x-ray (200-2000 eV) radiation to
examine core-levels.
• Ultraviolet Photoelectron Spectroscopy (UPS)
- using vacuum UV (10-45 eV) radiation to
examine valence levels.
Optical band gap measurement by diffuse reflectance spectroscopy (drs)Sajjad Ullah
Introduction to Optical band gap measurement
by electronic spectroscopy and diffuse reflectance spectroscopy (DRS) with comparison of the results obtained suing different equation and measurement techniques.
The role of scattering in extinction of light as it passes through media is briefly discussed.
This presentation summarizes history and recent development of perovskite solar cells. If you have any questions or comments, you can reach me at agassifeng@gmail.com
The main objective of my PhD research at CEA Grenoble (M. Mazzanti, R. Demadrille) was related to a better understanding of the structure-property relationship in emissive lanthanide complexes with potential applications in opto-electronic devices. This was achieved by a careful design of lanthanide antennas based on either organic chromophores or transition metals as ligands, followed by a study of the structural and photophysical properties of the resulting complexes, in order to estimate and further predict the sensitization efficiencies.
In a first line of research, we have described and patented the incorporation of tetrazole groups as carboxylic acid replacements for the sensitization of lanthanide emission. We were able to show how the variation of ligand substituents influences the photophysical properties, allowing us to draw predictions and to adapt the structures for improving the emission efficiency. Some of the compounds have been successfully tested in OLED devices.
We also became interested in designing and studying new types of polymetallic architectures based on iridium complexes for the sensitization of lanthanide emission, as well as preliminary investigating the grafting of lanthanide complexes on silicon surfaces.
Overview of unique capabilities of the ADF modeling suite to model properties of organic electronics (charge transport, phosphorescence, light absorbance). Highlighted with examples from the recent literature.
Application of Dielectric Spectroscopy to Monitor Insulating Materials ahmdfurkan
PDC measurements, it was found that polarization and depolarization currents increase with temperature increase. Also, the shape of polarization current changes as temperature increases
Drying of the transformer shows a significant reduction of the polarization/depolarization currents.
Moisture and aging have great effect on dielectric response of oil-paper insulation in frequency domain both of them will cause the increase of tan δ
Diagnostics of oil-paper insulation based on Frequency Domain Spectroscopy has great advantage over traditional techniques for its simple operation and non-destructive
Characterization of silicon tunnel field effect transistor based on charge pl...IJEECSIAES
The aim of the proposed paper is an analytical model and realization of the characteristics for tunnel field-effect transistor (TFET) based on charge plasma (CP). One of the most applications of the TFET device which operates based on CP technique is the biosensor. CP-TFET is to be used as an effective device to detect the uncharged molecules of the bio-sample solution. Charge plasma is one of some techniques that recently invited to induce charge carriers inside the devices. In this proposed paper we use a high work function in the source (ϕ=5.93 eV) to induce hole charges and we use a lower work function in drain (ϕ=3.90 eV) to induce electron charges. Many electrical characterizations in this paper are considered to study the performance of this device like a current drain (ID) versus voltage gate (Vgs), ION/IOFF ratio, threshold voltage (VT) transconductance (gm), and subthreshold swing (SS). The signification of this paper comes into view enhancement the performance of the device. Results show that high dielectric (K=12), oxide thickness (Tox=1 nm), channel length (Lch=42 nm), and higher work function for the gate (ϕ=4.5 eV) tend to best charge plasma silicon tunnel field-effect transistor characterization.
haracterization of silicon tunnel field effect transistor based on charge plasmanooriasukmaningtyas
The aim of the proposed paper is an analytical model and realization of the characteristics for tunnel field-effect transistor (TFET) based on charge plasma (CP). One of the most applications of the TFET device which operates based on CP technique is the biosensor. CP-TFET is to be used as an effective device to detect the uncharged molecules of the bio-sample solution. Charge plasma is one of some techniques that recently invited to induce charge carriers inside the devices. In this proposed paper we use a high work function in the source (ϕ=5.93 eV) to induce hole charges and we use a lower work function in drain (ϕ=3.90 eV) to induce electron charges. Many electrical characterizations in this paper are considered to study the performance of this device like a current drain (ID) versus voltage gate (Vgs), ION/IOFF ratio, threshold voltage (VT) transconductance (gm), and sub-threshold swing (SS). The signification of this paper comes into view enhancement the performance of the device. Results show that high dielectric (K=12), oxide thickness (Tox=1 nm), channel length (Lch=42 nm), and higher work function for the gate (ϕ=4.5 eV) tend to best charge plasma silicon tunnel field-effect transistor characterization.
