Periodic Table of ElementsPeriodic Table of Elements
Periodic TablePeriodic Table
Is a tabular arrangement of the
chemical elements organized on
the basis of their atomic number,
electronic configurations and
recurring chemical properties.
Development of the
Periodic Table
Johann Wolfgang Dobereiner’sJohann Wolfgang Dobereiner’s
Triads (1817)Triads (1817)
He grouped the elements, which
exhibit very similar characteristics
into triads.
The atomic weight of the second
element was found to be the
average of the first and third
elements.
Atomic weight could be used to
determine the position of the
elements in the periodic table.
Berzelius (1828)Berzelius (1828)
published his table of atomic masses
containing 54 elements. Most of his
values conform with those in the
modern periodic table.
John Newlands (1864)John Newlands (1864)
 an English chemist, arranged the
elements in an order of increasing
atomic mass.
He arranged elements in groups
with seven members each similar to
the octave of the musical scale.
Referred to as Newlands’ Law of
Octaves.
Julius Lothar Meyer (1830-1895)Julius Lothar Meyer (1830-1895)
o He was working on his periodic table
consisting of 56 elements.
o He maintained that the properties of
the elements were functions of their
atomic mass and prepared a graph
wherein he plotted the atomic
volume of the elements against its
atomic mass.
Dmitri MendeleevDmitri Mendeleev
In 1869, he created the first acceptedIn 1869, he created the first accepted
version of the periodic table.version of the periodic table.
He arranged the elements in order ofHe arranged the elements in order of
increasing atomic weight providingincreasing atomic weight providing
intervals on periods which were notintervals on periods which were not
always of the same length. always of the same length. 
Blank spaces were left open to addBlank spaces were left open to add
the new elements he predicted wouldthe new elements he predicted would
occur.occur.
The early periodic tables were
arranged according to increasing
atomic weights and this misplaced
several elements, such as Argon, Ar
(A= 40)and Potassium, K (A=39),
Cobalt, Co (A= 58.9) and Nickel, Ni
(A= 58.7), Tellerium, Te (A= 128) and
Iodine, I (A=127) in the periodic
table.
Henry Moseley (1911)Henry Moseley (1911)
He suggested that it was the charge
of the nucleus and not the atomic
weight that accounted for the
periodic trends in the properties of the
elements. Thus, the position of
elements in the periodic table is
showed by the atomic number.
This concept gave rise to the Modern
Periodic Table.
The Modern Periodic LawThe Modern Periodic Law

states that there is a periodicstates that there is a periodic
repetition of chemical and physicalrepetition of chemical and physical
properties of the elements whenproperties of the elements when
they are arranged in increasingthey are arranged in increasing
atomic number.atomic number.
Features of the PeriodicFeatures of the Periodic
TableTable
The periodic table is divided into
horizontal rows called PERIODS or
SERIES and the vertical columns are
called GROUPS or FAMILIES.
Periods are assigned in Arabic
numerals 1 to 7.
Families are assigned in Roman
numerals (paired with A or B)
IA to VIIIA and IB to VIIIB
Metals, Non-Metals andMetals, Non-Metals and
MetalloidsMetalloids
Elements can be classified as metals,
non-metals and metalloids.
Metals are elements that are good
conductors of heat and electricity,
generally shiny, solid at room
temperature, malleable and ductile.
 Non-Metals are elements that are
poor conductors of electricity and
heat and generally gases and brittle
solids.
 Metalloids are elements that exhibit
some properties of metals and
some properties of non-metals.
The elements in the periodicThe elements in the periodic
table divided into groupstable divided into groups
namely:namely:
1.1. Main-group (representative)Main-group (representative)
elementselements
2.2. Transition elementsTransition elements
3.3. Inner transition elementsInner transition elements
Main Group
(Representative
Elements)
Alkali Metals (Li, Na, K, Rb, Cs, Fr)
The alkali family is found
in the first column of the
periodic table.
 Alkali metals are found
in Group 1A or 1
Atoms of the alkali
metals have a single
electron in their
outermost level, in other
words, 1 valence
electron.
Alkali Metals They are the most
reactive metals.
 They react with
water to release
hydrogen gas.
