Carbon nanotubes are fullerene-related structures consisting of graphene cylinders closed at either end with pentagonal rings. There are two main types: single-walled nanotubes (SWNTs), which have diameters around 1 nanometer, and multi-walled nanotubes (MWNTs) made of multiple concentric graphene cylinders. Functionalization of carbon nanotubes is important for applications and can occur through non-covalent interactions like wrapping of surfactants or polymers or through covalent bonding by attaching molecules to existing defects or through reactions to functionalize the graphene sidewalls. The document discusses different methods of non-covalent and covalent functionalization of carbon nanotubes.
Chemical Vapour Deposition is a Chemical Synthesis route of Nanomaterials. Specially thin films like Graphene and Carbon NanoTubes are grown by this method.
Nano Material
Introduction and Synthesis
Nanomaterials describe, in principle, materials of which a single unit is sized (in at least one dimension) between 1 and 1000 nanometres (10−9 meter) but is usually 1—100 nm (the usual definition of nanoscale[1]).
Nanomaterials research takes a materials science-based approach to nanotechnology, leveraging advances in materials metrology and synthesis which have been developed in support of microfabrication research. Materials with structure at the nanoscale often have unique optical, electronic, or mechanical properties.
Nanomaterials are slowly becoming commercialized[2] and beginning to emerge as commodities.[3]
It's simple to understand the synthesis. Hydrothermal method is a chemical reaction in water in a sealed pressure vessel, which is in fact a type of reaction at both high temperature and pressure.
Novel effects can occur in materials when structures are formed with sizes comparable to any one of many possible length scales, such as the de Broglie wavelength of electrons, or the optical wavelengths of high energy photons. In these cases quantum mechanical effects can dominate material properties. One example is quantum confinement where the electronic properties of solids are altered with great reductions in particle size. The optical properties of nanoparticles, e.g. fluorescence, also become a function of the particle diameter. This effect does not come into play by going from macrosocopic to micrometer dimensions, but becomes pronounced when the nanometer scale is reached.
Chemical Vapour Deposition is a Chemical Synthesis route of Nanomaterials. Specially thin films like Graphene and Carbon NanoTubes are grown by this method.
Nano Material
Introduction and Synthesis
Nanomaterials describe, in principle, materials of which a single unit is sized (in at least one dimension) between 1 and 1000 nanometres (10−9 meter) but is usually 1—100 nm (the usual definition of nanoscale[1]).
Nanomaterials research takes a materials science-based approach to nanotechnology, leveraging advances in materials metrology and synthesis which have been developed in support of microfabrication research. Materials with structure at the nanoscale often have unique optical, electronic, or mechanical properties.
Nanomaterials are slowly becoming commercialized[2] and beginning to emerge as commodities.[3]
It's simple to understand the synthesis. Hydrothermal method is a chemical reaction in water in a sealed pressure vessel, which is in fact a type of reaction at both high temperature and pressure.
Novel effects can occur in materials when structures are formed with sizes comparable to any one of many possible length scales, such as the de Broglie wavelength of electrons, or the optical wavelengths of high energy photons. In these cases quantum mechanical effects can dominate material properties. One example is quantum confinement where the electronic properties of solids are altered with great reductions in particle size. The optical properties of nanoparticles, e.g. fluorescence, also become a function of the particle diameter. This effect does not come into play by going from macrosocopic to micrometer dimensions, but becomes pronounced when the nanometer scale is reached.
ان السر الكامن وراء هذا المنتج هو قدرة أجزاء النانو الصغيرة على الاندماج مع أنسجة القماش مما يجعل من طبقة الحماية رقيقة جدا لدرجة انها تصبح غير مرئية لتشكل طبقة حماية قوية تمتد لفترات طويلة من الزمن.
Carbon nanotube is an allotrope of carbon and it is widely used in many Research and Development companies. The presentation will help students to get some idea on this topic.
EFFECT OF FLAME RETARDANT ADDITIVES IN FLAME RETARDANT GRADE OF ABSArjun K Gopi
In this study the effect of flame retardants in flame retardant grade of abs is compared with natural ABS grade. ABS is a flammable material. It is easily burn with high flammability value. ABS materials without flame retardant are easily burned with a luminous yellow flame, smoking strongly and continue to burn after removal of the ignition source. So for some particular applications we are incorporating flame retardants into ABS. But the addition of flame retardants may leads to variation in properties. For that I have done several physical, thermal, and rheological tests to investigate the properties of the respective ABS grades. The results obtained was very interesting
The Internet is amazing, but overwhelming. This list of sites covers a wide array of interests, and each site listed can give you the information that you need without having to spend your valuable time searching and searching. Here are some of the most useful websites on the internet that you may not know about. These web sites, well most of them, solve at least one problem really well and they all have simple web addresses (URLs) that you can memorize.