Observation of Io’s Resurfacing via Plume Deposition Using Ground-based Adapt...Sérgio Sacani
Since volcanic activity was first discovered on Io from Voyager images in 1979, changes
on Io’s surface have been monitored from both spacecraft and ground-based telescopes.
Here, we present the highest spatial resolution images of Io ever obtained from a groundbased telescope. These images, acquired by the SHARK-VIS instrument on the Large
Binocular Telescope, show evidence of a major resurfacing event on Io’s trailing hemisphere. When compared to the most recent spacecraft images, the SHARK-VIS images
show that a plume deposit from a powerful eruption at Pillan Patera has covered part
of the long-lived Pele plume deposit. Although this type of resurfacing event may be common on Io, few have been detected due to the rarity of spacecraft visits and the previously low spatial resolution available from Earth-based telescopes. The SHARK-VIS instrument ushers in a new era of high resolution imaging of Io’s surface using adaptive
optics at visible wavelengths.
Cancer cell metabolism: special Reference to Lactate PathwayAADYARAJPANDEY1
Normal Cell Metabolism:
Cellular respiration describes the series of steps that cells use to break down sugar and other chemicals to get the energy we need to function.
Energy is stored in the bonds of glucose and when glucose is broken down, much of that energy is released.
Cell utilize energy in the form of ATP.
The first step of respiration is called glycolysis. In a series of steps, glycolysis breaks glucose into two smaller molecules - a chemical called pyruvate. A small amount of ATP is formed during this process.
Most healthy cells continue the breakdown in a second process, called the Kreb's cycle. The Kreb's cycle allows cells to “burn” the pyruvates made in glycolysis to get more ATP.
The last step in the breakdown of glucose is called oxidative phosphorylation (Ox-Phos).
It takes place in specialized cell structures called mitochondria. This process produces a large amount of ATP. Importantly, cells need oxygen to complete oxidative phosphorylation.
If a cell completes only glycolysis, only 2 molecules of ATP are made per glucose. However, if the cell completes the entire respiration process (glycolysis - Kreb's - oxidative phosphorylation), about 36 molecules of ATP are created, giving it much more energy to use.
IN CANCER CELL:
Unlike healthy cells that "burn" the entire molecule of sugar to capture a large amount of energy as ATP, cancer cells are wasteful.
Cancer cells only partially break down sugar molecules. They overuse the first step of respiration, glycolysis. They frequently do not complete the second step, oxidative phosphorylation.
This results in only 2 molecules of ATP per each glucose molecule instead of the 36 or so ATPs healthy cells gain. As a result, cancer cells need to use a lot more sugar molecules to get enough energy to survive.
Unlike healthy cells that "burn" the entire molecule of sugar to capture a large amount of energy as ATP, cancer cells are wasteful.
Cancer cells only partially break down sugar molecules. They overuse the first step of respiration, glycolysis. They frequently do not complete the second step, oxidative phosphorylation.
This results in only 2 molecules of ATP per each glucose molecule instead of the 36 or so ATPs healthy cells gain. As a result, cancer cells need to use a lot more sugar molecules to get enough energy to survive.
introduction to WARBERG PHENOMENA:
WARBURG EFFECT Usually, cancer cells are highly glycolytic (glucose addiction) and take up more glucose than do normal cells from outside.
Otto Heinrich Warburg (; 8 October 1883 – 1 August 1970) In 1931 was awarded the Nobel Prize in Physiology for his "discovery of the nature and mode of action of the respiratory enzyme.
