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International Journal of Research in Engineering and Science (IJRES)
ISSN (Online): 2320-9364, ISSN (Print): 2320-9356
www.ijres.org Volume 4 Issue 2 ǁ February. 2016 ǁ PP.36-39
www.ijres.org 36 | Page
Study and evaluation for different types of Sudanese crude oil
properties
Wamda faisal Elmobarak 1
, Alaedin Ibrahim mohamed2
, Amin Babiker. A.Nabi
Mustafa3
P.G. Student, Department of Chemical Engineering, Faculty of Engineering, AL Neelain University Kh, sudan1
Associated Professor, Department of Chemical Engineering, Faculty of Engineering, AL Neelain University,
Kh, Sudan2
Associated Professor, Department of Telecommunication Engineering, Faculty of Engineering, AL Neelain
University, Kh, Sudan3
Abstract: Sudanese crude oil is regarded as one of the sweet types of crude in the world, Sulphur containing
compounds are un desirable in petroleum because they de activate the catalyst during the refining processes and
are the main source of acid rains and environmental pollution.(Mark Cullen 2001),Since it contains considerable
amount of salts and acids, it negatively impact the production facilities and transportation lines with corrosive
materials. However it suffers other problems in flow properties represented by the high viscosity and high
percentage of wax. Samples were collected after the initial and final treatment at CPF, and tested for
physical and chemical properties.wax content is in the range 23-31 weight % while asphalting content is about
0.1 weight% . Resin content is 13-7 weight % and deposits are 0.01 weight%. The carbon number distribution in
the crude is in the range 7-35 carbon atoms. The pour point vary between 39°C-42°C and the boiling point is in
the range 70 °C - 533 °C.
Keywords: Sudanese crude oil, evaluation, properties.
I. Introduction
Sudanese crude oil is waxy in character, has an average API degree of 32 and possesses no sulfur .Crude oil
and high-boiling crude oil fractions are composed of many members of a relatively few homologous series of
hydrocarbons Petroleum is essentially a mixture of hydrocarbons, but containing small quantities of oxygen,
sulfur, nitrogen, vanadium, nickel, and chromium .The hydrocarbons present in crude petroleum are classified
into three general types: paraffin’s, naphthenic, and aromatics. In addition, there is a fourth type, olefins, that is
formed during processing by the cracking or dehydrogenation of paraffin’s and naphthenic. There are no olefins
in crude oil .Crude oil appear as liquids of varying viscosities. Their color can range from green to dark brown.
and there are many properties that can tested for crude oil: density, API gravity specific gravity, wax content ,
pour point, TAN ,water content, sulfur content, asphalting content, nitrogen content, salt content, viscosity ,
vapors , pressure and flash point.
II. Material and methodology
The samples of crude oil tested for properties study was supplied by Greater Nile Petroleum company
(GNPOC) Petroleum Operating Company and Petroleum Training And Research Centre The main sources was
Nile blend, Full a light, Sargas and Star oil fields. The samples was tested for density , kinematic viscosity ,
specific gravity, Total acid number (TAN) , pour point, asphalting content ,sulphur content and wax content.
Density and specific gravity was measured by the density meter analyser (DMA) according to(ASTMD5002),
API was calculated from specific gravity equation. Total acid number (TAN) was tested by TAN titration
equipment (ASTMD664)Pour point was measured according to ASTM D97-04. Kinematic viscosity was
measured with 400 and 450 universal viscometers, Asphalting content was tested according to IP143 method
and lastly Wax content was measured according to UOP46 method.
III. Results and discussions
The TBP (True Boiling Point) distillation gives an almost exact picture of a crude petroleum by measuring
the boiling points of the components making up the crude.
