This document outlines mercury spill cleanup procedures from the Department of University Safety & Assurances. It details the hazards of mercury, personal protective equipment needs, and steps to contain, control, clean up, and dispose of mercury spills. These include using spill powder, a mercury vacuum, and proper disposal of contaminated waste. The document stresses prevention and contains information on who to contact for assistance with a mercury spill.

1. Anbr Cama
Presents
Mercury Spill CleanupMercury Spill Cleanup
ProceduresProcedures
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2. Department of University Safety &
Assurances
Mercury Spill CleanupMercury Spill Cleanup
ProceduresProcedures

3. US&A (v. 2/07)
Mercury is a Hazardous Material
• Mercury (Hg) is a
hazardous material
as defined by:
• U.S. Environmental
Protection Agency
• Wisconsin
Department of
Natural Resources
• U.S. Dept. of
Transportation

4. US&A (v. 2/07)
• Mercury poisoning can result in
severe health problems affecting
the nervous system and other
organs.
• Tremors
• Changes in vision or hearing
• Insomnia
• Weakness
• Difficulty with memory
• Headaches
• Irritability
• Shyness and nervousness
• Acrodynia (painful extremities), a
condition caused by chronic exposure to
mercury
Mercury is a Toxic Substance

5. US&A (v. 2/07)
Mercury Exposure & Prevention
• Routes of exposure
• Inhalation
• Main hazard
• Evaporates releasing
hazardous vapors
• Skin absorption
• Personal Protective
Equipment Required
• Nitrile gloves
• Safety glasses
• Closed-toed shoes
• Lab coat

6. US&A (v. 2/07)
• Questions regarding mercury or
spill procedures should directed to:
• Professor
• Laboratory supervisor
• Own supervisor
• UWM Department of Safety &
Assurances at x6339
• Note: Any release greater than one
pound (two tablespoons) to the
environment is a Reportable
Quantity.
Who do you Contact?

7. US&A (v. 2/07)
Spills
• Prevention is the best
way to handle mercury
spills.
• All mercury "spills,"
including droplets of
mercury from a broken
lab thermometer, must
be cleaned up following
safe and
environmentally sound
procedures.

8. US&A (v. 2/07)
• Prevent the spread of
mercury.
• Trays should be used under
equipment wherever a
mercury spill is possible.
• Mercury beads can splash
and roll around.
• Prevent mercury from
entering cracks, crevices,
and drains.
• Do not walk in area of spill.
• Evacuate room via route
away from spill.
Contain Spill

9. US&A (v. 2/07)
• Cease activities.
• Secure the area around the spill,
so the mercury does not get
"tracked" or "kicked" around.
• Keep the area restricted until
the entire spill is cleaned up.
• Lower room temperature to
reduce evaporation.
Restricted Area

10. US&A (v. 2/07)
• Spill powder may be
used as a temporary
control measure.
• Commercial spill kits.
• Mix 85 grams of finely
powdered Sodium
Thiosulfate with 15
grams of finely
powdered EDTA.
Temporary Control

11. US&A (v. 2/07)
Temporary Control
• Cover from the perimeter of the spill
toward the center.
• Do not walk through the spill or spill
powder.
• Pick-up glass and other large debris,
then clean up mercury.
• All debris must be disposed of as hazardous
waste.

12. US&A (v. 2/07)
• A special vacuum
cleaner, which is
designed to pick up
mercury droplets
safely, is available for
cleanup.
• NEVER use a regular
vacuum.
Mercury Vacuum

13. US&A (v. 2/07)
• Chemistry Department:
• Second floor stockroom.
• Contact the stockroom
personnel when needed.
• Other departments:
• Contact University Safety
& Assurances (x6339) for
assistance with spill clean-
up.
Location of Mercury Vacuum

14. US&A (v. 2/07)
• The stockroom
personnel will clean up
the spill.
• You may be trained in
the proper use of the
mercury vacuum.
• UWM Department of
Safety & Assurances
staff may also be
called for assistance.
Use of Mercury Vacuum

15. US&A (v. 2/07)
Other Cleanup Tools
• A side-arm flask connected to a vacuum pump or
sink aspirator can be used to vacuum up small
beads.

16. US&A (v. 2/07)
Other Cleanup Tools
• Wet toweling to consolidate small beads into larger
pieces for vacuuming
• Commercial spill kits
• Disposable
eyedropper
• Adhesive tape
• Cardboard

17. US&A (v. 2/07)
• Special attention
must be given to
cleaning cracks
and crevices
where the
mercury beads
may have easily
settled.
Special Care

18. US&A (v. 2/07)
• Includes the mercury
and all waste materials
contaminated with
mercury.
• Gloves and other
contaminated debris.
• Must be placed in a
labeled leak-proof,
polyethylene container.
Mercury Waste

19. US&A (v. 2/07)
• No mercury,
including broken
thermometers, may
be disposed of in the
normal trash or into
the sewer system.
• UWM Hazardous
Waste Manager
(x4999) will properly
dispose of all waste.
Disposal

20. US&A (v. 2/07)
After Hours:After Hours:
• If no help is available,
contact the University
Police.
• 9-911 in an emergency
(229-9911 by cell phone)
• x4627 if non-emergency.
• Explain that you have a
mercury spill.
• Indicate whether the spill
is small, a broken
thermometer, or large,
more than 1 or 2 ml (1/4
teaspoon).
Assistance After Hours

21. US&A (v. 2/07)
Assistance After Hours
• The police will contact a
University Safety &
Assurances staff member for
assistance.
• If the spill is large or if it
must be cleaned up right
away, you will be directed to:
• Secure the area.
• Wait until response personnel
arrive (usually 30 to 60
minutes).
• The area will be secured/off-
limits until the next working
day.

22. US&A (v. 2/07)
Special Consideration
• Large spills, spills in
confined areas with
poor ventilation, or
spills in areas heated
above room
temperature must be
addressed by trained
personnel with
protective equipment.
A risk of high exposure
to mercury vapors can
occur in these
situations.

23. US&A (v. 2/07)
• Mercury spills are very disruptive.
• Lab personnel are encouraged to use
extreme caution when using mercury or
mercury-containing apparatus.
• Thorough decontamination is essential
to ensure both personal safety and
protection of the environment.
Summary

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