WARNBURG EFFECT : cancer cells under aerobic (well-oxygenated) conditions to metabolize glucose to lactate (aerobic glycolysis) is known as the Warburg effect. Warburg made the observation that tumor slices consume glucose and secrete lactate at a higher rate than normal tissues.
Introduction:
RNA interference (RNAi) or Post-Transcriptional Gene Silencing (PTGS) is an important biological process for modulating eukaryotic gene expression.
It is highly conserved process of posttranscriptional gene silencing by which double stranded RNA (dsRNA) causes sequence-specific degradation of mRNA sequences.
dsRNA-induced gene silencing (RNAi) is reported in a wide range of eukaryotes ranging from worms, insects, mammals and plants.
This process mediates resistance to both endogenous parasitic and exogenous pathogenic nucleic acids, and regulates the expression of protein-coding genes.
What are small ncRNAs?
micro RNA (miRNA)
short interfering RNA (siRNA)
Properties of small non-coding RNA:
Involved in silencing mRNA transcripts.
Called “small” because they are usually only about 21-24 nucleotides long.
Synthesized by first cutting up longer precursor sequences (like the 61nt one that Lee discovered).
Silence an mRNA by base pairing with some sequence on the mRNA.
Discovery of siRNA?
The first small RNA:
In 1993 Rosalind Lee (Victor Ambros lab) was studying a non- coding gene in C. elegans, lin-4, that was involved in silencing of another gene, lin-14, at the appropriate time in the
development of the worm C. elegans.
Two small transcripts of lin-4 (22nt and 61nt) were found to be complementary to a sequence in the 3' UTR of lin-14.
Because lin-4 encoded no protein, she deduced that it must be these transcripts that are causing the silencing by RNA-RNA interactions.
Types of RNAi ( non coding RNA)
MiRNA
Length (23-25 nt)
Trans acting
Binds with target MRNA in mismatch
Translation inhibition
Si RNA
Length 21 nt.
Cis acting
Bind with target Mrna in perfect complementary sequence
Piwi-RNA
Length ; 25 to 36 nt.
Expressed in Germ Cells
Regulates trnasposomes activity
MECHANISM OF RNAI:
First the double-stranded RNA teams up with a protein complex named Dicer, which cuts the long RNA into short pieces.
Then another protein complex called RISC (RNA-induced silencing complex) discards one of the two RNA strands.
The RISC-docked, single-stranded RNA then pairs with the homologous mRNA and destroys it.
THE RISC COMPLEX:
RISC is large(>500kD) RNA multi- protein Binding complex which triggers MRNA degradation in response to MRNA
Unwinding of double stranded Si RNA by ATP independent Helicase
Active component of RISC is Ago proteins( ENDONUCLEASE) which cleave target MRNA.
DICER: endonuclease (RNase Family III)
Argonaute: Central Component of the RNA-Induced Silencing Complex (RISC)
One strand of the dsRNA produced by Dicer is retained in the RISC complex in association with Argonaute
ARGONAUTE PROTEIN :
1.PAZ(PIWI/Argonaute/ Zwille)- Recognition of target MRNA
2.PIWI (p-element induced wimpy Testis)- breaks Phosphodiester bond of mRNA.)RNAse H activity.
MiRNA:
The Double-stranded RNAs are naturally produced in eukaryotic cells during development, and they have a key role in regulating gene expression .
Multi-source connectivity as the driver of solar wind variability in the heli...Sérgio Sacani
The ambient solar wind that flls the heliosphere originates from multiple
sources in the solar corona and is highly structured. It is often described
as high-speed, relatively homogeneous, plasma streams from coronal
holes and slow-speed, highly variable, streams whose source regions are
under debate. A key goal of ESA/NASA’s Solar Orbiter mission is to identify
solar wind sources and understand what drives the complexity seen in the
heliosphere. By combining magnetic feld modelling and spectroscopic
techniques with high-resolution observations and measurements, we show
that the solar wind variability detected in situ by Solar Orbiter in March
2022 is driven by spatio-temporal changes in the magnetic connectivity to
multiple sources in the solar atmosphere. The magnetic feld footpoints
connected to the spacecraft moved from the boundaries of a coronal hole
to one active region (12961) and then across to another region (12957). This
is refected in the in situ measurements, which show the transition from fast
to highly Alfvénic then to slow solar wind that is disrupted by the arrival of
a coronal mass ejection. Our results describe solar wind variability at 0.5 au
but are applicable to near-Earth observatories.
