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IOSR Journal of Environmental Science, Toxicology and Food Technology (IOSR-JESTFT)
e-ISSN: 2319-2402,p- ISSN: 2319-2399.Volume 9, Issue 11 Ver. II (Nov. 2015), PP 25-28
www.iosrjournals.org
DOI: 10.9790/2402-091122528 www.iosrjournals.org 25 | Page
Low Cost Anaerobic Treatment of Municipal Solid Waste
Leachate
Pooja Majge1
, Ravindra Gaikwad2
1
(PG student,Chemical Engineering Department, Pravara Rural Engineering College, Loni, India)
2
(Head, Chemical Engineering,Pravara Rural Engineering College, Loni,, India)
Abstract :Anaerobic treatment of municipal solid waste leachate is the treatment process of leachate generated
in solid waste disposal site. Biological treatment removes the most contaminants, by converting it into less
harmful substances. This process is natural process which use the naturally available organisms in the
environment. In this paper the process of anaerobic treatment of municipal solid waste leachate and recovering
the methane gas produced is presented. The UASB bioreactor was operated at 3 different processes i.e. batch
process, semi-continuous process and continuous process. The results of these three processes are compared
and semi-continuous process gives the best results. The results of semi-continuous process at 3 day HRT are
96.6% COD reduction, TVA reduced from 954 mg/L, alkalinity increased from 160 mg/L to 1180 mg/L. Total
solids reduction was 68.14%, suspended solids reduction was 86%, volatile solids reduction was 86.7% and
biogas production was 2650 ml.
Keywords: - Biological anaerobic treatment, batch process, continuous process, semi-continuous process,
solid waste landfill leachate.
I. Introduction
Solid waste management problem has become the greatest concern now a days. Various environmental
pollution problems i.e. contamination of soil, water and other health related problems etc. are caused due to the
traditional method of solid waste disposal. The waste dumped into the landfills are the major sources of
emission of methane to atmosphere which has global warming potential. The main environmental problem of
the landfill sites is infiltration of leachate and its subsequent contamination of surrounding land and aquifers,
odour problem etc. Processes which have been the lowest cost and consistently successfully applied, for
municipal waste landfill leachate from controlled landfills, are biological processes.
Anaerobic treatment of municipal solid waste leachate is a series of processes in which microorganisms
break down the biodegradable material in the absence of oxygen. Anaerobic digestion reduces the emission of
landfill gases into the atmosphere. Anaerobic digestion produces methane gas and CO2 rich digestate which can
be used as fertilizer. Up flow anaerobic sludge blanket reactor (UASB) is a modern anaerobic treatment process
which have high treatment efficient and a short hydraulic retention time.
The work in this paper is divided in two stages. 1) Design and setup of reactor 2) Determination of
various parameters and methane generation study. Reactor includes the designing the cylindrical reactor of
plastic fibre having capacity 26 L arrangement for feeding, gas collection, and draining out the residue. Setup
include stabilization of the reactor. In second stage the operation and determination of various parameters and
methane collection is carried out for 3 day HRT for batch, semi continuous and continuous processes.
II. Reactor Setup
Reactor includes the designing the cylindrical reactor of plastic fibre having capacity 26 L arrangement
for feeding, gas collection, and draining out the residue. Thereafter the municipal solid waste landfill leachate is
collected from charholi village and after passing hot water from that waste leachate is collected and used as feed
for reactor. Inoculum is prepared by mixing 300 gm of cow dung which contains millions of methanogenic
bacteria with 3 L of water and sieved through filter for 3 to 4 times to remove bigger particles and stored in
capped bottle to maintain anaerobic condition. After 20 days 12 L of cow dung slurry mixed with secondary
sludge of treatment plant and stabilized by recirculation process. Fig. 1 shows the reactor setup.
III. Operation Of Reactor
Inside the reactor pressure drops due to sudden contraction and expansion in the organic matter present
inside the reactor. Formation of eddies create sufficient turbulence which help in retaining the solid mass in
suspension by preventing settling of particles.
