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A presentation by
ABU DARDA
13pstm 19
gd4688
Presentation
on
Submitted to
Department of applied chemistry
Aligarh muslim university
Direct Piezoelectric Effect
Piezoelectric Material will generate electric
potential when subjected to some kind of
mechanical stress.
The direct Effect :
Generator
 Compression
Effect: Decrease in volume
and it has a voltage with the
same polarity as the
material
 Tension
Effect: Increase in volume
and it has a voltage with
opposite polarity as the
material
F
F
Inverse Piezoelectric
Effect
If the piezoelectric material is exposed to an
electric field (voltage) it consequently
lengthens or shortens proportional to the
voltage.
The Inverse Piezoelectric
Effect
 If the applied voltage has
the same polarity then the
material expands.
 If the applied voltage has
the opposite polarity then
the material contracts.
The History of Piezo
 The name Piezo
originates from the
Greek word piezein,
which means to
squeeze or press.
 The piezoelectric effect
was first proven in 1880
by the brothers Pierre
and Jacques Curie.
 
 
 
Developing theories…
 Pierre and Jacques Curie predicted and
demonstrated the piezoelectric effect using tinfoil,
glue, wire, magnets, and a jeweler’s saw.
 They showed that crystals of tourmaline, quartz,
topaz, cane sugar, and Rochelle salt generate
electrical polarization from mechanical stress.
 The converse effect was mathematically derived by
Gabriel Lippman in 1881 using fundamental
thermodynamic principles and was later
experimentally confirmed by the Curies.
How are Piezoelectric
ceramics made?
 Fine powders of the component metal oxides are mixed
in specific proportions, then heated to form a uniform
powder.
 The powder is mixed with an organic binder and is
formed into structural elements.
 The elements are fired according to a specific time and
temperature program, during which the powder particles
sinter and the material attains a dense crystalline
structure.
 The elements are cooled, then shaped or trimmed to
specifications. Electrodes are applied to a conducting
material, which is connected to the elements.
Crystal Structure and
Dipole Moments
 A traditional piezoelectric ceramic is a mass
of perovskite crystals. Each crystal consists
of a small tetravalent metal ion, usually
titanium or zirconium, in a lattice of larger
divalent metal ions, usually lead or barium,
and O2- ions
 At temperatures below the Curie point,
however, each crystal has tetragonal or
rhombohedral symmetry and a dipole
moment. Above the Curie point each
perovskite crystal in the fired ceramic
element exhibits a cubic symmetry with no
dipole moment.
Polarizing Piezoelectric
Material
 Adjoining dipoles form regions of local alignment called domains. The
alignment gives a net dipole moment to the domain, and thus a net
polarization. The direction of polarization among neighboring domains is
random, however, so the ceramic element has no overall polarization.
 The domains in a ceramic element are aligned by exposing the element
to a strong, direct current electric field, usually at a temperature slightly
below the Curie point
 When the electric field is removed most of the dipoles are locked into a
configuration of near alignment
Types of Piezoelectric
Materials Naturally occurring crystals:
Berlinite (AlPO4), cane sugar, Quartz, Rochelle salt, Topaz, Tourmaline
Group Minerals, and dry bone (apatite crystals)
 Man-made crystals:
Gallium orthophosphate (GaPO4), Langasite (La3Ga5SiO14)
 Man-made ceramics:
Barium titanate (BaTiO3), Lead titanate (PbTiO3), Lead zirconate
titanate (Pb[ZrxTi1-x]O3 0<x<1) - More commonly known as PZT,
Potassium niobate (KNbO3), Lithium niobate (LiNbO3), Lithium
tantalate (LiTaO3), Sodium tungstate (NaxWO3), Ba2NaNb5O5,
Pb2KNb5O15
 Polymers:
Polyvinylidene fluoride (PVDF)
Sonic and Ultrasonic
Applications
 Sonar with Ultrasonic time-
domain reflectometers
 Materials testing to detect
flaws inside cast metals
and stone objects as well
as measure elasticity or
viscosity in gases and
liquids
 Compact sensitive
microphones and guitar
pickups.
 Loudspeakers
Pressure Applications
 Transient pressure measurement to
study explosives, internal combustion
engines (knock sensors), and any other
vibrations, accelerations, or impacts.
 Piezoelectric microbalances are used as
very sensitive chemical and biological
sensors.
 Transducers are used in electronic drum
pads to detect the impact of the
drummer's sticks.