Richard's entangled aventures in wonderlandRichard Gill
Since the loophole-free Bell experiments of 2020 and the Nobel prizes in physics of 2022, critics of Bell's work have retreated to the fortress of super-determinism. Now, super-determinism is a derogatory word - it just means "determinism". Palmer, Hance and Hossenfelder argue that quantum mechanics and determinism are not incompatible, using a sophisticated mathematical construction based on a subtle thinning of allowed states and measurements in quantum mechanics, such that what is left appears to make Bell's argument fail, without altering the empirical predictions of quantum mechanics. I think however that it is a smoke screen, and the slogan "lost in math" comes to my mind. I will discuss some other recent disproofs of Bell's theorem using the language of causality based on causal graphs. Causal thinking is also central to law and justice. I will mention surprising connections to my work on serial killer nurse cases, in particular the Dutch case of Lucia de Berk and the current UK case of Lucy Letby.
The increased availability of biomedical data, particularly in the public domain, offers the opportunity to better understand human health and to develop effective therapeutics for a wide range of unmet medical needs. However, data scientists remain stymied by the fact that data remain hard to find and to productively reuse because data and their metadata i) are wholly inaccessible, ii) are in non-standard or incompatible representations, iii) do not conform to community standards, and iv) have unclear or highly restricted terms and conditions that preclude legitimate reuse. These limitations require a rethink on data can be made machine and AI-ready - the key motivation behind the FAIR Guiding Principles. Concurrently, while recent efforts have explored the use of deep learning to fuse disparate data into predictive models for a wide range of biomedical applications, these models often fail even when the correct answer is already known, and fail to explain individual predictions in terms that data scientists can appreciate. These limitations suggest that new methods to produce practical artificial intelligence are still needed.
In this talk, I will discuss our work in (1) building an integrative knowledge infrastructure to prepare FAIR and "AI-ready" data and services along with (2) neurosymbolic AI methods to improve the quality of predictions and to generate plausible explanations. Attention is given to standards, platforms, and methods to wrangle knowledge into simple, but effective semantic and latent representations, and to make these available into standards-compliant and discoverable interfaces that can be used in model building, validation, and explanation. Our work, and those of others in the field, creates a baseline for building trustworthy and easy to deploy AI models in biomedicine.
Bio
Dr. Michel Dumontier is the Distinguished Professor of Data Science at Maastricht University, founder and executive director of the Institute of Data Science, and co-founder of the FAIR (Findable, Accessible, Interoperable and Reusable) data principles. His research explores socio-technological approaches for responsible discovery science, which includes collaborative multi-modal knowledge graphs, privacy-preserving distributed data mining, and AI methods for drug discovery and personalized medicine. His work is supported through the Dutch National Research Agenda, the Netherlands Organisation for Scientific Research, Horizon Europe, the European Open Science Cloud, the US National Institutes of Health, and a Marie-Curie Innovative Training Network. He is the editor-in-chief for the journal Data Science and is internationally recognized for his contributions in bioinformatics, biomedical informatics, and semantic technologies including ontologies and linked data.
1. Presentation
By
Biswajit Kumar Barman
Harnessing Triplet Excitons for Organic Light Emitting
Devices by Thermally Activated Delayed Fluorescence
Harnessing Triplet Excitons for Organic Light Emitting
Devices by Thermally Activated Delayed Fluorescence
1
2. ContentContent
❑ Introduction-Thermally Activated Delayed Fluorescence (TADF)
❑ Detailed Mechanism and Factors affecting TADF
❑ Molecular Design strategy and introduction to present work
2
✓ Radiative process is from singlet state
✓ Thermally activated from triplet state
✓ Life time higher than prompt one ,so delayed
✓ Triplet state to Singlet state and Singlet to ground state radiative transition
✓ Energetics and structural feature to enhance the TADF process
3. Organic Light Emitting Diode - comprises of
doped/ non-doped organic electroluminescent
material as the active layer with appropriate
transport layer and injection contacts.