Alkali metals are
never found as
free elements in
nature. They are
always bonded
with another
element.
Alkaline Earth Metals
(Be, Mg, Ca, Sr, Ba, Ra)
They are found in Group IIA or 2
 They have two valence electrons.
They are very reactive, but not as much as
the alkali metals.
Boron Family
The Boron Family is
named after the first
element in the family.
 They are found in
Group IIIA or 13.
Atoms in this family
have 3 valence
electrons.
 B, Al, Ga, In, Tl are
the elements belong
to the group.
Carbon Family
Atoms of this family
have 4 valence
electrons.
 They found in Group IVA
or 14.
This family includes C, Si,
Ge, Sn, Pb
Nitrogen Family
 The nitrogen family is
named after the
element that makes up
78% of our atmosphere.
 They can be found in
Group VA or 15
 Atoms in the nitrogen
family have 5 valence
electrons. They tend to
share electrons when
they bond.
 Other elements in this
family are phosphorus,
arsenic, antimony, and
bismuth.
Oxygen Family
 Atoms of this family have
6 valence electrons.
 They belong to Group VIA
or 16.
 Most elements in this
family share electrons
when forming
compounds.
 This family includes S, Se,
Te, Po
Halogen Family
The elements in
this family are
fluorine, chlorine,
bromine, iodine,
and astatine.
They can be found
in Group VIIA or
17.
Halogens have 7
valence electrons.
They react with alkali
metals to form salts.
Transition Metals
 Transition Elements
include those
elements in the B
families.
 These are the metals
you are probably
most familiar: copper,
tin, zinc, iron, nickel,
gold, and silver.
 They are good
conductors of heat
and electricity.
Transition Metals
 The compounds of transition metals are usually
brightly colored and are often used to color
paints.
 Transition elements have 1 or 2 valence electrons,
which they lose when they form bonds with other
atoms.
Noble Gases
 Noble Gases are colorless gases that are extremely
un-reactive.
 One important property of the noble gases is their
inactivity. They are inactive because their
outermost energy level is full.
 Because they do not readily combine with other
elements to form compounds, the noble gases are
called inert.
 The family of noble gases includes helium, neon,
argon, krypton, xenon, and radon.
 All the noble gases are found in small amounts in
the earth's atmosphere.
Rare Earth Elements
The thirty rare earth
elements are
composed of the
lanthanide and
actinide series.
One element of the
lanthanide series
and most of the
elements in the
actinide series are
called trans-
uranium, which
means synthetic or
man-made.
Electron Configurations and theElectron Configurations and the
Periodic TablePeriodic Table
Elements belonging to the same
group have the same number of
valence electrons.
Elements belonging to the same
period have the same number of
shells.
The s, p, d and f blocks ofThe s, p, d and f blocks of
elementselements
Elements are easily differentiated
from one another because of
differences in the number of their
outermost electrons.
 The first 2 columns to the right of the
periodic table fill up the nsns orbitals
and are referred to as s-block
elements.
o The last 6 columns fill up the npnp
orbitals and are called the p-block
elements.
o Between the s-block and the p-block
elements are 10 columns which fill up
the (n-1)d orbitals. These are the d-
block elements.
o On the lower part of the Periodic
Table are two series of elements
which fill up the (n-2) f orbital and are
called the f-block elements.
Predicting Periods and GroupsPredicting Periods and Groups
The period and groups of an element
can be predicted from the electron
configuration of that element.
 The following guidelines can help in
determining the period and group of
an elements.
 If the electron configuration of the element ends in
s or p, then the element belongs to family A;
otherwise, the element belongs to family B.
 The outermost energy of the element corresponds
to its period.
 For an element belonging to family A, the number
of electrons in the outermost energy level
corresponds to the group of the elements.
 For an element belonging to B (provided that the
electron configuration does not end in f the total
number of electrons in the outermost energy in
level and the incomplete inner sub-level is equal to
the group number except for the following sums
whose corresponding groups are indicated.
Practice Exercise:
Noble Gas Core Notation
This is the shorthand way of writing
the electronic configuration of an
element.
The noble gas that precedes a given
element is called the core element of
the given element.