Original Post http://www.attittudeblogger.in/2016/12/list-of-100-very-useful-websites.html
Richard's aventures in two entangled wonderlandsRichard Gill
Since the loophole-free Bell experiments of 2020 and the Nobel prizes in physics of 2022, critics of Bell's work have retreated to the fortress of super-determinism. Now, super-determinism is a derogatory word - it just means "determinism". Palmer, Hance and Hossenfelder argue that quantum mechanics and determinism are not incompatible, using a sophisticated mathematical construction based on a subtle thinning of allowed states and measurements in quantum mechanics, such that what is left appears to make Bell's argument fail, without altering the empirical predictions of quantum mechanics. I think however that it is a smoke screen, and the slogan "lost in math" comes to my mind. I will discuss some other recent disproofs of Bell's theorem using the language of causality based on causal graphs. Causal thinking is also central to law and justice. I will mention surprising connections to my work on serial killer nurse cases, in particular the Dutch case of Lucia de Berk and the current UK case of Lucy Letby.
A brief information about the SCOP protein database used in bioinformatics.
The Structural Classification of Proteins (SCOP) database is a comprehensive and authoritative resource for the structural and evolutionary relationships of proteins. It provides a detailed and curated classification of protein structures, grouping them into families, superfamilies, and folds based on their structural and sequence similarities.
This pdf is about the Schizophrenia.
For more details visit on YouTube; @SELF-EXPLANATORY;
https://www.youtube.com/channel/UCAiarMZDNhe1A3Rnpr_WkzA/videos
Thanks...!
Multi-source connectivity as the driver of solar wind variability in the heli...Sérgio Sacani
The ambient solar wind that flls the heliosphere originates from multiple
sources in the solar corona and is highly structured. It is often described
as high-speed, relatively homogeneous, plasma streams from coronal
holes and slow-speed, highly variable, streams whose source regions are
under debate. A key goal of ESA/NASA’s Solar Orbiter mission is to identify
solar wind sources and understand what drives the complexity seen in the
heliosphere. By combining magnetic feld modelling and spectroscopic
techniques with high-resolution observations and measurements, we show
that the solar wind variability detected in situ by Solar Orbiter in March
2022 is driven by spatio-temporal changes in the magnetic connectivity to
multiple sources in the solar atmosphere. The magnetic feld footpoints
connected to the spacecraft moved from the boundaries of a coronal hole
to one active region (12961) and then across to another region (12957). This
is refected in the in situ measurements, which show the transition from fast
to highly Alfvénic then to slow solar wind that is disrupted by the arrival of
a coronal mass ejection. Our results describe solar wind variability at 0.5 au
but are applicable to near-Earth observatories.
Observation of Io’s Resurfacing via Plume Deposition Using Ground-based Adapt...Sérgio Sacani
Since volcanic activity was first discovered on Io from Voyager images in 1979, changes
on Io’s surface have been monitored from both spacecraft and ground-based telescopes.
Here, we present the highest spatial resolution images of Io ever obtained from a groundbased telescope. These images, acquired by the SHARK-VIS instrument on the Large
Binocular Telescope, show evidence of a major resurfacing event on Io’s trailing hemisphere. When compared to the most recent spacecraft images, the SHARK-VIS images
show that a plume deposit from a powerful eruption at Pillan Patera has covered part
of the long-lived Pele plume deposit. Although this type of resurfacing event may be common on Io, few have been detected due to the rarity of spacecraft visits and the previously low spatial resolution available from Earth-based telescopes. The SHARK-VIS instrument ushers in a new era of high resolution imaging of Io’s surface using adaptive
optics at visible wavelengths.
Earliest Galaxies in the JADES Origins Field: Luminosity Function and Cosmic ...Sérgio Sacani
We characterize the earliest galaxy population in the JADES Origins Field (JOF), the deepest
imaging field observed with JWST. We make use of the ancillary Hubble optical images (5 filters
spanning 0.4−0.9µm) and novel JWST images with 14 filters spanning 0.8−5µm, including 7 mediumband filters, and reaching total exposure times of up to 46 hours per filter. We combine all our data
at > 2.3µm to construct an ultradeep image, reaching as deep as ≈ 31.4 AB mag in the stack and
30.3-31.0 AB mag (5σ, r = 0.1” circular aperture) in individual filters. We measure photometric
redshifts and use robust selection criteria to identify a sample of eight galaxy candidates at redshifts
z = 11.5 − 15. These objects show compact half-light radii of R1/2 ∼ 50 − 200pc, stellar masses of
M⋆ ∼ 107−108M⊙, and star-formation rates of SFR ∼ 0.1−1 M⊙ yr−1
. Our search finds no candidates
at 15 < z < 20, placing upper limits at these redshifts. We develop a forward modeling approach to
infer the properties of the evolving luminosity function without binning in redshift or luminosity that
marginalizes over the photometric redshift uncertainty of our candidate galaxies and incorporates the
impact of non-detections. We find a z = 12 luminosity function in good agreement with prior results,
and that the luminosity function normalization and UV luminosity density decline by a factor of ∼ 2.5
from z = 12 to z = 14. We discuss the possible implications of our results in the context of theoretical
models for evolution of the dark matter halo mass function.