Organic Light Emitting Diode (OLED)Organic Light Emitting Diode (OLED)
3
Advantages of OLEDs
➢ Flexible lighting
➢ Large panel displays
➢ Low Power consumption
Disadvantages of OLED
➢ Low stability
4. Fluorescent OLEDFluorescent OLED
Conversion of triplet excitons into
light is necessary.
Two popular ways
4
Electron from cathode Hole from anode
Exciton in Light emitting layer
Recombination
25% singlet exciton 75% triplet exciton
Spin –Statistics rule
Phosphorescence channel - IQE =100%
TADF channel - IQE =100%
Maximum theoretical IQE=25%
5. Effect of heavy metal atom
Phosphorescent emitters have high cost, toxic and triplet-polaron annihilation,
triplet-triplet annihilation effect that decreases device efficiency.
Problems
Phosphorescence channelPhosphorescence channel
Iridium, Platinum
⇒High atomic number
⇒Large spin–orbit coupling constant
S1
T1
S0
ISC
Phosphorescence
λ = spin orbit coupling constant
Z = atomic number
l = orbital angular momentum
n = principle quantum number
In phosphorescent emitter,
Triplet excitons go to ground state
radiatively.Lifetime of this process is
around ms to s .
5
6. S1
S0
T1
Reverse Inter System Crossing (RISC)
Fluorescence Delayed fluorescence(TADF)
Electrical
excitation
Electrical
excitation
25%
75%
TADF channelTADF channel
In TADF, reverse intersystem crossing (RISC) from the lowest triplet state (T1) to the
lowest excited singlet state (S1), and followed by radiative decay from S1 to the
ground state (S0).
6
8. Mechanism of TADF processMechanism of TADF process
Electroluminescence process
Electrical
excitation
Electrical
excitation
S1
S0
T1
8Ref: Chem. Mater. 2017, 29, 1946−1963
Thermal energy = 25.9 meV at 298K.
9. Key Parameters of TADF Emitters
Small Singlet−Triplet Energy Gap
High PL Quantum Yield
High Oscillator strength from S1 to S0 electronic state
9
If energy gap is low,then rate of reverse inter system crossing is high
If the oscillator strength is high,then radiative rate of transition is quite high
PLQY =
Quantum efficiency increasing with increase PLQY .
10. Design principleDesign principle
Strong donor/acceptor
Phenyl linker
HOMO dispersion
Dual emitting core
Frozen donor/acceptor
Rigid acceptor
High BDE
10Ref: Chem. Mater. 2017, 29, 1946−1963
Distortion between Donors and Acceptors
Small energy gapSmall energy gap
High PLQYHigh PLQY
Narrow emissionNarrow emission
Stable structureStable structure
11. Small Singlet−Triplet Energy Gap(ΔEST)
1
Minimal overlap between the HOMO and LUMO
Minimum overlap
Low exchange energy
That reduce energy gap between S1 and T1
E= orbital energy
K=electron repulsion energy
J =electron exchange
energy
S1 state have energy
ES=E+K+J
T1 state have energy
ET=E+K –J
ΔEST=ES – ET
ΔEST= 2J
Ref: Chem. Soc. Rev., 2017,46,915-1016 & Adv. Mater. 2014, 26, 7931–7958
12. 1. Separation of HOMO - LUMO , (small ΔEST)
(a) Introduction of steric hindrance
(b) Spiro linker, physical separation of donor and acceptor units
(c) X shaped molecular structure