Table (1) true boiling points(TBP) of the components
Study and evaluation for different types of Sudanese crude oil properties
www.ijres.org 37 | Page
Boiling point range C°component
C3-C4Gas
C5 -70
C5-80
C5-100
Light debutanized
gasoline
70 -140
80 -180
100 -180
Heavy gasoline
160 -260
180 -260
kerosene
160 -360
260 -325
260 -360
260 -370
Gas oil
T > 325
T > 360
T > 370
residue
Table (2) Density of crude oil
Density @15CO
Sample type
913.6Dar blend
881.3Fulla light
927.8Sargas
878.4Nile blend
836.3B.of fulla+staroil
Table (3) Specific Gravity of tested oil
S.GSample type
914.5Dar blend
882.1Fulla light
928.6sargas
872.9Nile blend
836.9B.of fulla+staroil
Table (4) Wax content
Wax content %Sample type
19.28Dar blend
21.68Fulla light
20.99Sargas
29,95Nile blend
36,88B.of fulla+staroil
Table (5) Pour point for samples
Pour point C°Sample type
39Dar blend
12Fulla light
12Sargas
30Nile blend
42B.of fulla+staroil
Table (6) Total acid number (TAN) for samples
TAN mg KoH/gSample type
4.47Dar blend
0.35Fulla light
1.64Sargas
0.66Nile blend
0.12B.of fulla+staroil
Table (7) water content of crude oil
Study and evaluation for different types of Sudanese crude oil properties
www.ijres.org 38 | Page
Water content wt%Sample type
0.4Dar blend
3.0Fulla light
0.05Sargas
0.20Nile blend
2.8B.of fulla+staroil
Table (8) sulfur content of crude oil
sulfur content wt%Sample type
0.1272Dar blend
0.0813Fulla light
0.1227Sargas
0.0745Nile blend
0.0885B.of fulla+staroil
Table (9) The Kinematic viscosity
k. Viscosity @70CO
k. Viscosity @60CO
k. Viscosity @50 CO
Sample type
139,8233.4440.5Dar blend
16.0621,3432,54Fulla light
170.6278.7499.4Sargas
17.8825.0639.03Nile blend
6.6967.76112.97B.of fulla+staroil
Table (10) Asphalting content of the tested oil
Asphalting content wt%Sample type
0.12Dar blend
0.1Fulla light
0.08Sargas
0.14Nile blend
0.04B.of fulla+staroil
Table (11) The Percentages and the products yield of crude oil
Crude oil Naphtha Kerosene Atmospheric gasoil Vacuum gasoil Residue
Vol % Vol % Vol % Vol % Vol %
Nile blend 2.99 6.89 2.16 8.24 65.07
Sargas 2.46 4.55 1.45 8.84 77.54
Fulla light 6.34 6.33 3.11 4.39 69.65
Blend of fulla+staroil 12.43 8.48 11.10 8.29 52.63
Figure (1) : percentages of products yield for crude oil
IV. CONCLUSION
45.383
35.538
32.314
17.438
0
10
20
30
40
50
60
70
80
90
100
B.of Fulla light+star oil
Fulla light
Nile blend
sargas
light products boiling point range c°
lightproductsvolumepercentages
Study and evaluation for different types of Sudanese crude oil properties
www.ijres.org 39 | Page
From the tests and results in tables (2,3,4,5,6,7,8,9,10) we found that Dar blend oil is a heavy crude based
on API, low asphalting content (only 0.12%) and high TAN value (4.47).
And from the tests the optimum crude oil is star oil because it have law viscosity, law total acid number
(TAN)law sulfur content ,law asphalting content ,law wax content and high API. Because of high API the crude
oil produced light products more than heavy products. This crude oil not need a lot of treatments specially for
wax ,water and sulfur content. star oil and full a blend give an ideal crude with low total acid number and pour
point the refining
It is quite evident that star oil and nile blend are scare resources since any increase in these resources will
improve process and petroleum light products quality.
REFERENCES
[1] Prasd R. Petroleum Refining Technology, Volume 4. Khanna Publisher; Canpur- India (1997).
[2] Gurwitch L and Moor H.The Scientific Principles of PetroleTechnology,Volume 4. Van Nostrand, New
York, USA. (1932).
[3] Abbas M.S Oil,Water, Mineral, and the Crisis in Darfur, Journal of Institute of African Research and
Studies SUDAN (2005) (http://www.petrdar/content.pht. (2011).
[4] James H. Gary Glann E. Hand werk Petroleum Refinery and Technology and Economics. Volume
4,Marcel Dekker,Taylor,Francis(2005).
[5] WillamL.Leffer Petroleum Refining .volume4 .Renn Wellcorporation. USA(1932)
[6] Jean-Pierr Waruquier, Crude oil petroleum products process flow sheets. Volume 4, Institute Francis
of Petroleum, Paris(1995).
[7] ASTM Standards D5002, Standard Test Method for Specification for Density and Relative Density of
Crude Oils by Digital Density Analyzer, ASTM International, West Conshohocken, PA DOI:
10.1520/D5002 (2013). www.astm.org.
[8] Standard Test Method for Specification for color petroleum products (ASTM Color Scale), ASTM
International ASTM Standards D1500,, West Conshohocken, PA, DOI: 10.1520/D1500-12 (2012),
www.astm.org.