The up flow pattern of liquid in the column reactor help in the stratification of individual type of
biomass such as hydrolytic, acidogenic biomass and methanogenic biomass.
Low cost anaerobic treatment of municipal solid waste leachate
DOI: 10.9790/2402-091122528 www.iosrjournals.org 26 | Page
Difference in density of water/liquid and biomass/solids creates the velocity difference at same
pumping energy due to difference in densities and velocities.
Clarified liquid is desired to be treated as effluent it may not be possible.
Clarified effluent can be recycled for slurry preparation and so the settled sludge can be considered as
compost.
The generation of biogas makes this process more economical.
IV. Figures And Tables
Fig.1: Reactor set-up of laboratory scale reactor for treatment of MSW leachate.
Figure 2: COD removal (%) profile throughout the process.
Low cost anaerobic treatment of municipal solid waste leachate
DOI: 10.9790/2402-091122528 www.iosrjournals.org 27 | Page
Figure 3: Variation in Total Volatile Acids profile throughout the process at 3 day HRT
Figure 4: Variation in Total Solids (mg/L) conc. in reactor throughout the process.
Fig 5: Graph showing Biogas production throughout different processes.
Low cost anaerobic treatment of municipal solid waste leachate
DOI: 10.9790/2402-091122528 www.iosrjournals.org 28 | Page
V. Conclusion
The best performance of reactor in treatment of landfill leachate was obtained at semi continuous
process at 3 day HRT with 96.6% COD reduction, TVA reduced from 954 mg/L to 20 mg/l, alkalinity increased
from 160 mg/L to 1180 mg/L. Total solid reduction was 68.14 %, suspended solid reduction was 86 %, volatile
solid reduction was 86.7% and biogas production was 2650 ml.
From this study, it is concluded that anaerobic treatment of municipal solid waste landfill leachate is feasible.
References
[1]. Ahn.D.H., Yun-Chul.C., Won-Seok.C.,(2002). Use of coagulant and zeolite to enhance the biological treatment efficiency of high
ammonia leachate. J. Environ. Sci. Heal., 163–173.
[2]. Aktas.O, Cecen.F., (2001) Addition of activated carbon to batch activated sludge reactors in the treatment of landfill leachate and
domestic wastewater, J. Chem. Technol. Biotechnol. 76 ,793–802.
[3]. Alessandro, S., Stefano, M.L., (2008). Nitrogen removal via nitrite in a sequencing batch reactor treating sanitary landfill leachate.
Bioresour. Technol. 99, 609– 614.
[4]. Amokrane.A., C. Comel., J. Veron., (1997), Landfill leachates pretreatment by coagulation–flocculation, Water Res. 31, 2775–
2782.
[5]. APHA., (2005). Standard Methods for the Examination of Water and Waste Water, twenty first ed. American Public Health
Association, Washington, DC.
[6]. Aziz, H.A., Daud, Z., Adlan, M.N., Hung, Y.T., (2009). The use of polyaluminium chloride for removing colour, COD and
ammonia from semi-aerobic leachate. Int. J. Environ. Eng. 1, 20-35
[7]. Bae.B, Jung.E., Kim.Y., Shin.H, (1999), Treatment of landfill leachate using activated sludge process and electron-beam radiation,
Water Res. 33, 2669–2673.
[8]. Baig.S, Coulomb.I.., Courant.P., Liechti.P., (1999) Treatment of landfill leachates: Lapeyrouse and Satrod case studies, Ozone Sci.
Eng. 21, 1–22.
[9]. Bashir,M.J.K., Aziz, H.A., Yusoff,M.S., Adlan,M.N., (2010a). Application of response surface methodology (RSM) for
optimization of ammoniacal nitrogen removal from semiaerobic landfill leachate using ion exchange resin. Desalination 254, 154-
161.
[10]. Berrueta.J, Castrillon.L., (1992), Anaerobic treatment of leachates in UASB reactors, J. Chem. Technol. Biotechnol. 54 33–37.
[11]. Bernd Bilitewski; Georg Härdtle; Klaus Marek (1997): Waste Management. Springer, Berlin, ISBN: 3-540-59210-5.