HOMO-LUMO SeparationHOMO-LUMO Separation
Ref : Chem. Soc. Rev., 2017,46,915-1016
Methods: Donor- Acceptor backbone
1
13. oBFCzTrz mBFCzTrz pBFCzTrz
Compound Energy of S1(eV) Energy of T1(eV) ΔEST(eV) Life time(τ),μs
oBFCzTrz 2.78 2.73 0.05 5.4
mBFCzTrz 2.79 2.68 0.11 29.6
pBFCzTrz 2.89 2.64 0.25 31.2
Short LifetimeShort Lifetime
Ref: Appl. Mater. Interfaces, 2016, 8, 23190−23196
The increased CT character due to geometrical distortion
Short conjugation length of oBFCzTrz, that increase T1 value
13
15. DDCzIPNDCZIPN
PLQY: Dual emitting corePLQY: Dual emitting core
Absorption coefficient = 1.1 X 105
M-1
cm-1
PLQY = 67%
EQE = 16.4%
Absorption coefficient = 3.7 X 105
M-1
cm-1
PLQY = 91%
EQE = 18.9%
The UV/Vis absorption of DDCzIPN was stronger than that of DCzIPN
Ref: Angew. Chem. Int. Ed. 2015, 54, 5201–5204 15
16. Narrow EmissionNarrow Emission
To freeze the donor−acceptor
based core structure by fused
structure or sterically hindered
structure. To adopt a rigid
acceptor structure to minimize
vibrational motion of the TADF
emitters
DABNA 1
FWHM=33nm
DABNA 2
FWHM=34nm
Large steric hindrance
Ref: Adv. Mater. 2016, 28, 2777–2781
Rigid π-conjugated
framework
CNBPCz
FWHM=76nm
CzBPCN
FWHM=48nm
16
17. Role of steric hindranceRole of steric hindrance
1. Dihedral angle = 470
2. ΔEST = 0.10 eV
3. EQE = 14.4%
1. Dihedral angle = 600
2. ΔEST = 0.03 eV
3. EQE = 20.1%
Ref: J. Mater. Chem. C, 2017, 5, 4797--4803 17
DCz-TRCz-TR
18. Role of Donor partRole of Donor part
Ref: Org. Electron, 50 (2017) ,70-76 18
1 (TADF inactive) 2 (TADF active)
1. S1 = 3.809 eV
2. T1 = 3.108 eV
3. ΔEST = 0.701 eV
1. S1 = 3.526 eV
2. T1 = 3.100 eV
3. ΔEST = 0.426 eV
19. HIL
HTL
EBL
Anode
EML
HBL
ETL
EIL
Cathode
Device structureDevice structure
ITO = 4.6 eV
Al = 4.28 eV
PEDOT:PSS
5.2 ,2.4
Ref: J. Mater. Chem. C, 2013, 1, 1739–1744 19
PPV= hole transporting materials
CN-PPV= electron transporting materials
Where,
HIL = hole injection layer
HTL = hole transport layer
EBL = electron blocking layer
EML= emissive layer
HBL = hole blocking layer
ETL = electron transport layer
EIL = electron injection layer
20. Electroluminescence propertyElectroluminescence property
Device HOMO(eV) LUMO(eV) Turn on voltage (V) EQE (%)
1 5.2 2.6 8.1 5.6
2 5.0 2.6 6.7 8.3
Host= mCP (5.9,2.4)
1
2
Device 1 Device 2
Turn on voltage –
1. Mobility of charges/carrier
2. Hole injection barrier
Fig: Current density vs. Voltage plot
Ref: Dyes and Pigments, 2017,141, 83-92 20
22. Photophysical characteristicsPhotophysical characteristics
Fig: Photoluminescence quantum yield vs.
Emitter concentration plot
Fig: (a) Molecular structures of the emitters.
Ref: Chem. Commun., 2015, 51, 9443—9446
➢ Bridging sp3
carbon
➢ Concentration quenching in emitter 4, due to planer structure
22
23. Ref: Chem. Commun., 2015, 51, 9443—9446
Photophysical characteristicsPhotophysical characteristics
Fig: Normalized intensity vs. Wavelength plot
Conclusion = Delayed transition from S1 to S0 state like prompt flurescence one
23