 Energy Harvesting from impact on the
ground
 Atomic force and scanning tunneling
microscopes.
 Electric igniters and cigarette lighters
Consumer Electronics
Applications
 Quartz crystals resonators as
frequency stabilizers for
oscillators in all computers.
 Phonograph pick-ups
 Accelerometers: In a
piezoelectric accelerometer a
mass is attached to a spring that
is attached to a piezoelectric
crystal. When subjected to
vibration the mass compresses
and stretches the piezo electric
crystal. (iPhone)
Motor Applications
 Piezoelectric elements can be used
in laser mirror alignment, where
their ability to move a large mass
(the mirror mount) over microscopic
distances is exploited. By
electronically vibrating the mirror it
gives the light reflected off it a
Doppler shift to fine tune the laser's
frequency.
 The piezo motor is viewed as a high-
precision replacement for the
stepper motor.
 Traveling-wave motors used for
auto-focus in cameras.
Procedure
1) Attach a mirror to the piezoelectric buzzer. Position that laser so that
the beam can reflect off of the mirror and hit the wall across the room.
2) Connect the function generator to the Piezoelectric device. Find the
resonant frequency of the device by slowly increasing the frequency at
10Vp-p.The laser will vibrate the most at the resonant frequency.
3) Measure the diameter of the laser without any signal. Then measure
the diameter of the laser with the AC signal applied.
4) Calculate the displacement of the laser and divide it by two to get the
amplitude of the magnified change in volume for the piezoelectric
material.
5) Measure the distance from the piezo to the wall and to the laser. Also
measure the height of the laser and reflected beam in relation to the
piezo.
6) Calculate the change in volume for the piezoelectric material.
Error Analysis
The laser’s diameter expands over a distance.
The quality of the mirror scatters the laser.
The sinusoidal vibration of the material amplifies the laser’s displacement.
Works Cited
 Images:
1. http://en.wikipedia.org/wiki/Image:SchemaPiezo.gif
2.
http://images.google.com/imgres?imgurl=http://www.hvwtech.com/products/266/35170_PV.jpg&imgrefurl=http://www.hvwtech.com/products
=
3.
http://images.google.com/imgres?imgurl=http://surveying.wb.psu.edu/psu-surv/SURIs/Images/NOAA_sonar.gif&imgrefurl=http://surveying.wb.
=
4.
http://images.google.com/imgres?imgurl=http://www.pc-control.co.uk/images/curie1.jpg&imgrefurl=http://www.pc-control.co.uk/piezoelectric_
=
5.http://www1.eere.energy.gov/vehiclesandfuels/pdfs/deer_2005/session1/2005_deer_troy.pdf
6. http://ch.mt.com/mt_ext_files/FilterHierarchy/ProductFamily/1/MX-UMX_FilterHierarchy-ProductFamily_1101466637484_files/micro_big.jpg
7.
http://images.google.com/imgres?imgurl=http://euroross.blogspot.com/Moscow%2520Traffic%25202.jpg&imgrefurl=http://euroross.blogspot.c
=
8.
http://images.google.com/imgres?imgurl=http://farm1.static.flickr.com/116/252342964_2fffa201a8.jpg&imgrefurl=http://www.flickr.com/photo
=
 Information:
1. http://www.piezo.com/tech1terms.html
2. http://www.piezo.com/tech4history.html
3. http://www.piezoelectrics.net/piezoelectrichistory.htm
4. http://www.americanpiezo.com/piezo_theory/index.html
5. http://www.cedrat-groupe.com/
6. http://www.sensotec.com/accelerometer_faq.asp?category=All
7. http://www.apple.com/iphone/features/index.html#accelerometer
8. http://www.patent-invent.com/electricity/inventions/piezoelectricity.html
9. http://en.wikipedia.org/wiki/Piezoelectricity

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Piezo material

  • 1. A presentation by ABU DARDA 13pstm 19 gd4688 Presentation on Submitted to Department of applied chemistry Aligarh muslim university
  • 2.
  • 3. Direct Piezoelectric Effect Piezoelectric Material will generate electric potential when subjected to some kind of mechanical stress.
  • 4. The direct Effect : Generator  Compression Effect: Decrease in volume and it has a voltage with the same polarity as the material  Tension Effect: Increase in volume and it has a voltage with opposite polarity as the material F F
  • 5. Inverse Piezoelectric Effect If the piezoelectric material is exposed to an electric field (voltage) it consequently lengthens or shortens proportional to the voltage.