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Low Cost Anaerobic Treatment of Municipal Solid Waste Leachate

  • 1. IOSR Journal of Environmental Science, Toxicology and Food Technology (IOSR-JESTFT) e-ISSN: 2319-2402,p- ISSN: 2319-2399.Volume 9, Issue 11 Ver. II (Nov. 2015), PP 25-28 www.iosrjournals.org DOI: 10.9790/2402-091122528 www.iosrjournals.org 25 | Page Low Cost Anaerobic Treatment of Municipal Solid Waste Leachate Pooja Majge1 , Ravindra Gaikwad2 1 (PG student,Chemical Engineering Department, Pravara Rural Engineering College, Loni, India) 2 (Head, Chemical Engineering,Pravara Rural Engineering College, Loni,, India) Abstract :Anaerobic treatment of municipal solid waste leachate is the treatment process of leachate generated in solid waste disposal site. Biological treatment removes the most contaminants, by converting it into less harmful substances. This process is natural process which use the naturally available organisms in the environment. In this paper the process of anaerobic treatment of municipal solid waste leachate and recovering the methane gas produced is presented. The UASB bioreactor was operated at 3 different processes i.e. batch process, semi-continuous process and continuous process. The results of these three processes are compared and semi-continuous process gives the best results. The results of semi-continuous process at 3 day HRT are 96.6% COD reduction, TVA reduced from 954 mg/L, alkalinity increased from 160 mg/L to 1180 mg/L. Total solids reduction was 68.14%, suspended solids reduction was 86%, volatile solids reduction was 86.7% and biogas production was 2650 ml. Keywords: - Biological anaerobic treatment, batch process, continuous process, semi-continuous process, solid waste landfill leachate. I. Introduction Solid waste management problem has become the greatest concern now a days. Various environmental pollution problems i.e. contamination of soil, water and other health related problems etc. are caused due to the traditional method of solid waste disposal. The waste dumped into the landfills are the major sources of emission of methane to atmosphere which has global warming potential. The main environmental problem of the landfill sites is infiltration of leachate and its subsequent contamination of surrounding land and aquifers, odour problem etc. Processes which have been the lowest cost and consistently successfully applied, for municipal waste landfill leachate from controlled landfills, are biological processes. Anaerobic treatment of municipal solid waste leachate is a series of processes in which microorganisms break down the biodegradable material in the absence of oxygen. Anaerobic digestion reduces the emission of landfill gases into the atmosphere. Anaerobic digestion produces methane gas and CO2 rich digestate which can be used as fertilizer. Up flow anaerobic sludge blanket reactor (UASB) is a modern anaerobic treatment process which have high treatment efficient and a short hydraulic retention time. The work in this paper is divided in two stages. 1) Design and setup of reactor 2) Determination of various parameters and methane generation study. Reactor includes the designing the cylindrical reactor of plastic fibre having capacity 26 L arrangement for feeding, gas collection, and draining out the residue. Setup include stabilization of the reactor. In second stage the operation and determination of various parameters and methane collection is carried out for 3 day HRT for batch, semi continuous and continuous processes. II. Reactor Setup Reactor includes the designing the cylindrical reactor of plastic fibre having capacity 26 L arrangement for feeding, gas collection, and draining out the residue. Thereafter the municipal solid waste landfill leachate is collected from charholi village and after passing hot water from that waste leachate is collected and used as feed for reactor. Inoculum is prepared by mixing 300 gm of cow dung which contains millions of methanogenic bacteria with 3 L of water and sieved through filter for 3 to 4 times to remove bigger particles and stored in capped bottle to maintain anaerobic condition. After 20 days 12 L of cow dung slurry mixed with secondary sludge of treatment plant and stabilized by recirculation process. Fig. 1 shows the reactor setup. III. Operation Of Reactor Inside the reactor pressure drops due to sudden contraction and expansion in the organic matter present inside the reactor. Formation of eddies create sufficient turbulence which help in retaining the solid mass in suspension by preventing settling of particles. The up flow pattern of liquid in the column reactor help in the stratification of individual type of biomass such as hydrolytic, acidogenic biomass and methanogenic biomass.