2. Example Bullet Point Slide
Carbon nanotubes are fullerene-related
structures which consist of graphene
cylinders closed at either end with caps
containing pentagonal rings
CARBON NANOTUBES
3. SINGLE WALLED NANO TUBES
Most single-walled nanotubes (SWNT) have a diameter of
close to 1 nanometer, with a tube length that can be
many millions of times longer
The structure of a SWNT can be conceptualized by
wrapping a one-atom-thick layer of graphite called
graphene into a seamless cylinder
The way the graphene sheet is wrapped is represented by
a pair of indices (n,m) called the chiral vector
The integers n and m denote the number of unit vectors
along two directions in the honeycomb crystal lattice of
graphene
If m = 0, the nanotubes are called "zigzag". If n = m,
the nanotubes are called "armchair". Otherwise, they are
called "chiral"
Zigzag (n,0)
Chiral (n,m)
4. MULTI WALLED NANOTUBES
Multi-walled nanotubes (MWNT) consist of multiple
rolled layers (concentric tubes) of graphite
In the Russian Doll, sheets of graphite are
arranged in concentric cylinders
In the Parchment model, a single sheet of graphite
is rolled in around itself, resembling a scroll of
parchment or a rolled newspaper
5. TREATMENT AND
FUNCTIONALIZATION
CNTs unique properties make them desirable for many different applications.
However, to exploit as much as possible these properties, most of the
applications require the functionalization of carbon nanotubes, such as
changing the surface properties to make nanotubes soluble in different
media, or attaching functional groups or polymer chains for specific
utilizations of modified nanotubes
7. Example Bullet Point SlideEndohedral functionalization; CNTs are
treated by filling their inner empty cavity with different
molecules or nano particles
Schematic representation of a SWNT filled with C60 fullerenes
8. Example Bullet Point Slide
Exohedral functionalization;
It involves grafting of molecules on the outer surface of
nanotubes
Several approaches have been developed and include defect
functionalization covalent functionalization and noncovalent
functionalization with surfactants or polymers
The different types of exohedral functionalization can be
classified via the nature of the interactions between the
surface of carbon nanotubes and the functional groups or
polymer chains
These interactions can rely upon covalent or non-
covalent bonds.
9. Example Bullet Point Slide
• Bullet point
– Sub Bullet
Functionalization possibilities for CNTs: defect functionalization
(A),
covalent sidewall functionalization (B), noncovalent
functionalization with surfactants (C) and polymer wrapping (D)
10. NON-COvALENT
FUNCTIONALIZATION wITh
SUrFACTANT Or POLYmEr
The noncovalent interaction is based on van der Waals forces
or - stacking and it is controlled by thermodynamicsπ π
The great advantage of this type of functionalization relies
upon the possibility of attaching various groups without
disturbing the electronic system of the rolled grapheneπ
sheets of CNTs
The formation of non-covalent aggregates with surfactants is a
suitable method for dispersing individual nanotubes in aqueous
or organic solvents
11. Example Bullet Point Slide
• Bullet point
– Sub Bullet
Interaction of nanotubes with pyrene derivatives
12. Carbon nanotubes can be also wrapped with polymer chains to form supramolecular
complexes of CNTs
Different steps in PE coating of nanotubes is given below
13. Covalent funCtionalization
Two major groups of chemical functionalization of CNTs via
covalent attachment can be distinguished, the end and
“defect-group” chemistry and the sidewall functionalization
end and defeCt-side Chemistry
The functionalization via “end and defect-side” chemistry
consists to graft functional group directly on the already
existing defects in the structure of CNTs
Indeed, carbon nanotubes are generally described as perfect
graphite sheets rolled into nanocylinders.
In reality, all CNTs present defects and can be curved
14. Typical defects in a SWNT
This method was used to graft amine
moieties onto carbon nanotubes via the reaction
with diamines such as triethylenetetramine,
ethylenediamine or 1,6-hexamethylenediamine
The figure shows open end of the SWNT
terminated with –COOH groups. Other
terminal groups, such as –OH, -H and =O, are also
possible
15. sidewall funCtionalization
It involves grafting of chemical groups through reactions onto
the -conjugated skeleton of CNTsπ
The reactivity of CNT sidewalls remains low and sidewall-
functionalization is only successful if a highly reactive reagent
is used, whereas the nanotube caps are quite reactive due to
their fullerene-like structure
Another constraint for sidewall functionalization is the tendency
of CNTs to form
bundles and to limit the available nanotube surface for the
grafting of chemical reagents
A large majority of covalent sidewall functionalizations is
carried out in organic solvent, which allows the utilization of
sonication process to improve the dispersion of CNTs and, thus,
the available surface of carbon nanotubes
16. Schematic describing various common covalent sidewall functionalization reactions of CNTs
using organic solvents