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Study and evaluation for different types of Sudanese crude oil properties

  • 1. International Journal of Research in Engineering and Science (IJRES) ISSN (Online): 2320-9364, ISSN (Print): 2320-9356 www.ijres.org Volume 4 Issue 2 ǁ February. 2016 ǁ PP.36-39 www.ijres.org 36 | Page Study and evaluation for different types of Sudanese crude oil properties Wamda faisal Elmobarak 1 , Alaedin Ibrahim mohamed2 , Amin Babiker. A.Nabi Mustafa3 P.G. Student, Department of Chemical Engineering, Faculty of Engineering, AL Neelain University Kh, sudan1 Associated Professor, Department of Chemical Engineering, Faculty of Engineering, AL Neelain University, Kh, Sudan2 Associated Professor, Department of Telecommunication Engineering, Faculty of Engineering, AL Neelain University, Kh, Sudan3 Abstract: Sudanese crude oil is regarded as one of the sweet types of crude in the world, Sulphur containing compounds are un desirable in petroleum because they de activate the catalyst during the refining processes and are the main source of acid rains and environmental pollution.(Mark Cullen 2001),Since it contains considerable amount of salts and acids, it negatively impact the production facilities and transportation lines with corrosive materials. However it suffers other problems in flow properties represented by the high viscosity and high percentage of wax. Samples were collected after the initial and final treatment at CPF, and tested for physical and chemical properties.wax content is in the range 23-31 weight % while asphalting content is about 0.1 weight% . Resin content is 13-7 weight % and deposits are 0.01 weight%. The carbon number distribution in the crude is in the range 7-35 carbon atoms. The pour point vary between 39°C-42°C and the boiling point is in the range 70 °C - 533 °C. Keywords: Sudanese crude oil, evaluation, properties. I. Introduction Sudanese crude oil is waxy in character, has an average API degree of 32 and possesses no sulfur .Crude oil and high-boiling crude oil fractions are composed of many members of a relatively few homologous series of hydrocarbons Petroleum is essentially a mixture of hydrocarbons, but containing small quantities of oxygen, sulfur, nitrogen, vanadium, nickel, and chromium .The hydrocarbons present in crude petroleum are classified into three general types: paraffin’s, naphthenic, and aromatics. In addition, there is a fourth type, olefins, that is formed during processing by the cracking or dehydrogenation of paraffin’s and naphthenic. There are no olefins in crude oil .Crude oil appear as liquids of varying viscosities. Their color can range from green to dark brown. and there are many properties that can tested for crude oil: density, API gravity specific gravity, wax content , pour point, TAN ,water content, sulfur content, asphalting content, nitrogen content, salt content, viscosity , vapors , pressure and flash point. II. Material and methodology The samples of crude oil tested for properties study was supplied by Greater Nile Petroleum company (GNPOC) Petroleum Operating Company and Petroleum Training And Research Centre The main sources was Nile blend, Full a light, Sargas and Star oil fields. The samples was tested for density , kinematic viscosity , specific gravity, Total acid number (TAN) , pour point, asphalting content ,sulphur content and wax content. Density and specific gravity was measured by the density meter analyser (DMA) according to(ASTMD5002), API was calculated from specific gravity equation. Total acid number (TAN) was tested by TAN titration equipment (ASTMD664)Pour point was measured according to ASTM D97-04. Kinematic viscosity was measured with 400 and 450 universal viscometers, Asphalting content was tested according to IP143 method and lastly Wax content was measured according to UOP46 method. III. Results and discussions The TBP (True Boiling Point) distillation gives an almost exact picture of a crude petroleum by measuring the boiling points of the components making up the crude. Table (1) true boiling points(TBP) of the components
