X-rays are invisible electromagnetic radiation that can pass through and image opaque objects. They were accidentally discovered in 1895 by Wilhelm Röntgen in Germany while experimenting with cathode ray tubes. Röntgen found that a new type of ray could pass through paper and wood but was blocked by denser materials like lead. He called them X-rays due to their unknown nature. X-rays revolutionized fields like medicine by allowing internal body structures to be imaged without surgery. They enabled diagnoses and medical advances but also posed health risks from radiation exposure.