Steps in Writing the Noble
Gas Notation:
1. Put symbol for noble gas from the
previous row in brackets.
2. Start at the beginning of the row
where the element is located.
3. Move to the right, writing down any
sublevels (blocks) that you move
through.
Practice Exercise:
Trends in theTrends in the
Periodic TablePeriodic Table
Periodic Trends
 are specific patterns that are present
in the periodic table that illustrate
different aspects of a certain element,
including its size and its electronic
properties.
1. Atomic Size
 Usually expressed as an atomic
radius measured in picometers.
 Atomic radius is equal to half the
distance between the nuclei of two
atoms of the same element when
they are joined.
 Atomic size increases as you move
down a group.
Going down a row adds another
energy level of electrons.
Atomic sizes decreases as you
move from left to right across a
period.
 Moving from left to right there is an
increase in protons causing greater
attraction to electrons.
2. Ionization Energy
 is the energy required to remove
an electron from an atom.
Shielding Effect
-- when inner electrons block the
positive charge from outer
electrons.
 Ionization energy tends to
decrease down a group in the
periodic table.
The farther, the distance of an
electron from the nucleus the
more easily it can be removed.
 Ionization energy tends to
increases from left to right across a
period.
Atoms with fewer electrons hold
on to the more tightly.
3. Electronegativity
 is the ability of an atom to attract
electrons to itself.
Electronegativity decreases from
top to bottom and increases from
left to right of the periodic table.
4. Electron Affinity
 is the amount of energy released or
exerted when an atom gains an
electron.
The electron affinity of an atom can be
described either as the energy gained
by an atom when an electron is added
to it.
 Down a group the electron affinity of
the elements decreases.
 Electron Affinity increases within a
period.
5. Metallic Property
 Within a period of the periodic
table, the elements become more
nonmetallic from left to right across
a series.
Within a group or from top to
bottom metallic properties
increase.
 Periodic Properties of the elements
Electron affinity
Ionization energy
Ionizationenergy
Electronaffinity
Atomicradius
Atomic radius
Nonmetallic character
metallic character
 Atomic properties and the periodic table a summary
Atomic Properties

Periodic table Development and Trends

  • 1.
    Periodic Table ofElementsPeriodic Table of Elements
  • 2.
    Periodic TablePeriodic Table Isa tabular arrangement of the chemical elements organized on the basis of their atomic number, electronic configurations and recurring chemical properties.
  • 3.
  • 4.
    Johann Wolfgang Dobereiner’sJohannWolfgang Dobereiner’s Triads (1817)Triads (1817) He grouped the elements, which exhibit very similar characteristics into triads. The atomic weight of the second element was found to be the average of the first and third elements. Atomic weight could be used to determine the position of the elements in the periodic table.
  • 5.
    Berzelius (1828)Berzelius (1828) publishedhis table of atomic masses containing 54 elements. Most of his values conform with those in the modern periodic table.
  • 6.
    John Newlands (1864)JohnNewlands (1864)  an English chemist, arranged the elements in an order of increasing atomic mass. He arranged elements in groups with seven members each similar to the octave of the musical scale. Referred to as Newlands’ Law of Octaves.
  • 8.
    Julius Lothar Meyer(1830-1895)Julius Lothar Meyer (1830-1895) o He was working on his periodic table consisting of 56 elements. o He maintained that the properties of the elements were functions of their atomic mass and prepared a graph wherein he plotted the atomic volume of the elements against its atomic mass.
  • 10.
    Dmitri MendeleevDmitri Mendeleev In1869, he created the first acceptedIn 1869, he created the first accepted version of the periodic table.version of the periodic table. He arranged the elements in order ofHe arranged the elements in order of increasing atomic weight providingincreasing atomic weight providing intervals on periods which were notintervals on periods which were not always of the same length. always of the same length.  Blank spaces were left open to addBlank spaces were left open to add the new elements he predicted wouldthe new elements he predicted would occur.occur.
  • 12.
    The early periodictables were arranged according to increasing atomic weights and this misplaced several elements, such as Argon, Ar (A= 40)and Potassium, K (A=39), Cobalt, Co (A= 58.9) and Nickel, Ni (A= 58.7), Tellerium, Te (A= 128) and Iodine, I (A=127) in the periodic table.