  • 2. Low cost anaerobic treatment of municipal solid waste leachate DOI: 10.9790/2402-091122528 www.iosrjournals.org 26 | Page Difference in density of water/liquid and biomass/solids creates the velocity difference at same pumping energy due to difference in densities and velocities. Clarified liquid is desired to be treated as effluent it may not be possible. Clarified effluent can be recycled for slurry preparation and so the settled sludge can be considered as compost. The generation of biogas makes this process more economical. IV. Figures And Tables Fig.1: Reactor set-up of laboratory scale reactor for treatment of MSW leachate. Figure 2: COD removal (%) profile throughout the process.
  • 3. Low cost anaerobic treatment of municipal solid waste leachate DOI: 10.9790/2402-091122528 www.iosrjournals.org 27 | Page Figure 3: Variation in Total Volatile Acids profile throughout the process at 3 day HRT Figure 4: Variation in Total Solids (mg/L) conc. in reactor throughout the process. Fig 5: Graph showing Biogas production throughout different processes.
  • 4. Low cost anaerobic treatment of municipal solid waste leachate DOI: 10.9790/2402-091122528 www.iosrjournals.org 28 | Page V. Conclusion The best performance of reactor in treatment of landfill leachate was obtained at semi continuous process at 3 day HRT with 96.6% COD reduction, TVA reduced from 954 mg/L to 20 mg/l, alkalinity increased from 160 mg/L to 1180 mg/L. Total solid reduction was 68.14 %, suspended solid reduction was 86 %, volatile solid reduction was 86.7% and biogas production was 2650 ml. From this study, it is concluded that anaerobic treatment of municipal solid waste landfill leachate is feasible. References [1]. Ahn.D.H., Yun-Chul.C., Won-Seok.C.,(2002). Use of coagulant and zeolite to enhance the biological treatment efficiency of high ammonia leachate. J. Environ. Sci. Heal., 163–173. [2]. Aktas.O, Cecen.F., (2001) Addition of activated carbon to batch activated sludge reactors in the treatment of landfill leachate and domestic wastewater, J. Chem. Technol. Biotechnol. 76 ,793–802. [3]. Alessandro, S., Stefano, M.L., (2008). Nitrogen removal via nitrite in a sequencing batch reactor treating sanitary landfill leachate. Bioresour. Technol. 99, 609– 614. [4]. Amokrane.A., C. Comel., J. Veron., (1997), Landfill leachates pretreatment by coagulation–flocculation, Water Res. 31, 2775– 2782. [5]. APHA., (2005). Standard Methods for the Examination of Water and Waste Water, twenty first ed. American Public Health Association, Washington, DC. [6]. Aziz, H.A., Daud, Z., Adlan, M.N., Hung, Y.T., (2009). The use of polyaluminium chloride for removing colour, COD and ammonia from semi-aerobic leachate. Int. J. Environ. Eng. 1, 20-35 [7]. Bae.B, Jung.E., Kim.Y., Shin.H, (1999), Treatment of landfill leachate using activated sludge process and electron-beam radiation, Water Res. 33, 2669–2673. [8]. Baig.S, Coulomb.I.., Courant.P., Liechti.P., (1999) Treatment of landfill leachates: Lapeyrouse and Satrod case studies, Ozone Sci. Eng. 21, 1–22. [9]. Bashir,M.J.K., Aziz, H.A., Yusoff,M.S., Adlan,M.N., (2010a). Application of response surface methodology (RSM) for optimization of ammoniacal nitrogen removal from semiaerobic landfill leachate using ion exchange resin. Desalination 254, 154- 161. [10]. Berrueta.J, Castrillon.L., (1992), Anaerobic treatment of leachates in UASB reactors, J. Chem. Technol. Biotechnol. 54 33–37. [11]. Bernd Bilitewski; Georg Härdtle; Klaus Marek (1997): Waste Management. Springer, Berlin, ISBN: 3-540-59210-5.