  • 6. The Inverse Piezoelectric Effect  If the applied voltage has the same polarity then the material expands.  If the applied voltage has the opposite polarity then the material contracts.
  • 7. The History of Piezo  The name Piezo originates from the Greek word piezein, which means to squeeze or press.  The piezoelectric effect was first proven in 1880 by the brothers Pierre and Jacques Curie.      
  • 8. Developing theories…  Pierre and Jacques Curie predicted and demonstrated the piezoelectric effect using tinfoil, glue, wire, magnets, and a jeweler’s saw.  They showed that crystals of tourmaline, quartz, topaz, cane sugar, and Rochelle salt generate electrical polarization from mechanical stress.  The converse effect was mathematically derived by Gabriel Lippman in 1881 using fundamental thermodynamic principles and was later experimentally confirmed by the Curies.
  • 9. How are Piezoelectric ceramics made?  Fine powders of the component metal oxides are mixed in specific proportions, then heated to form a uniform powder.  The powder is mixed with an organic binder and is formed into structural elements.  The elements are fired according to a specific time and temperature program, during which the powder particles sinter and the material attains a dense crystalline structure.  The elements are cooled, then shaped or trimmed to specifications. Electrodes are applied to a conducting material, which is connected to the elements.
  • 10. Crystal Structure and Dipole Moments  A traditional piezoelectric ceramic is a mass of perovskite crystals. Each crystal consists of a small tetravalent metal ion, usually titanium or zirconium, in a lattice of larger divalent metal ions, usually lead or barium, and O2- ions  At temperatures below the Curie point, however, each crystal has tetragonal or rhombohedral symmetry and a dipole moment. Above the Curie point each perovskite crystal in the fired ceramic element exhibits a cubic symmetry with no dipole moment.
  • 11.
  • 12. Polarizing Piezoelectric Material  Adjoining dipoles form regions of local alignment called domains. The alignment gives a net dipole moment to the domain, and thus a net polarization. The direction of polarization among neighboring domains is random, however, so the ceramic element has no overall polarization.  The domains in a ceramic element are aligned by exposing the element to a strong, direct current electric field, usually at a temperature slightly below the Curie point  When the electric field is removed most of the dipoles are locked into a configuration of near alignment
  • 13. Types of Piezoelectric Materials Naturally occurring crystals: Berlinite (AlPO4), cane sugar, Quartz, Rochelle salt, Topaz, Tourmaline Group Minerals, and dry bone (apatite crystals)  Man-made crystals: Gallium orthophosphate (GaPO4), Langasite (La3Ga5SiO14)  Man-made ceramics: Barium titanate (BaTiO3), Lead titanate (PbTiO3), Lead zirconate titanate (Pb[ZrxTi1-x]O3 0<x<1) - More commonly known as PZT, Potassium niobate (KNbO3), Lithium niobate (LiNbO3), Lithium tantalate (LiTaO3), Sodium tungstate (NaxWO3), Ba2NaNb5O5, Pb2KNb5O15  Polymers: Polyvinylidene fluoride (PVDF)
  • 14. Sonic and Ultrasonic Applications  Sonar with Ultrasonic time- domain reflectometers  Materials testing to detect flaws inside cast metals and stone objects as well as measure elasticity or viscosity in gases and liquids  Compact sensitive microphones and guitar pickups.  Loudspeakers
  • 15. Pressure Applications  Transient pressure measurement to study explosives, internal combustion engines (knock sensors), and any other vibrations, accelerations, or impacts.  Piezoelectric microbalances are used as very sensitive chemical and biological sensors.  Transducers are used in electronic drum pads to detect the impact of the drummer's sticks.  Energy Harvesting from impact on the ground  Atomic force and scanning tunneling microscopes.  Electric igniters and cigarette lighters
  • 16. Consumer Electronics Applications  Quartz crystals resonators as frequency stabilizers for oscillators in all computers.  Phonograph pick-ups  Accelerometers: In a piezoelectric accelerometer a mass is attached to a spring that is attached to a piezoelectric crystal. When subjected to vibration the mass compresses and stretches the piezo electric crystal. (iPhone)
  • 17. Motor Applications  Piezoelectric elements can be used in laser mirror alignment, where their ability to move a large mass (the mirror mount) over microscopic distances is exploited. By electronically vibrating the mirror it gives the light reflected off it a Doppler shift to fine tune the laser's frequency.  The piezo motor is viewed as a high- precision replacement for the stepper motor.  Traveling-wave motors used for auto-focus in cameras.