  • 13.
    Henry Moseley (1911)HenryMoseley (1911) He suggested that it was the charge of the nucleus and not the atomic weight that accounted for the periodic trends in the properties of the elements. Thus, the position of elements in the periodic table is showed by the atomic number. This concept gave rise to the Modern Periodic Table.
  • 15.
    The Modern PeriodicLawThe Modern Periodic Law  states that there is a periodicstates that there is a periodic repetition of chemical and physicalrepetition of chemical and physical properties of the elements whenproperties of the elements when they are arranged in increasingthey are arranged in increasing atomic number.atomic number.
  • 16.
    Features of thePeriodicFeatures of the Periodic TableTable The periodic table is divided into horizontal rows called PERIODS or SERIES and the vertical columns are called GROUPS or FAMILIES. Periods are assigned in Arabic numerals 1 to 7. Families are assigned in Roman numerals (paired with A or B) IA to VIIIA and IB to VIIIB
  • 18.
    Metals, Non-Metals andMetals,Non-Metals and MetalloidsMetalloids Elements can be classified as metals, non-metals and metalloids. Metals are elements that are good conductors of heat and electricity, generally shiny, solid at room temperature, malleable and ductile.
  • 19.
     Non-Metals areelements that are poor conductors of electricity and heat and generally gases and brittle solids.  Metalloids are elements that exhibit some properties of metals and some properties of non-metals.
  • 20.
    The elements inthe periodicThe elements in the periodic table divided into groupstable divided into groups namely:namely: 1.1. Main-group (representative)Main-group (representative) elementselements 2.2. Transition elementsTransition elements 3.3. Inner transition elementsInner transition elements
  • 21.
  • 22.
    Alkali Metals (Li,Na, K, Rb, Cs, Fr) The alkali family is found in the first column of the periodic table.  Alkali metals are found in Group 1A or 1 Atoms of the alkali metals have a single electron in their outermost level, in other words, 1 valence electron.
  • 23.
    Alkali Metals Theyare the most reactive metals.  They react with water to release hydrogen gas. Alkali metals are never found as free elements in nature. They are always bonded with another element.
  • 24.
    Alkaline Earth Metals (Be,Mg, Ca, Sr, Ba, Ra) They are found in Group IIA or 2  They have two valence electrons. They are very reactive, but not as much as the alkali metals.
  • 25.
    Boron Family The BoronFamily is named after the first element in the family.  They are found in Group IIIA or 13. Atoms in this family have 3 valence electrons.  B, Al, Ga, In, Tl are the elements belong to the group.
  • 26.
    Carbon Family Atoms ofthis family have 4 valence electrons.  They found in Group IVA or 14. This family includes C, Si, Ge, Sn, Pb
  • 27.
    Nitrogen Family  Thenitrogen family is named after the element that makes up 78% of our atmosphere.  They can be found in Group VA or 15  Atoms in the nitrogen family have 5 valence electrons. They tend to share electrons when they bond.  Other elements in this family are phosphorus, arsenic, antimony, and bismuth.
  • 28.
    Oxygen Family  Atomsof this family have 6 valence electrons.  They belong to Group VIA or 16.  Most elements in this family share electrons when forming compounds.  This family includes S, Se, Te, Po
  • 29.
    Halogen Family The elementsin this family are fluorine, chlorine, bromine, iodine, and astatine. They can be found in Group VIIA or 17. Halogens have 7 valence electrons. They react with alkali metals to form salts.
  • 30.
    Transition Metals  TransitionElements include those elements in the B families.  These are the metals you are probably most familiar: copper, tin, zinc, iron, nickel, gold, and silver.  They are good conductors of heat and electricity.
  • 31.
    Transition Metals  Thecompounds of transition metals are usually brightly colored and are often used to color paints.  Transition elements have 1 or 2 valence electrons, which they lose when they form bonds with other atoms.
  • 32.
