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Chemical bond
by mohsin
By
Azim
khan
Octet Rule-
bond
ion
ozone
changes
Valence shell electron pair
repulsion (VSEPR) theory
VSEPR theory
Lewis dot structure fail to explain correct 3D shape of molecule.
VSEPR theory
state that
electron pair
repel each
other make
shape.
Example of VSEPR
Condition for combination of atomic orbital.
Both atom have same energy.eg. 1s orbit combine with 1s. 1s doesn't combine
with 2s.
Both atom have same symmetry .eg. 2Px orbit combine with 2Px. 2Px doesn't
combine with 2Pz.
Both atom have overlap.
O2 is paramagnetic while C2 is diamagnetic?
Paramagnetic substance are those which attract magnetic field. Paramagnetic
arise those ion, molecule which contain unpaired electron.
O = 1s2 2s2 2px
2 , 2P2
y, 2p1
z
Diamagnetic substance are those which repelled magnetic field. Diamagnetism
arise those ion or molecule which contain paired electron.
Unpaird electron
C = 1s2 2s2 2px
2
Hydrogen bonding
“Attractive force which bind H-atom to another electronegative atom.”
It is weaker then covalent bond.
H bond with other electronegative element like F,Cl,Br,O etc.
H2O exist as liquid while H2S exist in gas?
Electronegative of ‘O’ is higher then ‘S’.
Hence electronegativity of H2O is higher then H2S.
Hydrogen bond in H2O is stronger then H2S.
hence water is liquid and hydrogen sulphide is gas.
Density of ice is lesser then water.
At atmospheric pressure, ice is hexagonal form and low T become cube.
Ice has highly ordered 3D hydrogen bond structure.
Due to H-bonding ice get open structure with wide holes.
Therefore ice density lesser then water.
LiBr is more covalent bond the LiCl?
Br- anion is larger then Cl- anion.
Due to greater the size of anion stronger bonding.
Nature of chemical bond 2017
Nature of chemical bond 2017
Nature of chemical bond 2017
Nature of chemical bond 2017
Nature of chemical bond 2017
Nature of chemical bond 2017
Nature of chemical bond 2017
Nature of chemical bond 2017
Nature of chemical bond 2017
Nature of chemical bond 2017
Nature of chemical bond 2017
Nature of chemical bond 2017
Nature of chemical bond 2017
Nature of chemical bond 2017
Nature of chemical bond 2017

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Nature of chemical bond 2017

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  • 142. Valence shell electron pair repulsion (VSEPR) theory
  • 143. VSEPR theory Lewis dot structure fail to explain correct 3D shape of molecule.
  • 144. VSEPR theory state that electron pair repel each other make shape.
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  • 156. Condition for combination of atomic orbital. Both atom have same energy.eg. 1s orbit combine with 1s. 1s doesn't combine with 2s. Both atom have same symmetry .eg. 2Px orbit combine with 2Px. 2Px doesn't combine with 2Pz. Both atom have overlap.
  • 157. O2 is paramagnetic while C2 is diamagnetic? Paramagnetic substance are those which attract magnetic field. Paramagnetic arise those ion, molecule which contain unpaired electron. O = 1s2 2s2 2px 2 , 2P2 y, 2p1 z Diamagnetic substance are those which repelled magnetic field. Diamagnetism arise those ion or molecule which contain paired electron. Unpaird electron C = 1s2 2s2 2px 2
  • 158. Hydrogen bonding “Attractive force which bind H-atom to another electronegative atom.” It is weaker then covalent bond. H bond with other electronegative element like F,Cl,Br,O etc.
  • 159.
  • 160. H2O exist as liquid while H2S exist in gas? Electronegative of ‘O’ is higher then ‘S’. Hence electronegativity of H2O is higher then H2S. Hydrogen bond in H2O is stronger then H2S. hence water is liquid and hydrogen sulphide is gas.
  • 161. Density of ice is lesser then water. At atmospheric pressure, ice is hexagonal form and low T become cube. Ice has highly ordered 3D hydrogen bond structure. Due to H-bonding ice get open structure with wide holes. Therefore ice density lesser then water.
  • 162. LiBr is more covalent bond the LiCl? Br- anion is larger then Cl- anion. Due to greater the size of anion stronger bonding.