  • 18. Procedure 1) Attach a mirror to the piezoelectric buzzer. Position that laser so that the beam can reflect off of the mirror and hit the wall across the room. 2) Connect the function generator to the Piezoelectric device. Find the resonant frequency of the device by slowly increasing the frequency at 10Vp-p.The laser will vibrate the most at the resonant frequency. 3) Measure the diameter of the laser without any signal. Then measure the diameter of the laser with the AC signal applied. 4) Calculate the displacement of the laser and divide it by two to get the amplitude of the magnified change in volume for the piezoelectric material. 5) Measure the distance from the piezo to the wall and to the laser. Also measure the height of the laser and reflected beam in relation to the piezo. 6) Calculate the change in volume for the piezoelectric material.
  • 19.
  • 20. Error Analysis The laser’s diameter expands over a distance. The quality of the mirror scatters the laser. The sinusoidal vibration of the material amplifies the laser’s displacement.
  • 21. Works Cited  Images: 1. http://en.wikipedia.org/wiki/Image:SchemaPiezo.gif 2. http://images.google.com/imgres?imgurl=http://www.hvwtech.com/products/266/35170_PV.jpg&imgrefurl=http://www.hvwtech.com/products = 3. http://images.google.com/imgres?imgurl=http://surveying.wb.psu.edu/psu-surv/SURIs/Images/NOAA_sonar.gif&imgrefurl=http://surveying.wb. = 4. http://images.google.com/imgres?imgurl=http://www.pc-control.co.uk/images/curie1.jpg&imgrefurl=http://www.pc-control.co.uk/piezoelectric_ = 5.http://www1.eere.energy.gov/vehiclesandfuels/pdfs/deer_2005/session1/2005_deer_troy.pdf 6. http://ch.mt.com/mt_ext_files/FilterHierarchy/ProductFamily/1/MX-UMX_FilterHierarchy-ProductFamily_1101466637484_files/micro_big.jpg 7. http://images.google.com/imgres?imgurl=http://euroross.blogspot.com/Moscow%2520Traffic%25202.jpg&imgrefurl=http://euroross.blogspot.c = 8. http://images.google.com/imgres?imgurl=http://farm1.static.flickr.com/116/252342964_2fffa201a8.jpg&imgrefurl=http://www.flickr.com/photo =  Information: 1. http://www.piezo.com/tech1terms.html 2. http://www.piezo.com/tech4history.html 3. http://www.piezoelectrics.net/piezoelectrichistory.htm 4. http://www.americanpiezo.com/piezo_theory/index.html 5. http://www.cedrat-groupe.com/ 6. http://www.sensotec.com/accelerometer_faq.asp?category=All 7. http://www.apple.com/iphone/features/index.html#accelerometer 8. http://www.patent-invent.com/electricity/inventions/piezoelectricity.html 9. http://en.wikipedia.org/wiki/Piezoelectricity

Editor's Notes

  1. They combined their knowledge of pyroelectricity with their understanding of the underlying crystal structures that gave rise to pyroelectricity to predict crystal behavior.
  2. Perovskite: An oxide having the same crystalline structure as the mineral, CaTiO 3 Above the Curie point each perovskite crystal in the fired ceramic element exhibits a simple cubic symmetry
  3. Sonar: Transducers that are a mosaic of thin quartz crystals glued between two steel plates (the composite having a resonant frequency of about 50 KHz), mounted in a housing suitable for submersion. It emits a high frequency &amp;quot;chirp&amp;quot; underwater and measures depth by timing the return echo. Materials testing: elastic and viscous properties of liquids and gases could be determined with comparative ease, and previously invisible flaws in solid metal structural members could be detected
  4. Automotive engine management systems use a piezoelectric transducer to detect detonation, by sampling the vibrations of the engine block.
  5. Piezo motors are driven by dual orthogonal vibration modes with a phase shift of 90°, the contact point between two surfaces vibrates in an elliptical path, producing a frictional force between the surfaces. Usually, one surface is fixed causing the other to move. In most piezoelectric motors the piezoelectric crystal is excited by a sine wave signal at the resonant frequency of the motor.
  6. Me: 3 6 7 11 12 13 16 17 19 20 22 Moe: 4 5 8 9 10 14 15 18 21 22