    Noble Gases  NobleGases are colorless gases that are extremely un-reactive.  One important property of the noble gases is their inactivity. They are inactive because their outermost energy level is full.  Because they do not readily combine with other elements to form compounds, the noble gases are called inert.  The family of noble gases includes helium, neon, argon, krypton, xenon, and radon.  All the noble gases are found in small amounts in the earth's atmosphere.
  • 33.
    Rare Earth Elements Thethirty rare earth elements are composed of the lanthanide and actinide series. One element of the lanthanide series and most of the elements in the actinide series are called trans- uranium, which means synthetic or man-made.
  • 35.
    Electron Configurations andtheElectron Configurations and the Periodic TablePeriodic Table Elements belonging to the same group have the same number of valence electrons. Elements belonging to the same period have the same number of shells.
  • 36.
    The s, p,d and f blocks ofThe s, p, d and f blocks of elementselements Elements are easily differentiated from one another because of differences in the number of their outermost electrons.  The first 2 columns to the right of the periodic table fill up the nsns orbitals and are referred to as s-block elements.
  • 37.
    o The last6 columns fill up the npnp orbitals and are called the p-block elements. o Between the s-block and the p-block elements are 10 columns which fill up the (n-1)d orbitals. These are the d- block elements. o On the lower part of the Periodic Table are two series of elements which fill up the (n-2) f orbital and are called the f-block elements.
  • 39.
    Predicting Periods andGroupsPredicting Periods and Groups The period and groups of an element can be predicted from the electron configuration of that element.  The following guidelines can help in determining the period and group of an elements.
  • 40.
     If theelectron configuration of the element ends in s or p, then the element belongs to family A; otherwise, the element belongs to family B.  The outermost energy of the element corresponds to its period.  For an element belonging to family A, the number of electrons in the outermost energy level corresponds to the group of the elements.  For an element belonging to B (provided that the electron configuration does not end in f the total number of electrons in the outermost energy in level and the incomplete inner sub-level is equal to the group number except for the following sums whose corresponding groups are indicated.
  • 41.
  • 42.
    Noble Gas CoreNotation This is the shorthand way of writing the electronic configuration of an element. The noble gas that precedes a given element is called the core element of the given element.
  • 43.
    Steps in Writingthe Noble Gas Notation: 1. Put symbol for noble gas from the previous row in brackets. 2. Start at the beginning of the row where the element is located. 3. Move to the right, writing down any sublevels (blocks) that you move through.
  • 45.
  • 46.
    Trends in theTrendsin the Periodic TablePeriodic Table
  • 47.
    Periodic Trends  arespecific patterns that are present in the periodic table that illustrate different aspects of a certain element, including its size and its electronic properties.
  • 48.
    1. Atomic Size Usually expressed as an atomic radius measured in picometers.  Atomic radius is equal to half the distance between the nuclei of two atoms of the same element when they are joined.
  • 50.
     Atomic sizeincreases as you move down a group. Going down a row adds another energy level of electrons. Atomic sizes decreases as you move from left to right across a period.  Moving from left to right there is an increase in protons causing greater attraction to electrons.
  • 52.
    2. Ionization Energy is the energy required to remove an electron from an atom. Shielding Effect -- when inner electrons block the positive charge from outer electrons.
  • 53.
     Ionization energytends to decrease down a group in the periodic table. The farther, the distance of an electron from the nucleus the more easily it can be removed.  Ionization energy tends to increases from left to right across a period. Atoms with fewer electrons hold on to the more tightly.
  • 55.
    3. Electronegativity  isthe ability of an atom to attract electrons to itself. Electronegativity decreases from top to bottom and increases from left to right of the periodic table.
  • 56.
    4. Electron Affinity is the amount of energy released or exerted when an atom gains an electron. The electron affinity of an atom can be described either as the energy gained by an atom when an electron is added to it.  Down a group the electron affinity of the elements decreases.  Electron Affinity increases within a period.
  • 57.
    5. Metallic Property Within a period of the periodic table, the elements become more nonmetallic from left to right across a series. Within a group or from top to bottom metallic properties increase.
  • 58.
     Periodic Propertiesof the elements Electron affinity Ionization energy Ionizationenergy Electronaffinity Atomicradius Atomic radius Nonmetallic character metallic character  Atomic properties and the periodic table a summary Atomic Properties