  • 2. Study and evaluation for different types of Sudanese crude oil properties www.ijres.org 37 | Page Boiling point range C°component C3-C4Gas C5 -70 C5-80 C5-100 Light debutanized gasoline 70 -140 80 -180 100 -180 Heavy gasoline 160 -260 180 -260 kerosene 160 -360 260 -325 260 -360 260 -370 Gas oil T > 325 T > 360 T > 370 residue Table (2) Density of crude oil Density @15CO Sample type 913.6Dar blend 881.3Fulla light 927.8Sargas 878.4Nile blend 836.3B.of fulla+staroil Table (3) Specific Gravity of tested oil S.GSample type 914.5Dar blend 882.1Fulla light 928.6sargas 872.9Nile blend 836.9B.of fulla+staroil Table (4) Wax content Wax content %Sample type 19.28Dar blend 21.68Fulla light 20.99Sargas 29,95Nile blend 36,88B.of fulla+staroil Table (5) Pour point for samples Pour point C°Sample type 39Dar blend 12Fulla light 12Sargas 30Nile blend 42B.of fulla+staroil Table (6) Total acid number (TAN) for samples TAN mg KoH/gSample type 4.47Dar blend 0.35Fulla light 1.64Sargas 0.66Nile blend 0.12B.of fulla+staroil Table (7) water content of crude oil
  • 3. Study and evaluation for different types of Sudanese crude oil properties www.ijres.org 38 | Page Water content wt%Sample type 0.4Dar blend 3.0Fulla light 0.05Sargas 0.20Nile blend 2.8B.of fulla+staroil Table (8) sulfur content of crude oil sulfur content wt%Sample type 0.1272Dar blend 0.0813Fulla light 0.1227Sargas 0.0745Nile blend 0.0885B.of fulla+staroil Table (9) The Kinematic viscosity k. Viscosity @70CO k. Viscosity @60CO k. Viscosity @50 CO Sample type 139,8233.4440.5Dar blend 16.0621,3432,54Fulla light 170.6278.7499.4Sargas 17.8825.0639.03Nile blend 6.6967.76112.97B.of fulla+staroil Table (10) Asphalting content of the tested oil Asphalting content wt%Sample type 0.12Dar blend 0.1Fulla light 0.08Sargas 0.14Nile blend 0.04B.of fulla+staroil Table (11) The Percentages and the products yield of crude oil Crude oil Naphtha Kerosene Atmospheric gasoil Vacuum gasoil Residue Vol % Vol % Vol % Vol % Vol % Nile blend 2.99 6.89 2.16 8.24 65.07 Sargas 2.46 4.55 1.45 8.84 77.54 Fulla light 6.34 6.33 3.11 4.39 69.65 Blend of fulla+staroil 12.43 8.48 11.10 8.29 52.63 Figure (1) : percentages of products yield for crude oil IV. CONCLUSION 45.383 35.538 32.314 17.438 0 10 20 30 40 50 60 70 80 90 100 B.of Fulla light+star oil Fulla light Nile blend sargas light products boiling point range c° lightproductsvolumepercentages
  • 4. Study and evaluation for different types of Sudanese crude oil properties www.ijres.org 39 | Page From the tests and results in tables (2,3,4,5,6,7,8,9,10) we found that Dar blend oil is a heavy crude based on API, low asphalting content (only 0.12%) and high TAN value (4.47). And from the tests the optimum crude oil is star oil because it have law viscosity, law total acid number (TAN)law sulfur content ,law asphalting content ,law wax content and high API. Because of high API the crude oil produced light products more than heavy products. This crude oil not need a lot of treatments specially for wax ,water and sulfur content. star oil and full a blend give an ideal crude with low total acid number and pour point the refining It is quite evident that star oil and nile blend are scare resources since any increase in these resources will improve process and petroleum light products quality. REFERENCES [1] Prasd R. Petroleum Refining Technology, Volume 4. Khanna Publisher; Canpur- India (1997). [2] Gurwitch L and Moor H.The Scientific Principles of PetroleTechnology,Volume 4. Van Nostrand, New York, USA. (1932). [3] Abbas M.S Oil,Water, Mineral, and the Crisis in Darfur, Journal of Institute of African Research and Studies SUDAN (2005) (http://www.petrdar/content.pht. (2011). [4] James H. Gary Glann E. Hand werk Petroleum Refinery and Technology and Economics. Volume 4,Marcel Dekker,Taylor,Francis(2005). [5] WillamL.Leffer Petroleum Refining .volume4 .Renn Wellcorporation. USA(1932) [6] Jean-Pierr Waruquier, Crude oil petroleum products process flow sheets. Volume 4, Institute Francis of Petroleum, Paris(1995). [7] ASTM Standards D5002, Standard Test Method for Specification for Density and Relative Density of Crude Oils by Digital Density Analyzer, ASTM International, West Conshohocken, PA DOI: 10.1520/D5002 (2013). www.astm.org. [8] Standard Test Method for Specification for color petroleum products (ASTM Color Scale), ASTM International ASTM Standards D1500,, West Conshohocken, PA, DOI: 10.1520/D1500-12 (2012), www.astm.org.